CN113576946A

CN113576946A - Hair conditioner and preparation method thereof

Info

Publication number: CN113576946A
Application number: CN202110759012.2A
Authority: CN
Inventors: 陈幼婷; 万岳鹏
Original assignee: Guangzhou Huanya Cosmetic Science and Technology Co Ltd
Current assignee: Guangzhou Huanya Cosmetic Science and Technology Co Ltd
Priority date: 2021-07-05
Filing date: 2021-07-05
Publication date: 2021-11-02
Anticipated expiration: 2041-07-05
Also published as: CN113576946B

Abstract

The invention discloses a hair conditioner and a preparation method thereof, wherein the hair conditioner comprises the following components: 0.5-2.5% of cetrimide, 0.5-2.5% of behenyl trimethyl ammonium chloride, 5-20% of hydrogenated polyisobutene, 2-8% of octyldodecanol myristate, 0.5-2.5% of C12-13 alcohol lactate, 0.2-3% of alkyl, 0.5-2.5% of sodium isostearoyl lactylate, 0.2-2% of polyethylene glycol-14M, 0.01-0.3% of chelating agent, 0.01-0.8% of preservative, 0.01-4% of conditioner B and 0.2-1% of aromatic. The hair conditioner is compounded by adopting various vegetable oils, locks water and moisturizes, nourishes dry and withered hair, improves the frizziness degree of the hair, increases the smoothness of the hair, and improves the toughness of the hair. The components have synergistic effect, can bring double-layer milk cover-shaped appearance, have thick and rich foam, and can more quickly and more easily penetrate into a hair core.

Description

Hair conditioner and preparation method thereof

Technical Field

The invention belongs to the technical field of washing and caring products, and particularly relates to a hair conditioner and a preparation method thereof.

Background

The modern society develops at a high speed, people also have great change to the consciousness of appearance management and fashion, the change is directly reflected in the requirement of cosmetics, and the phenomena of dry hair, split hair, no luster and the like are caused by protein denaturation, hair scale damage, large amount of water loss, and the like of the hair exposed in the external environment and the hair straightening, curling, dyeing and the like, so that the hair loses the original softness and toughness.

At present, a plurality of products which are popular for hair care exist in the market, the forms of the products are not only emulsion or transparent single forms, but also the forms are single in use. Therefore, the double-layer milk cap type product can penetrate into the hair core more quickly, smoothes frightened hair, repairs the hair, enables the hair to become flexible, and has funny and interesting effects.

Disclosure of Invention

The invention aims to provide a double-layer bubble hair conditioner with a soft and moist repairing effect and a preparation method thereof.

The technical scheme adopted by the invention is as follows:

in a first aspect of the present invention, there is provided a hair conditioner comprising the following ingredients: 0.5-2.5% of cetrimide, 0.5-2.5% of behenyl trimethyl ammonium chloride, 5-20% of hydrogenated polyisobutene, 2-8% of octyldodecanol myristate, 0.5-2.5% of C12-13 alcohol lactate, 0.2-3% of alkyl, 0.5-2.5% of sodium isostearoyl lactylate, 0.2-2% of polyethylene glycol-14M, 0.01-0.3% of chelating agent, 0.01-0.8% of preservative, 0.01-4% of conditioner B and 0.2-1% of aromatic.

In some preferred embodiments of the present invention, the hair conditioner comprises the following ingredients: cetroronium chloride 1.5%, behenyl trimethyl ammonium chloride 1.5%, hydrogenated polyisobutene 15%, octyldodecanol myristate 5%, C12-13 alcohol lactate 2%, alkyl 2%, sodium isostearoyl lactylate 0.5%, polyethylene glycol-14M 1.2%, chelating agent 0.1%, preservative 0.2%, conditioner B3.5%, and aromatic 1%.

In some embodiments of the present invention, the conditioning agent B is selected from at least one of polyquaternium-52, PPG-3 octyl ether, camellia seed oil, sodium hyaluronate, complex amino acids, and camellia extract.

In some embodiments of the invention, the complex amino acid is selected from at least one of arginine, aspartic acid, glycine, serine, and proline.

In some embodiments of the invention, the alkane is selected from at least one of undecane and tridecane.

In some embodiments of the invention, the chelating agent is disodium EDTA.

In some embodiments of the invention, the preservative is selected from at least one of sodium benzoate and phenoxyethanol.

In some embodiments of the invention, the fragrance is a perfume.

In a second aspect of the present invention, there is provided a process for preparing the hair conditioner according to the first aspect, comprising the steps of:

s1: heating to 80-85 ℃, mixing and adding cetrimide, behenyl trimethyl ammonium chloride, polyethylene glycol-14M, hydrogenated polyisobutene, octyldodecanol myristate, C12-13 alcohol lactate, sodium isostearoyl lactylate, alkyl, PPG-3 octyl ether and camellia seed oil, and stirring to obtain a mixture A;

s2: adding EDTA disodium and sodium benzoate into the mixture A, and uniformly stirring to obtain a mixture B;

s3: cooling to 40-50 ℃, adding phenoxyethanol, polyquaternium-52, sodium hyaluronate, compound amino acid, camellia extract and essence into the mixture B, uniformly stirring, and cooling.

In some embodiments of the invention, said step S1 is performed in an emulsifying pan.

In some embodiments of the present invention, the stirring in step S1 is homogeneous stirring.

In some embodiments of the present invention, the stirring time in step S1 is 10-20 min.

In some embodiments of the invention, the stirring in step S2 is performed uniformly, and then the temperature is maintained for 15-25 min.

In some embodiments of the invention, the temperature of the cooling is 30 to 40 ℃.

The invention has the beneficial effects that:

the invention provides a double-layer bubble hair conditioner for softening and repairing hair and a preparation method thereof. The hair conditioner is a stable and double-layer hair conditioner, and consists of a lipophilic conditioner, a cationic conditioner and a hydrophilic component. The hair conditioner adopts a plurality of vegetable oil which is beneficial to hair to be compounded, locks water and preserves moisture, and nourishes dry and withered hair. Has the effects of softening and repairing hair, and can improve the frizziness of hair, increase the smoothness of hair, and improve the toughness of hair by electrostatic attraction, free radical scavenging, and unique hair scale repairing technology. Through the electrostatic attraction effect, the free radical scavenging effect and the unique hair scale repairing technology, the frizziness degree of the hair is improved, the smoothness of the hair is increased, and the toughness of the hair is improved. And each component has the synergistic effect, can bring double-layer milk cover-shaped appearance and have continuous and abundant foam, and can quickly and easily go deep into the hair core to solve the problems of difficult combing, low softness and low toughness of damaged hair.

This hair conditioner divide into the bilayer, and the one deck contains the oil phase that is emulsified, and the one deck contains the aqueous phase of one or more composition, can the misce bene when the oscillation, extrudes soft foam, conveniently paints and is convenient for absorb to keep the homogeneous state in sufficient time, help the consumer to use this product more conveniently. Compared with the existing hair care technical products, the double-layer hair conditioner disclosed by the invention not only has a more interesting use method, but also can enable effective substances to penetrate into hair cores more quickly and better, repair damaged and beautiful hair, lock water and preserve moisture, and enable the beautiful hair to be soft, smooth and smooth.

Drawings

FIG. 1 is a graph of wet hair combing performance of a damaged hair bundle.

Fig. 2 is a dry combing performance of a damaged hair bundle.

Fig. 3 is a stretch-break test of a damaged hair strand.

FIG. 4 is a foam richness test.

Detailed Description

The concept and technical effects of the present invention will be clearly and completely described below in conjunction with the embodiments to fully understand the objects, features and effects of the present invention. It is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments, and those skilled in the art can obtain other embodiments without inventive effort based on the embodiments of the present invention, and all embodiments are within the protection scope of the present invention.

The capryl C12-13 alcohol lactate was purchased from sasol; the sodium isostearoyl lactylate is available from chow lion chemical; the undecane/tridecane was purchased from BASF; the cetrorhiza chloride is purchased from winning creations; the behenyl trimethyl ammonium chloride was purchased from Clariant; the polyethylene glycol-14M was purchased from Dow. The hydrogenated polyisobutenes are purchased from NOF CORPORATION; the octyldodecanol myristate was purchased from BASF.

The double-layer bubble hair conditioner with the function of moistening and repairing hair comprises the following components:

(1) the hair conditioner upper layer composition mainly comprises the following components:

(2) the lower layer composition of the hair conditioner comprises the following main components:

the alkane is at least one of undecane and tridecane.

The conditioner B is at least one selected from oleum Camelliae Japonicae (Camellia JAPONICA) oil, PPG-3 octyl ether, sodium hyaluronate, flos Camelliae Japonicae extract, compound amino acids and polyquaternium-52.

The compound amino acid is at least one of arginine, aspartic acid, glycine, serine and proline.

The chelating agent is disodium EDTA.

The preservative is at least one selected from sodium benzoate and phenoxyethanol.

The aromatic is essence.

In the invention, the function of the double-layer bubble hair conditioner with soft and moist repair is introduced as follows:

the cetroronium chloride and behenyl trimethyl ammonium chloride can be emulsified with hydrogenated polyisobutene, octyldodecanol myristate, C12-13 alcohol lactate, sodium isostearoyl lactylate and undecane/tridecane in a certain proportion range, and can be rapidly demulsified to form double-layer milk cover-shaped liquid with softening and hair care effects.

The PPG-3 octyl ether can effectively promote the uniform adsorption of grease on hair, repair damaged hair scales, improve the frizziness degree of hair and increase the smoothness of hair.

The compound amino acid and the sodium hyaluronate are mutually cooperated, so that the hair moisture loss is slowed down, the moisture preservation and adjustment are realized, and the flexibility of the hair is improved.

Polyethylene glycol-14M acts as an excellent synergist and lubricant with a slight electronegativity capable of interacting with the counter ions of the surface active agent and hydrogen in water molecules to strengthen the membrane wall structure of the foam, increasing the foam richness and persistence of the system while giving a hair plump experience.

Example 1

This example provides a double-layer bubble conditioner with soft and moist conditioning, the specific ingredients are shown in table 1.

The compositions shown in table 1 are all in mass percent.

Table 1 examples 1-3 double layer conditioner formula table

The complex amino acids described in table 1 are glycine, serine and proline, wherein the ratio of glycine, serine and proline is 1:1: 4.

The preparation method of the hair conditioner comprises the following steps:

s1: heating to 80 deg.C, sequentially adding cetrorhium chloride, behenyl trimethyl ammonium chloride, polyethylene glycol-14M, hydrogenated polyisobutene, octyldodecanol myristate, C12-13 alcohol lactate, sodium isostearoyl lactylate, undecane, tridecane, PPG-3 octyl ether, and oleum Camelliae Japonicae (Camellia Japonica) into an emulsifying pot, homogenizing and stirring for 10 min;

s2: adding EDTA disodium and sodium benzoate, stirring, and keeping the temperature for 20 min;

s3: cooling to 40 deg.C, adding phenoxyethanol, polyquaternium-52, sodium hyaluronate, compound amino acids, flos Camelliae Japonicae extract, and essence, homogenizing, and stirring; cooling to 35 ℃, filtering by 200 meshes and discharging; and (5) after the inspection is qualified, subpackaging, packaging, inspecting again, and warehousing the finished product.

Example 2

The preparation method of the hair conditioner comprises the following steps:

s1: heating to 85 deg.C, sequentially adding cetrorhiza chloride, behenyl trimethyl ammonium chloride, polyethylene glycol-14M, hydrogenated polyisobutene, octyldodecanol myristate, C12-13 alcohol lactate, sodium isostearoyl lactylate, undecane/tridecane, PPG-3 octyl ether, and oleum Camelliae Japonicae (Camellia Japonica) into an emulsifying pot, homogenizing and stirring for 20 min;

s2: adding EDTA disodium and sodium benzoate, stirring, and keeping the temperature for 25 min;

s3: cooling to 45 deg.C, adding phenoxyethanol, polyquaternium-52, sodium hyaluronate, compound amino acid, flos Camelliae Japonicae extract, and essence, homogenizing, and stirring; cooling to 40 ℃, filtering by 200 meshes and discharging; and (5) after the inspection is qualified, subpackaging, packaging, inspecting again, and warehousing the finished product.

Example 3

The preparation method of the hair conditioner comprises the following steps:

s1: heating to 83 deg.C, sequentially adding cetrorhium chloride, behenyl trimethyl ammonium chloride, polyethylene glycol-14M, hydrogenated polyisobutene, octyldodecanol myristate, C12-13 alcohol lactate, sodium isostearoyl lactylate, undecane, tridecane, PPG-3 octyl ether, and oleum Camelliae Japonicae (Camellia Japonica) into an emulsifying pot, homogenizing and stirring for 15 min;

s2: adding EDTA disodium and sodium benzoate, stirring, and keeping the temperature for 15 min;

s3: cooling to 50 deg.C, adding phenoxyethanol, polyquaternium-52, sodium hyaluronate, compound amino acids, flos Camelliae Japonicae extract, and essence, homogenizing, and stirring; cooling to 30 ℃, filtering by 200 meshes and discharging; and (5) after the inspection is qualified, subpackaging, packaging, inspecting again, and warehousing the finished product.

Comparative example 1

Except that comparative example 1 did not contain cetrorhium chloride, as in example 2.

The specific components of the comparative examples are shown in tables 2 and 3.

The compositions shown in table 2 and table 3 are in mass percent.

TABLE 2 hair conditioner formulations of comparative examples 1-7

TABLE 3 hair conditioner formula tables of comparative examples 8-15

The complex amino acids in tables 2 and 3 are glycine, serine and proline, wherein the ratio of glycine, serine and proline is 1:1: 4.

Comparative example 2

The difference from example 2 is that the percentage of cetrorhium chloride is 0.3, which is lower than the lower limit value.

Comparative example 3

Except that behenyltrimethylammonium chloride was not included in example 2.

Comparative example 4

The difference from example 2 is that the percentage of behenyltrimethylammonium chloride is 0.3, below the lower limit.

Comparative example 5

The difference from example 2 is that the percentage of behenyltrimethylammonium chloride is 4, above the upper limit.

Comparative example 6

The difference from example 2 is that hydrogenated polyisobutene is not included.

Comparative example 7

The difference from example 2 is that the percentage of hydrogenated polyisobutene is 4, below the lower limit value.

Comparative example 8

The difference from example 2 is that the percentage of hydrogenated polyisobutene is 25, above the upper limit.

Comparative example 9

Except that octyl dodecanol myristate was not included as in example 2.

Comparative example 10

The difference from example 2 is that the percentage of octyldodecanol myristate was 1%, which is lower than the lower limit.

Comparative example 11

The difference from example 2 is that the percentage of octyldodecanol myristate was 12%, which is higher than the upper limit.

Comparative example 12

The difference from example 2 is that C12-13 alcohol lactate is not included.

Comparative example 13

The difference from example 2 is that undecane and tridecane were not contained.

Comparative example 14

Unlike example 2 in that it does not contain sodium isostearoyl lactylate.

Comparative example 15

The difference from example 2 is that polyethylene glycol-14M is not included.

Example 4 efficacy testing experiment

1) Hair tress dynamic combing laboratory test

1. Testing an instrument: a hair softness detector SK-3A.

2. Principle of testing

The working principle of the hair softness detector SK-3A is as follows: the sensory quantification process is realized through constant pressure and automatic operation, the combing data are processed results, the lower the numerical value is, the better the combing performance is represented, and the more flexible the hair is. The hair flexibility detector used in the experiment mainly comprises a shower nozzle, a displacement meter, a loading unit, an electrostatic sensor and other parts.

3. Test method

Refer to the carding test flow Manual developed in BHI laboratories.

4. Test procedure

Respectively selecting 19 bundles of damaged hair bleached by hydrogen peroxide, and uniformly spraying 18 damaged hair bundles of example 1, example 2, example 3, comparative example 1, comparative example 2, comparative example 3, comparative example 4, comparative example 5, comparative example 6, comparative example 7, comparative example 8, comparative example 9, comparative example 11, comparative example 12, comparative example 13, comparative example 14 and comparative example 15 to obtain hair conditioner samples of experiment groups, wherein the damaged hair bundles are sequentially marked as 1#, 2#, 3#, 4#, 6#, 7#, 8#, 9#, 10#, 11#, 12#, 13#, 14#, 15#, 16#, 3#, 4#, 5#, 6#, 8#, 10#, 12#, 13#, 14 and 18 #; the No. 19 hair tresses are evenly coated with a commercial mousse hair conditioner which is equal to that of the experimental group, in the comparison of combing force performance, a normal standard sample is selected as a base line for comparison, then the base line is washed for 10 seconds by warm water at 40 ℃, and the base line is placed on a dynamic hair combing machine to compare the wet combing performance of 10 groups of hair tresses. After the wet combing performance of 10 groups of hair tresses is measured, the hair tresses are placed in a constant temperature chamber (the temperature is 25 ℃ and the humidity is 35%) for natural drying, and then the hair tresses are placed in a dynamic hair combing instrument for comparing the dry combing performance of 10 groups of hair tresses.

Wherein the wet combing performance test results of the damaged hair tresses are shown in figure 1, and the dry combing performance of the damaged hair tresses are shown in figure 2. As can be seen from fig. 1 and 2:

a) the wet combing value and the dry combing value of the three groups of hair strands 1#, 2#, 3# coated with the hair conditioner of the embodiment 1-3 are less than the percentage of the composition lacking a certain component or not in the range in the comparative example;

b) the wet combing values of the three groups of hair strands 1#, 2#, and 3# coated with the hair conditioner of the embodiments 1-3 are all less than the hair strand 19# coated with the commercially-available good mousse hair conditioner, and the combing performance after hair drying is also obviously lower than the hair strand 19# coated with the commercially-available good mousse hair conditioner;

c) therefore, after the hair conditioner is used for damaged hair strands, the smoothness of the damaged hair strands is better than that of a commercially available better mousse hair conditioner, the hair conditioner can be adsorbed on the surface of damaged hair, holes of damaged hair scales can be effectively filled, and the smoothness and the frizziness of the damaged hair can be further improved.

2) Hair bundle stretch-break test

1. Testing an instrument: hair multifunction tester MTT 175.

2. Test method

In order to help understand the improvement of the hair stretching resistance of the hair conditioners in the examples 1-3, 19 bundles of damaged hair bleached by hydrogen peroxide are selected respectively, and 18 groups of damaged hair bundles, namely A, B, C, D, E, F, G, H, I, J, K, L, M, N, O, P, Q, R, S, A, B, C, D, E, F, G, H, I, J, K, L, M, N, O, P, Q and R, are uniformly coated on samples of the examples 1, 2 and 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14 and 15 respectively in equal amount and serve as an experimental group; and uniformly coating the same amount of the hair strands of the S group with the good mousse hair conditioner sold in the market, washing the hair strands for 10 seconds by warm water at 40 ℃, and naturally airing the hair strands in a thermostatic chamber (the temperature is 25 ℃ and the humidity is 35%). In the above manner, the hair tensile properties were compared after 1 week of continuous use.

In performing the hair stretching experiment, the hair will undergo 3 stress phases. In the first stage, the expansion and contraction of the hair are reversible during the stress of the hair in the elastic zone; a second stage during which the elongation transition experienced by the hair is irreversible during stressing of the hair at its elastic yield zone, during which the covalent bonds between the hair fibre macromolecules may break; in the third stage, the hair is out of tolerance and breaks. The stretch breaking work is an index for displaying the whole condition and the integrity of the hair, is an external expression of damage to substances in the hair, and can reflect the condition of the hair from the macroscopic view. The smaller the breaking work, the lower the tensile properties, the more the internal structure and tissue of the hair are destroyed, keratin and lipid are important components of the hair structure and play an important role in maintaining the toughness and strength of the hair, and damage to protein and lipid causes the corresponding function to be reduced or lost, and the hair becomes fragile and breakable.

In the experiment process, one hair with the length of 20cm is selected from A, B, C, D, E, F, G, H, I, J, K, L, M, N, O, P, Q, R, S groups of hair bundles, experiment parameters are set on an MTT175 hair tension tester, the hair is stretched at the stretching speed of 100mm per minute by using the tension of 20 g, and then the damage degree and the repair degree of the hair are deduced by calculating the breaking work. The experiment was repeated three times or more and the average was calculated. The results are shown in FIG. 3. The measurement results of fig. 3 show that:

a) the stretch-breaking work of A, B, C three groups of hair strands coated with the hair conditioner of the embodiments 1-3 can reach or even exceed that of hair strands S coated with a mousse hair conditioner with better market sales;

b) the snap of the hair strand A, B, C coated with the conditioners of examples 1-3 was greater than the percentage of the composition of the comparative example lacking or out of range of a certain composition of hair strand D, E, F, G, H, I, J, K, L, M, N, O, P, Q, R;

c) in summary, the hair strands using the conditioners of examples 1 to 3 had better snap-off performance than hair strands lacking a certain component or not within the range, and on the other hand, had advantages over commercially available mousse conditioners in terms of snap-off performance. In conclusion, after the composition disclosed by the invention is used for damaged hair strands, the strength and the toughness are improved to a certain extent, the tensile resistance is improved overall, and therefore the data obtained by the stretch-breaking power is larger.

3) Foam richness test

1. Testing an instrument: 2 100ml measuring cylinders.

2. The test method comprises the following steps:

in order to make the audience feel the richness of the hair conditioner more intuitively, the experiment compares the samples of example 1, example 2, example 3, comparative example 1, comparative example 2, comparative example 3, comparative example 4, comparative example 5, comparative example 6, comparative example 7, comparative example 8, comparative example 9, comparative example 10, comparative example 11, comparative example 12, comparative example 13, comparative example 14 and comparative example 15 with the commercial mousse hair conditioner, the sample of example 1 is pressed into a 100ml measuring cylinder by a 200-mesh foam pump head until the 100ml scale mark is reached, and the commercial mousse hair conditioner is pressed into another 100ml measuring cylinder until the 100ml scale mark is reached, and then the appearance of the foam and the change of the volume of the foam after 5min are recorded. The results are shown in FIG. 4. As can be seen from fig. 4: the double-layer bubble conditioners of examples 1-3 can achieve foam richness close to that of a commercially available mousse; after 5min the foam height difference of example 2 was 15ml compared to the foam height differences of comparative examples 1, 3, 15, with a phase difference of 23-25 ml; after 5min the difference in foam height of example 2 was 15ml compared to 12-13ml for comparative examples 2, 4; after 5min the foam height difference of example 2 was 15ml compared to 6-7ml for comparative examples 8, 11.

In conclusion, the foam richness of the double-layer bubble conditioner of the present embodiment is close to that of the commercially available mousse conditioner; one of cetrimide, behenyltrimethylammonium chloride and polyethylene glycol-14M in the formula is lacked, so that the richness of the foam can be greatly reduced; the foam height of the cetrimide, behenyltrimethylammonium chloride and polyethylene glycol-14M in the formula, which is lower than the component proportion in the range, can also be greatly influenced; the addition of the formula to the selected oil within a certain range has little influence on the foam richness of the hair conditioner, but when the selected oil is higher than the implementation range, the foam richness of the hair conditioner is reduced.

The experimental results of this example are summarized below:

1. after the hair conditioner is uniformly sprayed on the surface of damaged hair, the combing values of wet combing and dry combing of the hair are obviously reduced, which shows that the hair conditioner in the embodiments 1-3 can reduce the friction force on the surface of the hair and improve the smoothness and the frizziness degree of the damaged hair.

2. After the hair conditioner of the embodiment is continuously used for damaged hair, the stretch-resistant performance of the hair is obviously improved. The hair conditioner in the embodiments 1 to 3 can improve the binding force between hair fiber molecules, repair damaged hair scales and improve the toughness and strength of hair.

3. The double-layer milk cap is in a shape of milk cap, can be used after being shaken and mixed evenly, can extrude rich foam, increases the contact area of the hair care effective substance and the hair, and can meet the pursuit of young people for fashion.

The present invention is not limited to the above embodiments, and various changes can be made without departing from the spirit of the present invention within the knowledge of those skilled in the art. Furthermore, the embodiments of the present invention and the features of the embodiments may be combined with each other without conflict.

Claims

1. A hair conditioner comprises the following components: 0.5-2.5% of cetrimide, 0.5-2.5% of behenyl trimethyl ammonium chloride, 5-20% of hydrogenated polyisobutene, 2-8% of octyldodecanol myristate, 0.5-2.5% of C12-13 alcohol lactate, 0.2-3% of alkyl, 0.5-2.5% of sodium isostearoyl lactylate, 0.2-2% of polyethylene glycol-14M, 0.01-0.3% of chelating agent, 0.01-0.8% of preservative, 0.01-4% of conditioner B and 0.2-1% of aromatic.

2. The hair conditioner according to claim 1, wherein the conditioner B is at least one selected from the group consisting of polyquaternium-52, PPG-3 octyl ether, camellia oil, sodium hyaluronate, complex amino acids, and camellia extract.

3. The hair conditioner according to claim 2, wherein the complex amino acid is at least one selected from the group consisting of arginine, aspartic acid, glycine, serine and proline.

4. The hair conditioner of claim 1, wherein the alkane is selected from at least one of undecane and tridecane.

5. The hair conditioner of claim 1, wherein the chelating agent is disodium EDTA.

6. The hair conditioner of claim 1, wherein the preservative is selected from at least one of sodium benzoate and phenoxyethanol.

7. The hair conditioner of claim 1, wherein the fragrance is a perfume.

8. A process for preparing a hair conditioner according to any of claims 1 to 7, comprising the steps of:

9. The method of claim 8, wherein the step S1 is performed in an emulsification pan.

10. The method according to claim 8, wherein the stirring of step S1 is homogeneous stirring.