CN113684685A - 亲水性纤维浆料 - Google Patents
亲水性纤维浆料 Download PDFInfo
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- CN113684685A CN113684685A CN202110922157.XA CN202110922157A CN113684685A CN 113684685 A CN113684685 A CN 113684685A CN 202110922157 A CN202110922157 A CN 202110922157A CN 113684685 A CN113684685 A CN 113684685A
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- 239000002002 slurry Substances 0.000 title claims abstract description 28
- 239000000835 fiber Substances 0.000 title claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 229920002472 Starch Polymers 0.000 claims abstract description 17
- 235000019698 starch Nutrition 0.000 claims abstract description 17
- 239000008107 starch Substances 0.000 claims abstract description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 10
- 230000003449 preventive effect Effects 0.000 claims abstract description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000004513 sizing Methods 0.000 claims abstract description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract description 6
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 6
- 239000000178 monomer Substances 0.000 claims abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 6
- 239000010452 phosphate Substances 0.000 claims abstract description 6
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 5
- 230000000149 penetrating effect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005470 impregnation Methods 0.000 abstract 1
- 238000009941 weaving Methods 0.000 description 5
- 239000004744 fabric Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229920000881 Modified starch Polymers 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920000945 Amylopectin Polymers 0.000 description 1
- 206010020112 Hirsutism Diseases 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002357 osmotic agent Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明公开了一种亲水性纤维浆料，包括醋酸酯淀粉0‑65份，磷酸酯淀粉0‑47份，ASP淀粉25‑53份，丙烯酸类浆料0‑10份，砂浆油剂2份，渗透剂0.6份，防霉剂0.1份。所述丙烯酸类浆料为丙烯酸、丙烯酸乙酯、甲基丙烯酸甲酯和丙烯酸丁酯四种单体，配合符合乳化剂通过聚合反应制得。所述砂浆油剂为LMO‑96。所述渗透剂为JFC。所述防霉剂为NL‑4。本发明主槽内的砂浆温度均衡，纱线浸渍效果更佳。
Description
技术领域
本发明涉及一种浆料，属于织物织造领域。
背景技术
一般单纱织物在生产过程中，均通过上浆工序使经纱吸附一定量的浆液，经烘干后在经纱表面形成薄薄的浆膜，以利织造。传统的浆料选取PVA作为原料生产。而造成浆料的黏附性不佳，而且不方便退浆。
发明内容
本发明的目的在于提供一种具有更好的黏附性，方便退浆的亲水性纤维浆料。
为了达到上述目的，本发明的技术方案是：一种亲水性纤维浆料，包括醋酸酯淀粉0-65份，磷酸酯淀粉0-47份，ASP淀粉25-53份，丙烯酸类浆料0-10 份，砂浆油剂2份，渗透剂0.6份，防霉剂0.1份。
优选的，所述丙烯酸类浆料为丙烯酸、丙烯酸乙酯、甲基丙烯酸甲酯和丙烯酸丁酯四种单体，配合符合乳化剂通过聚合反应制得。
优选的，所述砂浆油剂为LMO-96。
优选的，所述渗透剂为JFC。
优选的，所述防霉剂为NL-4。
采用上述结构后，本发明采用醚化变性淀粉ASP取代PVA。对亲水性纤维具有很好的黏附性，浆液的流动性好、黏度低且稳定，浆膜性能符合织造要求，同时ASP在水中可以完全溶解，很容易退浆。
具体实施方式
以下给出实施例对本发明作进一步详细的说明。
实施例一，一种亲水性纤维浆料，包括醋酸酯淀粉0份，磷酸酯淀粉47份， ASP淀粉25份，丙烯酸类浆料0份，砂浆油剂2份，渗透剂0.6份，防霉剂0.1 份，通过搅拌混合而成浆料。
丙烯酸类浆料为丙烯酸、丙烯酸乙酯、甲基丙烯酸甲酯和丙烯酸丁酯四种单体，配合符合乳化剂通过聚合反应制得。合成浆料的主要原料为丙烯酸、丙烯酸乙酯、甲基丙烯酸甲酯和丙烯酸丁酯4种单体，选用SDS和OP210为复合乳化剂，m(SDS)∶m(OP210)＝314∶1，用量为单体总质量的4％，选用过硫酸铵为引发剂，用量为单体总质量的0、3％～1％。通过聚合反应，得到纳米改性聚丙烯酸类浆料SX25PTiO2。SX25PTi02为白色黏性液体，黏度8mPa·s(质量分数4％、温度25℃，NDJ 79型黏度计)，pH值为7，含固率35％。
砂浆油剂为LMO-96。该油剂为白色块状结构，在70℃的水中搅拌形成乳状，砂浆油剂具有抗静电消泡作用，使用后提高了浆纱平滑性能，降低抹茶系数，减少再生毛羽，提高织造效率。
渗透剂为JFC。为脂肪醇聚氧乙烯醚，属于无色至淡黄色透明粘稠液体，具有较强的洗毛能力，易于洗去各种油污且手感柔软。
防霉剂为NL-4。NL-4是一种低毒，高效，广谱防霉剂，使用方便防霉效果好，与浆料有良好的配伍性。
实施例二，采用醋酸酯淀粉65份，磷酸酯淀粉0份，ASP淀粉53份，丙烯酸类浆料10份，砂浆油剂2份，渗透剂0.6份，防霉剂0.1份，搅拌而成。
实施例一中采用磷酸酯淀粉作为主浆料，而实施例二中采用醋酸酯淀粉作为主浆料，两个实施例中，都选用新型醚化变性淀粉ASP取代PVA。ASP是100％的支链淀粉，对亲水性纤维具有很好的黏附性，浆液的流动性好、黏度低且稳定，浆膜性能符合织造要求，同时ASP在水中可以完全溶解，很容易退浆。
以上所述的仅是本发明的优选实施方式，应当指出，对于本领域的普通技术人员来说，在不脱离本发明创造构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。
Claims (5)
1.一种亲水性纤维浆料，其特征在于：包括醋酸酯淀粉0-65份，磷酸酯淀粉0-47份，ASP淀粉25-53份，丙烯酸类浆料0-10份，砂浆油剂2份，渗透剂0.6份，防霉剂0.1份。
2.根据权利要求1所述的亲水性纤维浆料，其特征在于：所述丙烯酸类浆料为丙烯酸、丙烯酸乙酯、甲基丙烯酸甲酯和丙烯酸丁酯四种单体，配合符合乳化剂通过聚合反应制得。
3.根据权利要求1所述的亲水性纤维浆料，其特征在于：所述砂浆油剂为LMO-96。
4.根据权利要求1所述的亲水性纤维浆料，其特征在于：所述渗透剂为JFC。
5.根据权利要求1所述的亲水性纤维浆料，其特征在于：所述防霉剂为NL-4。
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532399A (zh) * | 2011-12-10 | 2012-07-04 | 江阴市尼美达助剂有限公司 | 丙烯酸类纺织浆料及其制备方法 |
| CN104947426A (zh) * | 2015-06-30 | 2015-09-30 | 青岛精石通精密机械制造有限公司 | 一种改进的淀粉纺织浆料 |
| CN106283745A (zh) * | 2016-08-31 | 2017-01-04 | 西达（无锡）生物科技有限公司 | 一种聚丙烯酸类纺织浆料 |
| CN106592226A (zh) * | 2016-12-15 | 2017-04-26 | 吴江市北厍盛源纺织品助剂厂 | 一种稳定性强的环保型纺织浆料及其制备方法 |
| CN106758224A (zh) * | 2016-12-19 | 2017-05-31 | 长兴荣煜纺织科技有限公司 | 一种复合纺织浆料及其制备方法 |
-
2021
- 2021-08-11 CN CN202110922157.XA patent/CN113684685A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532399A (zh) * | 2011-12-10 | 2012-07-04 | 江阴市尼美达助剂有限公司 | 丙烯酸类纺织浆料及其制备方法 |
| CN104947426A (zh) * | 2015-06-30 | 2015-09-30 | 青岛精石通精密机械制造有限公司 | 一种改进的淀粉纺织浆料 |
| CN106283745A (zh) * | 2016-08-31 | 2017-01-04 | 西达（无锡）生物科技有限公司 | 一种聚丙烯酸类纺织浆料 |
| CN106592226A (zh) * | 2016-12-15 | 2017-04-26 | 吴江市北厍盛源纺织品助剂厂 | 一种稳定性强的环保型纺织浆料及其制备方法 |
| CN106758224A (zh) * | 2016-12-19 | 2017-05-31 | 长兴荣煜纺织科技有限公司 | 一种复合纺织浆料及其制备方法 |
Non-Patent Citations (1)
| Title |
|---|
| 蔡永东: "《现代机织技术》", 东华大学出版社, pages: 230 - 232 * |
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