CN113878957A - 一种具有抗污除臭的工作服面料 - Google Patents

一种具有抗污除臭的工作服面料 Download PDF

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CN113878957A
CN113878957A CN202111225289.3A CN202111225289A CN113878957A CN 113878957 A CN113878957 A CN 113878957A CN 202111225289 A CN202111225289 A CN 202111225289A CN 113878957 A CN113878957 A CN 113878957A
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fabric
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deodorant
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CN113878957B (zh
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吴昆明
陈岩
刘汉春
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Gaofan Zhejiang Information Technology Co Ltd
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Abstract

本发明涉及一种具有抗污除臭的工作服面料，包括基层面料、通过除臭粘接层粘接于基层面料表面的外抗污除臭层；所述除臭粘接层包括光敏胶、羊毛纤维、儿茶素和纳米二氧化钛；所述外抗污除臭层包括由海藻炭、甲壳素、儿茶素制成且表面设置有疏水纹路的网状纤维层，所述网状纤维层表面以及疏水纹路内均设置有超疏水蜡质。本发明通过在外抗污除臭层表面均设置疏水纹路以及超疏水蜡质，能够使得超疏水蜡质致密并全面的附着在网状纤维层和疏水纹路内，实现面料的抗污抗油；通过在除臭粘接层中添加光敏胶、羊毛纤维、儿茶素和纳米二氧化钛，采用紫外线光线照射时，能够实现各层之间的紧密粘接，还能够实现长效抑菌除臭。

Description

一种具有抗污除臭的工作服面料
技术领域
本发明属于工作服领域，具体涉及一种具有抗污除臭的工作服面料。
背景技术
劳保工作服是劳动者工作时穿的，可以对劳动者身体起到保护作用，分为高温工作服，防尘防油拒水工作服，防辐射服，防毒服，防静电服等。现在，在很多工作岗位中，常常会遇到很多的油污，油污不仅会污染人们的服装，而且有可能会对人们的健康和安全带来隐患。
常规的抗油拒水工作服在长时间使用时，会存在较大的气味，不具有除臭功能，特别地在夏季，气温高，人体排汗量大，细菌和异味的滋生，使得工作服气味更加让人难以忍受。
发明内容
本发明的目的就在于为了解决上述问题而提供一种具有抗污除臭的工作服面料。
本发明通过以下技术方案来实现上述目的：
一种具有抗污除臭的工作服面料，包括基层面料、通过除臭粘接层粘接于基层面料表面的外抗污除臭层；
所述除臭粘接层包括光敏胶、羊毛纤维、儿茶素和纳米二氧化钛；
所述外抗污除臭层包括由海藻炭、甲壳素、儿茶素制成且表面设置有疏水纹路的网状纤维层，所述网状纤维层表面以及疏水纹路内均设置有超疏水蜡质。
作为本发明的进一步优化方案，所述基层面料由聚酯纤维制成。
作为本发明的进一步优化方案，所述光敏胶、羊毛纤维、儿茶素和纳米二氧化钛的质量比为10：0.5-1：0.5-1：0.5-1。
作为本发明的进一步优化方案，所述海藻炭纤维、甲壳素纤维、儿茶素按重量份数计分别为20-30份、50-70份、10-20份。
作为本发明的进一步优化方案，所述超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂75-88份、二氧化硅凝胶材料2-5份、海藻炭5-10份、甲壳素纤维5-10份。
作为本发明的进一步优化方案，所述疏水纹路为防三穗苔草条纹结构。
一种具有抗污除臭的工作服面料的制备方法，包括以下步骤：
S1、采用聚酯纤维纺织得到基层面料；
S2、将氟季胺硅烷耦合剂、二氧化硅凝胶材料、海藻炭、甲壳素纤维混合，得到液体状的超疏水蜡质备用；
S3、利用湿法纺丝将混合的海藻炭纤维、甲壳素纤维、儿茶素加工成表面带有疏水纹路的网状纤维层，再喷涂超疏水蜡质至网状纤维层表面以及疏水纹路内，干燥后得到外抗污除臭层；
S4、将光敏胶、羊毛纤维、儿茶素和纳米二氧化钛混合并涂覆于基础面料表面，再将外抗污除臭层置于基础面料表面，并通过紫外线光照射，得到工作服面料。
作为本发明的进一步优化方案，步骤S1中，基层面料在纺织后采用磨毛机将其两侧表面进行磨毛处理。
作为本发明的进一步优化方案，步骤S3中，喷涂超疏水蜡质至网状纤维层表面以及疏水纹路内的方法为：先垂直于网状纤维层进行高压射流喷涂至少一次，再分别左右倾斜低压射流喷涂至少一次。
作为本发明的进一步优化方案，高压射流的超疏水蜡质的压力值大于3MPa，低压射流的超疏水蜡质的压力值介于0.5MPa-1MPa之间，倾斜角度在10-30°之间。
本发明的有益效果在于：
1)本发明通过在除臭粘接层中添加光敏胶、羊毛纤维和纳米二氧化钛，在后续采用紫外线光线照射时，羊毛纤维的毛鳞片打开，一方面能够充分抓紧磨毛后的聚酯纤维以及多孔的网状纤维层，增强粘接效果，另一方面能够充分吸收充分吸收纳米二氧化钛和儿茶素，延长纳米二氧化钛和儿茶素的抑菌时间，最后一方面纳米二氧化钛吸收紫外线能够实现光催化降解整个羽绒服中含有的有机污染物和微生物等，整个工艺简单实用；
2)本发明在外抗污除臭层表面均设置疏水纹路，采用高压射流和倾斜低压射流的方式喷涂超疏水蜡质，能够使得超疏水蜡质致密并全面的附着在网状纤维层和疏水纹路内，全面提高网状纤维层的疏水效果，实现面料的抗污抗油；
3)本发明通过在外抗污除臭层以及除臭粘接层内添加的甲壳素、儿茶素，能够起到很好的抗菌除臭效果，并且能够抗辐射和紫外线；
4)本发明甲壳素为碱性材料，与羊毛纤维接触时，也能够打开羊毛纤维毛鳞片，充分吸收光敏胶内的纳米二氧化钛和儿茶素，使得纳米二氧化钛和儿茶素不易脱落，抗菌作用时间长，也充分与磨毛的聚酯纤维以及多孔的网络纤维层内的纤维结合粘接，实现各面料层之间粘接稳定。
具体实施方式
下面对本申请作进一步详细描述，有必要在此指出的是，以下具体实施方式只用于对本申请进行进一步的说明，不能理解为对本申请保护范围的限制，该领域的技术人员可以根据上述申请内容对本申请作出一些非本质的改进和调整。
实施例1
一种具有抗污除臭的工作服面料，包括基层面料、通过除臭粘接层粘接于基层面料表面的外抗污除臭层；
所述基层面料由聚酯纤维制成；
所述除臭粘接层包括光敏胶、羊毛纤维、儿茶素和纳米二氧化钛，所述光敏胶、羊毛纤维、儿茶素和纳米二氧化钛的质量比为10：0.5：0.5：0.5；
所述外抗污除臭层包括由海藻炭、甲壳素、儿茶素制成且表面设置有疏水纹路的网状纤维层，所述网状纤维层表面以及疏水纹路内均设置有超疏水蜡质；所述海藻炭纤维、甲壳素纤维、儿茶素按重量份数计分别为20份、70份、10份；所述超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂75份、二氧化硅凝胶材料5份、海藻炭10份、甲壳素纤维10份；所述疏水纹路为防三穗苔草条纹结构。
本实施例具有抗污除臭的工作服面料的制备方法，包括以下步骤：
S1、采用聚酯纤维纺织得到基层面料，再采用磨毛机将其两侧表面进行磨毛处理，备用；
S2、将氟季胺硅烷耦合剂、二氧化硅凝胶材料、海藻炭、甲壳素纤维混合，得到液体状的超疏水蜡质备用；
S3、利用湿法纺丝将混合的海藻炭纤维、甲壳素纤维、儿茶素加工成表面带有疏水纹路的网状纤维层，再喷涂超疏水蜡质至网状纤维层表面以及疏水纹路内，干燥后得到外抗污除臭层；其中，喷涂超疏水蜡质至网状纤维层表面以及疏水纹路内的方法为：先垂直于网状纤维层进行高压射流喷涂至少一次，再分别左右倾斜低压射流喷涂至少一次，高压射流的超疏水蜡质的压力值大于3MPa，低压射流的超疏水蜡质的压力值介于0.5MPa-1MPa之间，倾斜角度在10-30°之间；
S4、将光敏胶、羊毛纤维、儿茶素和纳米二氧化钛混合并涂覆于基础面料表面，再将外抗污除臭层置于基础面料表面，并通过紫外线光照射，得到工作服面料。
将本实施例制得的工作服面料进行抗油污等测试、抗菌测试，拒油等级参考标准AATCC118-2002，耐污等级参照GB/T30159.1-2013《纺织品防污性能的检测和评价第一部分：耐沾污性》，抗菌率参照美国AATCCTestMethod100标准检测；制得的工作服面料耐油污等级在5级，大肠杆菌抑菌率高达99.3％，使用一天后无异味。
实施例2
该实施例提供一种具有抗污除臭的工作服面料及其制备方法，其工作服面料及其制备方法与实施例1基本相同，区别在于：
光敏胶、羊毛纤维、儿茶素和纳米二氧化钛的质量比为10：0.8：0.8：0.8；
海藻炭纤维、甲壳素纤维、儿茶素按重量份数计分别为25份、60份、15份；
超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂81份、二氧化硅凝胶材料4份、海藻炭7.5份、甲壳素纤维7.5份；
将本实施例制得的工作服面料进行抗油污等测试、抗菌测试，拒油等级参考标准AATCC118-2002，耐污等级参照GB/T30159.1-2013《纺织品防污性能的检测和评价第一部分：耐沾污性》，抗菌率参照美国AATCCTestMethod100标准检测；制得的工作服面料耐油污等级在6级，大肠杆菌抑菌率高达99.9％，使用一天后无异味。
实施例3
该实施例提供一种具有抗污除臭的工作服面料及其制备方法，其工作服面料及其制备方法与实施例1基本相同，区别在于：
光敏胶、羊毛纤维、儿茶素和纳米二氧化钛的质量比为10：1：1：1；
海藻炭纤维、甲壳素纤维、儿茶素按重量份数计分别为30份、50份、20份；
超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂88份、二氧化硅凝胶材料2份、海藻炭10份、甲壳素纤维10份；
将本实施例制得的工作服面料进行抗油污等测试、抗菌测试，拒油等级参考标准AATCC118-2002，耐污等级参照GB/T30159.1-2013《纺织品防污性能的检测和评价第一部分：耐沾污性》，抗菌率参照美国AATCCTestMethod100标准检测；制得的工作服面料耐油污等级在5级，大肠杆菌抑菌率高达99.4％，使用一天后无异味。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对本发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。

Claims (10)

1.一种具有抗污除臭的工作服面料，其特征在于：包括基层面料、通过除臭粘接层粘接于基层面料表面的外抗污除臭层；
所述除臭粘接层包括光敏胶、羊毛纤维、儿茶素和纳米二氧化钛；
所述外抗污除臭层包括由海藻炭、甲壳素、儿茶素制成且表面设置有疏水纹路的网状纤维层，所述网状纤维层表面以及疏水纹路内均设置有超疏水蜡质。
2.根据权利要求1所述的一种具有抗污除臭的工作服面料，其特征在于：所述基层面料由聚酯纤维制成。
3.根据权利要求1所述的一种具有抗污除臭的工作服面料，其特征在于：所述光敏胶、羊毛纤维、儿茶素和纳米二氧化钛的质量比为10：0.5-1：0.5-1：0.5-1。
4.根据权利要求1所述的一种具有抗污除臭的工作服面料，其特征在于：所述海藻炭纤维、甲壳素纤维、儿茶素按重量份数计分别为20-30份、50-70份、10-20份。
5.根据权利要求1所述的一种具有抗污除臭的工作服面料，其特征在于：所述超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂75-88份、二氧化硅凝胶材料2-5份、海藻炭5-10份、甲壳素纤维5-10份。
6.根据权利要求1所述的一种具有抗污除臭的工作服面料，其特征在于：所述疏水纹路为防三穗苔草条纹结构。
7.一种具有抗污除臭的工作服面料的制备方法，其特征在于，包括以下步骤：
S1、采用聚酯纤维纺织得到基层面料；
S2、将氟季胺硅烷耦合剂、二氧化硅凝胶材料、海藻炭、甲壳素纤维混合，得到液体状的超疏水蜡质备用；
S3、利用湿法纺丝将混合的海藻炭纤维、甲壳素纤维、儿茶素加工成表面带有疏水纹路的网状纤维层，再喷涂超疏水蜡质至网状纤维层表面以及疏水纹路内，干燥后得到外抗污除臭层；
S4、将光敏胶、羊毛纤维、儿茶素和纳米二氧化钛混合并涂覆于基础面料表面，再将外抗污除臭层置于基础面料表面，并通过紫外线光照射，得到工作服面料。
8.根据权利要求7所述的一种具有抗污除臭的工作服面料的制备方法，其特征在于：步骤S1中，基层面料在纺织后采用磨毛机将其两侧表面进行磨毛处理。
9.根据权利要求7所述的一种具有抗污除臭的工作服面料的制备方法，其特征在于：步骤S3中，喷涂超疏水蜡质至网状纤维层表面以及疏水纹路内的方法为：先垂直于网状纤维层进行高压射流喷涂至少一次，再分别左右倾斜低压射流喷涂至少一次。
10.根据权利要求9所述的一种具有抗污除臭的工作服面料的制备方法，其特征在于：高压射流的超疏水蜡质的压力值大于3MPa，低压射流的超疏水蜡质的压力值介于0.5MPa-1MPa之间，倾斜角度在10-30°之间。
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