CN113785833B - Mixed application method of terpinene-4 alcohol-containing biological agent and biological pesticide - Google Patents

Mixed application method of terpinene-4 alcohol-containing biological agent and biological pesticide Download PDF

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CN113785833B
CN113785833B CN202111238547.1A CN202111238547A CN113785833B CN 113785833 B CN113785833 B CN 113785833B CN 202111238547 A CN202111238547 A CN 202111238547A CN 113785833 B CN113785833 B CN 113785833B
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parts
weight
alcohol
terpinen
terpinene
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CN113785833A (en
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任启均
曹亭
杨廉勇
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Yibin Zhangzhimei Biotechnology Co ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00—Protecting plants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G22/00—Cultivation of specific crops or plants not otherwise provided for
    • A01G22/15—Leaf crops, e.g. lettuce or spinach 
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Botany (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a biological composite preparation containing terpinene-4 alcohol and a preparation method thereof, wherein the biological composite preparation comprises 0.01-100 parts by weight of terpinene-4 alcohol, 0.01-100 parts by weight of cyano group-containing phthalamide compound, 1-10 parts by weight of sodium dodecyl sulfate, 1-10 parts by weight of sodium lignin sulfonate, 1-10 parts by weight of ammonium sulfate and 1-10 parts by weight of acacia. The biological compound preparation containing terpinene-4 alcohol has a synergistic killing effect and is particularly suitable for killing cabbage plutella xylostella.

Description

Mixed application method of terpinene-4 alcohol-containing biological agent and biological pesticide
Technical Field
The invention relates to the field of agricultural application, in particular to a biological composite preparation containing terpinene-4 alcohol and a use method thereof.
Background
Cabbage (Brassica oleracea l.): is annual or biennial herbaceous plant of Brassicaceae and Brassica, and biennial herbaceous plant is frosted. Short and strong annual stem pulp, no branching, green or grayish green. The basal leaves are thick, are wrapped into spheres layer by layer, are flat-spherical, and are milky white or light green; the biennial stems are branched and have stems and leaves. The top end of the basal leaf is round, the basal part is suddenly narrowed into a leaf stem with extremely short wide wings, and the edge of the basal leaf is provided with wavy unobvious saw teeth; an upper cauliflower oval or oblong oval, with the base embracing the stems; the uppermost leaf is oblong, about 4.5 cm long, about 1 cm wide, and embraces the stem. Topgenesis and axillary growth of the overall inflorescence; flower light yellow, diameter 2-2.5 cm; the pedicel is 7-15 mm long; the sepal is upright and linear and oblong; the petals are wide in ellipse, reverse in oval shape or nearly circular, the top ends are slightly short, the base parts are narrowed to form claws, and the lengths of the claws are 5-7 mm. The silique is cylindrical, two sides are slightly flattened, the midvein is prominent, and the beak is conical; the fruit stalks are thick and are developed vertically. Seed spheres, brown. Flowering period is 4 months, and fruit period is 5 months.
In the cabbage cultivation process, the plutella xylostella is a major pest of vegetables worldwide, and is mainly harmful to cruciferous vegetables such as cabbage, broccoli, chinese cabbage, green vegetables, rape and radishes. The generation of algebra is more in the year, the hazard time is long, all the insect states of the plutella xylostella can be seen in Hua Ning county all the year round, no obvious overwintering and over-summer phenomenon exists, the low-age larvae before 2 years are drilled into mesophyll for feeding, and only the epidermis of leaves is left after feeding, so that transparent spots are formed, and the process is called as skylight opening. The 3-4-year-old larvae form scarves or holes after damaging the leaves, and form a net when serious, so that the quality of vegetables is seriously affected. The vegetable farmers are quite difficult to control, the cost is increased in control, and the quality of vegetable products is also influenced.
Cinnamomum camphora (academic name: cinnamomum longipaniculatum (Gamble) N.Chaoex H.W.Li) is a evergreen arbor of Cinnamomum genus of Lauraceae family, up to 20 m, 50 cm chest diameter; the tree bark is gray, the branches are cylindrical, no hair, the young branches are slender, the leaves are mutually grown, the oval or elliptic shape is formed, the front ends are suddenly and rapidly tapered to be long and tapered, the upper part is dark green and bright, the lower part is gray green and dark, the two sides are not hair, the leaf stalk abdomen is flat and back convex, the light green, the conical inflorescence axillary grows, the slender branches are thin and weak, each branch is 3-7 flowers of the polyparatus, the sequence shaft is not hair, the flowers are light yellow, the fragrance is provided, the flower stalks are slender, the flower quilt cylinder is in an inverted cone shape, the flower quilt is split oval, the flower silk is white and soft, the flower silk is not glandular, the anther is oblong, the ovary egg bead shape is formed, the young fruit is spherical, 5-6 months of flowering, and 7-9 months of results are achieved.
The Yibin is the original resource land of the Cinnamomum camphora, the Lin Jide mu of Cinnamomum camphora in the whole market is cut off at the end of 2018, the yield of crude Cinnamomum camphora accounts for over 70% of the whole country, the oil yield of the Yibin crude Cinnamomum camphora is high, the oil quality is good, and the Cinnamomum camphora belongs to a non-inspection product in the international market.
At present, the main methods for extracting the crude camphor oil comprise a CO2 supercritical extraction method, a steam stripping method, an extraction method and the like, and target products are extracted from the crude camphor oil by the extraction methods, wherein terpinen-4 alcohol is one of the target products.
The prior terpinen-4 alcohol is generally used as an essential oil component, and other applications have not been reported yet.
Disclosure of Invention
Based on the problems, in one aspect, the invention provides a biological composite preparation containing terpinen-4 alcohol, which has a synergistic effect of killing cabbage plutella xylostella.
A terpinen-4 alcohol-containing biocomposite formulation comprising:
terpinen-4 alcohol 0.01-100 weight parts, cyano group-containing phthalamide compound 0.01-100 weight parts, sodium dodecyl sulfate 1-10 weight parts, sodium lignin sulfonate 1-10 weight parts, ammonium sulfate 1-10 weight parts and acacia 1-10 weight parts.
In one or more specific embodiments of the present application, the terpinen-4 alcohol is 0.1-10 parts by weight, the cyano group-containing phthalamide compound is 0.1-10 parts by weight, sodium dodecyl sulfate is 4 parts by weight, sodium lignin sulfonate is 2 parts by weight, ammonium sulfate is 4 parts by weight, and acacia is 2 parts by weight.
In one or more specific embodiments of the present application, the terpinen-4 alcohol is prepared from Cinnamomum camphora.
In one or more specific embodiments of the present application, the phthalamide compound is cyhalodiamide.
In one aspect, the invention also provides a method for using the terpinen-4 alcohol-containing biological composite preparation.
The application method of the biological composite preparation containing terpinen-4 alcohol comprises the step of spraying the biological composite preparation containing terpinen-4 alcohol on plants to kill plant pests.
In one or more specific embodiments of the present application, the plant is cabbage.
In one or more specific embodiments of the present application, the plant pest is plutella xylostella.
The invention principle and beneficial effect of this application lie in:
the invention uses the cyhalodiamide and terpinen-4 alcohol as biological compound preparation, and surprisingly discovers that the synergistic effect of killing cabbage plutella xylostella is achieved.
Detailed Description
The present invention will be further described below.
The examples provided herein are merely to further illustrate the invention and should not be construed as limiting the invention in any way.
It will be clear to a person skilled in the art that hereinafter, unless otherwise indicated, the materials and methods of operation used in the present invention are well known in the art.
In the present invention, the term "parts by weight" means in terms of weight, and for example, 1 part by weight means: when the weight is Kg, 1 part by weight means 1Kg; when the weight is g, 1 part by weight means 1g, and so on, not limited to a specific Kg or g.
In the following examples, cyhalodiamide, terpinen-4 alcohol, sodium dodecyl sulfate, sodium lignin sulfonate and ammonium sulfate are all commercial products, wherein terpinen-4 alcohol is prepared by extracting crude camphor oil.
Example 1
Taking 10 parts by weight of cyhalodiamide, 0.1 part by weight of terpinen-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum, uniformly mixing, and adding the mixture into water to prepare a composition solution 1 with 10ppm of active constituent cyhalodiamide and 0.1ppm of terpinen-4 alcohol for later use.
Example 2
Taking 10 parts by weight of cyhalodiamide, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum, uniformly mixing, and adding the mixture into water to prepare a composition solution 2 with 10ppm of active ingredient cyhalodiamide for later use.
Example 3
And (3) uniformly mixing 0.1 part by weight of terpinene-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum, and adding the mixture into water to prepare a composition solution 3 with 0.1ppm of terpinene-4 alcohol as an active ingredient for later use.
Example 4
Taking 10 parts by weight of cyhalodiamide, 1 part by weight of terpinen-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum, uniformly mixing, and adding the mixture into water to prepare a composition solution 4 with 10ppm of active constituent cyhalodiamide and 1ppm of terpinen-4 alcohol for later use.
Example 5
Taking 10 parts by weight of cyhalodiamide, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum, uniformly mixing, and adding the mixture into water to prepare a composition solution 5 with 10ppm of active ingredient cyhalodiamide for later use.
Example 6
1 part by weight of terpinene-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum are taken, uniformly mixed, and the mixture is added into water to prepare a composition solution 6 with 1ppm of terpinene-4 alcohol as an active ingredient for standby.
Example 7
6 parts by weight of cyhalodiamide, 5 parts by weight of terpinen-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum are taken, uniformly mixed, and the mixture is added into water to prepare a composition solution 7 with 10ppm of active constituent cyhalodiamide and 5ppm of terpinen-4 alcohol for later use.
Example 8
6 parts by weight of cyhalodiamide, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum are taken, uniformly mixed, and the mixture is added into water to prepare a composition solution 8 with 10ppm of active ingredient cyhalodiamide for standby.
Example 9
And (3) uniformly mixing 5 parts by weight of terpinene-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum, and adding the mixture into water to prepare a composition solution 9 with 5ppm of terpinene-4 alcohol as an active ingredient for later use.
Example 10
1 part by weight of cyhalodiamide, 10 parts by weight of terpinen-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum are taken, uniformly mixed, and the mixture is added into water to prepare a composition solution 10 with active ingredients of 1ppm of cyhalodiamide and 10ppm of terpinen-4 alcohol for later use.
Example 11
1 part by weight of cyhalodiamide, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum are taken, uniformly mixed, and the mixture is added into water to prepare a composition solution 11 with 1ppm of active ingredient cyhalodiamide for standby.
Example 12
10 parts by weight of terpinene-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum are taken, uniformly mixed, and the mixture is added into water to prepare a composition solution 12 with 10ppm of terpinene-4 alcohol as an active ingredient for standby.
Example 13
Taking 0.1 part by weight of cyhalodiamide, 10 parts by weight of terpinen-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum, uniformly mixing, and adding the mixture into water to prepare a composition solution 13 with 0.1ppm of active ingredient cyhalodiamide and 10ppm of terpinen-4 alcohol for later use.
Example 14
0.1 part by weight of cyhalodiamide, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum are taken, uniformly mixed, and the mixture is added into water to prepare a composition solution 14 with 0.1ppm of active ingredient cyhalodiamide for later use.
Example 15
10 parts by weight of terpinene-4 alcohol, 4 parts by weight of sodium dodecyl sulfate, 2 parts by weight of sodium lignin sulfonate, 4 parts by weight of ammonium sulfate and 2 parts by weight of Arabic gum are taken, uniformly mixed, and the mixture is added into water to prepare a composition solution 15 with 10ppm of terpinene-4 alcohol as an active ingredient for later use.
Example 16
Selecting healthy cabbages without insect pests, inoculating 50 plutella xylostella larvae on each strain, and then respectively spraying composition solutions 1-15 and pure water (serving as blank control). Wherein, each composition solution is a treatment, each treatment corresponds to 10 cabbages, and the repeated spraying amounts of the treatments are consistent. After 7 days of each treatment, the mortality was investigated and the mortality was finally calculated (test repeated 3 times, averaged) and the results are shown in table 1 below, and the theoretical insecticidal rate is the insecticidal rate calculated using the Colby formula.
TABLE 1
Figure BDA0003318378990000071
Figure BDA0003318378990000081
From Table 1, it can be seen that the active ingredients of cyhalodiamide and terpinen-4 alcohol have synergistic killing effect on cabbage moth.
The above description is only of the preferred embodiments of the present invention and is not intended to limit the present invention, but various modifications and variations can be made to the present invention by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (2)

1. A terpinen-4 alcohol-containing biocomposite formulation comprising:
0.1-10 parts of terpinen-4 alcohol, 0.1-10 parts of cyano phthalamide compound, 4 parts of sodium dodecyl sulfate, 2 parts of sodium lignin sulfonate, 4 parts of ammonium sulfate and 2 parts of Arabic gum; the terpinene-4 alcohol-containing biological composite preparation is specially used for killing plutella xylostella; the terpinen-4 alcohol is prepared from Cinnamomum camphora; the cyano group-containing phthalamide compound is chlorofluorocyantraniliprole.
2. A method of using the terpinen-4 alcohol-containing biocomposite formulation according to claim 1, wherein the terpinen-4 alcohol-containing biocomposite formulation according to claim 1 is sprayed onto plants.
CN202111238547.1A 2021-10-25 2021-10-25 Mixed application method of terpinene-4 alcohol-containing biological agent and biological pesticide Active CN113785833B (en)

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CN102524246A (en) * 2010-12-08 2012-07-04 福建诺德生物科技有限责任公司 Agricultural combination solvent and application thereof
CN102428973B (en) * 2011-10-18 2014-08-13 浙江农林大学 Agricultural pesticide with essential oil and application thereof
CN108308188B (en) * 2018-04-18 2022-06-21 中国人民解放军海军特色医学中心 Water-based insecticidal emulsion
CN109221126A (en) * 2018-09-26 2019-01-18 广西壮族自治区化工研究院 A kind of insecticide composition and its preparation method and application
CN109769842A (en) * 2019-01-30 2019-05-21 广西化工研究院有限公司 A kind of insecticide composition containing trifluoro-benzene pyrimidine, rotenoid

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