CN113693067A - Unitary peroxyacetic acid disinfectant and preparation method thereof - Google Patents
Unitary peroxyacetic acid disinfectant and preparation method thereof Download PDFInfo
- Publication number
- CN113693067A CN113693067A CN202110981869.9A CN202110981869A CN113693067A CN 113693067 A CN113693067 A CN 113693067A CN 202110981869 A CN202110981869 A CN 202110981869A CN 113693067 A CN113693067 A CN 113693067A
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- CN
- China
- Prior art keywords
- disinfectant
- acid
- solution
- peroxyacetic acid
- peroxyacetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 title claims abstract description 82
- 239000000645 desinfectant Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 31
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 25
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 239000003381 stabilizer Substances 0.000 claims abstract description 20
- 229960000583 acetic acid Drugs 0.000 claims abstract description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 18
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 239000008213 purified water Substances 0.000 claims description 5
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 4
- 229920001444 polymaleic acid Polymers 0.000 claims description 4
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 4
- 235000012207 sodium gluconate Nutrition 0.000 claims description 4
- 239000000176 sodium gluconate Substances 0.000 claims description 4
- 229940005574 sodium gluconate Drugs 0.000 claims description 4
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 4
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 229940116315 oxalic acid Drugs 0.000 claims description 2
- 229960004838 phosphoric acid Drugs 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 9
- 239000002253 acid Substances 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 6
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 6
- 238000007865 diluting Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 244000005700 microbiome Species 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 230000030833 cell death Effects 0.000 description 1
- 230000006037 cell lysis Effects 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002422 sporicide Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
Abstract
The invention discloses a unitary peroxyacetic acid disinfectant and a preparation method thereof. The invention belongs to the technical field of disinfection, and particularly provides a monoperoxyacetic acid disinfectant and a preparation method thereof. The components and mass percentage are as follows: 4 to 8 percent of hydrogen peroxide, 0.1 to 1 percent of compound stabilizer, 30 to 50 percent of glacial acetic acid, 1 to 3 percent of concentrated sulfuric acid, 0.01 to 0.02 percent of EDTA-2Na and the balance of water. The unitary peroxyacetic acid disinfectant prepared by the invention has a stable system, the peroxyacetic acid in the disinfectant is maintained in a qualified range for a long time and slowly reduced under the action of the compound stabilizer, and a user can directly use the disinfectant after directly diluting the disinfectant into a proper concentration in the disinfection process.
Description
Technical Field
The invention belongs to the technical field of disinfection, and particularly relates to a monoperoxyacetic acid disinfectant and a preparation method thereof.
Background
The peroxyacetic acid solution is an oxidative green ecological bactericide, is a novel sporicide compared with the traditional disinfectant, generally consists of peroxyacetic acid, hydrogen peroxide and acetic acid, and mainly contains the peroxyacetic acid as an active ingredient. It destroys the outer cell membrane and cell wall of microorganism by oxidation, so that the enzyme system is destroyed, the microorganism is inactivated, the peracetic acid can permeate the polypeptide shell of spore, and destroy the macromolecules in spore, such as saccharide, nucleic acid, lipid, etc., finally causing cell lysis and death. The peroxyacetic acid sold in the current market is of two types, one type is binary, the product is divided into A, B components, the A liquid is glacial acetic acid and sulfuric acid, the B liquid is hydrogen peroxide, the two components are separately stored at ordinary times, the A, B components are mixed according to a certain proportion before use, the mixture is reacted to generate peroxyacetic acid solution, and the peroxyacetic acid solution is diluted to the required concentration for use after being placed for 24 to 48 hours.
However, the concentration of peracetic acid after mixing decreases relatively quickly, and the tendency to decrease increases with increasing concentration of peracetic acid. Therefore, in practical application, the preparation can be carried out only according to the required amount of the peroxyacetic acid, which brings great inconvenience to the use and limits the application of the peroxyacetic acid. The other is a primary peroxyacetic acid, which overcomes the defects that some secondary peroxyacetic acids have poor stability, need to be prepared on site, need to be operated by professional personnel, are extremely inconvenient to use and cannot be marketed on a large scale, but the improvement of the stability is a great technical problem in the disinfection field.
Disclosure of Invention
The invention aims to: in order to solve the problems, a monobasic peroxyacetic acid disinfectant and a preparation method thereof are provided.
The technical scheme adopted by the invention is as follows: a monobasic peroxyacetic acid disinfectant and a preparation method thereof comprise: the preparation method of the unitary peroxyacetic acid disinfectant comprises the following steps:
s1, adding the EDTA-2Na with the formula amount into the purified water with the formula amount, stirring and dissolving to obtain solution A for later use;
s2, sequentially adding acetic acid and hydrogen peroxide into the beaker according to the formula ratio, and uniformly stirring and mixing;
s3, slowly adding concentrated sulfuric acid with the formula amount; stirring and reacting for 2 h;
s4, adding a corresponding compound stabilizer, stirring and reacting for 30min to prepare a solution B;
s5, mixing solution A and solution B, and packaging
In a preferred embodiment, the concentration of the hydrogen peroxide solution is 4% to 8%.
In a preferred embodiment, the concentration of the compound stabilizer is 0.1% -2%, and the compound stabilizer comprises one or more of phosphoric acid, sodium gluconate, sodium pyrophosphate, oxalic acid and polymaleic acid.
In a preferred embodiment, the concentration of glacial acetic acid is 30% to 50%.
In a preferred embodiment, the concentrated sulfuric acid has a concentration of 1% to 3%.
In a preferred embodiment, the concentration of the EDTA-2Na solution is 0.01% to 0.02%.
In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:
in the invention, the prepared unitary peroxyacetic acid disinfectant has a stable system, the peroxyacetic acid in the disinfectant is maintained in a qualified range for a long time and slowly decreases under the action of a compound stabilizer, and a user can directly dilute the peroxyacetic acid into a proper concentration in the disinfection process and then directly use the peroxyacetic acid.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are some embodiments of the present invention, but not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
a high-stability monoprotic peroxyacetic acid disinfectant capable of being directly used comprises, by mass, 5% of hydrogen peroxide, 0.1% of a compound stabilizer, 40% of glacial acetic acid, 3% of concentrated sulfuric acid, 0.01% of EDTA-2Na and the balance of water. The compound stabilizer comprises sodium pyrophosphate and polymaleic acid.
The preparation method of the unitary peroxyacetic acid disinfectant comprises the following steps:
step 1: 0.01kg of EDTA-2Na is added into the purified water with the formula amount, and stirred until the mixture is clear, so as to prepare solution A for later use.
Step 2: then, 10kg of 50% hydrogen peroxide and 40kg of glacial acetic acid were mixed uniformly.
And step 3: slowly adding 3kg of concentrated sulfuric acid on the basis of the step 2; stirring and reacting for 2 h;
and 4, step 4: adding 0.1kg of compound stabilizer, stirring and reacting for 30min to prepare a solution B;
and 5: mixing solution A and solution B, stirring, and packaging.
Example 2: 100kg of disinfectant liquid is prepared
A high-stability unary peroxyacetic acid disinfectant capable of being directly used comprises, by mass, 6% of hydrogen peroxide, 0.2% of a compound stabilizer, 40% of glacial acetic acid, 2% of concentrated sulfuric acid, 0.02% of EDTA-2Na, and the balance of water. The compound stabilizer comprises sodium gluconate and phosphoric acid.
The preparation method of the unitary peroxyacetic acid disinfectant comprises the following steps:
step 1: 0.02kg of EDTA-2Na is added into the purified water with the formula amount, and stirred until the mixture is clear, so as to prepare solution A for later use.
Step 2: then, 12kg of 50% hydrogen peroxide and 40kg of glacial acetic acid were mixed uniformly.
And step 3: slowly adding 2kg of concentrated sulfuric acid on the basis of the step 2; stirring and reacting for 2 h;
and 4, step 4: adding 0.2kg of compound stabilizer, stirring and reacting for 30min to prepare a solution B;
and 5: mixing solution A and solution B, stirring, and packaging.
Example 3: 100kg of disinfectant liquid is prepared
A high-stability unary peroxyacetic acid disinfectant capable of being directly used comprises, by mass, 8% of hydrogen peroxide, 0.4% of a compound stabilizer, 50% of glacial acetic acid, 2% of concentrated sulfuric acid, 0.02% of EDTA-2Na, and the balance of water. The compound stabilizer comprises sodium pyrophosphate, polymaleic acid and sodium gluconate.
The preparation method of the unitary peroxyacetic acid disinfectant comprises the following steps:
step 1: 0.02kg of EDTA-2Na is added into the purified water with the formula amount, and stirred until the mixture is clear, so as to prepare solution A for later use.
Step 2: then, 16kg of 50% hydrogen peroxide and 50kg of glacial acetic acid were mixed uniformly.
And step 3: slowly adding 2kg of concentrated sulfuric acid on the basis of the step 2; stirring and reacting for 2 h;
and 4, step 4: adding 0.4kg of compound stabilizer, stirring and reacting for 30min to prepare a solution B;
and 5: mixing solution A and solution B, stirring, and packaging.
The monoperoxyacetic acid disinfectant obtained in the embodiments 1 to 3 of the invention is colorless or light yellow clear transparent liquid.
The monoperoxyacetic acid disinfectant obtained in examples 1-3 was examined by accelerated test. The test shows that the compound has good stability, which is as follows:
and (3) accelerated test: 3 batches of the monoperoxyacetic acid disinfectant obtained by the invention are put in a constant temperature stabilizing box and are respectively treated at 0d, 2d, 4d, 6d, 8d, 12d and 14d under the conditions of 54 +/-2 ℃ and 65% +/-5% RH; the change of the peroxyacetic acid content is measured, and the result shows that the character of the peroxyacetic acid is unchanged and the content is stable under the accelerated test condition, meanwhile, the unitary peroxyacetic acid disinfectant prepared by the invention is stable in system, the peroxyacetic acid in the disinfectant is maintained in a qualified range for a long time under the action of a compound stabilizer and slowly decreases, and a user can directly use the disinfectant after the disinfectant is directly diluted to a proper concentration in the disinfection process.
In particular, see the following table:
TABLE 1 stability test of monoperoxyacetic acid disinfectant
In conclusion, the unitary peroxyacetic acid disinfectant provided by the invention has good stability, and better stability than that of unitary peroxyacetic acid disinfectants prepared by most manufacturers on the market, and the effective period can be as long as about 1 year.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
The above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (6)
1. A monobasic peroxyacetic acid disinfectant and a preparation method thereof comprise: hydrogen peroxide solution, compound stabilizer solution, glacial acetic acid solution, concentrated sulfuric acid solution, EDTA-2Na solution, the surplus is water, its characterized in that: the preparation method of the monoprotic peroxyacetic acid disinfectant comprises the following steps:
s1, adding the EDTA-2Na with the formula amount into the purified water with the formula amount, stirring and dissolving to obtain solution A for later use;
s2, sequentially adding acetic acid and hydrogen peroxide into the beaker according to the formula ratio, and uniformly stirring and mixing;
s3, slowly adding concentrated sulfuric acid with the formula amount; stirring and reacting for 2 h;
s4, adding a corresponding compound stabilizer, stirring and reacting for 30min to prepare a solution B;
and S5, stirring and mixing the solution A and the solution B uniformly, and subpackaging.
2. The mono-peroxyacetic acid disinfectant as claimed in claim 1, wherein the disinfectant comprises: the concentration of the hydrogen peroxide solution is 4-8%.
3. The mono-peroxyacetic acid disinfectant as claimed in claim 1, wherein the disinfectant comprises: the concentration of the compound stabilizer is 0.1-2%, and the compound stabilizer comprises one or more of phosphoric acid, sodium gluconate, sodium pyrophosphate, oxalic acid and polymaleic acid.
4. The mono-peroxyacetic acid disinfectant as claimed in claim 1, wherein the disinfectant comprises: the concentration of the glacial acetic acid is 30-50%.
5. The mono-peroxyacetic acid disinfectant as claimed in claim 1, wherein the disinfectant comprises: the concentration of the concentrated sulfuric acid is 1% -3%.
6. The mono-peroxyacetic acid disinfectant as claimed in claim 1, wherein the disinfectant comprises: the concentration of the EDTA-2Na solution is 0.01-0.02%.
Priority Applications (1)
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CN202110981869.9A CN113693067A (en) | 2021-08-25 | 2021-08-25 | Unitary peroxyacetic acid disinfectant and preparation method thereof |
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CN202110981869.9A CN113693067A (en) | 2021-08-25 | 2021-08-25 | Unitary peroxyacetic acid disinfectant and preparation method thereof |
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CN202110981869.9A Pending CN113693067A (en) | 2021-08-25 | 2021-08-25 | Unitary peroxyacetic acid disinfectant and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115152760A (en) * | 2022-06-23 | 2022-10-11 | 天津市标准生物制剂有限公司 | Peroxyacetic acid disinfectant, and preparation method and application thereof |
CN115669662A (en) * | 2022-11-21 | 2023-02-03 | 成都科宏达科技有限公司 | Low-irritation stable monoperoxyacetic acid disinfectant and preparation method thereof |
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CN102090393A (en) * | 2010-12-29 | 2011-06-15 | 广东环凯微生物科技有限公司 | Stable peroxyacetic acid disinfectant |
CN106689197A (en) * | 2016-12-27 | 2017-05-24 | 广州迈高化学有限公司 | Monobasic stable type peroxyacetic acid disinfection solution and preparation method of monobasic stable type peroxyacetic acid disinfection solution |
CN109077054A (en) * | 2018-09-27 | 2018-12-25 | 四川省畜牧科学研究院 | A kind of Peracetic acid composite disinfectant and preparation method thereof |
CN111328807A (en) * | 2018-12-19 | 2020-06-26 | 洛阳惠中兽药有限公司 | Peroxyacetic acid solution disinfectant, and preparation and application thereof |
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2021
- 2021-08-25 CN CN202110981869.9A patent/CN113693067A/en active Pending
Patent Citations (4)
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CN102090393A (en) * | 2010-12-29 | 2011-06-15 | 广东环凯微生物科技有限公司 | Stable peroxyacetic acid disinfectant |
CN106689197A (en) * | 2016-12-27 | 2017-05-24 | 广州迈高化学有限公司 | Monobasic stable type peroxyacetic acid disinfection solution and preparation method of monobasic stable type peroxyacetic acid disinfection solution |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115152760A (en) * | 2022-06-23 | 2022-10-11 | 天津市标准生物制剂有限公司 | Peroxyacetic acid disinfectant, and preparation method and application thereof |
CN115669662A (en) * | 2022-11-21 | 2023-02-03 | 成都科宏达科技有限公司 | Low-irritation stable monoperoxyacetic acid disinfectant and preparation method thereof |
CN115669662B (en) * | 2022-11-21 | 2024-04-30 | 成都科宏达科技有限公司 | Low-irritation-stability unitary peroxyacetic acid disinfectant and preparation method thereof |
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Application publication date: 20211126 |