CN1135512A - Aqueous emulsion paper-plastic composite adhesive - Google Patents
Aqueous emulsion paper-plastic composite adhesive Download PDFInfo
- Publication number
- CN1135512A CN1135512A CN 95111360 CN95111360A CN1135512A CN 1135512 A CN1135512 A CN 1135512A CN 95111360 CN95111360 CN 95111360 CN 95111360 A CN95111360 A CN 95111360A CN 1135512 A CN1135512 A CN 1135512A
- Authority
- CN
- China
- Prior art keywords
- plastic composite
- aqueous emulsion
- paper
- composite adhesive
- emulsion paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The water-soluble emulsion liquid type composite adhesive for paper and plastics is made up by using water as disperse medium in the presence of emulsifying agent, using acrylic monomer, phenylethylene and vinyl cyanide, adding initiating agent, and making them implement co-polymerization reaction. Its solid content is 50%, and use parameters are approaching to that of existent solvent adhesive. Said composite adhesive is non-toxic, fire-retardant and low in cost.
Description
The present invention relates to a kind of is the aqueous emulsion paper-plastic composite adhesive of the acrylic ester polymer system of dispersion medium with water, as various paper and color printing goods and polyester film, biaxially oriented polypropylene film, polymeric films such as polychloroethylene film compound, mixture are mainly used in the high gear packing or decorate.
Paper is compound to be one of trend of modern papery packing development, by paper with mould compound, can make packaging external appearance splendid, and antifouling, anti-tear resistance to compression is widely used in aspects such as various gift boxs, wall calendar, book cover and publicity materials.Chinese patent CN90106727.X, CN1049172A report a kind of low toxicity and mount glue, and it is compound to be mainly used in paper.Its main component is SBS, obedient alkene, vinyl acetic monomer, 120
#Gasoline, hexanaphthene, DBP, this product has certain representativeness in the market, it is to make the dispersion medium system with organic solvent, and is inflammable, stores transportation inconvenience, the cost height, certain toxicity is arranged, and working concentration is about 20%, and 80% organic solvent enters in the air, contaminate environment, application is restricted.Li Xuefang, Huang Weiguang " chemistry is with bonding ", № 3,141-144,1990.The document is reported a kind of thermally melting paper composite gum, and this product has been avoided solvent contamination effectively, but adaptive surface is narrow, is mainly used in the compound of kraft paper and Polywoven Bag, uses the equipment manufacturing cost costliness of this glue.The dry method coating machine can not use this glue at all.Therefore, do not see that it obtains application on paper is compound yet.Also have CN 1067065A " water base starch paper plastic adhesives " report in addition, this patent adds oxygenant, alkali, acid, new modified dose and thickening material, but does not see that in fact such launch products is arranged based on plant amylum.
The objective of the invention is provides a kind of aqueous emulsion paper-plastic composite adhesive at the deficiencies in the prior art; it is to be dispersion medium with water in the presence of emulsifying agent; add initiator by acrylic monomer and vinylbenzene and vinyl cyanide and carry out copolymerization; the aqueous emulsion paper-plastic composite adhesive that makes; solid content is 50%; its suitable type is identical with present solvent cement; just use parameter close; be the regeneration product of ideal solvent cement, it has thoroughly overcome the toxic of solvent cement, and is inflammable and explosive; contaminate environment; shortcomings such as cost height have improved economic benefit, for due contribution has been made in environment protection.
Aqueous emulsion paper-plastic composite adhesive provided by the invention, the recipe ingredient of its starting raw material (by weight) is:
Acrylic ester monomer (available vinylformic acid, ethyl propenoate, the mixture of one or more of butyl acrylate and the different monooctyl ester of vinylformic acid 2-) 60-92 part
Vinyl cyanide 2-10 part
Vinylbenzene 2-10 part
Emulsifying agent (available sodium lauryl sulphate, sodium lauryl sulfate, Sodium dodecylbenzene sulfonate, OP-8, the mixture of one or more of OP-9 and OP-10) 1.2-5 part
Initiator (available ammonium persulphate, Potassium Persulphate or Sodium Persulfate) 0.6-2 part
Water 150-300 part
With each starting raw material weighing in the above-mentioned prescription, in the reactor that has agitator, condenser and thermometer, add tap water, emulsifying agent earlier, stir, be warming up to about 75 ℃, add the aqueous solution of monomer and initiator simultaneously slowly, add in 2～3 hours, be warmed up to 80-82 ℃ and kept polymerization time 1-2 hours, be cooled to room temperature, be neutralized to PH=7-8, filter impurity with ammoniacal liquor, obtain aqueous emulsion paper-plastic composite adhesive, solid content is 50%.
Aqueous emulsion paper-plastic composite adhesive has good adhesive power to polymeric film and paper printing ink, and composite effect is good, mixture gloss＞89, and stripping strength＞Hard copy body intensity, wrinkle resistant through 15 centimetres of 25W infrared lamps irradiation 15 minutes, not delamination, nondiscoloration.
The present invention has following advantage:
1. aqueous emulsion paper-plastic composite adhesive is nontoxic, safety, and cost is low, and is easy to use, and it is the desirable regeneration product of present solvent cement stick.
2. the aqueous emulsion paper-plastic composite adhesive solid content is 50%, solvent then is about 35%, the comprehensive production cost of aqueous emulsion type is 8500-9000 unit/ton, solvent-borne type glue price is 12000-16000 unit/ton, according to estimating about 50,000 tons of national glue consumption in 94 years, visible the present invention has remarkable economic efficiency and social benefit.
3. aqueous emulsion paper-plastic composite adhesive is coated with dried glue amount approximately: art paper 2-3 gram/rice
2, rubber plate paper 3-4 gram/rice
2The compound paper of splitting per ton, 200,000 of rubber plate papers, 250,000 of art papers, the organic solvent diluting of necessary adding 1/3 before the solvent cement use per ton, multiple film number (folio) per ton is about: 200,000 of art papers, 14.4 ten thousand of rubber plate papers, there are a large amount of organic solvents (about 800 kilograms per ton) to diffuse in the air simultaneously, serious environment pollution and diminish workers ' health.
Embodiment:
1. with 150 kilograms in tap water, 2 kilograms of sodium lauryl sulphate, the OP-103 kilogram is added in and has agitator, in the reactor of condenser and thermometer, stir, be warming up to about 75 ℃; get 1025 kilograms of butyl acrylates; 125 kilograms of the different monooctyl esters of vinylformic acid 2-; 125 kilograms in vinylformic acid, 5 kilograms of vinyl cyanide, 5 kilograms of vinylbenzene; and 1.7 kilograms of ammonium persulphates are dissolved in 100 kilograms the water; then mix monomer and initiator solution are added in the reactor slowly, add in 2-3 hours, be warming up to 80-82 ℃; kept polymerization time 1-2 hours; be cooled to room temperature, be neutralized to PH=7-8, filter impurity; obtain aqueous emulsion paper-plastic composite adhesive, solid content is 50% with ammoniacal liquor.
2. with 150 kilograms in tap water, 2 kilograms of Sodium dodecylbenzene sulfonatees, the OP-93 kilogram adds in the previous reaction still, stir, be warming up to 75 ℃, get 125 kilograms of the different monooctyl esters of vinylformic acid-2,70 kilograms of ethyl propenoates, 12.5 kilograms of vinyl cyanide, 17.5 kilograms in vinylformic acid, 25 kilograms and 1.7 kilograms Potassium Persulphates of vinylbenzene are dissolved in 100 kg of water, slowly add mix monomer and initiator solution in the reactor then, add in 2-3 hours, be warming up to 80-82 ℃, kept polymerization time 1-2 hours, be cooled to room temperature, be neutralized to PH=7-8 with ammoniacal liquor, filter impurity, obtain the aqueous emulsion paper-plastic composite adhesive of 50% solid content.
3. with 150 kilograms in tap water, 2 kilograms of sodium lauryl sulfates, the OP-83 kilogram adds in the previous reaction still, stir, be warming up to 75 ℃; get 162.5 kilograms of the different monooctyl esters of vinylformic acid-2,37.5 kilograms in vinylformic acid, 25 kilograms of vinyl cyanide; 25 kilograms and 1.7 kilograms Sodium Persulfates of vinylbenzene are dissolved in 100 kg of water; then mix monomer and initiator solution are added in the reactor slowly, add in 2-3 hours, be warming up to 80-82 ℃; kept polymerization time 1-2 hour; be cooled to room temperature, be neutralized to PH=7-8, filter impurity; obtain the aqueous emulsion paper-plastic composite adhesive of 50% solid content with ammoniacal liquor.
Claims (5)
1. aqueous emulsion paper-plastic composite adhesive is characterized in that the recipe ingredient (by weight) of this aqueous emulsion paper-plastic composite adhesive starting raw material is:
Acrylic ester monomer 60-92 part
Vinyl cyanide 2-10 part
Vinylbenzene 2-10 part
Emulsifying agent 1.2-3 part
Initiator 0.1-2 part
Water 150-300 part
2. according to the described aqueous emulsion paper-plastic composite adhesive of claim 1, the acrylic ester monomer that it is characterized in that this tackiness agent is a vinylformic acid, ethyl propenoate, butyl acrylate, the mixture of one or more of the different monooctyl ester of vinylformic acid 2-.
3. according to claim 1 or 2 described aqueous emulsion paper-plastic composite adhesives, the emulsifying agent that it is characterized in that this tackiness agent is one or more a mixture of sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, sodium lauryl sulfate, OP-8, OP-9, OP-10.
4. according to claim 1 or 2 described aqueous emulsion paper-plastic composite adhesives, the initiator that it is characterized in that this tackiness agent is ammonium persulphate, Potassium Persulphate or Sodium Persulfate.
5. according to the preparation method of the described aqueous emulsion paper-plastic composite adhesive of claim 1, it is characterized in that:
In the reactor that has agitator, condenser and thermometer, add ordinary tap water, emulsifying agent earlier, stirring is warming up to about 75 ℃, adds mix monomer and initiator simultaneously slowly, add in about 2-3 hour, be warming up to 80-82 ℃, kept polymerization time 1-2 hour, be cooled to room temperature, be neutralized to PH=7-8 with ammoniacal liquor, impurity screening obtains paper-plastic composite adhesive, and solid content is 50%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95111360 CN1135512A (en) | 1995-05-12 | 1995-05-12 | Aqueous emulsion paper-plastic composite adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95111360 CN1135512A (en) | 1995-05-12 | 1995-05-12 | Aqueous emulsion paper-plastic composite adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1135512A true CN1135512A (en) | 1996-11-13 |
Family
ID=5078658
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 95111360 Pending CN1135512A (en) | 1995-05-12 | 1995-05-12 | Aqueous emulsion paper-plastic composite adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1135512A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109085C (en) * | 2000-06-13 | 2003-05-21 | 湖北省化学研究所 | Multi-component copolymer acrylate adhesive, its preparation method and application for covering aluminium plate with polyimide |
| CN1304693C (en) * | 2005-01-04 | 2007-03-14 | 浙江大学 | Automobile engine filter paper immersion resin emusion and preparation method thereof |
| CN1311041C (en) * | 2004-02-17 | 2007-04-18 | 南京林业大学 | High molecule compound of aldehyde-free adhesives for producing artificial board |
| CN1313555C (en) * | 2004-02-17 | 2007-05-02 | 南京林业大学 | Aldehyde-free adhesives for artificial board |
| CN103146327A (en) * | 2013-04-07 | 2013-06-12 | 王义奎 | Method for preparing adhesive used for timber |
| CN104893628A (en) * | 2015-06-30 | 2015-09-09 | 广西金虹环保包装科技有限公司 | Paper-plastic lamination adhesive and preparation method therefor |
| CN105418834A (en) * | 2015-12-29 | 2016-03-23 | 廊坊市北辰创业树脂材料有限公司 | Paper-plastic aqueous adhesive and preparation method thereof |
-
1995
- 1995-05-12 CN CN 95111360 patent/CN1135512A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109085C (en) * | 2000-06-13 | 2003-05-21 | 湖北省化学研究所 | Multi-component copolymer acrylate adhesive, its preparation method and application for covering aluminium plate with polyimide |
| CN1311041C (en) * | 2004-02-17 | 2007-04-18 | 南京林业大学 | High molecule compound of aldehyde-free adhesives for producing artificial board |
| CN1313555C (en) * | 2004-02-17 | 2007-05-02 | 南京林业大学 | Aldehyde-free adhesives for artificial board |
| CN1304693C (en) * | 2005-01-04 | 2007-03-14 | 浙江大学 | Automobile engine filter paper immersion resin emusion and preparation method thereof |
| CN103146327A (en) * | 2013-04-07 | 2013-06-12 | 王义奎 | Method for preparing adhesive used for timber |
| CN103146327B (en) * | 2013-04-07 | 2016-01-06 | 王义奎 | A kind of preparation method of adhesive for wood |
| CN104893628A (en) * | 2015-06-30 | 2015-09-09 | 广西金虹环保包装科技有限公司 | Paper-plastic lamination adhesive and preparation method therefor |
| CN105418834A (en) * | 2015-12-29 | 2016-03-23 | 廊坊市北辰创业树脂材料有限公司 | Paper-plastic aqueous adhesive and preparation method thereof |
| CN105418834B (en) * | 2015-12-29 | 2021-01-29 | 廊坊市北辰创业树脂材料股份有限公司 | Paper-plastic water-based adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101362929B (en) | Emulsion type adhesive for paper and plastics and preparation method thereof | |
| CN101649153B (en) | Organic silicon modified acrylic ester aqueous wood lacquer latex and synthesizing method thereof | |
| CN1959530B (en) | Ultraviolet light solidified coating in use for post processing of imaging material | |
| CN1082522C (en) | Tackified emulsion pressure-sensitive adhesive | |
| EP2167599B1 (en) | Colored acrylic adhesive and marking film | |
| CN101260259B (en) | Ink resin used for intaglio printing and preparation method thereof | |
| CN102585157B (en) | Ultraviolet light polymerization polyfunctionality polyurethane acrylate vacuum coating surface coating resin | |
| CN104263292B (en) | A kind of aqueous laminated adhesive stick and preparation method thereof | |
| CN102464938B (en) | Plastic cement list is coated with painted UV radiation curable coating and production thereof, using method | |
| CN1800225A (en) | Latex type hydroxy acryl acid resin possessing core-shell configuration | |
| CN103059211B (en) | Vinyl acetate-acrylate copolymer emulsion, its synthesis method and application | |
| CN108059858A (en) | It is a kind of suitable for coloring coating of silver color alumite thermoprinting foil and preparation method thereof | |
| CN108977134A (en) | A kind of environment-friendly water-based Laminating adhesive and preparation method thereof that cohesive force is strong | |
| CN112322092B (en) | Alumite coloring layer coating with high wrapping capacity and preparation method thereof | |
| CN101457026A (en) | Molded body having matt and structured surface properties | |
| CN1135512A (en) | Aqueous emulsion paper-plastic composite adhesive | |
| CN102899961A (en) | Novel environment-friendly paper surface glazing finishing emulsion and preparation method thereof | |
| CN104152084A (en) | High temperature-resistant low viscosity pressure-sensitive adhesive used for protection films, and preparation method and application thereof | |
| CN102732192A (en) | Emulsion acrylate pressure-sensitive adhesive, preparation method and application thereof | |
| CN107690459A (en) | A kind of compound ink coating of PVC tables/the inside printing heat | |
| CN103525293A (en) | Non-yellowing UV (Ultraviolet) gloss oil as well as preparation method thereof | |
| CN101921374B (en) | Preparation method of polyacrylate-polyurethane resin binder for single-fluid general plastic gravure alcohol-soluble and water-soluble composite ink | |
| CN1263921A (en) | Ultraviolet curing coating composite for cation electro-deposition | |
| CN102260475A (en) | Method for making environment-friendly pressure sensitive adhesive material | |
| CN110655618A (en) | Strong acid and strong base resistant and flame retardant pressure-sensitive adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |