CN114211894B - Color re-transfer printing film for transparent soft label base material - Google Patents
Color re-transfer printing film for transparent soft label base material Download PDFInfo
- Publication number
- CN114211894B CN114211894B CN202111534499.0A CN202111534499A CN114211894B CN 114211894 B CN114211894 B CN 114211894B CN 202111534499 A CN202111534499 A CN 202111534499A CN 114211894 B CN114211894 B CN 114211894B
- Authority
- CN
- China
- Prior art keywords
- color
- parts
- coating
- substrate
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 22
- 238000010023 transfer printing Methods 0.000 title claims abstract description 16
- 239000000758 substrate Substances 0.000 claims abstract description 83
- 239000010410 layer Substances 0.000 claims abstract description 71
- 239000011248 coating agent Substances 0.000 claims abstract description 69
- 238000000576 coating method Methods 0.000 claims abstract description 69
- 239000011241 protective layer Substances 0.000 claims abstract description 64
- 238000012546 transfer Methods 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 34
- 239000011347 resin Substances 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 18
- 229920001225 polyester resin Polymers 0.000 claims description 16
- 239000004645 polyester resin Substances 0.000 claims description 16
- -1 aldehyde ketone Chemical class 0.000 claims description 15
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 claims description 13
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 13
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 4
- 239000003973 paint Substances 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920000180 alkyd Polymers 0.000 claims description 2
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000011856 silicon-based particle Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000007639 printing Methods 0.000 abstract description 26
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 20
- 239000011737 fluorine Substances 0.000 description 20
- 229910052731 fluorine Inorganic materials 0.000 description 20
- 239000004611 light stabiliser Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 239000012790 adhesive layer Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical class C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 4
- 150000008360 acrylonitriles Chemical class 0.000 description 4
- 239000012965 benzophenone Substances 0.000 description 4
- 150000008366 benzophenones Chemical class 0.000 description 4
- 150000001565 benzotriazoles Chemical class 0.000 description 4
- XPBBUZJBQWWFFJ-UHFFFAOYSA-N fluorosilane Chemical compound [SiH3]F XPBBUZJBQWWFFJ-UHFFFAOYSA-N 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 150000003902 salicylic acid esters Chemical class 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007756 gravure coating Methods 0.000 description 2
- 238000007641 inkjet printing Methods 0.000 description 2
- 238000007648 laser printing Methods 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- 235000021419 vinegar Nutrition 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/42—Gloss-reducing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2427/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a color re-transfer printing film for a transparent soft label substrate, and belongs to the technical field of soft label printing. The color re-transfer printing film for the transparent soft label base material comprises a substrate, a protective layer and a pattern receiving layer which are sequentially attached from top to bottom; the protective layer is formed by coating the following raw materials in parts by weight: 50-90 parts of first resin and 10-50 parts of pigment; the pattern receiving layer is formed by coating the following raw materials in parts by weight: 99 parts of second resin and 1 part of matting powder. Has the advantages that: the adhesion between the re-transfer film and the soft label base material can not be influenced by adding the pigment into the protective layer, the pattern is printed on the colorful re-transfer film in a thermal transfer printing mode, then the colorful re-transfer film is hot-stamped to the surface of the transparent base material in a hot stamping mode, and the re-transfer film is self-provided with a background color when used for soft label printing on the transparent base material, so that extra background color printing is not needed, the printing process is simplified, the cost is reduced, and the printing quality is improved.
Description
Technical Field
The invention belongs to the technical field of soft label printing, and particularly relates to a color re-transfer printing film for a transparent soft label substrate.
Background
At present, the soft label printing modes mainly comprise ink-jet printing, laser printing, thermal transfer printing and the like. Ink jet printing is the process of jetting corresponding colored inks through nozzles onto a substrate to produce a desired image. Laser printing refers to that the surface of a substrate is partially discharged by laser to attract corresponding toner to finish printing. The two printing modes have poor environmental protection performance, and can only complete the printing of the whole image by printing the background color and then printing the pattern, thereby increasing the complexity of the printing process.
When soft label printing is carried out, the types of base materials are various, the colors and the transparencies of the base materials are different, and when image printing is carried out, a background color different from the base material color needs to be filled in a blank area of an image.
Therefore, a color re-transfer film for a transparent soft label substrate is provided to solve the defects in the prior art.
Disclosure of Invention
The present invention provides a color re-transfer film for a transparent soft label substrate, in which the addition of a pigment to a protective layer does not affect the adhesion between the re-transfer film and the soft label substrate.
The technical scheme for solving the technical problems is as follows: the color re-transfer printing film for the transparent soft label base material is sequentially laminated with a substrate, a protective layer and a pattern receiving layer from top to bottom; the protective layer is formed by coating the following raw materials in parts by weight: 50-90 parts of first resin and 10-50 parts of pigment; the pattern receiving layer is formed by coating the following raw materials in parts by weight: 99 parts of second resin and 1 part of matting powder.
Has the advantages that: the pigment is added into the protective layer, so that the adhesiveness between the re-transfer film and the soft label base material is not influenced, the pattern is printed on the color re-transfer film by using a thermal transfer printing mode, then the color re-transfer film is hot-stamped to the surface of the transparent base material by using a hot stamping mode, and the re-transfer film is self-provided with a background color when the soft label is printed on the transparent base material, so that extra background color printing is not required, the printing process is simplified, the cost is reduced, and the stable printing quality is improved.
Further, the first resin comprises one or a mixture of more than two of polyester resin, acrylic resin, aldehyde ketone resin, alkyd resin, polyvinyl alcohol and thermosetting resin.
Has the advantages that: the function of protecting and providing background color is achieved.
Further, the second resin includes one or a mixture of two or more of polyvinyl chloride, polyvinyl acetate, a vinyl chloride-vinyl acetate copolymer, and polyacrylate.
Has the advantages that: receiving the dye transferred from the dye layer of the dye-sublimation ribbon to form a pattern.
Further, the first resin also comprises an auxiliary agent.
Has the advantages that: the first resin and the pigment can be ensured to be fully mixed.
Further, the substrate is one of polypropylene, polyethylene naphthalate, polyethylene terephthalate, polyethylene, polyvinyl alcohol and polymethyl methacrylate.
Has the advantages that: the film is adopted as the substrate, so that the protective layer can be better ensured to be effectively coated on the surface of the substrate.
Further, the thickness of the substrate is 12-125 μm, the thickness of the protective layer is 0.5-5 μm, and the thickness of the pattern receiving layer is 1.5-15 μm.
Has the advantages that: the printing effect is good and the image is clear.
Further, the matting powder is gas-silicon particles with the particle size of 1-10 μm.
Has the advantages that: achieving a good matting effect requires the paint film to be given a matte finish and diffuse reflection.
The invention provides a preparation method of a color re-transfer printing film for a transparent soft label substrate, which comprises the following steps:
s1: providing a substrate, and applying corona on one side of the substrate;
s2: dissolving 50-90 parts of first resin in butanone and toluene solvent, then adding 10-50 parts of pigment and a small amount of auxiliary agent, and grinding to obtain protective layer paint;
s3: coating the protective layer pattern material obtained in the step S2 on the corona-striking surface of the substrate in the step S1, and drying after coating to obtain a protective layer;
s4: and (3) dissolving 99 parts of second resin in a butanone and toluene solvent, then adding 1 part of matting powder, and stirring and mixing to obtain the receiving layer coating.
S5: and (5) coating the receiving layer coating obtained in the step (S4) on one side of the protective layer far away from the substrate, and drying after coating to obtain the color re-transfer film.
Further, in step S3, the drying temperature is 60-120 ℃.
Further, in step S5, the drying temperature is 90-150 ℃.
Has the advantages that: the color re-transfer film can be prepared by the preparation method, the process of printing background color in soft label printing is reduced, the printing process is simplified, the cost is reduced, and the printing quality stability is improved.
Drawings
FIG. 1 is a schematic view of a layer structure of a color re-transfer film according to the present invention;
FIG. 2 is a schematic structural diagram of a carbon ribbon of an adhesion layer;
FIG. 3 is a schematic view of a ribbon;
in the drawings, the components represented by the respective reference numerals are listed below:
1. a substrate; 2. a protective layer; 3. a pattern receiving layer; 4. a PET substrate; 5. a release layer; 6. a bonding layer; 7. a soft label substrate.
Detailed Description
The principles and features of this invention are described below in conjunction with the following drawings, which are set forth by way of illustration only and are not intended to limit the scope of the invention.
Example 1:
the embodiment provides a color re-transfer film for a transparent soft label substrate, which comprises a substrate 1, a protective layer 2 and a pattern receiving layer 3, wherein the substrate, the protective layer 2 and the pattern receiving layer 3 are sequentially attached from top to bottom.
Wherein the substrate 1 is 100 μm polyethylene terephthalate;
the protective layer 2 is formed by coating the following raw materials in parts by weight:
80 parts of polyester resin and 20 parts of white color paste;
the pattern receiving layer 3 is formed by coating the following raw materials in parts by weight:
99 parts by mass of a vinyl chloride-vinyl acetate copolymer and 1 part by mass of a matting powder, and the thickness of the matting powder was 7 μm.
Preparing a color re-transfer printing film:
s1: providing a substrate 1, and applying corona on one side of the substrate 1;
s2: dissolving 80 parts of polyester resin in butanone and toluene solvent, then adding 20 parts of white color paste and a small amount of assistant light stabilizer and mildew-proof fluorine-containing agent,
the light stabilizer comprises one or more of salicylic acid esters, benzophenones, benzotriazoles, substituted acrylonitrile and triazine ultraviolet absorbers, and the mass of the light stabilizer accounts for 0.1-2wt% of the mass of the resin of the protective layer 2;
the fluorine-containing auxiliary agent comprises one or more of fluorosilane, a fluorine-containing surfactant and fluorine-containing acrylic resin, and the mass of the fluorine-containing auxiliary agent accounts for 0.1-2wt% of the mass of the resin in the protective layer 2; grinding to obtain a protective layer coating;
s3: coating the protective layer pattern material obtained in the step S2 on the corona-striking surface of the substrate 1 in the step S1, and drying after coating to obtain a protective layer 2;
s4: and (2) dissolving 99 parts by mass of vinyl chloride-vinyl acetate copolymer in a butanone and toluene solvent, adding 1 part of matting powder, and stirring and mixing to obtain the receiving layer coating.
S5: and (5) coating the receiving layer coating obtained in the step (S4) on one side of the protective layer (2) far away from the substrate (1), and drying after coating to obtain the color re-transfer film.
Example 2:
the embodiment provides a color re-transfer film for a transparent soft label substrate, which comprises a substrate 1, a protective layer 2 and a pattern receiving layer 3, wherein the substrate, the protective layer 2 and the pattern receiving layer 3 are sequentially attached from top to bottom.
Wherein the substrate 1 is 100 μm polyethylene terephthalate;
the protective layer 2 is formed by coating the following raw materials in parts by weight:
70 parts of polyester resin and 30 parts of white color paste;
the pattern receiving layer 3 is formed by coating the following raw materials in parts by weight:
99 parts by mass of a vinyl chloride-vinyl acetate copolymer and 1 part by mass of a matting powder, and the thickness of the matting powder was 7 μm.
Preparing a color re-transfer film:
s1: providing a substrate 1, and applying corona on one side of the substrate 1;
s2: 70 portions of polyester resin is dissolved in butanone and toluene solvent, then 30 portions of white color paste and a small amount of assistant light stabilizer and mildew-proof fluorine-containing agent are added,
the light stabilizer comprises one or more of salicylic acid esters, benzophenones, benzotriazoles, substituted acrylonitrile and triazine ultraviolet absorbers, and the mass of the light stabilizer accounts for 0.1-2wt% of the mass of the resin of the protective layer 2;
the fluorine-containing auxiliary agent comprises one or more of fluorosilane, a fluorine-containing surfactant and fluorine-containing acrylic resin, and the mass of the fluorine-containing auxiliary agent accounts for 0.1-2wt% of the mass of the resin in the protective layer 2; grinding to obtain a protective layer coating;
s3: coating the protective layer pattern material obtained in the step S2 on the corona-striking surface of the substrate 1 in the step S1, and drying after coating to obtain a protective layer 2;
s4: and (2) dissolving 99 parts by mass of vinyl chloride-vinyl acetate copolymer in a butanone and toluene solvent, adding 1 part of matting powder, and stirring and mixing to obtain the receiving layer coating.
S5: and (5) coating the receiving layer coating obtained in the step (S4) on one side of the protective layer (2) far away from the substrate (1), and drying after coating to obtain the color re-transfer film.
Example 3:
the embodiment provides a color re-transfer printing film for a transparent soft label substrate, which comprises a substrate 1, a protective layer 2 and a pattern receiving layer 3 which are sequentially attached from top to bottom.
Wherein, the substrate 1 is 100 μm polyethylene terephthalate;
the protective layer 2 is formed by coating the following raw materials in parts by weight:
60 parts of polyester resin and 40 parts of white color paste;
the pattern receiving layer 3 is formed by coating the following raw materials in parts by weight:
99 parts by mass of a vinyl chloride-vinyl acetate copolymer and 1 part by mass of a matting powder, and the thickness of the matting powder was 7 μm.
Preparing a color re-transfer film:
s1: providing a substrate 1, and applying corona on one side of the substrate 1;
s2: dissolving 60 parts of polyester resin in butanone and toluene solvent, then adding 40 parts of white color paste and a small amount of assistant light stabilizer and mildew-proof fluorine-containing agent,
the light stabilizer comprises one or more of salicylic acid esters, benzophenones, benzotriazoles, substituted acrylonitrile and triazine ultraviolet absorbers, and the mass of the light stabilizer accounts for 0.1-2wt% of the mass of the resin of the protective layer 2;
the fluorine-containing auxiliary agent comprises one or a combination of more of fluorosilane, fluorine-containing surfactant and fluorine-containing acrylic resin, and the mass of the fluorine-containing auxiliary agent accounts for 0.1-2wt% of the mass of the resin in the protective layer 2; grinding to obtain a protective layer coating;
s3: coating the protective layer pattern material obtained in the step S2 on the corona-striking surface of the substrate 1 in the step S1, and drying after coating to obtain a protective layer 2;
s4: and (2) dissolving 99 parts by mass of vinyl chloride-vinyl acetate copolymer in a butanone and toluene solvent, adding 1 part of matting powder, and stirring and mixing to obtain the receiving layer coating.
S5: and (5) coating the receiving layer coating obtained in the step (S4) on one side of the protective layer (2) far away from the substrate (1), and drying after coating to obtain the color re-transfer film.
Example 4:
the embodiment provides a color re-transfer film for a transparent soft label substrate, which comprises a substrate 1, a protective layer 2 and a pattern receiving layer 3, wherein the substrate, the protective layer 2 and the pattern receiving layer 3 are sequentially attached from top to bottom.
Wherein the substrate 1 is 100 μm polyethylene terephthalate;
the protective layer 2 is formed by coating the following raw materials in parts by weight:
50 parts of polyester resin and 50 parts of white color paste;
the pattern receiving layer 3 is formed by coating the following raw materials in parts by weight:
99 parts by mass of a vinyl chloride-vinyl acetate copolymer and 1 part by mass of a matting powder, and the thickness of the matting powder was 7 μm.
Preparing a color re-transfer printing film:
s1: providing a substrate 1, and applying corona on one side of the substrate 1;
s2: dissolving 50 parts of polyester resin in butanone and toluene solvent, then adding 50 parts of white color paste and a small amount of assistant light stabilizer and mildew-proof fluorine-containing agent,
the light stabilizer comprises one or more of salicylic acid esters, benzophenones, benzotriazoles, substituted acrylonitrile and triazine ultraviolet absorbers, and the mass of the light stabilizer accounts for 0.1-2wt% of the resin mass of the protective layer 2;
the fluorine-containing auxiliary agent comprises one or more of fluorosilane, a fluorine-containing surfactant and fluorine-containing acrylic resin, and the mass of the fluorine-containing auxiliary agent accounts for 0.1-2wt% of the mass of the resin in the protective layer 2; grinding to obtain a protective layer coating;
s3: coating the protective layer pattern material obtained in the step S2 on the corona-coated surface of the substrate 1 in the step S1, and drying after coating to obtain a protective layer 2;
s4: and (2) dissolving 99 parts by mass of vinyl chloride-vinyl acetate copolymer in a butanone and toluene solvent, adding 1 part of matting powder, and stirring and mixing to obtain the receiving layer coating.
S5: and (5) coating the receiving layer coating obtained in the step (S4) on one side, away from the substrate 1, of the protective layer 2, and drying after coating to obtain the color re-transfer printing film.
The color re-transfer film is transferred on the soft label substrate 7, a bonding carbon ribbon is needed, sometimes in order to further improve the adhesive force between the re-transfer film and the transparent soft label substrate 7, a bonding layer 6 needs to be transferred on the soft label substrate, and the invention also provides a corresponding formula and a preparation process of the bonding carbon ribbon.
The substrate adhered with the carbon tape is polyethylene terephthalate, the surface of the substrate is coated with a release layer 5 and an adhering layer coated on one side of the release layer far away from the substrate, and the thickness of the substrate is 12-125 μm, wherein the preferable thickness is 25-50 μm.
The release layer 5 is composed of vinyl resin and polyethylene glycol, the vinyl resin refers to one or more of polyvinyl chloride, polyvinyl acetate, vinyl chloride-vinyl acetate copolymer, polyvinylpyrrolidone and the like, and the number average molecular weight (Mn) of the polyethylene glycol is more than 3000 and less than 23000, preferably 10000-13000; the thickness of the release layer 5 is 0.5-1.5 μm.
The preparation method of the release layer 5 comprises the following steps: dissolving the polymer material into water or a corresponding organic solvent to prepare a coating, then coating the coating on the surface of a substrate by a gravure coating or slot coating mode, and drying.
The adhesive layer 6 is made of polyvinyl alcohol and polyester resin; the thickness of the adhesive layer 6 is 1-7 μm;
the preparation method of the adhesive layer 6 comprises the following steps: dissolving the polymer material into water or a corresponding solvent to prepare a coating, coating the coating on the surface of a substrate by a gravure coating or slot coating mode, and drying.
Finally, when the protective layer 2, the pattern receiving layer 1, the release layer 5 and the adhesion layer 6 coating of the present invention are prepared, a small amount of leveling agent, defoaming agent and the like may be added according to the requirements in addition to the above main materials.
Comparative example 1:
the present example uses UV inkjet to print the design and background color directly onto the transparent PET soft label substrate.
Comparative example 2:
this example adds pigment to the adhesion layer 6 and prints and thermally transfers the pattern as described in the previous example, and the specific receiving ribbon and adhesion ribbon formulations are as follows:
protective layer 2: polyester resin with a thickness of 2 μm;
receiving layer 3:99 parts by mass of a vinyl chloride-vinyl acetate copolymer and 1 part by mass of a matting powder, and the thickness of the matting powder was 7 μm.
The protective layer 3 and the receiving layer 3 were coated on a 25 μm PET substrate in the manner as in example 1;
then carbon ribbon formula:
the following formulation was used for release layer 5: 50 parts by mass of binary chlorine vinegar and 50 parts by mass of PEG (Mn: 10000), wherein the thickness of the coating is 1.2 +/-0.2 mu m;
the following formulation was used for the adhesion layer 6: 25 parts of polyester resin, 25 parts of polyvinyl alcohol and 50 parts of white color paste, wherein the particle size of the color paste is 0.5 mu m, and the thickness of the coating is 5 +/-0.2 mu m.
finally, the pattern is printed according to the following method: 1. printing a pattern mirror image on the receiving layer by using a thermal transfer ribbon (a resin ribbon, a wax-based ribbon, a semi-wax semi-resin ribbon or a thermal sublimation ribbon), and 2, transferring the subsequent layer ribbon to the surface of the soft label substrate by using thermal pasting at the temperature of 140 ℃.3. The receiving layer and the protective layer in 1 are transferred to the surface of the soft label substrate in 2 by using a hot mounting technology, and the hot mounting temperature is 140 ℃.
Comparative example 3:
an additional pigment layer is coated between the protective layer 2 and the dye receiving layer 3, and the printing and thermal transfer printing of the pattern are carried out according to the method of the embodiment, and the formulas of the carbon ribbon of the receiving layer and the following carbon ribbon are as follows:
protective layer 2: polyester resin with a thickness of 2 μm;
pigment layer: 50 parts by mass of polyester resin, 50 parts by mass of titanium dioxide (particle size of 0.5 mu m), and the thickness of the coating layer of 2 mu m
Receiving layer 6:99 parts by mass of a vinyl chloride-vinyl acetate copolymer and 1 part by mass of a matting powder, and the thickness of the coating was 7 μm.
The protective layer 2 and the receiving layer 6 were coated on a 25 μm PET substrate in the manner of example;
then, carbon ribbon formula:
the following formulation was used for release layer 5: 50 parts by mass of binary chlorine vinegar, 50 parts by mass of PEG (Mn: 10000), and coating thickness
1.2±0.2μm；
The following formulation was used for the adhesion layer: 50 parts by mass of a polyester resin and 50 parts by mass of polyvinyl alcohol, and the thickness of the coating is 5 +/-0.2 mu m.
finally, the pattern is printed according to the following method: 1. printing a pattern mirror image on the receiving layer by using a thermal transfer ribbon (a resin ribbon, a wax-based ribbon, a semi-wax semi-resin ribbon or a thermal sublimation ribbon), and 2, transferring the subsequent layer ribbon to the surface of the soft label substrate by using thermal pasting at the temperature of 140 ℃.3. The receiving layer and the protective layer in 1 are transferred to the surface of the soft label substrate in 2 by using a hot mounting technology, and the hot mounting temperature is 140 ℃.
Examples 1-4 were compared to comparative examples 1-3 for rub resistance, color layer bond fastness, solvent resistance, and background color hiding as shown in the following table:
wherein, the friction resistance test takes the weight loss before and after friction as the judgment standard;
color layer bonding fastness, using a disc peeling chamber test, and taking the residual weight after peeling as a judgment standard;
and (3) solvent resistance test: soaking in 75% ethanol solution for 1 min, wherein the color of the solution is A, the color of a small part of the solution is B, the color of a large part of the solution is C, and the color of the solution is D;
the background color hiding power is detected according to HG/T3851-2006, and the background color hiding power in the experimental example and the comparative example is divided into A, B, C and D from strong to weak.
As can be seen from the table, the color re-transfer film is applied to the thermal transfer technology, and has small friction resistance coefficient and low damage consumption; the color layer has high bonding fastness, no obvious fading and strong background color covering.
In the description of the specification, reference to the description of "one embodiment," "some embodiments," "an example," "a specific example," or "some examples" or the like means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Moreover, various embodiments or examples and features of various embodiments or examples described in this specification can be combined and combined by one skilled in the art without being mutually inconsistent.
The present invention is not limited to the above preferred embodiments, and any modifications, equivalent replacements, improvements, etc. within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (8)
1. The color re-transfer printing film for the transparent soft label base material is characterized by comprising a substrate (1), a protective layer (2) and a pattern receiving layer (3) which are sequentially attached from top to bottom;
the protective layer (2) is formed by coating the following raw materials in parts by weight: 50-90 parts of first resin and 10-50 parts of pigment;
the pattern receiving layer (3) is formed by coating the following raw materials in parts by weight: 99 parts of second resin and 1 part of matting powder;
the first resin comprises one or a mixture of more than two of polyester resin, acrylic resin, aldehyde ketone resin, alkyd resin and polyvinyl alcohol;
the second resin comprises one or a mixture of more than two of polyvinyl chloride, polyvinyl acetate, vinyl chloride-vinyl acetate copolymer and polyacrylate.
2. The color retransfer film for a transparent soft label substrate according to claim 1, wherein the first resin further comprises an auxiliary agent.
3. The color re-transfer film for the transparent soft label substrate according to claim 1, wherein the substrate (1) is one of polypropylene, polyethylene naphthalate, polyethylene terephthalate, polyethylene, polyvinyl alcohol, and polymethyl methacrylate.
4. The color re-transfer film for transparent soft label substrates according to claim 1, characterized in that the thickness of the base (1) is 12-125 μm, the thickness of the protective layer (2) is 0.5-5 μm, and the thickness of the pattern receiving layer (3) is 1.5-15 μm.
5. The color re-transfer film for the transparent soft label substrate according to claim 1, wherein the matting powder is gas-silicon particles with a particle size of 1 to 10 μm.
6. The method for manufacturing a color re-transfer film for a transparent soft label substrate according to any one of claims 1 to 5, comprising the steps of:
s1: providing a substrate (1), and applying corona on one side of the substrate (1);
s2: dissolving 50-90 parts of first resin in a butanone and toluene solvent, then adding 10-50 parts of pigment and a small amount of auxiliary agent, and grinding to obtain a protective layer coating;
s3: coating the protective layer paint obtained in the step S2 on the corona-striking surface of the substrate (1) in the step S1, and drying after coating to obtain a protective layer (2);
s4: dissolving 99 parts of second resin in a butanone and toluene solvent, then adding 1 part of matting powder, and stirring and mixing to obtain a receiving layer coating;
s5: and (5) coating the receiving layer coating obtained in the step (S4) on one side of the protective layer (2) far away from the substrate (1), and drying after coating to obtain the color re-transfer film.
7. The color re-transfer film for transparent soft label substrates according to claim 6, wherein the drying temperature in step S3 is 60-120 ℃.
8. The color re-transfer film for transparent soft label substrates according to claim 6, wherein the drying temperature in step S5 is 90-150 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111534499.0A CN114211894B (en) | 2021-12-15 | 2021-12-15 | Color re-transfer printing film for transparent soft label base material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111534499.0A CN114211894B (en) | 2021-12-15 | 2021-12-15 | Color re-transfer printing film for transparent soft label base material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114211894A CN114211894A (en) | 2022-03-22 |
| CN114211894B true CN114211894B (en) | 2023-04-07 |
Family
ID=80702579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111534499.0A Active CN114211894B (en) | 2021-12-15 | 2021-12-15 | Color re-transfer printing film for transparent soft label base material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114211894B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114653560B (en) * | 2022-04-02 | 2023-05-12 | 湖南鼎一致远科技发展有限公司 | Retransfer carbon belt suitable for textile printing and preparation method thereof |
| CN115521468A (en) * | 2022-09-13 | 2022-12-27 | 张家港威迪森化学有限公司 | Powdered ink resin and preparation method thereof |
| CN115556493A (en) * | 2022-11-11 | 2023-01-03 | 湖南鼎一致远科技发展有限公司 | Preparation method of thermal transfer ribbon suitable for glass substrate |
| CN115817048A (en) * | 2022-12-01 | 2023-03-21 | 湖南鼎一致远科技发展有限公司 | Thermal sublimation transfer film for glass printing stock |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4319964B2 (en) * | 2004-10-25 | 2009-08-26 | 大日本印刷株式会社 | Thermal transfer sheet |
| CN101462428B (en) * | 2007-12-19 | 2011-11-16 | 仁宝电脑工业股份有限公司 | Heat-transferring membrane as well as method for producing the same and transfer printing method |
| JP2017140703A (en) * | 2016-02-08 | 2017-08-17 | 凸版印刷株式会社 | Thermal transfer sheet and printed matter |
| US10556457B2 (en) * | 2016-03-31 | 2020-02-11 | Dai Nippon Printing Co., Ltd. | Thermal transfer sheet |
| JP6402840B2 (en) * | 2016-03-31 | 2018-10-10 | 大日本印刷株式会社 | Thermal transfer sheet |
| CN106808820B (en) * | 2017-01-05 | 2018-11-20 | 广东宏达印业股份有限公司 | It is a kind of digital to print standby transfer film, preparation method and applications |
| CN113442610A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Carbon ribbon and preparation method thereof |
| CN111703226A (en) * | 2020-07-03 | 2020-09-25 | 福建鸣友新材料科技有限公司 | Resin-based thermal transfer ribbon with strong universality and preparation method thereof |
| CN113178128A (en) * | 2021-04-29 | 2021-07-27 | 湖南鼎一致远科技发展有限公司 | High-temperature-resistant label for thermal transfer printing and preparation method thereof |
| CN113354857A (en) * | 2021-06-22 | 2021-09-07 | 湖南鼎一致远科技发展有限公司 | Thermal transfer printing resin carbon ribbon with excellent weather resistance and preparation method thereof |
| CN113478989B (en) * | 2021-07-07 | 2023-03-10 | 湖南鼎一致远科技发展有限公司 | Thermal transfer printing color ribbon applied to electroluminescent back electrode and preparation method thereof |
-
2021
- 2021-12-15 CN CN202111534499.0A patent/CN114211894B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN114211894A (en) | 2022-03-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN114211894B (en) | Color re-transfer printing film for transparent soft label base material | |
| AU6541999A (en) | Transfer media | |
| JPH1095164A (en) | Recording medium, ink jet recording method using the recording medium, and image forming method | |
| CN114261222B (en) | Carbon ribbon for increasing applicable base material of thermal sublimation ribbon and preparation method thereof | |
| CN114055977B (en) | Process method for printing soft label on thermal sublimation color band | |
| JP2002370443A (en) | Re-transferable ink jet image receiving sheet and image forming method | |
| KR101340976B1 (en) | Waterslide Decal Paper for Dye Sublimation Thermal Transfer Printing | |
| JPWO2004087432A1 (en) | Inkjet recording material, printed material laminate using the same, and method for producing printed material adhesive | |
| CN114261228B (en) | Thermal transfer printing soft label printing method, pattern receiving thermal transfer ribbon and auxiliary thermal transfer ribbon | |
| JP2009154503A (en) | Water transfer sheet and water transfer release sheet | |
| JPH06316173A (en) | Thermal transfer recording method | |
| JPH11321073A (en) | Manufacture of recording material for ink jet printer | |
| WO2024189721A1 (en) | Method for manufacturing transfer foil by hybrid printing and transfer foil | |
| US20230256765A1 (en) | Outdoor-Durable Inkjet-Receptive Topcoat Formula and Article | |
| JP3452189B2 (en) | Ink-jet recording material for oil-based ink | |
| JP3801599B2 (en) | Molded product manufacturing method and transfer sheet used therefor | |
| JP2022121060A (en) | Thermal transfer sheet | |
| JP3546993B2 (en) | Ink-jet recording material for oil-based ink | |
| JP2000158804A (en) | Recording medium, ink-jet recording method and image- forming method using the same | |
| JP2001071626A (en) | Fixation improving method for water-based pigment ink, material to be recorded for water-based pigment ink, recording body, and its manufacture | |
| KR200327620Y1 (en) | Printing Media for a Inkjet Printer | |
| JP3451758B2 (en) | Tape for inkjet label writer | |
| JPH0776175A (en) | Thermal transfer recording material | |
| JP2002200843A (en) | Recording material for ink jet printer and manufacturing method therefor | |
| JPH1035093A (en) | Ink jet recording sheet and production thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |