CN114075798A - 防刮超哑油及其应用工艺 - Google Patents
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Abstract
本发明涉及涂料技术领域，特别是涉及一种防刮超哑油，由以下质量百分比的原料组成：去离子水46％～55％、水性聚氨酯共聚物25％～35％、水溶性丙烯酸树脂5％～15％、哑光助剂2％～8％、水性助剂5％～10％、防腐剂0.1％～0.2％、水性聚酯3％～6％、抗刮剂2％～3％、耐水剂1％～2％、表面活性剂0.5％～1％、消泡剂0.1％～0.2％。本发明提供一种耐摩擦、耐折、流平性能优异、干燥速度适中的防刮超哑油。本发明还提供一种防刮超哑油的应用工艺，工艺简单，容易操作，使产品具有更好的流平性、更高的耐磨性及耐水性。
Description
技术领域
本发明涉及涂料技术领域，特别是涉及一种防刮超哑油及其应用工艺。
背景技术
哑油是一种印刷材料，其涂布在纸张、纸板或薄膜上，使得印刷的色彩亮丽、光滑、更具有立体感，具有安全、成本低、原材料来源广的优点，在印刷包装领域有着广泛的应用。但是，由于现在的哑油的耐摩擦性较差，防刮性、耐水性和耐折性弱，流平性能也较差，严重影响了印刷品的质量，再者，干燥性能较差，涂覆后所需的干燥时间长，从而延长了生产时间，降低了生产效率，同时环保性也较差。
发明内容
为解决上述技术问题，本发明提供一种耐摩擦、耐折、流平性能优异、干燥速度适中的防刮超哑油，替代传统的BOPP哑膜。
本发明还提供一种防刮超哑油的应用工艺，工艺简单，容易操作，使产品具有更好的流平性、更高的耐磨性及耐水性。
本发明采用如下技术方案：
一种防刮超哑油，由以下质量百分比的原料组成：
对上述技术方案的进一步改进为，所述哑光助剂为气相二氧化硅。
对上述技术方案的进一步改进为，所述水性助剂为聚醚。
对上述技术方案的进一步改进为，所述表面活性剂为聚醚表面活性剂。
对上述技术方案的进一步改进为，所述消泡剂设置为聚醚消泡剂。
对上述技术方案的进一步改进为，所述防腐剂为5-氯-2-甲基-4-异噻唑啉-3-酮与2-甲基-4-异噻唑啉-3-酮的复配物。
对上述技术方案的进一步改进为，所述5-氯-2-甲基-4-异噻唑啉-3-酮与2-甲基-4-异噻唑啉-3-酮的质量比为3：1。
对上述技术方案的进一步改进为，所述抗刮剂为有机硅。
对上述技术方案的进一步改进为，所述耐水剂为石蜡。
一种防刮超哑油的应用工艺，包括以下步骤：
按质量百分比称取去离子水、水性聚氨酯共聚物、水溶性丙烯酸树脂、气相二氧化硅、水性助剂、防腐剂、水性聚酯、抗刮剂、耐水剂、聚醚表面活性剂、聚醚消泡剂，将上述质量百分比物料依次投入混合、搅拌均匀，制得油料，对油料进行过滤得到防刮超哑油；
将哑油导入到涂布装置上，对产品进行涂布。
本发明的有益效果为：
本防刮超哑油具有超低光泽度和良好的透明度，耐摩擦性能优良，低粘着力、静电吸附自动不留气泡且容易撕下，并有超高透光率的光学效果，可呈现96％以上的原有色彩，表面硬度达到0.1～1H，耐折性、耐水性好，无论正折90°或180°、反折90°或180°，压线均不会爆线，水在表面不会渗透过纸，还可凹凸烫金、局部UV成logo，耐候性能佳，防潮、防湿、防高温，适应高温达58℃、湿度为85％～95％的环境，适用于彩盒、纸箱、烟包、卡盒、电子包装等印刷品上光使用，同时还具有优异的润湿流平性能，干燥速度适中，涂布有本防刮超哑油的产品还可回收利用，环保性强；通过涂布装置的上下辊结构，传动方向和速度方面方便调节控制，并采用反向速比传动，在涂布过程中稳定可靠，涂布精度高，进一步提高加工的便利性，本发明工艺简单，容易操作，可用水或酒精直接稀释，环保性强。
具体实施方式
下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述。
实施例一：
一种防刮超哑油，由以下质量百分比的原料组成：
去离子水46％、水性聚氨酯共聚物35％、水溶性丙烯酸树脂5％、哑光助剂2％、水性助剂5％、防腐剂0.1％、水性聚酯3％、抗刮剂2％、耐水剂1％、表面活性剂0.8％、消泡剂0.1％。
其中哑光助剂为气相二氧化硅，水性助剂为聚醚，表面活性剂为聚醚表面活性剂，消泡剂设置为聚醚消泡剂，防腐剂为质量比为3：1的5-氯-2-甲基-4-异噻唑啉-3-酮与2-甲基-4-异噻唑啉-3-酮的复配物，抗刮剂为有机硅，耐水剂为石蜡。
按质量百分比称取去离子水、水性聚氨酯共聚物、水溶性丙烯酸树脂、气相二氧化硅、水性助剂、防腐剂、水性聚酯、抗刮剂、耐水剂、聚醚表面活性剂、聚醚消泡剂，将上述质量百分比物料依次投入混合、搅拌均匀，制得油料，对油料进行过滤得到防刮超哑油；
将哑油导入到涂布装置上，对产品进行涂布。通过涂布装置的上下辊结构，传动方向和速度方面方便调节控制，并采用反向速比传动，在涂布过程中稳定可靠，涂布精度高，进一步提高加工的便利性。
实施例二：
一种防刮超哑油，其特征在于，由以下质量百分比的原料组成：
去离子水55％、水性聚氨酯共聚物25％、水溶性丙烯酸树脂6％、哑光助剂2％、水性助剂5％、防腐剂0.1％、水性聚酯3％、抗刮剂2％、耐水剂1.1％、表面活性剂0.7％、消泡剂0.1％。
其中哑光助剂为气相二氧化硅，水性助剂为聚醚，表面活性剂为聚醚表面活性剂，消泡剂设置为聚醚消泡剂，防腐剂为质量比为3：1的5-氯-2-甲基-4-异噻唑啉-3-酮与2-甲基-4-异噻唑啉-3-酮的复配物，抗刮剂为有机硅，耐水剂为石蜡。
按质量百分比称取去离子水、水性聚氨酯共聚物、水溶性丙烯酸树脂、气相二氧化硅、水性助剂、防腐剂、水性聚酯、抗刮剂、耐水剂、聚醚表面活性剂、聚醚消泡剂，将上述质量百分比物料依次投入混合、搅拌均匀，制得油料，对油料进行过滤得到防刮超哑油；
将哑油导入到涂布装置上，对产品进行涂布。通过涂布装置的上下辊结构，传动方向和速度方面方便调节控制，并采用反向速比传动，在涂布过程中稳定可靠，涂布精度高，进一步提高加工的便利性。
本防刮超哑油的pH值为7～9，固含量为28±2％，粘度(4#，秒)为80～120s，光泽度(4～7°)为5～15，耐磨性(纸对面)在4磅压力下往返磨400～1000次无掉色，在温度50℃、湿度80％、压强1.033Kg/平方厘米条件下，存放24小时并置于室温2小时，抗粘连性(面对面)无粘花现象，本发明具有优良的耐摩擦性能、超低光泽度、优异的润湿流平性能、低粘着力等优点。
本防刮超哑油具有超低光泽度和良好的透明度，耐摩擦性能优良，低粘着力、静电吸附自动不留气泡且容易撕下，并有超高透光率的光学效果，可呈现96％以上的原有色彩，表面硬度达到0.1～1H，耐折性、耐水性好，无论正折90°或180°、反折90°或180°，压线均不会爆线，水在表面不会渗透过纸，还可凹凸烫金、局部UV成logo，耐候性能佳，防潮、防湿、防高温，适应高温达58℃、湿度为85％～95％的环境，适用于彩盒、纸箱、烟包、卡盒、电子包装等印刷品上光使用，同时还具有优异的润湿流平性能，干燥速度适中，涂布有本防刮超哑油的产品还可回收利用，环保性强；通过涂布装置的上下辊结构，传动方向和速度方面方便调节控制，并采用反向速比传动，在涂布过程中稳定可靠，涂布精度高，进一步提高加工的便利性，本发明工艺简单，容易操作，可用水或酒精直接稀释，环保性强。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对本发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。因此，本发明专利的保护范围应以所附权利要求为准。
Claims (10)
1.一种防刮超哑油，其特征在于，由以下质量百分比的原料组成：
2.根据权利要求1所述的防刮超哑油，其特征在于，所述哑光助剂为气相二氧化硅。
3.根据权利要求1所述的防刮超哑油，其特征在于，所述水性助剂为聚醚。
4.根据权利要求1所述的防刮超哑油，其特征在于，所述表面活性剂为聚醚表面活性剂。
5.根据权利要求1所述的防刮超哑油，其特征在于，所述消泡剂设置为聚醚消泡剂。
6.根据权利要求1所述的防刮超哑油，其特征在于，所述防腐剂为5-氯-2-甲基-4-异噻唑啉-3-酮与2-甲基-4-异噻唑啉-3-酮的复配物。
7.根据权利要求6所述的防刮超哑油，其特征在于，所述5-氯-2-甲基-4-异噻唑啉-3-酮与2-甲基-4-异噻唑啉-3-酮的质量比为3：1。
8.根据权利要求1所述的防刮超哑油，其特征在于，所述抗刮剂为有机硅。
9.根据权利要求1所述的防刮超哑油，其特征在于，所述耐水剂为石蜡。
10.一种如权利要求1-9任一项所述的防刮超哑油的应用工艺，其特征在于，包括以下步骤：
按质量百分比称取去离子水、水性聚氨酯共聚物、水溶性丙烯酸树脂、气相二氧化硅、水性助剂、防腐剂、水性聚酯、抗刮剂、耐水剂、聚醚表面活性剂、聚醚消泡剂，将上述质量百分比物料依次投入混合、搅拌均匀，制得油料，对油料进行过滤得到防刮超哑油；
将哑油导入到涂布装置上，对产品进行涂布。
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