CN114176075B - Preparation method, disinfection method, preparation system and disinfection system of aerosol for disinfection - Google Patents

Preparation method, disinfection method, preparation system and disinfection system of aerosol for disinfection Download PDF

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CN114176075B
CN114176075B CN202111381153.1A CN202111381153A CN114176075B CN 114176075 B CN114176075 B CN 114176075B CN 202111381153 A CN202111381153 A CN 202111381153A CN 114176075 B CN114176075 B CN 114176075B
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sodium chloride
aerosol
disinfection
chlorine dioxide
gas
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CN114176075A (en
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兰彦顺
曹明庭
姜克容
田金超
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Qingdao Guangzhi Zhixiang Technology Co ltd
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Qingdao Guangzhi Zhixiang Technology Co ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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    • AHUMAN NECESSITIES
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    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/14Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/58Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0095Preparation of aerosols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2101/00Chemical composition of materials used in disinfecting, sterilising or deodorising
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61L2202/00Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/20Targets to be treated
    • A61L2202/25Rooms in buildings, passenger compartments
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
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Abstract

The application relates to a preparation method, a disinfection method, a preparation system and a disinfection system of aerosol for disinfection, wherein the preparation method of aerosol for disinfection comprises the following steps: preparing chlorine dioxide gas: chlorine dioxide disinfectant is adopted to release chlorine dioxide gas in an aeration mode; preparing sodium chloride particles: adopting pure sodium chloride aqueous solution and atomizing to generate sodium chloride vapor; gas-liquid separation is carried out on atomized sodium chloride water vapor to release sodium chloride gas particles with the size of 1-5 mu m, and the sodium chloride gas particles are dried to release submicron sodium chloride particles; mixing to prepare aerosol: sodium chloride particles are used as condensation nuclei to be mixed with carbon dioxide chlorine gas molecules to form aerosol. The sterilizing device has the advantages of high sterilizing efficiency and good humanization effect.

Description

Preparation method, disinfection method, preparation system and disinfection system of aerosol for disinfection
Technical Field
The application relates to the field of air sterilization, in particular to a preparation method, a sterilization method, a preparation system and a sterilization system of aerosol for sterilization.
Background
In the prior world, in the main infectious diseases, pathogenic microorganisms which are transmitted by air and account for the first place of various transmitted diseases are mainly adsorbed on dust particles with different particle diameters in the air, and the dust particles are suspended in the air in an aerosol mode and enter a human body through respiratory tracts to cause the transmission of the diseases, and the transmission of respiratory anthrax, tuberculosis, influenza virus, hepatitis, avian influenza virus, novel coronavirus and the like can be carried out through the air, and once the transmission is exploded, serious consequences are caused. Epidemic cerebrospinal meningitis, mumps, viral pneumonia, influenza, acute pharyngitis, tuberculosis, scarlet fever, legionella disease, pertussis, diphtheria, smallpox are all also air-borne and air-borne. Therefore, the air disinfection is an important measure for preventing and controlling infectious diseases and preventing cross infection, is particularly important for the air preventive disinfection in places with relatively concentrated personnel, such as hospitals, libraries, supermarkets, schools, stations, canteens and other public environments with large spaces, can effectively disinfect air, can kill and activate pathogenic microorganisms adhered and dyed on suspended particles in the air within a certain time, can play a key blocking role in the processes of preventing diseases, controlling the propagation of virus air droplets and aerosol, and is similar to an intangible mask.
The traditional method for disinfecting the surface of the object mainly comprises the steps of spraying, fumigating and soaking the disinfectant. The method for sterilizing the air in the space comprises the steps of closed fumigation, ultraviolet sterilization, ozone sterilization, physical filtration and sterilization of the air and the like.
The spray disinfection method has the advantages that the accuracy of concentration proportion of disinfectant, the sprayed areas, parts, alcohol spraying amount and the final disinfection and sterilization effect are directly affected by human factors. Meanwhile, the personnel who spray the disinfectant need to be in the body to pollute the environment, and also bear high risk;
the fumigation mode generally needs higher disinfectant concentration, the space is closed for a long time, and the use of places is influenced for a long time;
ultraviolet disinfection, high-power ultraviolet rays have harm to organism functions. The ultraviolet ray is influenced by the emission power, so that the ultraviolet ray is limited to adapt to and meet the disinfection of a large amount of space, meanwhile, the size of the humidity of the space directly influences the disinfection effect, and in addition, the ultraviolet ray has the defect of blindness control on eyes and is not suitable for being started under the condition of people;
ozone disinfection, bad humanization of ozone smell is suitable, and ozone is unstable in the air simultaneously, and the retention time is shorter, is unsuitable for large space disinfection, directly influences the effect of disinfecting to the virus continuously.
In conclusion, the existing disinfection has the defects of low disinfection efficiency and poor humanization.
Disclosure of Invention
In order to solve the technical problems, the application provides a preparation method, a disinfection method, a preparation system and a disinfection system of aerosol for disinfection, which have the advantages of high disinfection efficiency and good humanity.
In a first aspect, the present application provides a method for preparing an aerosol for disinfection, which adopts the following technical scheme:
a method for preparing an aerosol for disinfection, comprising the steps of:
preparing chlorine dioxide gas:
chlorine dioxide disinfectant is adopted to release chlorine dioxide gas in an aeration mode;
preparing sodium chloride particles:
adopting pure sodium chloride aqueous solution and atomizing to generate sodium chloride vapor;
gas-liquid separation is carried out on atomized sodium chloride water vapor, and sodium chloride gaseous particles with the size of 1-5 mu m are released;
drying the sodium chloride gas particles to release submicron sodium chloride particles;
mixing to prepare aerosol:
sodium chloride particles are used as condensation nuclei to be mixed with carbon dioxide chlorine gas molecules to form aerosol.
Through adopting above-mentioned technical scheme, the aerosol that chlorine dioxide and sodium chloride combination that adopts forms can directly put into in waiting various disinfection spaces, public health field and building and the mobile vehicle space environment in public places such as hospital medical field, harmful substance in the effective degradation air such as formaldehyde, sulfide, phenol etc. with the disinfection ability is strong, and harmless to the people, can also form deodorant, decompose hydrogen sulfide, ammonia, sulfur dioxide etc. effectively improves the comfort level of environment, and the suitability is good.
In a second aspect, the present application provides a method for sterilizing an aerosol for sterilization, which adopts the following technical scheme:
a method of sterilizing an aerosol for sterilization, comprising the steps of:
putting the aerosol formed by mixing into an air conveying device communicated with the sterilizing space;
air containing aerosol for disinfection is continuously put into the disinfection space by the air conveying device.
Through adopting above-mentioned technical scheme, with submicron sodium chloride particle and the aerosol that chlorine dioxide gas molecule mixed formation, continuously carry in air conveyor, the new trend of carrying along with air conveyor is inside through air conveyor then in sending the disinfection space, when having realized the disinfection to air conveyor inside, more carried the disinfection aerosol to the disinfection space of distal end, can make the continuous Brownian motion in the distal end disinfection space, the all-round no dead angle disinfection of air and object to the space.
Optionally, the method for sterilizing the aerosol for sterilization further comprises:
presetting a disinfectant concentration value and duration in a disinfection space;
monitoring the concentration of aerosol in the disinfection space in real time, and adjusting according to the concentration value of the disinfectant in the prefabricated disinfection space;
and stopping conveying the aerosol after the concentration of the aerosol in the disinfection space reaches a preset value and the preset duration is continued.
By adopting the technical scheme, after the disinfectant concentration in the disinfection space is preset, the disinfectant concentration in the disinfection space is detected, and compared, so that the concentration of the disinfectant can be timely regulated, the requirement of the disinfection space is met, and the disinfectant concentration index of the remote disinfection space meets the national standard.
Optionally, the air delivery device comprises an air conditioning system or a fresh air system.
In a third aspect, the present application provides a disinfection aerosol preparation system, which adopts the following technical scheme:
a disinfection aerosol production system, comprising:
the releasing device is internally provided with a first containing cavity which can contain chlorine dioxide disinfectant;
the aeration device is positioned at the bottom of the release device;
the high-frequency ultrasonic atomizer is internally provided with a second containing cavity which can contain sodium chloride melt;
the gas-liquid separator is connected to the mist outlet end of the high-frequency ultrasonic atomizer;
the dryer is connected to the discharge end of the gas-liquid separator;
the two branch pipes are respectively connected with the upper side of the release device and the discharge hole of the dryer;
and the collecting pipe is connected with one end of the two branch pipes far away from the releasing device or the dryer.
By adopting the technical scheme, when in use, the chlorine dioxide disinfectant with constant concentration and activity is put into the release device, the chlorine dioxide disinfectant in the release device is aerated by the aeration device to generate chlorine dioxide gas, and the chlorine dioxide gas enters a branch pipe; meanwhile, the pure sodium chloride aqueous solution is put into a second cavity of the high-frequency ultrasonic atomizer, the pure sodium chloride aqueous solution is atomized by the high-frequency ultrasonic atomizer to generate sodium chloride vapor, the sodium chloride vapor is subjected to gas-liquid separation by a gas-liquid separator to release sodium chloride gaseous particles, then the sodium chloride gaseous particles are dried by a dryer to generate sodium chloride particles, the sodium chloride particles enter another branch pipe, and finally chlorine dioxide gaseous molecules in the two branch pipes and the sodium chloride particles are gathered in a collecting pipe to form aerosol which takes the sodium chloride particles as condensation cores and the chlorine dioxide gas molecules.
Optionally, one side of the release device is provided with a variable fan, the variable fan is connected with the release device through an air supply pipeline, and the upper side of the aeration device is provided with a plurality of exhaust micropores.
Through adopting above-mentioned technical scheme, during operation, open variable fan, can send the aeration equipment with pressure wind through the air supply pipeline in, then, pressure air is arranged in the chlorine dioxide disinfection liquid by aeration equipment's exhaust micropore, forms the bubble that enlarges gradually and rise, and then overflows the disinfection liquid level, carries chlorine dioxide and escapes with gaseous direction from the disinfection liquid, generates chlorine dioxide gas.
Optionally, the aerosol preparation system for sterilization further comprises:
the chlorine dioxide mother liquor tank can contain chlorine dioxide mother liquor;
the activation liquid tank can contain activation liquid;
the activation tank, the activation tank feed inlet with chlorine dioxide mother liquor jar with the activation fluid pot is connected respectively, can mix chlorine dioxide mother liquor and activation liquid, the liquid outlet of activation tank connect in release.
Through adopting above-mentioned technical scheme, during operation, can place chlorine dioxide mother liquor in the chlorine dioxide mother liquor jar, place the activation liquid in the activation liquid jar, then according to the demand with the activation liquid in chlorine dioxide mother liquor and the activation liquid jar in the activation liquid jar send to the activation jar to carry out the activation treatment, form the chlorine dioxide antiseptic solution that has invariable concentration and activity.
In a fourth aspect, the present application provides a disinfection system for disinfecting an aerosol, which adopts the following technical scheme:
a disinfection system for disinfecting an aerosol, comprising:
an aerosol preparation system for sterilization; the method comprises the steps of,
and the air inlet end of the air conveying device is connected with the collecting pipe, and the air outlet end of the air conveying device is connected with the disinfection space.
Through adopting above-mentioned technical scheme, sodium chloride particle and chlorine dioxide gas molecule mix and form aerosol, will get into air conveyor's air inlet end through the header pipe to air is the dispersant system, along with air conveyor's continuous operation, carries new trend and aerosol together and disinfects air conveyor inside through air conveyor is inside, then carries the disinfection space of distal end, releases in the disinfection space, and the all-round no dead angle disinfection of air and object in disinfection space.
Optionally, the disinfection system further comprises:
the air quantity detector is arranged at the air inlet end of the air conveying device and is used for detecting the air quantity entering the disinfection space;
the chlorine dioxide concentration detector is arranged in the disinfection space and used for detecting the concentration of the disinfectant in the disinfection space.
Through adopting above-mentioned technical scheme, through the amount of wind detector that sets up, can detect the amount of wind in getting into disinfection space, the chlorine dioxide concentration detector of setting can detect the chlorine dioxide concentration in the disinfection space, is convenient for in time adjust, guarantees disinfection gas concentration dynamic accordance standard in the disinfection space.
In summary, the present application at least includes the following beneficial technical effects:
the aerosol formed by mixing submicron sodium chloride particles and chlorine dioxide gas molecules is continuously conveyed into the air conveying device, and then conveyed into the sterilizing space along with fresh air conveyed by the air conveying device, so that the sterilizing aerosol is conveyed to the remote sterilizing space while the inside of the air conveying device is sterilized, and the remote sterilizing space can continuously perform Brownian motion, so that the air and objects in the space are sterilized in an omnibearing manner without dead angles, and the sterilizing device has the advantages of high sterilizing efficiency and suitability for humanization.
Drawings
FIG. 1 is a schematic flow chart of a method of preparing a disinfection aerosol in an embodiment of the present application;
FIG. 2 is a flow diagram of a method of sterilizing an aerosol for sterilization in an embodiment of the present application;
FIG. 3 is a schematic structural view of a preparation system of a sterilizing aerosol in an embodiment of the present application;
FIG. 4 is a schematic structural view of a disinfection system of a disinfection aerosol in an embodiment of the present application;
fig. 5 is a schematic structural diagram of a chlorine dioxide disinfectant proportioning device in a disinfection system of a disinfection aerosol according to an embodiment of the present application;
FIG. 6 is a schematic structural view of a chlorine dioxide gas generating device in a disinfection system of a disinfection aerosol in an embodiment of the present application;
fig. 7 is a schematic view of a sterilization space in a sterilization system of a sterilization aerosol in an embodiment of the present application.
Reference numerals illustrate: 1. chlorine dioxide gas generating device; 11. a release device; 111. a filling port I; 112. a first regulating valve; 113. a liquid discharge pipe I; 114. a first switch valve; 12. an aeration device; 13. a variable fan; 14. an air supply pipeline; 2. sodium chloride particle generating device; 21. a high frequency ultrasonic atomizer; 211. a second filling port; 212. a second regulating valve; 213. a liquid discharge pipe II; 214. a second switching valve; 22. a gas-liquid separator; 23. a dryer; 3. a mixing device; 31. a branch pipe; 32. a header pipe; 33. a suction device; 4. a chlorine dioxide disinfectant proportioning device; 41. a mother liquor tank; 411. a first pipeline; 412. a constant displacement pump I; 42. an activation liquid tank; 421. a second pipeline; 422. a fixed displacement pump II; 43. an activation tank; 431. a water supply source; 432. a water supply pipe; 433. a water valve; 434. a liquid concentration detector; 5. a communication pipe; 51. a regulating valve; 6. an air delivery device; 61. an air quantity detector; 7. sterilizing the space; 71. chlorine dioxide concentration detector.
Detailed Description
The present application is described in further detail below in conjunction with figures 1-7.
The embodiment of the application discloses a preparation method of aerosol for disinfection.
Referring to fig. 1, a method for preparing an aerosol for sterilization includes the steps of:
s1, preparing chlorine dioxide gas:
selecting chlorine dioxide disinfectant with constant concentration and activity;
the aeration treatment is carried out on the chlorine dioxide by controlling the aeration quantity according to the requirement, and pure chlorine dioxide nanometer micromolecular gas is released;
s2, sodium chloride particle preparation:
1. pure sodium chloride aqueous solution is selected and atomized by adopting atomizing equipment such as a high-frequency ultrasonic atomizer and the like to release sodium chloride vapor;
2. carrying out gas-liquid separation on atomized sodium chloride water vapor to release sodium chloride gaseous molecules with the size of 1-5 mu m;
3. drying 1-5 μm sodium chloride gas molecules at high temperature by a drying device to release submicron sodium chloride particles;
s3, aerosol mixing:
sodium chloride particles are used as condensation nuclei to be mixed with chlorine dioxide gas molecules to form aerosol.
The implementation principle of the preparation method of the aerosol for disinfection in the embodiment of the application is as follows: the aerosol formed by combining the chlorine dioxide molecules and the sodium chloride particles can be directly put into various sterilizing spaces to be sterilized, such as public health fields of public places such as hospital medical fields, space environments of buildings and mobile vehicles, and the like, can effectively degrade harmful substances in the air such as formaldehyde, sulfide, phenol and the like, has strong sterilizing capability, is harmless to people, can also form deodorant, decomposes hydrogen sulfide, ammonia, sulfur dioxide and the like, effectively improves the comfort of the environment, and has strong pleasure.
The embodiment of the application discloses a disinfection method of aerosol for disinfection,
referring to fig. 2, a sterilization method of a sterilization aerosol includes the steps of:
s1, preparing a chlorine dioxide disinfectant:
quantitatively conveying the quantitatively configured chlorine dioxide disinfection mother solution and the quantitatively configured activating solution into a disinfection solution proportioning tank respectively, and activating to generate the chlorine dioxide disinfection solution with accurate concentration and activity;
s2, preparing chlorine dioxide gas:
performing aeration treatment on the prepared chlorine dioxide disinfectant with constant concentration and activity in a release device in an aeration mode of controlling aeration quantity to release pure chlorine dioxide gas;
s3, sodium chloride particle preparation:
1. pure sodium chloride aqueous solution is selected and atomized by adopting atomizing equipment such as a high-frequency ultrasonic atomizer and the like to release sodium chloride vapor;
2. carrying out gas-liquid separation on atomized sodium chloride water vapor to release sodium chloride gaseous molecules with the size of 1-5 mu m;
3. drying 1-5 μm sodium chloride gas molecules at high temperature by a drying device to release submicron sodium chloride particles;
s4, aerosol preparation: sodium chloride particles are used as condensation cores to be mixed with chlorine dioxide steam gas molecules to form aerosol;
s5, sterilizing space:
1. continuously conveying the aerosol into an air supply system communicated with the disinfection space, such as a negative pressure area of an air inlet pipeline of a central air conditioner, an air inlet pipeline of a fresh air system and the like, and continuously and uniformly mixing the aerosol and fresh air of the air supply system, which is sent to the disinfection space, on line by means of devices such as diversion, turbulence and the like;
2. an air inlet channel of an air supply system is used as an aerosol transmission channel, clean air containing aerosol with a certain concentration is conveyed to a disinfection space while the pipeline and the air inlet are disinfected in the whole process, so that the aerosol moves in the disinfection space for a long time in a Brownian manner until the whole space is gradually filled;
3. presetting a disinfectant concentration value and duration in a disinfection space;
4. monitoring the concentration of aerosol in the disinfection space in real time, and adjusting according to the concentration value of the disinfectant in the prefabricated disinfection space;
5. and stopping conveying the aerosol after the concentration of the aerosol in the disinfection space reaches a preset value and the preset duration is continued.
The implementation principle of the disinfection method of the aerosol for disinfection in the embodiment of the application is as follows:
the method comprises the steps of (1) releasing pure chlorine dioxide gas from carbon dioxide chlorine with preset concentration in an aeration mode; meanwhile, the sodium chloride purified water is atomized through the high-frequency ultrasonic atomizer, the sodium chloride gaseous particles with the size of 1-5 mu m are released through the gas-liquid separation device 22, then the sodium chloride particles with the size of 1-5 mu m are dried at high temperature through the drying device, submicron sodium chloride particles and chlorine dioxide gas molecules are released to be mixed to form aerosol, the aerosol is continuously conveyed to the inlet of the air inlet pipe of the air conveying device such as the central air conditioning system or the fresh air system, and the air inlet pipe enters the air supply pipeline of the air conveying device such as the central air conditioning system or the fresh air system along with the fresh air, and the fresh air and the air supply pipeline are disinfected and simultaneously conveyed to a far-end place, and then the air is released into the space, so that the air and objects in the space are disinfected in an omnibearing manner, the disinfection efficiency is high, the environment comfort is effectively improved, and the comfort is strong.
The embodiment of the application also discloses a preparation system of the aerosol for disinfection.
Referring to fig. 3, a system for preparing an aerosol for sterilization includes a chlorine dioxide gas generating device 1, a sodium chloride fine particle generating device 2, and a mixing device 3.
Referring to fig. 3, the chlorine dioxide gas generating apparatus 1 includes a releasing device 11, the releasing device 11 is in a closed box structure, a filling port one 111 for filling chlorine dioxide disinfectant is fixed on one side of the releasing device 11, a regulating valve one 112 is provided on the filling port one 111, and the regulating valve one 112 is used for regulating the filling amount of the filling port one 111 or closing the filling port one 111. The bottom surface of the release device 11 is fixed with a first drain pipe 113 for discharging waste liquid, and the first drain pipe 113 is provided with a first switch valve 114 for closing or opening the first drain pipe 113. In use, a configured constant concentration and activity chlorine dioxide sanitizing liquid can be infused into the delivery device 11 through the infusion port 111.
Referring to fig. 3, an aeration device 12 is fixed on the inner bottom surface of a release device 11, a plurality of exhaust micropores are densely distributed on the upper side of the aeration device 12, a variable fan 13 is fixed on the outer side of the release device 11, an air outlet of the variable fan 13 is connected with an air supply pipeline 14, and one end, far away from the variable fan 13, of the air supply pipeline 14 extends into the release device 11 and is communicated with the aeration device 12.
Referring to fig. 3, when in operation, the variable fan 13 is started, the air supply pipeline 14 sends the pressure air into the aeration device 12, then the pressure air is discharged from a plurality of exhaust micropores on the upper side of the aeration device 12, and enters the chlorine dioxide disinfectant to form gradually enlarged and raised bubbles, so that the bubbles overflow the liquid level of the chlorine dioxide disinfectant, and chlorine dioxide is carried to escape from the disinfectant in a gas mode to form chlorine dioxide gas.
Referring to fig. 3, the sodium chloride particulate generating device 2 includes a high-frequency ultrasonic atomizer 21, a gas-liquid separator 22, and a dryer 23. The downside of high frequency ultrasonic atomizer 21 is provided with the stock solution chamber, and one side of stock solution chamber is provided with filler second 211 for filling pure sodium chloride aqueous solution, is provided with governing valve second 212 on the filler second 211, is used for adjusting filler second 211's filling volume or closes filler second 211. A second liquid discharge pipe 213 for discharging waste liquid is fixed at the lower side of the liquid storage cavity, and a second switching valve 214 for switching on or off the second liquid discharge pipe 213 is fixed on the second liquid discharge pipe 213.
Referring to fig. 3, in use, after the pure sodium chloride aqueous solution is filled into the liquid storage cavity of the high-frequency ultrasonic atomizer 21 through the second filling port 211, the high-frequency ultrasonic atomizer 21 is started, and the high-frequency ultrasonic atomizer 21 atomizes the pure sodium chloride aqueous solution to form sodium chloride vapor.
Referring to fig. 3, the gas-liquid separator 22 is disposed above the high-frequency ultrasonic atomizer 21 and located at the position of the mist outlet of the high-frequency ultrasonic atomizer 21, and the sodium chloride vapor atomized by the high-frequency ultrasonic atomizer 21 enters the gas-liquid separator 22 to be separated into gas and liquid, and the gas-liquid separator 22 releases 1-5 μm gaseous particles.
Referring to fig. 3, a dryer 23 is provided at the upper side of the gas-liquid separator 22, and gaseous 1-5 μm small particles are introduced into the dryer 23 to be dried at a high temperature, thereby releasing submicron-sized sodium chloride particles.
Referring to fig. 3, the mixing apparatus 3 includes two branch pipes 31 and a header pipe 32 connected to one end of the two branch pipes 31.
Referring to fig. 3, one branch pipe 31 is connected to the release device 11 for discharging chlorine dioxide molecules after aeration treatment, and the other branch pipe 31 is connected to the discharge port of the dryer 23 for discharging sodium chloride particles after drying. The collection pipe 32 is connected to a suction device 33.
Referring to fig. 3, in operation, the suction device 33 is started to suck chlorine dioxide gas and sodium chloride particles through the two branch pipes 31, so that the chlorine dioxide gas and the sodium chloride particles are simultaneously sucked into the collecting pipe 32, and the chlorine dioxide gas and the sodium chloride particles are mutually adsorbed to form an aerosol by mixing the sodium chloride particles as condensation nuclei with chlorine dioxide gas molecules.
The implementation principle of the preparation system of the aerosol for disinfection in the embodiment of the application is as follows: the sterilizing liquid with preset concentration is discharged with pure chlorine dioxide gas in an aeration mode through a discharge device 11; simultaneously, sodium chloride purified water is gasified through a high-frequency atomizer, sodium chloride particles with the particle diameter of minus mu m are released through a gas-liquid separation device 22, then gaseous sodium chloride particles with the particle diameter of minus mu m are dried at high temperature through a dryer 23, submicron sodium chloride particles are released, and then the sodium chloride particles and chlorine dioxide gas molecules are respectively sent into a collecting pipe 32 through two branch pipes 31 to be mixed, so that aerosol formed by mixing the sodium chloride particles as condensation nuclei and the chlorine dioxide steam gas molecules can be formed. Can be directly put into various sterilizing spaces 7 to be sterilized, can effectively degrade harmful substances in the air such as formaldehyde, sulfide, phenol and the like, has strong sterilizing capability, is harmless to people, and has strong pleasure.
The embodiment of the application also discloses a disinfection system of the aerosol for disinfection.
Referring to fig. 4, a sterilizing system for a sterilizing aerosol includes a chlorine dioxide sterilizing solution proportioning device 4, a chlorine dioxide gas generating device 1, a sodium chloride particle generating device 2, a mixing device 3, and an air conveying device 6.
Referring to fig. 5, the chlorine dioxide sterilizing solution proportioning device 4 includes a mother liquor tank 41, an activation liquor tank 42, and an activation tank 43.
Referring to fig. 5, the mother liquor tank 41 can store chlorine dioxide disinfection mother liquor, the activated liquid tank 42 can store activated liquid, a first pipeline 411 is fixed between the activated tank 43 and the mother liquor tank 41, the first pipeline 411 is communicated with the mother liquor tank 41 and the activated tank 43, and a first metering pump 412 is fixedly connected to the first pipeline 411 and used for controlling the mother liquor conveying amount of the first pipeline 411; a second pipeline 421 is fixed between the activation tank 43 and the activation tank 42, the second pipeline 421 is communicated with the activation tank 42 and the activation tank 43, and a second dosing pump 422 is connected to the second pipeline 421 and used for controlling the conveying amount of the activation liquid in the second pipeline 421. A water supply source 431 is further provided at one side of the activation tank 43, a water supply pipe 432 is connected between the water supply source 431 and the activation tank 43, and a water valve 433 is provided on the water supply pipe 432. To facilitate detection of the concentration of chlorine dioxide sanitizing solution within the activation tank 43, the activation tank 43 is further coupled to a liquid concentration detector 434.
Referring to fig. 5, in use, according to the ratio adjustment, the first and second metering pumps 412 and 422 and the water valve 433 are respectively turned on, the sterilizing liquid mother liquor is quantitatively conveyed from the mother liquor tank 41 to the activation tank 43 through the first pipe 411, the activating liquid is quantitatively conveyed from the activation tank 43 to the activation tank 43 through the second pipe 421, and the water source is conveyed to the activation tank 43 through the water supply pipe 432, so that the sterilizing liquid mother liquor, the activating liquid and the water are mixed in the activation tank 43 to form the chlorine dioxide sterilizing liquid with accurate concentration and activity.
Referring to fig. 6, the chlorine dioxide gas generating apparatus 1 includes a releasing apparatus 11, an aerating apparatus 12, and a variable volume fan 13.
Referring to fig. 6, the releasing device 11 is in a closed box structure, a communication pipeline 5 is fixed between the releasing device 11 and the activation tank 43, and a regulating valve 51 is connected to the communication pipeline 5 for delivering chlorine dioxide disinfectant with accurate concentration and activity into the releasing device 11. The bottom surface of the release device 11 is fixed with a first drain pipe 113 for discharging waste liquid, and the first drain pipe 113 is provided with a first switch valve 114 for closing or opening the first drain pipe 113.
Referring to fig. 6, the aeration device 12 is disposed on the inner bottom surface of the release device 11, and a plurality of exhaust micropores are uniformly and densely distributed on the upper side of the aeration device 12, the variable fan 13 is disposed on one side of the release device 11, and an air supply pipe 14 is fixed between the air outlet of the variable fan 13 and the aeration device 12, and the air supply pipe 14 can supply pressure air into the aeration device 12.
Referring to fig. 6, in operation, the variable fan 13 is turned on, pressurized air is fed into the aeration device 12 through the air supply pipeline 14, then the pressurized air is discharged from a plurality of exhaust micropores on the upper side of the aeration device 12, and enters the chlorine dioxide disinfectant to form gradually enlarged and raised bubbles, and enters the liquid level of the overflowed chlorine dioxide disinfectant to carry chlorine dioxide to escape from the disinfectant in a gas mode, so that chlorine dioxide gas is formed.
Referring to fig. 6, the sodium chloride particulate generating device 2 includes a high-frequency ultrasonic atomizer 21, a gas-liquid separator 22, and a dryer 23. The downside of high frequency ultrasonic atomizer 21 is provided with the stock solution chamber, and one side of stock solution chamber is provided with filler second 211 for filling pure sodium chloride aqueous solution, is provided with governing valve second 212 on the filler second 211, is used for adjusting filler second 211's filling volume or closes filler second 211. A second liquid discharge pipe 213 for discharging waste liquid is fixed at the lower side of the liquid storage cavity, and a second valve is fixed on the second liquid discharge pipe 213 for opening or closing the second liquid discharge pipe 213.
Referring to fig. 6, in use, after the pure sodium chloride aqueous solution is filled into the liquid storage cavity of the high-frequency ultrasonic atomizer 21 through the second filling port 211, the high-frequency ultrasonic atomizer 21 is started, and the high-frequency ultrasonic atomizer 21 atomizes the pure sodium chloride aqueous solution to form sodium chloride vapor.
Referring to fig. 6, the gas-liquid separator 22 is disposed above the high-frequency ultrasonic atomizer 21 and located at the position of the mist outlet of the high-frequency ultrasonic atomizer 21, and the sodium chloride vapor atomized by the high-frequency ultrasonic atomizer 21 enters the gas-liquid separator 22 to be separated into gas and liquid, and the- μm gaseous particles are released by the gas-liquid separator 22.
Referring to fig. 6, a dryer 23 is provided at the upper side of the gas-liquid separator 22, and small particles of- μm in a gaseous state are discharged into the dryer 23 to be dried at a high temperature.
Referring to fig. 6, the mixing device 3 includes two branch pipes 31 and a header pipe 32 connected to one end of the two branch pipes 31.
One branch pipe 31 is connected with the release device 11 for discharging chlorine dioxide molecules after aeration treatment, and the other branch pipe 31 is connected with a discharge hole of the dryer 23 for discharging sodium chloride particles after drying.
Referring to fig. 6 and 7, the air conveying device 6 may be an air conveying device such as a fresh air system or an air conditioner, one end of the collecting pipe 32 far away from the two branch pipes 31 is connected to the inlet of the negative pressure section of the air supply pipeline 14 of the air conveying device 6, the air outlet pipeline of the air conveying device 6 is connected in the sterilizing space 7, and the sterilizing space 7 may be different public places with dense personnel such as hospitals, supermarkets, slaughterhouses, seafood markets, underground civil air defense projects, office buildings, shopping malls, school canteens, kindergartens, restaurants, hotels, nursing homes, station waiting halls, airport terminal buildings, subway stations, bank business halls, subway high-speed rail carriages, and mail wheels. The air inlet end of the air conveying device 6 is also connected with an air quantity detector 61 which can detect the air quantity entering the disinfection space 7, and the disinfection space 7 is also connected with a chlorine dioxide concentration detector 71 which is used for detecting the concentration of the disinfectant in the disinfection space 7.
Referring to fig. 6 and 7, in operation, the air supply system is operated, when external air is pumped into the sterilizing space 7, and meanwhile, the sterilizing aerosol is pumped into the air supply system from the collecting pipe 32, and the colleagues sterilizing fresh air and an air supply channel are conveyed into the sterilizing space 7 at the far end, so that the air and objects in the sterilizing space 7 are sterilized in an omnibearing manner without dead angles, in addition, the air quantity entering the sterilizing space 7 can be detected through the set air quantity detector 61, the set chlorine dioxide concentration detector 71 can detect the concentration of sterilizing liquid in the sterilizing space 7, and then the concentration proportion of the sterilizing liquid in the activating tank 43 can be quickly adjusted by combining with the liquid concentration detector 434, so that the sterilizing gas concentration in the sterilizing space 7 is ensured to dynamically meet the standard.
The application principle is that a sterilizing liquid with preset concentration is supplied to a releasing device 11, and pure chlorine dioxide gas is released in an aeration mode through the releasing device 11; simultaneously, sodium chloride purified water is gasified through a high-frequency ultrasonic atomizer 21, sodium chloride particles with the size of 1-5 mu m are released through a gas-liquid separation device 22, then gaseous sodium chloride particles with the size of 1-5 mu m are dried at high temperature through a dryer 23, submicron sodium chloride particles and chlorine dioxide gas molecules are released to be mixed to form aerosol, the aerosol is continuously conveyed to an air inlet pipe inlet of an air conveying device 6 such as a central air conditioning system or a fresh air system, and the aerosol enters an air supply pipeline 14 of the air conveying device 6 such as the central air conditioning system or the fresh air system along with fresh air, and the air supply pipeline 14 are conveyed to a far-end place while being disinfected, and the aerosol is released into a space to be disinfected in an all-round dead angle-free manner for air and objects in the space.
The foregoing are all preferred embodiments of the present application, and are not intended to limit the scope of the present application in any way, therefore: all equivalent changes in structure, shape and principle of this application should be covered in the protection scope of this application.

Claims (6)

1. A system for preparing a sterilizing aerosol, comprising:
the releasing device (11) is internally provided with a first containing cavity which can contain chlorine dioxide disinfectant;
the aeration device (12) is positioned at the bottom of the release device (11) and is used for generating chlorine dioxide gas;
the high-frequency ultrasonic atomizer (21) is internally provided with a second containing cavity which can contain sodium chloride melt to generate sodium chloride vapor;
the gas-liquid separator (22) is connected to the mist outlet end of the high-frequency ultrasonic atomizer (21) and is used for performing gas-liquid separation on sodium chloride water vapor to release sodium chloride gaseous particles;
the dryer (23) is connected to the discharge end of the gas-liquid separator (22) and is used for drying the sodium chloride gaseous particles to generate sodium chloride particles;
the two branch pipes (31) are respectively connected with the upper side of the release device (11) and the discharge port of the dryer (23) and are used for receiving chlorine dioxide gaseous molecules and sodium chloride particles;
and a collecting pipe (32) which is connected with one end of the two branch pipes (31) far away from the releasing device (11) or the dryer (23) and is used for mixing sodium chloride particles into aerosol with condensation nuclei and chlorine dioxide gas molecules.
2. The aerosol preparation system for sterilization as defined in claim 1, wherein:
one side of the release device (11) is provided with a variable fan (13), the variable fan (13) and the release device (11) are connected with an air supply pipeline (14), and the upper side of the aeration device (12) is provided with a plurality of exhaust micropores.
3. The aerosol sterilizing preparation system of claim 1, further comprising:
a chlorine dioxide mother liquor tank (41) capable of containing chlorine dioxide mother liquor;
an activation liquid tank (42) that can contain an activation liquid;
the activation tank (43), activation tank (43) feed inlet with chlorine dioxide mother liquor jar (41) with activation fluid jar (42) are connected respectively, can mix chlorine dioxide mother liquor and activation liquid, the liquid outlet of activation tank (43) connect in release device (11).
4. A disinfection system for disinfecting an aerosol, comprising:
comprising a disinfection aerosol production system according to any one of claims 1 to 2; the method comprises the steps of,
the air delivery device (6), the air inlet end of air delivery device (6) is connected header pipe (32), and the air outlet end of air delivery device (6) is connected in disinfection space (7).
5. The disinfection system of a disinfection aerosol of claim 4, further comprising:
the air quantity detector (61) is arranged at the air inlet end of the air conveying device (6) and is used for detecting the air quantity entering the disinfection space (7);
and the chlorine dioxide concentration detector (71) is arranged in the disinfection space (7) and is used for detecting the concentration of the disinfectant in the disinfection space (7).
6. A method of preparing an aerosol for sterilization using the system for preparing an aerosol for sterilization according to claim 1, comprising the steps of:
preparing chlorine dioxide gas:
chlorine dioxide disinfectant is adopted to release chlorine dioxide gas in an aeration mode;
preparing sodium chloride particles:
adopting pure sodium chloride aqueous solution and atomizing to generate sodium chloride vapor;
gas-liquid separation is carried out on atomized sodium chloride water vapor, and sodium chloride gaseous particles with the size of 1-5 mu m are released;
drying the sodium chloride gas particles to release submicron sodium chloride particles;
mixing to prepare aerosol:
sodium chloride particles are used as condensation nuclei to be mixed with carbon dioxide chlorine gas molecules to form aerosol.
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KR100813308B1 (en) * 2006-08-31 2008-03-13 한국식품연구원 The technique of producing aerosol sanitizer by ultrasonic transducer device
CN100411987C (en) * 2006-09-22 2008-08-20 清华大学 Submicron level solid sodium chloride aerosol preparing process and apparatus
CN101352661B (en) * 2008-09-18 2010-08-18 中国建筑科学研究院 Monodisperse aerosol generator
CN202143720U (en) * 2011-06-29 2012-02-15 太原和瑞环保科技有限公司 Chlorine dioxide air sterilizer
CN104208737B (en) * 2014-09-17 2017-05-10 济南市大秦机电设备有限公司 Chlorine dioxide aeration device for disinfecting air
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