CN113715440A - 用于抗菌面料的制造工艺 - Google Patents

用于抗菌面料的制造工艺 Download PDF

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CN113715440A
CN113715440A CN202010446132.2A CN202010446132A CN113715440A CN 113715440 A CN113715440 A CN 113715440A CN 202010446132 A CN202010446132 A CN 202010446132A CN 113715440 A CN113715440 A CN 113715440A
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manufacturing process
parts
double
screw extruder
antibacterial fabric
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张子睿
姜亚
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Nantong Dongyi High New Fiber Technology Co ltd
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Nantong Dongyi High New Fiber Technology Co ltd
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/02—Layered materials
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/30—Antimicrobial, e.g. antibacterial
    • A41D31/305—Antimicrobial, e.g. antibacterial using layered materials
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    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
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    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
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    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract

本发明公开一种用于抗菌面料的制造工艺，包括以下步骤：步骤一、将所述聚丙烯组合物、聚烯烃弹性体、烷基聚氧乙烯醚、烃类化合物、聚氧化丙烯二胺、硬脂基辛基二甲基硫酸甲酯铵、羧甲基纤维素钠、硬脂酸钙和抗氧化剂搅拌混合；步骤二、将得到的混合物加到双螺杆挤出机中双螺杆挤出机内的温度控制为约200~300℃，之后在120~150℃的挤出温度下挤出反应产物；步骤三、将双螺杆挤出机中获得的挤出产物加到冷却水槽中进行冷却，之后进入造粒机中进行造粒获得所述母料。本发明制造工艺获得的抗菌面料提高了防护层的亲水性，从而改善了面料过滤效果，尤其是对细菌和病毒的过滤效果。

Description

用于抗菌面料的制造工艺
技术领域
本发明涉及面料领域，尤其涉及一种用于抗菌面料的制造工艺。
背景技术
世界范围内发现和确认的新发传染病几乎每年都在递增，常见的感染原因是接触灰尘污染或外科医生与患者及病原体表上含尘空气的污染，因此，医护人员需要穿着防护服装以降低感染的风险。现有用于医用的面料湿润性差，降低了对细菌和病毒的过滤效果。因此，研制一种改善了面料过滤效果，尤其是对细菌和病毒的过滤效果的医用防护服面料成为本领域技术人员亟需解决的技术问题。
发明内容
本发明目的在于提供一种用于抗菌面料的制造工艺，该制造工艺获得的抗菌面料提高了防护层的亲水性，从而改善了面料过滤效果，尤其是对细菌和病毒的过滤效果。
为达到上述目的，本发明采用的技术方案是：一种用于抗菌面料的制造工艺，所述抗菌面料包括基布层和位于基布层上的防护层，此防护层由母料熔喷加工而成，此母料进一步由以下组分组成：聚丙烯组合物100份、聚氨酯弹性体20~25份、烷基聚氧乙烯醚5~10份、环氧烷烃类化合物3~5份、硬脂基辛基二甲基硫酸甲酯铵2~3份、羧甲基纤维素钠1~2份、硬脂酸钙1~2份、抗氧化剂0.1~0.3份；
所述母料通过以下步骤获得：
步骤一、将所述聚丙烯组合物、聚烯烃弹性体、烷基聚氧乙烯醚、烃类化合物、聚氧化丙烯二胺、硬脂基辛基二甲基硫酸甲酯铵、羧甲基纤维素钠、硬脂酸钙和抗氧化剂搅拌混合；所述聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯混合而成；所述聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯按照10：4~6的重量份混合而成；所述聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯按照10：4~6的重量份混合而成；
步骤二、将得到的混合物加到双螺杆挤出机中双螺杆挤出机内的温度控制为约200~300℃，之后在120~150℃的挤出温度下挤出反应产物；
步骤三、将双螺杆挤出机中获得的挤出产物加到冷却水槽中进行冷却，之后进入造粒机中进行造粒获得所述母料。
上述技术方案中进一步改进的技术方案如下：
1. 上述方案中，所述基布层和防护层通过胶粘剂或者热压连接。
2. 上述方案中，所述抗氧剂为四[甲基-（3，5-二叔丁基-4-羟基苯基）丙酸]季戊四醇酯，或者，β-（3，5-二叔丁基-4-羟基苯基）丙酸十八醇酯。
3. 上述方案中，所述均聚聚丙烯在230℃、2.16kg负荷条件下，熔体流动速率为30~100g/10min。
4. 上述方案中，所述嵌段共聚丙烯在230℃、2.16kg负荷条件下，熔体流动速率为5~60g/10min。
5. 上述方案中，所述步骤二中混合物加到双螺杆挤出机中双螺杆挤出机内的温度控制为约180℃，螺杆转速控制为300转/分钟。
由于上述技术方案的运用，本发明与现有技术相比具有下列优点：
本发明用于抗菌面料的制造工艺，其位于基布层上防护层的母料基于由均聚聚丙烯和嵌段共聚丙烯混合而成聚丙烯组合物，进一步添加硬脂基辛基二甲基硫酸甲酯铵2~3份、羧甲基纤维素钠1~2份，提高了防护层的亲水性，从而改善了面料过滤效果，尤其是对细菌和病毒的过滤效果。
具体实施方式
在本发明的描述中，需要说明的是，术语“中心”、“上”、“下”、“左”、“右”、“竖直”、“水平”、“内”、“外”等指示的方位或位置关系为基于所示的方位或位置关系，仅是为了便于描述本发明和简化描述，而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作，因此不能理解为对本发明的限制；术语“第一”、“第二”、“第三”仅用于描述目的，而不能理解为指示或暗示相对重要性；此外，除非另有明确的规定和限定，术语“安装”、“相连”、“连接”应做广义理解，例如，可以是固定连接，也可以是可拆卸连接，或一体地连接；可以是机械连接，也可以是电连接；可以是直接相连，也可以通过中间媒介间接相连，可以是两个元件内部的连通。对于本领域的普通技术人员而言，可以具体情况理解上述术语在本发明中的具体含义。
下面结合实施例对本发明作进一步描述：
实施例1~4：一种用于抗菌面料的制造工艺，所述抗菌面料包括基布层和位于基布层上的防护层，此防护层由母料熔喷加工而成，此母料进一步由以下组分组成，如表1所示：
表1
Figure 608663DEST_PATH_IMAGE002
实施例1的聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯按照10：5的重量份混合而成，基布层1和防护层2通过胶粘剂连接，所述防护层2的厚度为37克/平米；
实施例2的聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯按照10：4的重量份混合而成，基布层1和防护层2通过热压连接，所述防护层2的厚度为53克/平米；
实施例3的聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯按照10：5的重量份混合而成，基布层1和防护层2通过热压连接，所述防护层2的厚度为42克/平米；
实施例4的聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯按照10：4的重量份混合而成，基布层1和防护层2通过胶粘剂连接，所述防护层2的厚度为51克/平米。
上述均聚聚丙烯在230℃、2.16kg负荷条件下，熔体流动速率为30~100g/10min。
上述嵌段共聚丙烯在230℃、2.16kg负荷条件下，熔体流动速率为5~60g/10min。
所述母料通过以下步骤获得：
步骤一、将聚丙烯组合物、聚氨酯弹性体、烷基聚氧乙烯醚、烃类化合物、硬脂基辛基二甲基硫酸甲酯铵、羧甲基纤维素钠、硬脂酸钙和抗氧化剂搅拌混合；所述聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯混合而成；
步骤二、将得到的混合物加到双螺杆挤出机中双螺杆挤出机内的温度控制为约180℃，螺杆转速控制为300转/分钟，之后在140℃的挤出温度下挤出反应产物；
步骤三、将双螺杆挤出机中获得的挤出产物加到冷却水槽中进行冷却，之后进入造粒机中进行造粒获得所述母料。
对比例1~2：一种面料的制造工艺，所述面料包括基布层和位于基布层上的防护层，此防护层由母料熔喷加工而成，此母料进一步由以下组分组成，如表2所示：
表2
Figure DEST_PATH_IMAGE003
对比例2的聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯按照10：5的重量份混合而成。
对比例的母料制造工艺同实施例。
上述实施例1~4和对比例1~2制得面料性能如表3所示：
表3
Figure 734751DEST_PATH_IMAGE004
注：实施例和对比例的水接触角按照ISO15989：2004的方法检测。
如表3的评价结果所示，本发明实施例相对于对比例，面料水接触角小于30°，提高了防护层的亲水性，从而改善了面料过滤效果，尤其是对细菌和病毒的过滤效果。
上述实施例只为说明本发明的技术构思及特点，其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施，并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰，都应涵盖在本发明的保护范围之内。

Claims (6)

1.一种用于抗菌面料的制造工艺，其特征在于：所述抗菌面料包括基布层和位于基布层上的防护层，此防护层由母料熔喷加工而成，此母料进一步由以下组分组成：聚丙烯组合物100份、聚氨酯弹性体20~25份、烷基聚氧乙烯醚5~10份、环氧烷烃类化合物3~5份、硬脂基辛基二甲基硫酸甲酯铵2~3份、羧甲基纤维素钠1~2份、硬脂酸钙1~2份、抗氧化剂0.1~0.3份；
所述母料通过以下步骤获得：
步骤一、将所述聚丙烯组合物、聚烯烃弹性体、烷基聚氧乙烯醚、烃类化合物、聚氧化丙烯二胺、硬脂基辛基二甲基硫酸甲酯铵、羧甲基纤维素钠、硬脂酸钙和抗氧化剂搅拌混合；所述聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯混合而成；所述聚丙烯组合物由均聚聚丙烯和嵌段共聚丙烯按照10：4~6的重量份混合而成；
步骤二、将得到的混合物加到双螺杆挤出机中双螺杆挤出机内的温度控制为约200~300℃，之后在120~150℃的挤出温度下挤出反应产物；
步骤三、将双螺杆挤出机中获得的挤出产物加到冷却水槽中进行冷却，之后进入造粒机中进行造粒获得所述母料。
2.根据权利要求1所述的用于抗菌面料的制造工艺，其特征在于：所述抗氧剂为四[甲基-（3，5-二叔丁基-4-羟基苯基）丙酸]季戊四醇酯，或者，β-（3，5-二叔丁基-4-羟基苯基）丙酸十八醇酯。
3.根据权利要求1所述的用于抗菌面料的制造工艺，其特征在于：所述基布层（1）和防护层（2）通过胶粘剂或者热压连接。
4.根据权利要求1所述的用于抗菌面料的制造工艺，其特征在于：所述均聚聚丙烯在230℃、2.16kg负荷条件下，熔体流动速率为30~100g/10min。
5.根据权利要求1所述的用于抗菌面料的制造工艺，其特征在于：所述嵌段共聚丙烯在230℃、2.16kg负荷条件下，熔体流动速率为5~60g/10min。
6.根据权利要求1所述的用于抗菌面料的制造工艺，其特征在于：所述步骤二中混合物加到双螺杆挤出机中双螺杆挤出机内的温度控制为约180℃，螺杆转速控制为300转/分钟。
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