CN113666673A - Inorganic water-based high-temperature-resistant artificial quartz stone and preparation method thereof - Google Patents
Inorganic water-based high-temperature-resistant artificial quartz stone and preparation method thereof Download PDFInfo
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- CN113666673A CN113666673A CN202110758897.4A CN202110758897A CN113666673A CN 113666673 A CN113666673 A CN 113666673A CN 202110758897 A CN202110758897 A CN 202110758897A CN 113666673 A CN113666673 A CN 113666673A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to an inorganic water-based high-temperature-resistant artificial quartz stone and a preparation method thereof, wherein the inorganic water-based artificial quartz stone comprises the raw materials of inorganic water-based nano glue, a curing agent, quartz powder, quartz sand, alumina, glass sand, ferric oxide toner, titanium dioxide, glass sand and fiber yarns; by using the formula and the preparation method of the technical scheme of the invention, the pollution in the processing process can be effectively overcome, and the health and safety of production personnel can be guaranteed; overcomes the defects of high VOC content, pungent taste, no environmental protection, no high temperature resistance, no wear resistance and poor weather resistance.
Description
Technical Field
The invention relates to the technical field of inorganic materials, in particular to inorganic water-based high-temperature-resistant artificial quartz stone and a preparation method thereof.
Background
The artificial quartz stone is used as a novel artificial building material and has the advantages incomparable with natural stone materials in the aspects of moisture resistance, acid resistance, splicing property and the like. In the day that natural stone resources are gradually exhausted, artificial quartz is the best substitute; meanwhile, the artificial quartz stone can adopt waste glass as a raw material, so that the resource recycling is realized while the environment is protected, the advantages enable the artificial quartz stone to become a new choice for the architectural decoration industry, and at present, the artificial quartz stone is composed of about 90 parts of natural quartz and about 10 parts of additives such as pigments, resins, curing agents and the like. Is formed by negative pressure vacuum and high-frequency vibration, and is heated and cured (the temperature is determined according to the type of curing agent); the product has the characteristics of hard texture (Mohs hardness of 5-7), compact structure (density of 2.3-2.5 g/cubic centimeter) and incomparable wear resistance, pressure resistance, high temperature resistance, corrosion resistance and the like compared with other decorative materials.
After the common artificial quartz stone is processed into a finished product, the artificial quartz stone is directly polished and polished without carrying out deep treatment on the surface, and the surface of the artificial quartz stone is easy to be polluted and has poor stain resistance.
The invention discloses a patent application with the patent publication number of CN102643052B, in particular to a manufacturing method of a stain-resistant artificial quartz stone. The invention relates to a method for preparing quartz sand, which is characterized in that the raw material quartz sand for preparing quartz stone is subjected to mechanical activation modification, so that the fluidity of the quartz sand in the pressing process is enhanced, the quartz sand tends to be orderly and densely stacked, and meanwhile, the bonding force between the quartz sand and resin is increased in the curing process; the proportion and the particle size distribution range of the artificial quartz stone are strictly controlled, and the number of micron-sized holes on the surface of the artificial quartz stone is reduced to the maximum extent; the surface of the artificial quartz stone is filled to form chemical adsorption, so that the surface glossiness of the artificial quartz stone is improved; the micron-sized film formed on the surface of the artificial quartz stone has the hydrophobic characteristic, oily pollution can be removed within 24 hours by using wet cotton cloth, dirt hiding and bleeding are effectively prevented, and the micron-sized film has a strong stain resistance characteristic. The treatment method has the advantages of simple process, easy operation and short time consumption. The technical problem that this technical scheme hopes to solve is that synthetic quartz is easily contaminated problem.
The invention discloses a method for manufacturing a man-made quartz stone plate with the invention name of CN 108483995B. The method solves the technical problems that the existing artificial quartz stone plate is not provided with a corresponding manufacturing method, is manufactured only by manual experience, is low in manufacturing speed and the like. The manufacturing method of the man-made quartz stone plate comprises the following steps: a. weighing the following raw materials: 30-40 parts of quartz sand, 20-26 parts of quartz powder, 2-6 parts of epoxy resin, 1-5 parts of polyvinyl chloride resin, 11-16 parts of medical stone powder, 2-6 parts of pigment, 4-9 parts of silica sand, 6-10 parts of wollastonite, 6-12 parts of coconut shell carbon and 7-11 parts of coal cinder; b. b, uniformly mixing the raw materials in the step a in a stirrer, flatly paving the mixture on a mold, then conveying the mold into a vacuum chamber, and carrying out vibration molding to obtain the artificial quartz stone; c. polishing the molded artificial quartz stone by using a water mill polishing device; d. and punching, spraying and drying the polished artificial quartz stone through a processing device. The invention has the advantage of rapid manufacture. The technical scheme solves the preparation problem of the artificial quartz stone plate.
The invention discloses an artificial quartz stone plate with the invention name of CN206737352U, which comprises an artificial quartz stone substrate and a bamboo skin reticular surface lattice, wherein the bamboo skin reticular surface lattice is pressed on the upper surface of the artificial quartz stone substrate, the upper surface of the artificial quartz stone substrate is provided with protrusions embedded into grid holes of the bamboo skin reticular surface lattice, an aluminum honeycomb plate is arranged in the artificial quartz stone substrate, and the honeycomb holes of the aluminum honeycomb plate are through holes. The technical proposal introduces structures such as bamboo splits net-shaped surface lattices into the plate, and is suitable for being used as decorative materials such as home decoration floors and the like.
In the prior art, the defects of processing pollution, high VOC content, strong and pungent taste, environmental pollution, high temperature resistance, wear resistance, poor weather resistance, outdoor use, toxic and odorous plates and the like still exist. Further improvements in production technology are an objective need in the art.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide inorganic aqueous high-temperature-resistant artificial quartz stone and a preparation method thereof. Overcomes the technical defects of pollution in the processing process of the artificial quartz stone and big smell and toxicity of the product in the prior art.
The invention relates to an inorganic water-based high-temperature-resistant artificial quartz stone and a preparation method thereof.
The raw materials of the inorganic water-based artificial quartz stone comprise inorganic water-based nano glue, a curing agent, quartz powder, quartz sand, alumina, glass sand, ferric oxide toner, titanium dioxide, glass sand and fiber yarns.
Further, the inorganic aqueous artificial quartz stone comprises the following raw materials in parts by weight: 13-17 parts of inorganic water-based nano glue, 7-10 parts of curing agent, 15-20 parts of quartz powder, 5-10 parts of alumina, 35-45 parts of quartz sand, 10-15 parts of glass sand, 0.1-0.3 part of ferric oxide toner and 0.2-0.5 part of fiber yarn.
The method comprises weighing raw materials, mixing in a stirrer, stirring, and mixing color to obtain texture; and then flatly spreading the mixture on a mould, then sending the mould into a vacuum chamber, vacuumizing, defoaming, jolting or pressing, drying, curing and cooling to obtain a final product.
The stirring speed in the stirring step is 450-550 rpm; the stirring time in the stirring step is 20-30 min; the air pressure of the mould is controlled to be-0.10 to-0.05 MPa in the vacuumizing step; the drying and curing temperature is 80-200 ℃, and preferably 120-180 ℃.
Further, the preferable technical scheme of the invention is that the raw materials comprise, by weight: 14.2-16 parts of inorganic water-based nano glue, 7.8-8.2 parts of curing agent, 16-18 parts of quartz powder, 7.5-8.5 parts of aluminum oxide, 38-42 parts of quartz sand, 11.5-12.8 parts of glass sand, 0.15-0.2 part of ferric oxide toner and 0.38-0.45 part of fiber yarn.
More preferably, the raw materials comprise, in parts by weight: 15 parts of inorganic water-based nano glue, 8 parts of curing agent, 17.5 parts of quartz powder, 8 parts of alumina, 40 parts of quartz sand, 12 parts of glass sand, 0.18 part of ferric oxide toner and 0.4 part of fiber yarn.
Compared with the prior art, the invention has the following remarkable advantages and effects: by using the formula and the preparation method of the technical scheme of the invention, the pollution in the processing process can be effectively overcome, and the health and safety of production personnel can be guaranteed; overcomes the defects of high VOC content, pungent taste, no environmental protection, no high temperature resistance, no wear resistance and poor weather resistance.
In order to make the purpose and technical solution of the embodiments of the present invention clearer, the technical solution of the embodiments of the present invention will be clearly and completely described below with reference to the implementation examples of the embodiments of the present invention. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be made by a person skilled in the art without inventive effort based on the described embodiments of the invention, fall within the scope of protection of the invention.
Detailed description of the preferred embodiments
The technical solution of the present invention is further illustrated by the following specific examples. In the following embodiments, the raw materials are all commercial products purchased from the relevant manufacturing enterprises or commercial departments, unless otherwise specified.
Example 1
This embodiment 1 specifically includes the following steps:
(1) weighing raw materials: 14.2 kg of inorganic water-based nano-gel, 7.8 kg of curing agent, 16 kg of quartz powder, 7.5 kg of alumina, 38 kg of quartz sand, 11.5 kg of glass sand, 0.15 kg of ferric oxide toner and 0.38 kg of fiber yarn are accurately weighed.
(2) Putting the mixture into a stirrer for uniform mixing, and uniformly stirring, wherein the stirring speed in the stirring step is 450 rpm; stirring for 30 min; color matching and texture making;
(3) then flatly spreading the mixture on a mold, then sending the mold into a vacuum chamber, vacuumizing and defoaming, wherein the air pressure of the mold is controlled to be-0.08 MPa in the vacuumizing step;
(4) and (5) jolting, drying and curing at 200 ℃, cooling, and then grinding and polishing to obtain the final product.
Example 2
This embodiment 2 specifically includes the following steps:
(1) weighing raw materials: 16 kg of inorganic water-based nano-gel, 8.2 kg of curing agent, 18 kg of quartz powder, 8.5 kg of alumina, 42 kg of quartz sand, 12.8 kg of glass sand, 0.2 kg of iron oxide toner and 0.45 kg of fiber yarn are accurately weighed.
(2) Putting the mixture into a stirrer for uniform mixing, and uniformly stirring, wherein the stirring speed in the stirring step is 500 rpm; stirring for 30 min; color matching and texture making;
(3) then flatly spreading the mixture on a mold, then sending the mold into a vacuum chamber, vacuumizing and defoaming, wherein the air pressure of the mold is controlled to be-0.05 MPa in the vacuumizing step;
(4) and (4) jolting, drying and curing at 120 ℃, cooling, and then grinding and polishing to obtain the final product.
Example 3
This embodiment 3 specifically includes the following steps:
(1) weighing raw materials: accurately weighing 15 kg of inorganic water-based nano-gel, 8 kg of curing agent, 17.5 kg of quartz powder, 8 kg of alumina, 40 kg of quartz sand, 12 kg of glass sand, 0.18 kg of ferric oxide toner and 0.4 kg of fiber yarn.
(2) Putting the mixture into a stirrer for uniform mixing, and uniformly stirring, wherein the stirring speed in the stirring step is 520 rpm; stirring for 25 min; color matching and texture making;
(3) then flatly spreading the mixture on a mold, then sending the mold into a vacuum chamber, vacuumizing and defoaming, wherein the air pressure of the mold is controlled to be-0.10 MPa in the vacuumizing step;
(4) and (4) jolting, drying and curing at 180 ℃, cooling, and then grinding and polishing to obtain the final product.
Example 4
This embodiment 4 specifically includes the following steps:
(1) weighing raw materials: 17 kg of inorganic water-based nano-gel, 10 kg of curing agent, 20 kg of quartz powder, 10 kg of alumina, 45 kg of quartz sand, 15 kg of glass sand, 0.3 kg of iron oxide toner and 0.5 kg of fiber yarn are accurately weighed.
(2) Uniformly mixing the materials in a stirrer, and uniformly stirring the materials at a stirring speed of 550rpm in the stirring step; stirring for 28 min; color matching and texture making;
(3) then flatly spreading the mixture on a mold, then sending the mold into a vacuum chamber, vacuumizing and defoaming, wherein the air pressure of the mold is controlled to be-0.10 MPa in the vacuumizing step;
(4) jolting, drying and solidifying at 175 ℃, cooling, and then grinding and polishing to obtain the final product.
Example 5
This embodiment 5 specifically includes the following steps:
(1) weighing raw materials: 13 kg of inorganic water-based nano-gel, 7 kg of curing agent, 15 kg of quartz powder, 5 kg of alumina, 35 kg of quartz sand, 10 kg of glass sand, 0.1 kg of iron oxide toner and 0.2 kg of fiber yarn are accurately weighed.
(2) Putting the mixture into a stirrer for uniform mixing, and uniformly stirring, wherein the stirring speed in the stirring step is 500 rpm; stirring for 25 min; color matching and texture making;
(3) then flatly spreading the mixture on a mold, then sending the mold into a vacuum chamber, vacuumizing and defoaming, wherein the air pressure of the mold is controlled to be-0.08 MPa in the vacuumizing step;
(4) jolting, drying and solidifying at 150 ℃, cooling, and then grinding and polishing to obtain the final product.
The above description further describes a specific embodiment of the present invention with reference to specific examples, which are intended for the detailed description of the present invention and are not intended to limit the present invention. The above-mentioned embodiments are merely descriptions of the preferred embodiments of the present invention, and do not limit the technical concept and the protection scope of the present invention, and various modifications and improvements made to the technical concept by those skilled in the art without departing from the design concept of the present invention shall fall within the protection scope of the present invention.
Claims (10)
1. The inorganic water-based high-temperature-resistant artificial quartz stone is characterized in that raw materials of the inorganic water-based high-temperature-resistant artificial quartz stone comprise inorganic water-based nano glue, a curing agent, quartz powder, quartz sand, alumina, glass sand, ferric oxide toner, titanium dioxide, glass sand and fiber yarns.
2. The inorganic aqueous high-temperature-resistant artificial quartz stone according to claim 1, wherein the inorganic aqueous high-temperature-resistant artificial quartz stone raw material comprises, by weight: 13-17 parts of inorganic water-based nano glue, 7-10 parts of curing agent, 15-20 parts of quartz powder, 5-10 parts of alumina, 35-45 parts of quartz sand, 10-15 parts of glass sand, 0.1-0.3 part of ferric oxide toner and 0.2-0.5 part of fiber yarn.
3. The inorganic aqueous high-temperature-resistant artificial quartz stone according to claim 2, wherein the inorganic aqueous high-temperature-resistant artificial quartz stone raw material comprises the following components in parts by weight: 14.2-16 parts of inorganic water-based nano glue, 7.8-8.2 parts of curing agent, 16-18 parts of quartz powder, 7.5-8.5 parts of aluminum oxide, 38-42 parts of quartz sand, 11.5-12.8 parts of glass sand, 0.15-0.2 part of ferric oxide toner and 0.38-0.45 part of fiber yarn.
4. The inorganic aqueous high temperature resistant artificial quartz stone according to claim 3, characterized in that the raw materials comprise, in parts by weight: 15 parts of inorganic water-based nano glue, 8 parts of curing agent, 17.5 parts of quartz powder, 8 parts of alumina, 40 parts of quartz sand, 12 parts of glass sand, 0.18 part of ferric oxide toner and 0.4 part of fiber yarn.
5. A preparation method of inorganic water-based high-temperature-resistant artificial quartz stone is characterized by comprising the following steps of weighing raw materials, uniformly mixing the raw materials in a stirrer, uniformly stirring, and carrying out color mixing to obtain textures; and then flatly spreading the mixture on a mould, then sending the mould into a vacuum chamber, vacuumizing, defoaming, jolting or pressing, drying, solidifying and cooling to obtain a final product.
6. The method according to claim 5, wherein the stirring speed in the stirring step is 450 to 550 rpm.
7. The method according to claim 5, wherein the stirring time in the stirring step is 20 to 30 min.
8. The method according to claim 5, wherein the mold pressure is controlled to be-0.10 to-0.05 MPa in the evacuation step.
9. The method according to claim 5, wherein the drying and curing temperature is 80-200 ℃, and the polishing is carried out after cooling.
10. The method as claimed in claim 9, wherein the drying and curing temperature is 120-180 ℃.
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| CN202110758897.4A CN113666673B (en) | 2021-07-05 | 2021-07-05 | Inorganic water-based high-temperature-resistant artificial quartz stone and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007920A (en) * | 2007-01-22 | 2007-08-01 | 陈东阜 | Inorganic corrosion-proof fire-resistant abrasive-proof nano cementing agent |
| CN104496271A (en) * | 2014-12-15 | 2015-04-08 | 田忠和 | Artificial quartzite plate and manufacturing method thereof |
| CN106810115A (en) * | 2015-12-01 | 2017-06-09 | 衡阳双雁运输机械有限公司 | Fire resisting quartzite slate and its manufacture method |
| JP2020006412A (en) * | 2018-07-09 | 2020-01-16 | 花王株式会社 | Fire-resistant aggregate |
| CN111439967A (en) * | 2020-03-09 | 2020-07-24 | 浙江巍华新型建材有限公司 | Saltpetering-resistant high-strength inorganic artificial stone material and preparation process for decorative plate by using same |
-
2021
- 2021-07-05 CN CN202110758897.4A patent/CN113666673B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007920A (en) * | 2007-01-22 | 2007-08-01 | 陈东阜 | Inorganic corrosion-proof fire-resistant abrasive-proof nano cementing agent |
| CN104496271A (en) * | 2014-12-15 | 2015-04-08 | 田忠和 | Artificial quartzite plate and manufacturing method thereof |
| CN106810115A (en) * | 2015-12-01 | 2017-06-09 | 衡阳双雁运输机械有限公司 | Fire resisting quartzite slate and its manufacture method |
| JP2020006412A (en) * | 2018-07-09 | 2020-01-16 | 花王株式会社 | Fire-resistant aggregate |
| CN111439967A (en) * | 2020-03-09 | 2020-07-24 | 浙江巍华新型建材有限公司 | Saltpetering-resistant high-strength inorganic artificial stone material and preparation process for decorative plate by using same |
Non-Patent Citations (1)
| Title |
|---|
| 袁林等: "《绿色耐火材料》", 31 January 2015, 中国建材工业出版社 * |
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