CN113897224B - Straw briquette fuel and carbon dioxide cooperative thermal conversion method - Google Patents
Straw briquette fuel and carbon dioxide cooperative thermal conversion method Download PDFInfo
- Publication number
- CN113897224B CN113897224B CN202111264625.5A CN202111264625A CN113897224B CN 113897224 B CN113897224 B CN 113897224B CN 202111264625 A CN202111264625 A CN 202111264625A CN 113897224 B CN113897224 B CN 113897224B
- Authority
- CN
- China
- Prior art keywords
- carbon dioxide
- gasification furnace
- straw
- furnace body
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0969—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0986—Catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention belongs to the technical field of comprehensive utilization of biomass energy and carbon dioxide, and particularly relates to a method for synergistically converting straw briquette fuel and carbon dioxide through heat. Putting a nickel-based catalyst in a gasification furnace body, keeping the temperature in the gasification furnace body at 810-960 ℃, adding straw formed fuel in the gasification furnace, setting the reaction time to be 60min, and according to different reaction temperatures, not introducing carbon dioxide in 0-10 min, wherein the carbon dioxide introduced into the gasification furnace body in 5-10 min is 0.016-0.04 unit weight/min, and the carbon dioxide introduced into the gasification furnace body in 14-60 min is 0.012-0.03 unit weight/min. And after the reaction is finished, removing or leaking the slag after the reaction, adding the straw briquette again, starting timing, and carrying out the carbon dioxide introduction flow and the carbon dioxide introduction time until the reaction is finished within 60 min. The steps are circularly carried out, so that the straw briquette fuel and the carbon dioxide are cooperatively converted, high-quality combustible gas is generated, and the carbon dioxide is fixed and the carbon neutralization is promoted to be realized.
Description
Technical Field
The invention belongs to the technical field of comprehensive utilization of biomass energy and carbon dioxide, and particularly relates to a method for synergistically converting straw briquette fuel and carbon dioxide through heat.
Background
The annual crop straw yield of China is quite rich, 8-9 million tons are produced annually, except for being partially used for papermaking and livestock feed, about 3.5 million tons can be used as energy, and the annual crop straw yield is reduced by about 1.8 million tons of standard coal and is a huge resource, but the crop straw has the defects of resource dispersion, low energy density, small volume weight, inconvenient storage and transportation and the like, and the large-scale application of the crop straw is severely restricted. With the increase of income of people, commercial energy (such as coal, liquefied petroleum gas and the like) becomes main cooking energy in rural areas close to commercial energy production areas, so that crop straws utilized in the traditional mode can become replaced objects firstly, are abandoned in fields as organic solid wastes, and part of the organic solid wastes are incinerated randomly, thereby wasting precious renewable resources, seriously polluting the atmosphere and damaging the living environment of human beings. The crop straw forming fuel technology can lead the original dispersed crop straws to be compressed into the formed fuel with fixed shape and larger density without raw materials with certain shape through the processes of drying, crushing, forming and the like, saves the transportation and storage cost, expands the application range, and improves the utilization efficiency (Wangzaiwei, Reyngiu, Yueyanfeng, Yangyua, Lifeng, He in the summit, Hakking, Zhujinling. straw forming fuel system economic analysis, agricultural organization research, 2012, 34(2), 203:206. Wangzaiwei, Liangfeng, Leishu, Lijinyuli, Yangyu, Hakkaihe, biomass forming system integration and automation design renewable energy, 2011, (29) (4) 132), Wanjiawei, Changyu, Chanxia, Lejiu, Lifeng, Cifeng, Zhaofei, Yanhua, display, Wuyi, Hefeng, Haokui and Zhujinling. forming fuel forming mold, china, ZL 2015100746651). And the relevant industrial standard (the technical condition of the biomass solid briquette fuel, NY/T1878-2010) and the local standard (the basic requirement of clean utilization of the straw briquette fuel, DB 34/T3656-2020) are issued and implemented, so that the popularization and the application of the straw briquette fuel are powerfully promoted.
The gasification or pyrolysis of the straw briquette is a process of converting hydrocarbon which forms the straw briquette into combustible gas containing carbon monoxide, hydrogen and the like under certain thermodynamic conditions. The gasification of the straw-shaped fuel is generally carried out by using gases such as nitrogen, argon, helium, air, steam, etc., or a mixture of partial gases thereof, and converting the crop-shaped fuel into combustible gases such as carbon monoxide, hydrogen, methane, etc., by thermochemical reaction under high temperature conditions (Zhang Weijie, Guanhai, Jiang, Sun Feng, Xun, Yan Li, Liu, Hu safety, gasification test of the corn straw-shaped fuel in a composite fixed bed, Shandong science, 2017;30(4): 67-72.). Pyrolysis of straw briquettes generally heats straw briquettes under gas-insulated conditions to convert them into low-molecular combustible gases (Wangzagwei, Hexiaofeng, Zhaobaozhu, Baiwei, Zhujinling, Lotisu. Experimental research on biomass pyrolysis utilization system. agro-computerized research, 2009;31(3): 150-.
The straw formed fuel is different from fossil fuels such as coal and the like, contains more oxygen elements while containing carbon and hydrogen elements, so that the straw formed fuel can be subjected to oxygen-containing bond breakage when being subjected to high temperature heat to generate gas containing carbon dioxide, the oxygen elements are exhausted along with the breakage after pyrolysis lasts for a certain time, and volatile components at the time can be further broken under the conditions of atmosphere gases such as air, oxygen, water vapor and the like (Rongshui, Luzhou. In addition, the addition of the catalyst can promote the further deep cracking reaction of volatile components, hydrocarbon and other gases in the thermal conversion process of the biomass to generate combustible gas with smaller molecular weight, thereby reducing the generation of tar in the thermal conversion process, improving the gasification efficiency of straw forming fuel, improving the heat value of the combustible gas and improving the energy conversion rate (Yuyiming, Mongolian dream, field river epitaxy, ash building, beauty and economic, summer sesame aroma. the catalyst has influence on the gasification property of rice hull steam and the conversion of tar. energy engineering 2021, (4) 8-16+ 24.). The nickel-based catalyst in the catalyst has the advantages of high catalytic activity and low cost, can effectively reduce the generation of tar in the thermal conversion of biomass, but is easy to inactivate by carbon deposit and nickel sintering (Shangshang, Lanqui, Wang Yan, Zhang Juan, Qizhenhua, Lijianfen. research progress of biomass tar reforming catalyst, biomass chemical engineering 2020;54(6): 65-73.).
The efficient and reasonable utilization of carbon dioxide is an important way for reducing greenhouse gases in the atmosphere and achieving the aim of carbon neutralization. During the pyrolysis and gasification processes of the straw formed fuel, the volatile components contain long-chain hydrocarbon gas, so that the tar problem is caused, and the long-chain hydrocarbon gas becomes a main factor for preventing the efficient utilization of the straw formed fuel. But no method for the synergistic thermal conversion of straw briquette fuel and carbon dioxide under the action of a catalyst is disclosed and reported at present.
Disclosure of Invention
The invention adopts the straw briquette fuel and the carbon dioxide as raw materials, and the straw briquette fuel and the carbon dioxide are converted into high-quality combustible gas under the combined action of the nickel-based catalyst. The invention divides the pyrolysis and gasification of the crop straw formed fuel into a plurality of stages through the process of supplying carbon dioxide, ensures the cooperative conversion of the carbon dioxide and the straw formed fuel, and generates more combustible gases such as carbon monoxide, hydrogen, hydrocarbon with shorter chains and the like. In addition, the method of combining carbon dioxide and the catalyst promotes the efficient utilization of the catalyst, avoids the covering, carbon deposition and dust deposition of the catalyst in the process of thermal conversion of the raw materials, greatly prolongs the service life of the catalyst, and reduces the operation cost.
The invention provides a method for the cooperative thermal conversion of straw briquette fuel and carbon dioxide, which realizes the cooperative thermal conversion of the straw briquette fuel and the carbon dioxide, generates high-quality combustible gas and simultaneously consumes and fixes the carbon dioxide.
The raw materials utilized by the invention are straw briquette fuel and carbon dioxide, and the reasonable cracking and gasification reaction of the straw briquette fuel and the carbon dioxide is realized by controlling the input flow of the carbon dioxide along with the reaction time under the conditions of fixed reaction temperature and reasonable catalyst and straw briquette fuel ratio, so that high-quality synthesis gas is generated, and the effect of fixing the carbon dioxide is achieved. The invention has simple process method, gas products do not need to be separated, the carbon deposition and ash deposition of the catalyst are avoided, the heat value of combustible gas is high, the hydrogen content is high, the implementation of the invention is beneficial to the large-scale treatment and energy utilization of straw and other organic solid wastes, and the carbon neutralization is accelerated to realize.
Preferably, 1 unit weight of nickel-based catalyst is placed in the gasification furnace, and the straw briquette fuel with the mass 1-3 times that of the catalyst is placed after the reaction temperature is stable, namely the original mass ratio of the straw briquette fuel to the nickel-based catalyst is about 3: 1-1: 1.
Preferably, the temperature in the gasification furnace body is kept at 810-960 ℃, the reaction time is set to be 60min, carbon dioxide is not introduced in 0-10 min according to different reaction temperatures, the carbon dioxide introduced into the gasification furnace body in 5-10 min is 0.016-0.04 unit weight/min, the carbon dioxide introduced into the gasification furnace body in 14-60 min is 0.012-0.03 unit weight/min, and the gas in the gasification furnace body is pumped out to a gas storage device and the like through a Roots blower.
Preferably, after the first reaction is carried out for 60min, removing or leaking the slag after the reaction, and adding the straw briquette fuel 1-3 times of the weight of the catalyst again, wherein the step of introducing the carbon dioxide is the same as that of the first reaction for 60min, and the subsequent reaction is carried out circularly, so that the synergistic thermal conversion of the straw briquette fuel and the carbon dioxide is realized, high-quality combustible gas is generated, and the carbon dioxide is fixed.
In a preferred embodiment, the above complete reaction can be performed in a cycle of 2 times or more, or 3 times or more, 4 times or more, 5 times or more, or 6 times or more, such as 8 times, to realize the co-transformation of the straw-formed fuel and the carbon dioxide, and to generate high-quality combustible gas while fixing the carbon dioxide.
The principle of the invention is as follows: under a certain temperature, certain carbon dioxide can be generated by the initial cracking of the straw formed fuel, certain combustible gases such as carbon monoxide, hydrogen and long-chain hydrocarbon are generated by the reaction of volatile components generated after cracking for a certain time with the carbon dioxide, and then the long-chain hydrocarbon components are subjected to deep catalytic cracking under the action of a nickel-based catalyst to generate more gases such as hydrogen and short-chain hydrocarbon, so that the gasification efficiency of the straw formed fuel is improved, and the carbon dioxide is fixedly utilized.
The invention adopts the straw briquette fuel and the carbon dioxide as raw materials, and prepares the high-quality combustible gas by the straw briquette fuel and the carbon dioxide under the combined action of the nickel-based catalyst. Compared with the prior reports, the invention has the advantages that: the adopted nickel-based catalyst has low cost and high catalytic activity, and simultaneously combines with the participation of carbon dioxide, the nickel-based catalyst avoids being covered, deposited carbon and deposited dust, the service life of the catalyst is greatly prolonged, and the operation cost is reduced; meanwhile, under the condition of reasonable time planning, the carbon dioxide can fully react with the pyrolysis gas of the straw formed fuel, so that the carbon dioxide is fixed, and more combustible gas is generated. However, in the prior art, no report related to a catalytic synergistic thermal conversion method of straw briquette fuel and carbon dioxide is found.
Detailed Description
The technical solution of the present invention is illustrated by the following specific examples, but the scope of the present invention is not limited thereto:
the reaction temperatures selected in examples 1-4 were 810 ℃, 860 ℃, 910 ℃ and 960 ℃, respectively, and the straw briquette fuels selected were corn straw briquette fuels, respectively.
Example 1:
a nickel-based catalyst (Ni/Al) is arranged in a biomass gasification furnace (adopting a common biomass gasification furnace on the market)2O3) The weight of the biomass gasification furnace is 1 unit weight (100 kg), the temperature in the gasification furnace is kept at 810 ℃, corn straw molding fuel with the weight 2 times that of the catalyst (200 kg) is added, the reaction time is set to be 60min, wherein carbon dioxide is not introduced in 0-10 min, the carbon dioxide introduced into the gasification furnace is 0.016 unit weight/min in 11-20 min, the carbon dioxide introduced into the gasification furnace is 0.012 unit weight/min in 21-60 min, and the gas in the gasification furnace is pumped out to a gas storage device and the like through a Roots blower. And after 60min, removing or leaking the reacted furnace slag, adding the corn straw briquette fuel with the weight 1-3 times that of the catalyst again, starting timing, and introducing the carbon dioxide according to the flow and time until 60 min. The steps are circularly carried out.
Example 2:
a nickel-based catalyst (Ni/Al) is arranged in a biomass gasification furnace body (adopting a common biomass gasification furnace on the market)2O3) The weight of the biomass is 1 unit weight (100 kg), the temperature in the gasification furnace body is kept at 860 ℃, corn straw molding fuel (200 kg) which is 2 times of the weight of the catalyst is added, the reaction time is set to be 60min, wherein carbon dioxide is not introduced in 0-8 min, the carbon dioxide introduced in the gasification furnace body is 0.022 unit weight/min in 9-18 min, the carbon dioxide introduced in the gasification furnace body is 0.017 unit weight/min in 19-60 min, and the gas in the gasification furnace body is pumped out to a gas storage device and the like through a Roots blower. And after 60min, removing or leaking the reacted furnace slag, adding the corn straw briquette fuel with the weight being 1-3 times that of the catalyst again, starting timing, and introducing the carbon dioxide according to the flow and time until 60 min. The steps are circularly carried out.
Example 3:
a nickel-based catalyst (Ni/Al) is arranged in a biomass gasification furnace body (adopting a common biomass gasification furnace on the market)2O3) The weight of the biomass is 1 unit weight (100 kg), the temperature in the gasification furnace body is kept at 910 ℃, corn straw molding fuel (200 kg) which is 2 times of the weight of the catalyst is added, the reaction time is set to be 60min, wherein carbon dioxide is not introduced in 0-6 min, the carbon dioxide introduced into the gasification furnace body in 7-16 min is 0.031 unit weight/min, the carbon dioxide introduced into the gasification furnace body in 17-60 min is 0.023 unit weight/min, and the gas in the gasification furnace body is pumped out to a gas storage device and the like through a Roots blower. And after 60min, removing or leaking the reacted furnace slag, adding the corn straw briquette fuel with the weight 1-3 times that of the catalyst again, starting timing, and introducing the carbon dioxide according to the flow and time until 60 min. The steps are circularly carried out.
Example 4:
a nickel-based catalyst (Ni/Al) is arranged in a biomass gasification furnace body (adopting a common biomass gasification furnace on the market)2O3) The weight of the biomass is 1 unit weight (100 kg), the temperature in the gasification furnace body is kept at 960 ℃, corn straw molding fuel (200 kg) which is 2 times of the weight of the catalyst is added, the reaction time is set to be 60min, wherein carbon dioxide is not introduced in 0-4 min, the carbon dioxide introduced into the gasification furnace body is 0.040 unit weight/min in 5-13 min, the carbon dioxide introduced into the gasification furnace body is 0.030 unit weight/min in 14-60 min, and the gas in the gasification furnace body is pumped out to a gas storage device and the like through a Roots blower. And after 60min, removing or leaking the reacted furnace slag, adding the corn straw briquette fuel with the weight 1-3 times that of the catalyst again, starting timing, and introducing the carbon dioxide according to the flow and time until 60 min. The steps are circularly carried out.
Table 1 shows the amount of combustible gas components and the amount of carbon dioxide consumed in example 1 to 4 within 60min of a reaction time:
TABLE 1 combustible gas component yield and ratio of carbon dioxide fixation to 1 unit weight of corn stalk briquette
| Item | Example 1 | Example 2 | Example 3 | Example 4 |
| Amount of CO produced | 0.68 | 0.93 | 1.21 | 1.83 |
| H2Amount of production | 0.011 | 0.014 | 0.019 | 0.030 |
| CH4Amount of production | 0.072 | 0.071 | 0.070 | 0.069 |
| C2～C3Amount of gas generated | 0.041 | 0.038 | 0.035 | 0.032 |
| CO2Consumption of | 0.29 | 0.55 | 0.96 | 1.27 |
As can be seen from Table 1, under the conditions of the temperature of 810 ℃, 860 ℃, 910 ℃ and 960 ℃, 1 unit weight of the corn stalk molding fuel can generate about 0.68-1.83 unit weight of carbon monoxide, about 0.011-0.030 unit weight of hydrogen, about 0.069-0.072 unit weight of methane and about 0.032-0.041 unit weight of low carbon chain hydrocarbon gas by the conversion of the corn stalk molding fuel by the method, and can fixedly consume about 0.29-1.27 unit weight of carbon dioxide.
Claims (8)
1. A method for synergistically converting straw briquette fuel and carbon dioxide is characterized in that a nickel-based catalyst and the straw briquette fuel are placed in a gasification furnace, the reaction temperature in the gasification furnace is kept at 810-960 ℃, then the reaction time is set, carbon dioxide is not introduced in 0-10 min, carbon dioxide introduced in the gasification furnace is 0.016-0.04 unit weight/min in 5-10 min, carbon dioxide is introduced in the gasification furnace for 14-60 min, 0.012-0.03 unit weight/min in 14-60 min, and gas in the gasification furnace is extracted in the process;
wherein the original mass ratio of the straw briquette fuel to the nickel-based catalyst is 3: 1-1: 1.
2. The straw briquette fuel and carbon dioxide synergistic thermal conversion method as claimed in claim 1, wherein the reaction time is set to 50min-60 min.
3. The method for the synergistic thermal conversion of straw briquette fuel and carbon dioxide as claimed in claim 1, wherein carbon dioxide is not introduced for 0-10 min, carbon dioxide is introduced into the gasification furnace body for 5-10 min at a weight/min of 0.025-0.03 unit, and carbon dioxide is introduced into the gasification furnace body for 14-60 min at a weight/min of 0.018-0.025 unit.
4. The method for the synergistic thermal conversion of straw briquette fuel and carbon dioxide as claimed in claim 2, wherein when the temperature in the gasification furnace body is maintained at 810 ℃, carbon dioxide is not introduced for 0-10 min, carbon dioxide is introduced into the gasification furnace body for 11-20 min at a weight/min of 0.016 unit, and carbon dioxide is introduced into the gasification furnace body for 21-60 min at a weight/min of 0.012 unit; when the temperature in the gasification furnace body is kept at 860 ℃, carbon dioxide is not introduced in 0-8 min, the weight/min of carbon dioxide introduced in the gasification furnace body is 0.022 unit weight/min in 9-18 min, and the weight/min of carbon dioxide introduced in the gasification furnace body is 0.017 unit weight/min in 19-60 min; when the temperature in the gasification furnace body is kept at 910 ℃, carbon dioxide is not introduced for 0-6 min, the weight of carbon dioxide introduced into the gasification furnace body is 0.031 unit weight/min for 7-16 min, and the weight of carbon dioxide introduced into the gasification furnace body is 0.023 unit weight/min for 17-60 min; when the temperature in the gasification furnace body is kept at 960 ℃, carbon dioxide is not introduced for 0-4 min, the carbon dioxide introduced into the gasification furnace body for 5-13 min is 0.040 unit weight/min, and the carbon dioxide introduced into the gasification furnace body for 14-60 min is 0.030 unit weight/min.
5. The method for thermal conversion of straw briquette fuel and carbon dioxide in coordination with one another as set forth in any one of claims 1 to 4, wherein the gas in the gasifier body is pumped out to the gas storage device by a Roots blower.
6. The method for the synergistic thermal conversion of straw briquettes fuel and carbon dioxide as claimed in claim 1, wherein the straw briquettes fuel is selected from one or more of corn straw briquettes fuel, wheat straw briquettes fuel, and rice straw briquettes fuel.
7. The method for the synergistic thermal conversion of straw briquette fuel and carbon dioxide as claimed in claim 1, wherein after the reaction is completed, the slag after the reaction is removed or leaked out, the straw briquette fuel is added again, and the reaction process is repeated until the reaction is completed.
8. The straw briquette fuel and carbon dioxide cooperative thermal conversion method according to claim 7, wherein the straw briquette fuel and carbon dioxide cooperative conversion is realized by circulating for more than 2 times, and carbon dioxide is fixed while generating high-quality combustible gas.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111264625.5A CN113897224B (en) | 2021-10-28 | 2021-10-28 | Straw briquette fuel and carbon dioxide cooperative thermal conversion method |
| PCT/CN2022/128090 WO2023072220A1 (en) | 2021-10-28 | 2022-10-27 | Method for combined thermal conversion of straw briquette fuel and carbon dioxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111264625.5A CN113897224B (en) | 2021-10-28 | 2021-10-28 | Straw briquette fuel and carbon dioxide cooperative thermal conversion method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113897224A CN113897224A (en) | 2022-01-07 |
| CN113897224B true CN113897224B (en) | 2022-07-01 |
Family
ID=79027298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111264625.5A Active CN113897224B (en) | 2021-10-28 | 2021-10-28 | Straw briquette fuel and carbon dioxide cooperative thermal conversion method |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN113897224B (en) |
| WO (1) | WO2023072220A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113897224B (en) * | 2021-10-28 | 2022-07-01 | 河南工业大学 | Straw briquette fuel and carbon dioxide cooperative thermal conversion method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105907424A (en) * | 2016-05-06 | 2016-08-31 | 河南晋煤天庆煤化工有限责任公司 | Method for gasifying anthracite by Lurgi gasifier |
| CN112812930A (en) * | 2021-02-05 | 2021-05-18 | 清华大学 | System and process for producing oxygen-containing organic matters from carbon dioxide and coal |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51111205A (en) * | 1975-03-26 | 1976-10-01 | Univ Tohoku | Method of gasification accompanied by liquid ammonia treatment of the carbonnaceous substance |
| US20090077891A1 (en) * | 2007-09-25 | 2009-03-26 | New York Energy Group | Method for producing fuel gas |
| CN104907076A (en) * | 2015-04-08 | 2015-09-16 | 宋华 | Coal carbon dioxide gasification catalyst and preparation method thereof |
| CN109233879A (en) * | 2017-07-11 | 2019-01-18 | 南京勤丰秸杆科技有限公司 | A kind of processing method of biomass straw thermal cracking |
| CN109609190B (en) * | 2018-12-14 | 2021-04-20 | 西安交通大学 | Garbage gasification and tar catalytic gasification device |
| CN112831351B (en) * | 2020-12-30 | 2021-12-28 | 西安交通大学 | Method for in-situ resource utilization of high-temperature carbon dioxide of power plant |
| CN113072981B (en) * | 2021-03-15 | 2022-05-24 | 中南大学 | Chemical chain deoxidation gasification synergistic CO for functional composite oxygen carrier2Transformation method |
| CN113897224B (en) * | 2021-10-28 | 2022-07-01 | 河南工业大学 | Straw briquette fuel and carbon dioxide cooperative thermal conversion method |
-
2021
- 2021-10-28 CN CN202111264625.5A patent/CN113897224B/en active Active
-
2022
- 2022-10-27 WO PCT/CN2022/128090 patent/WO2023072220A1/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105907424A (en) * | 2016-05-06 | 2016-08-31 | 河南晋煤天庆煤化工有限责任公司 | Method for gasifying anthracite by Lurgi gasifier |
| CN112812930A (en) * | 2021-02-05 | 2021-05-18 | 清华大学 | System and process for producing oxygen-containing organic matters from carbon dioxide and coal |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113897224A (en) | 2022-01-07 |
| WO2023072220A1 (en) | 2023-05-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102786994B (en) | Method for preparing methane-rich gas through autocatalytic gasification of biomass | |
| Udomsirichakorn et al. | Review of hydrogen-enriched gas production from steam gasification of biomass: the prospect of CaO-based chemical looping gasification | |
| WO2006113293B1 (en) | Efficient and selective conversion of carbon dioxide to methanol, dimethyl ether and derived products | |
| CN107324331A (en) | A kind of method that utilization agricultural shell discarded object prepares activated carbon from activated sludge | |
| CN111363572B (en) | Method for co-producing gas-liquid fuel, chemicals and carbon materials by catalytic pyrolysis of biomass | |
| CN102133528A (en) | Method for preparing biomass gasification tar cracking composite catalyst | |
| CN113897224B (en) | Straw briquette fuel and carbon dioxide cooperative thermal conversion method | |
| Raheem et al. | Gasification of algal residue for synthesis gas production | |
| CN109134151A (en) | A kind of fluidized bed biomass carbon prepares charcoal base organic fertilizer recycling device and method | |
| CN105623685B (en) | A kind of continuous biomass raw material In-stiu catalysis gas, charcoal coproduction method and apparatus | |
| Bansal et al. | Upgradation of biogas using combined method of alkaline water scrubbing and adsoption through carbon molecular sieve | |
| Zhang et al. | A comparative review on the progress of thermochemical hydrogen production technologies from agricultural waste | |
| CN110848665B (en) | Steam/carbon combined production process based on biomass pyrolysis gasification and combustion and application thereof | |
| CN103484163A (en) | Biomass double-mode reforming gasifying preparation method for pure synthesis gas | |
| CN107586567A (en) | A kind of reformed based on continuous carbonization, gasification cleans joint production process with the pyrolysis gas of biomass charcoal for bakeing coupling processing | |
| David et al. | Biomass-alternative renewable energy source and its conversion for hydrogen rich gas production | |
| Singh et al. | Potential of pine needle biomass as an alternative fuel to mitigate forest fire in Uttarakhand Himalayas-a review | |
| CN204824146U (en) | Marsh gas is reformed and is prepared equipment of synthetic gas | |
| CN208980605U (en) | A kind of fluidized bed biomass carbon prepares charcoal base organic fertilizer recycling device | |
| CN113881462A (en) | Organic solid waste semi-in-situ carbon fixation gasification device and application thereof | |
| Wang et al. | Nitrogen removal of ramie stalk treated by acid wastewater combined with Clostridium thermocellum and the kinetic study of pyrolysis | |
| JP2005053771A (en) | Method and system for producing hydrogen | |
| CN105111034A (en) | Method utilizing micro-algae for preparing methane in hydrothermal gasification mode | |
| AU2021101768A4 (en) | A System and a Process for Formation of a Renewable Natural Coal from Waste Output of a Cattle/Agricultural based Biogas Plant | |
| Osuolale et al. | AN OVERVIEW OF HYDROGEN FUEL FROM BIOMASS GASIFICATION-COST EFFECTIVE ENERGY FOR DEVELOPING ECONOMY |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |