CN114144449A - 配制的多元醇组合物 - Google Patents
配制的多元醇组合物 Download PDFInfo
- Publication number
- CN114144449A CN114144449A CN202080050951.3A CN202080050951A CN114144449A CN 114144449 A CN114144449 A CN 114144449A CN 202080050951 A CN202080050951 A CN 202080050951A CN 114144449 A CN114144449 A CN 114144449A
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- CN
- China
- Prior art keywords
- polyol composition
- parts
- formulated polyol
- formulated
- propoxylated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 94
- 229920005862 polyol Polymers 0.000 title claims abstract description 94
- 150000003077 polyols Chemical class 0.000 title claims abstract description 94
- 150000001412 amines Chemical class 0.000 claims abstract description 29
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 28
- 229920000570 polyether Polymers 0.000 claims abstract description 28
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 26
- 229930006000 Sucrose Natural products 0.000 claims abstract description 26
- 239000005720 sucrose Substances 0.000 claims abstract description 26
- 229920001519 homopolymer Polymers 0.000 claims abstract description 23
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims abstract description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000006260 foam Substances 0.000 claims description 47
- 239000003054 catalyst Substances 0.000 claims description 35
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 32
- 239000012948 isocyanate Substances 0.000 claims description 31
- 150000002513 isocyanates Chemical class 0.000 claims description 31
- 238000009472 formulation Methods 0.000 claims description 25
- 239000004094 surface-active agent Substances 0.000 claims description 14
- 238000007664 blowing Methods 0.000 claims description 12
- 239000004604 Blowing Agent Substances 0.000 claims description 11
- 239000002666 chemical blowing agent Substances 0.000 claims description 3
- 239000004088 foaming agent Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 13
- 150000001298 alcohols Chemical class 0.000 description 11
- -1 aliphatic amines Chemical class 0.000 description 11
- 239000006071 cream Substances 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000005056 polyisocyanate Substances 0.000 description 10
- 229920001228 polyisocyanate Polymers 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000012973 diazabicyclooctane Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000037075 skin appearance Effects 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 5
- 150000004072 triols Chemical class 0.000 description 5
- 238000011179 visual inspection Methods 0.000 description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 238000005829 trimerization reaction Methods 0.000 description 4
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical group COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229920013701 VORANOL™ Polymers 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical compound O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 description 2
- RLYCRLGLCUXUPO-UHFFFAOYSA-N 2,6-diaminotoluene Chemical compound CC1=C(N)C=CC=C1N RLYCRLGLCUXUPO-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical group C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000001983 dialkylethers Chemical class 0.000 description 2
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical class [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 2
- 239000002983 wood substitute Substances 0.000 description 2
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 1
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 description 1
- NLOLSXYRJFEOTA-UPHRSURJSA-N (z)-1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)\C=C/C(F)(F)F NLOLSXYRJFEOTA-UPHRSURJSA-N 0.000 description 1
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- DUAKCVSNUIDZMC-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluorobutane Chemical compound CC(F)(F)C(F)(F)C(F)(F)F DUAKCVSNUIDZMC-UHFFFAOYSA-N 0.000 description 1
- NVSXSBBVEDNGPY-UHFFFAOYSA-N 1,1,1,2,2-pentafluorobutane Chemical compound CCC(F)(F)C(F)(F)F NVSXSBBVEDNGPY-UHFFFAOYSA-N 0.000 description 1
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- CVMVAHSMKGITAV-UHFFFAOYSA-N 1,1,1,4,4,5,5,5-octafluoropent-2-ene Chemical compound FC(F)(F)C=CC(F)(F)C(F)(F)F CVMVAHSMKGITAV-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- GFNDFCFPJQPVQL-UHFFFAOYSA-N 1,12-diisocyanatododecane Chemical compound O=C=NCCCCCCCCCCCCN=C=O GFNDFCFPJQPVQL-UHFFFAOYSA-N 0.000 description 1
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 1
- OHTRJOZKRSVAOX-UHFFFAOYSA-N 1,3-diisocyanato-2-methylcyclohexane Chemical compound CC1C(N=C=O)CCCC1N=C=O OHTRJOZKRSVAOX-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- AHBNSOZREBSAMG-UHFFFAOYSA-N 1,5-diisocyanato-2-methylpentane Chemical compound O=C=NCC(C)CCCN=C=O AHBNSOZREBSAMG-UHFFFAOYSA-N 0.000 description 1
- KHXVVWQPIQVNRH-UHFFFAOYSA-N 1-isocyanato-3-(isocyanatomethyl)-1-methylcyclohexane Chemical compound O=C=NC1(C)CCCC(CN=C=O)C1 KHXVVWQPIQVNRH-UHFFFAOYSA-N 0.000 description 1
- CXBDYQVECUFKRK-UHFFFAOYSA-N 1-methoxybutane Chemical compound CCCCOC CXBDYQVECUFKRK-UHFFFAOYSA-N 0.000 description 1
- GEEGPFGTMRWCID-UHFFFAOYSA-N 1-n,1-n,1-n',1-n'-tetramethylbutane-1,1-diamine Chemical compound CCCC(N(C)C)N(C)C GEEGPFGTMRWCID-UHFFFAOYSA-N 0.000 description 1
- BFXXDIVBYMHSMP-UHFFFAOYSA-L 2,2-diethylhexanoate;tin(2+) Chemical compound [Sn+2].CCCCC(CC)(CC)C([O-])=O.CCCCC(CC)(CC)C([O-])=O BFXXDIVBYMHSMP-UHFFFAOYSA-L 0.000 description 1
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-O N-dimethylethanolamine Chemical compound C[NH+](C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-O 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- XTPWKTDOZRVFAT-UHFFFAOYSA-N [4-methyl-1,3-bis(6-methylheptyl)cyclohexyl] cyanate Chemical compound CC(C)CCCCCC1CC(CCCCCC(C)C)(OC#N)CCC1C XTPWKTDOZRVFAT-UHFFFAOYSA-N 0.000 description 1
- CQQXCSFSYHAZOO-UHFFFAOYSA-L [acetyloxy(dioctyl)stannyl] acetate Chemical compound CCCCCCCC[Sn](OC(C)=O)(OC(C)=O)CCCCCCCC CQQXCSFSYHAZOO-UHFFFAOYSA-L 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001621 bismuth Chemical class 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- PYBNTRWJKQJDRE-UHFFFAOYSA-L dodecanoate;tin(2+) Chemical compound [Sn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O PYBNTRWJKQJDRE-UHFFFAOYSA-L 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- UKACHOXRXFQJFN-UHFFFAOYSA-N heptafluoropropane Chemical compound FC(F)C(F)(F)C(F)(F)F UKACHOXRXFQJFN-UHFFFAOYSA-N 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- RLEFZEWKMQQZOA-UHFFFAOYSA-M potassium;octanoate Chemical compound [K+].CCCCCCCC([O-])=O RLEFZEWKMQQZOA-UHFFFAOYSA-M 0.000 description 1
- WQKGAJDYBZOFSR-UHFFFAOYSA-N potassium;propan-2-olate Chemical compound [K+].CC(C)[O-] WQKGAJDYBZOFSR-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
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Abstract
本公开的实施方式涉及配制的多元醇组合物,所述配制的多元醇组合物包含蔗糖丙氧基化多元醇、丙氧基化均聚物三醇和胺引发的聚醚醇。
Description
技术领域
本公开的实施方式涉及配制的多元醇组合物,更具体地,实施方式涉及包括蔗糖丙氧基化多元醇、丙氧基化均聚物三醇和胺引发的聚醚醇的配制的多元醇组合物。
背景技术
泡沫为其中气体分散在液体材料、固体材料或凝胶材料中的分散体。泡沫可通过多元醇和异氰酸酯的化学反应形成。泡沫可用于许多不同的应用,包括绝缘体、床上用品、家具、车辆座椅和地毯底布等。
发明内容
本公开提供了配制的多元醇组合物,其包括:蔗糖丙氧基化多元醇,其具有3.0至6.0的平均羟基官能度,360至460mg KOH/g的平均羟基数和400至800g/mol的数均分子量;丙氧基化均聚物三醇,其具有2.6至3.4的平均羟基官能度,300至500mg KOH/g的平均羟基数和250至650g/mol的数均分子量;胺引发的聚醚醇,其具有1.0至3.5的平均羟基官能度,550至750mg KOH/g的平均羟基数和125至250g/mol的数均分子量;发泡剂;表面活性剂;以及选自发泡催化剂、凝胶催化剂以及它们的组合的催化剂。
本公开提供了包含配制的多元醇组合物和异氰酸酯的泡沫配制物。
本公开提供了通过固化泡沫配制物而形成的泡沫产品。
本公开的以上发明内容并非旨在描述本公开的每个所公开的实施例或每个实施方案。以下描述更具体地示范说明性实施例。在本申请整篇的若干处,通过实施例列表提供指导,所述实施例可以各种组合形式使用。在每种情况下,所列举的列表仅充当代表性群组并且不应解释为排它性列表。
具体实施方式
本文公开了包含蔗糖丙氧基化多元醇、聚醚三醇和胺引发的聚醚醇的配制的多元醇组合物。有利地,本文公开的配制的多元醇组合物可用于制备具有对许多应用为期望的特性的组合的泡沫配制物和泡沫产品。例如,本文所公开的配制的多元醇组合物可用于制造可经固化以制造木材替代材料的泡沫配制物,所述木材替代材料可称为聚氨基甲酸酯木材材料。
如本文所公开的,可以固化成泡沫产品的泡沫配制物具有期望的反应性特性,即期望的乳白时间和凝胶时间。泡沫产品具有期望的特性,即期望的模塑密度、肖氏D硬度和表皮方面。
本文所公开的配制的多元醇组合物包含蔗糖丙氧基化多元醇。如本文所用,“蔗糖丙氧基化多元醇”是指经由蔗糖和环氧丙烷的反应形成的化合物。一种或多种实施方式规定,蔗糖丙氧基化多元醇不包含衍生自环氧乙烷或环氧丁烷的结构单元。
蔗糖丙氧基化多元醇可具有3.0到6.0的平均羟基官能度。包括3.0到6.0的所有个别值和子范围;例如,蔗糖丙氧基化多元醇可具有从下限3.0、3.2、3.5或4.0到上限6.0、5.7、5.5或5.0的平均羟基官能度。
蔗糖丙氧基化多元醇可具有360至460mg KOH/g的平均羟基数。包括360至460mgKOH/g的所有个别值和子范围;例如,蔗糖丙氧基化多元醇可具有从下限360、370或380mgKOH/g至上限460、440或420mg KOH/g的平均羟基数。平均羟基数如KOH可根据ASTM D4274测定。
蔗糖丙氧基化多元醇可具有400至800g/mol的数均分子量。包括400至800g/mol的所有个别值和子范围;例如,蔗糖丙氧基化多元醇可具有从下限400、450或500g/mol至上限800、750或700g/mol的数均分子量。
蔗糖丙氧基化多元醇可以具有91.7至183.5g/eq的当量。可将当量确定为分子量和官能度的商。包括从91.7至183.5g/eq的所有个别值和子范围;例如,蔗糖丙氧基化多元醇可具有从下限91.7、103.2或114.7g/eq至上限183.5,172.0或160.0.6g/eq的当量。
蔗糖丙氧基化多元醇可以使用已知的设备、反应条件和反应组分制备。例如,蔗糖丙氧基化多元醇可由包括蔗糖、环氧丙烷、甘油和单丙二醇以及其它反应组分的反应混合物形成。
蔗糖丙氧基化多元醇可以商购获得。可商购获得的蔗糖丙氧基化多元醇的示例包括但不限于以商品名VORANOLTM出售的多元醇,如可购自陶氏化学公司(Dow ChemicalCompany)的VORANOLTM 466,等。
按配制的多元醇组合物为100份计,蔗糖丙氧基化多元醇可以是配制的多元醇组合物的60至85份。包括从60到85份的所有个别值和子范围;例如,按配制的多元醇组合物为100份计,蔗糖丙氧基化多元醇可以是配制的多元醇组合物的下限60、65或70份至上限85、80、76、或74份。
本文所公开的配制的多元醇组合物包括丙氧基化均聚物三醇。如本文所用,“三醇”是指具有2.6至3.4的平均羟基官能度的化合物。如本文所用,“丙氧基化均聚物三醇”是指通过环氧丙烷和引发剂的聚合产生的聚醚多元醇。引发剂可以是甘油、丙三醇或其组合。聚合的各种混合比率可用于不同的应用。本公开的实施例规定,聚醚多元醇(即丙氧基化均聚物三醇)的端基为仲醇羟基。
丙氧基化均聚物三醇可具有2.6至3.4的平均羟基官能度。包括2.6到3.4的所有个别值和子范围;例如,丙氧基化均聚物三醇可具有从下限2.6、2.7或2.8到上限3.4、3.3或3.2的平均羟基官能度。
丙氧基化均聚物三醇可以具有300至500mg KOH/g的平均羟基数。包括300至500mgKOH/g的所有个别值和子范围;例如,丙氧基化均聚物三醇可具有从下限300、315或325mgKOH/g至上限500、475或450mg KOH/g的平均羟基数。
丙氧基化均聚物三醇可具有250至650g/mol的数均分子量。包括250至650g/mol的所有个别值和子范围;例如,丙氧基化均聚物三醇可具有从下限250、300或350g/mol至上限650、600或550g/mol的数均分子量。
丙氧基化均聚物三醇可以具有83.3至216.7g/eq的当量。包括从83.3至216.7g/eq的所有个别值和子范围;例如,丙氧基化均聚物三醇可以具有从下限83.3、100.0或116.7g/eq至上限216.7、200或183.3g/eq的当量。
丙氧基化均聚物三醇可以使用已知的设备、反应条件和反应组分制备。
丙氧基化均聚物三醇可以商购获得。可商购获得的丙氧基化均聚物三醇的示例包括(但不限于)以商品名VORANOLTM出售的丙氧基化均聚物三醇,如购自陶氏化学公司的VORANOLTM 450N,等。
按配制的多元醇组合物为100份计,丙氧基化均聚物三醇可以是配制的多元醇组合物的9至18份。包括从9至18份的所有个别值和子范围;例如,按配制的多元醇组合物为100份计,丙氧基化均聚物三醇可以是配制的多元醇组合物的下限9、9.5、或10份至上限18、13、12.5、12份。
本文所公开的配制的多元醇组合物包含胺引发的聚醚醇。胺引发的聚醚醇可由芳族胺或脂肪族胺引发,例如,胺引发的聚醚醇可以是邻甲苯二胺(o-TDA)引发的醇、乙二胺引发的醇、二亚乙基三胺、三异丙醇胺引发的多元醇,或它们的组合等。
胺引发的聚醚醇可以具有1.0至3.5的平均羟基官能度。包括1.0至3.5的所有个别值和子范围;例如,胺引发的聚醚醇可具有1.0、1.4或1.8的下限至3.5、3.0或2.5的上限的平均官能度。
胺引发的聚醚醇可以具有550至750mg KOH/g的平均羟基数。包括550至750mgKOH/g的所有个别值和子范围;例如,胺引发的聚醚醇可具有从下限550、575或600mg KOH/g至上限750、725或700mg KOH/g的平均羟基数。
胺引发的聚醚醇的数均分子量可为125至250g/mol。包括125至250g/mol的所有个别值和子范围;例如,胺引发的聚醚醇的数均分子量可为125、135或145g/mol的下限至250、225或200g/mol的上限。
胺引发的聚醚醇可具有62.5至125g/mol的当量。包括62.5至125g/mol的所有个别值和子范围;例如,胺引发的聚醚醇可具有62.5、67.5或77.5的下限至125、112.5或100的上限的当量。
可使用已知设备和反应条件来制备胺引发的聚醚醇,例如在催化剂存在下包括胺和环氧烷(例如,环氧丙烷)的反应过程。胺引发的聚醚醇可由脂肪族胺引发,所述脂肪族胺具有小于5.0(例如,大于2.5)的氨基官能度和/或小于60g/mol(例如,15g/mol到60g/mol、20g/mol到50g/mol等)的氨基当量。可使用的示范性脂肪族胺包括乙二胺,所述乙二胺可以单独或与其它胺引发剂组合使用。一个或多个实施方式规定,胺引发的聚醚醇不包括衍生自环氧乙烷或环氧丁烷的结构单元。胺引发的聚醚醇可以商业获得。商购可得的胺引发的聚醚醇的示例尤其包括但不限于购自陶氏化学公司的以商标名VORANOLTM(例如VORANOLTMRA 640)出售的醇。
按配制的多元醇组合物为100份计,胺引发的聚醚醇可以是配制的多元醇组合物的3至12份。包括从3至12份的所有个别值和子范围;例如,按配制的多元醇组合物为100份计,胺引发的聚醚醇可以是配制的多元醇组合物的下限3、3.5、或4重量百分比至上限12、7、6.5或6份。
本公开的实施方式规定,多元醇组合物包含发泡剂。发泡剂可为物理发泡剂、化学发泡剂或它们的组合。
物理发泡剂的示例包括液态二氧化碳;烷烃;环烷烃,例如环戊烷、环己烷、环丁烷和其混合物;其它具有最多7个碳原子的环烷烃;二烷基醚、亚环烷基醚、氟烷烃、氢氟烯烃、氢氯氟烯烃以及它们的混合物。烷烃的示例包括(但不限于)丙烷、丁烷、正丁烷、异丁烷、戊烷、异戊烷和它们的组合。二烷基醚的示例包括二甲醚、甲基乙基醚、甲基丁基醚、乙醚和它们的组合。亚环烷基醚的示例为呋喃。氟烷烃的示例包括但不限于五氟丙烷、三氟甲烷、二氟甲烷、二氟乙烷、四氟乙烷、七氟丙烷、五氟丁烷、七氟丁烷以及它们的组合等。氢氟烯烃和/或氢氯氟烯烃的示例包括(但不限于)1,1,1,4,4,5,5,5-八氟-2-戊烯(HFC-1438mzz)、Z-1,1,1,4,4,4-六氟-2-丁烯(HFC-1336mzz,Z-异构体)、反式-1,3,3,3-四氟丙烯、1-氯-3,3,3-三氟丙烯(HFO-1233zd)。一个或多个实施方式规定物理发泡剂是二丙二醇甲醚。二丙二醇甲醚可商购获得,例如作为可从陶氏化学公司获得的DOWANOLTM DPM。
化学发泡剂的示例为水。
按配制的多元醇组合物为100份计,发泡剂可以是配制的多元醇组合物的4至10份。包括从4至10份的所有个别值和子范围;例如,按配制的多元醇组合物为100份计,发泡剂可以是配制的多元醇组合物的下限4、5.5、或5重量百分比至上限10、9.5或8份。
本文所公开的配制的多元醇组合物包含表面活性剂。用于制备聚氨基甲酸酯泡沫的表面活性剂为本领域技术人员众所周知的,并且许多为可商购的。表面活性剂可以是硅酮表面活性剂、非硅酮表面活性剂或它们的组合。合适的硅酮表面活性剂的示例包括但不限于来自赢创(Evonik)的TEGOSTAB B-8427、B-8454、B-8404、B-8407、B-8409和B-8462;来自迈图(MOMENTIVE)的L-5130、L-5180、L-5340、L-5440、L-6100、L-6900、L-6980和L-6988,以及来自美国道康宁(Dow Corning)的DC-5374、DC-193、DC-197、DC-5582和DC-5598。非硅酮表面活性剂的示例包括但不限于乙氧基化烷基酚、乙氧基化脂肪醇、石蜡油、蓖麻油酯、蓖麻油酸酯、火鸡红油、花生油、石蜡、硅酮表面活性剂和脂肪醇。
按配制的多元醇组合物为100份计,表面活性剂可以是配制的多元醇组合物的0.5至5.0份。包括从0.5到5.0份的所有个别值和子范围;例如,按配制的多元醇组合物为100份计,表面活性剂可以是配制的多元醇组合物的下限0.5、1.0或2.0份至上限5.0、4.5或4.0份。
本文所公开的配制的多元醇组合物包含催化剂。催化剂可为发泡催化剂、胶凝催化剂、三聚催化剂或其组合。如本文所用,发泡催化剂和胶凝催化剂可通过有利于脲(发泡)反应(在发泡催化剂的情况下)或氨基甲酸酯(胶凝)反应(在胶凝催化剂的情况下)的催化倾向来进行区分。三聚催化剂可用于促进组合物的反应性。一个或多个实施例规定,催化剂选自发泡催化剂、凝胶催化剂或它们的组合。
发泡催化剂(例如通常促进发泡反应的催化剂)的示例包括但不限于短链叔胺或含氧叔胺。例如,发泡催化剂包括双-(2-二甲氨基乙基)醚;五甲基二亚乙基-三胺、三乙胺、三丁胺、N,N-二甲氨基丙胺、N,N-二甲基乙醇胺、N,N,N',N'-四甲基乙二胺以及它们的组合等。商业发泡催化剂的具体示例是来自迈图(MOMENTIVE)的NIAX A1。
胶凝催化剂(例如通常有利于胶凝反应的催化剂)的示例包括但不限于有机金属化合物、环状叔胺和/或长链胺(例如含有若干氮原子)和其组合。有机金属化合物包括有机锡化合物,如有机羧酸的锡(II)盐,例如二乙酸锡(II)、二辛酸锡(II)、二乙基己酸锡(II)和二月桂酸锡(II),和有机羧酸的二烷基锡(IV)盐,例如二乙酸二丁基锡、二月桂酸二丁基锡、顺丁烯二酸二丁基锡和二乙酸二辛基锡。有机羧酸的铋盐也可用作胶凝催化剂,例如辛酸铋。环状叔胺和/或长链胺包括二甲基苄胺、N,N,N',N'-四甲基丁二胺、二甲基环己胺、三亚乙基二胺和其组合。商业胶凝催化剂的具体示例为来自赢创(Evonik)的DABCO 33-LV和DABCO T-12。
三聚催化剂的示例包括三(二烷氨基烷基)-s-六氢三嗪,如1,3,5-三(N,N-二甲氨基丙基)-s-六氢三嗪;[2,4,6-三(二甲氨基甲基)苯酚];乙酸钾、辛酸钾;氢氧化四烷基铵,如氢氧化四甲基铵;碱金属氢氧化物,如氢氧化钠;碱金属醇盐,如甲醇钠和异丙醇钾;和具有10至20个碳原子的长链脂肪酸的碱金属盐和它们的组合。一些可商购的三聚催化剂包括来自赢创的DABCO TMR、DABCO TMR-2和DABCO TMR-30。
按配制的多元醇组合物为100份计,催化剂可以是配制的多元醇组合物的0.5至7份。包括从0.5到7份的所有个别值和子范围;例如,按配制的多元醇组合物为100份计,催化剂可以是配制的多元醇组合物的下限0.5、1或2份至上限7、6.5或6份。
本公开的一个或多个实施例规定配制的多元醇组合物可包括一种或多种额外组分。可针对各种应用利用不同的附加组分和/或不同量的附加组分。附加组分的示例包括颜料、着色剂、抗氧化剂、生物阻滞剂、阻燃剂以及它们的组合等。不同量的附加组分可用于不同的应用。
本公开提供了包含本文所公开的配制的多元醇组合物和异氰酸酯的泡沫配制物。异氰酸酯可为聚异氰酸酯。如本文所用,“聚异氰酸酯”是指平均具有大于1.0个异氰酸酯基/分子,例如大于1.0的平均官能度的分子。
举例来说,异氰酸酯可为脂肪族聚异氰酸酯、环脂肪族聚异氰酸酯、芳香脂肪族聚异氰酸酯、芳香族聚异氰酸酯或其组合。异氰酸酯的示例包括但不限于聚亚甲基聚苯基异氰酸酯、甲苯2,4-/2,6-二异氰酸酯(TDI)、亚甲基二苯基二异氰酸酯(MDI)、聚合MDI、三异氰酸基壬烷(TIN)、萘基二异氰酸酯(NDI)、4,4'-二异氰酸基二环己基甲烷、3-异氰酸基甲基-3,3,5-三甲基环己基异氰酸酯(异佛尔酮二异氰酸酯IIPDI)、四亚甲基二异氰酸酯、六亚甲基二异氰酸酯(HDI)、2-甲基五亚甲基二异氰酸酯、2,2,4-三甲基六亚甲基二异氰酸酯(THDI)、十二碳亚甲基二异氰酸酯、1,4-二异氰酸基环己烷、4,4'-二异氰酸基-3,3'-二甲基二环己基甲烷、4,4'-二异氰酸基-2,2-二环己基丙烷、3-异氰酸基甲基-1-甲基-1-异氰酸基环己烷(MCI)、1,3-二异辛基氰酸基-4-甲基环己烷、1,3-二异氰酸基-2-甲基环己烷和其组合等。除上文所提及的异氰酸酯之外,可利用部分改性的聚异氰酸酯,包括脲二酮、异氰尿酸酯、碳二亚胺、脲酮亚胺、脲基甲酸酯或缩二脲结构和其组合等。
异氰酸酯可为聚合的。如本文所用,在描述异氰酸酯时,“聚合的”是指具有较高分子量的同系物和/或异构体。例如,聚合的亚甲基二苯基异氰酸酯是指亚甲基二苯基异氰酸酯的较高分子量同系物和/或异构体。
如所提及,异氰酸酯的平均官能度可大于1.0个异氰酸酯基/分子。例如,异氰酸酯可具有1.5至8.0的平均官能度。包括1.5至8.0的所有个别值和子范围;例如,异氰酸酯的平均官能度可为1.5、1.7、2.0、2.3、2.5、2.7或3.0的下限至8.0、7.5、7.0、6.7、6.5、6.3、6.0、5.7或5.5的上限。
异氰酸酯可以具有80g/eq至500g/eq的异氰酸酯当量。包括80至500g/eq的所有个别值和子范围;例如,异氰酸酯的异氰酸酯当量可为80、82、84、90或100的下限至500、450、400、375或350g/eq的上限。
异氰酸酯可通过已知方法制备。举例来说,可通过使对应的多元胺光气化并且形成聚氨基甲酰氯并且对其进行热分解以提供聚异氰酸酯和氯化氢或通过无光气的方法,如通过使对应的多元胺与脲和醇反应以得到聚氨基甲酸酯并且对其进行热分解以得到聚异氰酸酯和醇来制备聚异氰酸酯。
异氰酸酯可商购获得。可商购获得的异氰酸酯的示例包括但不限于可购自陶氏化学公司的商品名为VORANATETM、VORACORTM(例如VORACOR CL100或VORACOR CE 101)和PAPITM(例如PAPI 27)的聚异氰酸酯以及其它可商购获得的异氰酸酯。
按配制的多元醇组合物为100份的泡沫配制物计,异氰酸酯可以是泡沫配制物的90至130份。包括从90到130份的所有个别值和子范围;例如,在配制的多元醇组合物为100份的泡沫配制物的情况下,异氰酸酯可以是泡沫配制物的下限90、95或100份至上限130、125或120份。
可以使用异氰酸酯使得泡沫配制物具有90至130的异氰酸酯指数。可将异氰酸酯指数确定为所利用的异氰酸酯的实际量与用于固化的异氰酸酯的理论量的商(乘以一百)。包括90至130的所有个别值和子范围;例如,泡沫配制物可具有下限90、100或105至上限130、125或120的异氰酸酯指数。
可固化本文所公开的泡沫配制物以形成泡沫产品。例如,泡沫配制物可以固化以形成木材替代材料。泡沫产品可使用已知方法和条件来制备,例如固化,所述已知方法和条件可针对不同应用而变化。
本文所公开的泡沫配制物和泡沫产品具有对许多应用为有利的特性的组合。
泡沫配制物的乳白时间为20至35秒。乳白时间可以定义为材料混合开始与细小气泡开始出现、颜色变化发生和/或泡沫开始上升之间的时间。乳白时间可根据ASTM D7487确定。乳白时间可以通过目测检视来确定。从20至35秒的乳白时间可为期望的,因为此类乳白时间可以满足许多发泡工艺应用和/或相关设备(例如原位浇筑应用)的加工参数。
该泡沫配制物的胶凝时间为50至70秒。胶凝时间可以定义为当泡沫配制物的表面与压舌板或类似器械的边缘接触时,粘性材料“串”可以从该表面拉开的时间。胶凝时间可以根据ASTM D7487测定。从50至70秒的胶凝时间可为期望的,因为此类胶凝时间可以满足许多发泡工艺应用和/或相关设备(例如原位浇筑应用)的加工参数。
泡沫产品的模塑密度为225至300kg/m3。模塑密度可以根据ASTM D-3574测定。从225至300kg/m3的模塑密度可为期望的,因为此类模塑密度可以满足许多发泡工艺应用和/或相关设备(例如原位浇筑应用)的加工参数。
泡沫产品的肖氏D硬度为21至35。肖氏D硬度可根据ASTM D-2240测定。从21至35的肖氏D硬度可为期望的,以帮助维持泡沫产品的尺寸稳定性和/或大小。
泡沫产品具有合格的表皮外观。合格或不合格的表皮外观可以通过目视检视确定,其中观察到的均质表皮表面具有合格的表皮外观,而观察到的非均质表皮表面具有不合格的皮肤外观。具有合格的表皮外观对于泡沫产品的美学和/或功能特征来说可为期望的。
实施例
在实施例中,使用材料的各种术语和名称,所述术语和名称包括例如以下:
VORANOLTM 466(蔗糖丙氧基化多元醇;平均羟基官能度4.36;平均羟基数392.5mgKOH/g;数均分子量600g/mol;从陶氏化学公司获得);
VORANOLTM 450N(丙氧基化均聚物三醇;甘油引发的;平均羟基官能度3;平均羟基数374mg KOH/g;数均分子量450g/mol;从陶氏化学公司获得);
VORANOLTM RA 640(胺引发的聚醚醇;乙二胺引发的丙氧基化醇;平均羟基官能度2;平均羟基数640mg KOH/g;平均数均分子量175g/mol;从陶氏化学公司获得);
DOWANOLTM DPM(物理发泡剂;二丙二醇甲醚;从陶氏化学公司获得);
DC-5374(表面活性剂;从陶氏化学公司获得);
DABCO 33-LV(凝胶催化剂;从赢创公司获得);
N,N-二甲基乙醇胺(发泡催化剂;从赢创公司获得);
PAPITM 27(异氰酸酯;含有MDI的聚亚甲基多苯基异氰酸酯;从陶氏化学公司获得)。
如下制备实施例1的配制的多元醇组合物。对于实施例1,表1中列出的项目通过混合在容器中组合。表1中所示的量是基于总共100份配制的多元醇组合物的份数。
如实施例1制备比较例A至U,其中改变之处在于分别利用表1中所指示的组分/量。
表1
实施例2,通过以下方式形成泡沫配制物:通过用实验室混合器以3000rpm混合10秒将PAPI 27(110份)和实施例1(100份)在容器中组合,然后于25℃固化20分钟以形成泡沫产品。
如实施例2制备比较例AA-UU,其中改变之处在于利用比较例A-U而不是实施例1。
确定了泡沫配制物和由其形成的泡沫产品的许多特性。乳白时间按ASTM D7487测定。乳白时间是通过在材料混合开始与细小气泡开始出现、颜色变化发生和/或泡沫开始上升之间的时间进行目视检视测定的。胶凝时间按ASTM D7487测定。胶凝时间是通过当泡沫配制物的表面与压舌板的边缘接触时粘性材料“串”被从该表面拉开的时间进行目视检视测定的。模塑密度是根据ASTM D-3574测定的。肖氏D硬度是根据ASTM D-2240测定的。表皮外观是通过目视检视确定的,其中观察到的均质表皮表面具有合格的表皮外观,而观察到的非均质表皮表面具有不合格的皮肤外观。结果报告于表2中。
表2
表2的数据说明实施例2提供了本文所讨论的有利特性,即实施例2提供了:20至35秒的乳白时间;50至70秒的胶凝时间;225至300kg/m3的模塑密度;21至35的肖氏D硬度;和合格的表皮外观。
与实施例2不同,表2的数据说明比较例AA-UU中没有一者提供了:20至35秒的乳白时间;50至70秒的胶凝时间;225至300kg/m3的模塑密度;21至35的肖氏D硬度;和合格的表皮外观。
Claims (8)
1.一种配制的多元醇组合物,其包含:
蔗糖丙氧基化多元醇,其具有3.0至6.0的平均羟基官能度,360至460mg KOH/g的平均羟基数和400至800g/mol的数均分子量;
丙氧基化均聚物三醇,其具有2.6至3.4的平均羟基官能度,300至500mg KOH/g的平均羟基数和250至650g/mol的数均分子量;
胺引发的聚醚醇,其具有1.0至3.5的平均羟基官能度,550至750mg KOH/g的平均羟基数和125至250g/mol的数均分子量;
发泡剂;
表面活性剂;以及
催化剂,其选自发泡催化剂、凝胶催化剂以及它们的组合。
2.根据权利要求1所述的配制的多元醇组合物,
其中按所述配制的多元醇组合物为100份计,所述蔗糖丙氧基化多元醇为所述配制的多元醇组合物的60至85份;
其中按所述配制的多元醇组合物为100份计,所述丙氧基化均聚物三醇为所述配制的多元醇组合物的9至18份;并且
其中按所述配制的多元醇组合物为100份计,所述胺引发的聚醚醇为所述配制的多元醇组合物的3至12份。
3.根据权利要求1-2中任一项所述的配制的多元醇组合物,其中所述发泡剂选自物理发泡剂、化学发泡剂以及它们的组合。
4.根据权利要求1-3中任一项所述的配制的多元醇组合物,其中按所述配制的多元醇组合物为100份计,所述发泡剂为所述配制的多元醇组合物的4至10份。
5.根据权利要求1-4中任一项所述的配制的多元醇组合物,其中按所述配制的多元醇组合物为100份计,所述表面活性剂为所述配制的多元醇组合物的0.5至5.0份。
6.根据权利要求1-5中任一项所述的配制的多元醇组合物,其中按所述配制的多元醇组合物为100份计,所述催化剂为所述配制的多元醇组合物的0.5至7份。
7.一种泡沫配制物,其包含:
根据权利要求1-6中任一项所述的配制的多元醇组合物;以及
异氰酸酯,其中在所述配制的多元醇组合物为100份的所述泡沫配制物的情况下,所述异氰酸酯为所述泡沫配制物的90至130份。
8.一种泡沫产品,其通过固化根据权利要求7所述的泡沫配制物而形成。
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US201962877897P | 2019-07-24 | 2019-07-24 | |
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PCT/US2020/042970 WO2021016295A1 (en) | 2019-07-24 | 2020-07-22 | Formulated polyol compositions |
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Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4230824A (en) * | 1978-06-12 | 1980-10-28 | Mobay Chemical Corporation | Sucrose based polyether polyols |
JPS6040129A (ja) * | 1983-07-26 | 1985-03-02 | アルコ・ケミカル・カンパニー | 混合された開始剤より製造されたポリエーテルポリオール類及びそれを用いたポリウレタンフオームの製造方法 |
US5310766A (en) * | 1992-06-15 | 1994-05-10 | The Dow Chemical Company | Foam stabilizing additive and polyurethane foam prepared in the presence thereof |
CN1149063A (zh) * | 1995-07-26 | 1997-05-07 | 阿科化学技术公司 | 共引发固体多羟基引发剂水溶液制备适合于柔性聚氨酯泡沫的聚醚多元醇 |
WO2000005289A1 (en) * | 1998-07-23 | 2000-02-03 | Huntsman Ici Chemicals, Llc | Blends of sucrose- and aromatic amine initiated polyether polyols and their use in rigid polyurethane foam manufacture |
WO2002050148A2 (en) * | 2000-12-20 | 2002-06-27 | Orycle Applications Ltd. | Polyurethane compositions useful as shock absorbers and a method for their preparation |
CN101035826A (zh) * | 2004-10-05 | 2007-09-12 | 巴斯福股份公司 | 生产硬聚氨酯泡沫材料的方法 |
WO2013030101A1 (en) * | 2011-09-02 | 2013-03-07 | Dow Global Technologies Llc | Polyurethane rigid foams |
CN103261258A (zh) * | 2010-12-16 | 2013-08-21 | 陶氏环球技术有限责任公司 | 聚氨酯和多异氰脲酸酯泡沫体 |
CN105377932A (zh) * | 2013-07-18 | 2016-03-02 | 陶氏环球技术有限责任公司 | 减压下形成的不连续板用聚氨酯泡沫组合物 |
CN106103520A (zh) * | 2014-03-20 | 2016-11-09 | 陶氏环球技术有限责任公司 | 包括基于烯烃的发泡剂的调配异氰酸酯反应性掺合物 |
CN107428901A (zh) * | 2015-03-31 | 2017-12-01 | 陶氏环球技术有限责任公司 | 聚醚多元醇组合物 |
CN107531873A (zh) * | 2015-03-17 | 2018-01-02 | 陶氏环球技术有限责任公司 | 硬质聚氨酯泡沫的异氰酸酯反应性配制物 |
CN108055850A (zh) * | 2015-09-29 | 2018-05-18 | 陶氏环球技术有限责任公司 | 包含聚酯聚醚多元醇的硬质聚氨酯泡沫 |
CN108350136A (zh) * | 2015-10-28 | 2018-07-31 | 巴斯夫欧洲公司 | 聚醚酯及其在硬质聚氨酯泡沫材料制备中的用途 |
Patent Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4230824A (en) * | 1978-06-12 | 1980-10-28 | Mobay Chemical Corporation | Sucrose based polyether polyols |
JPS6040129A (ja) * | 1983-07-26 | 1985-03-02 | アルコ・ケミカル・カンパニー | 混合された開始剤より製造されたポリエーテルポリオール類及びそれを用いたポリウレタンフオームの製造方法 |
US5310766A (en) * | 1992-06-15 | 1994-05-10 | The Dow Chemical Company | Foam stabilizing additive and polyurethane foam prepared in the presence thereof |
CN1149063A (zh) * | 1995-07-26 | 1997-05-07 | 阿科化学技术公司 | 共引发固体多羟基引发剂水溶液制备适合于柔性聚氨酯泡沫的聚醚多元醇 |
WO2000005289A1 (en) * | 1998-07-23 | 2000-02-03 | Huntsman Ici Chemicals, Llc | Blends of sucrose- and aromatic amine initiated polyether polyols and their use in rigid polyurethane foam manufacture |
WO2002050148A2 (en) * | 2000-12-20 | 2002-06-27 | Orycle Applications Ltd. | Polyurethane compositions useful as shock absorbers and a method for their preparation |
CN1491256A (zh) * | 2000-12-20 | 2004-04-21 | ¿ | 用作减震器的聚氨酯组合物和其制备方法 |
CN101035826A (zh) * | 2004-10-05 | 2007-09-12 | 巴斯福股份公司 | 生产硬聚氨酯泡沫材料的方法 |
CN103261258A (zh) * | 2010-12-16 | 2013-08-21 | 陶氏环球技术有限责任公司 | 聚氨酯和多异氰脲酸酯泡沫体 |
WO2013030101A1 (en) * | 2011-09-02 | 2013-03-07 | Dow Global Technologies Llc | Polyurethane rigid foams |
CN105377932A (zh) * | 2013-07-18 | 2016-03-02 | 陶氏环球技术有限责任公司 | 减压下形成的不连续板用聚氨酯泡沫组合物 |
CN106103520A (zh) * | 2014-03-20 | 2016-11-09 | 陶氏环球技术有限责任公司 | 包括基于烯烃的发泡剂的调配异氰酸酯反应性掺合物 |
CN107531873A (zh) * | 2015-03-17 | 2018-01-02 | 陶氏环球技术有限责任公司 | 硬质聚氨酯泡沫的异氰酸酯反应性配制物 |
CN107428901A (zh) * | 2015-03-31 | 2017-12-01 | 陶氏环球技术有限责任公司 | 聚醚多元醇组合物 |
CN108055850A (zh) * | 2015-09-29 | 2018-05-18 | 陶氏环球技术有限责任公司 | 包含聚酯聚醚多元醇的硬质聚氨酯泡沫 |
CN108350136A (zh) * | 2015-10-28 | 2018-07-31 | 巴斯夫欧洲公司 | 聚醚酯及其在硬质聚氨酯泡沫材料制备中的用途 |
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