CN113520057A - Bacteriostatic and peculiar smell-removing adjustable type sliding-door shoe cabinet and production process thereof - Google Patents
Bacteriostatic and peculiar smell-removing adjustable type sliding-door shoe cabinet and production process thereof Download PDFInfo
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- CN113520057A CN113520057A CN202110944913.9A CN202110944913A CN113520057A CN 113520057 A CN113520057 A CN 113520057A CN 202110944913 A CN202110944913 A CN 202110944913A CN 113520057 A CN113520057 A CN 113520057A
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- Prior art keywords
- shoe cabinet
- placing
- plate
- sliding
- bacteriostatic
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 230000003385 bacteriostatic effect Effects 0.000 title claims description 31
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 44
- 238000004332 deodorization Methods 0.000 claims abstract description 14
- 238000005192 partition Methods 0.000 claims abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 238000003756 stirring Methods 0.000 claims description 30
- 239000002781 deodorant agent Substances 0.000 claims description 21
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 20
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 14
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 14
- 238000001291 vacuum drying Methods 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000009210 therapy by ultrasound Methods 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 8
- 239000007795 chemical reaction product Substances 0.000 claims description 8
- 229910017604 nitric acid Inorganic materials 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 claims description 7
- KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 claims description 7
- 239000005048 methyldichlorosilane Substances 0.000 claims description 7
- 239000012459 cleaning agent Substances 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 6
- 230000010355 oscillation Effects 0.000 claims description 5
- 230000007306 turnover Effects 0.000 claims description 5
- GOLSFPMYASLXJC-UHFFFAOYSA-N 2-(dimethylamino)ethyl acetate Chemical compound CN(C)CCOC(C)=O GOLSFPMYASLXJC-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 3
- 230000000149 penetrating effect Effects 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 15
- 230000008569 process Effects 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 6
- 239000000243 solution Substances 0.000 description 14
- 241000894006 Bacteria Species 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 9
- 230000001877 deodorizing effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000012065 filter cake Substances 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000000748 compression moulding Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000002390 rotary evaporation Methods 0.000 description 2
- 238000003828 vacuum filtration Methods 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- BGCNBOFPABQGNG-UHFFFAOYSA-N ethyl 2-(dimethylamino)acetate Chemical compound CCOC(=O)CN(C)C BGCNBOFPABQGNG-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000011012 sanitization Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B61/00—Wardrobes
- A47B61/04—Wardrobes for shoes, hats, umbrellas, or the like
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B57/00—Cabinets, racks or shelf units, characterised by features for adjusting shelves or partitions
- A47B57/04—Cabinets, racks or shelf units, characterised by features for adjusting shelves or partitions with means for adjusting the inclination of the shelves
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B57/00—Cabinets, racks or shelf units, characterised by features for adjusting shelves or partitions
- A47B57/06—Cabinets, racks or shelf units, characterised by features for adjusting shelves or partitions with means for adjusting the height of the shelves
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B96/00—Details of cabinets, racks or shelf units not covered by a single one of groups A47B43/00 - A47B95/00; General details of furniture
- A47B96/02—Shelves
- A47B96/025—Shelves with moving elements, e.g. movable extensions or link elements
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B96/00—Details of cabinets, racks or shelf units not covered by a single one of groups A47B43/00 - A47B95/00; General details of furniture
- A47B96/06—Brackets or similar supporting means for cabinets, racks or shelves
- A47B96/07—Brackets or similar supporting means for cabinets, racks or shelves adjustable in themselves
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B97/00—Furniture or accessories for furniture, not provided for in other groups of this subclass
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27M—WORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
- B27M1/00—Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching
- B27M1/02—Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching by compressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27M—WORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
- B27M3/00—Manufacture or reconditioning of specific semi-finished or finished articles
- B27M3/18—Manufacture or reconditioning of specific semi-finished or finished articles of furniture or of doors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Veterinary Medicine (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Forests & Forestry (AREA)
- Dentistry (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Toxicology (AREA)
- Manufacturing & Machinery (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses an antibacterial and peculiar smell-removing adjustable sliding-door shoe cabinet and a production process thereof, and relates to the field of furniture, wherein the adjustable sliding-door shoe cabinet comprises a shoe cabinet body, a shoe cabinet door, a partition plate, a placing plate, an antibacterial and peculiar smell-removing plate and an exhaust fan, the height of the placing plate can be adjusted according to shoes, the adjustable sliding-door shoe cabinet is suitable for placing shoes with different heights, the angle of the placing plate can be adjusted at will, the placing plate can be cleaned quickly, the sanitation of the shoe cabinet can be maintained, the adjustable sliding-door shoe cabinet is also suitable for placing shoes for users with different heights, and the use effect is improved; the start-up air discharge fan drives the air current and flows, and the air current carries the smell circulation of shoes release through the inner chamber of placing the board, is detached the peculiar smell and is disinfected by antibacterial deodorization board, accomplishes antibacterial deodorization process to promote this adjustable turns over a shoes cabinet antibacterial, remove the peculiar smell effect.
Description
Technical Field
The invention relates to the field of furniture, in particular to an adjustable type hinged-door shoe cabinet with functions of bacteriostasis and peculiar smell removal and a production process thereof.
Background
In daily household life, the quantity and quality of shoes are continuously increasing and becoming higher, and the importance of putting and placing the shoes is becoming more and more important; although the existing shoe cabinet is provided with the ultraviolet germicidal lamp to reduce the peculiar smell in the shoe cabinet, the distance between every two partitions is difficult to adjust due to the fact that the shoes are various in height, the distance between every two partitions cannot be reasonably arranged according to the height of every shoe, the ultraviolet germicidal lamp can only sterilize the uppermost area and cannot carry out bacteriostasis and odor removal on the whole inner cavity of the shoe cabinet, and the existing shoe cabinet has the defects of sterilization dead angles and incomplete sterilization, so that the existing shoe cabinet is poor in peculiar smell removal effect and bacteriostatic and bactericidal effect;
therefore, an adjustable shoe cabinet which can effectively remove peculiar smell and has a good bacteriostatic effect is needed to solve the above problems.
Disclosure of Invention
In order to overcome the technical problems, the invention aims to provide an adjustable sliding door shoe cabinet with bacteriostasis and peculiar smell removal and a production process thereof, wherein the adjustable sliding door shoe cabinet comprises the following steps: this adjustable turns over a shoe cabinet, can place the height of board according to the shoes adjustment, be applicable to not shoes of co-altitude and place, and the angle of placing the board can be adjusted at will, can be fast will place the board sanitization, maintain the shoe cabinet health, shoes are placed to the user that still is applicable to different heights, promote the result of use, the air discharge fan operation drives the smell circulation that the air current flow carried shoes release and is through the inner chamber of placing the board, detach the peculiar smell and disinfect by antibacterial deodorization board, accomplish antibacterial deodorization process, with solving current shoe cabinet and can not adjust, and get rid of the effect to the peculiar smell poor problem of antibacterial sterilization.
The purpose of the invention can be realized by the following technical scheme:
the bacteriostatic and peculiar smell-removing adjustable type hinged-door shoe cabinet comprises a shoe cabinet body, a shoe cabinet door, a partition plate, a placing plate, a bacteriostatic and deodorant plate and an exhaust fan, wherein one side of the shoe cabinet body is movably connected with the shoe cabinet door through a hinge, the partition plate is vertically arranged in the inner cavity of the shoe cabinet body, a plurality of air outlets are formed in the top end of the partition plate, an air inlet pipe is installed at the bottom end of the shoe cabinet body in a penetrating manner, and the exhaust fan is installed in the inner cavity of the air inlet pipe;
the shoe cabinet is characterized in that a plurality of placing plates are arranged in the inner cavity of the shoe cabinet body, and bacteriostatic and deodorant plates are slidably mounted in the inner cavity of the placing plates.
As a further scheme of the invention: the shoe cabinet comprises a shoe cabinet body and is characterized in that a plurality of sliding grooves are formed in two sides of the shoe cabinet body, a plurality of sliding plates are arranged on two sides of the shoe cabinet body, sliding blocks are mounted at two ends of one side of each sliding plate, the sliding plates are connected to the inner wall of the shoe cabinet body in a sliding mode through the sliding blocks and the sliding grooves, a height adjusting hand wheel is mounted in the middle of each sliding plate in a threaded mode, and one end of the height adjusting hand wheel abuts against the inner wall of the shoe cabinet body.
As a further scheme of the invention: the bottom of sliding plate is provided with the mounting panel, regulation hole and waist type hole have been seted up respectively to one side both ends of mounting panel, equal swing joint has the spliced pole in regulation hole and the waist type hole, a plurality of the spliced pole is installed respectively at the both ends corner of placing the board, the one end threaded connection of mounting panel has angle adjusting hand wheel, the spliced pole that the one end butt of angle adjusting hand wheel is located the regulation hole inner chamber.
As a further scheme of the invention: the top of placing the board has seted up a plurality of bleeder vent, the both ends of placing the board have seted up a plurality of air intake respectively, the handle is all installed at one side both ends of antibacterial deodorization board.
The production process of the bacteriostatic peculiar smell-removing adjustable type sliding door shoe cabinet comprises the following steps:
step one, preparing an adjustable type sliding door shoe cabinet: cutting plates according to specifications, and then assembling the cut plates to form the adjustable turnover door shoe cabinet;
step two, preparing the antibacterial deodorant board:
a1: uniformly mixing a water-based ultrasonic cleaning agent and distilled water to form an ultrasonic cleaning solution, adding activated carbon into the ultrasonic cleaning solution, soaking for 10-20min, then carrying out ultrasonic treatment for 10-15min under the condition that the ultrasonic frequency is 30-60kHz, then taking out the activated carbon, adding the activated carbon into deionized water, carrying out ultrasonic treatment for 10-15min under the condition that the ultrasonic frequency is 30-60kHz, then taking out the activated carbon, washing for 2-3 times with the deionized water, then placing in a vacuum drying box, and drying to constant weight under the condition that the temperature is 90-100 ℃ to obtain pretreated activated carbon;
a2: adding the pretreated activated carbon into a nitric acid solution, carrying out oscillation treatment for 2-3h at the temperature of 30-35 ℃, standing for 10-15h, then placing in a vacuum drying box, drying to constant weight at the temperature of 120-130 ℃, then washing to neutrality with deionized water, then placing in the vacuum drying box again, and drying to constant weight at the temperature of 120-130 ℃ to obtain oxidized activated carbon;
a3: adding methyl dichlorosilane and a catalyst into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, heating while stirring under the condition that the stirring speed is 300-500r/min, controlling the heating speed to be 3-5 ℃/min until the temperature is raised to 100-110 ℃, then dropwise adding allyl chloride while stirring, controlling the dropwise adding speed to be 1 drop/s, continuing to react for 2-3h after the dropwise adding is finished, and cooling a reaction product to room temperature after the reaction is finished to obtain an intermediate 1;
the reaction principle is as follows:
a4: adding the intermediate 1, N-dimethylaminoethyl acetate and N, N-dimethylformamide into a three-neck flask provided with a stirrer, a constant-pressure dropping funnel and a gas-guide tube, introducing nitrogen for protection, stirring and reacting for 25-30h under the conditions that the temperature is 110-;
the reaction principle is as follows:
a5: adding the intermediate 2 and deionized water into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, stirring at the stirring rate of 800-;
the reaction principle is as follows:
step three, preparing an antibacterial and peculiar smell-removing adjustable type sliding door shoe cabinet: the handle is installed on the antibacterial deodorizing plate and inserted into the inner cavity of the placing plate, so that the antibacterial odor-removing adjustable type hinged-door shoe cabinet is obtained.
As a further scheme of the invention: a production process of an antibacterial and peculiar smell-removing adjustable turnover door shoe cabinet comprises the following steps of A1, wherein the mass ratio of the water-based ultrasonic cleaning agent to distilled water is 1: 4-5.
As a further scheme of the invention: the production process of the bacteriostatic and peculiar smell-removing adjustable sliding door shoe cabinet is characterized in that the mass fraction of the nitric acid solution in the step A2 is 40-50%.
As a further scheme of the invention: the production process of the bacteriostatic and peculiar smell-removing adjustable sliding door shoe cabinet is characterized in that the catalyst in the step A3 is a 0.05mol/L solution formed by dissolving chloroplatinic acid in isopropanol, and the molar ratio of the methyldichlorosilane, the chloroplatinic acid and the allyl chloride is 1000: 0.05: 900.
as a further scheme of the invention: the dosage ratio of the intermediate 1, the ethyl N, N-dimethylamino acetate and the N, N-dimethylformamide in the step A4 is 0.06 mol: 0.03 mol: 25 mL.
As a further scheme of the invention: the dosage ratio of the intermediate 2, the deionized water and the hydrochloric acid solution in the step A5 is 0.2-1.0 g: 38mL of: 2.0mL, and the molar concentration of the hydrochloric acid solution is 4 mol/L.
As a further scheme of the invention: the working process of the antibacterial and peculiar smell removing adjustable type sliding door shoe cabinet is as follows:
the adjusting process comprises the following steps: rotating a height adjusting hand wheel to ensure that the end part of the height adjusting hand wheel is not contacted with the inner wall of the shoe cabinet body, moving a sliding block in a sliding groove by pulling a sliding plate, adjusting the heights among a plurality of placing plates according to the heights of shoes, and screwing the height adjusting hand wheel to finish the height adjustment of the placing plates; rotating the angle adjusting hand wheel to ensure that the angle adjusting hand wheel is not abutted against the connecting column, moving the connecting column in the kidney-shaped hole, adjusting the downward inclination angle of the inner side of the placing plate according to the use habit of a user, and adjusting the upward inclination angle of the inner side of the placing plate when the placing plate needs to be cleaned to complete the angle adjustment of the placing plate;
the antibacterial and deodorant process comprises the following steps: place antibacterial deodorization board in the inner chamber of placing the board, treat that shoes are placed on placing the board, close the shoe cabinet door, start the air discharge fan, the air discharge fan drives the air current and follows the air-supply line input, get into the inner chamber of placing the board through air intake and bleeder vent, later discharge from the air exit, later carry forward through the air discharge fan once more, accomplish the air current circulation, the smell circulation that the air current flow carried shoes release is through the inner chamber of placing the board, detach the peculiar smell and disinfect by antibacterial deodorization board, accomplish antibacterial deodorization process.
The invention has the following beneficial effects:
according to the bacteriostatic and peculiar smell-removing adjustable type door-turning shoe cabinet and the production process thereof, the end part of the height adjusting hand wheel is not contacted with the inner wall of the shoe cabinet body by rotating the height adjusting hand wheel, the sliding block is moved in the sliding groove by pulling the sliding plate, the heights among a plurality of placing plates are adjusted according to the heights of shoes, and the height adjusting hand wheel is screwed to finish the height adjustment of the placing plates; rotating the angle adjusting hand wheel to ensure that the angle adjusting hand wheel is not abutted against the connecting column, moving the connecting column in the kidney-shaped hole, adjusting the downward inclination angle of the inner side of the placing plate according to the use habit of a user, and adjusting the upward inclination angle of the inner side of the placing plate when the placing plate needs to be cleaned to complete the angle adjustment of the placing plate; the adjustable shoe cabinet with the turnover door can adjust the height of the placing plate according to shoes, is suitable for placing shoes with different heights, can adjust the angle of the placing plate at will, can clean the placing plate quickly and maintain the sanitation of the shoe cabinet, is also suitable for users with different heights to place shoes, and improves the using effect;
the active carbon is taken as a raw material, soluble gas, impurities and grease exist on the surface of the active carbon, SO that micropores of the active carbon are blocked, the active carbon is subjected to ultrasonic treatment to remove attachments on the surface of the active carbon, SO that the micropores of the active carbon are cleaned, then the cleaned active carbon is subjected to oxidation treatment through nitric acid, a large number of oxygen-containing groups can be generated through nitric acid modification, acidic oxygen-containing functional groups can enable the surface of the active carbon to have polarity, and are favorable for adsorbing various compounds with stronger polarity, such as SO2, NOx, formaldehyde, water and the like, SO that peculiar smell emitted by shoes can be effectively removed, then methyl dichlorosilane and allyl chloride are taken as raw materials, a hydrosilylation reaction is performed to generate an intermediate 1, then the intermediate 1 reacts with N, N-dimethylaminoethyl acetate to generate an intermediate 2, the intermediate 2 contains quaternary ammonium groups, and the quaternary ammonium groups are contacted with a bacterial cell membrane with negative charges due to the strong electropositivity of the quaternary nitrogen atoms, the method comprises the steps of breaking the charge balance of bacteria, breaking the bacteria to die under the action of the osmotic pressure of the bacteria, adsorbing an intermediate 2 by oxidized activated carbon, carrying out in-situ polymerization on micropores and the surface of the oxidized activated carbon to form a high molecular compound, carrying out compression molding on the high molecular compound to obtain a plate, obtaining the antibacterial deodorizing plate, endowing the antibacterial deodorizing plate with good antibacterial and bacteriostatic properties through a large number of quaternary ammonium groups on a polymer molecular chain, placing the antibacterial deodorizing plate in an inner cavity of a placing plate, placing shoes on the placing plate, closing a cabinet door of the shoe cabinet, starting an exhaust fan, driving airflow to enter the inner cavity of the placing plate through an air inlet pipe and an air vent, then exhausting the airflow from an air outlet, carrying the odor released by the shoes to circulate through the inner cavity of the placing plate by the airflow, removing peculiar smell by the antibacterial deodorizing plate and sterilizing, the bacteriostatic and deodorant processes are completed to improve the bacteriostatic and peculiar smell removing effects of the adjustable type hinged-door shoe cabinet.
Drawings
The invention is further described below with reference to the accompanying drawings.
FIG. 1 is a schematic structural view of an adjustable sliding door shoe cabinet for inhibiting bacteria and removing peculiar smell in the invention;
FIG. 2 is a connection view of the cabinet body and the partition plate of the shoe chest in the present invention;
FIG. 3 is a schematic view showing an inner structure of a cabinet body of the shoe chest according to the present invention;
FIG. 4 is a schematic view of the structure of the mounting plate and the sliding plate in the present invention;
FIG. 5 is a view of the slide plate and slide block connection of the present invention;
fig. 6 is a connection view of the placing plate and the bacteriostatic deodorant plate in the invention.
In the figure: 100. a shoe cabinet body; 101. a cabinet door of the shoe cabinet; 102. a partition plate; 103. mounting a plate; 104. an angle adjusting hand wheel; 105. a sliding plate; 106. a height adjustment hand wheel; 107. placing the plate; 108. a bacteriostatic deodorant plate; 109. an air inlet pipe; 110. an exhaust fan; 111. an air outlet; 112. an adjustment hole; 113. a kidney-shaped hole; 114. a slider; 115. air holes are formed; 116. an air inlet; 117. connecting columns.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
referring to fig. 1-6, the present embodiment is an antibacterial and odor-removing adjustable type sliding-door shoe cabinet, which includes a shoe cabinet body 100, a shoe cabinet door 101, a partition plate 102, a placing plate 107, an antibacterial and odor-removing plate 108 and an exhaust fan 110, wherein one side of the shoe cabinet body 100 is movably connected with the shoe cabinet door 101 through a hinge, the partition plate 102 is vertically installed in an inner cavity of the shoe cabinet body 100, a plurality of air outlets 111 are formed in the top end of the partition plate 102, an air inlet pipe 109 is installed at the bottom end of the shoe cabinet body 100 in a penetrating manner, and the exhaust fan 110 is installed in the inner cavity of the air inlet pipe 109;
a plurality of placing plates 107 are arranged in the inner cavity of the shoe cabinet body 100, and an antibacterial and deodorant plate 108 is slidably mounted in the inner cavity of the placing plates 107.
A plurality of sliding grooves are formed in the two sides of the shoe cabinet body 100, a plurality of sliding plates 105 are arranged on the two sides of the shoe cabinet body 100, sliding blocks 114 are mounted at the two ends of one side of each sliding plate 105, the sliding plates 105 are slidably connected to the inner wall of the shoe cabinet body 100 through the sliding blocks 114 and the sliding grooves, a height adjusting hand wheel 106 is mounted in the middle of each sliding plate 105 in a threaded mode, and one end of each height adjusting hand wheel 106 abuts against the inner wall of the shoe cabinet body 100.
The bottom of sliding plate 105 is provided with mounting panel 103, adjustment hole 112 and waist type hole 113 have been seted up respectively to one side both ends of mounting panel 103, all swing joint has spliced pole 117 in adjustment hole 112 and the waist type hole 113, and a plurality of spliced pole 117 is installed respectively in the both ends corner of placing board 107, and the one end threaded connection of mounting panel 103 has angle adjusting hand wheel 104, and the one end butt of angle adjusting hand wheel 104 is located the spliced pole 117 of adjustment hole 112 inner chamber.
The top of the placing plate 107 is provided with a plurality of air holes 115, two ends of the placing plate 107 are respectively provided with a plurality of air inlets 116, and two ends of one side of the antibacterial and deodorant plate 108 are respectively provided with a handle.
Example 2:
the embodiment is a preparation method of a bacteriostatic deodorant plate, which comprises the following steps:
water-based ultrasonic cleaning agent and distilled water are mixed according to the mass ratio of 1: 5, uniformly mixing to form ultrasonic cleaning liquid, adding activated carbon into the ultrasonic cleaning liquid, soaking for 10min, then carrying out ultrasonic treatment for 10min under the condition that the ultrasonic frequency is 30kHz, then taking out the activated carbon, adding into deionized water, carrying out ultrasonic treatment for 10min under the condition that the ultrasonic frequency is 30kHz, then taking out the activated carbon, washing for 2 times with the deionized water, then placing in a vacuum drying box, and drying to constant weight under the condition that the temperature is 90 ℃ to obtain pretreated activated carbon;
adding the pretreated activated carbon into a nitric acid solution with the mass fraction of 40%, carrying out oscillation treatment for 2h at the temperature of 30 ℃, standing for 10h, then placing in a vacuum drying box, drying to constant weight at the temperature of 120 ℃, then washing to neutrality with deionized water, then placing in the vacuum drying box again, and drying to constant weight at the temperature of 120 ℃ to obtain oxidized activated carbon;
adding 10g of methyldichlorosilane and 10mL of chloroplatinic acid-isopropanol solution with the molar concentration of 0.05mol/L into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, heating while stirring under the condition of the stirring speed of 300r/min, controlling the heating speed to be 3 ℃/min until the temperature is raised to 100 ℃, then dropwise adding 9g of allyl chloride while stirring, controlling the dropwise adding speed to be 1 drop/s, continuing to react for 2 hours after the dropwise adding is finished, and cooling the reaction product to room temperature after the reaction is finished to obtain an intermediate 1;
adding 0.06mol of the intermediate 1, 0.03mol of N, N-dimethylamino ethyl acetate and 25mLN, N-dimethylformamide into a three-neck flask provided with a stirrer, a constant-pressure dropping funnel and a gas guide tube, introducing nitrogen for protection, stirring and reacting for 25 hours at the temperature of 110 ℃ and the stirring speed of 200r/min, and after the reaction is finished, carrying out rotary evaporation on a reaction product to remove the N, N-dimethylformamide to obtain an intermediate 2;
adding 0.2g of the intermediate 2 and 38mL of deionized water into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, stirring until the intermediate 2 is completely dissolved under the condition of stirring speed of 800r/min, then adding oxidized activated carbon, continuously stirring for 10min, then dropwise adding 2.0mL of hydrochloric acid solution with the molar concentration of 4mol/L, controlling the dropwise adding speed to be 1 drop/s, heating to 50 ℃ after dropwise adding, continuously stirring for reacting for 6h, after the reaction is finished, carrying out vacuum filtration on a reaction product, placing a filter cake into a vacuum drying oven, drying for 2h under the condition of temperature of 120 ℃, and then carrying out press forming on the filter cake to obtain the antibacterial deodorant plate 108.
Example 3:
the embodiment is a preparation method of the antibacterial deodorant plate 108, which comprises the following steps:
the method comprises the following steps: water-based ultrasonic cleaning agent and distilled water are mixed according to the mass ratio of 1: 4, uniformly mixing to form ultrasonic cleaning liquid, adding activated carbon into the ultrasonic cleaning liquid, soaking for 20min, then carrying out ultrasonic treatment for 15min under the condition that the ultrasonic frequency is 60kHz, then taking out the activated carbon, adding into deionized water, carrying out ultrasonic treatment for 15min under the condition that the ultrasonic frequency is 60kHz, then taking out the activated carbon, washing for 3 times with the deionized water, then placing in a vacuum drying box, and drying to constant weight under the condition that the temperature is 100 ℃ to obtain pretreated activated carbon;
step two: adding the pretreated activated carbon into a nitric acid solution with the mass fraction of 50%, carrying out oscillation treatment for 3h at the temperature of 35 ℃, standing for 15h, then placing in a vacuum drying oven, drying to constant weight at the temperature of 130 ℃, then washing to neutrality with deionized water, then placing in the vacuum drying oven again, and drying to constant weight at the temperature of 130 ℃ to obtain oxidized activated carbon;
step three: adding 10g of methyldichlorosilane and 10mL of chloroplatinic acid-isopropanol solution with the molar concentration of 0.05mol/L into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, heating while stirring under the condition of the stirring speed of 500r/min, controlling the heating speed to be 5 ℃/min until the temperature is raised to 110 ℃, then dropwise adding 9g of allyl chloride while stirring, controlling the dropwise adding speed to be 1 drop/s, continuing to react for 3 hours after the dropwise adding is finished, and cooling the reaction product to room temperature after the reaction is finished to obtain an intermediate 1;
step four: adding 0.06mol of the intermediate 1, 0.03mol of N, N-dimethylamino ethyl acetate and 25mLN, N-dimethylformamide into a three-neck flask provided with a stirrer, a constant-pressure dropping funnel and a gas guide tube, introducing nitrogen for protection, stirring and reacting for 30 hours at the temperature of 115 ℃ and at the stirring speed of 300r/min, and after the reaction is finished, carrying out rotary evaporation on a reaction product to remove the N, N-dimethylformamide to obtain an intermediate 2;
step five: adding 1.0g of the intermediate 2 and 38mL of deionized water into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, stirring until the intermediate 2 is completely dissolved under the condition of stirring speed of 1000r/min, then adding oxidized activated carbon, continuously stirring for 30min, then dropwise adding 2.0mL of hydrochloric acid solution with the molar concentration of 4mol/L, controlling the dropwise adding speed to be 1 drop/s, heating to 60 ℃ after dropwise adding, continuously stirring for reaction for 8h, after the reaction is finished, carrying out vacuum filtration on a reaction product, placing a filter cake into a vacuum drying oven, drying for 3h under the condition of temperature of 130 ℃, and then carrying out compression molding on the filter cake to obtain the antibacterial deodorant plate 108.
Example 4:
referring to fig. 1-6, the present embodiment is a process for manufacturing an adjustable sliding door shoe cabinet with antibacterial and deodorizing effects, including the following steps:
the method comprises the following steps: cutting plates according to specifications, and then assembling the cut plates to form the adjustable turnover door shoe cabinet;
step two: preparing the bacteriostatic deodorant plate 108 according to the preparation method of the embodiment 2 or the embodiment 3;
step three: the antibacterial deodorizing plate 108 is inserted into the inner cavity of the placing plate 107, and the antibacterial odor-removing adjustable type door-turning shoe cabinet is obtained.
Selecting escherichia coli and staphylococcus aureus as test bacteria, weighing 0.75g of compression molding raw materials of the antibacterial and deodorant plates in the embodiments 2 and 3, putting the raw materials into a 250mL conical flask, adding 75.00mL of PBS buffer solution and 0.75mL of bacterial liquid cultured for 24 hours, putting the conical flask into a 37 ℃ oscillation water tank, oscillating the conical flask at the rotating speed of 200r/min, taking 1.00mL of supernatant for gradient dilution at 30min and 90min respectively, and measuring the colony population of viable bacteria by adopting the counting of flat viable bacteria.
The calculation formula of the bacteriostatic rate is as follows:
the bacteriostatic rate (%) [ (initial number of bacteria-number of surviving bacteria)/initial number of bacteria ] × 100%;
the detection results are as follows:
referring to the data in the table, it can be known that the raw materials for press forming of the antibacterial deodorant board in examples 2 and 3 can reach an antibacterial rate of 99% or more after contacting bacteria for 90min, and the antibacterial effect is good.
Referring to fig. 1 to 6, the working process of the adjustable sliding-door shoe cabinet with bacteriostasis and deodorization in the present embodiment is as follows:
the adjusting process comprises the following steps: rotating the height adjusting hand wheel 106 to prevent the end of the height adjusting hand wheel 106 from contacting the inner wall of the shoe cabinet body 100, pulling the sliding plate 105 to move the sliding block 114 in the sliding groove, adjusting the heights of the plurality of placing plates 107 according to the heights of the shoes, and screwing the height adjusting hand wheel 106 to complete the height adjustment of the placing plates 107; rotating the angle adjusting handwheel 104 to ensure that the angle adjusting handwheel 104 is not abutted against the connecting column 117, moving in the kidney-shaped hole 113 through the connecting column 117, adjusting the downward inclination angle of the inner side of the placing plate 107 according to the use habit of a user, and adjusting the upward inclination angle of the inner side of the placing plate 107 when the cleaning is needed to complete the angle adjustment of the placing plate 107;
the antibacterial and deodorant process comprises the following steps: place antibacterial deodorization board 108 in the inner chamber of placing board 107, treat that shoes are placed on placing board 107, close shoe cabinet door 101, start exhaust fan 110, exhaust fan 110 drives the air current and inputs from air-supply line 109, get into the inner chamber of placing board 107 through air intake 116 and bleeder vent 115, later discharge from air exit 111, later carry forward through exhaust fan 110 once more, accomplish the air current circulation, the smell circulation that the air current flows and carries shoes release is through the inner chamber of placing board 107, detach the peculiar smell and disinfect by antibacterial deodorization board 108, accomplish antibacterial deodorization process.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing is illustrative and explanatory only and is not intended to be exhaustive or to limit the invention to the precise embodiments described, and various modifications, additions, and substitutions may be made by those skilled in the art without departing from the scope of the invention or exceeding the scope of the claims.
Claims (10)
1. The adjustable type overturning-door shoe cabinet with the functions of bacteriostasis and peculiar smell removal is characterized by comprising a shoe cabinet body (100), a shoe cabinet door (101), a partition plate (102), a placing plate (107), a bacteriostasis and deodorization plate (108) and an exhaust fan (110), wherein one side of the shoe cabinet body (100) is movably connected with the shoe cabinet door (101) through a hinge, the partition plate (102) is vertically arranged in the inner cavity of the shoe cabinet body (100), a plurality of air outlets (111) are formed in the top end of the partition plate (102), an air inlet pipe (109) is arranged at the bottom end of the shoe cabinet body (100) in a penetrating manner, and the exhaust fan (110) is arranged in the inner cavity of the air inlet pipe (109);
a plurality of placing plates (107) are arranged in the inner cavity of the shoe cabinet body (100), and bacteriostatic and deodorant plates (108) are slidably mounted in the inner cavity of the placing plates (107).
2. The bacteriostatic and peculiar smell-removing adjustable sliding-door shoe cabinet according to claim 1, characterized in that a plurality of sliding grooves are respectively formed at both sides of the shoe cabinet body (100), a plurality of sliding plates (105) are respectively arranged at both sides of the shoe cabinet body (100), sliding blocks (114) are respectively installed at both ends of one side of each sliding plate (105), the sliding plates (105) are slidably connected to the inner wall of the shoe cabinet body (100) through the sliding blocks (114) and the sliding grooves, a height adjusting hand wheel (106) is installed at the middle part of each sliding plate (105) in a threaded manner, and one end of each height adjusting hand wheel (106) is abutted to the inner wall of the shoe cabinet body (100).
3. The adjustable overturning door shoe cabinet with the functions of bacteriostasis and peculiar smell removal according to claim 2, wherein a mounting plate (103) is arranged at the bottom of the sliding plate (105), an adjusting hole (112) and a waist-shaped hole (113) are respectively formed at two ends of one side of the mounting plate (103), connecting columns (117) are movably connected in the adjusting hole (112) and the waist-shaped hole (113), a plurality of connecting columns (117) are respectively installed at corners at two ends of a placing plate (107), an angle adjusting hand wheel (104) is in threaded connection with one end of the mounting plate (103), and one end of the angle adjusting hand wheel (104) is abutted to the connecting column (117) in the inner cavity of the adjusting hole (112).
4. The adjustable shoe cabinet with the functions of bacteriostasis and peculiar smell removal according to claim 1, wherein a plurality of air holes (115) are formed in the top of the placing plate (107), a plurality of air inlets (116) are respectively formed in two ends of the placing plate (107), and handles are respectively installed at two ends of one side of the bacteriostasis and deodorization plate (108).
5. The production process of the bacteriostatic and peculiar smell-removing adjustable type sliding door shoe cabinet as claimed in claim 1, is characterized by comprising the following steps:
step one, preparing an adjustable type sliding door shoe cabinet: cutting plates according to specifications, and then assembling the cut plates to form the adjustable turnover door shoe cabinet;
step two, preparing a bacteriostatic deodorant plate (108):
a1: uniformly mixing a water-based ultrasonic cleaning agent and distilled water to form an ultrasonic cleaning solution, adding activated carbon into the ultrasonic cleaning solution, soaking for 10-20min, then carrying out ultrasonic treatment for 10-15min under the condition that the ultrasonic frequency is 30-60kHz, then taking out the activated carbon, adding the activated carbon into deionized water, carrying out ultrasonic treatment for 10-15min under the condition that the ultrasonic frequency is 30-60kHz, then taking out the activated carbon, washing for 2-3 times with the deionized water, then placing in a vacuum drying box, and drying to constant weight under the condition that the temperature is 90-100 ℃ to obtain pretreated activated carbon;
a2: adding the pretreated activated carbon into a nitric acid solution, carrying out oscillation treatment for 2-3h at the temperature of 30-35 ℃, standing for 10-15h, then placing in a vacuum drying box, drying to constant weight at the temperature of 120-130 ℃, then washing to neutrality with deionized water, then placing in the vacuum drying box again, and drying to constant weight at the temperature of 120-130 ℃ to obtain oxidized activated carbon;
a3: adding methyl dichlorosilane and a catalyst into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, heating while stirring under the condition that the stirring speed is 300-500r/min, controlling the heating speed to be 3-5 ℃/min until the temperature is raised to 100-110 ℃, then dropwise adding allyl chloride while stirring, controlling the dropwise adding speed to be 1 drop/s, continuing to react for 2-3h after the dropwise adding is finished, and cooling a reaction product to room temperature after the reaction is finished to obtain an intermediate 1;
a4: adding the intermediate 1, N-dimethylaminoethyl acetate and N, N-dimethylformamide into a three-neck flask provided with a stirrer, a constant-pressure dropping funnel and a gas-guide tube, introducing nitrogen for protection, stirring and reacting for 25-30h under the conditions that the temperature is 110-;
a5: adding the intermediate 2 and deionized water into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, stirring at the stirring rate of 800-;
step three, preparing an antibacterial and peculiar smell-removing adjustable type sliding door shoe cabinet: the handle is arranged on the bacteriostatic and deodorant plate (108) and is inserted into the inner cavity of the placing plate (107), so that the bacteriostatic and deodorant adjustable sliding door shoe cabinet is obtained.
6. The production process of the bacteriostatic and odor-removing adjustable sliding-door shoe cabinet according to claim 5, wherein the mass ratio of the water-based ultrasonic cleaning agent to the distilled water in the step A1 is 1: 4-5.
7. The production process of the bacteriostatic and odor-removing adjustable sliding-door shoe cabinet according to claim 5, wherein the mass fraction of the nitric acid solution in the step A2 is 40-50%.
8. The production process of the bacteriostatic and odor-removing adjustable sliding door shoe cabinet according to claim 5, wherein the catalyst in the step A3 is a 0.05mol/L solution of chloroplatinic acid dissolved in isopropanol, and the molar ratio of the methyldichlorosilane, the chloroplatinic acid and the allyl chloride is 1000: 0.05: 900.
9. the production process of the bacteriostatic and odor-removing adjustable sliding door shoe cabinet according to claim 5, wherein the dosage ratio of the intermediate 1, the N, N-dimethylamino ethyl acetate and the N, N-dimethylformamide in the step A4 is 0.06 mol: 0.03 mol: 25 mL.
10. The production process of the bacteriostatic and odor-removing adjustable sliding door shoe cabinet according to claim 5, wherein the dosage ratio of the intermediate 2, deionized water and hydrochloric acid solution in the step A5 is 0.2-1.0 g: 38mL of: 2.0mL, and the molar concentration of the hydrochloric acid solution is 4 mol/L.
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| WO1995018556A1 (en) * | 1994-01-10 | 1995-07-13 | Michel Bouchet | Set of shelves with rigifying pillars |
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Address after: 234200 fengmiao Hongling Industrial Park, Lingbi County, Suzhou City, Anhui Province Applicant after: Lingbi Dejun Furniture Manufacturing Co.,Ltd. Address before: 234200 fengmiao Hongling Industrial Park, Lingbi County, Suzhou City, Anhui Province Applicant before: Lingbi Dejun Furniture Manufacturing Co.,Ltd. |
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Denomination of invention: Adjustable flip door shoe cabinet with antibacterial and odor removal properties and its production process Granted publication date: 20221209 Pledgee: Lingbi County Tongling financing Company limited by guarantee Pledgor: Lingbi Dejun Furniture Manufacturing Co.,Ltd. Registration number: Y2024980011702 |
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