CN110367251A - A kind of synergetic pesticide composition containing nopinene - Google Patents
A kind of synergetic pesticide composition containing nopinene Download PDFInfo
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- CN110367251A CN110367251A CN201910720840.8A CN201910720840A CN110367251A CN 110367251 A CN110367251 A CN 110367251A CN 201910720840 A CN201910720840 A CN 201910720840A CN 110367251 A CN110367251 A CN 110367251A
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- fluorine
- nopinene
- bacterium
- chlorine
- grass
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing heterocyclic radicals
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Abstract
The invention discloses a kind of synergetic pesticide compositions containing nopinene, it is A and B containing active constituent, active components A is nopinene, active constituent B is selected from avermectin, etoxazole, Envidor, Bifenazate, second azoles mite nitrile, dinotefuran, Diacloden, flonicamid, capillary, Rynaxypyr, bromine cyanogen insect amide, emamectin-benzoate, fipronil bisamide formates, Tolfenpyrad, four chlorantraniliproles, indoxacarb, cyflumetofen, malicious fluorine phosphine, octyl trichlamide, Fluoxastrobin, pyraclostrobin, fluorine thiazole pyrrole ethyl ketone, isopyrazam, cyhalofop-butyl, fenoxapropPethyl etc..Nopinene is the broad spectrum activity synergist of a kind of desinsection/microbial inoculum and herbicide, the use of nopinene synergist, the enhancing of chemical pesticide preventive effect in the present invention; drug effect is rapid, can reduce the use of chemical pesticide amount, reduce cost; it preserves the ecological environment, delays harmful organism to the drug resistance of chemical pesticide.
Description
Technical field
The invention belongs to technical field of pesticide, specifically a kind of synergetic pesticide composition containing nopinene.
Background technique
Nopinene is also known as β-turpentine alkene, bicyclic diterpene class compound, is oil with australene double-bond positional isomerization body each other
Shape is one of turpentine oil main component, can be used for the allotment of daily chemical essence and for other industrial goods flavorings, is mainly used for various terpenes
The starting material of alkenes synthetic perfume, for manufacturing citral, citronellol, laurine, geraniol, linalool, violet
The synthetic perfumes such as ketone, methylionone, menthol, but also be the important original closed nopinene resin and produce vitamin E etc.
One of material.The structural formula of nopinene is as follows:
In agricultural production due to long-term, single use or abuse desinsection/microbial inoculum, make pest or disease to desinsection/microbial inoculum
Produce drug resistance, or even development is cross resistance and multiresistance, at the same a large amount of uses of herbicide easily cause phytotoxicity or
Drift or even resistance rise.It is complicated to develop synthesis new varieties of pesticides technology process, appointed condition requires high, registration
It is cumbersome, hinder the development of agricultural production.The generation of harmful organism drug resistance mainly selects to press due to medicament to harmful organism
Power as a result, this selection pressure again mainly as single dose it is single to controlling object position or less caused by.Therefore, it selects
There are two or more composite reagents of synergistic effect, is the key of solving the problem.
Synergist refers to a kind of chemical substance of no to insect or few insecticidal properties, but makes an addition to a certain kill
After worm/microbial inoculum or herbicide, the insecticidal power of desinsection/microbial inoculum or herbicide can be greatly improved.The advantages of adding synergist exists
In, insecticidal effect can be greatly increased, insecticide dosage is reduced, to reduce cost, reduces the content of insecticide in human environment,
Pest resistance to insecticide can be reduced over a period to come, and can economically control pest.Inventor is after study
It was found that nopinene has good synergistic effect to pesticide, currently without the research report about nopinene as pesticide synergistic agent
Road.
The disclosure of background above technology contents is only used for auxiliary and understands inventive concept and technical solution of the invention, not
The prior art for necessarily belonging to present patent application shows above content in the applying date of present patent application in no tangible proof
In the case where having disclosed, above-mentioned background technique should not be taken to the novelty and creativeness of evaluation the application.
Summary of the invention
It is an object of that present invention to provide a kind of synergetic pesticide compositions containing nopinene.The present invention is sent out by long term test
Now addition nopinene synergist can greatly increase the pesticide-germicide effect of pesticide, reduce pesticide dosage, reduce cost, and reduce evil
Worm is to desinsection/microbial inoculum drug resistance.
In order to achieve the goal above, The technical solution adopted by the invention is as follows:
A kind of synergetic pesticide composition containing nopinene of new discovery of the present invention, the composition pesticide is by active components A
And B, active components A are nopinene, active constituent B is selected from one of following compound or multiple combinations or their Pesticide Science
On the salt allowed, the mass ratio of the A and B are 1:100-100:1；
3,5- xylyl methyl carbamate (XMC), Dipel Aizawa subspecies
(Bacillusthuringienses aizawai), Bacillus thuringiensis subsp. israelensis (Bacillus
Thuringiensesisraelensis), Dipel Japan subspecies (Bacillus thuringienses
Japonensis), (B-5) Dipel Kurstaki (Bacillus thuringienses kurstaki), Su Yun
Golden bacillus intends ground beetle subspecies (Bacillus thuringienses tenebrionis), (B-7) Dipel
(Bacillusthuringienses) crystalline protein toxin generated, chlorfenizon, acrinathrin, nimbin, acequinocyl, pyridine
Worm amidine, acetyl worm nitrile, orthene, avermectin, sulfanilamide (SN) mite ester, Amitraz, α -5a,6,9,9a-hexahydro-6,9-methano-2,4, α-cypermethrin, rosickyite miaow
Azoles, allethrin, isazofos, isoxathion, isofenphos, Mobucin, ivermectin, imidacloprid, Imiprothrin, indoxacarb, S-
Fenvalerate, (B-49) ethiofencarb, Ethodan, ethiprole, etoxazole, ethofenprox, phonamiphos, etrimfos, emaricin,
Emaricin benzoate, 5a,6,9,9a-hexahydro-6,9-methano-2,4, Prallethrin, oxamyl, cadusafos, cartap, carbaryl, carbosulfan, carbofuran,
Gamma-cyhalothrin, Meobal, quinalphos, kinoprene, chinomethionat, cloethocarb, clothianidin, clofentezine, ring tebufenozide, chlorine
Worm benzamide, chlorethoxyfos, Spanon, Niran, chlopyrifos, chlorpyrifos-methyl, chlorfenapyr, chlorfenizon, (B-89) chlorfenviphos,
Chlorfluazuron, chlorobenzilate, dicofol, cynock, diafenthiuron, Nellite, bromine cyanogen insect amide, efficiently trans- chlorine cyanogen chrysanthemum
Ester, Hooker HRS 16, nitrile pyrrole mite ester, σ-cypermethrin, (B-105) ring bromine insect amide, dichlofenthion, (B-107) cycloprothrin, enemy enemy
Fear, disulfoton, dinotefuran, lambda-cyhalothrin, cyphenothrin, cyfloxylate, diflubenzuron, cyflumetofen, flufenzine, tricyclic
Tin, cypermethrin, dimethylvinphos, Rogor, dimefluthrin, silafluofene, cyromazine, ethyl pleocidin, more sterilizations
Element, Envidor, spiral shell first mite, thiodicarb, thiocyclam, desinsection bisgallic acid, dimehypo, thionazin, thiometon, Metadelphene, Di Shi
Agent, Ravap, tetradiphon, fluorine cyanogen insect amide, etrafluorine ethofenprox, tetramethrin, butyl pyrimidine phosphorus, tebufenozide, tebufenpyrad, seven
Flumethrin, fluorobenzene urea, demeton-methyl, Swebate, decis, terbufos, bromo pyrrole carbonitrile, tralomethrin, phenyl tetrafluoride
Pyrethroids, triaguron, trichlamide, metrifonate, triflumuron, Tolfenpyrad, Nithiazine, Nitenpyram, novaluron, noviflumuron,
Hydroprene, fluorine pyrazoles worm, (B-178) vamidothion, parathion, parathion-methyl, halfenprox, chlorine tebufenozide, bistrifluron,
Dimehypo, hydramethylnon, hydroxypropul starch, binapacryl, Bifenazate, Biphenthrin, pymetrozine, pyraclofos, pyrazine Fipronil,
Pyridaphethione, fluoroform pyrrole ether, pyridine Fipronil, Nylar, Aphox, pyrimidifen, pirimiphos-methyl, pyrethrin, fluorine worm
Nitrile, fenazaquin, fenamiphos, fenisobromolate, fenifrothion, fenoxycarb, fenothiocarb, phenothrin, Bassa, fensulfothion, Entex,
Phenthoate dimephenthoate cidial, fenvalerate, fenpyroximate, Fenpropathrin, Phenbendasol, special Pyrimitate, Buprofezin, furathiocarb, prallethrin, phonetic mite
Ester, fluazinam, fluazuron, fluorine thiophene worm sulfone, flucycloxuron, flucythrinate, DL- taufluvalinate fluorine pyrrole furanone, Flupyrazofos-containpesticide,
Butene-fipronil, phonetic worm amine, flufenoxuron, flufenzine, trifluoro ethofenprox, halfenprox, brofluthrinate, fipronil bisamide, flumethrin,
Fluorine worm sweet smell, Toyodan, fluorobenzene ethofenprox, flonicamid, Kayaphos, propargite, Profenofos, the third Flumethrin, arprocarb, bromine mite
Ester, β-cyfloxylate, flubenzuron, Hexythiazox, seven fluorine methothrins, heptenophos, permethrin, Ficam, bensultap, benzene mite
Spy, Benfuracard micro, phoxim, zolone, lythidathion, fosthietan, phosphamidon, phosphorus worm prestige, phosmet, Carzol, peace sulphur
Phosphorus, thimet, malathion, milbemycin, milbemycin A, milbemectin, Afos, Entex sulfoxide, Methomyl,
The methaldehyde, metaflumizone, acephatemet, metham-sodium, methiocarb, methidathion, enemy line ester, the new decyl amide of methyl, methyl paraoxon,
Metoxadiazone, methoxychlor, methoxyfenozide, metofluthrin, methoprene, MTMC, fluorine chlorine ether pyrethroids, Menite, long
Imitate phosphorus, Cupric sulfate, λ-lambda-cyhalothrin, lufenuron, rayperidin, rotenone, fenbutatin oxide, Morantel Tartrate, bromomethane,
It is plictran, azithiram, isotianil, chlorobenzene Climbazole, isopyrazam, isopropyl metsulfovax, Isoprothiolane, iprodione, different
Third bacterium amine, different rice blast net, imazalil, iminoctadine, metham-sodium, iminoctadine triacetate, uniconazole P, kobam, edifenphos, second
Ring azoles, Guardian, ethirimol, Ethisul, ethoxyquinoline, Enestroburin, epoxiconazole, Wakil, oxycarboxin 8- hydroxyl
Base copper 8-hydroxyquinolinate, terramycin, copper 8-hydroxyquinolinate, dislike imidazoles, dislike oxpoconazole fumarate, octhilinone, fenfuram, orysastrobin, metham-sodium,
Kasugarnycin, ring propionyl bacterium amine, carbendazim, carboxin, quinoxyfen, chinomethionat, chinomethionat, difoltan, captan, refining benzene frost
Spirit, azoles oxolinic acide, pentachloronitrobenzene, double pungent guanamines, cufraneb, cuprobam, kresoxim-methyl, chlozolinate, clotrimazole, pest of going out azoles,
Imugan, tetrachloroquinone, four chloro-quinoxalines, benzene imidazoles bacterium, chlorine nitre naphthalene, Bravo, chloroneb, salicylanilide, zarilamid cyanogen
White azoles, diethofencarb, ring bacterium amine, double chlorine zarilamid, sclex, diclobutrazol, dichlofluanid, diclomezin, botran, double chlorine
Phenol, dichlone, disulfiram, Plondrel, metalaxyl, dithianon, olefin conversion, olefin conversion M, zineb, dinocap, double pyrrole sulphur
Father-in-law, difenoconazole, cyflufenamid, fluorine mepanipyrim, Cyproconazole, cyprodinil, cyprofuram, cypendazole, simeconazoles, diformazan are phonetic
Phenol, dimethomorph, cymoxanil, dimoxystrobin, bromomethane, ziram, Silthiopham, streptomysin, volution bacterium amine, sultropen, fluorine azoles
Ring bacterium amine, zoxamide, Carbatene, dazomet, milneb, tiadinil, thiophene difluoro probenazole sulphur benzonitrile formamide, Eradex,
Sulphur chlorobenzene imines, thiophanate, thiophanate-methyl, methyl-isorhodanate, thicyofen, thifluzamide, thiram, decafentin, tetrachloro
Nitrobenzene, tecloftalam, thiram connection, fluorine ether azoles, debacarb, Tebuconazole, isobutyl ethoxyquin, dodemorfe, drazoxolon, triazole
Alcohol, triazolone, metalaxyl M, fourth triazole, azoles bacterium piperazine, triamiphos, triarimol, trichlamide, tricyclazole, triticonazole, 13
Quinoline, tributyltin oxide, fluorine bacterium azoles, trifloxystrobin, triforine, Tolylfluanid, tolelofos-methyl, natamycin, nitrothalisopropyl, fluorine
Benzene ancymidol, halacrinate, jinggangmeisu, figured silk fabrics ammonia bacterium ester, super quick albumen, biphenyl pyrrole bacterium amine, ZEN 90160, fluorine pyrrole bacterium
Amine, Bithionol, bitertanol, binapacryl, Biphenthrin, hymexazol, pyraoxystrobin, pyracarbolin, pyraclostrobin, pyrazophos,
Azoles amine bacterium ester, methoxy benzene pyridine bacterium, pyridinitril, pyrifenox, pyrrole bacterium benzene prestige, pyrimethanil, chloromethane oxy picolinate, chlorine pyrrole furan ether, pyroquilon,
Vinclozolin, fervam, Famoxate, fenapanil, Fenamidone, fenaminosulf, Fenarimol, kind clothing ester, fenoxanil,
Ferimzone, fentin, fenpiclonil, amine benzene pyrrole bacterium ketone, benzoxazole, fenfuram, fenpropidin, butadiene morpholine, fenhexamid, tetrachloro
Phthalide, buthiobate, butylamine, the mite that disappears be more, bupirimate, furidazol, blasticidin-S, furametpyr, furalaxyl, fluacrypyrim, fluorine
Pyridine amine, fluoxastrobin, fluotrimazole, fluopicolide, fluopyram, fluoromide, furcarbanil, fluxapyroxad,
Fluquinconazole, furconazole, iminoctadine alkylbenzene sulfonate, furconazole_cis, fludioxonil, Flusilazole, flusulfamide, fluorine thiophene bacterium be net, fluorine acyl
Amine, Flutriafol, furfural, seed dressing amine, fluorine acyl bacterium amine, flumorph, the third oxygen quinoline, Prochloraz, procymidone, prothiocarb, prothioconazoles,
Propamocarb, propiconazole, Propineb, furan first thiophanate, probenazole, bromuconazole, hexachlorobutadiene, hexaconazole, hexamethylene sulphur phosphorus,
Bethoxazin, M 9834, smart M 9834, benodanil, benomyl, pefurazoate, benquinox, penconazole, Pencycuron, the third azoles grass be grand,
Benthiozole, benzene metsulfovax, benzene metsulfovax isopropyl ester, pyrrole metsulfovax, fluorine azoles bacterium aniline, Boscalid, phosdiphen, ethane phosphonic acid,
It is phosethyl-Al, Polyoxin, polyoxin, Polycarbamate, m-chloro drazoxolon, folpet, maneb, Mancozeb, double
Mandipropamid, myclozolin, nitrile bacterium azoles, midolthromycin, milneb, benzo prestige methasulfocarb, Enestroburin, fluorine thiazole pyrrole ethyl ketone, fourth
Fragrant bacterium ester, chlorine nalidixic bacterium ester, oxazole, pyriminostrobin, alkene oxime amine, fluorine bacterium mite ester, metconazole, metsulfovax, methuroxam, benzene oxygen bacterium
Amine, metrafenone, mepanipyrim, Metalaxyl-M, mebenil, mebenil, pyrrole imidazoles) benzalkonium chloride, basic copper chloride, alkali formula sulfuric acid
Copper, Kocide SD, aclonifen, azafenidin, acifluorfen, azimsulfuron, bispyribac-sodium acid, Acetochlor, atrazine, green bristlegrass are gone
Logical, anilofos, amicarbazone, Ciamexone acid, chlorine ammonia azoles pyridine acid, special careless piperazine ketone, amiprophos-methyl, special saliva ketone, ametryn, first
It is careless amine, allidochlor, alloxydimsodium, isocarbamide, isoxachlorotole, isoxapyrifop, isoxaflutole, ixoxaben, different
Careless fixed, isonoruron, isoproturon, isopropalin, isomethiozin, ipazine, three azole amides, the third delimitation, imazaquin, first
Imazapyr, imazapyr, first Imazethapyr, miaow oxalic acid, miaow acid methyl esters, imazamox, imazosulfuron, indenes piperazine benfluralin,
Indanofan, Yin make a din western acid, uniconazole P, Radix Glycyrrhizae saliva, esprocarb, ethametsulfuron acid, nitre stroke phenol, ethoxysulfuron, ethoxyfenethyl, ethamine
Careless ether, Oxyfluorfen, oryzalin, orthosulfamuron, orbencarb, cafenstrole, than up to agriculture, kecaoan ester, kappa grass spirit, azoles
Ketone grass ester, carfentrazone, karbutilate, double acyls grass, special oxazole prestige, quizalofop-ethyl, Quizalotop-ethyl acid, xylachlor, algae removal be awake, quinone duckweed
Amine, dichloro quinolinic acid, quinmerac, Benzyl grass be grand, chlorine acyl grass phosphine, iodine chlorine pyridine ester, city phosphine, glufosinate-ammonium, smart glufosinate-ammonium, ether grass
Ether, clethodim, alkynes oxalic acid, clopyralid, the third oxygen of chlorine are fixed, neoprene is careless, different evil pine, chlomethoxynil, chlomethoxyfen, chloroformyl grass
Amine, chloroazifoppropynyl, chloranocryl, chlorine ester iodine oxamate complex, cloransulammethyl, the grand acid in the phonetic left side of chlorine, chlorimuronethyl, chlorsulfuron, chlorine phthalandione,
Chlorthiamide, chlortoluron, chlorpropham, bromax, ethoxy benzene is grand, chloroxifenidium, chlortoluron, pinoxaden, chloropon, benzene
Flumetsulam, cyanatryn, Avadex, diuron, dicamba, Alipur-O, cycloxydim, diclosulam, cypromisulfuron, 2,4-
Drip propionic acid, dichlobenil, diclofop acid, diclofop-methyl, dichlormate, diquat dibromide, cisanilide, Tupersan, dithiopyr, dinitramine, Yin
Quinoline ketone grass ester, dinosam, cinosulfuron, dinoseb, dinoterb, Di Lete, cyhalofop-butyl, diphenamide, difenoxuron, Sigma
Saliva, sulphur humulone, sulfentrazone, Sulfosulfuron, Sulfometuron Methyl, sulfometuronmethyl, Bassa, sigh standing grain pyridine, special careless pyridine, is disliked always at swep
Spirit, thiazfluron, three methoxyphenones, triaziflam, triasulfuron, fluorine ketone sulphur grass amine, trichlopyr, trifloxysulfuron, alkynes
Humulone, benzene iodine is grand, bispyribac-sodium, fluorine benzofenap, paclobutrazol, paraquat, halozydine, fluazifop-butyl, efficient fluazifop-butyl, fluorine pyrrole first
Standing grain spirit, fluorine nitre sulfonamide, chlorine pyrrole acyl grass amine, phenobenzuron, fentrazamide, diclofop-methyl thiazole, trifluoromethoxy phenoxy ethyl alcohol, polybenzobisoxazole grass
Nitrile, sulphonyl grass pyrazoles, pyrazoxyfen, pyrazosulfuron, bilanafos, pyribenzoxim, flumetsulam, primisulfuronmethyl acid, phonetic grass
Ether, pyroxsulam, fenoxaprop-P, fenoxapropPethyl, fenoxaprop-P ethyl ester, Zhong Xiling, butroxydim, wheat straw fluorine,
Furyloxyfen, prynachlor, fluazifop acid, efficient fluazifop acid, fluazifop, fluazolate, fluroxypramide, fluorine
Sulphur is grand, the careless life of fluorine, fluoroglycofen-ethyl, three nitre grass ethers, flucarbazonesodium, flucarbazone, KIH 9201, flupyrsulfuron-methyl-sodium, flufenacet,
Octyl trichlamide, bromine bacterium dried meat, propamidine, tetrachloro morning amide, prothioconazoles, fluorine chlorine ether bacterium azoles, fluorine ether bacterium amide, Zhongshengmycin, thiazole
The fixed old element of the gloomy copper of zinc, thiophene, second azoles mite nitrile, 2-cyano-3-amino-3-phenylancryic acetate, S-Ethyl ethylthio sulfonate, phenylsulfonyl ester, toxic fluoride phosphate, Ningnanmycin, Chinese parasol tree, Jinggangmei
Element, matrine, jervine, azalomycin.
Preferably, the active constituent B is avermectin, etoxazole, Envidor, Bifenazate, second azoles mite nitrile, furan worm
Amine, Diacloden, flonicamid, capillary, Rynaxypyr, bromine cyanogen insect amide, emamectin-benzoate, fluorine
Worm bisamide formates, Tolfenpyrad, four chlorantraniliproles, indoxacarb, cyflumetofen, malicious fluorine phosphine, octyl trichlamide, Fluoxastrobin, pyrazoles
One of kresoxim-methyl, fluorine thiazole pyrrole ethyl ketone, isopyrazam, cyhalofop-butyl, fenoxapropPethyl.Preferably, the activity
The mass ratio of ingredient A and active constituent B is 1:10-10:1.
Water dispersible granules, aqueous suspension agent, missible oil, dispersible oil suspension can be made by the way that certain auxiliary agent is added in the composition
Agent, seed treatment, wettable powder, suspoemulsion, smoke agent, aqueous emulsion, micro-capsule suspension, ultra low volume liquids, micro emulsion
Agent etc. is in agriculturally acceptable dosage form.
For composition of the present invention as insecticide, can be used for preventing and treating includes but is not limited to lepidopterous insects, coleoptera elder brother
Worm, Homoptera insect, dipteral insect, hymenopteran, hemipteran, orthopteran, mite class, Thysanoptera insect etc.；
Preferably, the desinsection group things is for preventing and treating mite class, Bemisia tabaci, trialeurodes vaporariorum, thrips, planthopper, tea lesser leafhopper, beet night
Moth, striped flea-beetle, scale insect, pink bollworm, bollworm, cabbage caterpillar, turnip aphid, vegetable aphid, red spider, bridging worm, cotton plant bug,
Tea geometrid, Euproctis pseudoconspersa, pink tea rust mite, leaf goitre mite, citrus leaf moth, citrus cotten aphid, phyllocnistis citrella stainton, rust mite, small heart-eating peach worm and
Oriental fruit months.
Composition of the present invention is as herbicide, suitable for being suitable for preventing and kill off packet hand but be not limited to unwanted dicotyledonous
Plant, monocotyledon, pteridophyte, algae etc., it is preferred that the Herbicidal combinations are preventing and treating answering in undesirable plant
With.Undesirable plant includes grass family, broad-leaved section and/or sedge weed.There is also a desire for plant include Stellaria, beans
Valve Lepidium, knotgrass, Avena, setaria, Europe sinapsis alba category, Lolium, Solanum, Brome, amur foxtail category, Matricaria,
Tong fiber crops category, tribute flower harvest category, Xanthium, Amaranthus, Chenopodium, Ipomoea, crowndaisy chrysanthemum category, Bedstraw and Veronica.Especially for flat
Bar rattan grass, needle spikesedge herb, Herba Cyperi Glomerati, cyperus iria, difformed galingale herb, barnyard grass, rice barnyard grass, herba digitariae, herba eleusines indicae, semen euphorbiae, herba setariae viridis, morning
Ripe standing grain, firefly Lin, Monochoria vaginalis, mexicana, water starwort, dragon's tongue, cyperus iria L. rhizoma scirpi, angustifolia arrowhead herb, bog pondweed, clearvers, shepherd's purse, thorn
Dish, the rhizome of nutgrass flatsedge, acalypha copperleaf, Chenopodiaceae, thorn amaranth, branch amaranth, holds back blue dish, grass of meadow rue, purslane, Procumbent Falsepimpernel, short Brittle Falsepimpernel Herb, Monochoria korsakowii at Siberian cocklebur
Deng.
For composition of the present invention as nematicidal composition, being suitable for prevention and treatment includes but is not limited to plant pathogeny line insect
Disease；Preferably, it can be used for preventing and treating plant pathogeny line insect disease entirely for described group, such as Aphelenchoides, Bursaphelenchus, Ditylenchus dipsaci
Category, ball Heterodera, Heterodera, minute hand Turbatrix want tie lines Eimeria, Pratylenchus, shield Turbatrix, secondary burr line
Eimeria, wooden dipper Turbatrix, thorn Turbatrix, section's cloth Turbatrix, shallow bid spin line Eimeria, the Turbatrix that spirals, cone Turbatrix, tie nematode
Category, spot rubber-insulated wire Eimeria, small loop wire Eimeria, five ditch Eimerias, sheath Turbatrix, Man Turbatrix, sub- Turbatrix, half Criconemoides, wheel line
Crop nematodiasis caused by Eimeria.
Composition of the present invention as fungicide, be suitable for prevention and treatment include but is not limited to plant pathogenic fungi venereal disease evil,
Plant pathogenetic bacteria venereal disease evil, the viroses of plant, the preferred composition can be used for preventing and treating the phytophthora root rot of tomato, gray mold,
Leaf rust, spot disease, anthracnose and early phytophthora root rot；The downy mildew of cucumber, powdery mildew, gray mold, anthracnose, wilt disease, black class
Sick and brown class's disease；Grass mould anthracnose and gray mold；Powdery mildew, anthracnose and the wilt disease of pumpkin；The hickie leaf blight of onion,
Black spot, gray mold；Powdery mildew, gray mold and the wilt disease of eggplant；The black spot of shallot；The Leucoplakia and black spot of Chinese cabbage；
The sclerotiniose and gray mold of green pepper；Powdery mildew, anthracnose, wilt disease and the blight dis-ease of muskmelon；The gray mold of lettuce；Red bayberry
Black spot and gray mold；Powdery mildew, anthracnose and the defoliation of persimmon；The canker of citrus, shot hole；It is the scab of pears, black
Pinta and early blight；Gray mold, anthracnose, brown spot, anthrachose of grape, dead-arm, coal spot disease, diplostomiasis and the brown rot of traffic police's grape
Disease；Stem wilt, anthracnose, gray mold and the sclerotiniose of mung bean；The wheel line of the anthracnose of Kidney bean, gray mold and sclerotiniose semen viciae fabae
Disease；The purple spot of soybean；The powdery mildew of tobacco；The brown spot and spot disease of beet；The anthracnose of tea, zonate spot and sprouting are withered
Disease；The plant diseases such as scab, anthracnose, gray mold and the powdery mildew of flower class；Rice sheath blight disease and false smut.
The present composition can also be administered in combination with other active components, and the other active components can be sterilization
Agent, attractant, insecticide, acaricide, nematicide, growth regulator, herbicide, safener, fertilizer or semiochemical etc..
Preferably, the composition is nopinene and avermectin, nopinene and emamection benaoate, β-
Firpene and flonicamid, nopinene and clothianidin, nopinene and etoxazole.The mass ratio of nopinene and active constituent B is
1:10-10:1.These compositions have good effect in prevention and treatment red spider.
Compared with prior art, it advantages of the present invention and has the beneficial effect that
Nopinene is the broad spectrum activity synergist of a kind of desinsection/microbial inoculum and herbicide in the present invention, and effective ingredient is promoted to enter
The intracorporal efficient transdermal enhancer of activity, to reduce pesticide dosage, the use of nopinene synergist, drug effect enhances, and drug effect is fast
Speed is conducive to preferably play the effect of chemical pesticide and it can be made to increase the preventive effect to harmful organism, reduces chemical pesticide amount
Use, reduce cost, preserve the ecological environment, delay harmful organism to the drug resistance of chemical pesticide.
Specific embodiment
For clearer expression the present invention program, below in conjunction with specific embodiment to the present invention further specifically
It is bright, but it is not limited to protection scope of the present invention.
One, test and method
Using slide infusion process evaluation nopinene and other acaricides to citrus Tetranychus cinnabarinus and panonychus citri, with minimum
Square law calculates virulence equation and lethal concentration of 50 LC50, toxicity index and mixed co-toxicity coefficient according to Sun Yunpei calculating medicament
(CTC value).
According to Sun Yunpei's Method, the synergistic effect of pharmacy mix is evaluated according to co-toxicity coefficient (CTC), i.e. CTC≤80 are association
Same antagonism, 80 < CTC < 120 are joint action of antagonism, and CTC >=120 are synergistic function.Survey toxicity index
(ATI)=(LC50 of the LC50/ reagent agent of standard agent) × 100；
The virulence of the percentage composition+B medicament of A medicament refers in toxicity index × mixture of theoretical toxicity index TTI=A medicament
The percentage composition of B medicament in number × mixture；
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] × 100.
Table 1: synergy of the avermectin nopinene to citrus Tetranychus cinnabarinus
As shown in Table 1, nopinene and avermectin mixture make citrus Tetranychus cinnabarinus with synergy between 10:1-1:30
With.
Table 2: synergy of the etoxazole nopinene to citrus Tetranychus cinnabarinus
As shown in Table 2, nopinene and etoxazole mixture make citrus Tetranychus cinnabarinus with synergy between 100:1-1:100
With.
Table 3: synergy of the Envidor nopinene to citrus Tetranychus cinnabarinus
| Reagent agent | Proportion | LC50(μg/ml) | ATI | TTI | CTC |
| Envidor | - | 4.220 | 30252.60664 | ||
| Nopinene | - | 1468.00 | 100 | ||
| Nopinene: Envidor | 100:1 | 282.562 | 519.53 | 443.40 | 117.17 |
| Nopinene: Envidor | 50:1 | 157.469 | 932.24 | 779.86 | 119.54 |
| Nopinene: Envidor | 30:1 | 97.575 | 1504.49 | 1220.38 | 123.28 |
| Nopinene: Envidor | 10:1 | 32.294 | 4545.78 | 3253.02 | 139.74 |
| Nopinene: Envidor | 5:1 | 15.540 | 9446.35 | 5882.28 | 160.59 |
| Nopinene: Envidor | 3.1 | 8.793 | 16694.27 | 8771.68 | 190.32 |
| Nopinene: Envidor | 1:1 | 5.409 | 27138.39 | 17443.36 | 155.58 |
| Nopinene: Envidor | 1:5 | 3.635 | 40385.80 | 29004.45 | 139.24 |
| Nopinene: Envidor | 1:10 | 3.728 | 39377.64 | 31633.71 | 124.48 |
| Nopinene: Envidor | 1:30 | 3.531 | 41571.42 | 33642.00 | 123.57 |
| Nopinene: Envidor | 1:50 | 3.535 | 41528.52 | 34106.87 | 121.76 |
| Nopinene: Envidor | 1:100 | 3.543 | 41438.03 | 34439.85 | 120.32 |
| Nopinene: Envidor | 1:150 | 24.400 | 6016.51 | 34557.80 | 17.41 |
As shown in Table 3, nopinene and Envidor mixture make citrus Tetranychus cinnabarinus with synergy between 50:1-1:50
With.
Table 4: synergy of the Bifenazate nopinene to citrus Tetranychus cinnabarinus
As shown in Table 4, nopinene and Bifenazate mixture make citrus Tetranychus cinnabarinus with synergy between 30:1-1:30
With.
Table 5: synergy of the second azoles mite nitrile nopinene to citrus Tetranychus cinnabarinus
| Reagent agent | Proportion | LC50(mg/ml) | ATI | TTI | CTC |
| Second azoles mite nitrile | - | 0.950 | 134328.7037 | ||
| Nopinene | - | 1.468 | 100 | ||
| Nopinene: second azoles mite nitrile | 150:1 | 1.232 | 119.16 | 100.35 | 118.74 |
| Nopinene: second azoles mite nitrile | 100:1 | 1.215 | 120.78 | 100.54 | 120.13 |
| Nopinene: second azoles mite nitrile | 50:1 | 1.188 | 123.56 | 101.07 | 122.25 |
| Nopinene: second azoles mite nitrile | 30:1 | 1.106 | 132.77 | 101.76 | 130.47 |
| Nopinene: second azoles mite nitrile | 10:1 | 0.842 | 174.34 | 104.96 | 166.11 |
| Nopinene: second azoles mite nitrile | 5:1 | 0.704 | 208.52 | 109.09 | 191.15 |
| Nopinene: second azoles mite nitrile | 3.1 | 0.620 | 236.66 | 113.63 | 208.27 |
| Nopinene: second azoles mite nitrile | 1:1 | 0.582 | 252.27 | 127.26 | 198.23 |
| Nopinene: second azoles mite nitrile | 1:5 | 0.586 | 250.66 | 145.44 | 172.35 |
| Nopinene: second azoles mite nitrile | 1:10 | 0.624 | 235.32 | 149.57 | 157.33 |
| Nopinene: second azoles mite nitrile | 1:30 | 0.668 | 219.78 | 152.66 | 143.97 |
| Nopinene: second azoles mite nitrile | 1:50 | 0.705 | 208.15 | 153.46 | 135.64 |
| Nopinene: second azoles mite nitrile | 1:100 | 0.751 | 195.37 | 153.97 | 126.89 |
| Nopinene: second azoles mite nitrile | 1:150 | 0.812 | 180.87 | 154.17 | 117.32 |
As shown in Table 5, nopinene and second azoles mite nitrile mixture have synergy to citrus Tetranychus cinnabarinus between 100:1-1:100
Effect.
Table 6: synergy of the dinotefuran nopinene to tomato Bemisia tabaci (two age nymphs)
| Reagent agent | Proportion | LC50(mg/ml) | ATI | TTI | CTC |
| Dinotefuran | - | 0.468 | 2091.03 | ||
| Nopinene | - | 1.468 | 100 | ||
| Nopinene: dinotefuran | 100:1 | 1.477 | 99.38 | 102.12 | 97.32 |
| Nopinene: dinotefuran | 50:1 | 1.311 | 111.97 | 104.19 | 107.47 |
| Nopinene: dinotefuran | 30:1 | 1.192 | 123.19 | 106.90 | 115.24 |
| Nopinene: dinotefuran | 10:1 | 0.998 | 147.09 | 119.42 | 123.17 |
| Nopinene: dinotefuran | 5:1 | 0.782 | 187.77 | 135.62 | 138.45 |
| Nopinene: dinotefuran | 3.1 | 0.625 | 234.91 | 153.42 | 153.12 |
| Nopinene: dinotefuran | 1:1 | 0.575 | 255.32 | 206.84 | 123.44 |
| Nopinene: dinotefuran | 1:5 | 0.434 | 338.20 | 278.06 | 121.63 |
| Nopinene: dinotefuran | 1:10 | 0.414 | 354.22 | 294.25 | 120.38 |
| Nopinene: dinotefuran | 1:30 | 0.405 | 362.71 | 306.55 | 118.32 |
| Nopinene: dinotefuran | 1:50 | 0.410 | 357.89 | 309.49 | 115.64 |
| Nopinene: dinotefuran | 1:100 | 0.451 | 325.77 | 311.53 | 104.57 |
| Nopinene: dinotefuran | 1:150 | 0.478 | 307.02 | 312.26 | 98.32 |
As shown in Table 6, nopinene and it is dinotefuran mixed between 10:1-1:10 to tomato Bemisia tabaci have synergistic effect.
Table 7: synergy of the Diacloden nopinene to tomato Bemisia tabaci (two age nymphs)
As shown in Table 7, nopinene and Diacloden mixture have synergistic effect to tomato Bemisia tabaci between 5:1-1:1.
Table 8: synergy of the flonicamid nopinene to tomato Bemisia tabaci (two age nymphs)
| Reagent agent | Proportion | LC50(μg/ml) | ATI | TTI | CTC |
| Flonicamid | - | 0.578 | 1693.08 | ||
| Nopinene | - | 1468 | 100 | ||
| Nopinene: flonicamid | 100:1 | 47.994 | 3058.73 | 2613.41 | 117.04 |
| Nopinene: flonicamid | 50:1 | 24.142 | 6080.58 | 5076.03 | 119.79 |
| Nopinene: flonicamid | 30:1 | 14.185 | 10348.81 | 8300.30 | 124.68 |
| Nopinene: flonicamid | 10:1 | 4.531 | 32397.68 | 23177.62 | 139.78 |
| Nopinene: flonicamid | 5:1 | 2.289 | 64137.32 | 42421.67 | 151.19 |
| Nopinene: flonicamid | 3.1 | 1.278 | 114896.07 | 63569.81 | 180.74 |
| Nopinene: flonicamid | 1:1 | 0.705 | 208319.57 | 127039.62 | 163.98 |
| Nopinene: flonicamid | 1:5 | 0.481 | 305062.06 | 211657.57 | 144.13 |
| Nopinene: flonicamid | 1:10 | 0.477 | 307584.04 | 230901.62 | 133.21 |
| Nopinene: flonicamid | 1:30 | 0.476 | 308450.49 | 245601.15 | 125.59 |
| Nopinene: flonicamid | 1:50 | 0.485 | 302389.49 | 249003.21 | 121.44 |
| Nopinene: flonicamid | 1:100 | 0.491 | 299138.69 | 251440.44 | 118.97 |
| Nopinene: flonicamid | 1:150 | 0.523 | 280637.33 | 252303.64 | 111.23 |
As shown in Table 8, nopinene and flonicamid mixture have synergy to tomato Bemisia tabaci between 30:1-1:100
Effect.
Colby equation is used to determine the desired effect of mixture, and following equatioies contain two kinds of active components A for calculating
Activity it is expected in mixing with B:
In formula:
The effect of active components A of same concentrations used in the mixture that A=is observed
The effect of active constituent B of same concentrations used in the mixture that B=is observed
When the concentration activity actual observation value used in the mixture is greater than desired value, mixture, which shows as having target, to be expected
Less than synergistic effect.
The prevention and treatment percentage (%) of OBS- observation；Prevention and treatment percentage (%) desired by Exp-Colby equation.
Table 9: nopinene and capillary test the synergistic effect of rice leaf roller
3 days investigation preventive effects after medicine, for test method referring to GBT 17980.2-2000, chlorfenapyr is raw using commercially available Guangxi rural area
The 240g/L capillary SC of production, 30 grams/acre (45 liters of water)), learn nopinene and capillary to rice leaf roller from test result
Prevention and treatment has good coordinative role.
Table 10: nopinene and Rynaxypyr test the synergistic effect of rice leaf roller
3 days investigation preventive effects after medicine, test method use commercially available FMC referring to GBT 17980.2-2000, Rynaxypyr
5% Rynaxypyr SC of production, 20 grams/acre (45 liters of water).It is learnt from test result, nopinene and Rynaxypyr pair
Rice leaf roller has synergistic effect well.
Table 11: nopinene and bromine cyanogen insect amide test the synergistic effect of rice leaf roller
3 days investigation preventive effects after medicine, test method use commercially available BASF referring to GBT 17980.2-2000, bromine cyanogen insect amide
10% bromine cyanogen insect amide SC of production, 20 grams/acre (45 liters of water).Learn that nopinene and bromine cyanogen insect amide are vertical to rice from test result
Leaf roll snout moth's larva has synergistic effect well.
Table 12: nopinene and emamectin-benzoate test the synergistic effect of rice leaf roller
3 days investigation preventive effects after medicine, test method make referring to GBT 17980.2-2000, emamectin-benzoate
The 5% emamectin-benzoate ME won with commercially available Shandong capital, 20 grams/acre (45 liters of water).It is learnt from test result, β-
Firpene and emamectin-benzoate have synergistic effect well to rice leaf roller.
Table 13: nopinene and fipronil bisamide formates test the synergistic effect of rice leaf roller
4 days investigation preventive effects after medicine, test method use commercially available referring to GBT 17980.2-2000, fipronil bisamide formates
20% fipronil bisamide formates SC of Jiangsu dragon lantern, 30 grams/acre (45 liters of water).It is learnt from test result, nopinene and fluorine worm
Bisamide formates has good synergy to rice leaf roller.
Table 14: nopinene and Tolfenpyrad test the synergistic effect of rice leaf roller
4 days investigation preventive effects after medicine, test method are reached referring to GBT 17980.2-2000, Tolfenpyrad using commercially available Japanese Cao
15% Tolfenpyrad SC, 30 grams/acre (45 liters of water).It is learnt from test result, nopinene and Tolfenpyrad are to rice leaf roller
With good synergistic effect.
Table 15: nopinene and four chlorantraniliproles test the synergistic effect of rice leaf roller
4 days investigation preventive effects after medicine, test method use commercially available Shenyang section referring to GBT 17980.2-2000, four chlorantraniliproles
10% 4 chlorantraniliprole SC of wound, 6 grams/acre (45 liters of water).It is learnt from test result, nopinene and four chlorantraniliproles are to the vertical volume of rice
Leaf snout moth's larva has synergistic effect well.
Table 16: nopinene and indoxacarb test the synergistic effect of tea lesser leafhopper
3 days investigation preventive effects after medicine, test method use the 5% of commercially available Bayer referring to GBT 17980.2-2000, indoxacarb
Indoxacarb missible oil 10 grams/acre (45 liters of water), learns that nopinene and indoxacarb have very well tea lesser leafhopper from test result
Synergistic effect.
Table 17: nopinene and cyflumetofen test the synergistic effect of citrus red mite
3 days investigation preventive effects after medicine, test method use the rich beauty in the commercially available U.S. referring to GBT 17980.2-2000, cyflumetofen
20% real cyflumetofen missible oil, 10 grams/acre (45 liters of water).Test result shows that nopinene and cyflumetofen are to the red spider of citrus
Spider has good trade-off effect.
Table 18: nopinene and malicious fluorine phosphine test the synergistic effect of bacterial wilt of peanut
14 days investigation preventive effects after medicine, test method use commercially available Guangxi rural area referring to GBT 17980.2-2000, malicious fluorine phosphine
25% malicious fluorine phosphine WP, 30 grams/acre (45 liters of water), test result show, and nopinene and malicious fluorine phosphine are to bacterial wilt of peanut with very
Good synergistic effect.
Table 19: nopinene and octyl trichlamide test the synergistic effect of pepper ralstonia solanacearum
14 days investigation preventive effects after medicine, test method use fast in commercially available Guangdong referring to GBT 17980.2-2000, octyl trichlamide
15% octyl trichlamide aqua, 60 grams/acre (45 liters of water).Test result shows that nopinene and octyl trichlamide have pepper ralstonia solanacearum
Synergistic effect well.
Table 20: nopinene and Fluoxastrobin test the synergistic effect of rice sheath blight disease
14 days investigation preventive effects after medicine, test method use commercially available Anhui methylene blue referring to GBT 17980.2-2000, Fluoxastrobin
25% Fluoxastrobin SC, 30 grams/acre (45 liters of water).Test result shows that nopinene and Fluoxastrobin have very rice sheath blight disease
Good synergistic effect.
Table 21: nopinene and pyraclostrobin test the synergistic effect of rice sheath blight disease
14 days investigation preventive effects after medicine, test method use Shandong Kang Qiao referring to GBT 17980.2-2000, pyraclostrobin
25% pyraclostrobin missible oil of Biotechnology Co., Ltd, 10 grams/acre (45 liters of water).It is learnt from above-mentioned test result, nopinene
There is synergistic effect well to rice sheath blight disease with pyraclostrobin.
Table 22: nopinene and fluorine thiazole pyrrole ethyl ketone test the synergistic effect of downy mildew of garpe
14 days investigation preventive effects after medicine, test method use commercially available beauty referring to GBT 17980.2-2000, fluorine thiazole pyrrole ethyl ketone
10% fluorine thiazole pyrrole ethyl ketone OD of Du Pont, state, 10 grams/acre (45 liters of water).The results show that nopinene and fluorine thiazole pyrrole ethyl ketone are to Portugal
The prevention and treatment of grape downy mildew has good synergy.
Table 23: nopinene and isopyrazam test the synergistic effect of downy mildew of garpe
14 days investigation preventive effects after medicine, test method use commercially available Switzerland referring to GBT 17980.2-2000, isopyrazam
30% isopyrazam SC of Syngenta, 10 grams/acre (45 liters of water).Test result shows that nopinene and isopyrazam are to Portugal
Grape downy mildew has good synergy.
Table 24: nopinene and cyhalofop-butyl test the synergistic effect of rice a thousand pieces of gold
14 days investigation preventive effects after medicine, test method use commercially available cyanogen fluorine grass referring to GBT 17980.2-2000, cyhalofop-butyl
Ester 20% (missible oil), 10 grams/acre (45 liters of water).The results show that nopinene and cyhalofop-butyl have association well to rice a thousand pieces of gold
Same effect.
Table 25: nopinene and fenoxapropPethyl test the synergistic effect of cogongrass
14 days investigation preventive effects after medicine, test method use commercially available mountain referring to GBT 17980.2-2000, fenoxapropPethyl
The prosperous 220g/L fenoxapropPethyl missible oil of east emigrant, 20 grams/acre (45 liters of water).Nopinene and fenoxapropPethyl have cogongrass
Synergistic effect well.
Embodiment 1:5% abamectin emulsifiable concentrate
By weight: 5% avermectin, 6% nonylphenol polyethylene ether, 4% dodecyl sulphate calcium, 50% nopinene,
Trimethylbenzene complements to 100%.Active constituent avermectin and nopinene and other other auxiliary agents and filler are stirred evenly
5% abamectin emulsifiable concentrate is obtained afterwards.Through detecting, emulsibility, 200 times of dilutions without precipitating without oil slick, 54 ± 2 DEG C of heat storage, cold storage 0 ±
It is 2 DEG C after 14 days, not stratified, it does not crystallize, resolution ratio 1.7%.Mu with 4.5 grams be watered 45 liters by spraying prevention and treatment citrus red mite medicine after 3
Its control efficiency 100%.
Embodiment 2:10% etoxazole microemulsion
By weight: 10% etoxazole, 15% nonylphenol polyethylene ether, 15% dodecyl sulphate calcium, 30% nopinene,
3% glycerine, 0.1% organic silicon defoamer, water complement to 100%.After active constituent etoxazole is dissolved with nopinene, it is added
Nonylphenol polyethylene ether and dodecyl sulphate calcium put into water and organic silicon defoamer, 10% second after stirring to transparency liquid again
Mite azoles microemulsion.Through detecting, 200 times of dilutions are colorless and transparent, -5 DEG C -65 DEG C of transparency temperature range, store 54 ± 2 DEG C through overheat,
Cold 0 ± 2 DEG C of storage is not stratified after 14 days, does not crystallize, resolution ratio 3.8%.Mu is watered 45 liters with 10 grams and prevents and treats citrus red mite by spraying
3 days control efficiency 97.24% after medicine
Embodiment 3:30% Envidor suspoemulsion
By weight: 30% Envidor, 3% glycerine, 20% nopinene, 5% succinic acid polyethenoxy ether sodium sulfate,
1% nonylphenol polyoxyethylene ether phosphonates, 1% aluminium-magnesium silicate, 0.1% xanthan gum, water complement to 100%.By active constituent spiral shell
After mixing evenly, the speed with high-speed shearing machine at 9000 revs/min shears material for mite and nopinene and other auxiliary agents and filler
30 minutes；After having sheared, 2 hours are sanded using sand mill, until effective component partial size obtains the suspension of stable and uniform less than 5 μm
System obtains 30% Envidor suspending agent；Through detecting, suspensibility >=98%, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is after 14 days, regardless of
Layer, do not crystallize, resolution ratio 2.7%, suspensibility >=98%. mu with 10 grams be watered 45 liters by spraying prevent and treat citrus red mite medicine after 14 days
Control efficiency 93.89%
Embodiment 4:5% second azoles mite nitrile suspoemulsion
By weight: 5% second azoles mite nitrile, 3% glycerine, 15% nopinene, 5% succinic acid polyethenoxy ether sodium sulfate,
1% nonylphenol polyoxyethylene ether phosphonates, 1% aluminium-magnesium silicate, 0.1% xanthan gum, water complement to 100%.By active constituent spiral shell
After mixing evenly, the speed with high-speed shearing machine at 9000 revs/min shears material for mite and nopinene and other auxiliary agents and filler
30 minutes；After having sheared, 2 hours are sanded using sand mill, until effective component partial size obtains the suspension of stable and uniform less than 5 μm
System obtains 5% second azoles mite nitrile；Through detecting, suspensibility >=98%, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is not stratified after 14 days, no
Crystallization, resolution ratio 2.7%, suspensibility >=98%. mu with 2 grams be watered 45 liters by spraying prevent and treat citrus red mite medicine after prevention and treatment in 14 days effect
Fruit 99.03%.
Embodiment 5:43% Bifenazate suspoemulsion
By weight: 43% Bifenazate, 3% glycerine, 20% nopinene, 5% succinic acid polyethenoxy ether sodium sulfate,
1% nonylphenol polyoxyethylene ether phosphonates, 1% aluminium-magnesium silicate, 0.1% xanthan gum, water complement to 100%.By active constituent spiral shell
After mixing evenly, the speed with high-speed shearing machine at 9000 revs/min shears material for mite and nopinene and other auxiliary agents and filler
30 minutes；After having sheared, 2 hours are sanded using sand mill, until effective component partial size obtains the suspension of stable and uniform less than 5 μm
System obtains 43% Bifenazate；Through detecting, suspensibility >=97%, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is not stratified after 14 days,
Do not crystallize, resolution ratio 2.7%, suspensibility >=98%. mu with 3 grams be watered 45 liters by spraying prevent and treat citrus red mite medicine after 14 days prevent and treat
Effect 99.39%.
Oil suspending agent can be dispersed in embodiment 6:20% dinotefuran
By weight: 20% dinotefuran, 3% glycerine, 20% nopinene, 15% castor oil polyoxyethylene ether, oleic acid first
Ester complements to 100%.Active constituent furan is pacified into amine and nopinene and other auxiliary agents and filler after mixing evenly, uses high speed shear
Machine is sheared material 30 minutes in 9000 revs/min of speed；After having sheared, 2 hours are sanded using sand mill, until effective component grain
Diameter obtains the suspension system of stable and uniform less than 5 μm, obtains 20% dinotefuran oil-suspending agent；Through detecting, suspensibility >=98%, heat storage
54 ± 2 DEG C, cold 0 ± 2 DEG C of storage is not stratified after 14 days, does not crystallize, resolution ratio 2.7%, suspensibility >=96%. mu are watered with 20 grams
45 liters are prevented and treated 7 days control efficiency 98.42% after tomato Bemisia tabaci medicine by spraying
Oil suspending agent can be dispersed in embodiment 7:20% Diacloden
By weight: 20% Diacloden, 3% glycerine, 20% nopinene, 15% castor oil polyoxyethylene ether, oleic acid first
Ester complements to 100%.Active constituent furan is pacified into amine and nopinene and other auxiliary agents and filler after mixing evenly, uses high speed shear
Machine is sheared material 30 minutes in 9000 revs/min of speed；After having sheared, 2 hours are sanded using sand mill, until effective component grain
Diameter obtains the suspension system of stable and uniform less than 5 μm, obtains 20% Diacloden oil-suspending agent；Through detecting, suspensibility >=98%, heat storage
54 ± 2 DEG C, cold 0 ± 2 DEG C of storage is not stratified after 14 days, does not crystallize, resolution ratio 3.7%, suspensibility >=96%. mu are watered with 20 grams
45 liters are prevented and treated 7 days control efficiency 91.29% after tomato Bemisia tabaci medicine by spraying
Oil suspending agent can be dispersed in embodiment 8:30% flonicamid
By weight: 30% flonicamid, 3% glycerine, 20% nopinene, 15% castor oil polyoxyethylene ether, oil
Sour methyl esters complements to 100%.Active constituent furan is pacified into amine and nopinene and other auxiliary agents and filler after mixing evenly, with high speed
Cutter is sheared material 30 minutes in 9000 revs/min of speed；After having sheared, using sand mill be sanded 2 hours, until effectively at
Gradation diameter obtains the suspension system of stable and uniform less than 5 μm, obtains 20% flonicamid oil-suspending agent；Through detecting, suspensibility >=
98%, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is not stratified after 14 days, does not crystallize, resolution ratio 3.7%, suspensibility >=97%. mu use
20 grams are watered 45 liters and prevent and treat 7 days control efficiency 95.49% after tomato Bemisia tabaci medicine by spraying
Embodiment 9:6% emamectin benzoate capillary missible oil
By weight: 1% methylamino man abamectin benzoate, 5% capillary, 4% dodecyl sulphate calcium, 20%
Trimethylbenzene, nopinene complement to 100%.Active constituent methylamino man abamectin benzoate and capillary nopinene is molten
Xie Hou, by other other auxiliary agents and stirring solvent it is uniform after 6% emamectin benzoate capillary missible oil.Through detecting, emulsibility,
For 200 times of dilutions without precipitating without oil slick, 54 ± 2 DEG C of heat storage is not stratified after 0 ± 2 DEG C of cold storage 14 days, does not crystallize, resolution ratio
1.7%.Mu is watered 45 liters with 50 grams and prevents and treats paddy rice rice leaf roller, 3 days control efficiency 99.37% after medicine by spraying.
Embodiment 10:10% Rynaxypyr can wet-milling
By weight: 10% Rynaxypyr, 20% nopinene, 5% sodium lignin sulfonate, 3% dodecyl sulphate
Sodium, 4% dodecyl sulphate calcium, 20% white carbon black, soil powder complement to 100%.After nopinene white carbon black absorption, by β-
Firpene female powder, Rynaxypyr stir evenly other other auxiliary agents and filler by air-flow crushing 30 minutes, and partial size≤
350 mesh, after 10% chlorine worm benzoyl can wet-milling.Through detecting, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is not hardened after 14 days, point
Solution rate 1.7%.Mu is watered 45 liters with 20 grams and prevents and treats paddy rice rice leaf roller, 3 days control efficiency 96.79% after medicine by spraying.
Embodiment 11:20% bromine cyanogen insect amide can wet-milling
By weight: 20% bromine cyanogen insect amide, 10% nopinene, 5% sodium lignin sulfonate, 3% lauryl sodium sulfate,
4% dodecyl sulphate calcium, 20% white carbon black, soil powder complement to 100%.After nopinene white carbon black absorption, by β-pinane
Alkene female powder, Rynaxypyr stir evenly other other auxiliary agents and filler by air-flow crushing 30 minutes, partial size≤350
Mesh, after 20% bromine cyanogen insect amide can wet-milling.Through detecting, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is after 14 days, not hardened, resolution ratio
1.7%.Mu is watered 45 liters with 15 grams and prevents and treats paddy rice rice leaf roller, 3 days control efficiency 94.22% after medicine by spraying.
Embodiment 12:30% fipronil bisamide can wet-milling
By weight: 30% fipronil bisamide, 20% nopinene, 5% sodium lignin sulfonate, 3% lauryl sodium sulfate,
4% dodecyl sulphate calcium, 20% white carbon black, soil powder complement to 100%.After nopinene white carbon black absorption, by β-pinane
Alkene female powder, Rynaxypyr stir evenly other other auxiliary agents and filler by air-flow crushing 30 minutes, partial size≤350
Mesh, after 30% fipronil bisamide can wet-milling.Through detecting, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is after 14 days, not hardened, resolution ratio
1.7%.Mu is watered 45 liters with 10 grams and prevents and treats paddy rice rice leaf roller, 3 days control efficiency 93.78% after medicine by spraying.
Embodiment 13:5% methylamino man's abamectin benzoate microemulsion
By weight: 5% methylamino man abamectin benzoate, 20% nonylphenol polyethylene ether, 10% dodecyl
Calcium sulfate, 20% nopinene, 3% glycerine, 0.1% organic silicon defoamer, water complement to 100%.By 5 methylamino of active constituent
After man's abamectin benzoate is dissolved with nopinene, nonylphenol polyethylene ether and dodecyl sulphate calcium is added, stirs to saturating
Water and organic silicon defoamer, 10% etoxazole microemulsion are put into after prescribed liquid again.Through detecting, 200 times of dilutions are colorless and transparent, thoroughly
- 5 DEG C -65 DEG C of bright temperature range, through 54 ± 2 DEG C of overheat storage, cold 0 ± 2 DEG C of storage is not stratified after 14 days, does not crystallize, resolution ratio
3.8%.Mu with 40 grams be watered 45 liters by spraying prevention and treatment green vegetables beet armyworm medicine after 3 days control efficiency 95.16%
Embodiment 14:5% Tolfenpyrad ultra low volume liquids
By weight: 5% Tolfenpyrad, 8% castor oil polyoxyethylene ether, 2% lauryl sodium sulfate, 10% β-pinane
Alkene, methyl oleate complement to 100%.After activity is dissolved at Tolfenpyrad with nopinene, be added castor oil polyoxyethylene ether and
5% Tolfenpyrad ultra low volume liquids are obtained after lauryl sodium sulfate and other auxiliary agents and stirring solvent are uniform.Through detecting,
Without precipitating without oil slick, 54 ± 2 DEG C of heat storage is not stratified after 0 ± 2 DEG C of cold storage 14 days for emulsibility, 200 times of dilutions, does not crystallize, point
Solution rate 1.7%.Mu with 4.5 grams be watered 45 liters by spraying prevention and treatment tea lesser leafhopper medicine after 3 days control efficiency 97.32%.
Oil suspending agent can be dispersed in tetra- chlorantraniliprole of embodiment 15:10%
By weight: 10% 4 chlorantraniliprole, 3% glycerine, 30% nopinene, 15% castor oil polyoxyethylene ether, oil
Sour methyl esters complements to 100%.After mixing evenly by four chlorantraniliprole of active constituent and nopinene and other auxiliary agents and filler, it uses
High-speed shearing machine is sheared material 30 minutes in 9000 revs/min of speed；After having sheared, 2 hours are sanded using sand mill, until having
Grain diameter of components is imitated less than 5 μm, the suspension system of stable and uniform is obtained, obtains 20% dinotefuran oil-suspending agent；Through detecting, suspensibility >=
98%, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is not stratified after 14 days, does not crystallize, resolution ratio 2.7%, suspensibility >=96%. mu use
20 grams are watered 45 liters and prevent and treat 7 days control efficiency 97.42% after tomato Bemisia tabaci medicine by spraying
Embodiment 16:5% indoxacarb missible oil
By weight: 5% indoxacarb, 6% nonylphenol polyethylene ether, 4% dodecyl sulphate calcium, nopinene complement to
100%.Active constituent indoxacarb and nopinene and other other auxiliary agents and filler are obtained into 5% indoxacarb cream after mixing evenly
Oil.Through detecting, without precipitating without oil slick, 54 ± 2 DEG C of heat storage is not stratified after 0 ± 2 DEG C of cold storage 14 days for emulsibility, 200 times of dilutions,
It does not crystallize, resolution ratio 1.7%.Mu with 4.5 grams be watered 45 liters by spraying prevention and treatment tea lesser leafhopper medicine after 3 days control efficiency 97.37%.
Embodiment 17:20% cyflumetofen missible oil
By weight: 20% cyflumetofen, 8% nonylphenol polyethylene ether, 4% dodecyl sulphate calcium, nopinene are supplied
To 100%.Active constituent cyflumetofen and nopinene and other other auxiliary agents and filler are obtained into 20% fourth after mixing evenly
Fluorine mite emulsifiable concentrate.Through detecting, without precipitating without oil slick, 54 ± 2 DEG C of heat storage is cold to store 0 ± 2 DEG C 14 days for emulsibility, 200 times of dilutions
Afterwards, not stratified, it does not crystallize, resolution ratio 1.1%.Mu with 10 grams be watered 45 liters by spraying prevent and treat citrus red mite medicine after prevention and treatment in 3 days effect
Fruit 98.12%.
Embodiment 18:15% poison fluorine phosphine can wet-milling
By weight: 15% malicious fluorine phosphine, 10% nopinene, 5% sodium lignin sulfonate, 3% lauryl sodium sulfate, 4%
Dodecyl sulphate calcium, 20% white carbon black, soil powder complement to 100%.After nopinene white carbon black absorption, by nopinene mother
Powder, malicious fluorine phosphine stir evenly other other auxiliary agents and filler by air-flow crushing 30 minutes, partial size≤350 mesh, after
15% malicious fluorine phosphine can wet-milling.Through detecting, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is after 14 days, not hardened, resolution ratio 3.87%.Mu is used
15 grams are watered 45 liters and prevent and treat bacterial wilt of peanut, 3 days control efficiency 96.79% after medicine by spraying.
Embodiment 19:15% octyl trichlamide can wet-milling
By weight: 15% octyl trichlamide, 10% nopinene, 5% sodium lignin sulfonate, 3% lauryl sodium sulfate, 4%
Dodecyl sulphate calcium, 20% white carbon black, soil powder complement to 100%.After nopinene white carbon black absorption, by nopinene mother
Powder, octyl trichlamide stir evenly other other auxiliary agents and filler by air-flow crushing 30 minutes, partial size≤350 mesh, after
15% malicious fluorine phosphine can wet-milling.Through detecting, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is after 14 days, not hardened, resolution ratio 1.81%.Mu is used
15 grams are watered 45 liters and prevent and treat bacterial wilt of peanut, 3 days control efficiency 95.36% after medicine by spraying.
Embodiment 20:25% Fluoxastrobin missible oil
By weight: 25% Fluoxastrobin, 6% nonylphenol polyethylene ether, 4% dodecyl sulphate calcium, nopinene complement to
100%.Active constituent Fluoxastrobin and nopinene and other other auxiliary agents and filler are obtained into 5% indoxacarb cream after mixing evenly
Oil.Through detecting, without precipitating without oil slick, 54 ± 2 DEG C of heat storage is not stratified after 0 ± 2 DEG C of cold storage 14 days for emulsibility, 200 times of dilutions,
It does not crystallize, resolution ratio 1.7%.Mu with 3 grams be watered 45 liters by spraying prevention and treatment banana freckle medicine after 3 days control efficiency 96.42%.
Embodiment 21:20% pyraclostrobin missible oil
By weight: 20% pyraclostrobin, 6% nonylphenol polyethylene ether, 4% dodecyl sulphate calcium, nopinene are mended
Enough to 100%.After mixing evenly by active constituent pyraclostrobin and nopinene and other other auxiliary agents and filler
20% pyraclostrobin missible oil.Through detecting, emulsibility, 200 times of dilutions are without precipitating without oil slick, 54 ± 2 DEG C of heat storage, cold storage 0 ± 2
It is not stratified DEG C after 14 days, it does not crystallize, resolution ratio 1.7%.Mu with 6 grams be watered 45 liters by spraying prevent and treat cucumber anthracnose medicine after 3 days prevent
Control effect 95.35%.
Oil suspending agent can be dispersed in embodiment 22:10% fluorine thiazole pyrrole ethyl ketone
By weight: 10% fluorine thiazole pyrrole ethyl ketone, 3% glycerine, 30% nopinene, 15% castor oil polyoxyethylene ether,
Methyl oleate complements to 100%.Active constituent fluorine thiazole pyrrole ethyl ketone and nopinene and other auxiliary agents and filler are stirred evenly
Afterwards, the speed with high-speed shearing machine at 9000 revs/min is sheared material 30 minutes；After having sheared, it is sanded using sand mill 2 small
When, until effective component partial size obtains the suspension system of stable and uniform less than 5 μm, obtain 20% dinotefuran oil-suspending agent；It is detected, is hanged
Floating rate >=98%, 54 ± 2 DEG C of heat storage is not stratified after 0 ± 2 DEG C of cold storage 14 days, does not crystallize, resolution ratio 1.8%, and suspensibility >=
96%. mu with 10 grams be watered 45 liters by spraying prevent and treat downy mildew of garpe medicine after 14 days control efficiency 95.31%
Embodiment 23:30% isopyrazam can wet-milling
By weight: 30% isopyrazam, 25% nopinene, 6% sodium lignin sulfonate, 3% lauryl sodium sulfate,
4% dodecyl sulphate calcium, 20% white carbon black, soil powder complement to 100%.After nopinene white carbon black absorption, by β-pinane
Alkene female powder, isopyrazam stir evenly other other auxiliary agents and filler by air-flow crushing 30 minutes, partial size≤350
Mesh, after 30% isopyrazam can wet-milling.Through detecting, 54 ± 2 DEG C of heat storage, cold 0 ± 2 DEG C of storage is after 14 days, not hardened, resolution ratio
3.87%.Mu is watered 45 liters with 15 grams and prevents and treats downy mildew of garpe, 3 days control efficiency 95.79% after medicine by spraying.
Embodiment 24:20% cyhalofop-butyl missible oil
By weight: 20% cyhalofop-butyl, 6% alkyl phenol polyvinylether polyoxypropylene, 4% dodecyl sulphate calcium, β-
Firpene complements to 100%.After mixing evenly by active constituent cyhalofop-butyl and nopinene and other other auxiliary agents and filler
Obtain 20% cyhalofop-butyl missible oil.Through detecting, emulsibility, 200 times of dilutions are without precipitating without oil slick, 54 ± 2 DEG C of heat storage, cold storage 0 ± 2
It is not stratified DEG C after 14 days, it does not crystallize, resolution ratio 0.7%.Mu with 10 grams be watered 45 liters by spraying prevent and treat rice a thousand pieces of gold medicine after 7 days prevent
Control effect 99.37%.
Embodiment 25:22% fenoxapropPethyl missible oil
By weight: 22% fenoxapropPethyl, 6% alkyl phenol polyvinylether polyoxypropylene, 4% dodecyl sulphate
Calcium, nopinene complement to 100%.Active constituent cyhalofop-butyl and nopinene and other other auxiliary agents and filler stirring are equal
20% cyhalofop-butyl missible oil is obtained after even.Through detecting, emulsibility, 200 times of dilutions are without precipitating without oil slick, 54 ± 2 DEG C of heat storage, cold storage
It is 0 ± 2 DEG C after 14 days, not stratified, it does not crystallize, resolution ratio 1.2%.Mu with 10 grams be watered 45 liters by spraying prevent and treat cogongrass medicine after 25 days prevent
Control effect 99.37%.
The above content is combine it is specific/further detailed description of the invention for preferred embodiment, cannot
Assert that specific implementation of the invention is only limited to these instructions.General technical staff of the technical field of the invention is come
It says, without departing from the inventive concept of the premise, some replacements or modifications can also be made to the embodiment that these have been described,
And these substitutions or variant are regarded as belonging to the scope of protection of the present invention.
Claims (10)
1. a kind of synergetic pesticide composition containing nopinene, it is characterised in that: the composition pesticide by active components A and B,
Active components A is nopinene, and active constituent B, which is selected from one of following compound or multiple combinations or their Pesticide Science, to be held
Perhaps the mass ratio of salt, the A and B are 1:100-100:1；
3,5- xylyl methyl carbamates (XMC), Dipel Aizawa subspecies
(Bacillusthuringienses aizawai), Bacillus thuringiensis subsp. israelensis (Bacillus
Thuringiensesisraelensis), Dipel Japan subspecies (Bacillus thuringienses
Japonensis), (B-5) Dipel Kurstaki (Bacillus thuringienses kurstaki), Soviet Union
Cloud gold bacillus intend ground beetle subspecies (Bacillus thuringienses tenebrionis), (B-7) Dipel (
Bacillusthuringienses) crystalline protein toxin generated, chlorfenizon, acrinathrin, nimbin, acequinocyl, pyridine worm
Amidine, acetyl worm nitrile, orthene, avermectin, sulfanilamide (SN) mite ester, Amitraz, α -5a,6,9,9a-hexahydro-6,9-methano-2,4, α-cypermethrin, albendazole,
Allethrin, isazofos, isoxathion, isofenphos, Mobucin, ivermectin, imidacloprid, Imiprothrin, indoxacarb, S- cyanogen penta
Pyrethroids, (B-49) ethiofencarb, Ethodan, ethiprole, etoxazole, ethofenprox, phonamiphos, etrimfos, emaricin, angstrom
Ma rhzomorph benzoate, 5a,6,9,9a-hexahydro-6,9-methano-2,4, Prallethrin, oxamyl, cadusafos, cartap, carbaryl, carbosulfan, carbofuran,
Gamma-cyhalothrin, Meobal, quinalphos, kinoprene, chinomethionat, cloethocarb, clothianidin, clofentezine, ring tebufenozide, chlorine
Worm benzamide, chlorethoxyfos, Spanon, Niran, chlopyrifos, chlorpyrifos-methyl, chlorfenapyr, chlorfenizon, (B-89) chlorfenviphos,
Chlorfluazuron, chlorobenzilate, dicofol, cynock, diafenthiuron, Nellite, bromine cyanogen insect amide, efficiently trans- chlorine cyanogen chrysanthemum
Ester, Hooker HRS 16, nitrile pyrrole mite ester, σ-cypermethrin, (B-105) ring bromine insect amide, dichlofenthion, (B-107) cycloprothrin, enemy enemy
Fear, disulfoton, dinotefuran, lambda-cyhalothrin, cyphenothrin, cyfloxylate, diflubenzuron, cyflumetofen, flufenzine, tricyclic
Tin, cypermethrin, dimethylvinphos, Rogor, dimefluthrin, silafluofene, cyromazine, ethyl pleocidin, more sterilizations
Element, Envidor, spiral shell first mite, thiodicarb, thiocyclam, desinsection bisgallic acid, dimehypo, thionazin, thiometon, Metadelphene, Di Shi
Agent, Ravap, tetradiphon, fluorine cyanogen insect amide, etrafluorine ethofenprox, tetramethrin, butyl pyrimidine phosphorus, tebufenozide, tebufenpyrad, seven
Flumethrin, fluorobenzene urea, demeton-methyl, Swebate, decis, terbufos, bromo pyrrole carbonitrile, tralomethrin, phenyl tetrafluoride
Pyrethroids, triaguron, trichlamide, metrifonate, triflumuron, Tolfenpyrad, Nithiazine, Nitenpyram, novaluron, noviflumuron,
Hydroprene, fluorine pyrazoles worm, (B-178) vamidothion, parathion, parathion-methyl, halfenprox, chlorine tebufenozide, bistrifluron,
Dimehypo, hydramethylnon, hydroxypropul starch, binapacryl, Bifenazate, Biphenthrin, pymetrozine, pyraclofos, pyrazine Fipronil,
Pyridaphethione, fluoroform pyrrole ether, pyridine Fipronil, Nylar, Aphox, pyrimidifen, pirimiphos-methyl, pyrethrin, fluorine worm
Nitrile, fenazaquin, fenamiphos, fenisobromolate, fenifrothion, fenoxycarb, fenothiocarb, phenothrin, Bassa, fensulfothion, Entex,
Phenthoate dimephenthoate cidial, fenvalerate, fenpyroximate, Fenpropathrin, Phenbendasol, special Pyrimitate, Buprofezin, furathiocarb, prallethrin, phonetic mite
Ester, fluazinam, fluazuron, fluorine thiophene worm sulfone, flucycloxuron, flucythrinate, DL- taufluvalinate fluorine pyrrole furanone, Flupyrazofos-containpesticide,
Butene-fipronil, phonetic worm amine, flufenoxuron, flufenzine, trifluoro ethofenprox, halfenprox, brofluthrinate, fipronil bisamide, flumethrin,
Fluorine worm sweet smell, Toyodan, fluorobenzene ethofenprox, flonicamid, Kayaphos, propargite, Profenofos, the third Flumethrin, arprocarb, bromine mite
Ester, β-cyfloxylate, flubenzuron, Hexythiazox, seven fluorine methothrins, heptenophos, permethrin, Ficam, bensultap, benzene mite
Spy, Benfuracard micro, phoxim, zolone, lythidathion, fosthietan, phosphamidon, phosphorus worm prestige, phosmet, Carzol, peace sulphur
Phosphorus, thimet, malathion, milbemycin, milbemycin A, milbemectin, Afos, Entex sulfoxide, Methomyl,
The methaldehyde, metaflumizone, acephatemet, metham-sodium, methiocarb, methidathion, enemy line ester, the new decyl amide of methyl, methyl paraoxon,
Metoxadiazone, methoxychlor, methoxyfenozide, metofluthrin, methoprene, MTMC, fluorine chlorine ether pyrethroids, Menite, long
Imitate phosphorus, Cupric sulfate, λ-lambda-cyhalothrin, lufenuron, rayperidin, rotenone, fenbutatin oxide, Morantel Tartrate, bromine first
Alkane, plictran, azithiram, isotianil, chlorobenzene Climbazole, isopyrazam, isopropyl metsulfovax, Isoprothiolane, iprodione,
Iprovalicarb, different rice blast net, imazalil, iminoctadine, metham-sodium, iminoctadine triacetate, uniconazole P, kobam, edifenphos,
Etaconazole, Guardian, ethirimol, Ethisul, ethoxyquinoline, Enestroburin, epoxiconazole, Wakil, oxycarboxin 8-
Copper quinolinate, copper 8-hydroxyquinolinate, dislikes imidazoles, dislikes oxpoconazole fumarate, octhilinone, fenfuram, orysastrobin, Wei Ba at terramycin
Nurse, kasugarnycin, ring propionyl bacterium amine, carbendazim, carboxin, quinoxyfen, chinomethionat, chinomethionat, difoltan, captan, essence
M 9834, azoles oxolinic acide, pentachloronitrobenzene, double pungent guanamines, cufraneb, cuprobam, kresoxim-methyl, chlozolinate, clotrimazole, pest of going out
Azoles, Imugan, tetrachloroquinone, four chloro-quinoxalines, benzene imidazoles bacterium, chlorine nitre naphthalene, Bravo, chloroneb, salicylanilide, zarilamid
Cyazofamid, diethofencarb, ring bacterium amine, double chlorine zarilamid, sclex, diclobutrazol, dichlofluanid, diclomezin, botran, double chlorine
Phenol, dichlone, disulfiram, Plondrel, metalaxyl, dithianon, olefin conversion, olefin conversion M, zineb, dinocap, double pyrrole sulphur
Father-in-law, difenoconazole, cyflufenamid, fluorine mepanipyrim, Cyproconazole, cyprodinil, cyprofuram, cypendazole, simeconazoles, diformazan are phonetic
Phenol, dimethomorph, cymoxanil, dimoxystrobin, bromomethane, ziram, Silthiopham, streptomysin, volution bacterium amine, sultropen, fluorine azoles
Ring bacterium amine, zoxamide, Carbatene, dazomet, milneb, tiadinil, thiophene difluoro probenazole sulphur benzonitrile formamide, Eradex,
Sulphur chlorobenzene imines, thiophanate, thiophanate-methyl, methyl-isorhodanate, thicyofen, thifluzamide, thiram, decafentin, tetrachloro
Nitrobenzene, tecloftalam, thiram connection, fluorine ether azoles, debacarb, Tebuconazole, isobutyl ethoxyquin, dodemorfe, drazoxolon, triazole
Alcohol, triazolone, metalaxyl M, fourth triazole, azoles bacterium piperazine, triamiphos, triarimol, trichlamide, tricyclazole, triticonazole, 13
Quinoline, tributyltin oxide, fluorine bacterium azoles, trifloxystrobin, triforine, Tolylfluanid, tolelofos-methyl, natamycin, nitrothalisopropyl, fluorine
Benzene ancymidol, halacrinate, jinggangmeisu, figured silk fabrics ammonia bacterium ester, super quick albumen, biphenyl pyrrole bacterium amine, ZEN 90160, fluorine pyrrole bacterium
Amine, Bithionol, bitertanol, binapacryl, Biphenthrin, hymexazol, pyraoxystrobin, pyracarbolin, pyraclostrobin, pyrazophos,
Azoles amine bacterium ester, methoxy benzene pyridine bacterium, pyridinitril, pyrifenox, pyrrole bacterium benzene prestige, pyrimethanil, chloromethane oxy picolinate, chlorine pyrrole furan ether, pyroquilon,
Vinclozolin, fervam, Famoxate, fenapanil, Fenamidone, fenaminosulf, Fenarimol, kind clothing ester, fenoxanil,
Ferimzone, fentin, fenpiclonil, amine benzene pyrrole bacterium ketone, benzoxazole, fenfuram, fenpropidin, butadiene morpholine, fenhexamid, tetrachloro
Phthalide, buthiobate, butylamine, the mite that disappears be more, bupirimate, furidazol, blasticidin-S, furametpyr, furalaxyl, fluacrypyrim, fluorine
Pyridine amine, fluoxastrobin, fluotrimazole, fluopicolide, fluopyram, fluoromide, furcarbanil, fluxapyroxad,
Fluquinconazole, furconazole, iminoctadine alkylbenzene sulfonate, furconazole_cis, fludioxonil, Flusilazole, flusulfamide, fluorine thiophene bacterium be net, fluorine acyl
Amine, Flutriafol, furfural, seed dressing amine, fluorine acyl bacterium amine, flumorph, the third oxygen quinoline, Prochloraz, procymidone, prothiocarb, rosickyite bacterium
Azoles, Propamocarb, propiconazole, Propineb, furan first thiophanate, probenazole, bromuconazole, hexachlorobutadiene, hexaconazole, hexamethylene sulphur
Phosphorus, bethoxazin, M 9834, smart M 9834, benodanil, benomyl, pefurazoate, benquinox, penconazole, Pencycuron, the third azoles grass
Grand, benthiozole, benzene metsulfovax, benzene metsulfovax isopropyl ester, pyrrole metsulfovax, fluorine azoles bacterium aniline, Boscalid, phosdiphen, ethyl phosphine
Acid, phosethyl-Al, Polyoxin, polyoxin, Polycarbamate, m-chloro drazoxolon, folpet, maneb, Mancozeb,
Mandipropamid, myclozolin, nitrile bacterium azoles, midolthromycin, milneb, benzo prestige methasulfocarb, Enestroburin, fluorine thiazole pyrrole ethyl ketone,
Coumoxystrobin, chlorine nalidixic bacterium ester, oxazole, pyriminostrobin, alkene oxime amine, fluorine bacterium mite ester, metconazole, metsulfovax, methuroxam, benzene oxygen
Bacterium amine, metrafenone, mepanipyrim, Metalaxyl-M, mebenil, mebenil, pyrrole imidazoles) benzalkonium chloride, basic copper chloride, alkali formula sulphur
Sour copper, Kocide SD, aclonifen, azafenidin, acifluorfen, azimsulfuron, bispyribac-sodium acid, Acetochlor, atrazine, green bristlegrass
Go to lead to, anilofos, amicarbazone, Ciamexone acid, chlorine ammonia azoles pyridine acid, special careless piperazine ketone, amiprophos-methyl, special saliva ketone, ametryn,
Alachlor, allidochlor, alloxydimsodium, isocarbamide, isoxachlorotole, isoxapyrifop, isoxaflutole, ixoxaben,
Isoprocil, isonoruron, isoproturon, isopropalin, isomethiozin, ipazine, three azole amides, the third delimitation, imazaquin,
AC 263222, imazapyr, first Imazethapyr, miaow oxalic acid, miaow acid methyl esters, imazamox, imazosulfuron, indenes piperazine fluorine grass
Amine, indanofan, Yin make a din western acid, uniconazole P, Radix Glycyrrhizae saliva, esprocarb, ethametsulfuron acid, nitre stroke phenol, ethoxysulfuron, ethoxyfenethyl,
Ethamine grass ether, Oxyfluorfen, oryzalin, orthosulfamuron, orbencarb, cafenstrole, than up to agriculture, kecaoan ester, kappa grass
Spirit, carfentrazoneethyl, carfentrazone, karbutilate, double acyls grass, special oxazole prestige, quizalofop-ethyl, Quizalotop-ethyl acid, xylachlor, algae removal
It wakes up, quinone duckweed amine, dichloro quinolinic acid, quinmerac, Benzyl grass are grand, chlorine acyl grass phosphine, iodine chlorine pyridine ester, city phosphine, glufosinate-ammonium, the careless ammonium of essence
Phosphine, ether grass ether, clethodim, alkynes oxalic acid, clopyralid, the third oxygen of chlorine is fixed, neoprene grass, different evil pine, chlomethoxynil, chlomethoxyfen,
Clomeprop, chloroazifoppropynyl, chloranocryl, chlorine ester iodine oxamate complex, cloransulammethyl, the grand acid in the phonetic left side of chlorine, chlorimuronethyl, chlorine sulphur
Grand, chlorine phthalandione, chlorthiamide, chlortoluron, chlorpropham, bromax, ethoxy benzene is grand, chloroxifenidium, chlortoluron, pinoxaden,
Chloropon, benzene flumetsulam, cyanatryn, Avadex, diuron, dicamba, Alipur-O, cycloxydim, diclosulam, cyclopropyl
Sulfometuron Methyl, 2,4- drop propionic acid, dichlobenil, diclofop acid, diclofop-methyl, dichlormate, diquat dibromide, cisanilide, Tupersan, fluorine sulphur grass
Fixed, dinitramine, Yin quinoline ketone grass ester, dinosam, cinosulfuron, dinoseb, dinoterb, Di Lete, cyhalofop-butyl, diphenamide,
Difenoxuron, Simanex, swep, sulphur humulone, sulfentrazone, Sulfosulfuron, Sulfometuron Methyl, sulfometuronmethyl, Bassa, sigh standing grain pyridine,
Old spirit, thiazfluron, three methoxyphenones, triaziflam, triasulfuron, fluorine ketone sulphur grass amine, trichlopyr, three are disliked in special grass pyridine
Fluorine pyridine sulphur is grand, alkynes humulone, benzene iodine are grand, bispyribac-sodium, fluorine benzofenap, paclobutrazol, paraquat, halozydine, fluazifop-butyl, efficient fluorine pyrrole
Standing grain spirit, haloxyfop-P-methyl, fluorine nitre sulfonamide, chlorine pyrrole acyl grass amine, phenobenzuron, fentrazamide, diclofop-methyl thiazole, trifluoromethoxy phenoxy second
Alcohol, pyraclonil, sulphonyl grass pyrazoles, pyrazoxyfen, pyrazosulfuron, bilanafos, pyribenzoxim, flumetsulam, the phonetic sulphur of fluorine
Grand acid, KIH 6127, pyroxsulam, fenoxaprop-P, fenoxapropPethyl, fenoxaprop-P ethyl ester, Zhong Xiling, butylbenzene grass
Ketone, wheat straw fluorine, furyloxyfen, prynachlor, fluazifop acid, efficient fluazifop acid, fluazifop, isopropyl pyrrole grass
Ester, fluroxypramide, fluorine sulphur is grand, the careless life of fluorine, fluoroglycofen-ethyl, three nitre grass ethers, flucarbazonesodium, flucarbazone, KIH 9201, the phonetic sulphur of fluorine pyridine
Grand, flufenacet, octyl trichlamide, bromine bacterium dried meat, propamidine, tetrachloro morning amide, prothioconazoles, fluorine chlorine ether bacterium azoles, fluorine ether bacterium amide, in
Raw rhzomorph, zinc thiazole, the gloomy copper of thiophene, second azoles mite nitrile, 2-cyano-3-amino-3-phenylancryic acetate, S-Ethyl ethylthio sulfonate, phenylsulfonyl ester, toxic fluoride phosphate, Ningnanmycin, Chinese parasol tree are fixed old
Element, jinggangmycin, matrine, jervine, azalomycin.
2. according to claim 1 containing the synergetic pesticide composition of nopinene, it is characterised in that: the active constituent B choosing
From avermectin, etoxazole, Envidor, Bifenazate, second azoles mite nitrile, dinotefuran, Diacloden, flonicamid, capillary, chlorine
Worm benzamide, bromine cyanogen insect amide, emamectin-benzoate, fipronil bisamide formates, Tolfenpyrad, tetrachloro worm
Amide, indoxacarb, cyflumetofen, malicious fluorine phosphine, octyl trichlamide, Fluoxastrobin, pyraclostrobin, fluorine thiazole pyrrole ethyl ketone, isopyrazam,
One of cyhalofop-butyl, fenoxapropPethyl.
3. according to claim 1 containing the synergetic pesticide composition of nopinene, it is characterised in that: the composition is β-
Firpene and avermectin.
4. according to claim 1 containing the synergetic pesticide composition of nopinene, it is characterised in that: the composition is β-pinane
Alkene and emamection benaoate.
5. according to claim 1 containing the synergetic pesticide composition of nopinene, it is characterised in that: the composition is β-pinane
Alkene and flonicamid.
6. according to claim 1 containing the synergetic pesticide composition of nopinene, it is characterised in that: the composition is β-pinane
Alkene and clothianidin.
7. according to claim 1 containing the synergetic pesticide composition of nopinene, it is characterised in that: the composition is β-pinane
Alkene and etoxazole.
8. according to claim 1 containing the synergetic pesticide composition of nopinene, it is characterised in that: the composition is β-pinane
Alkene is second azoles mite nitrile.
9. according to the synergetic pesticide composition containing nopinene described in claim any one of 3-8, it is characterised in that: the activity
The mass ratio of ingredient A and B are 1:10-10:1.
10. according to the synergetic pesticide composition containing nopinene described in claim any one of 3-8, it is characterised in that: described group
Close purposes of the object on prevention and treatment red spider.
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Cited By (6)
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| CN110612983A (en) * | 2019-10-29 | 2019-12-27 | 江苏扬农化工股份有限公司 | Insecticidal composition containing famoxadone and acetamiprid and application thereof |
| CN111449024A (en) * | 2020-04-01 | 2020-07-28 | 军事科学院军事医学研究院环境医学与作业医学研究所 | Method for establishing iodine absorption inhibition rat model |
| CN112239383A (en) * | 2020-10-28 | 2021-01-19 | 中诚国联（河南）生物科技有限公司 | Application of pesticide-fertilizer granules containing dinotefuran and monosultap to rice |
| CN113678821A (en) * | 2021-08-25 | 2021-11-23 | 青岛日晟源作物营养有限公司 | Synergistic auxiliary composition for D-limonene soluble solution |
| CN113712029A (en) * | 2021-09-06 | 2021-11-30 | 四川宸煜林业开发有限责任公司 | Pinene-containing plant protection additive and preparation method thereof |
| CN117426399A (en) * | 2023-12-18 | 2024-01-23 | 海南弘德农林技术有限公司 | Plant-source pesticide fertilizer synergist and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110612983A (en) * | 2019-10-29 | 2019-12-27 | 江苏扬农化工股份有限公司 | Insecticidal composition containing famoxadone and acetamiprid and application thereof |
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| CN111449024A (en) * | 2020-04-01 | 2020-07-28 | 军事科学院军事医学研究院环境医学与作业医学研究所 | Method for establishing iodine absorption inhibition rat model |
| CN112239383A (en) * | 2020-10-28 | 2021-01-19 | 中诚国联（河南）生物科技有限公司 | Application of pesticide-fertilizer granules containing dinotefuran and monosultap to rice |
| CN113678821A (en) * | 2021-08-25 | 2021-11-23 | 青岛日晟源作物营养有限公司 | Synergistic auxiliary composition for D-limonene soluble solution |
| CN113712029A (en) * | 2021-09-06 | 2021-11-30 | 四川宸煜林业开发有限责任公司 | Pinene-containing plant protection additive and preparation method thereof |
| CN117426399A (en) * | 2023-12-18 | 2024-01-23 | 海南弘德农林技术有限公司 | Plant-source pesticide fertilizer synergist and preparation method and application thereof |
| CN117426399B (en) * | 2023-12-18 | 2024-03-08 | 海南弘德农林技术有限公司 | Plant-source pesticide fertilizer synergist and preparation method and application thereof |
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