CN113652279A - Preparation method and use method of high-lubrication long-service-life cutting fluid - Google Patents

Preparation method and use method of high-lubrication long-service-life cutting fluid Download PDF

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Publication number
CN113652279A
CN113652279A CN202110908646.XA CN202110908646A CN113652279A CN 113652279 A CN113652279 A CN 113652279A CN 202110908646 A CN202110908646 A CN 202110908646A CN 113652279 A CN113652279 A CN 113652279A
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parts
cutting fluid
service life
lubrication
long service
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陈真
汪小龙
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Amer Technology Co Ltd
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Amer Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
    • C10M2203/1065Naphthenic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/221Six-membered rings containing nitrogen and carbon only
    • C10M2215/222Triazines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02Unspecified siloxanes; Silicones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64Environmental friendly compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/72Extended drain
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a high-lubrication long-life cutting fluid which is prepared from the following raw materials in percentage by weight: 20-50 parts of naphthenic base oil, 5-10 parts of rapeseed oil acid, 5-20 parts of trimethylolpropane oleate, 5-10 parts of surface active fatty alcohol EO-PO copolymer, 5-10 parts of triethanolamine, 5-10 parts of antirust sebacic acid, 1-3 parts of bactericide MBM, 1-3 parts of three-dimensional siloxane defoamer and the balance of water.

Description

Preparation method and use method of high-lubrication long-service-life cutting fluid
Technical Field
The invention relates to the technical field of cutting fluid, in particular to a preparation method and a use method of cutting fluid with high lubrication and long service life.
Background
The cutting fluid (coolant) is an industrial liquid used for cooling and lubricating cutters and workpieces in the metal cutting and grinding process, is formed by scientifically compounding and matching various super-strong functional additives, and has the characteristics of good cooling performance, lubricating performance, antirust performance, oil removal and cleaning functions, anticorrosion function and easiness in dilution. The defects that the traditional soap-based emulsion is easy to smell in summer, difficult to dilute in winter and poor in antirust effect are overcome, the lathe paint is not affected, and the soap-based emulsion is suitable for cutting and grinding ferrous metal and belongs to the most advanced grinding product at present.
The traditional cutting fluid has the problems of insufficient lubricity and short service life; these two problems, which will subsequently lead to insufficient tool life during machining, increase the tool cost; the finish degree of the processed workpiece is not enough, the repair cost of workers at the back is increased, the yield of products is reduced, and the like. The cutting fluid has short service life, the frequency of replacing the cutting fluid is increased, the fluid replacement time of workers is increased, the machine must be stopped when the fluid is replaced, the operation rate of the machine is reduced, and the productivity is reduced. The cutting fluid is frequently replaced, and a large amount of waste liquid cannot be treated, so that the environmental protection pressure is increased, and the treatment cost is further increased.
Disclosure of Invention
Aiming at the defects of insufficient lubricity, short service life and the like of the traditional cutting fluid, the invention provides a preparation method of the cutting fluid with high lubricity and long service life and a using method thereof, aiming at solving the technical problems, the invention provides the following technical scheme:
a high-lubrication long-life cutting fluid is composed of the following raw materials in percentage by weight:
20-50 parts of naphthenic base oil, 5-10 parts of rapeseed oil acid, 5-20 parts of trimethylolpropane oleate, 5-10 parts of surface active fatty alcohol EO-PO copolymer, 5-10 parts of triethanolamine, 5-10 parts of antirust sebacic acid, 1-3 parts of bactericide MBM, 1-3 parts of three-dimensional siloxane defoamer and the balance of water.
As a preferred technical scheme, the invention consists of the following raw materials in percentage by weight:
44 parts of naphthenic base oil, 6 parts of rapeseed oleic acid, 15 parts of trimethylolpropane oleate, 6 parts of surface active fatty alcohol EO-PO copolymer, 9 parts of triethanolamine, 6 parts of antirust sebacic acid, 3 parts of bactericide MBM, 1 part of three-dimensional siloxane defoamer and 10 parts of water.
As a preferred technical scheme of the invention, the water is deionized water.
The invention also provides a preparation method of the cutting fluid with high lubrication and long service life, which comprises the following steps:
(1) heating water to 50-60 ℃, and adding naphthenic base oil, rapeseed oleic acid, trimethylolpropane oleate, surface active fatty alcohol EO-PO copolymer, triethanolamine and antirust agent sebacic acid while stirring;
(2) adding an MBM bactericide and a three-dimensional siloxane defoaming agent into the mixed liquid prepared in the step (1), and stirring;
(3) and (3) cooling the liquid prepared in the step (2) to room temperature to obtain the cutting fluid with high lubrication and long service life.
The invention also provides a using method of the cutting fluid with high lubrication and long service life,
the material is section aluminum and die-casting aluminum, and the use concentration of the high-lubrication long-life cutting fluid is as follows: 8-10%;
the material is carbon steel and alloy steel, and the use concentration of the high-lubrication long-life cutting fluid is as follows: 8-15%;
the material is stainless steel and titanium alloy, and the use concentration of the cutting fluid with high lubrication and long service life is as follows: 15-30%.
The invention has the beneficial effects that:
(1) the cutting fluid with high lubrication and long service life can delay the service life of the cutter, and improve the smoothness of the surface of the workpiece and the production yield;
(2) the cutting fluid with high lubrication and long service life can greatly delay the replacement period of the cutting fluid, save labor cost, improve production efficiency and reduce waste liquid treatment cost;
the cutting fluid with long service life has the characteristics of good cooling, cleaning, rust prevention and the like, and has the characteristics of no toxicity, no odor, no corrosion to human bodies, no corrosion to equipment, no pollution to environment and the like.
Detailed Description
While the preferred embodiments of the present invention will be described below, it should be understood that the preferred embodiments described herein are merely illustrative and explanatory of the invention and are not restrictive thereof.
Example 1
The invention relates to a high-lubrication long-life cutting fluid which is prepared from the following raw materials in percentage by weight:
44 parts of naphthenic base oil, 6 parts of rapeseed oleic acid, 15 parts of trimethylolpropane oleate, 6 parts of surface active fatty alcohol EO-PO copolymer, 9 parts of triethanolamine, 6 parts of antirust sebacic acid, 3 parts of bactericide MBM, 1 part of three-dimensional siloxane defoamer and 10 parts of water.
A preparation method of a cutting fluid with high lubrication and long service life comprises the following steps:
(1) heating water to 50-60 ℃, and adding naphthenic base oil, rapeseed oleic acid, trimethylolpropane oleate, surface active fatty alcohol EO-PO copolymer, triethanolamine and antirust agent sebacic acid while stirring;
(2) adding an MBM bactericide and a three-dimensional siloxane defoaming agent into the mixed liquid prepared in the step (1), and stirring;
(3) and (3) cooling the liquid prepared in the step (2) to room temperature to obtain the cutting fluid with high lubrication and long service life.
Example 2
The invention relates to a high-lubrication long-life cutting fluid which is prepared from the following raw materials in percentage by weight:
40 parts of naphthenic base oil, 7 parts of rapeseed oleic acid, 20 parts of trimethylolpropane oleate, 6 parts of surface active fatty alcohol EO-PO copolymer, 8 parts of triethanolamine, 5 parts of antirust sebacic acid, 3 parts of bactericide MBM, 1 part of three-dimensional siloxane defoamer and 10 parts of water.
The preparation method is the same as that of example 1.
Example 3
The invention relates to a high-lubrication long-life cutting fluid which is prepared from the following raw materials in percentage by weight:
38 parts of naphthenic base oil, 8 parts of rapeseed oleic acid, 18 parts of trimethylolpropane oleate, 7 parts of surface active fatty alcohol EO-PO copolymer, 8 parts of triethanolamine, 7 parts of antirust sebacic acid, 2 parts of bactericide MBM, 2 parts of three-dimensional siloxane defoamer and 10 parts of water.
The preparation method is the same as that of example 1.
The long-life magnesium alloy cutting fluid 10% aqueous solution prepared in the examples 1-4 is tested according to tapping torque, and the data is as follows:
Figure RE-GDA0003297869680000041
the cutting fluid with high lubrication and long service life prepared by the method not only improves the service life of the cutter and the smoothness of the product, but also greatly prolongs the service life of the cutting fluid.
Although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that changes may be made in the embodiments and/or equivalents thereof without departing from the spirit and scope of the invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (5)

1. The cutting fluid with high lubrication and long service life is characterized by comprising the following raw materials in percentage by weight:
20-50 parts of naphthenic base oil, 5-10 parts of rapeseed oil acid, 5-20 parts of trimethylolpropane oleate, 5-10 parts of surface active fatty alcohol EO-PO copolymer, 5-10 parts of triethanolamine, 5-10 parts of antirust sebacic acid, 1-3 parts of bactericide MBM, 1-3 parts of three-dimensional siloxane defoamer and the balance of water.
2. The cutting fluid with high lubrication and long service life as claimed in claim 1, is characterized by comprising the following raw materials in percentage by weight:
44 parts of naphthenic base oil, 6 parts of rapeseed oleic acid, 15 parts of trimethylolpropane oleate, 6 parts of surface active fatty alcohol EO-PO copolymer, 9 parts of triethanolamine, 6 parts of antirust sebacic acid, 3 parts of bactericide MBM, 1 part of three-dimensional siloxane defoamer and 10 parts of water.
3. The cutting fluid with high lubrication and long service life as claimed in claim 1, wherein the water is deionized water.
4. The method for preparing the cutting fluid with high lubrication and long service life as claimed in claim 1, characterized by comprising the following steps:
(1) heating water to 50-60 ℃, and adding naphthenic base oil, rapeseed oleic acid, trimethylolpropane oleate, surface active fatty alcohol EO-PO copolymer, triethanolamine and antirust agent sebacic acid while stirring;
(2) adding an MBM bactericide and a three-dimensional siloxane defoaming agent into the mixed liquid prepared in the step (1), and stirring;
(3) and (3) cooling the liquid prepared in the step (2) to room temperature to obtain the cutting fluid with high lubrication and long service life.
5. The use method of a cutting fluid with high lubrication and long service life as claimed in claim 1,
the material is section aluminum and die-casting aluminum, and the use concentration of the high-lubrication long-life cutting fluid is as follows: 8-10%;
the material is carbon steel and alloy steel, and the use concentration of the high-lubrication long-life cutting fluid is as follows: 8-15%;
the material is stainless steel and titanium alloy, and the use concentration of the cutting fluid with high lubrication and long service life is as follows: 15-30%.
CN202110908646.XA 2021-08-09 2021-08-09 Preparation method and use method of high-lubrication long-service-life cutting fluid Pending CN113652279A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876435A (en) * 2012-09-27 2013-01-16 上海应用技术学院 Semisynthetic metal cutting fluid with trimethylolpropane oleate serving as base oil and preparation method of semisynthetic metal cutting fluid
CN104293466A (en) * 2014-09-25 2015-01-21 巢湖广丰金属制品有限公司 Micro-emulsion metal cutting liquid with stable property
CN108611170A (en) * 2018-05-07 2018-10-02 苏州捷德瑞精密机械有限公司 A kind of novel metal machining liquid and preparation method thereof
CN111961522A (en) * 2020-08-13 2020-11-20 华阳-恩赛有限公司 Universal micro-emulsion cutting fluid for aluminum material processing, and preparation method and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876435A (en) * 2012-09-27 2013-01-16 上海应用技术学院 Semisynthetic metal cutting fluid with trimethylolpropane oleate serving as base oil and preparation method of semisynthetic metal cutting fluid
CN104293466A (en) * 2014-09-25 2015-01-21 巢湖广丰金属制品有限公司 Micro-emulsion metal cutting liquid with stable property
CN108611170A (en) * 2018-05-07 2018-10-02 苏州捷德瑞精密机械有限公司 A kind of novel metal machining liquid and preparation method thereof
CN111961522A (en) * 2020-08-13 2020-11-20 华阳-恩赛有限公司 Universal micro-emulsion cutting fluid for aluminum material processing, and preparation method and application thereof

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Application publication date: 20211116