CN113520057B - Bacteriostatic and peculiar smell-removing adjustable type sliding-door shoe cabinet and production process thereof - Google Patents

Bacteriostatic and peculiar smell-removing adjustable type sliding-door shoe cabinet and production process thereof Download PDF

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Publication number
CN113520057B
CN113520057B CN202110944913.9A CN202110944913A CN113520057B CN 113520057 B CN113520057 B CN 113520057B CN 202110944913 A CN202110944913 A CN 202110944913A CN 113520057 B CN113520057 B CN 113520057B
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shoe cabinet
plate
placing
sliding
antibacterial
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CN113520057A (en
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刘兴旺
张云
王德军
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Lingbi Dejun Furniture Manufacturing Co ltd
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Lingbi Dejun Furniture Manufacturing Co ltd
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    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
    • A47B61/00—Wardrobes
    • A47B61/04—Wardrobes for shoes, hats, umbrellas, or the like
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
    • A47B57/00—Cabinets, racks or shelf units, characterised by features for adjusting shelves or partitions
    • A47B57/04—Cabinets, racks or shelf units, characterised by features for adjusting shelves or partitions with means for adjusting the inclination of the shelves
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
    • A47B57/00—Cabinets, racks or shelf units, characterised by features for adjusting shelves or partitions
    • A47B57/06—Cabinets, racks or shelf units, characterised by features for adjusting shelves or partitions with means for adjusting the height of the shelves
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
    • A47B96/00—Details of cabinets, racks or shelf units not covered by a single one of groups A47B43/00 - A47B95/00; General details of furniture
    • A47B96/02—Shelves
    • A47B96/025—Shelves with moving elements, e.g. movable extensions or link elements
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
    • A47B96/00—Details of cabinets, racks or shelf units not covered by a single one of groups A47B43/00 - A47B95/00; General details of furniture
    • A47B96/06—Brackets or similar supporting means for cabinets, racks or shelves
    • A47B96/07—Brackets or similar supporting means for cabinets, racks or shelves adjustable in themselves
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
    • A47B97/00—Furniture or accessories for furniture, not provided for in other groups of this subclass
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27M—WORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
    • B27M1/00—Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching
    • B27M1/02—Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching by compressing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27M—WORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
    • B27M3/00—Manufacture or reconditioning of specific semi-finished or finished articles
    • B27M3/18—Manufacture or reconditioning of specific semi-finished or finished articles of furniture or of doors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups

Abstract

The invention discloses an antibacterial and peculiar smell-removing adjustable sliding-door shoe cabinet and a production process thereof, and relates to the field of furniture, wherein the adjustable sliding-door shoe cabinet comprises a shoe cabinet body, a shoe cabinet door, a partition plate, a placing plate, an antibacterial and peculiar smell-removing plate and an exhaust fan, the height of the placing plate can be adjusted according to shoes, the adjustable sliding-door shoe cabinet is suitable for placing shoes with different heights, the angle of the placing plate can be adjusted at will, the placing plate can be cleaned quickly, the sanitation of the shoe cabinet can be maintained, the adjustable sliding-door shoe cabinet is also suitable for placing shoes for users with different heights, and the use effect is improved; the start-up air discharge fan drives the air current and flows, and the air current carries the smell circulation of shoes release through the inner chamber of placing the board, is detached the peculiar smell and is disinfected by antibacterial deodorization board, accomplishes antibacterial deodorization process to promote this adjustable turns over a shoes cabinet antibacterial, remove the peculiar smell effect.

Description

Bacteriostatic and peculiar smell-removing adjustable type sliding-door shoe cabinet and production process thereof
Technical Field
The invention relates to the field of furniture, in particular to an adjustable type hinged-door shoe cabinet with functions of bacteriostasis and peculiar smell removal and a production process thereof.
Background
In daily household life, the quantity and quality of shoes are continuously increasing and becoming higher, and the importance of putting and placing the shoes is becoming more and more important; although the existing shoe cabinet is provided with the ultraviolet germicidal lamp to reduce the peculiar smell in the shoe cabinet, the distance between every two partitions is difficult to adjust due to the fact that the shoes are various in height, the distance between every two partitions cannot be reasonably arranged according to the height of every shoe, the ultraviolet germicidal lamp can only sterilize the uppermost area and cannot carry out bacteriostasis and odor removal on the whole inner cavity of the shoe cabinet, and the existing shoe cabinet has the defects of sterilization dead angles and incomplete sterilization, so that the existing shoe cabinet is poor in peculiar smell removal effect and bacteriostatic and bactericidal effect;
therefore, an adjustable shoe cabinet which can effectively remove peculiar smell and has a good bacteriostatic effect is urgently needed to solve the problems.
Disclosure of Invention
In order to overcome the technical problems, the invention aims to provide an adjustable sliding door shoe cabinet with bacteriostasis and peculiar smell removal and a production process thereof, wherein the adjustable sliding door shoe cabinet comprises the following steps: this adjustable shoe cabinet that turns over a door, can place the height of board according to the shoes adjustment, it places to be applicable to the shoes of co-altitude not, and the angle of placing the board can be adjusted at will, can be fast will place the board clean up, maintain the shoe cabinet health, the user who still is applicable to different heights places shoes, promote the result of use, the air discharge fan operation drives the smell circulation process of carrying shoes release of air current flow and places the inner chamber of board, detach the peculiar smell and disinfect by antibacterial deodorization board, accomplish antibacterial deodorization process, can not adjust with solving current shoe cabinet, and it is poor to get rid of the effect to the peculiar smell, antibacterial not good problem of disinfecting.
The purpose of the invention can be realized by the following technical scheme:
the bacteriostatic and peculiar smell-removing adjustable type hinged-door shoe cabinet comprises a shoe cabinet body, a shoe cabinet door, a partition plate, a placing plate, a bacteriostatic and deodorant plate and an exhaust fan, wherein one side of the shoe cabinet body is movably connected with the shoe cabinet door through a hinge, the partition plate is vertically arranged in the inner cavity of the shoe cabinet body, a plurality of air outlets are formed in the top end of the partition plate, an air inlet pipe is installed at the bottom end of the shoe cabinet body in a penetrating manner, and the exhaust fan is installed in the inner cavity of the air inlet pipe;
the shoe cabinet is characterized in that a plurality of placing plates are arranged in the inner cavity of the shoe cabinet body, and bacteriostatic and deodorant plates are slidably mounted in the inner cavity of the placing plates.
As a further scheme of the invention: the shoe cabinet comprises a shoe cabinet body and is characterized in that a plurality of sliding grooves are formed in two sides of the shoe cabinet body, a plurality of sliding plates are arranged on two sides of the shoe cabinet body, sliding blocks are mounted at two ends of one side of each sliding plate, the sliding plates are connected to the inner wall of the shoe cabinet body in a sliding mode through the sliding blocks and the sliding grooves, a height adjusting hand wheel is mounted in the middle of each sliding plate in a threaded mode, and one end of the height adjusting hand wheel abuts against the inner wall of the shoe cabinet body.
As a further scheme of the invention: the bottom of sliding plate is provided with the mounting panel, regulation hole and waist type hole have been seted up respectively at one side both ends of mounting panel, equal swing joint has the spliced pole in regulation hole and the waist type hole, a plurality of the spliced pole is installed respectively at the both ends corner of placing the board, the one end threaded connection of mounting panel has angle adjusting hand wheel, the spliced pole that the one end butt of angle adjusting hand wheel was located the regulation hole inner chamber.
As a further scheme of the invention: the top of placing the board has seted up a plurality of bleeder vent, the both ends of placing the board have seted up a plurality of air intake respectively, the handle is all installed at one side both ends of antibacterial deodorization board.
The production process of the bacteriostatic and peculiar smell-removing adjustable type turnover door shoe cabinet comprises the following steps:
step one, preparing an adjustable type sliding door shoe cabinet: cutting plates according to specifications, and then assembling the cut plates to form the adjustable type turnover door shoe cabinet;
step two, preparing the antibacterial deodorant board:
a1: uniformly mixing a water-based ultrasonic cleaning agent and distilled water to form an ultrasonic cleaning solution, adding activated carbon into the ultrasonic cleaning solution, soaking for 10-20min, then carrying out ultrasonic treatment for 10-15min under the condition that the ultrasonic frequency is 30-60kHz, then taking out the activated carbon, adding the activated carbon into deionized water, carrying out ultrasonic treatment for 10-15min under the condition that the ultrasonic frequency is 30-60kHz, then taking out the activated carbon, washing for 2-3 times with the deionized water, then placing in a vacuum drying box, and drying to constant weight under the condition that the temperature is 90-100 ℃ to obtain pretreated activated carbon;
a2: adding the pretreated activated carbon into a nitric acid solution, carrying out oscillation treatment for 2-3h at the temperature of 30-35 ℃, standing for 10-15h, then placing in a vacuum drying box, drying to constant weight at the temperature of 120-130 ℃, then washing to neutrality with deionized water, then placing in the vacuum drying box again, and drying to constant weight at the temperature of 120-130 ℃ to obtain oxidized activated carbon;
a3: adding methyl dichlorosilane and a catalyst into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, heating while stirring under the condition that the stirring speed is 300-500r/min, controlling the heating speed to be 3-5 ℃/min until the temperature is raised to 100-110 ℃, then dropwise adding allyl chloride while stirring, controlling the dropwise adding speed to be 1 drop/s, continuing to react for 2-3h after the dropwise adding is finished, and cooling a reaction product to room temperature after the reaction is finished to obtain an intermediate 1;
the reaction principle is as follows:
Figure BDA0003216309290000031
a4: adding the intermediate 1, N-dimethylamino ethyl acetate and N, N-dimethylformamide into a three-neck flask provided with a stirrer, a constant-pressure dropping funnel and a gas guide tube, introducing nitrogen for protection, stirring and reacting for 25-30h at the temperature of 110-115 ℃ and the stirring speed of 200-300r/min, and after the reaction is finished, carrying out rotary evaporation on a reaction product to remove the N, N-dimethylformamide to obtain an intermediate 2;
the reaction principle is as follows:
Figure BDA0003216309290000041
a5: adding the intermediate 2 and deionized water into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, stirring until the intermediate 2 is completely dissolved under the condition that the stirring speed is 800-1000r/min, then adding oxidized activated carbon, continuously stirring for 10-30min, then dropwise adding a hydrochloric acid solution, controlling the dropwise adding speed to be 1 drop/s, continuously stirring and reacting for 6-8h under the condition that the temperature is raised to 50-60 ℃ after dropwise adding, after the reaction is finished, carrying out vacuum filtration on a reaction product, placing a filter cake into a vacuum drying box, drying for 2-3h under the condition that the temperature is 120-130 ℃, and then carrying out compression molding to obtain the antibacterial deodorant plate;
the reaction principle is as follows:
Figure BDA0003216309290000051
step three, preparing an antibacterial and peculiar smell-removing adjustable type turnover shoe cabinet: install the handle on the antibacterial deodorization board, insert to the inner chamber of placing the board in, obtain this antibacterial, remove adjustable shoe cabinet of turning over door of peculiar smell.
As a further scheme of the invention: a production process of an antibacterial and peculiar smell-removing adjustable type turnover door shoe cabinet comprises the following steps that in the step A1, the mass ratio of a water-based ultrasonic cleaning agent to distilled water is 1:4-5.
As a further scheme of the invention: the production process of the bacteriostatic and peculiar smell-removing adjustable type turnover shoe cabinet is characterized in that the mass fraction of the nitric acid solution in the step A2 is 40-50%.
As a further scheme of the invention: the production process of the bacteriostatic and peculiar smell-removing adjustable sliding door shoe cabinet is characterized in that the catalyst in the step A3 is a 0.05mol/L solution formed by dissolving chloroplatinic acid in isopropanol, and the molar ratio of the methyldichlorosilane, the chloroplatinic acid and the allyl chloride is 1000:0.05:900.
as a further scheme of the invention: the dosage ratio of the intermediate 1, the N, N-dimethylamino ethyl acetate and the N, N-dimethylformamide in the step A4 is 0.06mol:0.03mol:25mL.
As a further scheme of the invention: the dosage ratio of the intermediate 2, the deionized water and the hydrochloric acid solution in the step A5 is 0.2-1.0g:38mL of: 2.0mL, and the molar concentration of the hydrochloric acid solution is 4mol/L.
As a further scheme of the invention: the working process of the antibacterial and peculiar smell removing adjustable type sliding door shoe cabinet is as follows:
the adjusting process comprises the following steps: rotating a height adjusting hand wheel to ensure that the end part of the height adjusting hand wheel is not contacted with the inner wall of the shoe cabinet body, moving a sliding block in a sliding groove by pulling a sliding plate, adjusting the heights of a plurality of placing plates according to the heights of shoes, and screwing the height adjusting hand wheel to finish the height adjustment of the placing plates; rotating the angle adjusting hand wheel to ensure that the angle adjusting hand wheel is not abutted against the connecting column, moving the connecting column in the kidney-shaped hole, adjusting the downward inclination angle of the inner side of the placing plate according to the use habit of a user, and adjusting the upward inclination angle of the inner side of the placing plate when the placing plate needs to be cleaned to complete the angle adjustment of the placing plate;
the antibacterial and deodorant process comprises the following steps: place antibacterial deodorization board in the inner chamber of placing the board, treat that shoes are placed on placing the board, close the shoe cabinet door, start the air discharge fan, the air discharge fan drives the air current and follows the air-supply line input, in air intake and bleeder vent entering place the inner chamber of board, later discharge from the air exit, later carry forward through the air discharge fan once more, accomplish the air current circulation, the smell circulation that the air current flows and carries shoes release is through placing the inner chamber of board, detach the peculiar smell and disinfect by antibacterial deodorization board, accomplish antibacterial deodorization process.
The invention has the following beneficial effects:
according to the bacteriostatic and peculiar smell removing adjustable type door-turning shoe cabinet and the production process thereof, the end part of the height adjusting hand wheel is not contacted with the inner wall of the shoe cabinet body by rotating the height adjusting hand wheel, the sliding block is moved in the sliding groove by pulling the sliding plate, the heights of a plurality of placing plates are adjusted according to the heights of shoes, and the height adjusting hand wheel is screwed to finish the height adjustment of the placing plates; rotating the angle adjusting hand wheel to ensure that the angle adjusting hand wheel is not abutted against the connecting column, moving the connecting column in the kidney-shaped hole, adjusting the downward inclination angle of the inner side of the placing plate according to the use habit of a user, and adjusting the upward inclination angle of the inner side of the placing plate when the placing plate needs to be cleaned to complete the angle adjustment of the placing plate; the adjustable shoe cabinet with the turnover door can adjust the height of the placing plate according to shoes, is suitable for placing shoes with different heights, can adjust the angle of the placing plate at will, can clean the placing plate quickly and maintain the sanitation of the shoe cabinet, is also suitable for users with different heights to place shoes, and improves the using effect;
by using the active carbon as a raw material, because the surface of the active carbon has soluble gas, impurities and grease, the micropores of the active carbon are blocked, the active carbon is subjected to ultrasonic treatment to remove attachments on the surface of the active carbon, SO that the micropores of the active carbon are cleaned, then the cleaned active carbon is subjected to oxidation treatment by nitric acid, a large number of oxygen-containing groups can be generated through nitric acid modification, the acidic oxygen-containing functional groups can enable the surface of the active carbon to have polarity, and are favorable for adsorbing various compounds with stronger polarity, such as SO2, NOx, formaldehyde, water and the like, and can effectively remove peculiar smell emitted by shoes, then the methyl dichlorosilane and allyl chloride are used as the raw materials, the hydrosilylation reaction is performed to generate an intermediate 1, then the intermediate 1 reacts with N, N-dimethylaminoethyl acetate to generate an intermediate 2, the intermediate 2 contains quaternary ammonium groups, and the quaternary ammonium groups are contacted with the cell membranes of bacteria with negative charges due to the strong electropositivity of the quaternary nitrogen atoms, the bacteria charge balance is broken, the bacteria charge balance is broken and died under the action of the self osmotic pressure, the intermediate 2 is adsorbed by the oxidized activated carbon, then the oxidized activated carbon is polymerized in situ on micropores and the surface of the oxidized activated carbon to form a macromolecular compound, then the macromolecular compound is pressed and molded to prepare a plate, and the antibacterial deodorizing plate is obtained, the antibacterial deodorizing plate endows good antibacterial performance through a large amount of quaternary ammonium groups on a polymer molecular chain, the antibacterial deodorizing plate is placed in the inner cavity of the placing plate, when shoes are placed on the placing plate, a shoe cabinet door is closed, an exhaust fan is started, the exhaust fan drives air flow to enter the inner cavity of the placing plate through an air inlet and an air vent, then the air flow is discharged from an air outlet, the air flow is conveyed forwards through the exhaust fan again to complete air flow circulation, the air flow flows to carry the smell released by the shoes to circulate through the inner cavity of the placing plate, the peculiar smell is removed by the bacteriostatic and deodorant plate and the sterilization is carried out, so that the bacteriostatic and deodorant process is completed, and the bacteriostatic and deodorant effects of the adjustable type hinged-door shoe cabinet are improved.
Drawings
The invention is further described below with reference to the accompanying drawings.
FIG. 1 is a schematic structural view of an adjustable sliding door shoe cabinet for inhibiting bacteria and removing peculiar smell in the invention;
FIG. 2 is a connection view of the cabinet body and the partition plate of the shoe chest in the present invention;
FIG. 3 is a schematic view showing an inner structure of a cabinet body of the shoe chest according to the present invention;
FIG. 4 is a schematic view of the structure of the mounting plate and the sliding plate in the present invention;
FIG. 5 is a view showing the connection of the slide plate and the slide block according to the present invention;
fig. 6 is a connection view of the placement plate and the bacteriostatic deodorant plate in the invention.
In the figure: 100. a shoe cabinet body; 101. a cabinet door of the shoe cabinet; 102. a partition plate; 103. mounting a plate; 104. an angle adjusting hand wheel; 105. a sliding plate; 106. a height adjustment hand wheel; 107. placing the plate; 108. a bacteriostatic deodorant plate; 109. an air inlet pipe; 110. an exhaust fan; 111. an air outlet; 112. an adjustment hole; 113. a kidney-shaped hole; 114. a slider; 115. air holes are formed; 116. an air inlet; 117. connecting columns.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
referring to fig. 1-6, the present embodiment is an antibacterial and odor-removing adjustable type sliding-door shoe cabinet, which includes a shoe cabinet body 100, a shoe cabinet door 101, a partition plate 102, a placing plate 107, an antibacterial and odor-removing plate 108 and an exhaust fan 110, wherein one side of the shoe cabinet body 100 is movably connected with the shoe cabinet door 101 through a hinge, the partition plate 102 is vertically installed in an inner cavity of the shoe cabinet body 100, a plurality of air outlets 111 are formed in the top end of the partition plate 102, an air inlet pipe 109 is installed at the bottom end of the shoe cabinet body 100 in a penetrating manner, and the exhaust fan 110 is installed in the inner cavity of the air inlet pipe 109;
a plurality of placing plates 107 are arranged in the inner cavity of the shoe cabinet body 100, and an antibacterial and deodorant plate 108 is slidably mounted in the inner cavity of the placing plates 107.
A plurality of sliding grooves are formed in the two sides of the shoe cabinet body 100, a plurality of sliding plates 105 are arranged on the two sides of the shoe cabinet body 100, sliding blocks 114 are mounted at the two ends of one side of each sliding plate 105, the sliding plates 105 are connected to the inner wall of the shoe cabinet body 100 through the sliding blocks 114 and the sliding grooves in a sliding mode, a height adjusting hand wheel 106 is mounted in the middle of each sliding plate 105 in a threaded mode, and one end of the height adjusting hand wheel 106 abuts against the inner wall of the shoe cabinet body 100.
The bottom of sliding plate 105 is provided with mounting panel 103, and regulation hole 112 and waist type hole 113 have been seted up respectively to one side both ends of mounting panel 103, all swing joint has spliced pole 117 in regulation hole 112 and the waist type hole 113, and a plurality of spliced pole 117 is installed respectively at the both ends corner of placing board 107, and the one end threaded connection of mounting panel 103 has angle adjusting hand wheel 104, and the one end butt of angle adjusting hand wheel 104 is arranged in spliced pole 117 of regulation hole 112 inner chamber.
The top of the placing plate 107 is provided with a plurality of air holes 115, two ends of the placing plate 107 are respectively provided with a plurality of air inlets 116, and two ends of one side of the antibacterial and deodorant plate 108 are respectively provided with a handle.
Example 2:
the embodiment is a preparation method of a bacteriostatic and deodorant plate, which comprises the following steps:
the method comprises the following steps of (1) mixing a water-based ultrasonic cleaning agent and distilled water according to a mass ratio of 1:5, uniformly mixing to form ultrasonic cleaning liquid, adding activated carbon into the ultrasonic cleaning liquid, soaking for 10min, then carrying out ultrasonic treatment for 10min under the condition that the ultrasonic frequency is 30kHz, then taking out the activated carbon, adding the activated carbon into deionized water, carrying out ultrasonic treatment for 10min under the condition that the ultrasonic frequency is 30kHz, then taking out the activated carbon, washing the activated carbon with the deionized water for 2 times, then placing the activated carbon into a vacuum drying box, and drying the activated carbon to constant weight under the condition that the temperature is 90 ℃ to obtain pretreated activated carbon;
adding the pretreated activated carbon into a nitric acid solution with the mass fraction of 40%, oscillating for 2 hours at the temperature of 30 ℃, standing for 10 hours, placing in a vacuum drying oven, drying to constant weight at the temperature of 120 ℃, washing to neutrality with deionized water, placing in the vacuum drying oven again, and drying to constant weight at the temperature of 120 ℃ to obtain oxidized activated carbon;
adding 10g of methyldichlorosilane and 10mL of chloroplatinic acid-isopropanol solution with the molar concentration of 0.05mol/L into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, heating while stirring under the condition of the stirring speed of 300r/min, controlling the heating speed to be 3 ℃/min until the temperature is raised to 100 ℃, then dropwise adding 9g of allyl chloride while stirring, controlling the dropwise adding speed to be 1 drop/s, continuing to react for 2 hours after the dropwise adding is finished, and cooling the reaction product to room temperature after the reaction is finished to obtain an intermediate 1;
adding 0.06mol of intermediate 1, 0.03molN, N-dimethylamino ethyl acetate, 25mLN and N-dimethylformamide into a three-neck flask provided with a stirrer, a constant-pressure dropping funnel and a gas guide tube, introducing nitrogen for protection, stirring and reacting for 25 hours at the temperature of 110 ℃ and the stirring speed of 200r/min, and after the reaction is finished, carrying out rotary evaporation on a reaction product to remove the N, N-dimethylformamide to obtain an intermediate 2;
adding 0.2g of the intermediate 2 and 38mL of deionized water into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, stirring at a stirring speed of 800r/min until the intermediate 2 is completely dissolved, then adding oxidized activated carbon, continuously stirring for 10min, then dropwise adding 2.0mL of hydrochloric acid solution with a molar concentration of 4mol/L, controlling the dropwise adding speed to be 1 drop/s, heating to 50 ℃ after the dropwise adding, continuously stirring for reacting for 6h, after the reaction is finished, carrying out vacuum filtration on a reaction product, placing a filter cake into a vacuum drying oven, drying for 2h at the temperature of 120 ℃, and then carrying out compression molding on the product to obtain the antibacterial deodorizing board 108.
Example 3:
the embodiment is a preparation method of the antibacterial deodorant plate 108, which comprises the following steps:
the method comprises the following steps: water-based ultrasonic cleaning agent and distilled water are mixed according to the mass ratio of 1:4, uniformly mixing to form ultrasonic cleaning liquid, adding activated carbon into the ultrasonic cleaning liquid, soaking for 20min, then carrying out ultrasonic treatment for 15min under the condition that the ultrasonic frequency is 60kHz, then taking out the activated carbon, adding the activated carbon into deionized water, carrying out ultrasonic treatment for 15min under the condition that the ultrasonic frequency is 60kHz, then taking out the activated carbon, washing the activated carbon with the deionized water for 3 times, then placing the activated carbon into a vacuum drying box, and drying the activated carbon to constant weight under the condition that the temperature is 100 ℃ to obtain pretreated activated carbon;
step two: adding the pretreated activated carbon into a nitric acid solution with the mass fraction of 50%, oscillating for 3 hours at the temperature of 35 ℃, standing for 15 hours, placing in a vacuum drying oven, drying to constant weight at the temperature of 130 ℃, washing to neutrality with deionized water, placing in the vacuum drying oven again, and drying to constant weight at the temperature of 130 ℃ to obtain oxidized activated carbon;
step three: adding 10g of methyldichlorosilane and 10mL of chloroplatinic acid-isopropanol solution with the molar concentration of 0.05mol/L into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, heating while stirring under the condition of the stirring speed of 500r/min, controlling the heating speed to be 5 ℃/min until the temperature is raised to 110 ℃, then dropwise adding 9g of allyl chloride while stirring, controlling the dropwise adding speed to be 1 drop/s, continuing to react for 3 hours after the dropwise adding is finished, and cooling the reaction product to room temperature after the reaction is finished to obtain an intermediate 1;
step four: adding 0.06mol of the intermediate 1, 0.03molN, N-dimethylamino ethyl acetate, 25mLN and N-dimethylformamide into a three-neck flask provided with a stirrer, a constant-pressure dropping funnel and a gas guide tube, introducing nitrogen for protection, stirring and reacting for 30 hours at the temperature of 115 ℃ and at the stirring rate of 300r/min, and after the reaction is finished, rotationally evaporating a reaction product, removing the N, N-dimethylformamide to obtain an intermediate 2;
step five: adding 1.0g of the intermediate 2 and 38mL of deionized water into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, stirring at a stirring rate of 1000r/min until the intermediate 2 is completely dissolved, adding oxidized activated carbon, continuously stirring for 30min, dropwise adding 2.0mL of hydrochloric acid solution with a molar concentration of 4mol/L, controlling the dropwise adding rate to be 1 drop/s, heating to 60 ℃ after the dropwise adding, continuously stirring for reacting for 8h, after the reaction is finished, carrying out vacuum filtration on a reaction product, placing a filter cake into a vacuum drying oven, drying for 3h at a temperature of 130 ℃, and then carrying out compression molding to obtain the antibacterial deodorizing board 108.
Example 4:
referring to fig. 1-6, the present embodiment is a process for manufacturing an adjustable sliding door shoe cabinet with antibacterial and deodorizing effects, including the following steps:
the method comprises the following steps: cutting plates according to specifications, and then assembling the cut plates to form the adjustable turnover door shoe cabinet;
step two: preparing the bacteriostatic deodorant plate 108 according to the preparation method of the embodiment 2 or the embodiment 3;
step three: the antibacterial deodorizing plate 108 is inserted into the inner cavity of the placing plate 107, and the antibacterial odor-removing adjustable type door-turning shoe cabinet is obtained.
Selecting escherichia coli and staphylococcus aureus as test bacteria, weighing 0.75g of compression molding raw materials of the antibacterial and deodorant plates in the embodiments 2 and 3, putting the raw materials into a 250mL conical flask, adding 75.00mL of PBS buffer solution and 0.75mL of bacterial liquid cultured for 24 hours, putting the conical flask into a 37 ℃ oscillation water tank, oscillating the conical flask at the rotating speed of 200r/min, taking 1.00mL of supernatant for gradient dilution at 30min and 90min respectively, and measuring the colony population of viable bacteria by adopting the counting of flat viable bacteria.
The calculation formula of the bacteriostatic rate is as follows:
bacteriostatic rate (%) = [ (initial bacteria number-survival bacteria number)/initial bacteria number ] × 100%;
the detection results are as follows:
Figure BDA0003216309290000121
referring to the data in the table, it can be known that the raw materials for press forming of the antibacterial deodorant board in examples 2 and 3 can reach an antibacterial rate of 99% or more after contacting bacteria for 90min, and the antibacterial effect is good.
Referring to fig. 1 to 6, the working process of the adjustable sliding-door shoe cabinet with bacteriostasis and deodorization in the present embodiment is as follows:
the adjusting process comprises the following steps: rotating the height adjusting hand wheel 106 to prevent the end of the height adjusting hand wheel 106 from contacting the inner wall of the shoe cabinet body 100, pulling the sliding plate 105 to move the sliding block 114 in the sliding groove, adjusting the heights of the plurality of placing plates 107 according to the heights of the shoes, and screwing the height adjusting hand wheel 106 to complete the height adjustment of the placing plates 107; rotating the angle adjusting handwheel 104 to ensure that the angle adjusting handwheel 104 is not abutted against the connecting column 117, moving in the kidney-shaped hole 113 through the connecting column 117, adjusting the downward inclination angle of the inner side of the placing plate 107 according to the use habit of a user, and adjusting the upward inclination angle of the inner side of the placing plate 107 when the cleaning is needed to complete the angle adjustment of the placing plate 107;
the antibacterial and deodorant process comprises the following steps: place antibacterial deodorization board 108 in the inner chamber of placing board 107, treat that shoes are placed on placing board 107, close shoe cabinet door 101, start exhaust fan 110, exhaust fan 110 drives the air current and inputs from air-supply line 109, get into the inner chamber of placing board 107 through air intake 116 and bleeder vent 115, later discharge from air exit 111, later carry forward through exhaust fan 110 once more, accomplish the air current circulation, the smell circulation that the air current flows and carries shoes release is through the inner chamber of placing board 107, detach the peculiar smell and disinfect by antibacterial deodorization board 108, accomplish antibacterial deodorization process.
In the description herein, references to the description of "one embodiment," "an example," "a specific example," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing is illustrative and explanatory only and is not intended to be exhaustive or to limit the invention to the precise embodiments described, and various modifications, additions, and substitutions may be made by those skilled in the art without departing from the scope of the invention or exceeding the scope of the claims.

Claims (1)

1. The adjustable type overturning-door shoe cabinet with the functions of bacteriostasis and peculiar smell removal is characterized by comprising a shoe cabinet body (100), a shoe cabinet door (101), a partition plate (102), a placing plate (107), a bacteriostasis and deodorization plate (108) and an exhaust fan (110), wherein one side of the shoe cabinet body (100) is movably connected with the shoe cabinet door (101) through a hinge, the partition plate (102) is vertically arranged in the inner cavity of the shoe cabinet body (100), a plurality of air outlets (111) are formed in the top end of the partition plate (102), an air inlet pipe (109) is arranged at the bottom end of the shoe cabinet body (100) in a penetrating manner, and the exhaust fan (110) is arranged in the inner cavity of the air inlet pipe (109);
a plurality of placing plates (107) are arranged in the inner cavity of the shoe cabinet body (100), and antibacterial and deodorant plates (108) are slidably mounted in the inner cavity of the placing plates (107);
the shoe cabinet comprises a shoe cabinet body (100), a plurality of sliding grooves are formed in two sides of the shoe cabinet body (100), a plurality of sliding plates (105) are arranged on two sides of the shoe cabinet body (100), sliding blocks (114) are mounted at two ends of one side of each sliding plate (105), the sliding plates (105) are connected to the inner wall of the shoe cabinet body (100) in a sliding mode through the sliding blocks (114) and the sliding grooves, a height adjusting hand wheel (106) is mounted in the middle of each sliding plate (105) in a threaded mode, and one end of each height adjusting hand wheel (106) is abutted to the inner wall of the shoe cabinet body (100);
the bottom of the sliding plate (105) is provided with a mounting plate (103), two ends of one side of the mounting plate (103) are respectively provided with an adjusting hole (112) and a waist-shaped hole (113), connecting columns (117) are movably connected in the adjusting hole (112) and the waist-shaped hole (113), a plurality of connecting columns (117) are respectively mounted at two corners of the two ends of the placing plate (107), one end of the mounting plate (103) is in threaded connection with an angle adjusting hand wheel (104), and one end of the angle adjusting hand wheel (104) is abutted to the connecting column (117) located in the inner cavity of the adjusting hole (112);
the top of the placing plate (107) is provided with a plurality of air holes (115), two ends of the placing plate (107) are respectively provided with a plurality of air inlets (116), and two ends of one side of the antibacterial and deodorant plate (108) are respectively provided with a handle;
the production process of the bacteriostatic and peculiar smell-removing adjustable type turnover door shoe cabinet comprises the following steps:
step one, preparing an adjustable type sliding door shoe cabinet: cutting plates according to specifications, and then assembling the cut plates to form the adjustable type turnover door shoe cabinet;
step two, preparing a bacteriostatic deodorant plate (108):
a1: uniformly mixing a water-based ultrasonic cleaning agent and distilled water to form an ultrasonic cleaning solution, adding activated carbon into the ultrasonic cleaning solution, soaking for 10-20min, then carrying out ultrasonic treatment for 10-15min under the condition that the ultrasonic frequency is 30-60kHz, then taking out the activated carbon, adding the activated carbon into deionized water, carrying out ultrasonic treatment for 10-15min under the condition that the ultrasonic frequency is 30-60kHz, then taking out the activated carbon, washing for 2-3 times with the deionized water, then placing in a vacuum drying box, and drying to constant weight under the condition that the temperature is 90-100 ℃ to obtain pretreated activated carbon;
a2: adding the pretreated activated carbon into a nitric acid solution, carrying out oscillation treatment for 2-3h at the temperature of 30-35 ℃, standing for 10-15h, then placing in a vacuum drying box, drying to constant weight at the temperature of 120-130 ℃, then washing to neutrality with deionized water, then placing in the vacuum drying box again, and drying to constant weight at the temperature of 120-130 ℃ to obtain oxidized activated carbon;
a3: adding methyl dichlorosilane and a catalyst into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, heating while stirring under the condition that the stirring speed is 300-500r/min, controlling the heating speed to be 3-5 ℃/min until the temperature is raised to 100-110 ℃, then dropwise adding allyl chloride while stirring, controlling the dropwise adding speed to be 1 drop/s, continuing to react for 2-3h after the dropwise adding is finished, and cooling a reaction product to room temperature after the reaction is finished to obtain an intermediate 1;
a4: adding the intermediate 1, N-dimethylamino ethyl acetate and N, N-dimethylformamide into a three-neck flask provided with a stirrer, a constant-pressure dropping funnel and a gas guide tube, introducing nitrogen for protection, stirring and reacting for 25-30h at the temperature of 110-115 ℃ and the stirring speed of 200-300r/min, and after the reaction is finished, carrying out rotary evaporation on a reaction product to remove the N, N-dimethylformamide to obtain an intermediate 2;
a5: adding the intermediate 2 and deionized water into a three-neck flask provided with a stirrer and a constant-pressure dropping funnel, stirring at a stirring rate of 800-1000r/min until the intermediate 2 is completely dissolved, then adding oxidized activated carbon, continuously stirring for 10-30min, then dropwise adding a hydrochloric acid solution, controlling the dropwise adding rate to be 1 drop/s, continuously stirring and reacting for 6-8h under the condition of heating to 50-60 ℃ after dropwise adding is finished, after the reaction is finished, carrying out vacuum filtration on a reaction product, placing a filter cake into a vacuum drying oven, drying for 2-3h under the condition of temperature of 120-130 ℃, and then carrying out compression molding on the reaction product to obtain a plate material, thereby obtaining the antibacterial deodorant plate (108);
step three, preparing an antibacterial and peculiar smell-removing adjustable type turnover shoe cabinet: a handle is arranged on the bacteriostatic and deodorant plate (108) and is inserted into the inner cavity of the placing plate (107) to obtain the bacteriostatic and deodorant adjustable sliding door shoe cabinet;
the mass ratio of the water-based ultrasonic cleaning agent to the distilled water in the step A1 is 1:4-5;
the mass fraction of the nitric acid solution in the step A2 is 40-50%;
the catalyst in the step A3 is a 0.05mol/L solution formed by dissolving chloroplatinic acid in isopropanol, and the molar ratio of the methyldichlorosilane, the chloroplatinic acid and the allyl chloride is 1000:0.05:900;
the dosage ratio of the intermediate 1, the N, N-dimethylamino ethyl acetate and the N, N-dimethylformamide in the step A4 is 0.06mol:0.03mol:25mL;
the dosage ratio of the intermediate 2, the deionized water and the hydrochloric acid solution in the step A5 is 0.2-1.0g:38mL of: 2.0mL, wherein the molar concentration of the hydrochloric acid solution is 4mol/L;
according to the adjustable overturning-door shoe cabinet capable of inhibiting bacteria and removing peculiar smell and the production process thereof, the end part of the height adjusting hand wheel is not contacted with the inner wall of the shoe cabinet body by rotating the height adjusting hand wheel, the sliding block is moved in the sliding groove by pulling the sliding plate, the heights among a plurality of placing plates are adjusted according to the heights of shoes, and the height adjusting hand wheel is screwed to finish the height adjustment of the placing plates; rotating the angle adjusting hand wheel to ensure that the angle adjusting hand wheel is not abutted against the connecting column, moving the connecting column in the kidney-shaped hole, adjusting the downward inclination angle of the inner side of the placing plate according to the use habit of a user, and adjusting the upward inclination angle of the inner side of the placing plate when the placing plate needs to be cleaned to complete the angle adjustment of the placing plate; the adjustable type door-turning shoe cabinet can adjust the height of the placing plate according to shoes, is suitable for placing the shoes with different heights, can adjust the angle of the placing plate at will, can clean the placing plate quickly and maintain the sanitation of the shoe cabinet, is also suitable for placing the shoes for users with different heights, and improves the using effect;
the active carbon is used as a raw material, soluble gas, impurities and grease exist on the surface of the active carbon, so that micropores of the active carbon are blocked, the active carbon is subjected to ultrasonic treatment to remove attachments on the surface of the active carbon, so that the micropores of the active carbon are cleaned, the cleaned active carbon is subjected to oxidation treatment by nitric acid, a large number of oxygen-containing groups are generated through nitric acid modification, acidic oxygen-containing functional groups can enable the surface of the active carbon to have polarity, and are favorable for adsorbing various compounds with strong polarity, so that peculiar smell emitted by shoes can be effectively removed, then, methyl dichlorosilane and allyl chloride are used as raw materials, a hydrosilylation reaction is performed to generate an intermediate 1, then the intermediate 1 reacts with N, N-dimethylaminoethyl acetate to generate an intermediate 2, the intermediate 2 contains a quaternary ammonium group, and the quaternary ammonium group is contacted with a bacterial cell membrane with negative charges due to strong electropositivity of the quaternary nitrogen atom, the charge balance of bacteria is broken, the bacteria are broken and die under the action of the osmotic pressure of the bacteria, then the intermediate 2 is adsorbed by the oxidized activated carbon, then the high molecular compound is formed by in-situ polymerization on micropores and the surface of the oxidized activated carbon, the intermediate is pressed and formed to be made into a plate, and the antibacterial deodorizing plate is obtained, the antibacterial deodorizing plate endows good antibacterial and bacteriostatic properties through a large amount of quaternary ammonium groups on a polymer molecular chain, the antibacterial deodorizing plate is placed in the inner cavity of the placing plate, when shoes are placed on the placing plate, the cabinet door of the shoe cabinet is closed, the exhaust fan is started, the exhaust fan drives air flow to be input from the air inlet pipe, the air flow enters the inner cavity of the placing plate through the air inlet and the air holes, then the air flow is discharged from the air outlet and is conveyed forwards through the exhaust fan again to complete air flow circulation, and the air flow flows to carry the smell released by the shoes to circulate through the inner cavity of the placing plate, the peculiar smell is removed by the bacteriostatic and deodorant plate and the sterilization is carried out, so that the bacteriostatic and deodorant process is completed, and the bacteriostatic and deodorant effects of the adjustable type hinged-door shoe cabinet are improved.
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Denomination of invention: Adjustable flip door shoe cabinet with antibacterial and odor removal properties and its production process

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