CN113599305A - Walnut oil soap-based silicone oil-free shampoo and preparation method thereof - Google Patents
Walnut oil soap-based silicone oil-free shampoo and preparation method thereof Download PDFInfo
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- CN113599305A CN113599305A CN202110842864.8A CN202110842864A CN113599305A CN 113599305 A CN113599305 A CN 113599305A CN 202110842864 A CN202110842864 A CN 202110842864A CN 113599305 A CN113599305 A CN 113599305A
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- walnut oil
- oil
- weight
- soap
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- 239000008170 walnut oil Substances 0.000 title claims abstract description 86
- 235000019498 Walnut oil Nutrition 0.000 title claims abstract description 85
- 239000000344 soap Substances 0.000 title claims abstract description 48
- 239000002453 shampoo Substances 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 229920001296 polysiloxane Polymers 0.000 title claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 26
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 26
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000008117 stearic acid Substances 0.000 claims abstract description 26
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims abstract description 19
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims abstract description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 17
- 239000003921 oil Substances 0.000 claims abstract description 14
- 235000019198 oils Nutrition 0.000 claims abstract description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 10
- 229920001046 Nanocellulose Polymers 0.000 claims abstract description 9
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims abstract description 8
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 6
- 230000007935 neutral effect Effects 0.000 claims abstract description 6
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 6
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 6
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 6
- 239000011780 sodium chloride Substances 0.000 claims abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 50
- 238000003756 stirring Methods 0.000 claims description 36
- 239000000243 solution Substances 0.000 claims description 34
- 239000003208 petroleum Substances 0.000 claims description 25
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 18
- 239000000194 fatty acid Substances 0.000 claims description 18
- 229930195729 fatty acid Natural products 0.000 claims description 18
- 150000004665 fatty acids Chemical class 0.000 claims description 18
- 238000001816 cooling Methods 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 15
- 239000012295 chemical reaction liquid Substances 0.000 claims description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- 239000004202 carbamide Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 10
- 238000001556 precipitation Methods 0.000 claims description 10
- 238000010992 reflux Methods 0.000 claims description 10
- OVYTZAASVAZITK-UHFFFAOYSA-M sodium;ethanol;hydroxide Chemical compound [OH-].[Na+].CCO OVYTZAASVAZITK-UHFFFAOYSA-M 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000005642 Oleic acid Substances 0.000 claims description 5
- 235000021314 Palmitic acid Nutrition 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims description 5
- 235000020661 alpha-linolenic acid Nutrition 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 239000011363 dried mixture Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 230000007062 hydrolysis Effects 0.000 claims description 5
- 238000006460 hydrolysis reaction Methods 0.000 claims description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 5
- 229960004488 linolenic acid Drugs 0.000 claims description 5
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 5
- 235000021313 oleic acid Nutrition 0.000 claims description 5
- 229960002969 oleic acid Drugs 0.000 claims description 5
- 230000020477 pH reduction Effects 0.000 claims description 5
- 229940098695 palmitic acid Drugs 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 235000021342 arachidonic acid Nutrition 0.000 claims description 4
- 229940114079 arachidonic acid Drugs 0.000 claims description 4
- 230000032050 esterification Effects 0.000 claims description 4
- 238000005886 esterification reaction Methods 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical compound COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 claims description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 235000019794 sodium silicate Nutrition 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 2
- 239000004094 surface-active agent Substances 0.000 abstract description 7
- 238000005187 foaming Methods 0.000 abstract description 3
- 239000008233 hard water Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 13
- 210000004209 hair Anatomy 0.000 description 12
- 239000006260 foam Substances 0.000 description 10
- 229920002678 cellulose Polymers 0.000 description 8
- 239000001913 cellulose Substances 0.000 description 8
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 6
- 230000003301 hydrolyzing effect Effects 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- -1 methyl hydroxypropyl Chemical group 0.000 description 4
- 229920000896 Ethulose Polymers 0.000 description 3
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 3
- 229930003427 Vitamin E Natural products 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 3
- WCYAALZQFZMMOM-UHFFFAOYSA-N methanol;sulfuric acid Chemical compound OC.OS(O)(=O)=O WCYAALZQFZMMOM-UHFFFAOYSA-N 0.000 description 3
- 235000019165 vitamin E Nutrition 0.000 description 3
- 229940046009 vitamin E Drugs 0.000 description 3
- 239000011709 vitamin E Substances 0.000 description 3
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 210000003491 skin Anatomy 0.000 description 2
- 229940057950 sodium laureth sulfate Drugs 0.000 description 2
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 235000016804 zinc Nutrition 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 201000004384 Alopecia Diseases 0.000 description 1
- 238000010953 Ames test Methods 0.000 description 1
- 231100000039 Ames test Toxicity 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 241000758789 Juglans Species 0.000 description 1
- 244000184861 Juglans nigra Species 0.000 description 1
- 235000013740 Juglans nigra Nutrition 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 206010039793 Seborrhoeic dermatitis Diseases 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 235000001465 calcium Nutrition 0.000 description 1
- 229960005069 calcium Drugs 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000000658 coextraction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 210000003780 hair follicle Anatomy 0.000 description 1
- 230000003779 hair growth Effects 0.000 description 1
- 230000003646 hair health Effects 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 208000024963 hair loss Diseases 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 235000001055 magnesium Nutrition 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229940091250 magnesium supplement Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- CCBJILQUNRBMRS-UHFFFAOYSA-N methanol sulfuric acid Chemical compound CO.CO.S(O)(O)(=O)=O CCBJILQUNRBMRS-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000021281 monounsaturated fatty acids Nutrition 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 235000021315 omega 9 monounsaturated fatty acids Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 208000008742 seborrheic dermatitis Diseases 0.000 description 1
- 235000011649 selenium Nutrition 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 229940091258 selenium supplement Drugs 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000010677 tea tree oil Substances 0.000 description 1
- 229940111630 tea tree oil Drugs 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a walnut oil soap-based silicone-oil-free shampoo and a preparation method thereof, wherein the shampoo does not contain polyorganosiloxane, and comprises the following components in parts by weight: 10-20 parts of walnut oil polyhydroxy stearic acid; 5-8 parts of soap base; 1-6 parts of a water softener; 0.06-0.15 parts of essence; 15-20 parts of nano cellulose; 3-8 parts of polyethylene glycol; 5-10 parts of cocamidopropyl betaine; 5-10 parts of sodium dodecyl sulfate; 0.25-0.45 part of sodium benzoate; 1-3 parts of sodium carbonate; 0.1-0.5 part of sodium chloride. The walnut oil polyhydroxy stearic acid adopted by the shampoo prepared by the invention is a novel modified soap base surfactant, walnut oil with various unsaturated fatty acids is adopted, and the walnut oil polyhydroxy stearic acid has the hard water resistance of a modified soap base and has good dissolubility and foaming performance under neutral conditions and low temperature from the natural oil of the extracted walnut oil.
Description
Technical Field
The invention belongs to the technical field of washing and caring products, and particularly relates to a walnut oil soap-based silicone-oil-free shampoo and a preparation method thereof.
Background
Walnut oil is rich in polyunsaturated fatty acids and monounsaturated fatty acids. It contains Omega-6, Omega-9 and Omega-3 fats. The oil contains b vitamins, vitamin E, zinc, selenium, calcium, magnesium and niacin. All of these vitamins and minerals promote hair health and growth.
The beneficial components of walnut oil, especially unsaturated fatty acid, vitamin E and zinc, make your hair strong and lustrous. The fat in the oil is easily absorbed by the hair follicle, strengthening the hair from the inside. The fatty acid moisturizes the hair without losing moisture. Vitamin E protects the hair from harmful effects and helps prevent the hair from whitening. Walnut oil is useful for treating scalp infections that cause hair loss. Some people use it to remove seborrheic dermatitis, which is a widely spread disease according to wikipedia. The effect is better if walnut oil is mixed with jojoba oil or tea tree oil. Black walnut oil is even more effective against skin diseases and is believed to kill lice.
Walnut skin is a good method for naturally dyeing hair. Walnut oil does not color hair when applied to hair, but is believed to brighten the color.
However, in the prior art, no shampoo which adopts walnut oil as a part of oil to synthesize a modified surfactant, replaces a conventional surfactant, and can utilize beneficial components of the walnut oil to nourish hair and replace silicone oil is available.
Disclosure of Invention
Aiming at the defects, the invention provides the walnut oil soap-based silicone-oil-free shampoo which adopts walnut oil as a part of synthetic modified surfactant of grease, can utilize beneficial components of the walnut oil to nourish hair and replace silicone oil while achieving the purpose of replacing the conventional surfactant, and the preparation method thereof.
The invention provides the following technical scheme: the walnut oil soap-based silicone-free shampoo does not contain polyorganosiloxane and comprises the following components in parts by weight:
further, the diameter of the nano-cellulose is 10 nm-30 nm.
Further, the nano-cellulose is one or more of nano ethyl hydroxyethyl cellulose, nano methyl hydroxypropyl cellulose or nano methyl carboxypropyl cellulose.
Further, the water softener is one or more of sodium silicate, sodium tripolyphosphate and sodium hexametaphosphate.
Further, the raw materials for preparing the walnut oil polyhydroxy stearic acid comprise the following components in parts by weight:
further, the preparation method of the walnut oil polyhydroxy stearic acid comprises the following steps:
1) mixing the sodium hydroxide with half of the anhydrous ethanol by weight to obtain a sodium hydroxide ethanol solution with the mass fraction of 3% -5%, dripping the sodium hydroxide ethanol solution into the walnut oil by weight, saponifying at 55-65 ℃ for 1-1.5 h, and then cooling to room temperature to obtain a precipitation solution with a lower soap cake;
2) acidifying the soap cake in the precipitation liquid obtained in the step 1) by using hydrochloric acid with the mass fraction of 12%, controlling the final pH of the reaction liquid to be 2.5-3.5 in the acidification process, then washing the reaction liquid to be neutral by using saturated sodium chloride, standing and layering the reaction liquid, taking an upper oil layer as mixed fatty acid obtained by hydrolysis of walnut oil, and adding anhydrous sodium sulfate into the oil layer containing the mixed fatty acid for drying;
3) adding the urea in the weight part into the remaining half of the anhydrous ethanol in the weight part, heating and refluxing at 75-85 ℃, adding the dried mixture containing the mixed fatty acid obtained in the step 2) after the urea is completely dissolved, stirring uniformly, and refluxing in a water bath at 50-60 ℃ for 30min to obtain enriched unsaturated fatty acid;
4) mixing the enriched unsaturated fatty acid obtained in the step 3) with the weight part of H2O2Mixing, reacting at 30-35 ℃ for 30min, then placing in a methanol sulfate solution, performing water bath esterification at 60-70 ℃ for 3-4 h, cooling to room temperature after the reaction is finished, then adding 20-30 parts of water, equally dividing the petroleum ether by weight into 3 parts, extracting 1 part of petroleum ether for 3 times each time, combining into a petroleum ether phase, recovering the petroleum ether under reduced pressure, and weighing to constant weight to obtain the walnut oil polyhydroxy stearic acid.
Further, the unsaturated fatty acid obtained by hydrolyzing and enriching the walnut oil in the step 3) is one or more of oleic acid, linoleic acid, linolenic acid, arachidonic acid and palmitic acid.
Further, the sulfuric acid methanol solution in the step 4) is concentrated sulfuric acid and methanol which are mixed according to a volume ratio of 1: 200-1: 250.
Further, the pressure of the petroleum ether recovered by decompression in the step 4) is 1.0KPa to 1.2KPa, and the temperature is 105 ℃ to 115 ℃.
The invention also provides a preparation method of the walnut oil soap-based silicone oil-free shampoo, which comprises the following steps:
s1: adding the sodium benzoate and the water softener in parts by weight into 50 parts of distilled water, and stirring for dissolving;
s2: putting the mixed solution obtained in the step S1 into a reaction kettle under the condition of stirring, adding the sodium carbonate, the sodium dodecyl sulfate, the walnut oil polyhydroxy stearic acid and the soap base according to the parts by weight, uniformly stirring, heating at 70-80 ℃, continuously stirring in the heating process, and keeping the temperature for 15-20 min;
s3: after the temperature is reduced to 40-60 ℃, adding the cocamidopropyl betaine, the nanocellulose and the polyethylene glycol in parts by weight into the mixture obtained in the step S2, stirring until the nanocellulose and the polyethylene glycol are completely dissolved, and keeping the temperature for 5-10 min;
s4: cooling to 30-35 ℃, adding the essence in parts by weight and the sodium chloride in parts by weight, adjusting the viscosity to 2000-3500 cp, and continuously stirring for 10-30min to obtain the walnut oil soap base silicone oil-free shampoo.
The invention has the beneficial effects that:
1. the walnut oil in the walnut oil polyhydroxy stearic acid adopted by the shampoo prepared by the invention is prepared by a low-temperature extraction method, so that volatile nutritional ingredients in the walnut oil polyhydroxy stearic acid are reserved, the shampoo is beneficial to nourishing hair and skin, and the shampoo has the effects of growing and blackening hair after long-term use.
2. The walnut oil polyhydroxy stearic acid adopted by the shampoo prepared by the invention is a novel modified soap base surfactant, walnut oil with various unsaturated fatty acids is adopted, fatty acids with different unsaturation degrees are obtained by hydrolysis from natural grease of the extracted walnut oil, and polyhydroxy fatty acids with different hydroxyl numbers are obtained by oxidizing double bonds of the unsaturated fatty acids.
3. The nano-cellulose adopted by the shampoo prepared by the invention utilizes the hydrophilic chemical property of the nano-cellulose, so that the nano-cellulose has higher surface activity, and can effectively reduce the surface tension of an interface, thereby enhancing the foam stability of the shampoo in the using process.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
This example provides a walnut oil soap-based silicone-free shampoo, which does not contain polyorganosiloxane, and comprises the following components in parts by weight:
the walnut oil polyhydroxy stearic acid preparation raw material comprises the following components in parts by weight:
the preparation method of the walnut oil polyhydroxy stearic acid comprises the following steps:
1) mixing 20 parts of sodium hydroxide and 50 parts of absolute ethyl alcohol to obtain a sodium hydroxide ethanol solution with the mass fraction of 5%, dripping the sodium hydroxide ethanol solution into the walnut oil with the weight parts, saponifying at 55 ℃ for 1.5h, and then cooling to room temperature to obtain a precipitation solution with a lower soap cake;
2) acidifying the soap cake in the precipitation liquid obtained in the step 1) by using hydrochloric acid with the mass fraction of 12%, controlling the final pH of the reaction liquid to be 3.5 in the acidification process, then cleaning the soap cake by using saturated sodium chloride until the neutral pH is 6.5, standing and layering, taking an upper oil layer as mixed fatty acid obtained by hydrolysis from walnut oil, and adding anhydrous sodium sulfate into the oil layer containing the mixed fatty acid for drying;
3) adding 8 parts of urea into the remaining 50 parts of absolute ethyl alcohol, heating and refluxing at 75 ℃, adding the dried mixture containing the mixed fatty acid obtained in the step 2) after the urea is completely dissolved, uniformly stirring, and refluxing in a water bath at 60 ℃ for 30min to obtain enriched unsaturated fatty acid;
4) mixing the enriched unsaturated fatty acid obtained in the step 3) with 30 parts of H2O2Mixing, reacting at 30 ℃ for 30min, then placing in a sulfuric acid methanol solution obtained by concentrated sulfuric acid and methanol according to the volume ratio of 1:200, carrying out water bath esterification at 70 ℃ for 3h, cooling to room temperature after the reaction is finished, then adding 30 parts of water, equally dividing 30 parts of petroleum ether into 3 parts, extracting by 1 part of petroleum ether (namely 10 parts by weight of petroleum ether per 1 part) each time, carrying out co-extraction for 3 times, combining to obtain a petroleum ether phase, recovering the petroleum ether under reduced pressure at 105 ℃ and 1.2KPa, and weighing to constant weight to obtain the walnut oil polyhydroxy stearic acid.
Through detection, unsaturated fatty acids obtained by hydrolyzing and enriching the walnut oil in the step 3) are 92.38% of oleic acid, 3.5% of linoleic acid, 0.32% of linolenic acid and 3.8% of palmitic acid.
The embodiment also provides a preparation method of the walnut oil soap-based silicone-free shampoo, which comprises the following steps:
s1: adding 0.25 part of sodium benzoate and 1 part of sodium tripolyphosphate into 50 parts of distilled water, and stirring for dissolving;
s2: putting the mixed solution obtained in the step S1 into a reaction kettle under the condition of stirring, adding 3 parts of sodium carbonate, 5 parts of sodium dodecyl sulfate, 20 parts of walnut oil polyhydroxy stearic acid and the soap base in parts by weight, uniformly stirring, heating at 70 ℃, continuously stirring in the heating process, and keeping the temperature for 20 min;
s3: cooling to 50 ℃, adding 10 parts of cocamidopropyl betaine, 20 parts of nano-methylhydroxypropylcellulose with the diameter of 10nm and 3 parts of polyethylene glycol into the mixture obtained in the step S2, stirring until the mixture is completely dissolved, and keeping the temperature for 7 min;
s4: cooling to 35 deg.C, adding 0.15 parts of essence and 0.1 parts of sodium chloride, adjusting viscosity to 2000cp, and stirring for 10min to obtain walnut oil soap base silicone-free shampoo.
Example 2
This example provides a walnut oil soap-based silicone-free shampoo, which does not contain polyorganosiloxane, and comprises the following components in parts by weight:
the walnut oil polyhydroxy stearic acid preparation raw material comprises the following components in parts by weight:
the preparation method of the walnut oil polyhydroxy stearic acid comprises the following steps:
1) mixing 15 parts of sodium hydroxide and 25 parts of absolute ethyl alcohol to obtain a sodium hydroxide ethanol solution with the mass fraction of 3%, dripping the sodium hydroxide ethanol solution into the walnut oil with the weight part, saponifying at 65 ℃ for 1.2h, and cooling to room temperature to obtain a precipitation solution with a lower soap cake;
2) acidifying the soap cake in the precipitation liquid obtained in the step 1) by using hydrochloric acid with the mass fraction of 12%, controlling the final pH of the reaction liquid to be 3.0 in the acidification process, then cleaning the reaction liquid to be neutral by using saturated sodium chloride, standing and layering the reaction liquid, taking an upper oil layer as mixed fatty acid obtained by hydrolyzing walnut oil, and adding anhydrous sodium sulfate into the oil layer containing the mixed fatty acid for drying;
3) adding 6.5 parts of urea into the remaining 25 parts of absolute ethyl alcohol, heating and refluxing at 80 ℃, adding the dried mixture containing the mixed fatty acid obtained in the step 2) after the urea is completely dissolved, uniformly stirring, and refluxing in a water bath at 50 ℃ for 30min to obtain enriched unsaturated fatty acid;
4) mixing the enriched unsaturated fatty acid obtained in the step 3) with 20 parts of H2O2Mixing, reacting at 35 ℃ for 30min, then placing in concentrated sulfuric acid and methanol-sulfuric acid methanol solution according to the volume ratio of 1:250, esterifying for 4h in water bath at 65 ℃, cooling to room temperature after the reaction is finished, then adding 20 parts of water, equally dividing 15 parts of petroleum ether into 3 parts (namely, 5 parts of petroleum ether in each part), extracting with 1 part of petroleum ether each time, co-extracting for 3 times, combining into a petroleum ether phase, recovering the petroleum ether under reduced pressure at 100 ℃ and 1.0KPa, and weighing to constant weight to obtain the walnut oil polyhydroxy stearic acid.
Through detection, unsaturated fatty acids obtained by hydrolyzing and enriching the walnut oil in the step 3) are 90.8% of oleic acid, 1.1% of linoleic acid, 0.3% of linolenic acid, 3.3% of arachidonic acid and 4.5% of palmitic acid.
The embodiment also provides a preparation method of the walnut oil soap-based silicone-free shampoo, which comprises the following steps:
s1: adding 0.45 part of sodium benzoate and 3.5 parts of sodium silicate into 50 parts of distilled water, and stirring for dissolving;
s2: placing the mixed solution obtained in the step S1 into a reaction kettle under the condition of stirring, adding 2 parts of sodium carbonate, 8 parts of sodium dodecyl sulfate, 15 parts of walnut oil polyhydroxy stearic acid and 8 parts of soap base, uniformly stirring, heating at 80 ℃, continuously stirring in the heating process, and keeping the temperature for 15 min;
s3: after the temperature is reduced to 60 ℃, adding 5 parts of cocamidopropyl betaine, 15 parts of nano methyl carboxypropyl cellulose with the diameter of 20nm and 8 parts of polyethylene glycol into the mixture obtained in the step S2, stirring until the nano methyl carboxypropyl cellulose and the polyethylene glycol are completely dissolved, and then keeping the temperature for 5 min;
s4: cooling to 32 ℃, adding the essence in parts by weight and the sodium chloride in parts by weight, adjusting the viscosity to 2500cp, and continuously stirring for 20min to obtain the walnut oil soap-based silicone-oil-free shampoo.
Example 3
This example provides a walnut oil soap-based silicone-free shampoo, which does not contain polyorganosiloxane, and comprises the following components in parts by weight:
the walnut oil polyhydroxy stearic acid preparation raw material comprises the following components in parts by weight:
the preparation method of the walnut oil polyhydroxy stearic acid comprises the following steps:
1) mixing 10 parts of sodium hydroxide and 40 parts of absolute ethyl alcohol to obtain a sodium hydroxide ethanol solution with the mass fraction of 4%, dripping the sodium hydroxide ethanol solution into the walnut oil with the weight parts, saponifying at 60 ℃ for 1h, and cooling to room temperature to obtain a precipitation solution with a lower soap cake;
2) acidifying the soap cake in the precipitation liquid obtained in the step 1) by using hydrochloric acid with the mass fraction of 12%, controlling the final pH of the reaction liquid to be 2.5 in the acidification process, then cleaning the reaction liquid to be neutral by using saturated sodium chloride, standing and layering the reaction liquid, taking an upper oil layer as mixed fatty acid obtained by hydrolyzing walnut oil, and adding anhydrous sodium sulfate into the oil layer containing the mixed fatty acid for drying;
3) adding 5 parts of urea into the remaining 40 parts of absolute ethyl alcohol, heating and refluxing at 85 ℃, adding the dried mixture containing the mixed fatty acid obtained in the step 2) after the urea is completely dissolved, uniformly stirring, and performing water bath reflux at 55 ℃ for 30min to obtain enriched unsaturated fatty acid;
4) mixing the enriched unsaturated fatty acid obtained in the step 3) with 25 parts of H2O2Mixing, reacting at 33 deg.C for 30min, and standingPerforming water bath esterification for 3.5 hours at 60 ℃ in a sulfuric acid methanol solution of concentrated sulfuric acid and methanol according to the volume ratio of 1:220, cooling to room temperature after the reaction is finished, then adding 25 parts of water, equally dividing 21 parts of petroleum ether into 3 parts (namely, 7 parts of petroleum ether in each part), extracting 1 part of petroleum ether for 3 times each time, combining the petroleum ether phases, selecting and recovering petroleum ether under reduced pressure at 110 ℃ and 1.1KPa, and weighing to constant weight to obtain the walnut oil polyhydroxy stearic acid.
Through detection, unsaturated fatty acids obtained by hydrolyzing and enriching the walnut oil in the step 3) are 82.6% of oleic acid, 2.4% of linoleic acid, 7.6% of linolenic acid, 1.8% of arachidonic acid and 5.6% of palmitic acid.
The embodiment also provides a preparation method of the walnut oil soap-based silicone-free shampoo, which comprises the following steps:
s1: adding 0.35 part of sodium benzoate and 6 parts of sodium hexametaphosphate into 50 parts of distilled water, and stirring for dissolving;
s2: putting the mixed solution obtained in the step S1 into a reaction kettle under the stirring condition, adding 1 part of sodium carbonate, 10 parts of sodium dodecyl sulfate, 10 parts of walnut oil polyhydroxy stearic acid and 6 parts of soap base, uniformly stirring, heating at 75 ℃, continuously stirring in the heating process, and keeping the temperature for 17 min;
s3: after the temperature is reduced to 40 ℃, adding 7.5 parts of cocamidopropyl betaine, 18 parts of nano ethyl hydroxyethyl cellulose with the diameter of 30nm and 5 parts of polyethylene glycol into the mixture obtained in the step S2, stirring until the nano ethyl hydroxyethyl cellulose and the polyethylene glycol are completely dissolved, and then keeping the temperature for 10 min;
s4: cooling to 30 deg.C, adding 0.10 parts of essence and 0.5 parts of sodium chloride, adjusting viscosity to 3500cp, and stirring for 30min to obtain walnut oil soap base silicone-free shampoo.
Comparative example 1
This example differs from example 1 only in that the same amount by weight of the same amount of cocamidopropyl betaine as in example 1 was replaced by the same amount by weight of the polyorganosiloxane as cocamidopropyl betaine, which had the same lubricating and softening effect.
Comparative example 2
The difference between the embodiment and the embodiment 1 is that sodium laureth sulfate with surfactant effect is used to replace walnut oil polyhydroxy stearic acid in the embodiment, and the weight portion of the sodium laureth sulfate is the same as that of the walnut oil polyhydroxy stearic acid.
Comparative example 3
This example differs from example 1 only in that the shampoo was prepared without using nano-methylhydroxypropylcellulose having a diameter of 10 nm.
Experimental example 1
The shampoos of examples 1 to 3 and comparative examples 1 to 3 according to the present invention were prepared into a solution with a mass fraction of 1%, slowly heated or cooled, and when the critical temperature at which the solution suddenly changed from turbid to clear was its Krafft Point, the measurement was repeated three times, and the average value was taken. The results are shown in Table 1.
Experimental example 2
At a certain temperature, respectively measuring 10mL of the shampoos of examples 1-3 and comparative examples 1-3 of the present invention to prepare 0.1% by mass of solution, placing the solution in a 100mL measuring cylinder with a plug, adding a buffer solution to dilute the solution to 30mL, shaking the solution for 10 times after the plug is formed, standing the solution for 30s, recording a bubble volume H0, recording a foam stabilizing volume H1 after 5min, and taking the average value of the bubble volumes of 5 parallel experiments as the foaming power, wherein the larger the bubble volume is, the better the foaming power is. The results are shown in Table 1.
TABLE 1
| Kraff point | Volume of bubbles | |
| Example 1 | ＜0 | 93.6 |
| Example 2 | ＜0 | 92.5 |
| Example 3 | ＜0 | 93.0 |
| Comparative example 1 | ＜0 | 79.7 |
| Comparative example 2 | 16 | 39.6 |
| Comparative example 3 | ＜0 | 68.6 |
Experimental example 3
The shampoos of examples 1 to 3 and comparative examples 1 to 3 of the present invention were taken, 100g of water was added, and after stirring for 10 seconds with a stirrer, the foam height was recorded for evaluating foamability/initial foam height, and after standing for 5min, the height of the water surface (drainage height) of the lower layer of foam was recorded for evaluating the stability of foam. The results are shown in Table 2.
TABLE 2
| Height of foam | Height of water discharge | |
| Example 1 | 10.8cm | 0.67cm |
| Example 2 | 10.3cm | 0.72cm |
| Example 3 | 9.8cm | 0.75cm |
| Comparative example 1 | 8.6cm | 0.68cm |
| Comparative example 2 | 8.7cm | 0.73cm |
| Comparative example 3 | 6.3cm | 1.43cm |
As can be seen from Table 2, the addition of nanocellulose having a diameter of 10nm to 30nm effectively increased the foam height of the shampoo and effectively decreased the height of the water outlet below the foam, meaning that the stability of the foam was enhanced, while in comparative example 3, the height of the water outlet was greatly increased due to the absence of nanocellulose, indicating that the stability was poor.
Through Ames test detection, the shampoo prepared by the invention is specified in national standard GB7919-1987 cosmetic safety evaluation program and method
The above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.
Furthermore, those skilled in the art will appreciate that while some embodiments herein include some features included in other embodiments, rather than other features, combinations of features of different embodiments are meant to be within the scope of the invention and form different embodiments. For example, in the claims above, any of the claimed embodiments may be used in any combination. The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person skilled in the art.
Claims (10)
1. The walnut oil soap-based silicone-free shampoo is free of polyorganosiloxane and is characterized by comprising the following components in parts by weight:
2. the walnut oil soap-based silicone oil-free shampoo of claim 1 wherein the nanocellulose has a diameter of 10nm to 30 nm.
3. The walnut oil soap-based silicone-free shampoo of claim 1, wherein the nanocellulose is one or more of nanoethylhydroxyethylcellulose, nanomethylhydroxypropylcellulose, or nanomethylcarboxypropylcellulose.
4. The walnut oil soap-based silicone-free shampoo of claim 1 wherein the water softener is one or more of sodium silicate, sodium tripolyphosphate, and sodium hexametaphosphate.
5. The walnut oil soap-based silicone-oil-free shampoo as claimed in claim 1, wherein the walnut oil polyhydroxystearic acid is prepared from the following raw materials in parts by weight:
6. the walnut oil soap-based silicone oil-free shampoo according to claim 5, wherein the preparation method of the walnut oil polyhydroxystearic acid comprises the following steps:
1) mixing the sodium hydroxide with half of the anhydrous ethanol by weight to obtain a sodium hydroxide ethanol solution with the mass fraction of 3% -5%, dripping the sodium hydroxide ethanol solution into the walnut oil by weight, saponifying at 55-65 ℃ for 1-1.5 h, and then cooling to room temperature to obtain a precipitation solution with a lower soap cake;
2) acidifying the soap cake in the precipitation liquid obtained in the step 1) by using hydrochloric acid with the mass fraction of 12%, controlling the final pH of the reaction liquid to be 2.5-3.5 in the acidification process, then washing the reaction liquid to be neutral by using saturated sodium chloride, standing and layering the reaction liquid, taking an upper oil layer as mixed fatty acid obtained by hydrolysis of walnut oil, and adding anhydrous sodium sulfate into the oil layer containing the mixed fatty acid for drying;
3) adding the urea in the weight part into the remaining half of the anhydrous ethanol in the weight part, heating and refluxing at 75-85 ℃, adding the dried mixture containing the mixed fatty acid obtained in the step 2) after the urea is completely dissolved, stirring uniformly, and refluxing in a water bath at 50-60 ℃ for 30min to obtain enriched unsaturated fatty acid;
4) mixing the enriched unsaturated fatty acid obtained in the step 3) with the weight part of H2O2Mixing, reacting at 30-35 ℃ for 30min, then placing in a methanol sulfate solution, performing water bath esterification at 60-70 ℃ for 3-4 h, cooling to room temperature after the reaction is finished, then adding 20-30 parts of water, equally dividing the petroleum ether by weight into 3 parts, extracting 1 part of petroleum ether for 3 times each time, combining into a petroleum ether phase, recovering the petroleum ether under reduced pressure, and weighing to constant weight to obtain the walnut oil polyhydroxy stearic acid.
7. The walnut oil soap-based silicone oil-free shampoo according to claim 6, wherein the unsaturated fatty acid obtained by hydrolysis and enrichment of the walnut oil in step 3) is one or more of oleic acid, linoleic acid, linolenic acid, arachidonic acid, and palmitic acid.
8. The walnut oil soap-based silicone oil-free shampoo as claimed in claim 6, wherein the methanol sulfate solution in step 4) is concentrated sulfuric acid and methanol at a volume ratio of 1:200 to 1: 250.
9. The walnut oil soap-based silicone oil-free shampoo as claimed in claim 6 wherein the pressure of the petroleum ether recovered under reduced pressure in step 4) is 1.0KPa to 1.2KPa and the temperature is 105 ℃ to 115 ℃.
10. The method of preparing a walnut oil soap-based silicone free shampoo according to any of claims 1-9 comprising the steps of:
s1: adding the sodium benzoate and the water softener in parts by weight into 50 parts of distilled water, and stirring for dissolving;
s2: putting the mixed solution obtained in the step S1 into a reaction kettle under the condition of stirring, adding the sodium carbonate, the sodium dodecyl sulfate, the walnut oil polyhydroxy stearic acid and the soap base according to the parts by weight, uniformly stirring, heating at 70-80 ℃, continuously stirring in the heating process, and keeping the temperature for 15-20 min;
s3: after the temperature is reduced to 40-60 ℃, adding the cocamidopropyl betaine, the nanocellulose and the polyethylene glycol in parts by weight into the mixture obtained in the step S2, stirring until the nanocellulose and the polyethylene glycol are completely dissolved, and keeping the temperature for 5-10 min;
s4: cooling to 30-35 ℃, adding the essence in parts by weight and the sodium chloride in parts by weight, adjusting the viscosity to 2000-3500 cp, and continuously stirring for 10-30min to obtain the walnut oil soap base silicone oil-free shampoo.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1411797A (en) * | 2002-10-29 | 2003-04-23 | 山西大学 | Shampoo cream and its preparation method |
| CN101845362A (en) * | 2010-06-22 | 2010-09-29 | 中南林业科技大学 | Method for gathering oleic acid from tea-seed oil |
| CN104726228A (en) * | 2013-12-18 | 2015-06-24 | 江南大学 | Multifunctional soap produced from sodium polyhydroxy stearate |
| CN107312805A (en) * | 2017-08-07 | 2017-11-03 | 中国农业大学 | A kind of preparation and its application of the polyunsaturated fatty acid rich in CLA |
| CN107418737A (en) * | 2017-06-06 | 2017-12-01 | 江苏天晟药业股份有限公司 | The preparation method of unrighted acid in a kind of Silybum Marianum Gaertn Seed Oil |
-
2021
- 2021-07-26 CN CN202110842864.8A patent/CN113599305B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1411797A (en) * | 2002-10-29 | 2003-04-23 | 山西大学 | Shampoo cream and its preparation method |
| CN101845362A (en) * | 2010-06-22 | 2010-09-29 | 中南林业科技大学 | Method for gathering oleic acid from tea-seed oil |
| CN104726228A (en) * | 2013-12-18 | 2015-06-24 | 江南大学 | Multifunctional soap produced from sodium polyhydroxy stearate |
| CN107418737A (en) * | 2017-06-06 | 2017-12-01 | 江苏天晟药业股份有限公司 | The preparation method of unrighted acid in a kind of Silybum Marianum Gaertn Seed Oil |
| CN107312805A (en) * | 2017-08-07 | 2017-11-03 | 中国农业大学 | A kind of preparation and its application of the polyunsaturated fatty acid rich in CLA |
Non-Patent Citations (1)
| Title |
|---|
| 李泉岑等: "尿素包合法富集核桃油不饱和脂肪酸工艺优化" * |
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