CN113845945A - Biological blend fuel oil and application thereof - Google Patents

Biological blend fuel oil and application thereof Download PDF

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Publication number
CN113845945A
CN113845945A CN202111205079.8A CN202111205079A CN113845945A CN 113845945 A CN113845945 A CN 113845945A CN 202111205079 A CN202111205079 A CN 202111205079A CN 113845945 A CN113845945 A CN 113845945A
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fuel oil
oil
biological
bio
blended fuel
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CN202111205079.8A
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刘连军
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/28—Organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/08—Inhibitors
    • C10L2230/082—Inhibitors for anti-foaming
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention relates to the technical field of fuel oil, in particular to biological blend fuel oil and application thereof; comprises 95 to 99 portions of light white oil, 1 to 5 portions of cottonseed oil, 0.003 to 0.005 portion of defoaming agent, 0.1 to 0.3 portion of dispersing agent and 0.01 to 0.05 portion of combustion improver. The technical problems of large pollution, high burning point, low heat value, low freezing point, inconvenient use and the like of the existing civil fuel in the prior art are solved through the design of the biological blended fuel oil.

Description

Biological blend fuel oil and application thereof
Technical Field
The invention relates to the technical field of fuel oil, in particular to biological blend fuel oil and application thereof.
Background
The existing civil fuel mainly depends on coal, liquefied petroleum gas, coal gas and the like. Coal combustion produces enormous pollution and environmental deterioration, and the combustion produces by-products of various toxic substances harmful to human bodies or the environment, such as: nitrogen monoxide, nitrogen dioxide, carbon monoxide, unsaturated hydrocarbons, sulfur oxides (SO2, SO3), and the like. The poisonous substances harmful to human bodies cause people to be poisoned and syncope slightly and cause people to lose lives heavily; the environment is also a vicious circle pollution, for example, sulfides can circulate along the food chain and grow in a geometric grade finally, the environment is finally deteriorated, and various organisms are damaged.
The liquefied petroleum gas is a compressed canned gas, has strong smell and pungent taste, can affect the air of the environment, can cause death due to leakage without defence, has high ignition point, high risk factors, low combustion value and high use cost. Wind energy, solar energy, tidal energy, geothermal energy, which are gradually developed by human beings, but cannot be popularized due to instability and high use price thereof; in the biodiesel solidifying point, an oil pipeline needs to be heated in winter, so that potential safety hazards are increased, and the heat value is low.
Therefore, in view of the above problems, the present invention is urgently needed to provide a bio-blend fuel oil and its application.
Disclosure of Invention
The invention aims to provide biological blend fuel oil and application thereof, and solves the technical problems of high pollution, high ignition point, low heat value, low freezing point, inconvenience in use and the like of the existing civil fuel in the prior art through the design of the biological blend fuel oil.
The biological blend fuel oil provided by the invention comprises, by weight, 95-99 parts of light white oil, 1-5 parts of cottonseed oil, 0.003-0.005 part of defoaming agent, 0.1-0.3 part of dispersing agent and 0.01-0.05 part of combustion improver.
Preferably, the oil-free flame retardant comprises 99 parts of light white oil, 1 part of cottonseed oil, 0.003 part of defoaming agent, 0.2 part of dispersing agent and 0.03 part of combustion improver in parts by weight.
Preferably, the light white oil contains 95% of isomeric alkane with 13-14 carbon atoms and 5% of n-dodecane in parts by weight.
Preferably, the anti-foaming agent is silicone.
Preferably, the dispersant is of the type kangtai 203; the combustion improver is petroleum Kunlun 311 type.
Preferably, the heating value of the biological blended fuel oil is more than or equal to 11500 kcal/g.
Preferably, the mass percentage of the water in the bio-blending fuel oil is less than or equal to 0.1 percent.
Preferably, the flash point of the bio-blending fuel oil is 76 ℃ < flash point < 97 ℃.
Preferably, the freezing point of the bio-blending fuel oil is-63 ℃ to-50 ℃.
The invention also provides an application of the biological blending fuel oil in civil fuel based on any one of the biological blending fuel oils.
The invention also provides an application of the biological blended fuel oil.
Compared with the prior art, the biological blend fuel oil and the application thereof provided by the invention have the following advantages:
1. the biological blending fuel material is easy to obtain, nontoxic, odorless, non-corrosive and volatile, high in flash point, non-combustible, good in safety, low in nitrogen and sulfur content, low in waste gas emission amount which is one fifth of the industrial standard, and more in line with the environmental protection requirement and the national carbon neutralization strategy.
2. The biological blended fuel oil can be applied to a small boiler, a boiler and the like, so that the unified kitchen fuel is favorable for market supervision, the advantages of the fuel are complementary with those of natural gas, a safe and standard kitchen fuel market is constructed by point-surface combination, and the complementary coverage can be carried out on 'points' outside the natural gas coverage regardless of the scale.
3. The biological blended fuel oil has the advantages of higher calorific value greater than or equal to 11500 kilocalories, high flame temperature and far exceeding the traditional energy, thereby saving more energy.
Detailed Description
The technical solutions of the present invention will be described clearly and completely below, and it should be apparent that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides biological blend fuel oil which comprises, by weight, 95-99 parts of light white oil, 1-5 parts of cottonseed oil, 0.003-0.005 part of defoaming agent, 0.1-0.3 part of dispersing agent and 0.01-0.05 part of combustion improver.
Specifically, the oil comprises, by weight, 99 parts of light white oil, 1 part of cottonseed oil, 0.003 part of a defoaming agent, 0.2 part of a dispersing agent and 0.03 part of a combustion improver.
Specifically, the light white oil contains 95% of isomeric alkane with 13-14 carbon atoms and 5% of n-dodecane in parts by weight.
Specifically, the defoamer is silicone.
Specifically, the dispersant is kangtai 203 type; the combustion improver is petroleum Kunlun 311 type.
Specifically, the calorific value of the biological blended fuel oil is more than or equal to 11500 kcal/g.
Specifically, the mass percentage of the water in the biological blending fuel oil is less than or equal to 0.1 percent.
Specifically, the flash point of the biological blended fuel oil is more than 76 ℃ and less than 97 ℃.
Specifically, the freezing point of the biological blending fuel oil is-63 ℃ to-50 ℃.
The invention also provides an application of the biological blending fuel oil in civil fuel based on any one of the biological blending fuel oils.
Example one
The biological blend fuel oil (sample 1) comprises, by weight, 95 parts of light white oil, 4 parts of cottonseed oil, 0.003 part of a defoaming agent, 0.1 part of a dispersing agent and 0.01 part of a combustion improver.
The reference 1 is liquefied gas, the reference 2 is biodiesel, and the comparison of the performance of the sample 1 with the reference 1 and the reference 2 is shown in tables 1 and 2 respectively.
Example two
The biological blend fuel oil (sample 2) comprises 99 parts by weight of light white oil, 1 part by weight of cottonseed oil, 0.003 part by weight of defoaming agent, 0.2 part by weight of dispersing agent and 0.03 part by weight of combustion improver, and the performances of the sample 2 are shown in tables 1 and 2.
EXAMPLE III
A biological blended fuel oil (sample 3) comprises, by weight, 96 parts of light white oil, 3 parts of cottonseed oil, 0.003 part of a defoaming agent, 0.2 part of a dispersing agent and 0.03 part of a combustion improver, and the performances of the sample 3 are shown in tables 1 and 2.
The flame temperature of the sample 1, the sample 2 and the sample 3 is higher than that of the reference sample 1, and compared with the reference sample 1, a special steel bottle is not needed, and only a common container is needed, so that the method is safe and reduces the cost. Meanwhile, compared with a control sample 1, the flash point temperature is high, the usability is safe and reliable, and the use is not influenced at low temperature.
Compared with the control sample 2, the sample 1 has the freezing point of-50 ℃, does not need heat preservation treatment in winter, and has safe use.
TABLE 1 comparison of Bioblended Fuel oils to Fuel oils
Figure BDA0003306572660000041
Figure BDA0003306572660000051
TABLE 2 comparison of the Properties of Bioblended oils and biodiesel
Figure BDA0003306572660000052
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.

Claims (10)

1. A biological blended fuel oil is characterized in that: according to the weight portion, the oil-free environment-friendly oil comprises 95-99 portions of light white oil, 1-5 portions of cottonseed oil, 0.003-0.005 portion of defoaming agent, 0.1-0.3 portion of dispersing agent and 0.01-0.05 portion of combustion improver.
2. The bio-blended fuel oil of claim 1, wherein: the oil-free flame-retardant cotton seed oil comprises, by weight, 99 parts of light white oil, 1 part of cotton seed oil, 0.003 part of a defoaming agent, 0.2 part of a dispersing agent and 0.03 part of a combustion improver.
3. The bio-blended fuel oil of claim 1, wherein: according to the parts by weight, the light white oil contains 95% of 13-14 carbon isoparaffin and 5% of n-dodecane.
4. The bio-blended fuel oil of claim 1, wherein: the defoaming agent is organic silicon.
5. The bio-blended fuel oil of claim 1, wherein: the dispersant is Kangtai 203 type; the combustion improver is petroleum Kunlun 311 type.
6. The bio-blended fuel oil of claim 1, wherein: the calorific value of the biological blended fuel oil is more than or equal to 11500 kcal/g.
7. The bio-blended fuel oil of claim 1, wherein: the mass percentage of the water in the biological blending fuel oil is less than or equal to 0.1 percent.
8. The bio-blended fuel oil of claim 1, wherein: the flash point of the biological blended fuel oil is more than 76 ℃ and less than 97 ℃.
9. The bio-blended fuel oil of claim 1, wherein: the freezing point of the biological blending fuel oil is-63 ℃ to-50 ℃.
10. Use of a bio-blending fuel oil according to any of claims 1 to 9 in domestic fuels.
CN202111205079.8A 2021-10-15 2021-10-15 Biological blend fuel oil and application thereof Pending CN113845945A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106947548A (en) * 2017-03-29 2017-07-14 合肥天沃能源科技有限公司 A kind of energy-saving fuel oil and preparation method thereof
CN111647447A (en) * 2020-06-10 2020-09-11 河南坤清生物能源科技有限公司 Fischer-Tropsch synthesis liquid wax environment-friendly biofuel and preparation process thereof
CN113293036A (en) * 2021-05-06 2021-08-24 东奇能源技术有限公司 High-calorific-value coal-based biofuel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106947548A (en) * 2017-03-29 2017-07-14 合肥天沃能源科技有限公司 A kind of energy-saving fuel oil and preparation method thereof
CN111647447A (en) * 2020-06-10 2020-09-11 河南坤清生物能源科技有限公司 Fischer-Tropsch synthesis liquid wax environment-friendly biofuel and preparation process thereof
CN113293036A (en) * 2021-05-06 2021-08-24 东奇能源技术有限公司 High-calorific-value coal-based biofuel

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Application publication date: 20211228