CN107690459A - A kind of compound ink coating of PVC tables/the inside printing heat - Google Patents
A kind of compound ink coating of PVC tables/the inside printing heat Download PDFInfo
- Publication number
- CN107690459A CN107690459A CN201680027456.4A CN201680027456A CN107690459A CN 107690459 A CN107690459 A CN 107690459A CN 201680027456 A CN201680027456 A CN 201680027456A CN 107690459 A CN107690459 A CN 107690459A
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- China
- Prior art keywords
- pvc
- water
- ink coating
- acrylic resin
- following component
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of compound ink coating of PVC tables/the inside printing heat, it is calculated by weight percentage, is made up of following component and content：Acrylic resin 50% 70%；Pigment 8% 25%；Levelling agent 1% 3%；Dispersant 3% 8%；Wetting agent 3% 8%；Water surplus；The acrylic resin is made up of following component：Acrylic acid 5% 25%；Methyl methacrylate 10% 20%；Butyl acrylate 6% 15%；Isooctyl acrylate monomer 1% 5%；The benzoyl peroxide tert-butyl ester 1% 5%；Water 10% 30%；Ethanol 20% 40%.The present invention only needs, by the use of water as solvent, environmental sound, to print adjustment of the printing plate clear layer, bright-colored, thermal-adhering fastness is high.
Description
Technical field
The present invention relates to a kind of ink coating, and in particular to a kind of compound ink coating of PVC tables/the inside printing heat.
Background technology
Corvic (PVC) is one of earliest resins for universal use for realizing that industrialization, yield are larger, in material engineering
Occupy conclusive critical role.PVC has the premium properties such as fire-retardant, corrosion-resistant, insulation, wear-resistant, cheap, former material
Expect that wide material sources are a kind of important thermoplastics.It has good mechanical property and the transparency to PVC, medicine, food,
Packaging field is widely used.Common PVC film (pipe), the PVC tablecloths, PVC outdoor advertisings film, PVC seal, PVC vessel, PVC
Packaging of article etc. more come the more need PVC surface ink print.
For example, as people are increasing to the demand for decorating household, environment-friendly materials are also increasingly paid attention to.Traditional
Household industry decorating film prints decorations layer using PVC film as base material using solvent-based ink.And in order to improve PVC film as printing
Base material and the performance for being bonded facial mask, such as require that PVC film transparency is high, intensity is big, it is good to be resistant to low high temperature, tack, it is certain to have
Oxygen flow and moisture-inhibiting ability etc., it is necessary to add substantial amounts of plasticizer, stabilizer, while one can be remained during PVC film is produced
Quantitative monomer and catabolite, these chlorizates decomposed can form niff after discharging, and human body is made
Into a variety of harm.The auxiliary agent for having harm reported at present is primarily used to the phthalate and antioxidant pair of plasticizer
Solvent (benzene, ester, ketone) in phenol A and printing-ink etc..
VOC (VOC) is acknowledged as one of primary pollution source of current global atmosphere pollution, solvent-borne type oil
Ink can give out substantial amounts of low concentration VOC.And due to the characteristic that PVC film has in itself by its material, it is unintelligible such as to print adjustment of the printing plate
It is not high with thermal-adhering fastness, it also limit the development of PVC inks.
The content of the invention
In order to solve the above technical problems, it is an object of the invention to propose a kind of adjustment of the printing plate clear layer, bright-colored, heat posted
Close the high compound ink coating of PVC tables/the inside printing heat of fastness.
Used technical scheme is：
A kind of compound ink coating of PVC tables/the inside printing heat, is calculated, it is by following component and content groups by weight percentage
Into：
Acrylic resin 50%-70%；
Pigment 8%-25%；
Levelling agent 1%-3%；
Dispersant 3%-8%；
Wetting agent 3%-8%；
Water surplus；
The acrylic resin is calculated by weight percentage, and it is made up of following component：
Acrylic acid 5%-25%；
Methyl methacrylate 10%-20%；
Butyl acrylate 6%-15%；
Isooctyl acrylate monomer 1%-5%；
Benzoyl peroxide tert-butyl ester 1%-5%；
Water 10%-30%；
Ethanol 20%-40%.
Further, the pigment is titanium dioxide and/or carbon black.
Further, the compound ink coating of PVC tables/the inside printing heat is made up of following component and content：
Acrylic resin 60%；
Pigment 8%-25%；
Levelling agent 2%；
Dispersant 5%；
Wetting agent 5%；
Water surplus.
Further, the acrylic resin is made up of following component：
Acrylic acid 20%；
Methyl methacrylate 15%；
Butyl acrylate 10%；
Isooctyl acrylate monomer 2%；
The benzoyl peroxide tert-butyl ester 3%；
Water 20%；
Ethanol 30%.
The beneficial effects of the present invention are：
The present invention only needs, by the use of water as solvent, environmental sound, to print adjustment of the printing plate clear layer, bright-colored, thermal-adhering
Fastness is high.
Embodiment
The present invention is clearly and completely described below, makes the purpose of the present invention, technical scheme and effect more clear
Chu, clearly.It should be appreciated that embodiment is not used to protection domain being defined in this to explain the present invention.
The compound ink coating of PVC tables/the inside printing heat of the present invention, is calculated, it is by following component and contains by weight percentage
Amount composition：
Acrylic resin 50%-70%；
Pigment 8%-25%；
Levelling agent 1%-3%；
Dispersant 3%-8%；
Wetting agent 3%-8%；
Water surplus.
In the component of the compound ink coating of PVC tables/the inside printing heat, acrylic resin is calculated by weight percentage, by
Following component is made：
Acrylic acid 5%-25%；
Methyl methacrylate 10%-20%；
Butyl acrylate 6%-15%；
Isooctyl acrylate monomer 1%-5%；
Benzoyl peroxide tert-butyl ester 1%-5%；
Water 10%-30%；
Ethanol 20%-40%.
In the component of acrylic resin, the effect of acrylic acid is that water solubility can be increased, methyl methacrylate
Effect is that can provide group increases hardness, and the effect of butyl acrylate can increase pliability and water solubility；Acrylic acid is different
The effect of monooctyl ester is to increase adhesive force, and the effect of the benzoyl peroxide tert-butyl ester (TBPB) is to trigger as initiator
Monomer reaction；The effect of water is as solvent.The effect of ethanol is in the mixing in water between component is increased.
This acrylic resin is aggregated by acrylic acid, methyl methacrylate, butyl acrylate and Isooctyl acrylate monomer
React and be made, using the benzoyl peroxide tert-butyl ester as initiator, ethanol is cosolvent, using water as solvent.
This acrylic resin due to having the advantages that good weatherability, cementability, light resistance and filming performance, with
Other components, which coordinate, can efficiently solve that common water borne ink thermal-adhering fastness in PVC base is not high and adjustment of the printing plate is unsharp asks
Topic.The mean molecule quantity of this acrylic resin is moderate, between 10000-20000, printing adjustment of the printing plate can be made clear not sticky；
The thermoplasticity of this acrylic resin is preferable, and the thermal-adhering fastness of printing can be made high.
Pigment can for example select titanium dioxide and/or carbon black, can carry out black and white printing.Certain pigment can also select it
His color, such as the resistance to turn to red because of sun burn of lily chemical industry, everbright fast yellow, blue or green blue etc..
Levelling agent can for example select dimethyl silicone polymer class levelling agent, and it can increase glossiness, make printing levelling
Property is more preferable.
Dispersant can for example select glyceryl monostearate class dispersant, and it makes acrylic resin scattered evenly,
Make the printing uniformity more preferable.
Wetting agent for example can be using selective wetting levelling agent as acetylenic glycols Shuangzi based surfactants, and its role is to make this water
Property printing ink paint is more preferably attached on PVC film or base material.
Water makees dissolving carrier, either in its production process, when being also used to printing, is hardly distributed to air
VOC.This be solvent-based ink it is incomparable.
The preparation method of the compound ink coating of PVC tables/the inside printing heat of the present invention is as follows：
S1. acrylic resin is prepared：
After adding water, ethanol in a kettle, acrylic acid, methyl methacrylate, butyl acrylate and acrylic acid are added
Different monooctyl ester, leads to nitrogen protection, and 90 DEG C will be warming up in reactor using steam, adds the initiator benzoyl peroxide tert-butyl ester,
Initiated polymerization, 90-110 DEG C of controlling reaction temperature, after reacting 3-5 hours, then 10 hours insulation slow reactions are controlled, produced
Acrylic resin.
S2. it is equal acrylic resin, pigment, levelling agent, dispersant and wetting agent that weighing is got ready to be added to the water stirring
It is even.
Further illustrated below by embodiment.
Embodiment 1
The compound ink coating of PVC tables/the inside printing heat of the present embodiment, calculates, by following component and contains by weight percentage
Amount composition：
Acrylic resin 60%；
Pigment 10%；
Levelling agent 2%；
Dispersant 5%；
Wetting agent 5%；
Water surplus.
Acrylic resin is made up of following component：
Acrylic acid 20%；
Methyl methacrylate 15%；
Butyl acrylate 10%；
Isooctyl acrylate monomer 2%；
The benzoyl peroxide tert-butyl ester 3%；
Water 20%；
Ethanol 30%.
Preparation method is with reference to S1 the and S2 steps of method prepared above, and here is omitted.
Embodiment 2
Reference embodiment 1, as different from Example 1, the compound ink coating of PVC tables/the inside printing heat of the present embodiment,
Calculate, be made up of following component and content by weight percentage：
Acrylic resin 50%；
Pigment 15%；
Levelling agent 3%；
Dispersant 6%；
Wetting agent 6%；
Water surplus.
Embodiment 3
Reference embodiment 1, as different from Example 1, the compound ink coating of PVC tables/the inside printing heat of the present embodiment,
Calculate, be made up of following component and content by weight percentage：
Acrylic resin 70%；
Pigment 10%；
Levelling agent 2%；
Dispersant 3%；
Wetting agent 3%；
Water surplus.
By the compound ink coating of PVC tables/the inside printing heat made from embodiment 1- embodiments 3, performance test is carried out.
Printed with the compound ink coating of PVC tables/the inside printing heat on PVC outdoor advertising films, using gravure rotary printing,
Then 30 users are randomly choosed, whether evaluation adjustment of the printing plate is clear, is chosen as A if clear, B is chosen as if slightly hazy, such as
Fruit is very unintelligible, is chosen as C.
Test result is：All users are evaluated as A.
Thermal-adhering fastness and adhesive force correlation.By GB/T13217.7-2009《Liquid ink attachment fastness is examined
Proved recipe method》Water-based ink adhesive force is carried out to the compound ink coating of PVC tables/the inside printing heat made from above-described embodiment 1-3
It can test, its test result such as table 1 below：
Table 1
| Test sample | Ink attachment fastness (%) |
| Embodiment 1 | 99.5 |
| Embodiment 2 | 99.3 |
| Embodiment 3 | 99.2 |
Test result is that the compound ink coating of PVC tables/the inside printing heat that the present invention prepares has preferable thermal-adhering
Fastness.
Those listed above is a series of to describe illustrating only for possible embodiments of the invention in detail,
They simultaneously are not used to limit the scope of the invention, all equivalent embodiments made without departing from skill spirit of the present invention or change
It should be included in the scope of the protection.
Claims (4)
1. a kind of compound ink coating of PVC tables/the inside printing heat, it is characterised in that calculate by weight percentage, it is by following component
Formed with content：
Acrylic resin 50%-70%；
Pigment 8%-25%；
Levelling agent 1%-3%；
Dispersant 3%-8%；
Wetting agent 3%-8%；
Water surplus；
The acrylic resin is calculated by weight percentage, and it is made up of following component：
Acrylic acid 5%-25%；
Methyl methacrylate 10%-20%；
Butyl acrylate 6%-15%；
Isooctyl acrylate monomer 1%-5%；
Benzoyl peroxide tert-butyl ester 1%-5%；
Water 10%-30%；
Ethanol 20%-40%.
2. the compound ink coating of PVC tables/the inside printing heat according to claim 1, it is characterised in that the pigment is titanium
White powder and/or carbon black.
3. the compound ink coating of PVC tables/the inside printing heat according to claim 1, it is characterised in that it is by following component
Formed with content：
Acrylic resin 60%；
Pigment 8%-25%；
Levelling agent 2%；
Dispersant 5%；
Wetting agent 5%；
Water surplus.
4. the compound ink coating of PVC tables/the inside printing heat according to claim 1, it is characterised in that the acrylic compounds
Resin is made up of following component：
Acrylic acid 20%；
Methyl methacrylate 15%；
Butyl acrylate 10%；
Isooctyl acrylate monomer 2%；
The benzoyl peroxide tert-butyl ester 3%；
Water 20%；
Ethanol 30%.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2016/113495 WO2018120018A1 (en) | 2016-12-30 | 2016-12-30 | Thermally composite water-based ink coating for printing exterior/interior of pvc |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107690459A true CN107690459A (en) | 2018-02-13 |
Family
ID=61152326
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680027456.4A Pending CN107690459A (en) | 2016-12-30 | 2016-12-30 | A kind of compound ink coating of PVC tables/the inside printing heat |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN107690459A (en) |
| WO (1) | WO2018120018A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108822619A (en) * | 2018-06-06 | 2018-11-16 | 苏州华尔美特装饰材料股份有限公司 | A kind of seamless hard wallpaper printing layer ink |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116004054A (en) * | 2022-09-14 | 2023-04-25 | 东莞德芳油墨科技有限公司 | Environment-friendly water-based printing ink and preparation method thereof |
| CN115612416A (en) * | 2022-09-27 | 2023-01-17 | 无锡市喜飞翔科技有限公司 | Preparation method of special adhesive tape for PVC (polyvinyl chloride) floor |
| CN116875119B (en) * | 2023-07-25 | 2024-02-27 | 中山永辉化工股份有限公司 | Paint composition and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286235A (en) * | 2010-06-17 | 2011-12-21 | 纬创资通股份有限公司 | Water-based single solution type coating and method for forming a high lustrous coating layer by using the same |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9051485B2 (en) * | 2010-04-27 | 2015-06-09 | Konica Minolta, Inc. | Inkjet ink and inkjet recording method |
| CN102382506B (en) * | 2011-08-02 | 2013-11-06 | 周贤永 | Water-soluble environmentally-friendly gravure ink and preparation method thereof |
| JP6234221B2 (en) * | 2012-12-27 | 2017-11-22 | ジャパンコーティングレジン株式会社 | Acrylic resin emulsion for aqueous inkjet ink, and aqueous inkjet ink composition using the same |
| CN104031202B (en) * | 2014-06-17 | 2016-05-25 | 中国科学院化学研究所 | Polyacrylic acid ink resin and preparation method thereof |
| CN105622827A (en) * | 2014-11-28 | 2016-06-01 | 王栩 | Preparation method of liquid water-soluble resin |
| CN105315781B (en) * | 2015-02-12 | 2018-08-31 | 上海荟百精细化工有限公司 | Aqueous golden ink of a kind of quick-dry type and preparation method thereof |
-
2016
- 2016-12-30 CN CN201680027456.4A patent/CN107690459A/en active Pending
- 2016-12-30 WO PCT/CN2016/113495 patent/WO2018120018A1/en active Application Filing
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286235A (en) * | 2010-06-17 | 2011-12-21 | 纬创资通股份有限公司 | Water-based single solution type coating and method for forming a high lustrous coating layer by using the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108822619A (en) * | 2018-06-06 | 2018-11-16 | 苏州华尔美特装饰材料股份有限公司 | A kind of seamless hard wallpaper printing layer ink |
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| Publication number | Publication date |
|---|---|
| WO2018120018A1 (en) | 2018-07-05 |
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Application publication date: 20180213 |
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