CN102167540A - Anti-static flame-retardant quartz stone product and manufacturing method thereof - Google Patents
Anti-static flame-retardant quartz stone product and manufacturing method thereof Download PDFInfo
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- CN102167540A CN102167540A CN 201010601886 CN201010601886A CN102167540A CN 102167540 A CN102167540 A CN 102167540A CN 201010601886 CN201010601886 CN 201010601886 CN 201010601886 A CN201010601886 A CN 201010601886A CN 102167540 A CN102167540 A CN 102167540A
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Abstract
The invention provides an anti-static flame-retardant quartz stone product and a manufacturing method thereof. The quartz stone product comprises the following components in percentage by mass: 8 to 18 percent of resin, 70 to 90 percent of inorganic filler, 0 to 6 percent of color paste, 0.1 to 2 percent of silane coupling agent, 1.5 to 2 percent of antistatic agent, 1 to 15 percent of flame retardant, a promoter accounting for 0.3 to 2 percent of resin, and a curing agent accounting for 0.5 to 3 percent of resin. The invention also discloses a method for manufacturing the quartz stone product, which comprises the following steps of: mixing all raw materials, and filling in a mold; performing vacuum or high pressure vibration degassing, and curing and forming through normal temperature pouring or high temperature pressing; and performing surface polishing treatment. The quartz stone product has antistatic and flame-retardant properties, and is safe and environment-friendly.
Description
Technical field
The present invention relates to a kind of artificial stone product and making method, relate in particular to a kind of synthetic quartz stoneware and preparation method thereof.
Background technology
The quartzite goods are widely used as building and ornament materials all the time and make furniture, lay the ground, metope of various buildings etc.Present quartzite goods general using unsaturated polyester resin and quartz powder filler are produced, and there is no the special auxiliary agent of adding other, do not have anti-electrostatic and flame retardant properties.And static is a kind of objective spontaneous phenomenon, in daily life, during physical activity, friction mutually just can produce static between skin and the clothes and between clothes and the clothes, along with household electrical appliance increase and winter people wear the chemical fibre clothes more, the static charge that household electrical appliance produced can be absorbed by the body and accumulate, room interior walls and floor belong to isolator more in addition, dry air, the therefore easier statics that is subjected to.Static also is very harmful to a lot of industrial production, can attract dust as static, and static can cause spark, and static can disturb wireless apparatus, and these all can threaten to industrial quality and safety.In addition, the material behavior of quartzite goods has determined itself not have flame-retarding characteristic, has certain potential safety hazard.
Summary of the invention
The object of the present invention is to provide a kind of quartzite goods of anti-static inflaming-retarding.
The present invention is by adding static inhibitor and fire retardant realization in the making prescription of quartzite goods.
Above-mentioned quartzite goods contain following component: 8%-18% resin, 70%-90% mineral filler, 0%-6% mill base, the 0.1%-2% silane coupling agent, 1.5%-2% static inhibitor, 1%-15% fire retardant, account for the promotor of resin quality 0.3%-2%, account for the solidifying agent of resin quality 0.5-3%; Above per-cent is mass percent.
In the preferred embodiment of the present invention, described quartzite goods contain: the resin that accounts for total mass 16.66%, account for the mineral filler of total mass 78.16%, account for the mill base of total mass 1.28%, account for the silane coupling agent of total mass 0.19%, account for the static inhibitor of total mass 1.92%, account for the fire retardant of total mass 1.54%, and the promotor that accounts for resin quality 0.5%, account for the solidifying agent of resin quality 1%.
In another preferred embodiment of the present invention, described quartzite goods contain: the resin that accounts for total mass 10.68%, account for the mineral filler of total mass 85.42%, account for the mill base of total mass 0.97%, account for the silane coupling agent of total mass 0.15%, account for the static inhibitor of total mass 1.46%, account for the fire retardant of total mass 1.16%, and the promotor that accounts for resin quality 0.5%, account for the solidifying agent of resin quality 1.1%.
Above-mentioned resin is that resin used in the present invention is metaphenylene unsaturated polyester resin, adjacent benzene type unsaturated polyester resin, wherein a kind of of pure plexiglass.
Mineral filler used herein comprises granular filler and powder filler.Granular filler is: the inorganic mineral ground grains of high rigidity such as glass ground grains, quartz mine ground grains, and use wherein one or more to arrange in pairs or groups, granular size is that 2 orders are to 100 orders; Powder filler is: inorganic mineral powder such as silica powder, heavy carbonic calcium powder, and use wherein one or more to arrange in pairs or groups, the particle diameter of powder is 100 orders-800 orders.
Mill base used in the present invention is that this area is used for rostone painted various pigment or dyestuff, uses the mill base of different colours according to the goods color.
Silane coupling agent used in the present invention is silane coupling agents such as methacryloxy Trimethoxy silane.
Promotor used in the present invention is wherein a kind of of cobalt iso-octoate, cobalt naphthenate.
Solidifying agent used in the present invention is a methylethyl ketone peroxide, cyclohexanone peroxide, peroxidation ketones such as the peroxidation 2 ethyl hexanoic acid tert-butyl ester.
Static inhibitor used in the present invention is the commercially available prod Entire as 100 permanent anti-static agent that E.I.Du Pont Company produces.
Fire retardant used in the present invention is that fire retardant is the commercially available prod Doher-6200 of Dao Er Chemical Manufacture.
All raw materials and reagent that the present invention uses are commercially available getting.
The present invention also provides the making method of above-mentioned quartzite goods, and step is: at first, above-mentioned raw materials is mixed, pour into mould, secondly, carry out the vacuum vibration or the vacuum pressing degassing, adopt normal temperature or hot setting moulding; At last, carry out the surface finish processing and can obtain goods.
Beneficial effect of the present invention is: owing to added static inhibitor and fire retardant in prescription, above-mentioned quartzite goods have antistatic and fire-retardant performance.Adding static inhibitor can make in these quartzite goods static store to minimize, prevent buildup of static electricity and the adverse consequences of bringing thereof; The flame retardant properties that has owing to the adding fire retardant can significantly improve the security that these quartzite goods are used.
Embodiment
Below by embodiment, technical scheme of the present invention is described further, but does not limit the present invention in any form:
Embodiment 1: the manufacture method of the quartzite goods of casting type anti-static inflaming-retarding:
The composition of raw materials of present embodiment is: the resin that accounts for total mass 16.66%, account for the mineral filler of total mass 78.16%, account for the mill base of total mass 1.28%, account for the silane coupling agent of total mass 0.19%, account for the static inhibitor of total mass 1.92%, account for the fire retardant of total mass 1.54%, and the promotor that accounts for resin quality 0.5%, account for the solidifying agent of resin quality 1%.
Get by above-mentioned prescription: adjacent benzene type unsaturated polyester resin 13kg, white glass particle 33kg, 325 order quartz powder filler 28kg, stock white 1000g, silane coupling agent 150g, the Entire as100 of Du Pont permanent anti-static agent 1.5kg, the Doher-6200 fire retardant 1.2kg of Dao Er chemical industry, promotor cobalt iso-octoate 65 grams, solidifying agent methylethyl ketone peroxide 130 grams.
Above all raw materials are mixed, pour in the mould after stirring, vacuumize vibrations exhaust bubble, curing molding takes out and carries out the surface finish processing, obtains the quartzite goods of casting type anti-static inflaming-retarding.
Embodiment 2: the manufacture method of the quartzite goods of press type anti-static inflaming-retarding:
The composition of raw materials of present embodiment is: the resin that accounts for total mass 10.68%, account for the mineral filler of total mass 85.42%, account for the mill base of total mass 0.97%, account for the silane coupling agent of total mass 0.15%, account for the static inhibitor of total mass 1.46%, account for the fire retardant of total mass 1.16%, and the promotor that accounts for resin quality 0.5%, account for the solidifying agent of resin quality 1.1%.
Get by above-mentioned prescription: adjacent benzene type unsaturated polyester resin 11kg, white glass particle 55kg, 325 order quartz powder filler 33kg, stock white 1000g, silane coupling agent 150g, the Entire as100 of Du Pont permanent anti-static agent 1.5kg, the Doher-6200 fire retardant 1.2kg of Dao Er chemical industry, promotor cobalt iso-octoate 55 grams, solidifying agent methylethyl ketone peroxide 121g.
Above all raw materials are mixed, pour in the sunglasses after stirring, the vacuum high-pressure compacting shakes the exhaust bubble simultaneously, and curing molding under 90 degree high temperature takes out postcooling, carries out surface finish and handles, and obtains the quartzite goods of press type anti-static inflaming-retarding.
Claims (13)
1. quartzite goods, it is characterized in that containing following component: the resin that accounts for total mass 8%-18%, account for the mineral filler of total mass 70%-90%, account for the mill base of total mass 0%-6%, account for the silane coupling agent of total mass 0.1%-2%, account for the static inhibitor of total mass 1.5%-2%, account for the fire retardant of total mass 1%-15%, and the promotor that accounts for resin quality 0.3%-2%, account for the solidifying agent of resin quality 0.5%-3%.
2. a kind of quartzite goods according to claim 1, it is characterized in that: described quartzite contains following component: the resin that accounts for total mass 16.66%, account for the mineral filler of total mass 78.16%, account for the mill base of total mass 1.28%, account for the silane coupling agent of total mass 0.19%, account for the static inhibitor of total mass 1.92%, account for the fire retardant of total mass 1.54%, and the promotor that accounts for resin quality 0.5%, account for the solidifying agent of resin quality 1%.
3. a kind of quartzite goods according to claim 1, it is characterized in that: described quartzite contains following component: the resin that accounts for total mass 10.68%, account for the mineral filler of total mass 85.42%, account for the mill base of total mass 0.97%, account for the silane coupling agent of total mass 0.15%, account for the static inhibitor of total mass 1.46%, account for the fire retardant of total mass 1.16%, and the promotor that accounts for resin quality 0.5%, account for the solidifying agent of resin quality 1.1%.
4. according to each described quartzite goods of claim 1 to 3, it is characterized in that: this resin is wherein a kind of of metaphenylene unsaturated polyester resin, adjacent benzene type unsaturated polyester resin, pure plexiglass.
5. according to each described quartzite goods of claim 1 to 3, it is characterized in that: this mineral filler comprises granular filler and powder filler; This granular filler is that size is one or more in 2 order to 100 purpose glass cullet, the quartz mine particle; This powder filler is that size is one or more in 100 order to 800 purpose silica powders, the heavy carbonic calcium powder.
6. according to each described quartzite goods of claim 1 to 3, it is characterized in that: this mill base is industrial pigment.
7. according to each described quartzite goods of claim 1 to 3, it is characterized in that: this silane coupling agent is a methacryloxy Trimethoxy silane coupling agent.
8. according to each described quartzite goods of claim 1 to 3, it is characterized in that: this promotor is cobalt iso-octoate or cobalt naphthenate.
9. according to each described quartzite goods of claim 1 to 3, it is characterized in that: this solidifying agent is wherein a kind of of methylethyl ketone peroxide, cyclohexanone peroxide, the peroxidation 2 ethyl hexanoic acid tert-butyl ester.
10. according to each described quartzite goods of claim 1 to 3, it is characterized in that: this static inhibitor is Entire as 100 permanent anti-static agent.
11. according to each described quartzite goods of claim 1 to 3, it is characterized in that: this fire retardant is Doher-6200.
12. according to the making method of each described quartzite goods of claim 1 to 3, its step comprises: at first, raw material is mixed, pour into mould, secondly, carry out the vacuum vibration or the vacuum pressing degassing, adopt normal temperature or hot setting moulding; At last, carry out the surface finish processing and can obtain goods.
13. according to claim 10 described making methods, its feature also is: the temperature of hot setting moulding process is 90 degrees centigrade.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010601886 CN102167540A (en) | 2010-12-23 | 2010-12-23 | Anti-static flame-retardant quartz stone product and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201010601886 CN102167540A (en) | 2010-12-23 | 2010-12-23 | Anti-static flame-retardant quartz stone product and manufacturing method thereof |
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| CN 201010601886 Pending CN102167540A (en) | 2010-12-23 | 2010-12-23 | Anti-static flame-retardant quartz stone product and manufacturing method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102491682A (en) * | 2011-12-02 | 2012-06-13 | 罗志军 | Fire-proof plate and producing method thereof |
| CN103553436A (en) * | 2013-10-21 | 2014-02-05 | 岑巩县宏宇新型材料有限责任公司 | Artificial quartz plate and production method thereof |
| CN103588419A (en) * | 2013-11-15 | 2014-02-19 | 桂林理工大学 | Method for preparing quartz plate with changeable colors |
| CN106007480A (en) * | 2016-06-22 | 2016-10-12 | 金华知产婺源信息技术有限公司 | Preparation method of flame-retardant artificial stone containing pleonaste |
| CN109279819A (en) * | 2018-09-20 | 2019-01-29 | 佛山市欧泊石业有限公司 | A kind of preparation method of high-performance artificial marble |
| CN109293284A (en) * | 2018-09-20 | 2019-02-01 | 佛山市欧泊石业有限公司 | A kind of high-performance artificial marble |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1363475A (en) * | 2001-11-15 | 2002-08-14 | 郭旭清 | Artificial carved stone as decoration |
| CN1364685A (en) * | 2002-01-31 | 2002-08-21 | 梅县龙盘新型建材有限公司 | Method for producing reproduced quartzite slate |
-
2010
- 2010-12-23 CN CN 201010601886 patent/CN102167540A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1363475A (en) * | 2001-11-15 | 2002-08-14 | 郭旭清 | Artificial carved stone as decoration |
| CN1364685A (en) * | 2002-01-31 | 2002-08-21 | 梅县龙盘新型建材有限公司 | Method for producing reproduced quartzite slate |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102491682A (en) * | 2011-12-02 | 2012-06-13 | 罗志军 | Fire-proof plate and producing method thereof |
| CN103553436A (en) * | 2013-10-21 | 2014-02-05 | 岑巩县宏宇新型材料有限责任公司 | Artificial quartz plate and production method thereof |
| CN103553436B (en) * | 2013-10-21 | 2016-04-27 | 岑巩县宏宇新型材料有限责任公司 | A kind of artificial quartz plate and production method thereof |
| CN103588419A (en) * | 2013-11-15 | 2014-02-19 | 桂林理工大学 | Method for preparing quartz plate with changeable colors |
| CN103588419B (en) * | 2013-11-15 | 2015-07-22 | 桂林理工大学 | Method for preparing quartz plate with changeable colors |
| CN106007480A (en) * | 2016-06-22 | 2016-10-12 | 金华知产婺源信息技术有限公司 | Preparation method of flame-retardant artificial stone containing pleonaste |
| CN106007480B (en) * | 2016-06-22 | 2018-08-07 | 金华知产婺源信息技术有限公司 | A kind of preparation method of the fire retardant man-made stone containing magnesium aluminate spinel |
| CN109279819A (en) * | 2018-09-20 | 2019-01-29 | 佛山市欧泊石业有限公司 | A kind of preparation method of high-performance artificial marble |
| CN109293284A (en) * | 2018-09-20 | 2019-02-01 | 佛山市欧泊石业有限公司 | A kind of high-performance artificial marble |
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Application publication date: 20110831 |