CN114030246A - High-strength high-firmness color stone tile and production process thereof - Google Patents

High-strength high-firmness color stone tile and production process thereof Download PDF

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Publication number
CN114030246A
CN114030246A CN202111291698.3A CN202111291698A CN114030246A CN 114030246 A CN114030246 A CN 114030246A CN 202111291698 A CN202111291698 A CN 202111291698A CN 114030246 A CN114030246 A CN 114030246A
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layer
parts
aluminum
stone tile
zinc
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CN202111291698.3A
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Chinese (zh)
Inventor
胡庆平
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Zhejiang Jianzhan Technology Co ltd
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Zhejiang Jianzhan Technology Co ltd
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Priority to CN202111291698.3A priority Critical patent/CN114030246A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/18—Layered products comprising a layer of metal comprising iron or steel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/164—Drying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36—Elongated material
    • C23C2/40—Plates; Strips
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D1/00—Roof covering by making use of tiles, slates, shingles, or other small roofing elements
    • E04D1/28—Roofing elements comprising two or more layers, e.g. for insulation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/243—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/06—Coating on the layer surface on metal layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/28—Multiple coating on one surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/406—Bright, glossy, shiny surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/73—Hydrophobic

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Wood Science & Technology (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
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  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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Abstract

The invention relates to the technical field of production and processing of colored stone tiles, and discloses a high-strength high-firmness colored stone tile and a production process thereof, wherein 100 parts of ethylene glycol butyl ether acetate and 220 parts of heavy aromatic warp-150 are added into a coating formula in the invention, so that the formation of an acrylic resin coating is facilitated, 10 parts of styrene is added, the hardness of the coating is facilitated to be improved, the impact resistance of the colored stone tile can be indirectly improved, 6 parts of 2-hydroxyethyl methacrylate and 6 parts of vinyl trimethoxy silane are added, the adsorption force of the coating is facilitated to be improved, 5 parts of lower alkyl ester of methacrylic acid is added, the pollution resistance of the coating is facilitated to be improved, 15 parts of lauryl methacrylate is added, the water resistance of the coating is facilitated to be improved, the water resistance of the colored stone tile can be indirectly improved, and the colored stone tile is more durable, by adding 10 parts of n-butyl acrylate, the gloss retention of the coating can be improved, so that the color stone tile can keep certain gloss when in use.

Description

High-strength high-firmness color stone tile and production process thereof
Technical Field
The invention relates to the technical field of production and processing of colored stone tiles, in particular to a high-strength high-firmness colored stone tile and a production process thereof.
Background
Due to the rapid development of society, the pursuit of people for living matters is also improved correspondingly, for example, common residential buildings in our lives, the pursuit of people for the pursuit is not simple and can live in, but rather the pursuit of certain comfort and safety, under the background, more and more novel building materials are gradually appeared in the sight of people, for example, a novel material such as a color stone tile is one of hot door materials of the current novel building materials;
the color stone tile is named as color stone metal tile, which is produced by adopting high and new technology, the aluminum-zinc plated steel plate with excellent corrosion resistance is used as a substrate, the water-based acrylate is used as a bonding agent, the sintered color sand is used as a surface layer, and the acrylic resin with extremely strong weather resistance is used as a novel high-grade roofing material of an outermost surface layer (equivalent to paint).
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides a high-strength high-firmness encaustic stone tile and a production process thereof.
In order to achieve the purpose, the invention provides the following technical scheme: the utility model provides a various stone tile of high strength high fastness, includes various stone tile mechanism, various stone tile mechanism still includes the steel base layer, the bottom fixedly connected with second aluminized zinc layer of steel base layer, the outer wall on second aluminized zinc layer is equipped with the heat insulating layer, the first aluminized zinc layer of top fixedly connected with of steel base layer, the outer wall on first aluminized zinc layer is equipped with the acrylic acid bond line, the outer wall on acrylic acid bond line is equipped with various stone layer, the outer wall on various stone layer is equipped with the acrylic acid glazing layer, the outer wall on acrylic acid glazing layer is equipped with water-fast layer.
In a preferred embodiment, the first and second alnico layers are coated with an organic resin and colloidal silica to the inside of the passivation solution during the galvanization.
In a preferred embodiment, the water-resistant layer is made of water-resistant and impact-resistant glue, and after the water-resistant layer is coated, hot air is used for drying, and the temperature of the hot air needs to be controlled between 45 and 65 degrees, so that the drying of the glue is facilitated.
In a preferred embodiment, the heat-insulating layer is formed by coating heat-insulating and heat-preserving paint.
A production process of a high-strength high-firmness color stone tile comprises the following operation steps:
the production process of the acrylic resin coating comprises the following steps: firstly, 100 parts of ethylene glycol butyl ether acetate and 220 parts of aromatic amine-150 are added into a reaction kettle, heating is carried out manually for a certain time, then 10 parts of styrene, 12 parts of acrylic alcohol, 6 parts of 2-hydroxyethyl methacrylate, 6 parts of vinyl trimethoxy silane, 5 parts of lower alkyl methacrylate, 15 parts of lauryl methacrylate, 10 parts of n-butyl acrylate and 16 parts of itaconic acid are sequentially added into the reaction kettle manually, heating is carried out for a certain time, and after heating is finished, cooling is carried out for a certain time to obtain the acrylic resin coating.
Processing the color stone tiles:
a. cutting the steel plate and the aluminum-zinc plated plate to obtain a first aluminum-zinc plated layer, a second aluminum-zinc plated layer and a steel base layer with corresponding sizes;
b. the first aluminum-zinc-plated layer, the steel base layer and the second aluminum-zinc-plated layer are fixedly connected in sequence by manpower;
c. after the fixed connection, manually smearing acrylic resin paint on the surface of one side of the first aluminum-zinc plated layer;
d. after the acrylic resin coating is coated, manually spraying a layer of colored sand on the surface of the acrylic adhesive layer to form a colored stone layer, and manually drying the colored sand after the colored sand is sprayed;
e. after the drying is finished, manually coating a layer of acrylic resin coating on the surface of the fixed color stone layer to form an acrylic glazing layer, and manually drying after the coating is finished;
f. after the drying is finished, manually smearing water-resistant and impact-resistant glue on the surface of the acrylic acid glazing layer to form a water-resistant layer, manually smearing a heat-insulating and heat-preserving coating on the surface of the second aluminum-zinc-plated layer to form a heat-insulating layer, and after the water-resistant layer and the heat-insulating layer are smeared, drying for a certain time is required to finish the manufacturing of the colored stone tile.
In a preferred embodiment, in the step d, the drying temperature is 80-200 ℃, and the drying time is 12-14 minutes.
In a preferred embodiment, in the step e, the drying temperature is 80-200 ℃, and the drying time is 11-13 minutes.
In a preferred embodiment, the temperature for drying in the f step is 80-200 ℃, and the drying time is 14-16 minutes.
In a preferred embodiment, the modulus of fineness of the colored sand is 3.6 to 2.3.
The invention has the technical effects and advantages that:
1. the coating formula of the invention is favorable for forming acrylic resin coating by adding 100 parts of ethylene glycol butyl ether acetate and 220 parts of aromatic amine-150, is favorable for improving the hardness of the coating by adding 10 parts of styrene, can indirectly improve the impact resistance of the color stone tile, is favorable for improving the flexibility of the outer wall of the coating by adding 12 parts of acrylic alcohol, is favorable for improving the adsorption force of the coating by adding 6 parts of 2-hydroxyethyl methacrylate and 6 parts of vinyl trimethoxy silane, is favorable for improving the pollution resistance of the coating by adding 5 parts of lower alkyl ester of methacrylic acid, is favorable for improving the water resistance of the coating by adding 15 parts of lauryl methacrylate, can indirectly improve the water resistance of the color stone tile, and is more durable by adding 10 parts of n-butyl acrylate, the gloss retention of the coating can be improved, so that when the color stone tile is used, a certain gloss can be maintained, and the adsorption force and the water solubility of the coating can be improved to a certain extent by adding 16 parts of itaconic acid;
2. according to the invention, when galvanization is carried out, organic resin and colloidal silica are added into the passivation solution, so that a composite coating with corrosion resistance and fingerprint resistance is formed on the surfaces of the first aluminized zinc layer and the second aluminized zinc layer, the first aluminized zinc layer and the second aluminized zinc layer have the characteristics of smooth and flat surfaces, small tolerance and the like, the water-resistant layer is arranged, the color stone tile has stronger water resistance and impact resistance, the service life of the color stone tile is prolonged, and the heat-insulating layer is arranged, so that the building room has a certain heat-insulating effect.
Drawings
Fig. 1 is an exploded view of the overall structure of the present invention.
The reference signs are: 1. a color stone tile mechanism; 101. a water-resistant layer; 102. an acrylic glazing layer; 103. a color stone layer; 104. an acrylic adhesive layer; 105. a first aluminum-zinc plated layer; 106. a steel substrate; 107. a second aluminum-zinc plated layer; 108. a thermal insulation layer.
Detailed Description
The technical solution of the present invention will be clearly and completely described below with reference to the accompanying drawings of the present invention, and the forms of the structures described in the following embodiments are merely examples, and the high-strength and high-firmness encaustic stone tile and the production process thereof according to the present invention are not limited to the structures described in the following embodiments, and all other embodiments obtained by a person of ordinary skill in the art without creative efforts belong to the protection scope of the present invention.
The invention provides a high-strength high-firmness colored stone tile, which comprises a colored stone tile mechanism 1, wherein the colored stone tile mechanism 1 further comprises a steel base layer 106, the bottom end of the steel base layer 106 is fixedly connected with a second aluminum-zinc plated layer 107, the outer wall of the second aluminum-zinc plated layer 107 is provided with a heat insulation layer 108, the top end of the steel base layer 106 is fixedly connected with a first aluminum-zinc plated layer 105, the outer wall of the first aluminum-zinc plated layer 105 is provided with an acrylic acid bonding layer 104, the outer wall of the acrylic acid bonding layer 104 is provided with a colored stone layer 103, the outer wall of the colored stone layer 103 is provided with an acrylic acid glazing layer 102, and the outer wall of the acrylic acid glazing layer 102 is provided with a water-resistant layer 101.
Furthermore, the organic resin and the colloidal silica are required to be added into the passivation solution of the first aluminum zinc plating layer 105 and the second aluminum zinc plating layer 107 during the galvanization, and the organic resin and the colloidal silica are added into the passivation solution during the galvanization, so that a composite coating with corrosion resistance and fingerprint resistance is favorably formed on the surfaces of the first aluminum zinc plating layer 105 and the second aluminum zinc plating layer 107, and the first aluminum zinc plating layer 105 and the second aluminum zinc plating layer 107 can have the characteristics of smooth and flat surfaces, small tolerance and the like.
Furthermore, the water-resistant layer 101 is made of water-resistant and impact-resistant glue, hot air is required to be used for drying after the water-resistant layer 101 is coated, the temperature of the hot air is required to be controlled to be 45-65 ℃, the drying of the glue is facilitated, the water-resistant layer 101 is arranged, the color stone tile is facilitated to have stronger water resistance and impact resistance, and the service life of the color stone tile is prolonged.
Further, the heat insulation layer 108 is formed by smearing heat insulation paint, and the heat insulation layer 108 is arranged, so that the building room has a certain heat insulation effect.
Furthermore, in the step d, the drying temperature is 80-200 ℃, and the drying time is 12-14 minutes.
Furthermore, in the step e, the drying temperature is 80-200 ℃, and the drying time is 11-13 minutes.
Furthermore, in the step f, the drying temperature is 80-200 ℃, and the drying time is 14-16 minutes.
Furthermore, the fineness modulus of the colored sand is 3.6-2.3.
The working principle is as follows:
the production process of the acrylic resin coating comprises the following steps: firstly, 100 parts of ethylene glycol butyl ether acetate and 220 parts of aromatic amine-150 are added into a reaction kettle, heating is carried out manually for a certain time, then 10 parts of styrene, 12 parts of acrylic alcohol, 6 parts of 2-hydroxyethyl methacrylate, 6 parts of vinyl trimethoxy silane, 5 parts of lower alkyl methacrylate, 15 parts of lauryl methacrylate, 10 parts of n-butyl acrylate and 16 parts of itaconic acid are sequentially added into the reaction kettle manually, heating is carried out for a certain time, and after heating is finished, cooling is carried out for a certain time to obtain the acrylic resin coating.
Processing the color stone tiles:
a. cutting the steel plate and the aluminum-plated zinc plate to obtain a first aluminum-plated zinc layer 105, a second aluminum-plated zinc layer 107 and a steel base layer 106 with corresponding sizes;
b. the first aluminum-zinc plated layer 105, the steel base layer 106 and the second aluminum-zinc plated layer 107 are sequentially fixedly connected through manual work;
c. after the fixed connection, coating acrylic resin paint on the surface of one side of the first aluminum-zinc plated layer 105 by manpower;
d. after the acrylic resin coating is coated, manually spraying a layer of colored sand on the surface of the acrylic adhesive layer 104 to form a colored stone layer 103, and manually drying the colored sand after the colored sand is sprayed;
e. after the drying is finished, manually coating a layer of acrylic resin coating on the surface of the fixed color stone layer 103 to form an acrylic glazing layer 102, and after the coating is finished, manually drying;
f. after the drying is finished, water-resistant and impact-resistant glue is manually coated on the surface of the acrylic glazing layer 102 to form a water-resistant layer 101, meanwhile, a thermal insulation coating is manually coated on the surface of the second aluminum-zinc plating layer 107 to form a thermal insulation layer 108, and after the water-resistant layer 101 and the thermal insulation layer 108 are coated, the color stone tile is dried for a certain time to finish the manufacturing of the color stone tile.
The points to be finally explained are: first, in the description of the present application, it should be noted that, unless otherwise specified and limited, the terms "mounted," "connected," and "connected" should be understood broadly, and may be a mechanical connection or an electrical connection, or a communication between two elements, and may be a direct connection, and "upper," "lower," "left," and "right" are only used to indicate a relative positional relationship, and when the absolute position of the object to be described is changed, the relative positional relationship may be changed;
secondly, the method comprises the following steps: in the drawings of the disclosed embodiments of the invention, only the structures related to the disclosed embodiments are referred to, other structures can refer to common designs, and the same embodiment and different embodiments of the invention can be combined with each other without conflict;
and finally: the above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that are within the spirit and principle of the present invention are intended to be included in the scope of the present invention.

Claims (9)

1. The utility model provides a various stone tile of high strength high fastness, includes various stone tile mechanism (1), its characterized in that: the colored stone tile mechanism (1) further comprises a steel base layer (106), a second aluminum-zinc-plated layer (107) is fixedly connected to the bottom end of the steel base layer (106), a heat insulation layer (108) is arranged on the outer wall of the second aluminum-zinc-plated layer (107), a first aluminum-zinc-plated layer (105) is fixedly connected to the top end of the steel base layer (106), an acrylic acid bonding layer (104) is arranged on the outer wall of the first aluminum-zinc-plated layer (105), a colored stone layer (103) is arranged on the outer wall of the acrylic acid bonding layer (104), an acrylic acid glazing layer (102) is arranged on the outer wall of the colored stone layer (103), and a water-resistant layer (101) is arranged on the outer wall of the acrylic acid glazing layer (102).
2. The high strength, high firmness, stained stone tile of claim 1 wherein: the first aluminum zinc plating layer (105) and the second aluminum zinc plating layer (107) need to add organic resin and colloidal silica into the passivation solution during the zinc plating.
3. The high strength, high firmness, stained stone tile of claim 1 wherein: the water-resistant layer (101) is made of water-resistant and impact-resistant glue by smearing.
4. The high strength, high firmness, stained stone tile of claim 1 wherein: the heat insulation layer (108) is formed by smearing heat insulation paint.
5. The production process of the high-strength high-firmness color stone tile is characterized by comprising the following operation steps of:
the production process of the acrylic resin coating comprises the following steps: firstly, 100 parts of ethylene glycol butyl ether acetate and 220 parts of aromatic amine warp-150 are added into a reaction kettle, the mixture is manually heated for a certain time, then 10 parts of styrene, 12 parts of acrylic alcohol, 6 parts of 2-hydroxyethyl methacrylate, 6 parts of vinyl trimethoxy silane, 5 parts of lower alkyl methacrylate, 15 parts of lauryl methacrylate, 10 parts of n-butyl acrylate and 16 parts of itaconic acid are manually added into the reaction kettle in sequence, the heating is carried out for a certain time, and after the heating is finished, the temperature is reduced for a certain time to obtain the acrylic resin coating;
processing the color stone tiles:
a. cutting the steel plate and the aluminum-plated zinc plate to obtain a first aluminum-plated zinc layer (105), a second aluminum-plated zinc layer (107) and a steel base layer (106) with corresponding sizes;
b. the first aluminum-zinc plating layer (105), the steel base layer (106) and the second aluminum-zinc plating layer (107) are sequentially and fixedly connected through manual work;
c. after the fixed connection, manually smearing acrylic resin paint on the surface of one side of the first aluminum-zinc plating layer (105) of the first aluminum-zinc plating layer;
d. after the acrylic resin coating is coated, manually spraying a layer of colored sand on the surface of the acrylic bonding layer (104) to form a colored stone layer (103), and manually drying the colored sand after the colored sand is sprayed;
e. after the drying is finished, manually coating a layer of acrylic resin coating on the surface of the fixed color stone layer (103) to form an acrylic glazing layer (102), and after the coating is finished, manually drying;
f. after the drying is finished, water-resistant and impact-resistant glue is manually coated on the surface of the acrylic glazing layer (102) to form a water-resistant layer (101), meanwhile, a thermal insulation coating is manually coated on the surface of the second aluminum-zinc plated layer (107) to form a thermal insulation layer (108), and after the water-resistant layer (101) and the thermal insulation layer (108) are coated, the color stone tile is dried for a certain time to finish the manufacturing of the color stone tile.
6. The process for producing high strength and high firmness stained stone tile according to claim 5, wherein: and d, drying at the temperature of 80-200 ℃ for 12-14 minutes.
7. The process for producing high strength and high firmness stained stone tile according to claim 5, wherein: and e, drying at 80-200 ℃ for 11-13 minutes.
8. The process for producing high strength and high firmness stained stone tile according to claim 5, wherein: and in the step f, the drying temperature is 80-200 ℃, and the drying time is 14-16 minutes.
9. The process for producing high strength and high firmness stained stone tile according to claim 5, wherein: the fineness modulus of the colored sand is 3.6-2.3.
CN202111291698.3A 2021-11-03 2021-11-03 High-strength high-firmness color stone tile and production process thereof Pending CN114030246A (en)

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Citations (8)

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Publication number Priority date Publication date Assignee Title
JP2001089695A (en) * 1999-09-24 2001-04-03 Nisshin Steel Co Ltd Acrylic sol coating, coating method and coated article
CN101629288A (en) * 2009-08-21 2010-01-20 攀枝花新钢钒股份有限公司 Passivation treating agent for hot-dip aluminum zinc plate and preparation method thereof
CN203145335U (en) * 2013-04-11 2013-08-21 广州锘安建材有限公司 Metal tile
CN103967222A (en) * 2014-05-21 2014-08-06 宿迁金倍尔建筑材料有限公司 Waterproof heat-preservation composite material with self-adhesive layer
CN205777130U (en) * 2016-05-30 2016-12-07 徐雄飞 A kind of accumulating type color steel tile
CN108864359A (en) * 2018-08-06 2018-11-23 江西省科学院应用化学研究所 A kind of preparation method of high performance water-soluble high solid low viscosity acrylic resin
CN109796555A (en) * 2019-01-08 2019-05-24 江西省科学院应用化学研究所 A kind of preparation method of high-performance water-based acrylic resin
CN111495714A (en) * 2020-05-09 2020-08-07 浙江剑占科技有限公司 Secondary sand coating process for color steel tile

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001089695A (en) * 1999-09-24 2001-04-03 Nisshin Steel Co Ltd Acrylic sol coating, coating method and coated article
CN101629288A (en) * 2009-08-21 2010-01-20 攀枝花新钢钒股份有限公司 Passivation treating agent for hot-dip aluminum zinc plate and preparation method thereof
CN203145335U (en) * 2013-04-11 2013-08-21 广州锘安建材有限公司 Metal tile
CN103967222A (en) * 2014-05-21 2014-08-06 宿迁金倍尔建筑材料有限公司 Waterproof heat-preservation composite material with self-adhesive layer
CN205777130U (en) * 2016-05-30 2016-12-07 徐雄飞 A kind of accumulating type color steel tile
CN108864359A (en) * 2018-08-06 2018-11-23 江西省科学院应用化学研究所 A kind of preparation method of high performance water-soluble high solid low viscosity acrylic resin
CN109796555A (en) * 2019-01-08 2019-05-24 江西省科学院应用化学研究所 A kind of preparation method of high-performance water-based acrylic resin
CN111495714A (en) * 2020-05-09 2020-08-07 浙江剑占科技有限公司 Secondary sand coating process for color steel tile

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