TWI710187B - Structure of vcsel and method for manufacturing the same - Google Patents
Structure of vcsel and method for manufacturing the same Download PDFInfo
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本發明係有關於一種垂直共振腔面射雷射結構及製法,尤指一種藉由三溝渠結構來降低整體電容與縮短氧化製程時間的一種垂直共振腔面射雷射結構及製法。 The present invention relates to a vertical cavity surface-fired laser structure and manufacturing method, in particular to a vertical cavity surface-fired laser structure and manufacturing method that uses a three-channel structure to reduce overall capacitance and shorten the oxidation process time.
垂直共振腔面射雷射(Vertical Cavity Surface Emitting Laser;簡稱VCSEL)是屬於發光雷射二極體的其中一種,由於其功率與價格較低,主要應用在區域網路方面,且具有「高速」與「低價」的優勢。VCSEL發光及檢光的原材料一般以砷化鎵(GaAs)、磷化銦(InP)為主,通常採有機金屬氣相沈積法(MOCVD)製成磊晶圓。與一般側射型雷射相比,VCSEL的共振腔與光子在共振腔來回共振所需之鏡面不是由製程形成之自然晶格斷裂面,而是在元件結構磊晶成長時就已形成。 Vertical Cavity Surface Emitting Laser (VCSEL) is a type of light emitting laser diode. Because of its low power and price, it is mainly used in local area networks and has "high speed". And the "low price" advantage. The raw materials for VCSEL light emission and inspection are generally gallium arsenide (GaAs) and indium phosphide (InP), and metal organic vapor deposition (MOCVD) is usually used to make epitaxial wafers. Compared with general side-fired lasers, the mirror surface required for the VCSEL's resonant cavity and photon to resonate back and forth in the cavity is not a natural lattice fracture surface formed by the process, but is formed when the device structure is epitaxially grown.
一般VCSEL結構大致包含發光活性層、共振腔以及上下具有高反射率之布拉格反射鏡(Distributed Bragg Reflector;簡稱DBR)。當光子於發光活性層產生後便於共振腔內來回振盪,若達居量反轉(population inversion)時雷射光會於VCSEL元件的表面形成。而VCSEL由於採取面射型,雷射光呈現圓錐狀,較容易與光纖進行耦合,不需額外的光學鏡片。對於習知VCSEL的基本結構、製法與作動方式,可以參考美國專利US Pat.No.4,949,350以及US Pat.No.5,468,656的內容。 A general VCSEL structure roughly includes a light-emitting active layer, a resonant cavity, and a Bragg reflector (Distributed Bragg Reflector; DBR) with high reflectivity up and down. When the photon is generated in the light-emitting active layer, it is easy to oscillate back and forth in the cavity. If the population inversion is reached, the laser light will be formed on the surface of the VCSEL element. However, because VCSEL adopts the surface-emitting type, the laser light has a cone shape, which is easier to couple with the optical fiber and does not require additional optical lenses. For the basic structure, manufacturing method, and operating mode of the conventional VCSEL, you can refer to the contents of US Pat. No. 4,949,350 and US Pat. No. 5,468,656.
本發明係針對上述習知VCSEL的結構與製法加以改良,藉由獨特的三溝渠結構來降低整體電容與縮短氧化製程時間,並以光窗周圍的離子佈植區來控制模態及侷限電流,且在光窗上形成出光層來控制出光,以及,藉由階梯狀的雙層凸台結構來幫助熱傳導以降低熱效應。 The present invention improves the structure and manufacturing method of the above-mentioned conventional VCSEL. The unique three-channel structure reduces the overall capacitance and shortens the oxidation process time. The ion implantation area around the optical window is used to control the mode and limit the current. In addition, a light-emitting layer is formed on the light window to control the light-emitting, and the stepped double-layered boss structure helps heat conduction to reduce the thermal effect.
有鑑於此,本發明的主要目的在於提供一種垂直共振腔面射雷射結構及製法,可藉由獨特的三溝渠結構來降低整體電容、縮短氧化製程時間、以及形成階梯狀的雙層凸台結構以降低熱效應。 In view of this, the main purpose of the present invention is to provide a vertical resonant cavity surface-fired laser structure and manufacturing method, which can reduce the overall capacitance, shorten the oxidation process time, and form a stepped double-layer boss through the unique three-channel structure Structure to reduce thermal effects.
本發明的另一目的在於提供一種垂直共振腔面射雷射結構及製法,可藉由光窗周圍的離子佈植區來控制模態及侷限電流,且在光窗上形成一出光層來控制出光;其中出光層可為介電材質,材料成分可為二氧化矽(SiO2)、氮化矽(SiN)或是這兩種材料的混和體,反射係數介於1.5~2.0。 Another object of the present invention is to provide a vertical resonant cavity surface-fired laser structure and manufacturing method, which can control the mode and current limiting by the ion implantation area around the optical window, and form a light-emitting layer on the optical window to control The light-emitting layer can be a dielectric material, and the material composition can be silicon dioxide (SiO2), silicon nitride (SiN) or a mixture of these two materials, and the reflection coefficient is between 1.5 and 2.0.
為達上述之目的,本發明提供一種垂直共振腔面射雷射結構,包括有:一基底、一第一鏡層位於該基底之上、一活化層位於該第一鏡層上、一第二鏡層位於活化層上、一氧化層夾設於該第二鏡層內、一凸台區域、一第一溝渠、一第二溝渠、一第三溝渠、一介電材料、一第一接觸層、以及一第二接觸層;其中,該凸台區域是位於該基底之上、且是由至少一部分之該第一鏡層、該活化層、該第二鏡層以及該氧化層所組構而成;於該凸台區域的一頂面的一中央處具有一光窗;該第一溝渠是位於該凸台區域之內、且環繞於該光窗的外周緣的至少一部份;該第一溝渠是由該凸台區域的該頂面由上向下至少貫穿該第二鏡層、該氧化層與該活化層;該第二溝渠是環繞於該凸台區域的外周緣的至少一部份、且與該第一溝渠相隔一間距,該第二溝渠是由上向下至少貫穿該第二鏡層與該氧化層,使該第二溝渠的一底部是位於該活化層處或該第一鏡層處兩者其中之一;該第三溝渠是環繞於該凸台區域的外周緣的至少一部份且是自該第二溝渠的該底部向下凹陷,且該第三溝渠是由上向下至少貫穿該第一鏡層,使該第三溝渠的一底部是位於該基底處;該介電材料是至少填充於該第一溝渠中;該第一接觸層是位於該凸台區域之該頂面上且接觸於該第二鏡層;該第二接觸層是至少位於該第三溝渠的該底部且至少接觸於該基底。 To achieve the above objective, the present invention provides a vertical resonant cavity surface-fired laser structure including: a substrate, a first mirror layer on the substrate, an active layer on the first mirror layer, and a second mirror layer. The mirror layer is located on the active layer, an oxide layer is sandwiched in the second mirror layer, a boss area, a first trench, a second trench, a third trench, a dielectric material, and a first contact layer And a second contact layer; wherein the boss area is located on the substrate and is composed of at least a part of the first mirror layer, the activation layer, the second mirror layer and the oxide layer In the middle of a top surface of the boss area, there is a light window; the first trench is located in the boss area and surrounds at least a part of the outer periphery of the light window; A trench extends from the top surface of the boss region through at least the second mirror layer, the oxide layer and the activation layer from top to bottom; the second trench surrounds at least a part of the outer periphery of the boss region The second ditch penetrates at least the second mirror layer and the oxide layer from top to bottom, so that a bottom of the second ditch is located at the active layer or at the first ditch. One of the two at a mirror layer; the third trench surrounds at least a part of the outer periphery of the boss area and is recessed from the bottom of the second trench, and the third trench is formed by Up and down at least penetrate the first mirror layer, so that a bottom of the third trench is located at the substrate; the dielectric material is at least filled in the first trench; the first contact layer is located in the boss area The top surface is in contact with the second mirror layer; the second contact layer is at least located at the bottom of the third trench and at least in contact with the substrate.
於一較佳實施例中,該垂直共振腔面射雷射結構更包括有一絕緣層,覆蓋於該凸台區域之一外表面的至少一部份,且該第一接觸層與 該第二接觸層至少有一部份是暴露於該絕緣層之外;該第一鏡層是一n型分佈式布拉格反射鏡層(distributed Bragg reflector;簡稱DBR),且該第二鏡層是一p型分佈式布拉格反射鏡層;該第一鏡層與該第二鏡層之材質包含有不同鋁莫耳百分比之砷化鋁鎵(AlGaAs),並且,該氧化層在第二鏡層中是具有相對最高莫耳百分比的鋁;該氧化層是由該第一溝渠的內周緣朝向該凸台區域之中央水平延伸;該介電材料是低介電性質的聚合物材料;以及,該第一接觸層與該第二接觸層都是金屬層。 In a preferred embodiment, the vertical cavity surface-fired laser structure further includes an insulating layer covering at least a part of an outer surface of the boss region, and the first contact layer is in contact with the second contact layer At least a part of the layer is exposed outside the insulating layer; the first mirror layer is an n-type distributed Bragg reflector (DBR), and the second mirror layer is a p-type distributed Bragg reflector layer; the material of the first mirror layer and the second mirror layer include aluminum gallium arsenide (AlGaAs) with different aluminum mole percentages, and the oxide layer has the relatively highest moire in the second mirror layer Ear percentage aluminum; the oxide layer extends horizontally from the inner periphery of the first trench toward the center of the boss area; the dielectric material is a polymer material with low dielectric properties; and, the first contact layer and the The second contact layers are all metal layers.
於一較佳實施例中,該垂直共振腔面射雷射結構更包括有一離子佈植層,位於該第二鏡層中。離子佈植層部分與氧化層重疊,並藉由氧化層及離子佈植的相對孔徑大小來控制光學模態,其中離子佈植屬於增益波導(Gain-guided),氧化屬於折射波導(index guided),藉由兩者的混和應用可來控制光學模態;並且,位於該凸台區域內的該離子佈植層是位於該光窗與該第一溝渠之間、且是環繞於該光窗的外周緣的至少一部份;其中,該第一接觸層是接觸於該第二鏡層的一上表面。 In a preferred embodiment, the vertical resonant cavity surface-fired laser structure further includes an ion implantation layer located in the second mirror layer. The ion implantation layer partially overlaps the oxide layer, and the relative aperture size of the oxide layer and ion implantation is used to control the optical mode. The ion implantation belongs to gain-guided, and oxidation belongs to index guided. , The optical mode can be controlled by the mixed application of the two; and the ion implantation layer located in the boss area is located between the light window and the first trench, and surrounds the light window At least a part of the outer periphery; wherein the first contact layer is in contact with an upper surface of the second mirror layer.
於一較佳實施例中,該垂直共振腔面射雷射結構更包括有:一出光層,位於該凸台區域之該頂面的該光窗上。 In a preferred embodiment, the vertical resonant cavity surface-fired laser structure further includes: a light-emitting layer located on the light window on the top surface of the boss area.
於一較佳實施例中,該第二接觸層是由該第三溝渠的該底部沿著該第三溝渠與該第二溝渠分別各具有之一傾斜表面向上延伸至該第二鏡層的一上表面,使該第二接觸層的一頂面大致上是位於與該第一接觸層的相同高度;於該第二溝渠的該底部形成一平面,使該第二接觸層在該第二溝渠的該底部構成一水平延伸的狀態。 In a preferred embodiment, the second contact layer extends from the bottom of the third trench up to a portion of the second mirror layer along the third trench and the second trench each having an inclined surface. On the upper surface, a top surface of the second contact layer is approximately at the same height as the first contact layer; a plane is formed at the bottom of the second trench, so that the second contact layer is in the second trench The bottom constitutes a horizontally extending state.
為達上述之目的,本發明提供一種垂直共振腔面射雷射結構的製法,包括下列步驟:提供一雷射晶片基材,於該雷射晶片基材上藉由一半導體製程由下而上依序構成:一基底、一第一鏡層位於該基底之上、一活化層位於該第一鏡層上、以及第二鏡層位於活化層上;使用一第一光罩及實施一第一遮罩製程程序,在該第二鏡層的上表面形成具有一第一預定圖案的一第一遮罩層,該第一預定圖案是對應於該第一光罩的圖案;實施一離子佈植程序,對該第二鏡層未被該第一遮罩層覆蓋 的區域進行離子佈植以形成一離子佈植層,且該離子佈植層的一底部與該活化層仍相距有一預定高度;在尚未移除第一遮罩層的情況下,使用一第二光罩及實施一第二遮罩的製程程序,在該第二鏡層的該上表面及該第一光阻層的上方形成具有一第二預定圖案的一第二遮罩層,該第二預定圖案是對應於該第二光罩的圖案;實施一第一蝕刻程序,對該第二鏡層、該活化層及該第一鏡層未被該第二光阻層覆蓋的區域進行蝕刻,以形成一第一溝渠,且該第一溝渠是自該第二鏡層的該上表面向下貫穿該第二鏡層及該活化層,使該第一溝渠的一底部是位於該第一鏡層;實施一氧化程序,以便透過該第一溝渠而在該第二鏡層內形成水平延伸之一氧化層,且該氧化層於高度上是與該離子佈植層是接近的,甚至有部分是重疊;實施一第二蝕刻程序,以便在該第二鏡層上形成一第二溝渠,且該第二溝渠是自該第二鏡層的該上表面向下至少貫穿該第二鏡層與該氧化層,使該第二溝渠的一底部是位於該活化層處或該第一鏡層處兩者其中之一;實施一第三蝕刻程序,以便在該第二溝渠的該底部處形成向下凹陷之一第三溝渠,且該第三溝渠是由上向下至少貫穿該第一鏡層,使該第三溝渠的一底部是位於該基底處;於該第一溝渠中填充一介電材料,此介電材料是聚合物,可為Polymide,反射係數為1.5~1.6。本發明藉由挖出第一溝渠並填補聚合物,可減少高介電系數的半導體材料的面積,故可以降低電容。並且在該雷射晶片基材上的適當區域分別形成一絕緣層、一第一接觸層以及一第二接觸層;其中,該第一接觸層是位於該凸台區域之該頂面上且接觸於該第二鏡層的上表面;該第二接觸層是至少位於該第三溝渠的該底部且至少接觸於該基底,且該第二接觸層是由該第三溝渠的該底部沿著該第三溝渠與該第二溝渠分別各具有之一傾斜表面向上延伸至該第二鏡層的上表面,使該第二接觸層的一頂面大致上是位於與該第一接觸層的相同高度; 該第一接觸層與該第二接觸層至少有一部份是暴露於該絕緣層之外;其中,由該第二溝渠與該第三溝渠可在該雷射晶片基材上定義出一凸台區域,該第二溝渠與該第三溝渠兩者都是環繞於該凸台區域的外周緣的至少一部份;該凸台區域是位於該基底之上、且是由至少一部分之該第一鏡層、該活化層、該第二鏡層以及該氧化層所組構而成,於該凸台區域的一頂面的一中央處具有一光窗;該第一溝渠是位於該凸台區域之內、且環繞於該光窗的外周緣的至少一部份、且與該第二溝渠相隔一間距;該第一溝渠是由該凸台區域的頂面由上向下至少貫穿該第二鏡層、該氧化層與該活化層。 To achieve the above objective, the present invention provides a method for manufacturing a vertical cavity surface-fired laser structure, which includes the following steps: providing a laser chip substrate, on which a semiconductor process is performed from bottom to top Sequentially constituted: a substrate, a first mirror layer on the substrate, an active layer on the first mirror layer, and a second mirror layer on the active layer; using a first mask and implementing a first The masking process is to form a first mask layer having a first predetermined pattern on the upper surface of the second mirror layer, the first predetermined pattern is corresponding to the pattern of the first mask; an ion implantation is performed The procedure is to perform ion implantation on the area of the second mirror layer not covered by the first mask layer to form an ion implantation layer, and a bottom of the ion implantation layer is still a predetermined height away from the activation layer; When the first mask layer has not been removed, a second mask is used and a second mask is implemented to form the upper surface of the second mirror layer and above the first photoresist layer A second mask layer with a second predetermined pattern, the second predetermined pattern corresponding to the pattern of the second photomask; a first etching process is performed to the second mirror layer, the activation layer and the first The area of a mirror layer not covered by the second photoresist layer is etched to form a first trench, and the first trench penetrates the second mirror layer and the second mirror layer downward from the upper surface of the second mirror layer The activation layer is such that a bottom of the first trench is located on the first mirror layer; an oxidation process is performed to form a horizontally extending oxide layer in the second mirror layer through the first trench, and the oxide layer It is close to the ion implantation layer in height, and even partially overlaps. A second etching process is performed to form a second trench on the second mirror layer, and the second trench is from the first The upper surface of the two mirror layers penetrates at least the second mirror layer and the oxide layer downward, so that a bottom of the second trench is located at either the active layer or the first mirror layer; implement a The third etching process is to form a downwardly recessed third trench at the bottom of the second trench, and the third trench penetrates at least the first mirror layer from top to bottom, so that one of the third trenches The bottom is located at the substrate; a dielectric material is filled in the first trench. The dielectric material is a polymer, which can be Polymide, and the reflection coefficient is 1.5 to 1.6. In the present invention, by digging the first trench and filling the polymer, the area of the semiconductor material with high dielectric coefficient can be reduced, so the capacitance can be reduced. And an insulating layer, a first contact layer, and a second contact layer are respectively formed on appropriate areas on the laser wafer substrate; wherein the first contact layer is located on the top surface of the boss area and contacts On the upper surface of the second mirror layer; the second contact layer is located at least at the bottom of the third trench and at least in contact with the substrate, and the second contact layer is along the bottom of the third trench The third trench and the second trench each have an inclined surface extending upward to the upper surface of the second mirror layer, so that a top surface of the second contact layer is substantially at the same height as the first contact layer ; At least a portion of the first contact layer and the second contact layer are exposed outside the insulating layer; wherein, the second trench and the third trench can define a protrusion on the laser chip substrate The mesa region, the second trench and the third trench are both at least a part of the outer periphery of the boss region; the boss region is located on the substrate and is formed by at least a part of the second A mirror layer, the activation layer, the second mirror layer, and the oxide layer are assembled, and a light window is provided at a center of a top surface of the boss region; the first trench is located on the boss Within the area and surrounding at least a part of the outer periphery of the light window, and separated from the second trench; the first trench penetrates at least the first trench from the top surface of the boss area from top to bottom Two mirror layers, the oxide layer and the activation layer.
為使能更進一步瞭解本發明之特徵及技術內容,請參閱以下有關本發明之詳細說明與附圖,然而所附詳細說明與附圖僅提供參考與說明用,並非用來對本發明加以限制者。 In order to further understand the features and technical content of the present invention, please refer to the following detailed description and accompanying drawings of the present invention. However, the accompanying detailed description and accompanying drawings are only provided for reference and illustration and are not intended to limit the present invention. .
10:基底 10: Base
21:第一鏡層 21: The first mirror layer
22:活化層 22: activated layer
23:第二鏡層 23: second mirror layer
231:氧化層 231: Oxide layer
24:離子佈植層 24: Ion implantation layer
240:上表面 240: upper surface
25:絕緣層 25: insulating layer
26:介電材料 26: Dielectric materials
27:金屬層 27: Metal layer
270:第一接觸層 270: first contact layer
271:273:第二接觸層 271:273: second contact layer
2710:頂面 2710: top surface
274:出光層 274: light emitting layer
30:凸台區域 30: boss area
300:光窗 300: light window
31:第一溝渠 31: The first ditch
32:第二溝渠 32: The second ditch
321、331:底部 321, 331: bottom
33:第三溝渠 33: Third Ditch
51、52:圖案 51, 52: pattern
510、520:中心圓區域 510, 520: central circle area
511:環狀區域 511: ring area
521:外圍區域 521: Peripheral Area
5100、5110、5200、5210:遮罩5100, 5110, 5200, 5210: mask
圖一為本發明之垂直共振腔面射雷射結構一較佳實施例的剖面示意圖;圖二A為本發明之垂直共振腔面射雷射結構的製法中的第一階段示意圖;圖二B為本發明之該第一光罩的圖案的實施例示意圖;圖三A為本發明之垂直共振腔面射雷射結構的製法中的第二階段示意圖;圖三B為本發明之該第二光罩的圖案的實施例示意圖;圖四為本發明之垂直共振腔面射雷射結構的製法中的第三階段示意圖;圖五為本發明之垂直共振腔面射雷射結構的製法中的第四階段示意圖;圖六為本發明之垂直共振腔面射雷射結構的製法中的第五階段示意圖;以及 圖七為本發明之垂直共振腔面射雷射結構的製法中的第六階段示意圖。 Figure 1 is a schematic cross-sectional view of a preferred embodiment of the vertical cavity surface-fired laser structure of the present invention; Figure 2A is a schematic diagram of the first stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention; Figure 2B It is a schematic diagram of an embodiment of the pattern of the first mask of the present invention; FIG. 3A is a schematic diagram of the second stage in the manufacturing method of the vertical cavity surface shot laser structure of the present invention; FIG. 3B is the second stage of the present invention The schematic diagram of the embodiment of the mask pattern; Figure 4 is a schematic diagram of the third stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention; Figure 5 is the manufacturing method of the vertical cavity surface-fired laser structure of the present invention Schematic diagram of the fourth stage; Figure 6 is a schematic diagram of the fifth stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention; and Figure 7 is the sixth stage of the manufacturing method of the vertical cavity surface-fired laser structure of the present invention Schematic.
本發明之垂直共振腔面射雷射結構及製法,主要是藉由獨特的三溝渠結構來降低整體電容、縮短氧化製程時間、以及形成階梯狀的雙層凸台結構以降低熱效應。並且,藉由光窗周圍的離子佈植區來控制模態及侷限電流,以及在光窗上形成一傳出光層來控制出光。 The vertical cavity surface-fired laser structure and manufacturing method of the present invention mainly uses a unique three-channel structure to reduce the overall capacitance, shorten the oxidation process time, and form a stepped double-layered boss structure to reduce the thermal effect. In addition, the ion implantation area around the light window is used to control the modal and current limiting, and an outgoing light layer is formed on the light window to control the light.
請參閱圖一所示,為本發明之垂直共振腔面射雷射結構一較佳實施例的剖面示意圖。 Please refer to FIG. 1, which is a schematic cross-sectional view of a preferred embodiment of the vertical cavity surface-fired laser structure of the present invention.
於本實施例中,本發明之垂直共振腔面射雷射結構是架構在一以砷化鎵(Gallium Arsenide;簡稱GaAs)或磷化銦(InP)材料為主的雷射晶片基材上,且該基材由下而上依序包括有:一基底10、一第一鏡層21位於該基底10之上、一活化層22(Active Region)位於該第一鏡層21上、以及第二鏡層23位於活化層22上。於該第二鏡層23內夾設有一氧化層231(Oxide Layer)。於本實施例中,該第一鏡層21是一n型分佈式布拉格反射鏡層(distributed Bragg reflector;簡稱DBR)其也可以稱為下鏡層,且該第二鏡層23是一p型分佈式布拉格反射鏡層其也可以稱為上鏡層。該第一鏡層21與該第二鏡層23之材質包含有不同鋁莫耳百分比之砷化鋁鎵(AlGaAs)的多層結構,並且,該氧化層231在第二鏡層23中是具有相對最高莫耳百分比的鋁。藉此,在氧化程序時,該氧化層231在氧化過程中可以形成絕緣的氧化鋁(Al2O3)。 In this embodiment, the vertical cavity surface-fired laser structure of the present invention is constructed on a laser chip substrate mainly made of gallium arsenide (GaAs) or indium phosphide (InP). And the substrate sequentially includes from bottom to top: a
本發明之垂直共振腔面射雷射結構在該基材上還具有包括:一凸台區域30(Mesa)、一第一溝渠31(Isolation Trench)、一第二溝渠32、一第三溝渠33、一介電材料26(Dielectric Material)、一第一接觸層270(Contact Layer)、一第二接觸層271~273、一離子佈植層24(Implant Region)、一絕緣層25(Insolating Layer)、以及一出光層274(Power Output Layer)。 The vertical cavity surface-fired laser structure of the present invention further includes on the substrate: a boss region 30 (Mesa), a first trench 31 (Isolation Trench), a
該凸台區域30是位於該基底10之上、且是由至少一部分之該 第一鏡層21、該活化層22、該第二鏡層23以及該氧化層231所組構而成。於該凸台區域30的一頂面的一中央處具有一光窗300。於本實施例中,該氧化層231於高度上是與該離子佈植層24的底部是接近的,甚至有部分是重疊。 The
該第一溝渠31是位於該凸台區域30之內、且環繞於該光窗300的外周緣的至少一部份。該第一溝渠31是由該凸台區域30的該頂面由上向下至少貫穿該第二鏡層23、該氧化層231與該活化層22,使第一溝渠31的底部是位於第一鏡層21。 The
該第二溝渠32是環繞於該凸台區域30之上半部的外周緣的至少一部份、且與該第一溝渠31相隔一間距。該第二溝渠32是由上向下至少貫穿該第二鏡層23與該氧化層231,使該第二溝渠32的一底部321是位於該活化層22處或該第一鏡層21處兩者其中之一。該氧化層231是由該溝渠31的內周緣朝向該凸台區域30之中央水平延伸。 The
該第三溝渠33是環繞於該凸台區域30之下半部的外周緣的至少一部份且是自該第二溝渠32的該底部321向下凹陷。並且,該第三溝渠33是由上向下至少貫穿該第一鏡層21(或是貫穿該活化層22及該第一鏡層21),使該第三溝渠33的一底部331是位於該基底10上表面處。 The
於本實施例中,該介電材料26是低介電性質的聚合物材料為較佳,且該介電材料26是至少填充於該第一溝渠31中,可提供降低垂直共振腔面射雷射結構之整體電容的功效。於本實施例中,此介電材料26是聚合物,可為Polymide,反射係數為1.5~1.6。本發明藉由挖出第一溝渠31並填補聚合物(介電材料26),可減少高介電系數的半導體材料的面積,故可以降低電容。該第一接觸層270與該第二接觸層271~273都是屬於金屬層27的一部份。該第一接觸層270是位於該凸台區域30之該頂面上且接觸於該第二鏡層23的一上表面240。該第二接觸層271、272、273是至少位於該第三溝渠33的該底部331且至少接觸於該基底10。於本實施例中,該第二接觸層271、272、273是由該第三溝渠33的該底部331沿著該第三溝渠33與該第二溝渠32分別各具有之一傾斜表面向上延伸至該第二鏡層23的上表面240,使該第二接觸層271、272、273的一頂面2710大致上是位於與該第一接觸層270之頂面的差不多相同高度。因此,本發明之第一接觸層270與第二接觸層271、272、273不僅是位於基底10的同一面、且更是位於大致相同的高度位 置,可以方便後續的打線製程。此外,於該第二溝渠32的該底部321形成一平面,使該第二接觸層271、272、273在該第二溝渠32的該底部321構成一水平延伸的狀態。藉此,不僅可以構成階梯狀的雙層凸台結構,使較大的下層凸台可加大散熱面積及降低熱效應,同時,兩階段凹陷的第二、第三溝渠結構32、33的傾斜面坡度變緩、且在該第二溝渠32的該底部321形成平面,可讓第二接觸層271、272、273在進行電鍍、濺鍍或蒸鍍金屬層時不易造成斷金現象。 In this embodiment, it is preferable that the
該離子佈植層24是位於該第二鏡層23中、且是位於該主動層22的上方。於本實施例中,離子佈植層24的底部有部分與氧化層231重疊,並藉由氧化層231及離子佈植24的相對孔徑大小來控制光學模態。其中,離子佈植屬於增益波導(Gain-guided),氧化屬於折射波導(index guided),藉由兩者的混和應用可來控制光學模態。並且,位於該凸台區域30內的該離子佈植層24是位於該光窗300與該第一溝渠31之間、且是環繞於該光窗300的外周緣的至少一部份。其中,該第一接觸層270是接觸於該離子佈植層24的一上表面。本發明藉由在光窗300周圍額外設置的離子佈植區24,可用來控制光學模態及侷限電流;於本實施例中,離子佈植製程可植入質子(Proton)或氧離子,深度介於2~4um。 The
該絕緣層25是覆蓋於該凸台區域30之一外表面的至少一部份,且該第一接觸層270與該第二接觸層271、272、273至少有一部份是暴露於該絕緣層25之外。該出光層274是位於該凸台區域30之該頂面的該光窗300上,可用來控制出光,其原理是利用出光層274之材料的折射率、厚度與光學波長來調整出。於本實施例中,該出光層274的材質可以是Si3N4、SiO2、Si3O4、SiN、或是SiNO等等。於本實施例中,該出光層274可為介電材質,材料成分可為二氧化矽(SiO2)、氮化矽(SiN)或是這兩種材料的混和體,反射係數介於1.5~2.0 The insulating
請參閱圖二A至圖七,為本發明之垂直共振腔面射雷射結構的製法的一較佳實施例的其中數個階段示意圖。 Please refer to FIGS. 2A to 7, which are schematic diagrams of several stages of a preferred embodiment of the manufacturing method of the vertical cavity surface-fired laser structure of the present invention.
如圖二A所示,為本發明之垂直共振腔面射雷射結構的製法中的第一階段示意圖。本發明之垂直共振腔面射雷射結構的製法,首先是提供一雷射晶片基材,於該雷射晶片基材上由下而上依序構成:一基底10、 一第一鏡層21位於該基底10之上、一活化層22位於該第一鏡層21上、以及第二鏡層23位於活化層22上。接著,使用一第一光罩及實施一第一遮罩製程程序,在該第二鏡層23的一上表面240形成具有一第一預定圖案的一第一遮罩層,該第一預定圖案是對應於該第一光罩的圖案51。如圖二B所示,為本發明之該第一光罩的圖案51的實施例示意圖。於該第一光罩的圖案51中包含了一中心圓區域510以及環繞於該中心圓區域的外圍的一環狀區域511;其中,該中心圓區域510的半徑為r1,該環狀區域511之內圍的半徑為r2、且該環狀區域511之外圍的半徑為r3。該第一光罩圖案51之該中心圓區域510定義了在該第二鏡層23的上表面240會被遮罩5100覆蓋的該光窗300的位置,且該第一光罩圖案51之環狀區域511定義了在該第二鏡層23的上表面240會被遮罩5110覆蓋且不會被離子佈植的區域。該第一遮罩層即包括了該遮罩5100、5110。接著,如圖二A所示,實施一離子佈植程序,對該第二鏡層23未被該第一遮罩層(遮罩5100、5110)覆蓋的區域進行離子佈植以形成一離子佈植層24,且該離子佈植層24的一底部與該活化層22仍相距有一預定高度。於本實施例中,離子佈植有效區的底部可以有一部分與氧化層位置重疊。本發明藉由在光窗300周圍額外設置的離子佈植區24,可用來控制模態及侷限電流。 As shown in FIG. 2A, it is a schematic diagram of the first stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. The manufacturing method of the vertical cavity surface-fired laser structure of the present invention firstly provides a laser wafer substrate, on which the laser wafer substrate is formed sequentially from bottom to top: a
如圖三A所示,為本發明之垂直共振腔面射雷射結構的製法中的第二階段示意圖。在尚未移除第一遮罩層5100、5110的情況下,使用一第二光罩及實施一第二遮罩製程程序,在該第二鏡層23的該上表面240及該第一遮罩層5100、5110的上方形成具有一第二預定圖案的一第二遮罩層,該第二預定圖案是對應於該第二光罩的圖案52。如圖三B所示,為本發明之該第二光罩的圖案52的實施例示意圖。於該第二光罩的圖案52中包含了一中心圓區域520以及環繞於該中心圓區域的外圍的一外圍區域521;其中,該中心圓區域520的半徑為R1,該外圍區域521之內圍的半徑為R2。該第二光罩圖案52之該中心圓區域520及該外圍區域521定義了在該第二鏡層23的上表面240會被遮罩5200、5210覆蓋的位置,且未被該遮罩5200、5210覆蓋的區域就是稍後會被蝕刻產生第一溝渠31的位置。該第二遮罩層即包括了該遮罩5200、5210。 As shown in FIG. 3A, it is a schematic diagram of the second stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. In the case where the
於本實施例中,該第二光罩圖案52之該中心圓區域520的半 徑R1的值是介於該第一光罩圖案51之該環狀區域511之內圍半徑r2與外圍的半徑r3之間,亦即,r2<R1<r3;並且,該第二光罩圖案52之該外圍區域521之內圍的半徑R2的值是大於該第一光罩圖案51之該環狀區域511之外圍的半徑r3,亦即,r3<R2。因此,在進行前述第一遮罩與第二遮罩的兩道遮罩製程程序時,會具有自我對準的效果,使後續製程所得到之氧化層231孔徑與離子佈植層24孔徑對準精度增加。 In this embodiment, the value of the radius R1 of the central
接著,如圖四所示,為本發明之垂直共振腔面射雷射結構的製法中的第三階段示意圖。實施一第一蝕刻程序,對該第二鏡層23、該活化層22及該第一鏡層21未被該第二遮罩層(遮罩5200、5210)覆蓋的區域進行蝕刻,以形成一第一溝渠31,且該第一溝渠31是自該第二鏡層23的該上表面240向下貫穿該第二鏡層23及該活化層22,使該第一溝渠31的一底部是位於該第一鏡層21。 Next, as shown in FIG. 4, it is a schematic diagram of the third stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. A first etching process is performed to etch the
接著,如圖五所示,為本發明之垂直共振腔面射雷射結構的製法中的第四階段示意圖。實施一氧化程序,以便透過該第一溝渠31而在該第二鏡層23內形成水平延伸之一氧化層231,且該氧化層231於高度上是與離子佈植層24是接近的,甚至可以有部分重疊,並且,該氧化層231是位在活化層22之上。相較於習知技術因不具第一溝渠31的結構所以必須透過第二溝渠32來進行氧化層之氧化程序的習知技術而言,本發明由於該氧化層231的氧化程序是透過相對來說更接近光窗300的該第一溝渠31來進行,所以,所需氧化的距離相對較短、氧化程序所需的時間也因此縮短,也減少氧化層231因氧化距離長所衍伸的應力聚集問題。 Next, as shown in FIG. 5, it is a schematic diagram of the fourth stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. An oxidation process is performed to form a horizontally extending
接著,如圖六所示,為本發明之垂直共振腔面射雷射結構的製法中的第五階段示意圖。實施一第二蝕刻程序,以便在該第二鏡層23上形成一第二溝渠32,且該第二溝渠32是自該第二鏡層23的該上表面240向下至少貫穿該第二鏡層23與該氧化層231,使該第二溝渠32的一底部321是位於該活化層22處或該第一鏡層21處兩者其中之一。並且,以一金屬鍍層程序在該第二鏡層23的該上表面240的一預定區域形成一接觸墊也就是稍後會成為第一接觸層270的一部份。 Next, as shown in FIG. 6, it is a schematic diagram of the fifth stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. A second etching process is performed to form a
接著,如圖七所示,為本發明之垂直共振腔面射雷射結構的製法中的第六階段示意圖。實施一第三蝕刻程序,以便在該第二溝渠32的該底部321處形成向下凹陷之一第三溝渠33,且該第三溝渠33是由上向下至少貫穿該第一鏡層21(或是貫穿該活化層22及該第一鏡層21),使該第三溝渠33的一底部331是位於該基底10處。
Next, as shown in FIG. 7, it is a schematic diagram of the sixth stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. A third etching process is performed to form a downwardly recessed
之後,再於該第一溝渠31中填充一介電材料26,可提供降低垂直共振腔面射雷射結構之整體電容的功效;以及,在該雷射晶片基材上的適當區域分別形成一出光層274、一絕緣層25、一金屬層27(包括第一接觸層270以及第二接觸層271、272、273)。藉此,便能製作出如圖一所示之本發明之垂直共振腔面射雷射結構。
Afterwards, a
於本實施例中,如圖一所示,由該第二溝渠32與該第三溝渠33可在該雷射晶片基材上定義出一凸台區域30,該第二溝渠32與該第三溝渠33兩者都是環繞於該凸台區域30的外周緣的至少一部份。該凸台區域30是位於該基底10之上、且是由至少一部分之該第一鏡層21、該活化層22、該第二鏡層23以及該氧化層231所組構而成。於該凸台區域30的一頂面的一中央處具有一光窗300。該第一溝渠31是位於該凸台區域30之內、且環繞於該光窗300的外周緣的至少一部份、且與該第二溝渠32相隔一間距。該第一溝渠31是由該凸台區域30的頂面由上向下至少貫穿該第二鏡層23、該氧化層231與該活化層22。
In this embodiment, as shown in FIG. 1, the
於本實施例中,該出光層274是位於該凸台區域30之該頂面的該光窗300上,可用來控制出光。該離子佈植層24是位於該第二鏡層23中且是位於該氧化層231的上方但離子佈植層24底部可以和氧化層231部分重疊,並且,位於該凸台區域30內的該該離子佈植層24是位於該光窗300與該第一溝渠31之間、且是環繞於該光窗300的外周緣的至少一部份,可用來控制模態及侷限電流。
In this embodiment, the light-emitting
於本實施例中,該第一接觸層270是位於該凸台區域30之該頂面上且接觸於該第二鏡層23的上表面。該第二接觸層271、272、273是至少位於該第三溝渠33的該底部331且至少接觸於該基底10,且該第二接觸層271、272、273是由該第三溝渠33的該底部331沿著該第三溝渠33與該第二溝渠32分別各具有之一傾斜表面向上延伸至該第二鏡層23的該上表面,使該第二接觸層271、272、273的一頂面大致上是位於與該第一接觸層270的差不多相同高度。因此,本發明之第一接觸層270與第二接觸層271、272、
273不僅是位於基底10的同一面、且更是位於大致相同的高度位置,可以方便後續的打線製程。該第一接觸層270與該第二接觸層271、272、273至少有一部份是暴露於該絕緣層25之外。其中,於該第二溝渠32的該底部321形成一平面,使該第二接觸層271、272、273在該第二溝渠32的該底部321構成一水平延伸的狀態。藉此,不僅可以構成階梯狀的雙層凸台結構,使較大的下層凸台可加大散熱面積及降低熱效應,同時,兩階段凹陷的第二、第三溝渠結構32、33的傾斜面坡度變緩、且在該第二溝渠32的該底部321形成平面,可讓第二接觸層271、272、273在進行電鍍、濺鍍或蒸鍍金屬層時不易造成斷金現象。
In this embodiment, the
以上所述僅為本發明之較佳可行實施例,非因此侷限本發明之專利範圍,故舉凡運用本發明說明書及圖示內容所為之等效技術變化,均包含於本發明之範圍內。The above descriptions are only the preferred and feasible embodiments of the present invention, and do not limit the patent scope of the present invention. Therefore, all equivalent technical changes made by using the description and illustrations of the present invention are included in the scope of the present invention.
10‧‧‧基底 10‧‧‧Base
21‧‧‧第一鏡層 21‧‧‧First mirror layer
22‧‧‧活化層 22‧‧‧Activated layer
23‧‧‧第二鏡層 23‧‧‧Second mirror layer
231‧‧‧氧化層 231‧‧‧Oxide layer
24‧‧‧離子佈植層 24‧‧‧Ion implantation layer
240‧‧‧上表面 240‧‧‧Upper surface
25‧‧‧絕緣層 25‧‧‧Insulation layer
26‧‧‧介電材料 26‧‧‧Dielectric materials
27‧‧‧金屬層 27‧‧‧Metal layer
270‧‧‧第一接觸層 270‧‧‧First contact layer
271~273‧‧‧第二接觸層 271~273‧‧‧Second contact layer
2710‧‧‧頂面 2710‧‧‧Top surface
274‧‧‧出光層 274‧‧‧light emitting layer
30‧‧‧凸台區域 30‧‧‧Protrusion area
300‧‧‧光窗 300‧‧‧Light window
31‧‧‧第一溝渠 31‧‧‧First Ditch
32‧‧‧第二溝渠 32‧‧‧Second Ditch
321、331‧‧‧底部 321, 331‧‧‧Bottom
33‧‧‧第三溝渠 33‧‧‧Third Ditch
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