TWI710187B - Structure of vcsel and method for manufacturing the same - Google Patents

Structure of vcsel and method for manufacturing the same Download PDF

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TWI710187B
TWI710187B TW106104272A TW106104272A TWI710187B TW I710187 B TWI710187 B TW I710187B TW 106104272 A TW106104272 A TW 106104272A TW 106104272 A TW106104272 A TW 106104272A TW I710187 B TWI710187 B TW I710187B
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layer
trench
mirror
mirror layer
contact
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TW201830811A (en
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林炳成
陳志誠
曾竑維
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光環科技股份有限公司
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Abstract

The invention refers to a Vertical-Cavity Surface-Emitting Laser (VCSEL) having a novel three-trenches structure. By forming a first trench within a mesa around the periphery of an output window of the VCSEL, the overall capacitance is decreased and the time used in the oxidation process for an oxidation layer is shortened. By forming a second trench and a third trench on the periphery of the mesa in a step-like concave manner, the mesa becomes a step-like structure having double mesa-layers. Such that, a larger heat-radiating area can be obtained for decreasing thermal effects, while the metal-gap defects of the metal layer can also be avoided. An implant layer is formed around the periphery of the output window for controlling the modal and constraining the currents, in addition, an output layer is formed on the output window for controlling the output light.

Description

垂直共振腔面射雷射結構及製法 Vertical resonance cavity surface shot laser structure and manufacturing method

本發明係有關於一種垂直共振腔面射雷射結構及製法,尤指一種藉由三溝渠結構來降低整體電容與縮短氧化製程時間的一種垂直共振腔面射雷射結構及製法。 The present invention relates to a vertical cavity surface-fired laser structure and manufacturing method, in particular to a vertical cavity surface-fired laser structure and manufacturing method that uses a three-channel structure to reduce overall capacitance and shorten the oxidation process time.

垂直共振腔面射雷射(Vertical Cavity Surface Emitting Laser;簡稱VCSEL)是屬於發光雷射二極體的其中一種,由於其功率與價格較低,主要應用在區域網路方面,且具有「高速」與「低價」的優勢。VCSEL發光及檢光的原材料一般以砷化鎵(GaAs)、磷化銦(InP)為主,通常採有機金屬氣相沈積法(MOCVD)製成磊晶圓。與一般側射型雷射相比,VCSEL的共振腔與光子在共振腔來回共振所需之鏡面不是由製程形成之自然晶格斷裂面,而是在元件結構磊晶成長時就已形成。 Vertical Cavity Surface Emitting Laser (VCSEL) is a type of light emitting laser diode. Because of its low power and price, it is mainly used in local area networks and has "high speed". And the "low price" advantage. The raw materials for VCSEL light emission and inspection are generally gallium arsenide (GaAs) and indium phosphide (InP), and metal organic vapor deposition (MOCVD) is usually used to make epitaxial wafers. Compared with general side-fired lasers, the mirror surface required for the VCSEL's resonant cavity and photon to resonate back and forth in the cavity is not a natural lattice fracture surface formed by the process, but is formed when the device structure is epitaxially grown.

一般VCSEL結構大致包含發光活性層、共振腔以及上下具有高反射率之布拉格反射鏡(Distributed Bragg Reflector;簡稱DBR)。當光子於發光活性層產生後便於共振腔內來回振盪,若達居量反轉(population inversion)時雷射光會於VCSEL元件的表面形成。而VCSEL由於採取面射型,雷射光呈現圓錐狀,較容易與光纖進行耦合,不需額外的光學鏡片。對於習知VCSEL的基本結構、製法與作動方式,可以參考美國專利US Pat.No.4,949,350以及US Pat.No.5,468,656的內容。 A general VCSEL structure roughly includes a light-emitting active layer, a resonant cavity, and a Bragg reflector (Distributed Bragg Reflector; DBR) with high reflectivity up and down. When the photon is generated in the light-emitting active layer, it is easy to oscillate back and forth in the cavity. If the population inversion is reached, the laser light will be formed on the surface of the VCSEL element. However, because VCSEL adopts the surface-emitting type, the laser light has a cone shape, which is easier to couple with the optical fiber and does not require additional optical lenses. For the basic structure, manufacturing method, and operating mode of the conventional VCSEL, you can refer to the contents of US Pat. No. 4,949,350 and US Pat. No. 5,468,656.

本發明係針對上述習知VCSEL的結構與製法加以改良,藉由獨特的三溝渠結構來降低整體電容與縮短氧化製程時間,並以光窗周圍的離子佈植區來控制模態及侷限電流,且在光窗上形成出光層來控制出光,以及,藉由階梯狀的雙層凸台結構來幫助熱傳導以降低熱效應。 The present invention improves the structure and manufacturing method of the above-mentioned conventional VCSEL. The unique three-channel structure reduces the overall capacitance and shortens the oxidation process time. The ion implantation area around the optical window is used to control the mode and limit the current. In addition, a light-emitting layer is formed on the light window to control the light-emitting, and the stepped double-layered boss structure helps heat conduction to reduce the thermal effect.

有鑑於此,本發明的主要目的在於提供一種垂直共振腔面射雷射結構及製法,可藉由獨特的三溝渠結構來降低整體電容、縮短氧化製程時間、以及形成階梯狀的雙層凸台結構以降低熱效應。 In view of this, the main purpose of the present invention is to provide a vertical resonant cavity surface-fired laser structure and manufacturing method, which can reduce the overall capacitance, shorten the oxidation process time, and form a stepped double-layer boss through the unique three-channel structure Structure to reduce thermal effects.

本發明的另一目的在於提供一種垂直共振腔面射雷射結構及製法,可藉由光窗周圍的離子佈植區來控制模態及侷限電流,且在光窗上形成一出光層來控制出光;其中出光層可為介電材質,材料成分可為二氧化矽(SiO2)、氮化矽(SiN)或是這兩種材料的混和體,反射係數介於1.5~2.0。 Another object of the present invention is to provide a vertical resonant cavity surface-fired laser structure and manufacturing method, which can control the mode and current limiting by the ion implantation area around the optical window, and form a light-emitting layer on the optical window to control The light-emitting layer can be a dielectric material, and the material composition can be silicon dioxide (SiO2), silicon nitride (SiN) or a mixture of these two materials, and the reflection coefficient is between 1.5 and 2.0.

為達上述之目的,本發明提供一種垂直共振腔面射雷射結構,包括有:一基底、一第一鏡層位於該基底之上、一活化層位於該第一鏡層上、一第二鏡層位於活化層上、一氧化層夾設於該第二鏡層內、一凸台區域、一第一溝渠、一第二溝渠、一第三溝渠、一介電材料、一第一接觸層、以及一第二接觸層;其中,該凸台區域是位於該基底之上、且是由至少一部分之該第一鏡層、該活化層、該第二鏡層以及該氧化層所組構而成;於該凸台區域的一頂面的一中央處具有一光窗;該第一溝渠是位於該凸台區域之內、且環繞於該光窗的外周緣的至少一部份;該第一溝渠是由該凸台區域的該頂面由上向下至少貫穿該第二鏡層、該氧化層與該活化層;該第二溝渠是環繞於該凸台區域的外周緣的至少一部份、且與該第一溝渠相隔一間距,該第二溝渠是由上向下至少貫穿該第二鏡層與該氧化層,使該第二溝渠的一底部是位於該活化層處或該第一鏡層處兩者其中之一;該第三溝渠是環繞於該凸台區域的外周緣的至少一部份且是自該第二溝渠的該底部向下凹陷,且該第三溝渠是由上向下至少貫穿該第一鏡層,使該第三溝渠的一底部是位於該基底處;該介電材料是至少填充於該第一溝渠中;該第一接觸層是位於該凸台區域之該頂面上且接觸於該第二鏡層;該第二接觸層是至少位於該第三溝渠的該底部且至少接觸於該基底。 To achieve the above objective, the present invention provides a vertical resonant cavity surface-fired laser structure including: a substrate, a first mirror layer on the substrate, an active layer on the first mirror layer, and a second mirror layer. The mirror layer is located on the active layer, an oxide layer is sandwiched in the second mirror layer, a boss area, a first trench, a second trench, a third trench, a dielectric material, and a first contact layer And a second contact layer; wherein the boss area is located on the substrate and is composed of at least a part of the first mirror layer, the activation layer, the second mirror layer and the oxide layer In the middle of a top surface of the boss area, there is a light window; the first trench is located in the boss area and surrounds at least a part of the outer periphery of the light window; A trench extends from the top surface of the boss region through at least the second mirror layer, the oxide layer and the activation layer from top to bottom; the second trench surrounds at least a part of the outer periphery of the boss region The second ditch penetrates at least the second mirror layer and the oxide layer from top to bottom, so that a bottom of the second ditch is located at the active layer or at the first ditch. One of the two at a mirror layer; the third trench surrounds at least a part of the outer periphery of the boss area and is recessed from the bottom of the second trench, and the third trench is formed by Up and down at least penetrate the first mirror layer, so that a bottom of the third trench is located at the substrate; the dielectric material is at least filled in the first trench; the first contact layer is located in the boss area The top surface is in contact with the second mirror layer; the second contact layer is at least located at the bottom of the third trench and at least in contact with the substrate.

於一較佳實施例中,該垂直共振腔面射雷射結構更包括有一絕緣層,覆蓋於該凸台區域之一外表面的至少一部份,且該第一接觸層與 該第二接觸層至少有一部份是暴露於該絕緣層之外;該第一鏡層是一n型分佈式布拉格反射鏡層(distributed Bragg reflector;簡稱DBR),且該第二鏡層是一p型分佈式布拉格反射鏡層;該第一鏡層與該第二鏡層之材質包含有不同鋁莫耳百分比之砷化鋁鎵(AlGaAs),並且,該氧化層在第二鏡層中是具有相對最高莫耳百分比的鋁;該氧化層是由該第一溝渠的內周緣朝向該凸台區域之中央水平延伸;該介電材料是低介電性質的聚合物材料;以及,該第一接觸層與該第二接觸層都是金屬層。 In a preferred embodiment, the vertical cavity surface-fired laser structure further includes an insulating layer covering at least a part of an outer surface of the boss region, and the first contact layer is in contact with the second contact layer At least a part of the layer is exposed outside the insulating layer; the first mirror layer is an n-type distributed Bragg reflector (DBR), and the second mirror layer is a p-type distributed Bragg reflector layer; the material of the first mirror layer and the second mirror layer include aluminum gallium arsenide (AlGaAs) with different aluminum mole percentages, and the oxide layer has the relatively highest moire in the second mirror layer Ear percentage aluminum; the oxide layer extends horizontally from the inner periphery of the first trench toward the center of the boss area; the dielectric material is a polymer material with low dielectric properties; and, the first contact layer and the The second contact layers are all metal layers.

於一較佳實施例中,該垂直共振腔面射雷射結構更包括有一離子佈植層,位於該第二鏡層中。離子佈植層部分與氧化層重疊,並藉由氧化層及離子佈植的相對孔徑大小來控制光學模態,其中離子佈植屬於增益波導(Gain-guided),氧化屬於折射波導(index guided),藉由兩者的混和應用可來控制光學模態;並且,位於該凸台區域內的該離子佈植層是位於該光窗與該第一溝渠之間、且是環繞於該光窗的外周緣的至少一部份;其中,該第一接觸層是接觸於該第二鏡層的一上表面。 In a preferred embodiment, the vertical resonant cavity surface-fired laser structure further includes an ion implantation layer located in the second mirror layer. The ion implantation layer partially overlaps the oxide layer, and the relative aperture size of the oxide layer and ion implantation is used to control the optical mode. The ion implantation belongs to gain-guided, and oxidation belongs to index guided. , The optical mode can be controlled by the mixed application of the two; and the ion implantation layer located in the boss area is located between the light window and the first trench, and surrounds the light window At least a part of the outer periphery; wherein the first contact layer is in contact with an upper surface of the second mirror layer.

於一較佳實施例中,該垂直共振腔面射雷射結構更包括有:一出光層,位於該凸台區域之該頂面的該光窗上。 In a preferred embodiment, the vertical resonant cavity surface-fired laser structure further includes: a light-emitting layer located on the light window on the top surface of the boss area.

於一較佳實施例中,該第二接觸層是由該第三溝渠的該底部沿著該第三溝渠與該第二溝渠分別各具有之一傾斜表面向上延伸至該第二鏡層的一上表面,使該第二接觸層的一頂面大致上是位於與該第一接觸層的相同高度;於該第二溝渠的該底部形成一平面,使該第二接觸層在該第二溝渠的該底部構成一水平延伸的狀態。 In a preferred embodiment, the second contact layer extends from the bottom of the third trench up to a portion of the second mirror layer along the third trench and the second trench each having an inclined surface. On the upper surface, a top surface of the second contact layer is approximately at the same height as the first contact layer; a plane is formed at the bottom of the second trench, so that the second contact layer is in the second trench The bottom constitutes a horizontally extending state.

為達上述之目的,本發明提供一種垂直共振腔面射雷射結構的製法,包括下列步驟:提供一雷射晶片基材,於該雷射晶片基材上藉由一半導體製程由下而上依序構成:一基底、一第一鏡層位於該基底之上、一活化層位於該第一鏡層上、以及第二鏡層位於活化層上;使用一第一光罩及實施一第一遮罩製程程序,在該第二鏡層的上表面形成具有一第一預定圖案的一第一遮罩層,該第一預定圖案是對應於該第一光罩的圖案;實施一離子佈植程序,對該第二鏡層未被該第一遮罩層覆蓋 的區域進行離子佈植以形成一離子佈植層,且該離子佈植層的一底部與該活化層仍相距有一預定高度;在尚未移除第一遮罩層的情況下,使用一第二光罩及實施一第二遮罩的製程程序,在該第二鏡層的該上表面及該第一光阻層的上方形成具有一第二預定圖案的一第二遮罩層,該第二預定圖案是對應於該第二光罩的圖案;實施一第一蝕刻程序,對該第二鏡層、該活化層及該第一鏡層未被該第二光阻層覆蓋的區域進行蝕刻,以形成一第一溝渠,且該第一溝渠是自該第二鏡層的該上表面向下貫穿該第二鏡層及該活化層,使該第一溝渠的一底部是位於該第一鏡層;實施一氧化程序,以便透過該第一溝渠而在該第二鏡層內形成水平延伸之一氧化層,且該氧化層於高度上是與該離子佈植層是接近的,甚至有部分是重疊;實施一第二蝕刻程序,以便在該第二鏡層上形成一第二溝渠,且該第二溝渠是自該第二鏡層的該上表面向下至少貫穿該第二鏡層與該氧化層,使該第二溝渠的一底部是位於該活化層處或該第一鏡層處兩者其中之一;實施一第三蝕刻程序,以便在該第二溝渠的該底部處形成向下凹陷之一第三溝渠,且該第三溝渠是由上向下至少貫穿該第一鏡層,使該第三溝渠的一底部是位於該基底處;於該第一溝渠中填充一介電材料,此介電材料是聚合物,可為Polymide,反射係數為1.5~1.6。本發明藉由挖出第一溝渠並填補聚合物,可減少高介電系數的半導體材料的面積,故可以降低電容。並且在該雷射晶片基材上的適當區域分別形成一絕緣層、一第一接觸層以及一第二接觸層;其中,該第一接觸層是位於該凸台區域之該頂面上且接觸於該第二鏡層的上表面;該第二接觸層是至少位於該第三溝渠的該底部且至少接觸於該基底,且該第二接觸層是由該第三溝渠的該底部沿著該第三溝渠與該第二溝渠分別各具有之一傾斜表面向上延伸至該第二鏡層的上表面,使該第二接觸層的一頂面大致上是位於與該第一接觸層的相同高度; 該第一接觸層與該第二接觸層至少有一部份是暴露於該絕緣層之外;其中,由該第二溝渠與該第三溝渠可在該雷射晶片基材上定義出一凸台區域,該第二溝渠與該第三溝渠兩者都是環繞於該凸台區域的外周緣的至少一部份;該凸台區域是位於該基底之上、且是由至少一部分之該第一鏡層、該活化層、該第二鏡層以及該氧化層所組構而成,於該凸台區域的一頂面的一中央處具有一光窗;該第一溝渠是位於該凸台區域之內、且環繞於該光窗的外周緣的至少一部份、且與該第二溝渠相隔一間距;該第一溝渠是由該凸台區域的頂面由上向下至少貫穿該第二鏡層、該氧化層與該活化層。 To achieve the above objective, the present invention provides a method for manufacturing a vertical cavity surface-fired laser structure, which includes the following steps: providing a laser chip substrate, on which a semiconductor process is performed from bottom to top Sequentially constituted: a substrate, a first mirror layer on the substrate, an active layer on the first mirror layer, and a second mirror layer on the active layer; using a first mask and implementing a first The masking process is to form a first mask layer having a first predetermined pattern on the upper surface of the second mirror layer, the first predetermined pattern is corresponding to the pattern of the first mask; an ion implantation is performed The procedure is to perform ion implantation on the area of the second mirror layer not covered by the first mask layer to form an ion implantation layer, and a bottom of the ion implantation layer is still a predetermined height away from the activation layer; When the first mask layer has not been removed, a second mask is used and a second mask is implemented to form the upper surface of the second mirror layer and above the first photoresist layer A second mask layer with a second predetermined pattern, the second predetermined pattern corresponding to the pattern of the second photomask; a first etching process is performed to the second mirror layer, the activation layer and the first The area of a mirror layer not covered by the second photoresist layer is etched to form a first trench, and the first trench penetrates the second mirror layer and the second mirror layer downward from the upper surface of the second mirror layer The activation layer is such that a bottom of the first trench is located on the first mirror layer; an oxidation process is performed to form a horizontally extending oxide layer in the second mirror layer through the first trench, and the oxide layer It is close to the ion implantation layer in height, and even partially overlaps. A second etching process is performed to form a second trench on the second mirror layer, and the second trench is from the first The upper surface of the two mirror layers penetrates at least the second mirror layer and the oxide layer downward, so that a bottom of the second trench is located at either the active layer or the first mirror layer; implement a The third etching process is to form a downwardly recessed third trench at the bottom of the second trench, and the third trench penetrates at least the first mirror layer from top to bottom, so that one of the third trenches The bottom is located at the substrate; a dielectric material is filled in the first trench. The dielectric material is a polymer, which can be Polymide, and the reflection coefficient is 1.5 to 1.6. In the present invention, by digging the first trench and filling the polymer, the area of the semiconductor material with high dielectric coefficient can be reduced, so the capacitance can be reduced. And an insulating layer, a first contact layer, and a second contact layer are respectively formed on appropriate areas on the laser wafer substrate; wherein the first contact layer is located on the top surface of the boss area and contacts On the upper surface of the second mirror layer; the second contact layer is located at least at the bottom of the third trench and at least in contact with the substrate, and the second contact layer is along the bottom of the third trench The third trench and the second trench each have an inclined surface extending upward to the upper surface of the second mirror layer, so that a top surface of the second contact layer is substantially at the same height as the first contact layer ; At least a portion of the first contact layer and the second contact layer are exposed outside the insulating layer; wherein, the second trench and the third trench can define a protrusion on the laser chip substrate The mesa region, the second trench and the third trench are both at least a part of the outer periphery of the boss region; the boss region is located on the substrate and is formed by at least a part of the second A mirror layer, the activation layer, the second mirror layer, and the oxide layer are assembled, and a light window is provided at a center of a top surface of the boss region; the first trench is located on the boss Within the area and surrounding at least a part of the outer periphery of the light window, and separated from the second trench; the first trench penetrates at least the first trench from the top surface of the boss area from top to bottom Two mirror layers, the oxide layer and the activation layer.

為使能更進一步瞭解本發明之特徵及技術內容,請參閱以下有關本發明之詳細說明與附圖,然而所附詳細說明與附圖僅提供參考與說明用,並非用來對本發明加以限制者。 In order to further understand the features and technical content of the present invention, please refer to the following detailed description and accompanying drawings of the present invention. However, the accompanying detailed description and accompanying drawings are only provided for reference and illustration and are not intended to limit the present invention. .

10:基底 10: Base

21:第一鏡層 21: The first mirror layer

22:活化層 22: activated layer

23:第二鏡層 23: second mirror layer

231:氧化層 231: Oxide layer

24:離子佈植層 24: Ion implantation layer

240:上表面 240: upper surface

25:絕緣層 25: insulating layer

26:介電材料 26: Dielectric materials

27:金屬層 27: Metal layer

270:第一接觸層 270: first contact layer

271:273:第二接觸層 271:273: second contact layer

2710:頂面 2710: top surface

274:出光層 274: light emitting layer

30:凸台區域 30: boss area

300:光窗 300: light window

31:第一溝渠 31: The first ditch

32:第二溝渠 32: The second ditch

321、331:底部 321, 331: bottom

33:第三溝渠 33: Third Ditch

51、52:圖案 51, 52: pattern

510、520:中心圓區域 510, 520: central circle area

511:環狀區域 511: ring area

521:外圍區域 521: Peripheral Area

5100、5110、5200、5210:遮罩5100, 5110, 5200, 5210: mask

圖一為本發明之垂直共振腔面射雷射結構一較佳實施例的剖面示意圖;圖二A為本發明之垂直共振腔面射雷射結構的製法中的第一階段示意圖;圖二B為本發明之該第一光罩的圖案的實施例示意圖;圖三A為本發明之垂直共振腔面射雷射結構的製法中的第二階段示意圖;圖三B為本發明之該第二光罩的圖案的實施例示意圖;圖四為本發明之垂直共振腔面射雷射結構的製法中的第三階段示意圖;圖五為本發明之垂直共振腔面射雷射結構的製法中的第四階段示意圖;圖六為本發明之垂直共振腔面射雷射結構的製法中的第五階段示意圖;以及 圖七為本發明之垂直共振腔面射雷射結構的製法中的第六階段示意圖。 Figure 1 is a schematic cross-sectional view of a preferred embodiment of the vertical cavity surface-fired laser structure of the present invention; Figure 2A is a schematic diagram of the first stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention; Figure 2B It is a schematic diagram of an embodiment of the pattern of the first mask of the present invention; FIG. 3A is a schematic diagram of the second stage in the manufacturing method of the vertical cavity surface shot laser structure of the present invention; FIG. 3B is the second stage of the present invention The schematic diagram of the embodiment of the mask pattern; Figure 4 is a schematic diagram of the third stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention; Figure 5 is the manufacturing method of the vertical cavity surface-fired laser structure of the present invention Schematic diagram of the fourth stage; Figure 6 is a schematic diagram of the fifth stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention; and Figure 7 is the sixth stage of the manufacturing method of the vertical cavity surface-fired laser structure of the present invention Schematic.

本發明之垂直共振腔面射雷射結構及製法,主要是藉由獨特的三溝渠結構來降低整體電容、縮短氧化製程時間、以及形成階梯狀的雙層凸台結構以降低熱效應。並且,藉由光窗周圍的離子佈植區來控制模態及侷限電流,以及在光窗上形成一傳出光層來控制出光。 The vertical cavity surface-fired laser structure and manufacturing method of the present invention mainly uses a unique three-channel structure to reduce the overall capacitance, shorten the oxidation process time, and form a stepped double-layered boss structure to reduce the thermal effect. In addition, the ion implantation area around the light window is used to control the modal and current limiting, and an outgoing light layer is formed on the light window to control the light.

請參閱圖一所示,為本發明之垂直共振腔面射雷射結構一較佳實施例的剖面示意圖。 Please refer to FIG. 1, which is a schematic cross-sectional view of a preferred embodiment of the vertical cavity surface-fired laser structure of the present invention.

於本實施例中,本發明之垂直共振腔面射雷射結構是架構在一以砷化鎵(Gallium Arsenide;簡稱GaAs)或磷化銦(InP)材料為主的雷射晶片基材上,且該基材由下而上依序包括有:一基底10、一第一鏡層21位於該基底10之上、一活化層22(Active Region)位於該第一鏡層21上、以及第二鏡層23位於活化層22上。於該第二鏡層23內夾設有一氧化層231(Oxide Layer)。於本實施例中,該第一鏡層21是一n型分佈式布拉格反射鏡層(distributed Bragg reflector;簡稱DBR)其也可以稱為下鏡層,且該第二鏡層23是一p型分佈式布拉格反射鏡層其也可以稱為上鏡層。該第一鏡層21與該第二鏡層23之材質包含有不同鋁莫耳百分比之砷化鋁鎵(AlGaAs)的多層結構,並且,該氧化層231在第二鏡層23中是具有相對最高莫耳百分比的鋁。藉此,在氧化程序時,該氧化層231在氧化過程中可以形成絕緣的氧化鋁(Al2O3)。 In this embodiment, the vertical cavity surface-fired laser structure of the present invention is constructed on a laser chip substrate mainly made of gallium arsenide (GaAs) or indium phosphide (InP). And the substrate sequentially includes from bottom to top: a substrate 10, a first mirror layer 21 on the substrate 10, an active layer 22 (Active Region) on the first mirror layer 21, and a second The mirror layer 23 is located on the activation layer 22. An oxide layer 231 (Oxide Layer) is sandwiched in the second mirror layer 23. In this embodiment, the first mirror layer 21 is an n-type distributed Bragg reflector (distributed Bragg reflector; DBR for short), which can also be called a lower mirror layer, and the second mirror layer 23 is a p-type The distributed Bragg mirror layer may also be referred to as the upper mirror layer. The material of the first mirror layer 21 and the second mirror layer 23 includes a multilayer structure of aluminum gallium arsenide (AlGaAs) with different percentages of aluminum mol, and the oxide layer 231 has an opposite The highest molar percentage of aluminum. Therefore, during the oxidation process, the oxide layer 231 can form insulating aluminum oxide (Al2O3) during the oxidation process.

本發明之垂直共振腔面射雷射結構在該基材上還具有包括:一凸台區域30(Mesa)、一第一溝渠31(Isolation Trench)、一第二溝渠32、一第三溝渠33、一介電材料26(Dielectric Material)、一第一接觸層270(Contact Layer)、一第二接觸層271~273、一離子佈植層24(Implant Region)、一絕緣層25(Insolating Layer)、以及一出光層274(Power Output Layer)。 The vertical cavity surface-fired laser structure of the present invention further includes on the substrate: a boss region 30 (Mesa), a first trench 31 (Isolation Trench), a second trench 32, and a third trench 33 , A dielectric material 26 (Dielectric Material), a first contact layer 270 (Contact Layer), a second contact layer 271~273, an ion implantation layer 24 (Implant Region), an insulating layer 25 (Insolating Layer) , And a power output layer 274 (Power Output Layer).

該凸台區域30是位於該基底10之上、且是由至少一部分之該 第一鏡層21、該活化層22、該第二鏡層23以及該氧化層231所組構而成。於該凸台區域30的一頂面的一中央處具有一光窗300。於本實施例中,該氧化層231於高度上是與該離子佈植層24的底部是接近的,甚至有部分是重疊。 The boss area 30 is located on the substrate 10 and is composed of at least a part of the first mirror layer 21, the active layer 22, the second mirror layer 23, and the oxide layer 231. A light window 300 is provided at a center of a top surface of the boss area 30. In this embodiment, the oxide layer 231 is close to the bottom of the ion implantation layer 24 in height, and even partially overlaps.

該第一溝渠31是位於該凸台區域30之內、且環繞於該光窗300的外周緣的至少一部份。該第一溝渠31是由該凸台區域30的該頂面由上向下至少貫穿該第二鏡層23、該氧化層231與該活化層22,使第一溝渠31的底部是位於第一鏡層21。 The first trench 31 is located in the boss area 30 and surrounds at least a part of the outer periphery of the light window 300. The first trench 31 penetrates at least the second mirror layer 23, the oxide layer 231 and the activation layer 22 from the top surface of the boss region 30 from top to bottom, so that the bottom of the first trench 31 is located at the first Mirror layer 21.

該第二溝渠32是環繞於該凸台區域30之上半部的外周緣的至少一部份、且與該第一溝渠31相隔一間距。該第二溝渠32是由上向下至少貫穿該第二鏡層23與該氧化層231,使該第二溝渠32的一底部321是位於該活化層22處或該第一鏡層21處兩者其中之一。該氧化層231是由該溝渠31的內周緣朝向該凸台區域30之中央水平延伸。 The second trench 32 surrounds at least a part of the outer periphery of the upper half of the boss area 30 and is spaced apart from the first trench 31. The second trench 32 penetrates at least the second mirror layer 23 and the oxide layer 231 from top to bottom, so that a bottom 321 of the second trench 32 is located at the active layer 22 or the first mirror layer 21. One of them. The oxide layer 231 extends horizontally from the inner periphery of the trench 31 toward the center of the boss region 30.

該第三溝渠33是環繞於該凸台區域30之下半部的外周緣的至少一部份且是自該第二溝渠32的該底部321向下凹陷。並且,該第三溝渠33是由上向下至少貫穿該第一鏡層21(或是貫穿該活化層22及該第一鏡層21),使該第三溝渠33的一底部331是位於該基底10上表面處。 The third trench 33 surrounds at least a part of the outer periphery of the lower half of the boss area 30 and is recessed downward from the bottom 321 of the second trench 32. Moreover, the third trench 33 penetrates at least the first mirror layer 21 (or through the active layer 22 and the first mirror layer 21) from top to bottom, so that a bottom 331 of the third trench 33 is located on the At the upper surface of the substrate 10.

於本實施例中,該介電材料26是低介電性質的聚合物材料為較佳,且該介電材料26是至少填充於該第一溝渠31中,可提供降低垂直共振腔面射雷射結構之整體電容的功效。於本實施例中,此介電材料26是聚合物,可為Polymide,反射係數為1.5~1.6。本發明藉由挖出第一溝渠31並填補聚合物(介電材料26),可減少高介電系數的半導體材料的面積,故可以降低電容。該第一接觸層270與該第二接觸層271~273都是屬於金屬層27的一部份。該第一接觸層270是位於該凸台區域30之該頂面上且接觸於該第二鏡層23的一上表面240。該第二接觸層271、272、273是至少位於該第三溝渠33的該底部331且至少接觸於該基底10。於本實施例中,該第二接觸層271、272、273是由該第三溝渠33的該底部331沿著該第三溝渠33與該第二溝渠32分別各具有之一傾斜表面向上延伸至該第二鏡層23的上表面240,使該第二接觸層271、272、273的一頂面2710大致上是位於與該第一接觸層270之頂面的差不多相同高度。因此,本發明之第一接觸層270與第二接觸層271、272、273不僅是位於基底10的同一面、且更是位於大致相同的高度位 置,可以方便後續的打線製程。此外,於該第二溝渠32的該底部321形成一平面,使該第二接觸層271、272、273在該第二溝渠32的該底部321構成一水平延伸的狀態。藉此,不僅可以構成階梯狀的雙層凸台結構,使較大的下層凸台可加大散熱面積及降低熱效應,同時,兩階段凹陷的第二、第三溝渠結構32、33的傾斜面坡度變緩、且在該第二溝渠32的該底部321形成平面,可讓第二接觸層271、272、273在進行電鍍、濺鍍或蒸鍍金屬層時不易造成斷金現象。 In this embodiment, it is preferable that the dielectric material 26 is a polymer material with low dielectric properties, and the dielectric material 26 is filled at least in the first trench 31, which can reduce the vertical cavity surface laser The effectiveness of the overall capacitance of the radiation structure. In this embodiment, the dielectric material 26 is a polymer, which can be Polymide, and has a reflection coefficient of 1.5 to 1.6. In the present invention, by digging the first trench 31 and filling the polymer (dielectric material 26), the area of the semiconductor material with high dielectric coefficient can be reduced, so the capacitance can be reduced. The first contact layer 270 and the second contact layers 271 to 273 are all part of the metal layer 27. The first contact layer 270 is located on the top surface of the boss area 30 and contacts an upper surface 240 of the second mirror layer 23. The second contact layers 271, 272, and 273 are at least located at the bottom 331 of the third trench 33 and at least in contact with the substrate 10. In this embodiment, the second contact layers 271, 272, and 273 extend upward from the bottom 331 of the third trench 33 along the third trench 33 and the second trench 32 each having an inclined surface. The upper surface 240 of the second mirror layer 23 makes a top surface 2710 of the second contact layer 271, 272, and 273 approximately the same height as the top surface of the first contact layer 270. Therefore, the first contact layer 270 and the second contact layers 271, 272, and 273 of the present invention are not only located on the same surface of the substrate 10, but also located at approximately the same height, which facilitates the subsequent wire bonding process. In addition, a plane is formed on the bottom 321 of the second trench 32, so that the second contact layers 271, 272, and 273 form a horizontally extending state on the bottom 321 of the second trench 32. In this way, not only can a stepped double-layer boss structure be formed, the larger lower boss can increase the heat dissipation area and reduce the thermal effect, and at the same time, the two-stage recessed inclined surfaces of the second and third trench structures 32, 33 The slope becomes slower and the bottom 321 of the second trench 32 forms a plane, so that the second contact layer 271, 272, 273 is less likely to cause gold breakage during electroplating, sputtering, or vapor deposition of the metal layer.

該離子佈植層24是位於該第二鏡層23中、且是位於該主動層22的上方。於本實施例中,離子佈植層24的底部有部分與氧化層231重疊,並藉由氧化層231及離子佈植24的相對孔徑大小來控制光學模態。其中,離子佈植屬於增益波導(Gain-guided),氧化屬於折射波導(index guided),藉由兩者的混和應用可來控制光學模態。並且,位於該凸台區域30內的該離子佈植層24是位於該光窗300與該第一溝渠31之間、且是環繞於該光窗300的外周緣的至少一部份。其中,該第一接觸層270是接觸於該離子佈植層24的一上表面。本發明藉由在光窗300周圍額外設置的離子佈植區24,可用來控制光學模態及侷限電流;於本實施例中,離子佈植製程可植入質子(Proton)或氧離子,深度介於2~4um。 The ion implantation layer 24 is located in the second mirror layer 23 and above the active layer 22. In this embodiment, the bottom of the ion implantation layer 24 partially overlaps the oxide layer 231, and the relative aperture size of the oxide layer 231 and the ion implantation 24 is used to control the optical mode. Among them, ion implantation belongs to gain-guided, and oxidation belongs to index guided. The mixed application of the two can control the optical mode. Moreover, the ion implantation layer 24 located in the boss area 30 is located between the light window 300 and the first trench 31 and surrounds at least a part of the outer periphery of the light window 300. Wherein, the first contact layer 270 is in contact with an upper surface of the ion implantation layer 24. In the present invention, the ion implantation area 24 is additionally provided around the light window 300, which can be used to control the optical mode and limit the current. In this embodiment, the ion implantation process can implant protons (Proton) or oxygen ions. Between 2~4um.

該絕緣層25是覆蓋於該凸台區域30之一外表面的至少一部份,且該第一接觸層270與該第二接觸層271、272、273至少有一部份是暴露於該絕緣層25之外。該出光層274是位於該凸台區域30之該頂面的該光窗300上,可用來控制出光,其原理是利用出光層274之材料的折射率、厚度與光學波長來調整出。於本實施例中,該出光層274的材質可以是Si3N4、SiO2、Si3O4、SiN、或是SiNO等等。於本實施例中,該出光層274可為介電材質,材料成分可為二氧化矽(SiO2)、氮化矽(SiN)或是這兩種材料的混和體,反射係數介於1.5~2.0 The insulating layer 25 covers at least a part of an outer surface of the boss region 30, and at least a part of the first contact layer 270 and the second contact layers 271, 272, 273 are exposed to the insulating layer 25 outside. The light-emitting layer 274 is located on the light window 300 on the top surface of the boss region 30 and can be used to control the light. The principle is to adjust the refractive index, thickness and optical wavelength of the material of the light-emitting layer 274. In this embodiment, the material of the light emitting layer 274 can be Si3N4, SiO2, Si3O4, SiN, or SiNO, etc. In this embodiment, the light-emitting layer 274 can be a dielectric material, and the material composition can be silicon dioxide (SiO2), silicon nitride (SiN) or a mixture of these two materials, and the reflection coefficient is between 1.5 and 2.0.

請參閱圖二A至圖七,為本發明之垂直共振腔面射雷射結構的製法的一較佳實施例的其中數個階段示意圖。 Please refer to FIGS. 2A to 7, which are schematic diagrams of several stages of a preferred embodiment of the manufacturing method of the vertical cavity surface-fired laser structure of the present invention.

如圖二A所示,為本發明之垂直共振腔面射雷射結構的製法中的第一階段示意圖。本發明之垂直共振腔面射雷射結構的製法,首先是提供一雷射晶片基材,於該雷射晶片基材上由下而上依序構成:一基底10、 一第一鏡層21位於該基底10之上、一活化層22位於該第一鏡層21上、以及第二鏡層23位於活化層22上。接著,使用一第一光罩及實施一第一遮罩製程程序,在該第二鏡層23的一上表面240形成具有一第一預定圖案的一第一遮罩層,該第一預定圖案是對應於該第一光罩的圖案51。如圖二B所示,為本發明之該第一光罩的圖案51的實施例示意圖。於該第一光罩的圖案51中包含了一中心圓區域510以及環繞於該中心圓區域的外圍的一環狀區域511;其中,該中心圓區域510的半徑為r1,該環狀區域511之內圍的半徑為r2、且該環狀區域511之外圍的半徑為r3。該第一光罩圖案51之該中心圓區域510定義了在該第二鏡層23的上表面240會被遮罩5100覆蓋的該光窗300的位置,且該第一光罩圖案51之環狀區域511定義了在該第二鏡層23的上表面240會被遮罩5110覆蓋且不會被離子佈植的區域。該第一遮罩層即包括了該遮罩5100、5110。接著,如圖二A所示,實施一離子佈植程序,對該第二鏡層23未被該第一遮罩層(遮罩5100、5110)覆蓋的區域進行離子佈植以形成一離子佈植層24,且該離子佈植層24的一底部與該活化層22仍相距有一預定高度。於本實施例中,離子佈植有效區的底部可以有一部分與氧化層位置重疊。本發明藉由在光窗300周圍額外設置的離子佈植區24,可用來控制模態及侷限電流。 As shown in FIG. 2A, it is a schematic diagram of the first stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. The manufacturing method of the vertical cavity surface-fired laser structure of the present invention firstly provides a laser wafer substrate, on which the laser wafer substrate is formed sequentially from bottom to top: a substrate 10, a first mirror layer 21 On the substrate 10, an active layer 22 is on the first mirror layer 21, and the second mirror layer 23 is on the active layer 22. Next, using a first mask and implementing a first mask process procedure, a first mask layer having a first predetermined pattern is formed on an upper surface 240 of the second mirror layer 23, the first predetermined pattern It is the pattern 51 corresponding to the first mask. As shown in FIG. 2B, it is a schematic diagram of an embodiment of the pattern 51 of the first mask of the present invention. The pattern 51 of the first mask includes a central circular area 510 and an annular area 511 surrounding the periphery of the central circular area; wherein the radius of the central circular area 510 is r1, and the circular area 511 The radius of the inner circumference is r2, and the radius of the outer periphery of the annular region 511 is r3. The center circle area 510 of the first mask pattern 51 defines the position of the light window 300 that will be covered by the mask 5100 on the upper surface 240 of the second mirror layer 23, and the ring of the first mask pattern 51 The shaped area 511 defines an area where the upper surface 240 of the second mirror layer 23 will be covered by the mask 5110 and will not be implanted by ions. The first mask layer includes the masks 5100 and 5110. Next, as shown in FIG. 2A, an ion implantation procedure is implemented to perform ion implantation on the area of the second mirror layer 23 not covered by the first mask layer (masks 5100, 5110) to form an ion implant The implanted layer 24, and a bottom of the ion implanted layer 24 and the activation layer 22 are still separated by a predetermined height. In this embodiment, a part of the bottom of the ion implantation effective area may overlap with the position of the oxide layer. In the present invention, the ion implantation area 24 is additionally provided around the light window 300, which can be used to control the mode and limit the current.

如圖三A所示,為本發明之垂直共振腔面射雷射結構的製法中的第二階段示意圖。在尚未移除第一遮罩層5100、5110的情況下,使用一第二光罩及實施一第二遮罩製程程序,在該第二鏡層23的該上表面240及該第一遮罩層5100、5110的上方形成具有一第二預定圖案的一第二遮罩層,該第二預定圖案是對應於該第二光罩的圖案52。如圖三B所示,為本發明之該第二光罩的圖案52的實施例示意圖。於該第二光罩的圖案52中包含了一中心圓區域520以及環繞於該中心圓區域的外圍的一外圍區域521;其中,該中心圓區域520的半徑為R1,該外圍區域521之內圍的半徑為R2。該第二光罩圖案52之該中心圓區域520及該外圍區域521定義了在該第二鏡層23的上表面240會被遮罩5200、5210覆蓋的位置,且未被該遮罩5200、5210覆蓋的區域就是稍後會被蝕刻產生第一溝渠31的位置。該第二遮罩層即包括了該遮罩5200、5210。 As shown in FIG. 3A, it is a schematic diagram of the second stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. In the case where the first mask layers 5100 and 5110 have not been removed, a second mask is used and a second mask process procedure is performed. On the upper surface 240 of the second mirror layer 23 and the first mask A second mask layer having a second predetermined pattern is formed above the layers 5100 and 5110, and the second predetermined pattern corresponds to the pattern 52 of the second mask. As shown in FIG. 3B, it is a schematic diagram of an embodiment of the pattern 52 of the second mask of the present invention. The pattern 52 of the second mask includes a central circular area 520 and a peripheral area 521 surrounding the periphery of the central circular area; wherein the radius of the central circular area 520 is R1, which is within the peripheral area 521 The radius of the circumference is R2. The central circular area 520 and the peripheral area 521 of the second mask pattern 52 define the positions on the upper surface 240 of the second mirror layer 23 that will be covered by the masks 5200, 5210, and are not covered by the masks 5200, The area covered by 5210 is the location where the first trench 31 will be etched later. The second mask layer includes the masks 5200 and 5210.

於本實施例中,該第二光罩圖案52之該中心圓區域520的半 徑R1的值是介於該第一光罩圖案51之該環狀區域511之內圍半徑r2與外圍的半徑r3之間,亦即,r2<R1<r3;並且,該第二光罩圖案52之該外圍區域521之內圍的半徑R2的值是大於該第一光罩圖案51之該環狀區域511之外圍的半徑r3,亦即,r3<R2。因此,在進行前述第一遮罩與第二遮罩的兩道遮罩製程程序時,會具有自我對準的效果,使後續製程所得到之氧化層231孔徑與離子佈植層24孔徑對準精度增加。 In this embodiment, the value of the radius R1 of the central circular area 520 of the second mask pattern 52 is between the inner radius r2 and the outer radius r3 of the annular area 511 of the first mask pattern 51 In other words, r2<R1<r3; and, the value of the radius R2 of the inner circumference of the peripheral area 521 of the second mask pattern 52 is greater than the value of the ring-shaped area 511 of the first mask pattern 51 The outer radius r3, that is, r3<R2. Therefore, when performing the aforementioned two mask process procedures of the first mask and the second mask, it will have a self-alignment effect, so that the aperture of the oxide layer 231 obtained by the subsequent process is aligned with the aperture of the ion implantation layer 24 Increased accuracy.

接著,如圖四所示,為本發明之垂直共振腔面射雷射結構的製法中的第三階段示意圖。實施一第一蝕刻程序,對該第二鏡層23、該活化層22及該第一鏡層21未被該第二遮罩層(遮罩5200、5210)覆蓋的區域進行蝕刻,以形成一第一溝渠31,且該第一溝渠31是自該第二鏡層23的該上表面240向下貫穿該第二鏡層23及該活化層22,使該第一溝渠31的一底部是位於該第一鏡層21。 Next, as shown in FIG. 4, it is a schematic diagram of the third stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. A first etching process is performed to etch the second mirror layer 23, the activation layer 22, and the area of the first mirror layer 21 not covered by the second mask layer (mask 5200, 5210) to form a The first trench 31, and the first trench 31 penetrates the second mirror layer 23 and the activation layer 22 downward from the upper surface 240 of the second mirror layer 23, so that a bottom of the first trench 31 is located The first mirror layer 21.

接著,如圖五所示,為本發明之垂直共振腔面射雷射結構的製法中的第四階段示意圖。實施一氧化程序,以便透過該第一溝渠31而在該第二鏡層23內形成水平延伸之一氧化層231,且該氧化層231於高度上是與離子佈植層24是接近的,甚至可以有部分重疊,並且,該氧化層231是位在活化層22之上。相較於習知技術因不具第一溝渠31的結構所以必須透過第二溝渠32來進行氧化層之氧化程序的習知技術而言,本發明由於該氧化層231的氧化程序是透過相對來說更接近光窗300的該第一溝渠31來進行,所以,所需氧化的距離相對較短、氧化程序所需的時間也因此縮短,也減少氧化層231因氧化距離長所衍伸的應力聚集問題。 Next, as shown in FIG. 5, it is a schematic diagram of the fourth stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. An oxidation process is performed to form a horizontally extending oxide layer 231 in the second mirror layer 23 through the first trench 31, and the oxide layer 231 is close to the ion implantation layer 24 in height, even There may be a partial overlap, and the oxide layer 231 is located on the active layer 22. Compared with the conventional technology, which does not have the structure of the first trench 31, the oxidation process of the oxide layer must be performed through the second trench 32, in the present invention, since the oxidation process of the oxide layer 231 is relatively speaking The first trench 31 is closer to the light window 300, so the required oxidation distance is relatively short, and the time required for the oxidation process is therefore shortened, and the problem of stress accumulation due to the long oxidation distance of the oxide layer 231 is reduced. .

接著,如圖六所示,為本發明之垂直共振腔面射雷射結構的製法中的第五階段示意圖。實施一第二蝕刻程序,以便在該第二鏡層23上形成一第二溝渠32,且該第二溝渠32是自該第二鏡層23的該上表面240向下至少貫穿該第二鏡層23與該氧化層231,使該第二溝渠32的一底部321是位於該活化層22處或該第一鏡層21處兩者其中之一。並且,以一金屬鍍層程序在該第二鏡層23的該上表面240的一預定區域形成一接觸墊也就是稍後會成為第一接觸層270的一部份。 Next, as shown in FIG. 6, it is a schematic diagram of the fifth stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. A second etching process is performed to form a second trench 32 on the second mirror layer 23, and the second trench 32 penetrates at least through the second mirror from the upper surface 240 of the second mirror layer 23 downward The layer 23 and the oxide layer 231 make a bottom 321 of the second trench 32 located at either the active layer 22 or the first mirror layer 21. In addition, a contact pad is formed on a predetermined area of the upper surface 240 of the second mirror layer 23 by a metal plating process, which will become a part of the first contact layer 270 later.

接著,如圖七所示,為本發明之垂直共振腔面射雷射結構的製法中的第六階段示意圖。實施一第三蝕刻程序,以便在該第二溝渠32的該底部321處形成向下凹陷之一第三溝渠33,且該第三溝渠33是由上向下至少貫穿該第一鏡層21(或是貫穿該活化層22及該第一鏡層21),使該第三溝渠33的一底部331是位於該基底10處。 Next, as shown in FIG. 7, it is a schematic diagram of the sixth stage in the manufacturing method of the vertical cavity surface-fired laser structure of the present invention. A third etching process is performed to form a downwardly recessed third trench 33 at the bottom 321 of the second trench 32, and the third trench 33 penetrates at least the first mirror layer 21 from top to bottom ( Or penetrate the active layer 22 and the first mirror layer 21) so that a bottom 331 of the third trench 33 is located at the substrate 10.

之後,再於該第一溝渠31中填充一介電材料26,可提供降低垂直共振腔面射雷射結構之整體電容的功效;以及,在該雷射晶片基材上的適當區域分別形成一出光層274、一絕緣層25、一金屬層27(包括第一接觸層270以及第二接觸層271、272、273)。藉此,便能製作出如圖一所示之本發明之垂直共振腔面射雷射結構。 Afterwards, a dielectric material 26 is filled in the first trench 31 to provide the effect of reducing the overall capacitance of the vertical resonant cavity surface-fired laser structure; and to form an appropriate area on the laser chip substrate. The light emitting layer 274, an insulating layer 25, and a metal layer 27 (including the first contact layer 270 and the second contact layers 271, 272, and 273). In this way, the vertical cavity surface-fired laser structure of the present invention as shown in FIG. 1 can be manufactured.

於本實施例中,如圖一所示,由該第二溝渠32與該第三溝渠33可在該雷射晶片基材上定義出一凸台區域30,該第二溝渠32與該第三溝渠33兩者都是環繞於該凸台區域30的外周緣的至少一部份。該凸台區域30是位於該基底10之上、且是由至少一部分之該第一鏡層21、該活化層22、該第二鏡層23以及該氧化層231所組構而成。於該凸台區域30的一頂面的一中央處具有一光窗300。該第一溝渠31是位於該凸台區域30之內、且環繞於該光窗300的外周緣的至少一部份、且與該第二溝渠32相隔一間距。該第一溝渠31是由該凸台區域30的頂面由上向下至少貫穿該第二鏡層23、該氧化層231與該活化層22。 In this embodiment, as shown in FIG. 1, the second trench 32 and the third trench 33 define a boss area 30 on the laser chip substrate, and the second trench 32 and the third trench Both the trenches 33 surround at least a part of the outer periphery of the boss area 30. The boss area 30 is located on the substrate 10 and is composed of at least a part of the first mirror layer 21, the active layer 22, the second mirror layer 23 and the oxide layer 231. A light window 300 is provided at a center of a top surface of the boss area 30. The first trench 31 is located in the boss area 30 and surrounds at least a part of the outer periphery of the light window 300 and is separated from the second trench 32 by a distance. The first trench 31 penetrates at least the second mirror layer 23, the oxide layer 231 and the activation layer 22 from the top surface of the boss region 30 from top to bottom.

於本實施例中,該出光層274是位於該凸台區域30之該頂面的該光窗300上,可用來控制出光。該離子佈植層24是位於該第二鏡層23中且是位於該氧化層231的上方但離子佈植層24底部可以和氧化層231部分重疊,並且,位於該凸台區域30內的該該離子佈植層24是位於該光窗300與該第一溝渠31之間、且是環繞於該光窗300的外周緣的至少一部份,可用來控制模態及侷限電流。 In this embodiment, the light-emitting layer 274 is located on the light window 300 on the top surface of the boss area 30 and can be used to control light-emitting. The ion implantation layer 24 is located in the second mirror layer 23 and above the oxide layer 231, but the bottom of the ion implantation layer 24 can partially overlap with the oxide layer 231, and is located in the boss region 30 The ion implantation layer 24 is located between the light window 300 and the first trench 31 and surrounds at least a part of the outer periphery of the light window 300, and can be used to control mode and limit current.

於本實施例中,該第一接觸層270是位於該凸台區域30之該頂面上且接觸於該第二鏡層23的上表面。該第二接觸層271、272、273是至少位於該第三溝渠33的該底部331且至少接觸於該基底10,且該第二接觸層271、272、273是由該第三溝渠33的該底部331沿著該第三溝渠33與該第二溝渠32分別各具有之一傾斜表面向上延伸至該第二鏡層23的該上表面,使該第二接觸層271、272、273的一頂面大致上是位於與該第一接觸層270的差不多相同高度。因此,本發明之第一接觸層270與第二接觸層271、272、 273不僅是位於基底10的同一面、且更是位於大致相同的高度位置,可以方便後續的打線製程。該第一接觸層270與該第二接觸層271、272、273至少有一部份是暴露於該絕緣層25之外。其中,於該第二溝渠32的該底部321形成一平面,使該第二接觸層271、272、273在該第二溝渠32的該底部321構成一水平延伸的狀態。藉此,不僅可以構成階梯狀的雙層凸台結構,使較大的下層凸台可加大散熱面積及降低熱效應,同時,兩階段凹陷的第二、第三溝渠結構32、33的傾斜面坡度變緩、且在該第二溝渠32的該底部321形成平面,可讓第二接觸層271、272、273在進行電鍍、濺鍍或蒸鍍金屬層時不易造成斷金現象。 In this embodiment, the first contact layer 270 is located on the top surface of the boss area 30 and contacts the upper surface of the second mirror layer 23. The second contact layers 271, 272, 273 are located at least at the bottom 331 of the third trench 33 and at least contact the substrate 10, and the second contact layers 271, 272, 273 are formed by the third trench 33 The bottom 331 has an inclined surface along the third trench 33 and the second trench 32, respectively, and extends upward to the upper surface of the second mirror layer 23, so that a top surface of the second contact layer 271, 272, 273 The surface is approximately at the same height as the first contact layer 270. Therefore, the first contact layer 270 and the second contact layers 271, 272, 273 is not only located on the same surface of the substrate 10, but also located at approximately the same height position, which can facilitate the subsequent wire bonding process. At least a part of the first contact layer 270 and the second contact layers 271, 272, and 273 are exposed outside the insulating layer 25. Wherein, a plane is formed on the bottom 321 of the second trench 32, so that the second contact layers 271, 272, 273 form a horizontally extending state on the bottom 321 of the second trench 32. In this way, not only can a stepped double-layer boss structure be formed, the larger lower boss can increase the heat dissipation area and reduce the thermal effect, and at the same time, the two-stage recessed inclined surfaces of the second and third trench structures 32, 33 The slope becomes slower and the bottom 321 of the second trench 32 forms a plane, so that the second contact layer 271, 272, 273 is less likely to cause gold breakage during electroplating, sputtering, or vapor deposition of the metal layer.

以上所述僅為本發明之較佳可行實施例,非因此侷限本發明之專利範圍,故舉凡運用本發明說明書及圖示內容所為之等效技術變化,均包含於本發明之範圍內。The above descriptions are only the preferred and feasible embodiments of the present invention, and do not limit the patent scope of the present invention. Therefore, all equivalent technical changes made by using the description and illustrations of the present invention are included in the scope of the present invention.

10‧‧‧基底 10‧‧‧Base

21‧‧‧第一鏡層 21‧‧‧First mirror layer

22‧‧‧活化層 22‧‧‧Activated layer

23‧‧‧第二鏡層 23‧‧‧Second mirror layer

231‧‧‧氧化層 231‧‧‧Oxide layer

24‧‧‧離子佈植層 24‧‧‧Ion implantation layer

240‧‧‧上表面 240‧‧‧Upper surface

25‧‧‧絕緣層 25‧‧‧Insulation layer

26‧‧‧介電材料 26‧‧‧Dielectric materials

27‧‧‧金屬層 27‧‧‧Metal layer

270‧‧‧第一接觸層 270‧‧‧First contact layer

271~273‧‧‧第二接觸層 271~273‧‧‧Second contact layer

2710‧‧‧頂面 2710‧‧‧Top surface

274‧‧‧出光層 274‧‧‧light emitting layer

30‧‧‧凸台區域 30‧‧‧Protrusion area

300‧‧‧光窗 300‧‧‧Light window

31‧‧‧第一溝渠 31‧‧‧First Ditch

32‧‧‧第二溝渠 32‧‧‧Second Ditch

321、331‧‧‧底部 321, 331‧‧‧Bottom

33‧‧‧第三溝渠 33‧‧‧Third Ditch

Claims (10)

一種垂直共振腔面射雷射結構,包括:一基底;一第一鏡層,位於該基底之上;一活化層,位於該第一鏡層上;一第二鏡層,位於活化層上;一氧化層,夾設於該第二鏡層內;一凸台區域,位於該基底之上、且是由至少一部分之該第一鏡層、該活化層、該第二鏡層以及該氧化層所組構而成,於該凸台區域的一頂面的一中央處具有一光窗;一第一溝渠,位於該凸台區域之內、且環繞於該光窗的外周緣的至少一部份;該第一溝渠是由該凸台區域的該頂面由上向下至少貫穿該第二鏡層、該氧化層與該活化層;一第二溝渠,環繞於該凸台區域的外周緣的至少一部份、且與該第一溝渠相隔一間距,該第二溝渠是由上向下至少貫穿該第二鏡層與該氧化層,使該第二溝渠的一底部是位於該活化層處或該第一鏡層處兩者其中之一;一第三溝渠,環繞於該凸台區域的外周緣的至少一部份且是自該第二溝渠的該底部向下凹陷,且該第三溝渠是由上向下至少貫穿該第一鏡層,使該第三溝渠的一底部是位於該基底處;一介電材料,至少填充於該第一溝渠中;一第一接觸層,位於該凸台區域之該頂面上且接觸於該第二鏡層;以及一第二接觸層,至少位於該第三溝渠的該底部且至少接觸於該基底。 A vertical cavity surface-fired laser structure, comprising: a substrate; a first mirror layer on the substrate; an active layer on the first mirror layer; a second mirror layer on the active layer; An oxide layer is sandwiched in the second mirror layer; a boss area is located on the substrate and consists of at least a part of the first mirror layer, the activation layer, the second mirror layer, and the oxide layer Assembled, there is a light window at a center of a top surface of the boss area; a first trench is located in the boss area and surrounds at least a part of the outer periphery of the light window The first trench is from the top surface of the boss region through at least the second mirror layer, the oxide layer and the activation layer from top to bottom; a second trench surrounds the outer periphery of the boss region At least a part of and spaced apart from the first trench, the second trench at least penetrates the second mirror layer and the oxide layer from top to bottom, so that a bottom of the second trench is located on the active layer Or the first mirror layer; a third trench, which surrounds at least a part of the outer periphery of the boss area and is recessed downward from the bottom of the second trench, and the first Three trenches penetrate at least the first mirror layer from top to bottom, so that a bottom of the third trench is located at the substrate; a dielectric material is filled at least in the first trench; a first contact layer is located The top surface of the boss area is in contact with the second mirror layer; and a second contact layer is located at least at the bottom of the third trench and at least in contact with the substrate. 如申請專利範圍第1項所述之垂直共振腔面射雷射結構,其中:該垂直共振腔面射雷射結構更包括有一絕緣層,覆蓋於該凸台區域之一外表面的至少一部份,且該第一接觸層與該第二接觸層至少有一部份是暴露於該絕緣層之外;該第一鏡層是一n型分佈式布拉格反射鏡層(distributed Bragg reflector;簡稱DBR),且該第二鏡層是一p型分佈式布拉格反射鏡層;該第一鏡層與該第二鏡層之材質包含有不同鋁莫耳百分比之砷化鋁鎵 (AlGaAs),並且,該氧化層在第二鏡層中是具有相對最高莫耳百分比的鋁;該氧化層至少是由該第一溝渠的內周緣朝向該凸台區域之中央水平延伸;該介電材料是低介電性質的聚合物材料;以及該第一接觸層與該第二接觸層都是金屬層。 The vertical cavity surface-fired laser structure described in the first item of the scope of patent application, wherein: the vertical cavity surface-fired laser structure further includes an insulating layer covering at least a part of an outer surface of the boss area And at least a part of the first contact layer and the second contact layer are exposed outside the insulating layer; the first mirror layer is an n-type distributed Bragg reflector (DBR) , And the second mirror layer is a p-type distributed Bragg reflector layer; the materials of the first mirror layer and the second mirror layer include aluminum gallium arsenide (AlGaAs) with different aluminum mole percentages, and the The oxide layer in the second mirror layer is aluminum with the relatively highest molar percentage; the oxide layer extends at least horizontally from the inner periphery of the first trench toward the center of the boss region; the dielectric material has low dielectric properties的 polymer material; and the first contact layer and the second contact layer are both metal layers. 如申請專利範圍第1項所述之垂直共振腔面射雷射結構,更包括有:一離子佈植層,位於該第二鏡層中且其高度是與與該氧化層接近或重疊,並且,位於該凸台區域內的該離子佈植層是位於該光窗與該第一溝渠之間、且是環繞於該光窗的外周緣的至少一部份;其中,該第一接觸層是接觸於該第二鏡層的一上表面。 The vertical resonant cavity surface-fired laser structure described in item 1 of the scope of patent application further includes: an ion implantation layer located in the second mirror layer and whose height is close to or overlapping with the oxide layer, and , The ion implantation layer located in the boss area is located between the light window and the first trench and surrounds at least a part of the outer periphery of the light window; wherein, the first contact layer is It is in contact with an upper surface of the second mirror layer. 如申請專利範圍第1項所述之垂直共振腔面射雷射結構,更包括有:一出光層,位於該凸台區域之該頂面的該光窗上。 As described in item 1 of the scope of patent application, the vertical resonant cavity surface-fired laser structure further includes: a light emitting layer located on the light window on the top surface of the boss area. 如申請專利範圍第1項所述之垂直共振腔面射雷射結構,其中:該第二接觸層是由該第三溝渠的該底部沿著該第三溝渠與該第二溝渠分別各具有之一傾斜表面向上延伸至該第二鏡層的一上表面,使該第二接觸層的一頂面大致上是位於與該第一接觸層的相同高度;於該第二溝渠的該底部形成一平面,使該第二接觸層在該第二溝渠的該底部構成一水平延伸的狀態。 The vertical resonant cavity surface-fired laser structure described in the first item of the scope of patent application, wherein: the second contact layer is formed from the bottom of the third trench along the third trench and the second trench. An inclined surface extends upward to an upper surface of the second mirror layer, so that a top surface of the second contact layer is substantially at the same height as the first contact layer; a bottom of the second trench is formed The plane makes the second contact layer form a horizontally extending state at the bottom of the second trench. 一種垂直共振腔面射雷射結構的製法,包括下列步驟:提供一雷射晶片基材,於該雷射晶片基材上藉由一半導體製程由下而上依序構成:一基底、一第一鏡層位於該基底之上、一活化層位於該第一鏡層上、以及第二鏡層位於活化層上;使用一第一光罩及實施一第一遮罩製程程序,在該第二鏡層的一上表面形成具有一第一預定圖案的一第一遮罩層,該第一預定圖案是對應於該第一光罩的圖案;實施一離子佈植程序,對該第二鏡層未被該第一光阻層覆蓋的區域進行離子佈植以形成一離子佈植層,且該離子佈植層的一底部與該活化層仍相距有一預定高度;在尚未移除第一遮罩層的情況下,使用一第二光罩及實施一第二遮罩製程程序,在該第二鏡層的該上表面及該第一遮罩層的上方形成具有一第二 預定圖案的一第二遮罩層,該第二預定圖案是對應於該第二遮罩的圖案;實施一第一蝕刻程序,對該第二鏡層、該活化層及該第一鏡層未被該第二遮罩層覆蓋的區域進行蝕刻,以形成一第一溝渠,且該第一溝渠是自該第二鏡層的該上表面向下貫穿該第二鏡層及該活化層,使該第一溝渠的一底部是位於該第一鏡層;實施一氧化程序,以便透過該第一溝渠而在該第二鏡層內形成水平延伸之一氧化層,且該氧化層於高度上是接近或重疊於該離子佈植層的該底部;實施一第二蝕刻程序,以便在該第二鏡層上形成一第二溝渠,且該第二溝渠是自該第二鏡層的該上表面向下至少貫穿該第二鏡層與該氧化層,使該第二溝渠的一底部是位於該活化層處或該第一鏡層處兩者其中之一;並且,以一金屬鍍層程序在該第二鏡層的該上表面的一預定區域形成一接觸墊;實施一第三蝕刻程序,以便在該第二溝渠的該底部處形成向下凹陷之一第三溝渠,且該第三溝渠是由上向下至少貫穿該第一鏡層,使該第三溝渠的一底部是位於該基底處;以及,於該第一溝渠中填充一介電材料,以及在該雷射晶片基材上的適當區域分別形成一絕緣層、一第一接觸層以及一第二接觸層;其中,由該第二溝渠與該第三溝渠可在該雷射晶片基材上定義出一凸台區域,該第二溝渠與該第三溝渠兩者都是環繞於該凸台區域的外周緣的至少一部份;該凸台區域是位於該基底之上、且是由至少一部分之該第一鏡層、該活化層、該第二鏡層以及該氧化層所組構而成,於該凸台區域的一頂面的一中央處具有一光窗;該第一溝渠是位於該凸台區域之內、且環繞於該光窗的外周緣的至少一部份、且與該第二溝渠相隔一間距;該第一溝渠是由該凸台區域的頂面由上向下至少貫穿該第二鏡層、該氧化層與該活化層;其中,該第一接觸層是位於該凸台區域之該頂面上且接觸於該第二鏡層;該第二接觸層是至少位於該第三溝渠的該底部且至少接觸於該基底,且該第二接觸層是由該第三溝渠的該底部沿著該第三溝渠與該第二溝渠 分別各具有之一傾斜表面向上延伸至該第二鏡層的該上表面,使該第二接觸層的一頂面大致上是位於與該第一接觸層的相同高度;該第一接觸層與該第二接觸層至少有一部份是暴露於該絕緣層之外。 A method for manufacturing a vertical cavity surface-fired laser structure includes the following steps: a laser chip substrate is provided on which a semiconductor manufacturing process is formed from bottom to top: a substrate, a substrate A mirror layer is located on the substrate, an activation layer is located on the first mirror layer, and a second mirror layer is located on the activation layer; a first mask is used and a first mask process procedure is performed, and the second mirror layer is A first mask layer having a first predetermined pattern is formed on an upper surface of the mirror layer, the first predetermined pattern is corresponding to the pattern of the first mask; an ion implantation procedure is performed to the second mirror layer The area not covered by the first photoresist layer is ion implanted to form an ion implantation layer, and a bottom of the ion implantation layer is still a predetermined height away from the activation layer; the first mask has not been removed In the case of layer, a second mask is used and a second mask manufacturing process is performed, and a first mask with a second predetermined pattern is formed on the upper surface of the second mirror layer and above the first mask layer Two mask layers, the second predetermined pattern is a pattern corresponding to the second mask; a first etching process is performed, and the second mirror layer, the activation layer, and the first mirror layer are not covered by the second mirror layer The area covered by the mask layer is etched to form a first trench, and the first trench penetrates the second mirror layer and the activation layer from the upper surface of the second mirror layer downward to make the first trench A bottom is located on the first mirror layer; an oxidation process is performed to form an oxide layer extending horizontally in the second mirror layer through the first trench, and the oxide layer is close to or overlaps the second mirror layer in height The bottom of the ion implantation layer; a second etching process is performed to form a second trench on the second mirror layer, and the second trench is from the upper surface of the second mirror layer downward at least through the The second mirror layer and the oxide layer are such that a bottom of the second trench is located at one of the active layer or the first mirror layer; and a metal plating process is performed on the second mirror layer A predetermined area of the upper surface forms a contact pad; a third etching process is performed to form a third trench recessed downward at the bottom of the second trench, and the third trench is at least from top to bottom Pass through the first mirror layer so that a bottom of the third trench is located at the substrate; and fill a dielectric material in the first trench, and respectively form an appropriate area on the laser chip substrate An insulating layer, a first contact layer, and a second contact layer; wherein the second trench and the third trench define a boss area on the laser chip substrate, the second trench and the first Both of the three trenches surround at least a part of the outer periphery of the boss area; the boss area is located on the substrate and consists of at least a part of the first mirror layer, the activation layer, and the second The two mirror layers and the oxide layer are composed of a light window at a center of a top surface of the boss area; the first trench is located in the boss area and surrounds the light window At least a part of the outer periphery of the rim and the second trench is separated by a distance; the first trench is from the top surface of the boss region through at least the second mirror layer, the oxide layer and the activation Layer; where , The first contact layer is located on the top surface of the boss area and in contact with the second mirror layer; the second contact layer is located at least on the bottom of the third trench and at least in contact with the substrate, and the The second contact layer extends upward to the upper surface of the second mirror layer from the bottom of the third trench along the third trench and the second trench each having an inclined surface, so that the second contact layer A top surface of is substantially located at the same height as the first contact layer; at least a part of the first contact layer and the second contact layer are exposed outside the insulating layer. 如申請專利範圍第6項所述之垂直共振腔面射雷射結構的製法,其中:該第一鏡層是一n型分佈式布拉格反射鏡層(distributed Bragg reflector;簡稱DBR),且該第二鏡層是一p型分佈式布拉格反射鏡層;該第一鏡層與該第二鏡層之材質包含有不同鋁莫耳百分比之砷化鋁鎵(AlGaAs),並且,該氧化層在第二鏡層中是具有相對最高莫耳百分比的鋁;該氧化層至少是由該第一溝渠的內周緣朝向該凸台區域之中央水平延伸;該介電材料是低介電性質的聚合物材料;以及該第一接觸層與該第二接觸層都是金屬層。 As described in item 6 of the scope of patent application, the method for manufacturing a vertical cavity surface-fired laser structure, wherein: the first mirror layer is an n-type distributed Bragg reflector (DBR), and the first mirror layer The second mirror layer is a p-type distributed Bragg reflector layer; the materials of the first mirror layer and the second mirror layer include aluminum gallium arsenide (AlGaAs) with different percentages of aluminum mol, and the oxide layer is in the first The second mirror layer is aluminum with the relatively highest molar percentage; the oxide layer extends horizontally at least from the inner periphery of the first trench toward the center of the boss area; the dielectric material is a polymer material with low dielectric properties ; And the first contact layer and the second contact layer are both metal layers. 如申請專利範圍第6項所述之垂直共振腔面射雷射結構的製法,其中,該離子佈植層是位於該第二鏡層中,並且,位於該凸台區域內的該離子佈植層是位於該光窗與該第一溝渠之間、且是環繞於該光窗的外周緣的至少一部份。 As described in item 6 of the scope of patent application, the method for manufacturing a vertical resonant cavity surface shot laser structure, wherein the ion implantation layer is located in the second mirror layer, and the ion implantation layer located in the boss region The layer is located between the light window and the first trench and surrounds at least a part of the outer periphery of the light window. 如申請專利範圍第6項所述之垂直共振腔面射雷射結構的製法,更包括有下列步驟:形成一出光層,其位於該凸台區域之該頂面的該光窗上。 As described in item 6 of the scope of patent application, the manufacturing method of the vertical resonant cavity surface-fired laser structure further includes the following steps: forming a light emitting layer, which is located on the light window on the top surface of the boss area. 如申請專利範圍第6項所述之垂直共振腔面射雷射結構的製法,其中,於該第二溝渠的該底部形成一平面,使該第二接觸層在該第二溝渠的該底部構成一水平延伸的狀態。 The method for manufacturing a vertical resonant cavity surface-fired laser structure as described in item 6 of the scope of patent application, wherein a plane is formed on the bottom of the second trench, so that the second contact layer is formed on the bottom of the second trench A state of horizontal extension.
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