CN114268020B - Al with high refractive index contrast 2 O 3 Al x Ga 1-x As DBR VCSEL manufacturing method - Google Patents

Al with high refractive index contrast 2 O 3 Al x Ga 1-x As DBR VCSEL manufacturing method Download PDF

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CN114268020B
CN114268020B CN202111356428.6A CN202111356428A CN114268020B CN 114268020 B CN114268020 B CN 114268020B CN 202111356428 A CN202111356428 A CN 202111356428A CN 114268020 B CN114268020 B CN 114268020B
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dbr
refractive index
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high refractive
index contrast
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CN114268020A (en
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方照诒
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Shenzhen Jiaminli Photoelectric Co ltd
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Abstract

The invention relates to a high refractive index contrast Al 2 O 3 Al x Ga 1‑x The manufacturing method of the As DBR VCSEL comprises the following steps: major DBR Al over MQW layer x Ga 1‑x As/Al y Ga 1‑y As(x>y,0≤y<1) Medium and high Al% component Al x Ga 1‑x The part of As is completely oxidized to be converted into Al 2 O 3 Forming Al on a desired optical path 2 O 3 /Al y Ga 1‑y As DBR stack structure and by controlling the low Al% component Al nearer to MQW z Ga 1‑z Al whose oxidation rate controlling center of As is not oxidized z Ga 1‑z The size of the As current aperture; then, the peripheral portion is completely oxidized to form Al 2 O 3 Removing by chemical etching to retain Al of optical path 2 O 3 /Al y Ga 1‑y An As DBR stack structure; removing Al of peripheral portion 2 O 3 The space is filled with ohmic metal by one or more of atomic layer deposition, sputtering, evaporation and electroplating to form a low-resistance electrical conduction path.

Description

Al with high refractive index contrast 2 O 3 Al x Ga 1-x As DBR VCSEL manufacturing method
Technical Field
The invention relates to the technical field of VCSEL, in particular to an Al with high refractive index contrast 2 O 3 Al x Ga 1-x An As DBR VCSEL manufacturing method.
Background
The existing resonant cavity reflector is made of Al x Ga 1-x As/Al y Ga 1-y As is epitaxially stacked. Due to the small refractive index difference, a relatively large amount of Al is required x Ga 1-x As/Al y Ga 1-y As stacks to achieve a reflectivity of approximately 99%. AlGaAs is a semiconductor material which is difficult to dope, compared with metal, the resistance of the AlGaAs is higher, and the optical resonant cavity and the electrical channel are overlapped and can be influenced by piezoelectric effect.
Disclosure of Invention
In view of the above, it is necessary to propose a high refractive index contrast Al 2 O 3 Al x Ga 1-x An As DBR VCSEL manufacturing method.
In order to solve the technical problems, the invention adopts the following technical scheme: al with high refractive index contrast 2 O 3 Al x Ga 1-x The manufacturing method of the As DBR VCSEL comprises the following steps: major DBR Al over MQW layer x Ga 1-x As/Al y Ga 1-y As(x>y,0≤y<1) Medium and high Al% component Al x Ga 1-x The part of As (when x is 0.98, n is 3.01) is completely oxidized to be converted into Al 2 O 3 (n-1.67), al is formed on a desired optical path 2 O 3 /Al y Ga 1-y As DBR stack structure with at least one layer of low Al% component Al nearest to MQW in the structure z Ga 1-z As forms a current aperture and the size of the current aperture is controlled by controlling the oxidation rate thereof, wherein the Al% component satisfies x>Max (y, z); completely oxidizing the peripheral portion to form Al 2 O 3 Removing by chemical etching to retain Al of optical path 2 O 3 /Al y Ga 1-y An As DBR stack structure; removing Al of peripheral portion 2 O 3 The space is filled with ohmic metal by one or more of atomic layer deposition, sputtering, evaporation and electroplating to form a low-resistance electrical conduction path.
Further, the method also comprises the steps of previous epitaxial growth, platform etching and upper electrode manufacturing.
Further, the method also comprises the step of removing the Al at the peripheral part 2 O 3 The MQW is protected to be close to Al by negative photoresistance before 2 O 3
Further, al at the peripheral portion 2 O 3 An etching process is used.
Further, the method also comprises the following steps of secondary mesa etching, lower electrode manufacturing, dielectric layer coating and welding pad evaporation.
The invention has the beneficial effects that: converting the portion of the AlGaAs of the high Al% component of the DBR over the MQW layer to Al 2 O 3 With one or more layers of Al nearest to the MQW in the structure z Ga 1-z As(x>y and x>z) forming a current aperture in the unoxidized central part after the oxidation process, controlling the current aperture size by controlling the oxidation rate, so that the current aperture size can be conveniently adjusted and changed, and filling ohmic metal in one or more combination modes of atomic layer deposition, sputtering, evaporation and electroplating to form a low-resistance electric conduction path, thereby forming a high-heat-conduction, low-resistance and high-power conversion efficiency conduction path by AlGaAs/ohmic metal, and reducing Al in the epitaxial stage x Ga 1-x As/Al y Ga 1-y As(x>y,0≤y<1) DBR layer logarithm. The Al% size relationship in the structure is x>z, the mainstream z today>x>y, the highest aluminum component is changed as the current aperture limiting layer.
Drawings
FIG. 1 shows a high refractive index contrast Al according to an embodiment of the present invention 2 O 3 Al x Ga 1-x Al of As DBR VCSEL fabrication method y Ga 1-y Schematic flow chart of technological structure when y=0 in As;
FIG. 2 shows a high refractive index contrast Al according to an embodiment of the present invention 2 O 3 Al x Ga 1-x The flow chart of the As DBR VCSEL manufacturing method is shown.
Detailed Description
To make the objects, technical solutions and advantages of the present invention more apparent, the present invention relates to a high refractive index contrast Al 2 O 3 Al x Ga 1-x The As DBR VCSEL fabrication method is described in further detail. It should be understood that the detailed description hereinThe examples are only for explaining the present invention and are not intended to limit the present invention.
Referring to FIGS. 1-2, a high refractive index contrast Al 2 O 3 Al x Ga 1-x The manufacturing method of the As DBR VCSEL comprises the following steps: major DBR Al over MQW layer x Ga 1-x As/Al y Ga 1-y As(x>y,0≤y<1) Medium and high Al% component Al x Ga 1-x The part of As is completely oxidized to be converted into Al 2 O 3 Forming Al on a desired optical path 2 O 3 /Al y Ga 1- y As DBR stack structure with at least one layer of low Al% component Al nearest to MQW in the structure z Ga 1-z As forms a current aperture and the size of the current aperture is controlled by controlling the oxidation rate thereof, wherein the Al% component satisfies x>Max (y, z); completely oxidizing the peripheral portion to form Al 2 O 3 Removing by chemical etching to retain Al of optical path 2 O 3 /Al y Ga 1-y An As DBR stack structure; removing Al of peripheral portion 2 O 3 The space is filled with ohmic metal by one or more of atomic layer deposition, sputtering, evaporation and electroplating to form a low-resistance electrical conduction path.
Converting the high Al% component AlGaAs (n-3.01) portion of the DBR over the MQW layer to Al 2 O 3 As the lowest Al% component Al in the structure z Ga 1-z As forms a current aperture and controls the size of the current aperture by controlling the oxidation rate thereof, so that the size of the current aperture can be conveniently adjusted and changed, ohmic metal is filled in one or a plurality of combination modes of atomic layer deposition, sputtering, evaporation and electroplating to form a low-resistance electric conduction path, thereby forming a conduction path with high heat conduction, low resistance and high power conversion efficiency by AlGaAs/ohmic metal, and reducing Al in an epitaxial stage x Ga 1-x As/Al y Ga 1-y As(x>y,0≤y<1) DBR layer logarithm. That is, the Al% size relationship in the structure is x>z, the mainstream z today>x>y is different, and the highest aluminum component is changed as currentThe pore size limiting layer is made.
In particular, high Al% component Al x Ga 1-x As (when x is 0.98, n is 3.01, n is refractive index), and Al 2 O 3 The refractive index of (2) approaches 1.67.
It will be appreciated that x > Max (y, z), i.e., x is greater than the maximum of y and z, i.e., x is greater than y and x is greater than z.
Referring to fig. 1 and 2, the method further includes the previous epitaxial growth, mesa etching/upper electrode fabrication.
Referring to FIGS. 1 and 2, the method further comprises removing Al at the peripheral portion 2 O 3 The MQW is protected to be close to Al by negative photoresistance before 2 O 3
Referring to FIGS. 1 and 2, al is present at the peripheral portion 2 O 3 A chemical etching process is employed. The wet etching or dry etching process can be selected according to the requirement.
Referring to fig. 1 and 2, the method further includes a subsequent secondary mesa etching, bottom electrode fabrication, dielectric layer coating, and pad evaporation.
Major DBR Al over MQW layer x Ga 1-x As/Al y Ga 1-y As(x>y,0≤y<1) Medium and high Al% component Al x Ga 1-x The part of As is completely oxidized to be converted into Al 2 O 3 Forming Al on a desired optical path 2 O 3 /Al y Ga 1- y As DBR stack structure and by controlling the low Al% component Al nearer to MQW z Ga 1-z The oxidation rate of As, in turn, controls the Al whose center is not oxidized z Ga 1-z As current pore size, wherein the Al% component satisfies x>y and x>z; completely oxidizing the peripheral portion to form Al 2 O 3 Removing by chemical etching to retain Al of optical path 2 O 3 /Al y Ga 1-y An As DBR stack structure; removing Al of peripheral portion 2 O 3 The space is filled with ohmic metal by one or more of atomic layer deposition, sputtering, evaporation and electroplating to form a low-resistance electrical conduction path.
As can be appreciated, referring to fig. 1 and 2, the overall flow sequentially includes: epitaxially growing to form an epitaxial structure, wherein the epitaxial structure generally mainly comprises an upper DBR layer, an MQW, a lower DBR layer and a substrate; the upper electrode is formed on the primary etching table surface, and the electrode can be formed in a vapor deposition mode generally; oxidation to form HC-DBR (High thermal conductivity-distributed bragg reflectors, highly thermally conductive-distributed Bragg reflector), i.e., the main DBR Al over MQW layer x Ga 1-x As/Al y Ga 1- y As(x>y,0≤y<1) Medium and high Al% component Al x Ga 1-x The part of As (when x is 0.98, n is 3.01) is completely oxidized to be converted into Al 2 O 3 (n-1.67), al is formed on a desired optical path 2 O 3 /Al y Ga 1-y As DBR stack structure with one or more layers of Al nearest to MQW in the structure z Ga 1-z As(x>y and x>z) the central portion which has not been oxidized after the oxidation process forms a current aperture and the size of the current aperture is controlled by controlling the oxidation rate thereof, wherein the Al% component satisfies x>y and x>z; negative photoresist protects MQW from approaching Al 2 O 3 I.e. the upper surface of MQW is exposed out of the primary etching table surface 2 O 3 With the negative resist, the negative resist is typically formed by deposition; chemical etching to remove peripheral Al 2 O 3 I.e. Al formed by complete oxidation of peripheral portions 2 O 3 Removing by chemical etching to retain Al of optical path 2 O 3 /Al y Ga 1-y An As DBR stack structure; ohmic metal filling, namely filling ohmic metal by one or more combination modes of atomic layer deposition, sputtering, evaporation, electroplating and the like to form a low-resistance electric conduction path; etching the secondary mesa, namely immediately etching the lower DBR part below the MQW and above the substrate to form a secondary etched mesa; and manufacturing a lower electrode, namely forming the lower electrode on an electrode contact layer (a part between the lower DBR and the substrate) outside the secondary etching mesa.
Obviously, each ofFor Al 2 O 3 /Al y Ga 1-y The thickness of the As DBR stack layer satisfies the resonant cavity lambda/(2 n) eff ) Wherein lambda is the primary emission wavelength of the laser, n eff The equivalent refractive index at each pair of DBR stacks for that wavelength.
It can be understood that a VCSEL, vertical-Cavity Surface-Emitting Laser (VCSEL for short), translates a Vertical-Cavity Surface-Emitting Laser; MQW, multiple Quantum Well, multiple quantum wells; DBR Distributed Bragg Reflector, bragg mirror when distributed. AL, i.e. aluminium, it being understood that AL 2 O 3 That is, aluminum oxide generally refers to AlGaAs in a VCSEL structure oxidized to Al 2 O 3 Mainly contains a small amount of Ga 2 O 3 GaAs or AlAs. Ga is gallium, and As is arsenic.
It should be noted that, if directional indications (such as up, down, left, right, front, and rear … …) are included in the embodiments of the present invention, the directional indications are merely used to explain the relative positional relationship, movement conditions, etc. between the components in a specific posture (as shown in the drawings), and if the specific posture is changed, the directional indications are correspondingly changed.
In conclusion, the invention provides the Al with high refractive index contrast 2 O 3 Al x Ga 1-x A manufacturing method of As DBR VCSEL converts the high Al% component AlGaAs (n-3.01) part of DBR above MQW layer into Al 2 O 3 As the lowest Al% component Al in the structure z Ga 1-z As forms a current aperture and controls the size of the current aperture by controlling the oxidation rate of the current aperture, so that the size of the current aperture can be conveniently adjusted and changed, and one or more combination modes of atomic layer deposition, sputtering, evaporation, electroplating and the like are used for filling ohmic metal to form a low-resistance electric conduction path, so that an on path with high heat conduction, low resistance and high power conversion efficiency is formed by AlGaAs/ohmic metal. That is, the Al% size relationship in the structure is x>z, the mainstream z today>x>y, the highest aluminum component is changed as the current aperture limiting layer.
The present invention is not limited to the above-mentioned embodiments, but is intended to be limited to the following embodiments, and any modifications, equivalent changes and variations in the above-mentioned embodiments can be made by those skilled in the art without departing from the scope of the present invention.

Claims (5)

1. Al with high refractive index contrast 2 O 3 Al x Ga 1-x The manufacturing method of the As DBR VCSEL is characterized by comprising the following steps:
major DBR Al over MQW layer x Ga 1-x As/Al y Ga 1-y As(x>y,0≤y<1) Medium and high Al% component Al x Ga 1-x The part of As is completely oxidized to be converted into Al 2 O 3 Forming Al on a desired optical path 2 O 3 /Al y Ga 1-y As DBR stack structure with at least one layer of low Al% component Al nearest to MQW in the structure z Ga 1-z As forms a current aperture and the size of the current aperture is controlled by controlling the oxidation rate thereof, wherein the Al% component satisfies x>Max(y,z);
Completely oxidizing the peripheral portion to form Al 2 O 3 Removing by chemical etching to retain Al of optical path 2 O 3 /Al y Ga 1-y An As DBR stack structure;
removing Al of peripheral portion 2 O 3 The space is filled with ohmic metal by one or more of atomic layer deposition, sputtering, evaporation and electroplating to form a low-resistance electrical conduction path.
2. A high refractive index contrast Al according to claim 1 2 O 3 Al x Ga 1-x The manufacturing method of the As DBR VCSEL is characterized by further comprising the steps of epitaxial growth, platform etching and upper electrode manufacturing.
3. A high refractive index contrast Al according to claim 1 2 O 3 Al x Ga 1-x The manufacturing method of the As DBR VCSEL is characterized by further comprising the step of removing the Al at the peripheral part 2 O 3 The MQW is protected to be close to Al by negative photoresistance before 2 O 3
4. A high refractive index contrast Al according to claim 1 2 O 3 Al x Ga 1-x A manufacturing method of an As DBR VCSEL is characterized in that the method comprises the following steps of 2 O 3 An etching process is used.
5. A high refractive index contrast Al according to claim 1 2 O 3 Al x Ga 1-x The manufacturing method of the As DBR VCSEL is characterized by further comprising the following steps of secondary mesa etching, lower electrode manufacturing, dielectric layer coating and welding pad evaporation.
CN202111356428.6A 2021-11-16 2021-11-16 Al with high refractive index contrast 2 O 3 Al x Ga 1-x As DBR VCSEL manufacturing method Active CN114268020B (en)

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