CN113604166B - Preparation method and application of self-adhesive waterproof soft porcelain - Google Patents

Preparation method and application of self-adhesive waterproof soft porcelain Download PDF

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CN113604166B
CN113604166B CN202111011092.XA CN202111011092A CN113604166B CN 113604166 B CN113604166 B CN 113604166B CN 202111011092 A CN202111011092 A CN 202111011092A CN 113604166 B CN113604166 B CN 113604166B
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self
soft porcelain
adhesive
stirring
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CN113604166A (en
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李生贵
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
    • C09J125/02—Homopolymers or copolymers of hydrocarbons
    • C09J125/04—Homopolymers or copolymers of styrene
    • C09J125/08—Copolymers of styrene
    • C09J125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21—Paper; Textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/186—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials one of the layers is on one surface of the fibrous web and the other layer is on the other surface of the fibrous web
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/346—Applications of adhesives in processes or use of adhesives in the form of films or foils for building applications e.g. wrap foil
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/26—Presence of textile or fabric
    • C09J2400/263—Presence of textile or fabric in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2425/00—Presence of styrenic polymer
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/08—Bituminous material, e.g. asphalt, tar, bitumen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/02—Dispersion
    • D06N2205/023—Emulsion, aqueous dispersion, latex
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/24—Coagulated materials
    • D06N2205/243—Coagulated materials by heating, steam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/142—Hydrophobic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/06—Building materials
    • D06N2211/063—Wall coverings
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00—Adapting or protecting infrastructure or their operation
    • Y02A30/24—Structural elements or technologies for improving thermal insulation
    • Y02A30/244—Structural elements or technologies for improving thermal insulation using natural or recycled building materials, e.g. straw, wool, clay or used tires

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Architecture (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a preparation method and application of self-adhesive waterproof soft porcelain. The preparation method of the self-adhesive waterproof soft porcelain comprises the following steps: s1, self-adhesive waterproof soft porcelain production process: a. materials: preparing self-adhesive binder, reflective heat-insulating elastic real stone paint, isolating film and tyre base cloth; b. the raw material composition of the material includes the following group. The preparation method and the application of the self-adhesive waterproof soft porcelain provided by the invention can be used for precoating the self-adhesive binder on the soft porcelain binding surface, so that the construction convenience and the stability of construction quality are greatly improved, the construction can be completed without any other auxiliary materials during the construction, meanwhile, the self-adhesive waterproof soft porcelain has excellent waterproof performance and frost resistance, can replace waterproof materials to a certain extent, is not easy to freeze and fall off under extremely cold conditions, and has the advantage of excellent reflection heat insulation performance.

Description

Preparation method and application of self-adhesive waterproof soft porcelain
Technical Field
The invention belongs to the technical field of self-adhesive waterproof soft porcelain, and particularly relates to a preparation method and application of self-adhesive waterproof soft porcelain.
Background
Porcelain, not true porcelain, nor ceramic tile, is a novel building decoration material. According to the explanation of soft porcelain construction decoration engineering technical regulations formulated by Guangdong province: the flexible building decoration surface material is formed by using modified soil (MCM) as a main raw material and adopting a special temperature control modeling system for molding, baking and irradiation crosslinking, and is manufactured by the following steps of: the elastic emulsion is mixed with various sand to prepare elastic stone paint after adding proper amount of paint auxiliary agent, and then the elastic stone paint is prepared into sheet-shaped flexible ceramic tile building material by using a coating tool and a die, and the sheet-shaped flexible ceramic tile building material is applied to building veneers of inner and outer walls. The main application mode is to use cement binder to paste soft porcelain on wall surface for decoration.
However, in the prior art, the main technical characteristics of the existing soft porcelain are as follows: is prepared from inorganic sand and powder and high-molecular organic matter. The main performance characteristics are light weight and flexibility. The cement-based adhesive material is used for adhering the soft porcelain to the wall surface to achieve the decorative effect during construction, but meanwhile, the main raw material of the traditional soft porcelain is an inorganic porous material, the waterproof performance is poor, the cement-based adhesive material is needed to be adhered to the wall surface during the soft porcelain adhering, the adhesive material used for the soft porcelain is generally prepared on the construction site, the influence is great, the overall construction quality is unstable, and the soft porcelain is resistant to low temperature difference after construction and extremely easy to freeze and fall off.
Therefore, it is necessary to provide a new preparation method and application of the self-adhesive waterproof soft porcelain to solve the technical problems.
Disclosure of Invention
The invention solves the technical problem of providing a preparation method and application of self-adhesive waterproof soft porcelain with convenient construction, high stability and waterproof, anti-freezing and reflective heat insulation properties.
In order to solve the technical problems, the preparation method and application of the self-adhesive waterproof soft porcelain provided by the invention comprise the following steps:
s1, self-adhesive waterproof soft porcelain production process:
a. materials:
preparing self-adhesive binder, reflective heat-insulating elastic real stone paint, isolating film and tyre base cloth;
b. the raw material composition of the material comprises the following components:
(1) The self-adhesive binder comprises the following raw materials: 5-30 parts of water, 5-25 parts of emulsified asphalt, 0.1-1 part of thickener, 0.1-2 parts of first coating auxiliary agent, 0.1-2 parts of second coating auxiliary agent, 0.1-2 parts of third coating auxiliary agent, 20-50 parts of acrylic emulsion and 10-30 parts of polymer emulsion;
(2) The reflective heat-insulating elastic real stone paint comprises the following raw materials: 0-10 parts of water, 0.5-2 parts of thickener, 0.1-2 parts of first coating auxiliary agent, 0.1-2 parts of second coating auxiliary agent, 0.1-2 parts of third coating auxiliary agent, 10-35 parts of acrylic emulsion, 40-75 parts of natural color sand, 0-15 parts of heavy calcium carbonate and 0-15 parts of reflective heat insulation titanium dioxide.
As a further scheme of the invention, the thickener is hydroxyethyl cellulose, the first coating auxiliary agent is a defoaming agent, the second coating auxiliary agent is a film forming auxiliary agent, the third coating auxiliary agent is ethylene glycol, and the polymer emulsion is styrene-butadiene latex.
As a further scheme of the invention, the chemical structure and the components of the defoamer are mineral oil, organic silicon and polyether.
As a further aspect of the invention, the film forming aid composition is alcohol ester dodecanol and propylene glycol butyl ether.
As a further scheme of the invention, the components of the acrylic emulsion are pure acrylic emulsion, silicone acrylic emulsion, styrene acrylic emulsion and vinyl acetate acrylic emulsion, and the heavy calcium carbonate and the reflective heat insulation titanium pigment are not 0.
As a further aspect of the present invention, the forming step of the self-adhesive binder includes:
(1) Adding 20 parts of water and 0.5 part of hydroxyethyl cellulose into a stirring tank, stirring at 500-1000rpm for 5-10min;
(2) 15 parts of emulsified asphalt, 1.5 parts of organic silicon defoamer, 1.5 parts of alcohol ester, 1 part of glycol, 40 parts of styrene-acrylic emulsion and 20 parts of styrene-butadiene latex are sequentially added in the stirring process, and stirring is carried out while adding;
(3) All the raw materials are added and stirred for 20min, so as to prepare the self-adhesive binder.
As a further scheme of the invention, the forming step of the reflective heat-insulating elastic real stone paint comprises the following steps:
(1) Adding 5 parts of water and 1 part of hydroxyethyl cellulose into a stirring tank, and stirring at 500-1000rpm for 5-10min;
(2) Sequentially adding 1 part of organosilicon defoamer, 1.5 parts of alcohol ester, 1.5 parts of glycol and 30 parts of styrene-acrylic emulsion in the stirring process, and stirring while adding;
(3) Stirring at 500-1000rpm for 10-20min, and sequentially adding 60 parts of natural color sand, 10 parts of heavy calcium carbonate and 10 parts of reflective heat insulation titanium dioxide;
(4) All the raw materials are added and stirred for 10-20min after the rotating speed is 800-1000rpm, so that the reflective heat-insulating elastic stone-like paint is prepared.
As a further aspect of the present invention, S2: and (3) forming:
(1) Uniformly coating the prepared self-adhesive binder on one surface of the base fabric, and drying;
(2) Spreading the isolating film on the surface of the dried self-adhesive binder;
(3) And uniformly spraying the prepared reflective heat-insulating elastic stone-like paint on the other surface of the base cloth, and drying to prepare the self-adhesive waterproof soft porcelain.
The self-adhesive waterproof soft porcelain prepared by the method is used as indoor and outdoor decorations of industrial and civil buildings and indoor decorations of toilets and kitchens.
The self-adhesive reflective heat-insulating waterproof soft porcelain prepared by the method has the following performance tests:
impermeability to water: 0.3MPa,30min impermeable;
reflective insulation properties: hemispherical reflectivity (white and light) of 0.89, solar reflectance (white and light) of 0.86, near infrared reflectance (white and light) of 0.85.
Compared with the related art, the preparation method and application of the self-adhesive waterproof soft porcelain provided by the invention have the following beneficial effects:
1. the self-adhesive bonding material can be precoated on the soft porcelain bonding surface, so that the construction convenience and the stability of construction quality are greatly improved, the construction can be completed without any other auxiliary material during the construction, meanwhile, the self-adhesive bonding material also has excellent waterproof performance and frost resistance, can replace waterproof materials to a certain extent, is not easy to freeze and fall off under extremely cold conditions, and has excellent reflective heat insulation performance.
Detailed Description
The preparation method and application of the self-adhesive waterproof soft porcelain comprise the following steps:
s1, self-adhesive waterproof soft porcelain production process:
a. materials:
preparing self-adhesive binder, reflective heat-insulating elastic real stone paint, isolating film and tyre base cloth;
b. the raw material composition of the material comprises the following components:
(1) The self-adhesive binder comprises the following raw materials: 5-30 parts of water, 5-25 parts of emulsified asphalt, 0.1-1 part of thickener, 0.1-2 parts of first coating auxiliary agent, 0.1-2 parts of second coating auxiliary agent, 0.1-2 parts of third coating auxiliary agent, 20-50 parts of acrylic emulsion and 10-30 parts of polymer emulsion;
(2) The reflective heat-insulating elastic real stone paint comprises the following raw materials: 0-10 parts of water, 0.5-2 parts of thickener, 0.1-2 parts of first coating auxiliary agent, 0.1-2 parts of second coating auxiliary agent, 0.1-2 parts of third coating auxiliary agent, 10-35 parts of acrylic emulsion, 40-75 parts of natural color sand, 0-15 parts of heavy calcium carbonate and 0-15 parts of reflective heat insulation titanium dioxide.
The thickener is hydroxyethyl cellulose, the first coating auxiliary agent is a defoaming agent, the second coating auxiliary agent is a film-forming auxiliary agent, the third coating auxiliary agent is ethylene glycol, and the polymer emulsion is styrene-butadiene latex.
The chemical structure and the components of the defoamer are mineral oil, organic silicon and polyether.
The film forming auxiliary agent comprises alcohol ester twelve and propylene glycol butyl ether.
The components of the acrylic emulsion are pure acrylic emulsion, silicone acrylic emulsion, styrene acrylic emulsion and vinyl acetate acrylic emulsion, and the heavy calcium carbonate and the reflective heat insulation titanium pigment are not 0.
The forming step of the self-adhesive binder comprises the following steps:
(1) Adding 20 parts of water and 0.5 part of hydroxyethyl cellulose into a stirring tank, stirring at 500-1000rpm for 5-10min;
(2) 15 parts of emulsified asphalt, 1.5 parts of organic silicon defoamer, 1.5 parts of alcohol ester, 1 part of glycol, 40 parts of styrene-acrylic emulsion and 20 parts of styrene-butadiene latex are sequentially added in the stirring process, and stirring is carried out while adding;
(3) All the raw materials are added and stirred for 20min, so as to prepare the self-adhesive binder.
The forming step of the reflective heat-insulating elastic real stone paint comprises the following steps:
(1) Adding 5 parts of water and 1 part of hydroxyethyl cellulose into a stirring tank, and stirring at 500-1000rpm for 5-10min;
(2) Sequentially adding 1 part of organosilicon defoamer, 1.5 parts of alcohol ester, 1.5 parts of glycol and 30 parts of styrene-acrylic emulsion in the stirring process, and stirring while adding;
(3) Stirring at 500-1000rpm for 10-20min, and sequentially adding 60 parts of natural color sand, 10 parts of heavy calcium carbonate and 10 parts of reflective heat insulation titanium dioxide;
(4) All the raw materials are added and stirred for 10-20min after the rotating speed is 800-1000rpm, so that the reflective heat-insulating elastic stone-like paint is prepared.
Further comprising S2: and (3) forming:
(1) Uniformly coating the prepared self-adhesive binder on one surface of the base fabric, and drying;
(2) Spreading the isolating film on the surface of the dried self-adhesive binder;
(3) And uniformly spraying the prepared reflective heat-insulating elastic stone-like paint on the other surface of the base cloth, and drying to prepare the self-adhesive waterproof soft porcelain.
The self-adhesive waterproof soft porcelain prepared by the method is used as indoor and outdoor decorations of industrial and civil buildings and indoor decorations of toilets and kitchens.
The self-adhesive reflective heat-insulating waterproof soft porcelain prepared by the method has the following performance tests:
impermeability to water: 0.3MPa,30min impermeable;
reflective insulation properties: hemispherical reflectivity (white and light) of 0.89, solar reflectance (white and light) of 0.86, near infrared reflectance (white and light) of 0.85.
Example 1:
the preparation method of the self-adhesive waterproof soft porcelain comprises the following steps:
(1) Adding 20 parts of water and 0.5 part of hydroxyethyl cellulose into a stirring cylinder, stirring at 500-1000rpm for 5-10min, sequentially adding 15 parts of emulsified asphalt, 1.5 parts of organosilicon defoamer, 1.5 parts of alcohol ester twelve, 1 part of glycol, 40 parts of styrene-acrylic emulsion and 20 parts of styrene-butadiene latex in the stirring process, stirring while adding all the raw materials, and stirring for 20min again after adding all the raw materials, thereby preparing the self-adhesive binder;
(2) Adding 5 parts of water and 1 part of hydroxyethyl cellulose into a stirring cylinder, stirring at 500-1000rpm for 5-10min, sequentially adding 1 part of an organosilicon defoamer, 1.5 parts of alcohol ester, 1.5 parts of ethylene glycol and 30 parts of styrene-acrylic emulsion in the stirring process, stirring while adding, stirring at 500-1000rpm for 10-20min, sequentially adding 60 parts of natural color sand, 10 parts of heavy calcium carbonate and 10 parts of reflective heat insulation titanium dioxide, adding all raw materials, and stirring for 10-20min at 800-1000rpm, thereby preparing the reflective heat insulation elastic real stone paint;
(3) Uniformly coating the prepared self-adhesive binder on one surface of the base fabric, and drying;
(4) Spreading the isolating film on the surface of the dried self-adhesive binder;
(5) And uniformly spraying the prepared reflective heat-insulating elastic stone-like paint on the other surface of the base cloth, and drying to prepare the self-adhesive waterproof soft porcelain.
(6) The self-adhesive waterproof soft porcelain obtained by the method is used as indoor and outdoor decorations of industrial and civil buildings, and as indoor decorations of toilets and kitchens.
The self-adhesive waterproof soft porcelain prepared by the method is used as indoor and outdoor decorations of industrial and civil buildings and indoor decorations of toilets and kitchens.
The self-adhesive reflective heat-insulating waterproof soft porcelain prepared by the method has the following performance tests:
impermeability to water: 0.3MPa,30min impermeable;
reflective insulation properties: hemispherical reflectivity (white and light) of 0.89, solar reflectance (white and light) of 0.86, near infrared reflectance (white and light) of 0.85.
Example 2:
the preparation method of the self-adhesive waterproof soft porcelain comprises the following steps:
(1) Adding 30 parts of water and 1 part of hydroxyethyl cellulose into a stirring cylinder, stirring at 500-1000rpm for 5-10min, sequentially adding 25 parts of emulsified asphalt, 2 parts of an organosilicon defoamer, twelve 2 parts of alcohol ester, 2 parts of ethylene glycol, 50 parts of styrene-acrylic emulsion and 30 parts of styrene-butadiene latex in the stirring process, stirring while adding all the raw materials, and stirring for 30min again to prepare the self-adhesive binder;
(2) Adding 10 parts of water and 2 parts of hydroxyethyl cellulose into a stirring cylinder, stirring at 550-1000rpm for 7-12min, sequentially adding 1.5 parts of an organosilicon defoamer, twelve 2 parts of alcohol ester, 2 parts of ethylene glycol and 35 parts of styrene-acrylic emulsion in the stirring process, stirring while adding, stirring at 550-1000rpm for 12-22min, sequentially adding 75 parts of natural color sand, 15 parts of heavy calcium carbonate and 15 parts of reflective heat insulation titanium dioxide, adding all raw materials, and stirring for 12-22min at 850-1000rpm, thereby preparing reflective heat insulation elastic real stone paint;
(3) Uniformly coating the prepared self-adhesive binder on one surface of the base fabric, and drying;
(4) Spreading the isolating film on the surface of the dried self-adhesive binder;
(5) Uniformly spraying the prepared reflective heat-insulating elastic stone-like paint on the other surface of the base cloth, and drying to prepare the self-adhesive waterproof soft porcelain;
(6) The self-adhesive waterproof soft porcelain obtained by the method is used as indoor and outdoor decorations of industrial and civil buildings, and as indoor decorations of toilets and kitchens.
The self-adhesive waterproof soft porcelain prepared by the method is used as indoor and outdoor decorations of industrial and civil buildings and indoor decorations of toilets and kitchens.
The self-adhesive reflective heat-insulating waterproof soft porcelain prepared by the method has the following performance tests:
impermeability to water: 0.3MPa,30min impermeable;
reflective insulation properties: hemispherical reflectivity (white and light) of 0.89, solar reflectance (white and light) of 0.86, near infrared reflectance (white and light) of 0.85.
Example 3:
the preparation method of the self-adhesive waterproof soft porcelain comprises the following steps:
(1) Adding 15 parts of water and 0.3 part of hydroxyethyl cellulose into a stirring cylinder, stirring at the stirring speed of 450-1000rpm for 4-8min, sequentially adding 10 parts of emulsified asphalt, 1 part of organosilicon defoamer, twelve 1 parts of alcohol ester, 0.6 part of ethylene glycol, 30 parts of styrene-acrylic emulsion and 10 parts of styrene-butadiene latex in the stirring process, stirring while adding all the raw materials, and stirring for 15min again to prepare the self-adhesive binder;
(2) Adding 3 parts of water and 0.5 part of hydroxyethyl cellulose into a stirring cylinder, stirring at the stirring speed of 450-1000rpm for 4-8min, sequentially adding 0.5 part of organic silicon defoamer, twelve 1 parts of alcohol ester, 1 part of ethylene glycol and 25 parts of styrene-acrylic emulsion in the stirring process, stirring while adding, stirring at the stirring speed of 450-1000rpm for 8-18min, sequentially adding 50 parts of natural color sand, 7 parts of heavy calcium carbonate and 7 parts of reflective heat insulation titanium dioxide, adding all raw materials, and stirring for 8-18min at the rotating speed of 750-1000rpm, thereby preparing the reflective heat insulation elastic real stone paint;
(3) Uniformly coating the prepared self-adhesive binder on one surface of the base fabric, and drying;
(4) Spreading the isolating film on the surface of the dried self-adhesive binder;
(5) Uniformly spraying the prepared reflective heat-insulating elastic stone-like paint on the other surface of the base cloth, and drying to prepare the self-adhesive waterproof soft porcelain;
(6) The self-adhesive waterproof soft porcelain obtained by the method is used as indoor and outdoor decorations of industrial and civil buildings, and as indoor decorations of toilets and kitchens.
The self-adhesive waterproof soft porcelain prepared by the method is used as indoor and outdoor decorations of industrial and civil buildings and indoor decorations of toilets and kitchens.
The self-adhesive reflective heat-insulating waterproof soft porcelain prepared by the method has the following performance tests:
impermeability to water: 0.3MPa,30min impermeable;
reflective insulation properties: hemispherical reflectivity (white and light) of 0.89, solar reflectance (white and light) of 0.86, near infrared reflectance (white and light) of 0.85.

Claims (5)

1. The preparation method of the self-adhesive waterproof soft porcelain is characterized by comprising the following steps of:
s1, self-adhesive waterproof soft porcelain production process:
a. materials:
preparing self-adhesive binder, reflective heat-insulating elastic real stone paint, isolating film and tyre base cloth;
b. the raw material composition of the material comprises the following components:
(1) The self-adhesive binder comprises the following raw materials: 5-30 parts of water, 5-25 parts of emulsified asphalt, 0.1-1 part of thickener, 0.1-2 parts of first coating auxiliary agent, 0.1-2 parts of second coating auxiliary agent, 0.1-2 parts of third coating auxiliary agent, 20-50 parts of acrylic emulsion and 10-30 parts of polymer emulsion;
(2) The reflective heat-insulating elastic real stone paint comprises the following raw materials: 0-10 parts of water, 0.5-2 parts of thickener, 0.1-2 parts of first coating auxiliary agent, 0.1-2 parts of second coating auxiliary agent, 0.1-2 parts of third coating auxiliary agent, 10-35 parts of acrylic emulsion, 40-75 parts of natural color sand, 0-15 parts of heavy calcium carbonate and 0-15 parts of reflective heat insulation titanium dioxide;
the thickener is hydroxyethyl cellulose, the first coating auxiliary agent is a defoaming agent, the second coating auxiliary agent is a film-forming auxiliary agent, the third coating auxiliary agent is ethylene glycol, and the polymer emulsion is styrene-butadiene latex;
the chemical structure and the components of the defoamer are mineral oil, organic silicon and polyether;
the film forming auxiliary agent comprises alcohol ester twelve and propylene glycol butyl ether;
the components of the acrylic emulsion are pure acrylic emulsion, silicone acrylic emulsion, styrene acrylic emulsion and vinyl acetate acrylic emulsion, and the heavy calcium carbonate and the reflective heat insulation titanium pigment are not 0.
2. The method for preparing the self-adhesive waterproof soft porcelain according to claim 1, wherein the method comprises the following steps: the forming step of the self-adhesive binder comprises the following steps:
(1) Adding 20 parts of water and 0.5 part of hydroxyethyl cellulose into a stirring tank, stirring at 500-1000rpm for 5-10min;
(2) 15 parts of emulsified asphalt, 1.5 parts of organic silicon defoamer, 1.5 parts of alcohol ester, 1 part of glycol, 40 parts of styrene-acrylic emulsion and 20 parts of styrene-butadiene latex are sequentially added in the stirring process, and stirring is carried out while adding;
(3) All the raw materials are added and stirred for 20min, so as to prepare the self-adhesive binder.
3. The method for preparing the self-adhesive waterproof soft porcelain according to claim 2, wherein the method comprises the following steps: the forming step of the reflective heat-insulating elastic real stone paint comprises the following steps:
(1) Adding 5 parts of water and 1 part of hydroxyethyl cellulose into a stirring tank, and stirring at 500-1000rpm for 5-10min;
(2) Sequentially adding 1 part of organosilicon defoamer, 1.5 parts of alcohol ester, 1.5 parts of glycol and 30 parts of styrene-acrylic emulsion in the stirring process, and stirring while adding;
(3) Stirring at 500-1000rpm for 10-20min, and sequentially adding 60 parts of natural color sand, 10 parts of heavy calcium carbonate and 10 parts of reflective heat insulation titanium dioxide;
(4) All the raw materials are added and stirred for 10-20min after the rotating speed is 800-1000rpm, so that the reflective heat-insulating elastic stone-like paint is prepared.
4. The method for preparing the self-adhesive waterproof soft porcelain according to claim 1, wherein the method comprises the following steps:
further comprising S2: and (3) forming:
(1) Uniformly coating the prepared self-adhesive binder on one surface of the base fabric, and drying;
(2) Spreading the isolating film on the surface of the dried self-adhesive binder;
(3) And uniformly spraying the prepared reflective heat-insulating elastic stone-like paint on the other surface of the base cloth, and drying to prepare the self-adhesive waterproof soft porcelain.
5. Use of a self-adhesive waterproof soft porcelain according to claim 1, characterized in that: the self-adhesive waterproof soft porcelain is used as an indoor and outdoor decoration of industrial and civil buildings, and an internal decoration of toilets and kitchens.
CN202111011092.XA 2021-08-31 2021-08-31 Preparation method and application of self-adhesive waterproof soft porcelain Active CN113604166B (en)

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CN104312341B (en) * 2014-09-24 2017-04-26 上海宇培特种建材有限公司 Reflective heat-insulation type really stone paint and preparation method thereof
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