CN113652762A - Processing method of fishing net thread preventing adhesion and deposition of aquatic plants - Google Patents
Processing method of fishing net thread preventing adhesion and deposition of aquatic plants Download PDFInfo
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- CN113652762A CN113652762A CN202111006248.5A CN202111006248A CN113652762A CN 113652762 A CN113652762 A CN 113652762A CN 202111006248 A CN202111006248 A CN 202111006248A CN 113652762 A CN113652762 A CN 113652762A
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- 230000008021 deposition Effects 0.000 title claims abstract description 35
- 238000003672 processing method Methods 0.000 title claims abstract description 23
- 238000000151 deposition Methods 0.000 claims abstract description 42
- 238000000227 grinding Methods 0.000 claims abstract description 26
- 239000011324 bead Substances 0.000 claims abstract description 23
- 239000012767 functional filler Substances 0.000 claims abstract description 20
- 238000002074 melt spinning Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims abstract description 9
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 238000012545 processing Methods 0.000 claims abstract description 9
- 239000011812 mixed powder Substances 0.000 claims description 61
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 60
- 239000000203 mixture Substances 0.000 claims description 35
- 239000007788 liquid Substances 0.000 claims description 30
- 229910052757 nitrogen Inorganic materials 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 28
- 239000003242 anti bacterial agent Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 229940088710 antibiotic agent Drugs 0.000 claims description 23
- 238000009987 spinning Methods 0.000 claims description 22
- 238000005303 weighing Methods 0.000 claims description 21
- 238000001035 drying Methods 0.000 claims description 19
- 230000008635 plant growth Effects 0.000 claims description 17
- 239000002028 Biomass Substances 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 238000010298 pulverizing process Methods 0.000 claims description 14
- 229920001800 Shellac Polymers 0.000 claims description 13
- 239000004208 shellac Substances 0.000 claims description 13
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims description 13
- 229940113147 shellac Drugs 0.000 claims description 13
- 235000013874 shellac Nutrition 0.000 claims description 13
- 238000007873 sieving Methods 0.000 claims description 12
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 11
- -1 polyethylene Polymers 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- 229940005581 sodium lactate Drugs 0.000 claims description 11
- 235000011088 sodium lactate Nutrition 0.000 claims description 11
- 239000001540 sodium lactate Substances 0.000 claims description 11
- 238000007711 solidification Methods 0.000 claims description 11
- 230000008023 solidification Effects 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 11
- 238000005096 rolling process Methods 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 230000003115 biocidal effect Effects 0.000 claims description 7
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 230000014759 maintenance of location Effects 0.000 abstract description 5
- 239000000377 silicon dioxide Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 6
- 239000003610 charcoal Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007777 multifunctional material Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K75/00—Accessories for fishing nets; Details of fishing nets, e.g. structure
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M21/00—Apparatus for the destruction of unwanted vegetation, e.g. weeds
- A01M21/04—Apparatus for destruction by steam, chemicals, burning, or electricity
- A01M21/043—Apparatus for destruction by steam, chemicals, burning, or electricity by chemicals
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- Environmental Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Manufacturing & Machinery (AREA)
- Insects & Arthropods (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Mechanical Engineering (AREA)
- Marine Sciences & Fisheries (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a method for processing a fishing net thread preventing adhesion and deposition of aquatic plants, which belongs to the technical field of fishing net processing and comprises the following steps: (1) carrying out cryogenic crushing treatment; (2) microwave treatment; (3) carrying out cryogenic treatment; (4) performing bead grinding treatment; (5) coating treatment; (6) melt spinning; (7) and twisting the silk. The application provides a processing method of a fishing net thread preventing adhesion and deposition of aquatic plants, the finally prepared fishing net thread has high breaking strength and knot strength retention rate and excellent mechanical property, the quality of the fishing net thread is improved to a great extent, and the fishing net thread has high market popularization and application values. The application provides a processing method of preventing aquatic plant from attaching and depositing fishing net lines, effectively prevents the fishing net from attaching and depositing aquatic plants in the using process, effectively improves the quality of the fishing net, prolongs the service life of the fishing net lines, particularly adds functional fillers, and can also effectively prevent the attaching and depositing of the aquatic plants while improving the strength.
Description
Technical Field
The invention belongs to the technical field of fishing net processing, and particularly relates to a processing method of a fishing net line preventing adhesion and deposition of aquatic plants.
Background
The fishing net thread is a thread with the diameter of less than 4 mm for weaving net sheets and sewing net fishing tools, and is a main material for manufacturing fishing nets. The biomass charcoal is a porous solid particulate matter which is highly aromatic and rich in carbon and is generated by pyrolysis of carbon-rich biomass under the condition of no oxygen or lack of oxygen. It contains a great deal of carbon and plant nutrient substances, has rich pore structures, larger specific surface area and more oxygen-containing active groups on the surface, and is a multifunctional material. The novel biological carbon adsorption fishing net can adsorb heavy metals and organic pollutants in sewage, is not used for research in fishing net line processing at present, can effectively improve the quality of the fishing net when used for processing the fishing net line, but cannot well enhance the strength of the fishing net only by using the biological carbon, and cannot prevent aquatic plants from attaching and depositing when the fishing net is used by being immersed in a water body, so that the service life of the fishing net is shortened.
Disclosure of Invention
The invention aims to provide a method for processing a fishing net thread preventing attachment and deposition of aquatic plants, aiming at the existing problems.
The invention is realized by the following technical scheme:
a processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 30-40 parts of biomass carbon, 15-25 parts of shellac and 6-10 parts of nano silicon dioxide in corresponding parts by weight, putting the materials into a deep cooling type pulverizer together for pulverizing treatment, and obtaining mixed powder A for later use after the pulverizing treatment is finished;
(2) microwave treatment:
placing the mixed powder A obtained in the step (1) in a microwave environment for microwave treatment, and taking out the mixed powder A for later use;
(3) cryogenic treatment:
placing the mixture A obtained in the step (2) in liquid nitrogen;
(4) bead grinding treatment:
taking the mixture A treated by the liquid nitrogen in the step (3) out of the liquid nitrogen, grinding the mixture A in a bead mill immediately, and sieving the mixture A to obtain mixed powder B for later use;
(5) coating treatment:
suspending the plant growth antibiotics in the air by using a fluidized bed, then adding the mixed powder B obtained in the step (4) to a fluidized bed in a spraying mode, wrapping the antibiotics in a suspension rolling state, and then drying in cold air to obtain the functional filler for later use;
(6) melt spinning:
weighing 70-80 parts of polyethylene, 30-40 parts of the functional filler obtained in the step (5), 6-8 parts of sodium lactate and 75-85 parts of deionized water according to corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing, stretching and drying;
(7) twisting:
and (4) twisting the blended yarns obtained in the step (6) into yarns.
Further, the temperature in the pulverizing machine is controlled to be-20 to-10 ℃ during the pulverizing treatment in the step (1).
Further, the power of the microwave is controlled to be 600-700W during the microwave treatment in the step (2), and the time of the microwave treatment is 4-6 min.
Further, the rotating speed of the bead mill in the step (4) is 1000-2000 rpm.
Further, the sieving in the step (4) is 80-120 meshes.
Further, the weight ratio of the plant growth antibiotics in the step (5) to the mixed powder is 1: 20-28.
By adopting the technical scheme, the biomass charcoal, the shellac and the nano-silica are jointly placed in a cryogenic grinder according to a proper proportion for grinding treatment, the grinding is carried out under the cryogenic condition, the homogenized and refined powder can be obtained, insect eggs or pathogenic bacteria possibly carried in the raw materials can be killed, the obtained powder is placed in a microwave environment for microwave treatment, in the microwave treatment process, the activity of the biomass charcoal and the nano-dioxide in the mixed powder is enhanced, meanwhile, the shellac powder can be melted and adhered to the surfaces of the biomass charcoal powder and the nano-silica powder, and is placed in liquid nitrogen for rapid cooling, because the inside and the outside of the mixture generate a plurality of extremely large inside and outside temperature differences in an extremely short time, extremely large internal stress can be generated in the mixture, and simultaneously, because of the adhesion effect of the shellac, the release of the internal stress is restrained, thereby further increasing the internal stress, causing the internal structure of the mixture to deform, thereby improving the processing characteristics of the mixture, improving the performance of the mixture, taking out the mixture, putting the mixture in a grinding aid for grinding treatment, generating kinetic energy by grinding, causing the internal stress to act with the external kinetic energy simultaneously and quickly discharging to obtain activated, refined and homogeneous mixed powder, uniformly wrapping the powder on the surface of an antibiotic, effectively preventing the inactivation of the antibiotic during the storage and use of melt spinning and fishing net lines, and effectively preventing the attachment and deposition of aquatic plants by the synergistic action of the antibiotic, wherein during the use, the antibiotic is slowly released to permanently and effectively kill the temporarily attached aquatic plants, the filler can also improve the compactness of the surface of the fishing net, avoid the adhesion of the aquatic plants, and effectively improve the strength of the fishing net lines without influencing the attachment and deposition of the aquatic plants, thereby prolonging the service life of the fishing net, shortening the cleaning time of the fishing net and saving the cost.
Compared with the prior art, the invention has the following advantages:
the application provides a processing method of a fishing net thread preventing adhesion and deposition of aquatic plants, the finally prepared fishing net thread has high breaking strength and knot strength retention rate and excellent mechanical property, the quality of the fishing net thread is improved to a great extent, and the fishing net thread has high market popularization and application values. The application provides a processing method of preventing aquatic plant from attaching and depositing fishing net lines, effectively prevents the fishing net from attaching and depositing aquatic plants in the using process, effectively improves the quality of the fishing net, prolongs the service life of the fishing net lines, particularly adds functional fillers, and can also effectively prevent the attaching and depositing of the aquatic plants while improving the strength.
Detailed Description
A processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 30-40 parts of biomass carbon, 15-25 parts of shellac and 6-10 parts of nano silicon dioxide in corresponding parts by weight, putting the materials into a deep cooling type pulverizer, and pulverizing, wherein the temperature in the pulverizer is controlled to be-20 to-10 ℃, and obtaining mixed powder A for later use;
(2) microwave treatment:
placing the mixed powder A obtained in the step (1) in a microwave environment for microwave treatment, wherein the power is 600-700W, and taking out the mixed powder A for later use after treatment for 4-6 min;
(3) cryogenic treatment:
placing the mixture A obtained in the step (2) in liquid nitrogen;
(4) bead grinding treatment:
taking the mixture A treated by the liquid nitrogen in the step (3) out of the liquid nitrogen, immediately placing the mixture A into a bead mill, grinding at 1000-2000 rpm, and sieving with a 80-120-mesh sieve to obtain mixed powder B for later use;
(5) coating treatment:
suspending the plant growth antibiotics in the air by using a fluidized bed, then adding the mixed powder B obtained in the step (4) onto a fluidized bed in a spraying mode, wrapping the antibiotics in a suspension rolling state, and then drying in cold air to obtain a functional filler for later use, wherein the weight ratio of the plant growth antibiotics to the mixed powder is controlled to be 1: 20-28;
(6) melt spinning:
weighing 70-80 parts of polyethylene, 30-40 parts of the functional filler obtained in the step (5), 6-8 parts of sodium lactate and 75-85 parts of deionized water according to corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing, stretching and drying;
(7) twisting:
and (4) twisting the blended yarns obtained in the step (6) into yarns.
For further explanation of the present invention, reference will now be made to the following specific examples.
Example 1
A processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 30 parts of biomass carbon, 15 parts of shellac and 6 parts of nano-silica in corresponding parts by weight, putting the materials into a deep-cooling crusher together for crushing treatment, controlling the temperature in the crusher to be-20 ℃, and obtaining mixed powder A for later use;
(2) microwave treatment:
placing the mixed powder A obtained in the step (1) in a microwave environment for microwave treatment with the power of 600W, and taking out the mixed powder A for later use after treatment for 4 min;
(3) cryogenic treatment:
placing the mixture A obtained in the step (2) in liquid nitrogen;
(4) bead grinding treatment:
taking the mixture A treated by the liquid nitrogen in the step (3) out of the liquid nitrogen, immediately placing the mixture A into a bead mill, grinding at 1000rpm, and sieving by a 80-mesh sieve to obtain mixed powder B for later use;
(5) coating treatment:
suspending the plant growth antibiotics in the air by using a fluidized bed, then adding the mixed powder B obtained in the step (4) onto a fluidized bed in a spraying mode, wrapping the antibiotics in a suspension rolling state, and then drying in cold air to obtain a functional filler for later use, wherein the weight ratio of the plant growth antibiotics to the mixed powder is controlled to be 1: 20;
(6) melt spinning:
weighing 70 parts of polyethylene, 30 parts of the functional filler obtained in the step (5), 6 parts of sodium lactate and 75 parts of deionized water in corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing stretching and drying;
(7) twisting:
and (4) twisting the blended yarns obtained in the step (6) into yarns.
Example 2
A processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 35 parts of biomass carbon, 20 parts of shellac and 8 parts of nano-silica in corresponding parts by weight, putting the components in a deep cooling type pulverizer together for pulverization treatment, controlling the temperature in the pulverizer to be-15 ℃, and obtaining mixed powder A for later use;
(2) microwave treatment:
placing the mixed powder A obtained in the step (1) in a microwave environment for microwave treatment with the power of 650W, and taking out the mixed powder A for later use after 5min of treatment;
(3) cryogenic treatment:
placing the mixture A obtained in the step (2) in liquid nitrogen;
(4) bead grinding treatment:
taking the mixture A treated by the liquid nitrogen in the step (3) out of the liquid nitrogen, immediately placing the mixture A into a bead mill, grinding at 1500rpm, and sieving by a 100-mesh sieve to obtain mixed powder B for later use;
(5) coating treatment:
suspending the plant growth antibiotics in the air by using a fluidized bed, then adding the mixed powder B obtained in the step (4) onto a fluidized bed in a spraying mode, wrapping the antibiotics in a suspension rolling state, and then drying in cold air to obtain a functional filler for later use, wherein the weight ratio of the plant growth antibiotics to the mixed powder is controlled to be 1: 24;
(6) melt spinning:
weighing 75 parts of polyethylene, 35 parts of the functional filler obtained in the step (5), 7 parts of sodium lactate and 80 parts of deionized water in corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing stretching and drying;
(7) twisting:
and (4) twisting the blended yarns obtained in the step (6) into yarns.
Example 3
A processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 40 parts of biomass carbon, 25 parts of shellac and 10 parts of nano-silica in corresponding parts by weight, putting the materials into a deep cooling type pulverizer together for pulverization treatment, controlling the temperature in the pulverizer to be-10 ℃, and obtaining mixed powder A for later use;
(2) microwave treatment:
placing the mixed powder A obtained in the step (1) in a microwave environment for microwave treatment with the power of 700W, and taking out the mixed powder A for later use after 6min of treatment;
(3) cryogenic treatment:
placing the mixture A obtained in the step (2) in liquid nitrogen;
(4) bead grinding treatment:
taking the mixture A treated by the liquid nitrogen in the step (3) out of the liquid nitrogen, immediately placing the mixture A in a bead mill, grinding at 2000rpm, and sieving by a 120-mesh sieve to obtain mixed powder B for later use;
(5) coating treatment:
suspending the plant growth antibiotics in the air by using a fluidized bed, then adding the mixed powder B obtained in the step (4) onto a fluidized bed in a spraying mode, wrapping the antibiotics in a suspension rolling state, and then drying in cold air to obtain a functional filler for later use, wherein the weight ratio of the plant growth antibiotics to the mixed powder is controlled to be 1: 28;
(6) melt spinning:
weighing 80 parts of polyethylene, 40 parts of the functional filler obtained in the step (5), 8 parts of sodium lactate and 85 parts of deionized water in corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing stretching and drying;
(7) twisting:
and (4) twisting the blended yarns obtained in the step (6) into yarns.
Example 4
A processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 35 parts of biomass carbon, 20 parts of shellac and 8 parts of nano-silica in corresponding parts by weight, putting the components in a deep cooling type pulverizer together for pulverization treatment, controlling the temperature in the pulverizer to be-15 ℃, and obtaining mixed powder A for later use;
(2) cryogenic treatment:
putting the mixed powder A obtained in the step (1) into liquid nitrogen;
(3) bead grinding treatment:
taking the mixed powder A treated by the liquid nitrogen in the step (2) out of the liquid nitrogen, immediately placing the mixed powder A into a bead mill, grinding at 1500rpm, and sieving by a 100-mesh sieve to obtain mixed powder B for later use;
(4) coating treatment:
suspending the plant growth antibiotics in the air by using a fluidized bed, then adding the mixed powder B obtained in the step (3) to a fluidized bed in a spraying mode, wrapping the antibiotics in a suspension rolling state, and then drying in cold air to obtain a functional filler for later use, wherein the weight ratio of the plant growth antibiotics to the mixed powder is controlled to be 1: 24;
(5) melt spinning:
weighing 75 parts of polyethylene, 35 parts of the functional filler obtained in the step (4), 7 parts of sodium lactate and 80 parts of deionized water in corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing stretching and drying;
(6) twisting:
and (5) twisting the blended yarns obtained in the step (5) into yarns.
Example 5
A processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 35 parts of biomass carbon, 20 parts of shellac and 8 parts of nano-silica in corresponding parts by weight, putting the components in a deep cooling type pulverizer together for pulverization treatment, controlling the temperature in the pulverizer to be-15 ℃, and obtaining mixed powder A for later use;
(2) microwave treatment:
placing the mixed powder A obtained in the step (1) in a microwave environment for microwave treatment with the power of 650W, and taking out the mixed powder A for later use after 5min of treatment;
(3) bead grinding treatment:
taking the mixture A treated by the liquid nitrogen in the step (2) out of the liquid nitrogen, immediately placing the mixture A into a bead mill, grinding at 1500rpm, and sieving by a 100-mesh sieve to obtain mixed powder B for later use;
(4) coating treatment:
suspending the plant growth antibiotics in the air by using a fluidized bed, then adding the mixed powder B obtained in the step (3) to a fluidized bed in a spraying mode, wrapping the antibiotics in a suspension rolling state, and then drying in cold air to obtain a functional filler for later use, wherein the weight ratio of the plant growth antibiotics to the mixed powder is controlled to be 1: 24;
(5) melt spinning:
weighing 75 parts of polyethylene, 35 parts of the functional filler obtained in the step (4), 7 parts of sodium lactate and 80 parts of deionized water in corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing stretching and drying;
(6) twisting:
and (5) twisting the blended yarns obtained in the step (5) into yarns.
Example 6
A processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 35 parts of biomass carbon, 20 parts of shellac and 8 parts of nano-silica in corresponding parts by weight, putting the components in a deep cooling type pulverizer together for pulverization treatment, controlling the temperature in the pulverizer to be-15 ℃, and obtaining mixed powder A for later use;
(2) microwave treatment:
placing the mixed powder A obtained in the step (1) in a microwave environment for microwave treatment with the power of 650W, and taking out the mixed powder A for later use after 5min of treatment;
(3) cryogenic treatment:
placing the mixture A obtained in the step (2) in liquid nitrogen;
(4) bead grinding treatment:
taking the mixture A treated by the liquid nitrogen in the step (3) out of the liquid nitrogen, immediately placing the mixture A into a bead mill, grinding at 1500rpm, and sieving by a 100-mesh sieve to obtain mixed powder B for later use;
(5) mixing treatment:
uniformly mixing the plant growth antibiotic and the mixed powder according to the weight ratio of 1:24 to obtain a functional filler for later use;
(6) melt spinning:
weighing 75 parts of polyethylene, 35 parts of the functional filler obtained in the step (5), 7 parts of sodium lactate and 80 parts of deionized water in corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing stretching and drying;
(7) twisting:
and (4) twisting the blended yarns obtained in the step (6) into yarns.
Example 7
A processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) melt spinning:
weighing 108.54 parts of polyethylene, 1.46 parts of antibiotic, 7 parts of sodium lactate and 80 parts of deionized water in corresponding parts by weight, putting the materials in a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing stretching and drying;
(2) twisting:
twisting the blended yarns obtained in the step (1) into yarns.
Example 8
A processing method of a fishing net line preventing adhesion and deposition of aquatic plants comprises the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 35 parts of biomass carbon, 20 parts of shellac and 8 parts of nano-silica in corresponding parts by weight, putting the components in a deep cooling type pulverizer together for pulverization treatment, controlling the temperature in the pulverizer to be-15 ℃, and obtaining mixed powder A for later use;
(2) microwave treatment:
placing the mixed powder A obtained in the step (1) in a microwave environment for microwave treatment with the power of 650W, and taking out the mixed powder A for later use after 5min of treatment;
(3) cryogenic treatment:
placing the mixture A obtained in the step (2) in liquid nitrogen;
(4) bead grinding treatment:
taking the mixture A treated by the liquid nitrogen in the step (3) out of the liquid nitrogen, immediately placing the mixture A into a bead mill, grinding at 1500rpm, and sieving by a 100-mesh sieve to obtain mixed powder B for later use;
(5) melt spinning:
weighing 76.46 parts of polyethylene, 33.54 parts of the mixed powder B obtained in the step (4), 7 parts of sodium lactate and 80 parts of deionized water in corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing, stretching and drying;
(6) twisting:
and (5) twisting the blended yarns obtained in the step (5) into yarns.
In order to compare the technical effects of the application, the fishing net lines are correspondingly prepared by the methods of the above embodiments 2 and 4-8 respectively, and then the mechanical property test and the adhesion and deposition resistance test of the aquatic plants are carried out.
The method specifically comprises the following steps:
(1) and (3) testing mechanical properties:
the breaking strength is measured by a British INSTRON-4466 type strength tester, the temperature is controlled to be 20 +/-2 ℃, the relative humidity is controlled to be 65 +/-5 percent, the stretching speed is controlled to be 330mm/min, and the length of the monofilament is 600 mm; the knot strength retention rate is measured after each group of nylon fishing net wires which are correspondingly treated are exposed for 12 months under natural conditions of the temperature of 35 ℃ and the relative humidity of 85 percent so as to reflect the corrosion-resistant and anti-aging characteristics of the nylon fishing net wires. The specific experimental comparative data are shown in the following table 1:
TABLE 1 mechanical Properties of fishing net thread prepared by the methods of the examples
Breaking strength cN/dtex | Retention ratio of knot strength/%) | |
Example 2 | 19.6 | 93.5 |
Example 4 | 13.5 | 78.3 |
Example 5 | 15.8 | 86.1 |
Example 6 | 19.8 | 94.3 |
Example 7 | 6.9 | 45.6 |
Example 8 | 20.3 | 94.0 |
As can be seen from the above table 1, the application provides a processing method of the fishing net thread preventing the adhesion and deposition of the aquatic plants, the finally prepared fishing net thread has high breaking strength and knot strength retention rate and excellent mechanical properties, the quality of the fishing net thread is improved to a great extent, and the fishing net thread has great market popularization and application values.
(2) Observing the deposition condition of the aquatic plants:
weaving the fishing net wires correspondingly prepared by the group methods into a net according to the same mode, uniformly putting the fishing net correspondingly woven by the group methods into water with vigorous growth of aquatic plants, and checking the adhesion and deposition conditions of the aquatic plants on the surfaces of the groups of fishing nets after one year.
The specific experimental comparative data are shown in the following table 2:
TABLE 2 anti-deposition and adhesion condition of aquatic plants of fishing net braided by fishing net thread prepared by the method of each embodiment
Deposition of aquatic plants | |
Example 2 | Surface deposition of non-aquatic plant |
Example 4 | The surface aquatic plant attachment deposition area reaches 35 percent |
Example 5 | The surface aquatic plant attachment deposition area reaches 10 percent |
Example 6 | The surface aquatic plant attachment deposition area reaches 60 percent |
Example 7 | The surface aquatic plant attachment deposition area reaches 70 percent |
Example 8 | The surface aquatic plant attachment achievement area reaches 90 percent |
It can be seen from table 2 above that, the application provides a processing method of preventing aquatic plant from adhering to deposit fishing net line, has effectually prevented that the fishing net in the use, and aquatic plant's adhering to deposit has effectually improved the quality of fishing net, has prolonged the life of fishing net line, and especially the addition of function filler can also effectually prevent aquatic plant's adhering to deposit when the increase in strength.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention, and the present invention is not limited to the illustrated embodiments, and all the modifications and equivalents of the embodiments may be made without departing from the spirit of the present invention.
Claims (6)
1. A processing method of a fishing net line preventing adhesion and deposition of aquatic plants is characterized by comprising the following steps:
(1) and (3) cryogenic crushing treatment:
weighing 30-40 parts of biomass carbon, 15-25 parts of shellac and 6-10 parts of nano silicon dioxide in corresponding parts by weight, putting the materials into a deep cooling type pulverizer together for pulverizing treatment, and obtaining mixed powder A for later use after the pulverizing treatment is finished;
(2) microwave treatment:
placing the mixed powder A obtained in the step (1) in a microwave environment for microwave treatment, and taking out the mixed powder A for later use;
(3) cryogenic treatment:
placing the mixture A obtained in the step (2) in liquid nitrogen;
(4) bead grinding treatment:
taking the mixture A treated by the liquid nitrogen in the step (3) out of the liquid nitrogen, grinding the mixture A in a bead mill immediately, and sieving the mixture A to obtain mixed powder B for later use;
(5) coating treatment:
suspending the plant growth antibiotics in the air by using a fluidized bed, then adding the mixed powder B obtained in the step (4) to a fluidized bed in a spraying mode, wrapping the antibiotics in a suspension rolling state, and then drying in cold air to obtain the functional filler for later use;
(6) melt spinning:
weighing 70-80 parts of polyethylene, 30-40 parts of the functional filler obtained in the step (5), 6-8 parts of sodium lactate and 75-85 parts of deionized water according to corresponding parts by weight, putting the materials into a spinning tank together for melting, spinning after all the materials are melted, and then obtaining blended yarns for later use after solidification forming, water washing, stretching and drying;
(7) twisting:
and (4) twisting the blended yarns obtained in the step (6) into yarns.
2. The method for processing the fishing net thread preventing the adhesion and deposition of the aquatic plants according to claim 1, wherein the temperature inside the pulverizer is controlled to be-20 to-10 ℃ during the pulverizing treatment in the step (1).
3. The method for processing the fishing net thread preventing the adhesion and deposition of the aquatic plants according to claim 1, wherein the microwave treatment in the step (2) is performed by controlling the power of the microwave to be 600-700W and the time of the microwave treatment to be 4-6 min.
4. The processing method of the aquatic plant adhesion and deposition preventing fishing net thread according to claim 1, wherein the rotation speed of the bead mill in the step (4) is 1000-2000 rpm.
5. The processing method of the aquatic plant adhesion and deposition preventing fishing net line according to claim 1, wherein the sieving in the step (4) is 80-120 mesh sieve.
6. The processing method of the aquatic plant adhesion and deposition preventing fishing net line according to claim 1, wherein the weight ratio of the plant growth antibiotic to the mixed powder in the step (5) is 1: 20-28.
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