CN113712029A - Pinene-containing plant protection additive and preparation method thereof - Google Patents

Pinene-containing plant protection additive and preparation method thereof Download PDF

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Publication number
CN113712029A
CN113712029A CN202111037331.9A CN202111037331A CN113712029A CN 113712029 A CN113712029 A CN 113712029A CN 202111037331 A CN202111037331 A CN 202111037331A CN 113712029 A CN113712029 A CN 113712029A
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weight
parts
pinene
plant protection
containing plant
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CN202111037331.9A
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Chinese (zh)
Inventor
杨光胜
周杰
骆艳
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Sichuan Chenyu Forestry Development Co ltd
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Sichuan Chenyu Forestry Development Co ltd
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Priority to CN202111037331.9A priority Critical patent/CN113712029A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02—Acyclic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action

Abstract

The invention discloses a pinene-containing plant protection additive and a preparation method thereof, wherein the pinene-containing plant protection additive is prepared from the following components: 0.1-100 parts by weight of camphor oil extract; 0.1-100 parts by weight of rice hull ash; 0.1-100 parts by weight of 2-hydroxy-N, N, N-trimethylethanaminium; and 0.1-100 parts by weight of glycerin. The protective additive has a protective effect.

Description

Pinene-containing plant protection additive and preparation method thereof
Technical Field
The invention relates to the field of cinnamomum camphora application, and particularly relates to a pinene-containing plant protection auxiliary agent and a preparation method thereof.
Background
Cinnamomum camphora (with the academic name of Camphorum longipaniticulatum (Gamble) N. Chao ex H.W.Li) is evergreen arbor of Lauraceae, with height of 20 m and diameter at breast height of 50 cm; the bark is gray, the branch is cylindrical, hairless, the young branch is fine, the leaves are intergrowth, oval or elliptical, the tip is suddenly short and gradually sharp to long and gradually sharp, the upper surface is dark green, bright, the lower surface is grey green, dark, the two surfaces are hairless, the leaf stalk is flat and back convex, light green, the cone inflorescence axillary, is fine, the branch is fine and weak, each branch is 3-7 flowers of the polypodium, the shaft is hairless, the flower is light yellow, fragrance is provided, the stalk is fine, the flower quilt is cone-shaped, the flower quilt is oval, the filament is white and soft, the filament is glandless, the anther is long round, the ovary is oval, the young fruit is spherical, the flower is in 5-6 months, and the fruit is yielded in 7-9 months.
The cinnamomum camphora has the characteristics of rapid growth, strong sprout tillering, more leaf-carrying, less pest and disease, beautiful tree shape, ambitious posture, flexible wood and compact texture, has the service life of thousands of years, and is the preferred tree species for sheet afforestation and four-side greening.
The existing industrialized benefiting mode for cinnamomum camphora is to process the trunk and roots of cinnamomum camphora into cinnamomum camphora oil, and the processing method comprises the following steps:
(1) the stems and roots of camphor trees are selected as raw materials, the stems and roots respectively contain 2-4% of camphor and camphor oil, and the branches and leaves respectively contain 1-3%. The larger the age of the tree, the higher the content. Large pieces with bitter taste contain much camphor, and pungent and astringent taste contain much camphor oil. The collection should be done in autumn, and the leaves have high brain content. Leaves of 16 leaves are left in each plant during leaf picking, and old trees with the period of more than 30 years are suitable. The cut branches and roots should be cut into slices 2.5 cm wide, 1 cm thick and 10 cm long.
(2) The upper distillation steamer can not be made of iron, and is preferably made of copper or stainless steel. The steaming stove is provided with a wooden steaming barrel which is in accordance with the diameter of the pot mouth and is sleeved on the pot. When in processing, the camphor tree leaves or camphor wood slices are put into a steaming barrel. The water in the pan was separated from the raw materials by 10 cm. Immediately closing the pot cover and the charging port after feeding, checking the joint of the distillation pot and the cooler, and starting distillation only if no air leakage exists. During distillation, the water level in the pot should be kept to prevent from being dried or burnt. And returning the water after oil-water separation into the steamer for use.
(3) Cooling and separating the vapor with camphor and camphor oil, introducing the vapor into a multi-ring disc cooler through a gas guide pipe, and condensing the condensed camphor and camphor oil to float on the water surface. The separated water should be transparent, and if the separated water is not transparent, the separated water should be separated again, so that the oil yield is improved. Filtering the floating camphor and camphor oil with gauze to obtain crude camphor, and the rest camphor oil contains most camphor and is called camphor oil.
At present, the processed camphor oil has not been reported to be used for plant protection.
Disclosure of Invention
Based on the above problems, in one aspect, the present invention provides a pinene-containing plant protection auxiliary, which has a protective effect on plant growth.
A plant protection auxiliary agent containing pinene is mainly prepared from the following components:
0.1-100 parts by weight of camphor oil extract;
0.1-100 parts by weight of rice hull ash;
0.1-100 parts by weight of 2-hydroxy-N, N, N-trimethylethanaminium; and
0.1 to 100 parts by weight of glycerol.
In one or more specific embodiments herein, the camphor oil extract is 0.1 to 100 parts by weight, the rice hull ash is 0.1 to 100 parts by weight, the 2-hydroxy-N, N-trimethylethanaminium is 0.1 to 100 parts by weight, and the glycerin is 0.1 to 100 parts by weight.
In one or more specific embodiments herein, the camphor oil extract is 5 parts by weight, the rice hull ash is 20 parts by weight, the 2-hydroxy-N, N-trimethylethanaminium is 25 parts by weight, and the glycerin is 12 parts by weight.
In one or more specific embodiments of the present application, the camphor oil extract is prepared by the steps of:
taking camphor oil and ethanol, uniformly mixing, standing and layering;
② taking a layer dissolved in ethanol;
thirdly, adding the second step into water, uniformly mixing, standing for layering, and separating a water layer and an oil layer;
and the oil layer is the camphor oil extract.
In one or more specific embodiments herein, the camphor oil: ethanol: the weight ratio of water is 50-200: 50-200: 50-200.
On one hand, the invention also provides a preparation method of the pinene-containing plant protection auxiliary agent.
A preparation method of the pinene-containing plant protection additive comprises the following steps:
taking the camphor oil extract, rice hull ash, 2-hydroxy-N, N, N-trimethyl ethylammonium and glycerol, and mixing uniformly.
In one or more specific embodiments herein, the rice hull ash is the residue of rice hull combustion.
On one hand, the invention also provides a use method of the pinene-containing plant protection auxiliary agent.
The application method of the pinene-containing plant protection additive is characterized in that the pinene-containing plant protection additive is added into 1000 parts by weight of water to form the pinene-containing plant protection additive diluent.
On one hand, the invention also provides the application of the diluent containing pinene for the plant protection additive.
The application of the pinene-containing plant protection aid diluent is characterized in that the pinene-containing plant protection aid diluent is used for planting tomatoes or cucumbers.
The invention principle and the beneficial effects of the application are as follows:
according to the invention, through the combined synergistic effect of the camphor oil extract, the rice hull ash, the 2-hydroxy-N, N, N-trimethyl ethylammonium and the glycerol, the overall health of plants is improved, the plant diseases and insect pests are reduced, and the overall yield is improved.
Detailed Description
The present invention will be further explained below.
The examples provided herein are merely to further illustrate the invention and should not be construed as limiting the invention in any way.
It will be apparent to those skilled in the art that the materials and methods of operation used in the present invention are well known in the art, unless otherwise specified, in the following.
In the present invention, parts by weight means measured in units of weight, such as 1 part by weight means: when the weight is Kg, 1 part by weight means 1 Kg; when the weight is g, 1 part by weight means 1g, and the like, and is not limited to a specific Kg or g.
Example 1
Taking 100 parts by weight of camphor oil and 100 parts by weight of ethanol, uniformly mixing, standing and layering, and layering into a layer (lower layer) soluble in ethanol and a layer (upper layer) insoluble in ethanol.
② taking the layer (lower layer) dissolved in ethanol.
Thirdly, adding the mixture II into 200 parts by weight of water, standing for layering after uniform mixing, and separating a water-soluble layer (water layer) and a water-insoluble layer (oil layer).
And taking a water-insoluble layer (oil layer), wherein the water-insoluble layer (oil layer) is a camphor oil extract which is used in the subsequent examples.
The pinene content of the camphor oil extract can be detected by adopting gas chromatography.
Example 2
5 parts by weight of the camphor oil extract prepared in example 1, 20 parts by weight of rice hull ash, 25 parts by weight of 2-hydroxy-N, N, N-trimethylethanaminium, and 12 parts by weight of glycerin were mixed uniformly.
The mixture was added to 1000 parts by weight of water and stirred well.
In the present invention, the rice hull ash is the residue of rice hull after combustion. The 2-hydroxy-N, N, N-trimethyl ethylammonium and glycerol are purchased from the market.
Example 3
Taking 20 parts by weight of rice hull ash, 25 parts by weight of 2-hydroxy-N, N, N-trimethyl ethylammonium and 12 parts by weight of glycerol, and uniformly mixing.
The mixture was added to 1000 parts by weight of water and stirred well.
Example 4
5 parts by weight of the camphor oil extract prepared in example 1 and 20 parts by weight of rice hull ash were taken and mixed uniformly.
The mixture was added to 1000 parts by weight of water and stirred well.
Example 5
Adding 20 parts by weight of rice hull ash into 1000 parts by weight of water, and uniformly stirring.
Example 6
The specimens prepared in each of examples 2 to 5 were subjected to a field test for preventing the occurrence of diseases and the growth of crops.
The field test for preventing disease occurrence and crop growth is divided into field test (soil planting) of cucumbers and tomatoes, wherein three cucumber test fields are provided, three tomato test fields are provided, a cucumber plantation Fengyuan No. 6 green cucumber is provided, two plants are fixedly planted, and the hole distance is 28 cm; the tomatoes are planted with red British stone, the plant spacing of the tomatoes is 30cm, and the row spacing is 50-70 cm.
In the field test, the test field of each cucumber was divided into 4 portions, and one portion of each of the samples prepared in examples 2 to 5 was used.
After the cucumbers and tomatoes are planted and survive normally, spraying is started, wherein the spraying is performed once a week, and after fruiting is started, the spraying is performed once in half a month, and the spraying amount is 30L/mu.
Field management: except that the sprayed sample liquid is different, the same field management is adopted.
The test results are shown in tables 1 and 2 below, and the values in tables 1 and 2 are the average values of three cucumber trials (three tomato trials).
TABLE 1 Table for preventing diseases
Figure BDA0003247733490000061
Remarking:
in table 1, the incidence of disease is 100% × diseased number of plants/sample number of plants;
in table 1, the disease condition degree ∑ (each diseased leaf number × relative level value)/(total investigated leaf number × highest representative value) × 100, where the relative level value and the highest representative value are determined according to the disease condition grading criteria: grade 0, no scab; grade 1, the lesion area accounts for less than 5% of the whole leaf area; grade 3, the lesion area accounts for 6 to 10 percent of the whole leaf area; grade 5, the lesion area accounts for 11 to 20 percent of the whole leaf area; 7 grade, the lesion area accounts for 21 to 50 percent of the whole leaf area; grade 9, the lesion area accounts for more than 50% of the whole leaf area.
TABLE 2 crop growth yield
Figure BDA0003247733490000062
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (9)

1. A plant protection auxiliary agent containing pinene is prepared from the following components:
0.1-100 parts by weight of camphor oil extract;
0.1-100 parts by weight of rice hull ash;
0.1-100 parts by weight of 2-hydroxy-N, N, N-trimethylethanaminium; and
0.1 to 100 parts by weight of glycerol.
2. The pinene-containing plant protection additive according to claim 1, wherein the camphor oil extract is 0.1 to 100 parts by weight, the rice hull ash is 0.1 to 100 parts by weight, the 2-hydroxy-N, N, N-trimethylethanaminium is 0.1 to 100 parts by weight, and the glycerol is 0.1 to 100 parts by weight.
3. The pinene-containing plant protection additive according to claim 2, wherein the camphor oil extract comprises 5 parts by weight, 20 parts by weight of rice hull ash, 25 parts by weight of 2-hydroxy-N, N, N-trimethylethanaminium, and 12 parts by weight of glycerol.
4. The pinene-containing plant protection additive according to any one of claims 1 to 3, wherein the camphor oil extract is prepared by the following steps:
taking camphor oil and ethanol, uniformly mixing, standing and layering;
② taking a layer dissolved in ethanol;
thirdly, adding the second step into water, uniformly mixing, standing for layering, and separating a water layer and an oil layer;
and the oil layer is the camphor oil extract.
5. The pinene-containing plant protection additive according to claim 4, wherein the amount of the camphor oil: ethanol: the weight ratio of water is 50-200: 50-200: 50-200.
6. A method for preparing a pinene-containing plant protection additive as defined in any one of claims 1 to 5, comprising the steps of:
taking the camphor oil extract, rice hull ash, 2-hydroxy-N, N, N-trimethyl ethylammonium and glycerol, and mixing uniformly.
7. The method for preparing a pinene-containing plant protection aid according to claim 6, wherein the rice hull ash is a residue of rice hull after combustion.
8. A use method of the pinene-containing plant protection additive as described in any one of claims 1 to 5, wherein the pinene-containing plant protection additive is added to 1000 parts by weight of water to form a pinene-containing plant protection additive diluent.
9. The use of the pinene-containing plant protection aid diluent in claim 8, wherein the pinene-containing plant protection aid diluent is used for planting tomatoes or cucumbers.
CN202111037331.9A 2021-09-06 2021-09-06 Pinene-containing plant protection additive and preparation method thereof Pending CN113712029A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104351260A (en) * 2014-10-14 2015-02-18 深圳文科园林股份有限公司 Biological pesticide for killing aphids and preparation method for biological pesticide
CN110367251A (en) * 2019-08-06 2019-10-25 广西汇丰生物科技有限公司 A kind of synergetic pesticide composition containing nopinene

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104351260A (en) * 2014-10-14 2015-02-18 深圳文科园林股份有限公司 Biological pesticide for killing aphids and preparation method for biological pesticide
CN110367251A (en) * 2019-08-06 2019-10-25 广西汇丰生物科技有限公司 A kind of synergetic pesticide composition containing nopinene

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
宋小平 等: "《农用化学品制造技术》", 31 March 2012 *
张薇等: "植物挥发性物质成分分析及抑菌作用研究", 《生态环境》 *
杨洪强: "《有机园艺》", 30 June 2005 *
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Application publication date: 20211130