CN113683945A - Water-based polyester acrylate color aluminum plate water-based paint and preparation method thereof - Google Patents

Water-based polyester acrylate color aluminum plate water-based paint and preparation method thereof Download PDF

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Publication number
CN113683945A
CN113683945A CN202111098744.8A CN202111098744A CN113683945A CN 113683945 A CN113683945 A CN 113683945A CN 202111098744 A CN202111098744 A CN 202111098744A CN 113683945 A CN113683945 A CN 113683945A
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China
Prior art keywords
parts
water
agent
polyester acrylate
stirring
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CN202111098744.8A
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Chinese (zh)
Inventor
刘国民
王方文
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Shenzhen Shensaier Co Ltd
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Shenzhen Shensaier Co Ltd
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Priority to CN202111098744.8A priority Critical patent/CN113683945A/en
Publication of CN113683945A publication Critical patent/CN113683945A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a water-based polyester acrylate resin water-based paint for a color aluminum plate and a preparation method thereof. The raw materials comprise the following components in parts by weight: 35-45 parts of water-based polyester acrylate, 30-40 parts of deionized water, 1-3 parts of amino resin, 8-12 parts of titanium dioxide, 2-4 parts of a film-forming agent, 2-4 parts of a defoaming agent, 4-8 parts of a dispersing agent, 2-4 parts of a thickening agent, 2-4 parts of an antifreezing agent, 1-3 parts of a pH regulator, 6-9 parts of a contact insecticide, 2-3 parts of a solubilizer and 1-3 parts of a synergist. But also can decorate, beautify the environment, protect the human health, have long life, have very considerable practical benefit and economic value.

Description

Water-based polyester acrylate color aluminum plate water-based paint and preparation method thereof
Technical Field
The invention relates to the technical field of water-based paint, in particular to water-based paint for a color aluminum plate of water-based polyester acrylate resin and a preparation method thereof.
Background
The colored aluminum plate as a composite material can have the advantages of both the aluminum plate and the organic material. The aluminum product has high mechanical strength and good toughness, and can be processed into various shapes. And an organic polymer coating is added, so that the coating has good coloring and better decorative and corrosion resistance. In the fitment process, various aluminium sheet can be very easily just carry out processing such as cutting, bending, welding, adapts to any fitment place, also commonly uses in multiple public occasions such as industry factory building, airport, gymnasium.
The color aluminum plate is widely used, the surface of the color aluminum plate is often coated with the water-based paint during use, the existing water-based paint has single function and only plays a role in decoration and protection, and the practicability is not sufficient.
Therefore, there is a need to provide a new water-based polyester acrylate resin water-based paint for color aluminum plates and a preparation method thereof to solve the above technical problems.
Disclosure of Invention
In order to solve the technical problems, the invention provides a water-based polyester acrylate resin water-based paint for a color aluminum plate and a preparation method thereof.
In order to achieve the purpose, the invention provides the following technical scheme:
the water-based polyester acrylate resin water-based paint for the color aluminum plate comprises the following raw materials in parts by weight: 35-45 parts of water-based polyester acrylate resin, 30-40 parts of deionized water, 1-3 parts of amino resin, 8-12 parts of titanium dioxide, 2-4 parts of a film forming agent, 2-4 parts of a defoaming agent, 4-8 parts of a dispersing agent, 2-4 parts of a thickening agent, 2-4 parts of an antifreezing agent, 1-3 parts of a pH regulator, 6-9 parts of a contact killing agent, 2-3 parts of a solubilizing agent and 1-3 parts of a synergist.
Preferably, the weight parts of the raw materials are as follows: 40 parts of water-based polyester acrylate resin, 35 parts of deionized water, 2 parts of amino resin, 10 parts of titanium dioxide, 3 parts of a film forming agent, 4 parts of a defoaming agent, 6 parts of a dispersing agent, 3 parts of a thickening agent, 3 parts of an antifreezing agent, 1 part of a pH regulator, 7 parts of a solubilizing agent, 3 parts of a solubilizing agent and 3 parts of a synergist.
Preferably, the weight parts of the raw materials are as follows: 35 parts of water-based polyester acrylate resin, 30 parts of deionized water, 1 part of amino resin, 11 parts of titanium dioxide, 2 parts of a film forming agent, 3 parts of a defoaming agent, 5 parts of a dispersing agent, 2 parts of a thickening agent, 2 parts of an antifreezing agent, 2 parts of a pH regulator, 8 parts of a solubilizing agent, 2 parts of a solubilizing agent and 2 parts of a synergist.
Preferably, the weight parts of the raw materials are as follows: 45 parts of water-based polyester acrylate resin, 40 parts of deionized water, 2 parts of amino resin, 12 parts of titanium dioxide, 4 parts of a film forming agent, 4 parts of a defoaming agent, 8 parts of a dispersing agent, 4 parts of a thickening agent, 4 parts of an antifreezing agent, 3 parts of a pH regulator, 9 parts of a solubilizer, 3 parts of a solubilizer and 3 parts of a synergist.
Preferably, the contact insecticide is deltamethrin.
Preferably, the solubilizer is ethyl acetate.
Preferably, the synergist is synergistic phosphorus.
Preferably, the defoaming agent is polyoxyethylene polyoxypropylene pentaerythritol ether, and the pH regulator is sodium sesquicarbonate.
Preferably, the film forming agent is dodecyl alcohol ester, and the antifreezing agent is alkyl succinimide.
A preparation method of a water-based polyester acrylate resin water-based paint for color aluminum plates comprises the following specific steps:
the method comprises the following steps: sequentially adding water, water-based polyester acrylate resin and titanium dioxide into a stirring machine with a heating function;
step two: starting a stirring machine, stirring for 20-40 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-400r/min, adding a dispersing agent into the stirring machine during stirring, and obtaining a water-based polyester acrylate resin premix after stirring;
step three: adding amino resin into the stirring machine again, starting the stirring machine, heating and stirring for 15-20 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-;
step four: adding deltamethrin, ethyl acetate and phosphorus with synergistic effect into another stirring machine with heating function, stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-300r/min to obtain a sanitary preparation, and standing and cooling.
Step five: adding the cooled hygienic preparation into the pre-formed liquid, starting a stirring machine, heating and stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 100-150 r/min;
step six: after stirring, standing and cooling to obtain a finished product material, and discharging the finished product material from a stirring machine;
step seven: and filtering the finished product material to remove residues, and packaging to obtain the water-based paint.
Compared with the prior art, the epoxy resin color aluminum plate water-based paint and the preparation method thereof provided by the invention have the following beneficial effects:
the invention provides a water-based polyester acrylate resin water-based paint for a color aluminum plate and a preparation method thereof, the water-based polyester acrylate resin water-based paint is simple to manufacture, when in use, the water-based paint is coated on the color aluminum plate, in the using process, as the water-based paint contains a sanitary preparation prepared by mixing a contact insecticide, a solubilizer and a synergist, a plurality of medicine monomers are selected and reasonably allocated, and then the water-based polyester acrylate resin water-based paint can continuously kill insects without killing insects by spraying and fumigating through an integral control release system, so that the residual of the medicines and the environment are avoided, the insect killing effect can be achieved, the environmental hazard is reduced, the decoration and the environment beautification can be realized, the human health is protected, the life is prolonged, and the water-based polyester acrylate resin water-based paint has considerable practical benefit and economic value.
Detailed Description
The present invention will be further described with reference to the following embodiments.
The first embodiment is as follows:
in the embodiment of the invention, the raw materials of the water-based polyester acrylate resin water-based paint for the color aluminum plate comprise the following components in parts by weight: 40 parts of water-based polyester acrylate resin, 35 parts of deionized water, 2 parts of amino resin, 10 parts of titanium dioxide, 3 parts of a film forming agent, 4 parts of a defoaming agent, 6 parts of a dispersing agent, 3 parts of a thickening agent, 3 parts of an antifreezing agent, 1 part of a pH regulator, 7 parts of a contact killing agent, 3 parts of a solubilizing agent and 3 parts of a synergist.
The method comprises the following specific steps:
the method comprises the following steps: sequentially adding water, water-based polyester acrylate resin and titanium dioxide into a stirring machine with a heating function;
step two: starting a stirring machine, stirring for 20-40 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-400r/min, adding a dispersing agent into the stirring machine during stirring, and obtaining a water-based polyester acrylate resin premix after stirring;
step three: adding amino resin into the stirring machine again, starting the stirring machine, heating and stirring for 15-20 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-;
step four: adding deltamethrin, ethyl acetate and phosphorus with synergistic effect into another stirring machine with heating function, stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-300r/min to obtain a sanitary preparation, and standing and cooling.
Step five: adding the cooled hygienic preparation into the pre-formed liquid, starting a stirring machine, heating and stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 100-150 r/min;
step six: after stirring, standing and cooling to obtain a finished product material, and discharging the finished product material from a stirring machine;
step seven: and filtering the finished product material to remove residues, and packaging to obtain the water-based paint.
Example two:
in the embodiment of the invention, the raw materials of the water-based polyester acrylate resin water-based paint for the color aluminum plate comprise the following components in parts by weight: 35 parts of water-based polyester acrylate resin, 30 parts of deionized water, 1 part of amino resin, 11 parts of titanium dioxide, 2 parts of a film forming agent, 3 parts of a defoaming agent, 5 parts of a dispersing agent, 2 parts of a thickening agent, 2 parts of an antifreezing agent, 2 parts of a pH regulator, a contact killing agent, 2 parts of a solubilizing agent and 2 parts of a synergist.
The method comprises the following specific steps:
the method comprises the following steps: sequentially adding water, water-based polyester acrylate resin and titanium dioxide into a stirring machine with a heating function;
step two: starting a stirring machine, stirring for 20-40 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-400r/min, adding a dispersing agent into the stirring machine during stirring, and obtaining the aqueous epoxy resin premix after stirring;
step three: adding amino resin into the stirring machine again, starting the stirring machine, heating and stirring for 15-20 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-;
step four: adding deltamethrin, ethyl acetate and phosphorus with synergistic effect into another stirring machine with heating function, stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-300r/min to obtain a sanitary preparation, and standing and cooling.
Step five: adding the cooled hygienic preparation into the pre-formed liquid, starting a stirring machine, heating and stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 100-150 r/min;
step six: after stirring, standing and cooling to obtain a finished product material, and discharging the finished product material from a stirring machine;
step seven: and filtering the finished product material to remove residues, and packaging to obtain the water-based paint.
Example three:
in the embodiment of the invention, the raw materials of the water-based polyester acrylate resin water-based paint for the color aluminum plate comprise the following components in parts by weight: 45 parts of water-based polyester acrylate resin, 40 parts of deionized water, 2 parts of amino resin, 12 parts of titanium dioxide, 4 parts of a film forming agent, 4 parts of a defoaming agent, 8 parts of a dispersing agent, 4 parts of a thickening agent, 4 parts of an antifreezing agent, 3 parts of a pH regulator, 9 parts of a contact killing agent, 3 parts of a solubilizing agent and 3 parts of a synergist.
The method comprises the following specific steps:
the method comprises the following steps: sequentially adding water, water-based polyester acrylate resin and titanium dioxide into a stirring machine with a heating function;
step two: starting a stirring machine, stirring for 20-40 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-400r/min, adding a dispersing agent into the stirring machine during stirring, and obtaining the aqueous epoxy resin premix after stirring;
step three: adding amino resin into the stirring machine again, starting the stirring machine, heating and stirring for 15-20 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-;
step four: adding deltamethrin, ethyl acetate and phosphorus with synergistic effect into another stirring machine with heating function, stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-300r/min to obtain a sanitary preparation, and standing and cooling.
Step five: adding the cooled hygienic preparation into the pre-formed liquid, starting a stirring machine, heating and stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 100-150 r/min;
step six: after stirring, standing and cooling to obtain a finished product material, and discharging the finished product material from a stirring machine;
step seven: and filtering the finished product material to remove residues, and packaging to obtain the water-based paint.
The invention has simple manufacture, when in use, the coating is coated on the color aluminum plate, in the using process, as the water-based coating contains a sanitary preparation prepared by mixing a contact insecticide, a solubilizer and a synergist, a plurality of drug monomers are selected, the reasonable blending is carried out, and the insecticide can be continuously killed through an integral control release system without killing insects through spraying and fumigating, thereby avoiding drug residue and damaging the environment, achieving the effect of killing insects, reducing environmental damage, decorating, beautifying the environment, protecting the health of human bodies and prolonging the life, and having considerable practical benefit and economic value.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all modifications of equivalent structures and equivalent processes, which are made by the present specification, or directly or indirectly applied to other related technical fields, are included in the scope of the present invention.

Claims (10)

1. The water-based polyester acrylate water-based paint for the color aluminum plate is characterized by comprising the following raw materials in parts by weight: 35-45 parts of water-based polyester acrylate, 30-40 parts of deionized water, 1-3 parts of amino resin, 8-12 parts of titanium dioxide, 2-4 parts of a film forming agent, 2-4 parts of a defoaming agent, 4-8 parts of a dispersing agent, 2-4 parts of a thickening agent, 2-4 parts of an antifreezing agent, 1-3 parts of a pH regulator, 6-9 parts of a contact killing agent, 2-3 parts of a solubilizing agent and 1-3 parts of a synergist.
2. The water-based polyester acrylate color aluminum plate water-based paint as claimed in claim 1, which is characterized by comprising the following raw materials in parts by weight: 40 parts of water-based polyester acrylate, 35 parts of deionized water, 2 parts of amino resin, 10 parts of titanium dioxide, 3 parts of a film forming agent, 4 parts of a defoaming agent, 6 parts of a dispersing agent, 3 parts of a thickening agent, 3 parts of an antifreezing agent, 1 part of a pH regulator, 7 parts of a contact killing agent, 3 parts of a solubilizing agent and 3 parts of a synergist.
3. The water-based polyester acrylate color aluminum plate water-based paint as claimed in claim 1, which is characterized by comprising the following raw materials in parts by weight: 35 parts of water-based polyester acrylate, 30 parts of deionized water, 1 part of amino resin, 11 parts of titanium dioxide, 2 parts of a film forming agent, 3 parts of a defoaming agent, 5 parts of a dispersing agent, 2 parts of a thickening agent, 2 parts of an antifreezing agent, 2 parts of a pH regulator, 8 parts of a contact killing agent, 2 parts of a solubilizing agent and 2 parts of a synergist.
4. The water-based polyester acrylate color aluminum plate water-based paint as claimed in claim 1, which is characterized by comprising the following raw materials in parts by weight: 45 parts of water-based polyester acrylate, 40 parts of deionized water, 2 parts of amino resin, 12 parts of titanium dioxide, 4 parts of a film forming agent, 4 parts of a defoaming agent, 8 parts of a dispersing agent, 4 parts of a thickening agent, 4 parts of an antifreezing agent, 3 parts of a pH regulator, 9 parts of a contact killing agent, 3 parts of a solubilizing agent and 3 parts of a synergist.
5. The waterborne polyester acrylate paint for color aluminum plates as claimed in claim 1, wherein the contact insecticide is deltamethrin.
6. The waterborne polyester acrylate paint for color aluminum plates as claimed in claim 1, wherein the solubilizer is ethyl acetate.
7. The waterborne polyester acrylate paint for color aluminum plates as claimed in claim 1, wherein the synergist is synergistic phosphorus.
8. The waterborne polyester acrylate paint for color aluminum plate as claimed in claim 1, wherein the defoamer is polyoxyethylene polyoxypropylene pentaerythritol ether and the pH regulator is sodium sesquicarbonate.
9. The waterborne polyester acrylate paint for color aluminum plates as claimed in claim 1, wherein the film-forming agent is dodecyl alcohol ester, and the antifreezing agent is alkyl succinimide.
10. The preparation method of the water-based polyester acrylate water-based paint for color aluminum plates according to any one of claims 1 to 9, characterized by comprising the following specific steps:
the method comprises the following steps: sequentially adding water, water-based polyester acrylate and titanium dioxide into a stirring machine with a heating function;
step two: starting a stirring machine, stirring for 20-40 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-400r/min, adding a dispersing agent into the stirring machine during stirring, and obtaining a water-based polyester acrylate resin premix after stirring;
step three: adding amino resin into the stirring machine again, starting the stirring machine, heating and stirring for 15-20 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-;
step four: adding deltamethrin, ethyl acetate and phosphorus with synergistic effect into another stirring machine with heating function, stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 200-300r/min to obtain a sanitary preparation, and standing and cooling.
Step five: adding the cooled hygienic preparation into the pre-formed liquid, starting a stirring machine, heating and stirring for 5-10 minutes at the temperature of 40-50 ℃, wherein the rotating speed of a stirring blade is 100-150 r/min;
step six: after stirring, standing and cooling to obtain a finished product material, and discharging the finished product material from a stirring machine;
step seven: and filtering the finished product material to remove residues, and packaging to obtain the water-based paint.
CN202111098744.8A 2021-09-18 2021-09-18 Water-based polyester acrylate color aluminum plate water-based paint and preparation method thereof Pending CN113683945A (en)

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CN202111098744.8A CN113683945A (en) 2021-09-18 2021-09-18 Water-based polyester acrylate color aluminum plate water-based paint and preparation method thereof

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CN202111098744.8A CN113683945A (en) 2021-09-18 2021-09-18 Water-based polyester acrylate color aluminum plate water-based paint and preparation method thereof

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1346854A (en) * 2001-10-24 2002-05-01 赵培基 Environment protection type insecticidal emulsoid paint and its preparing process
CN101209047A (en) * 1994-06-08 2008-07-02 辛根塔参与股份公司 Synergistic compositions
CN110894394A (en) * 2019-11-12 2020-03-20 无锡华东锌盾科技有限公司 Water-based polyester amino baking varnish coating and preparation method and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101209047A (en) * 1994-06-08 2008-07-02 辛根塔参与股份公司 Synergistic compositions
CN1346854A (en) * 2001-10-24 2002-05-01 赵培基 Environment protection type insecticidal emulsoid paint and its preparing process
CN110894394A (en) * 2019-11-12 2020-03-20 无锡华东锌盾科技有限公司 Water-based polyester amino baking varnish coating and preparation method and application thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
徐峰主编: "《建筑涂料与涂装技术》", 31 May 2000, 化学工业出版社 *
熊方武主编: "《中国临床药物大辞典 化学药卷 下》", 31 August 2018, 中国医药科技出版社 *

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Application publication date: 20211123