CN113683826A - 一种耐迁移耐高温，减少颜料和助剂用量的色母专用改性剂 - Google Patents
一种耐迁移耐高温，减少颜料和助剂用量的色母专用改性剂 Download PDFInfo
- Publication number
- CN113683826A CN113683826A CN202010404613.7A CN202010404613A CN113683826A CN 113683826 A CN113683826 A CN 113683826A CN 202010404613 A CN202010404613 A CN 202010404613A CN 113683826 A CN113683826 A CN 113683826A
- Authority
- CN
- China
- Prior art keywords
- color master
- pigment
- modifier
- inorganic
- high temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 37
- 239000004595 color masterbatch Substances 0.000 title claims abstract description 31
- 239000003607 modifier Substances 0.000 title claims abstract description 26
- 230000005012 migration Effects 0.000 title claims abstract description 19
- 238000013508 migration Methods 0.000 title claims abstract description 19
- 239000012752 auxiliary agent Substances 0.000 title claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 239000000314 lubricant Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000001023 inorganic pigment Substances 0.000 claims description 2
- 239000012860 organic pigment Substances 0.000 claims description 2
- 230000009467 reduction Effects 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 claims 1
- 238000011065 in-situ storage Methods 0.000 abstract description 8
- 238000009396 hybridization Methods 0.000 abstract description 7
- 239000011258 core-shell material Substances 0.000 abstract description 6
- 238000006116 polymerization reaction Methods 0.000 abstract description 6
- 238000002360 preparation method Methods 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 238000004040 coloring Methods 0.000 abstract description 3
- 230000004048 modification Effects 0.000 abstract description 3
- 238000012986 modification Methods 0.000 abstract description 3
- 229920006351 engineering plastic Polymers 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- 239000004698 Polyethylene Substances 0.000 description 14
- -1 alkylbenzene sulfonate Chemical class 0.000 description 10
- 235000012239 silicon dioxide Nutrition 0.000 description 9
- 229910052681 coesite Inorganic materials 0.000 description 8
- 229910052906 cristobalite Inorganic materials 0.000 description 8
- 229910052682 stishovite Inorganic materials 0.000 description 8
- 229910052905 tridymite Inorganic materials 0.000 description 8
- 239000007822 coupling agent Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000003963 antioxidant agent Substances 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 239000011147 inorganic material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000001056 green pigment Substances 0.000 description 3
- 239000011368 organic material Substances 0.000 description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 235000014466 Douglas bleu Nutrition 0.000 description 2
- 239000004721 Polyphenylene oxide Chemical class 0.000 description 2
- 241000218683 Pseudotsuga Species 0.000 description 2
- 235000005386 Pseudotsuga menziesii var menziesii Nutrition 0.000 description 2
- 229920000142 Sodium polycarboxylate Polymers 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical class C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 2
- 239000006259 organic additive Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000570 polyether Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Chemical class 0.000 description 2
- 239000001267 polyvinylpyrrolidone Chemical class 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- XVCDKNBLRWOWMC-UHFFFAOYSA-N 1-o-ethyl 2-o-octadecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCC XVCDKNBLRWOWMC-UHFFFAOYSA-N 0.000 description 1
- SHVNPFLUMGTESQ-UHFFFAOYSA-N C[Cr]C(C=C)=O Chemical compound C[Cr]C(C=C)=O SHVNPFLUMGTESQ-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- MYBZUWXXEFKPEE-UHFFFAOYSA-N trichloro(prop-1-enyl)silane Chemical compound CC=C[Si](Cl)(Cl)Cl MYBZUWXXEFKPEE-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
发明名称:一种耐迁移耐高温，减少颜料和助剂用量的色母专用改性剂。所属技术领域:工程塑料改性领域。所解决的技术问题：使颜料、分散剂和载体的相互兼容，提高色母粒中颜料含量和着色效率。并且在降低色母行业中色母的制备成本，还能同时增加耐高温，耐迁移性能。主要技术特征：本发明以使用无机无机原位聚合包覆，再有机无机杂化后的形成核壳结构为主要技术特征。发明用途：降低色母行业中色母的制备成本，改善加工条件，扩大色母应用范围。
Description
技术领域
本发明属于工程塑料改性领域，具体涉及一种耐高温耐迁移改性剂。更具体而言，本发明涉及一种耐迁移耐高温，减少颜料和助剂用量的色母专用改性剂。
背景技术
高浓度色母粒是当下色母行业的潮流和趋势，色母粒中颜料含量越高，分散越困难，所以对颜料的要求(主要是微细化和可分散性)越来越高。因此，开发新型、高效、微细化、易分散、无毒和稳定性良好的颜料是未来的发展趋势。颜料含量愈高的母料，制造难度愈大。色母粒技术发展的核心在于颜料、分散剂和载体的相互兼容，提高色母粒中颜料含量和着色效率。
无机纳米材料应用于聚合物改性中，不仅可以起到降低成本的作用，还可以增加聚合物基体的韧性和强度，耐高温、耐迁移。同样，无机纳米材料也被应用于色母粒行业中，解决行业通病。
发明内容
本发明公开了一种耐迁移耐高温，减少颜料和助剂用量的色母专用改性剂。本发明的目的是为了降低色母行业中色母的制备成本，同时增加耐高温，耐迁移性能，改善加工条件以及扩大色母应用范围。
为了实现上述目的，本发明的改性剂采用表面处理，再通过改良的色母配方制备得到色母粒，最终通过制品得到。
通过以下详细说明使本发明的目的、特征、结构及优点更加明确。
附图说明
图1为本发明白色粉末状物体图。
具体实施方式
本发明人针对色母中使用的有机助剂和无机助剂的性能进行了具体的研究，结果发现单纯使用有机助剂耐高温、耐迁移性能并不理想，也无法达到降低成本的效果，而单纯的使用无机助剂并不具有良好的分散性。此外市场上有较多的有机材料为主，略带一些无机材料的助剂，从成分上的改变来增加分散性、耐高温、耐迁移性，但是往往与纯有机助剂特性相似，耐高温耐迁移性较为不好，而且有机助剂比较昂贵，同样无法达到降成本的效果。另外，无论有机颜料还是无机颜料本身颗粒较大，而且容易团聚，非常影响颜料的着色力。市场上的助剂由于颗粒大或者分子量高或者不够均一稳定等原因，普遍无法达到完全浸润包覆，所以并不能达到减少颜料用量的效果。因此本发明人展开了进一步的研究得到以下结论：在色母的制备中，使用无机无机原位聚合包覆，再有机无机杂化后的形成核壳结构的助剂，在色母现有使用工艺中对颜料有非常优秀的塑化和分散功能，并可以实现与颜料节枝包覆，良好地充当了颜料的核，提高了着色力和展色性，同时因为原位聚合的无机材料的高折射率，提高了核壳颜料的折射率，提高了颜料色泽、光泽、饱和度，双重手段来减少颜料用量，并且拥有分散性、耐高温、耐迁移性等性能。由此来完成本发明。
在本实施方式中，改性剂为90％～99.9％纯度的二氧化硅，通过研磨，无机无机原位聚合，有机无机杂化，达到一定结构。
研磨过程中，选择天然SiO2或者合成SiO2为原料，加入六偏磷酸钠、碳酸盐、二硅酸钠、烷基苯磺酸盐、聚羧酸钠、聚丙烯酸衍生物、顺丁烯二酸酐共聚物、缩合萘磺酸盐、聚乙烯吡咯酮、聚醚衍生物等一种或一种以上分散剂。并使其在温度50～150℃进行研磨，经过1～3个小时使SiO2粒径到达 500nm～2000nm。
原位聚合过程中，在研磨后得到的SiO2水溶液中，选择加入氧化锌，氧化钛、氧化铝、氧化铍、氧化锡、氧化镁等一种或一种以上，混合转速 500r/min～2000r/min，经过1～3个小时，再加热至50～150℃继续反应，SiO2 颗粒在水中，其表面极易形成大量的羟基，根据所选无机物等电点调节合适的PH 值，使SIO2表面带负电荷，加入的氧化锌，氧化钛、氧化铝、氧化铍、氧化锡、氧化镁等表面带正电荷，使其通过静电或者氢键的作用使加入的无机物能很好附着在载体的表面，然后通过加热使得SiO2与加入的无机物之间可能通过氢键缩合反应形成化学键结合，最终形成部分无机与无机的核壳且类球形结构，从而达到调节折射率的目的。使其折射率达到1.48以上，优选1.50---1.60，考虑高折射率并且不影响使用色母制品的透明度，更优选1.50-1.54。
杂化过程中，在原位聚合后的得到的溶液中，选择加入三氯乙烯基硅烷、三乙氧基乙烯基硅烷、γ-氨基丙基三乙氧硅烷、三氯丙烯基硅烷、钛酸四丁酯、三异硬脂酰基钛酸异丙酯、三钛酸异丙酯、二异硬酯酰基酞酸乙酯、甲基丙烯酰铬络合物，铝酸锆、乙烯基三乙氧基硅烷、乙烯基三(2-甲氧乙氧基)硅烷、γ-(2，3-环氧丙氧)丙基三乙氧基硅烷等一种或一种以上偶联剂，再选择加入六偏磷酸钠、碳酸盐、二硅酸钠、烷基苯磺酸盐、聚羧酸钠、聚丙烯酸衍生物、顺丁烯二酸酐共聚物、缩合萘磺酸盐、聚乙烯吡咯酮、聚醚衍生物等一种或一种以上分散剂。并使其在混合转速500r/min～2000r/min，温度50到100℃下，经过0.5～2个小时，完成杂化。
杂化过程后，最终使有机材料处于表面，包裹在纳米无机材料外层，形成核壳结构，同时对应不同的颜料、色粉、色母种类，可以选择不同的官能团参与接枝以及调控相应亲水、亲油基团裸露在外部，从而实现预期的表面极性大小调整。如非极性类，可以选择烷烃(—CH3，—CH2—)，烯烃(—CH＝CH—)，醚类(—O—CH3，—O—CH2—)，硝基化合物(—NO2)，二甲胺(CH3—N—CH3)，脂类(—COOR)，酮类(—CO—)等。如极性类，可以选择醛类(—CHO)，硫醇(—SH)，胺类(—NH2)，酰胺(—NHCO—CH3)，醇类(—OH)，酚类(— Ar—OH)，羧酸类(—COOH)等。其中原料中SiO2和参与反应物的所带官能团的含量均通过红外光谱测定，再通过控制物质的量，浓度等因素，可以较为精确的控制裸露在外部的不同的官能团的数量。
根据本实施方式制作而成的改性剂，使用中拥有很好的分散性的同时又兼顾了耐迁移性，而且所得到的改性剂可耐高温。又由于原位聚合的无机材料的高折射率和与颜料包覆且价格便宜的核壳结构中的核SiO2，可以减少色母中颜料用量，综合成本大幅降低。
以下，通过实施例对本发明更具体的进行说明，但本发明的范围并不局限于这些实施例。
[实施例]
(实施例1)实施例1由以下质量份数的各个组份组成：(中石化燕山 2100J)PE料40份、(巴斯夫1010)抗氧剂1.5份、(炭黑)颜料45份、(伊斯曼聚乙烯蜡C-10)分散剂4.5份、(印尼CMS P-130)润滑剂7份、(恒达众诚HD-E6103)偶联剂2份。
将原料加入混料机，用500r/min速度混合5min后上调速度至1000r/min混合10min后，再下调速度至300r/min混合3min后慢慢放料。将放下来的物料加入双螺杆挤出机，温度设定在140℃，挤出切粒。
(实施例2)实施例2由以下质量份数的各个组份组成：(中石化燕山 2100J)PE料40份、(巴斯夫1010)抗氧剂1.5份、(炭黑)颜料45份、(伊斯曼聚乙烯蜡C-10)分散剂4.5份、(印尼CMS P-130)润滑剂4份、冠旗改性剂3份、(恒达众诚HD-E6103)偶联剂2份。
制造工艺和实施例1相同。
(实施例3)实施例3由以下质量份数的各个组份组成：(中石化燕山 2100J)PE料40份、(巴斯夫1010)抗氧剂1.5份、(炭黑)颜料35份、冠旗改性剂3份、(恒达众诚HD-E6103)偶联剂2份。
制造工艺和实施例1相同。
(实施例4)实施例4由以下质量份数的各个组份组成：(中石化燕山 2100J)PE料40份、(巴斯夫1010)抗氧剂2份、(酞菁绿)颜料15份、(伊斯曼聚乙烯蜡C-10)分散剂5份、(印尼CMS P-130)润滑剂6份、(恒达众诚HD- E6103)偶联剂2份。
制造工艺和实施例1相同。
(实施例5)实施例5由以下质量份数的各个组份组成：(中石化燕山 2100J)PE料40份、(巴斯夫1010)抗氧剂2份、(酞菁绿)颜料15份、(伊斯曼聚乙烯蜡C-10)分散剂5份、(印尼CMS P-130)润滑剂4份、冠旗改性剂2 份、(恒达众诚HD-E6103)偶联剂2份。
制造工艺和实施例1相同。
(实施例6)实施例6由以下质量份数的各个组份组成：(中石化燕山 2100J)PE料40份、(巴斯夫1010)抗氧剂2份、(酞菁绿)颜料11.5份、冠旗改性剂2份、(恒达众诚HD-E6103)偶联剂2份。
制造工艺和实施例1相同。
使用获得的PE色母粒，根据PE色母料标准(QB1648-92)，进行下述评价。
表1
表1中<总色差>项目使用GB/T 3979-2008中规定的测色仪和注塑法制备标准色板，测试数据按照GB 7921-2008中公式计算。
表1中<耐迁移性>项目根据GB/T 251-2008测试方法进行评估。
表1中<耐热性>项目根据GB/T 250-2008测试方法进行评估。
根据表1，通过比较实施例1和2，我们可以得出，冠旗改性剂可替代润滑分散剂，且分散性、耐热性和耐迁移性优于部分润滑分散剂。
通过比较实施例1和3，我们可以得出，冠旗改性剂的加入，可以使配方减少一定比例的颜料，且分散性、耐热性和耐迁移性等性能还略增。
通过比较实施例(1、2、3)和(4、5、6)，我们可以得出，冠旗改性剂可以在不同的颜料体系中应用，且效果显著。
进一步的，从实施例2、3、5、6可以看出，冠旗改性剂可替代昂贵助剂，且可使颜料减少，最终使得色母粒综合成本大降。
如以上详述，本发明涉及改性剂，该改性剂通过研磨，无机无机原位聚合，有机无机杂化，制备而成。本发明可用在色母制备领域，替代助剂，减少颜料量，降低色母综合成本，且分散性、耐热性和耐迁移性等性能略增。因此，工业实用性极高。
Claims (9)
1.一种色母专用改性剂，其特征在于可减少色母中颜料和助剂用量，同时，耐高温，耐迁移。
2.根据权利要求1所述的改性剂，其特征在于，90％--99.99％纯度的二氧化硅粉体。
3.根据权利要求1所述的改性剂，其特征在于，粒径为500nm到2000nm。
4.根据权利要求1所述的颜料，其特征在于，包括有机和无机颜料。
5.根据权利要求1所述的颜料，其特征在于，减少比例为5％～20％。
6.根据权利要求1所述的助剂，其特征在于，包括有机和无机润滑剂，分散剂，改性剂等。
7.根据权利要求1所述的助剂，其特征在于，可按包括但不限于1：2(专用改性剂：助剂)或1：3或1：4的比例替换减少。
8.根据权利要求1所述的耐高温，其特征在于，耐温500到800度。
9.根据权利要求1所述的色母专用改性剂，其特征在于，可应用范围包括但不限于PE色母，PP色母，ABS色母，PS色母、PVC色母、EVA色母等。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010404613.7A CN113683826A (zh) | 2020-05-16 | 2020-05-16 | 一种耐迁移耐高温，减少颜料和助剂用量的色母专用改性剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010404613.7A CN113683826A (zh) | 2020-05-16 | 2020-05-16 | 一种耐迁移耐高温，减少颜料和助剂用量的色母专用改性剂 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113683826A true CN113683826A (zh) | 2021-11-23 |
Family
ID=78575264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010404613.7A Pending CN113683826A (zh) | 2020-05-16 | 2020-05-16 | 一种耐迁移耐高温，减少颜料和助剂用量的色母专用改性剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113683826A (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1554713A (zh) * | 2003-12-24 | 2004-12-15 | 东南大学 | 胶原基纳米红外低发射率着色颜料及制备方法 |
| CN1616554A (zh) * | 2003-09-25 | 2005-05-18 | 默克专利股份有限公司 | 包囊化颜料 |
| CN103626897A (zh) * | 2013-11-28 | 2014-03-12 | 上海化工研究院 | 具有核壳结构的有机/无机复合微球及其制备方法和应用 |
| CN104927283A (zh) * | 2015-07-06 | 2015-09-23 | 蓝星（成都）新材料有限公司 | 一种耐高温聚丙烯着色母料 |
| CN110964281A (zh) * | 2019-10-25 | 2020-04-07 | 广东波斯科技股份有限公司 | 一种金属免喷涂液体色母及其制备方法与应用 |
-
2020
- 2020-05-16 CN CN202010404613.7A patent/CN113683826A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1616554A (zh) * | 2003-09-25 | 2005-05-18 | 默克专利股份有限公司 | 包囊化颜料 |
| CN1554713A (zh) * | 2003-12-24 | 2004-12-15 | 东南大学 | 胶原基纳米红外低发射率着色颜料及制备方法 |
| CN103626897A (zh) * | 2013-11-28 | 2014-03-12 | 上海化工研究院 | 具有核壳结构的有机/无机复合微球及其制备方法和应用 |
| CN104927283A (zh) * | 2015-07-06 | 2015-09-23 | 蓝星（成都）新材料有限公司 | 一种耐高温聚丙烯着色母料 |
| CN110964281A (zh) * | 2019-10-25 | 2020-04-07 | 广东波斯科技股份有限公司 | 一种金属免喷涂液体色母及其制备方法与应用 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108485245B (zh) | 一种通用性黑色母粒及其制备方法 | |
| CN108610576A (zh) | 一种高耐候型pvc色母粒及其制备方法 | |
| CN112143184B (zh) | 一种生物降解色母及其制备方法 | |
| CN108503963A (zh) | 一种高抗菌型聚丙烯色母粒及其制备方法 | |
| CN114249935B (zh) | 一种耐候色母粒及其制备方法 | |
| CN109280389B (zh) | 一种银纳米粒子复合有机硅树脂的制备方法 | |
| JPH04130164A (ja) | 粒状着色剤及びその製造方法 | |
| CN106675152B (zh) | 粉末涂料用消光改性剂及其应用、以及含有其的消光粉末涂料 | |
| CN108587083A (zh) | 一种抗水解抗菌pet色母粒及其制备方法 | |
| CN113683826A (zh) | 一种耐迁移耐高温，减少颜料和助剂用量的色母专用改性剂 | |
| CN108530733A (zh) | 一种抗老化型聚乙烯色母粒及其制备方法 | |
| CN108546367A (zh) | 一种高分散阻燃abs色母粒及其制备方法 | |
| TW200305616A (en) | Process for production of titanium dioxide pigment and resin compositions containing the pigment | |
| CN108047666A (zh) | 一种抗拉强度环保塑料色母粒高分子载体及其制造方法 | |
| CN112280228B (zh) | Pvb高浓度色饼及其制备方法与应用 | |
| CN112852099B (zh) | 一种用于溶剂型涂料的色母粒及其制备方法 | |
| CN113402736A (zh) | 抗菌色母粒及其制备方法 | |
| CN115322658A (zh) | 一种纳米隔热降温涂料 | |
| CN113337012A (zh) | 一种复合抗菌剂、含有该复合抗菌剂的抗菌母粒及其制备方法 | |
| CN107189525A (zh) | 含纳米颜料的油画棒及其制备方法 | |
| JPS5937304B2 (ja) | 重合体組成物用二酸化チタン顔料 | |
| CN112159606A (zh) | 一种水性纳米通用色浆及其制备方法 | |
| CN112521723B (zh) | 一种纳米碳导电高韧性黑色母及其制备方法 | |
| CN1946774B (zh) | 功能化合物细小颗粒的固体分散体的制备方法 | |
| CN107955349A (zh) | 一种具有防霾功能的环保塑料高分子纳米色母粒其制造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Lin Feng Inventor after: Lin Chuyue Inventor before: Lin Chuyue |
|
| CB03 | Change of inventor or designer information | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20211123 |
|
| WD01 | Invention patent application deemed withdrawn after publication |