CN113493310A - AG anti-glare glass and production method thereof - Google Patents
AG anti-glare glass and production method thereof Download PDFInfo
- Publication number
- CN113493310A CN113493310A CN202110702448.8A CN202110702448A CN113493310A CN 113493310 A CN113493310 A CN 113493310A CN 202110702448 A CN202110702448 A CN 202110702448A CN 113493310 A CN113493310 A CN 113493310A
- Authority
- CN
- China
- Prior art keywords
- glass
- component
- minutes
- stirrer
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 114
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 230000003746 surface roughness Effects 0.000 claims abstract description 18
- 238000005530 etching Methods 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 238000004140 cleaning Methods 0.000 claims abstract description 14
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 5
- 230000014759 maintenance of location Effects 0.000 claims abstract description 5
- 238000009941 weaving Methods 0.000 claims abstract description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 52
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 48
- 238000003756 stirring Methods 0.000 claims description 48
- 239000003795 chemical substances by application Substances 0.000 claims description 45
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 36
- 238000002156 mixing Methods 0.000 claims description 36
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 32
- 239000002994 raw material Substances 0.000 claims description 25
- MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 claims description 24
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 24
- 229920002472 Starch Polymers 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 24
- 239000008107 starch Substances 0.000 claims description 24
- 235000019698 starch Nutrition 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- 239000006229 carbon black Substances 0.000 claims description 21
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 20
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 18
- 229930006000 Sucrose Natural products 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 238000000227 grinding Methods 0.000 claims description 18
- 239000001103 potassium chloride Substances 0.000 claims description 18
- 235000011164 potassium chloride Nutrition 0.000 claims description 18
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 claims description 18
- 239000005720 sucrose Substances 0.000 claims description 18
- 239000000230 xanthan gum Substances 0.000 claims description 18
- 229920001285 xanthan gum Polymers 0.000 claims description 18
- 229940082509 xanthan gum Drugs 0.000 claims description 18
- 235000010493 xanthan gum Nutrition 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 12
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 12
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 12
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims description 12
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 12
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 239000001110 calcium chloride Substances 0.000 claims description 6
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 6
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 239000011698 potassium fluoride Substances 0.000 claims description 6
- 235000003270 potassium fluoride Nutrition 0.000 claims description 6
- 235000010333 potassium nitrate Nutrition 0.000 claims description 6
- 239000004323 potassium nitrate Substances 0.000 claims description 6
- VBKNTGMWIPUCRF-UHFFFAOYSA-M potassium;fluoride;hydrofluoride Chemical compound F.[F-].[K+] VBKNTGMWIPUCRF-UHFFFAOYSA-M 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 3
- 230000004313 glare Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000004438 eyesight Effects 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The invention relates to the technical field of glass deep processing, in particular to AG anti-glare glass and a production method thereof, wherein the production method comprises the following steps: (1) preparing a silk screen, wherein the silk screen is an oblique weaving net, and the mesh number is 60-300 meshes; (2) preparing glass, and separating air surface and tin surface of the glass; (3) preparing glass pretreatment liquid, pretreating glass, and cleaning the surface of the glass; (4) preparing etching ink; (5) printing ink on the clean glass surface by using a full-automatic printing machine, wherein the retention time of the ink on the glass surface is 1-5 minutes, and the ink is printed twice on the air surface of the glass; (6) cleaning and drying the glass by a cleaning machine to obtain the AG anti-glare glass; the AG anti-glare glass provided by the invention realizes the adjustment of the surface roughness of the AG anti-glare glass by adjusting the components of the printing ink, and can meet the requirements of different application scenes.
Description
Technical Field
The invention relates to the technical field of glass deep processing, in particular to AG anti-glare glass and a production method thereof.
Background
In daily life, people have experience disturbed by glare. Sources of glare are classified as direct (e.g., sunlight, too strong light, etc.) and indirect (e.g., reflection from a smooth object surface). The life concept of modern people has changed silently along with the rapid development of economy, and various electronic products such as mobile phones, notebooks, tablet computers and the like have become necessities of modern people's life in the era of the prevailing internet nowadays. Many cell-phones, panel computer screen are the touch-sensitive screen, and touch and vision have been unified to the touch-sensitive screen, make human-computer interaction more directly perceived, convenient, and all operations can both be simply interactive through the touch, but the glass that the touch-sensitive screen used at present, the screen can not be seen clearly because of the reflection of light under the light shines. A phenomenon of light death occurs. To reduce the influence of reflected light and glare on our daily life, a great deal of research is carried out at home and abroad, wherein the AG anti-glare glass (anti-reflection glass) is greatly concerned about the fact that the reflectivity of the glass can be significantly reduced, so that the interference of ambient light can be reduced, the visual angle and brightness of a picture can be improved, the reflection of light on a screen can be reduced, an image is clearer, the color is more gorgeous, the color is more saturated, and the display effect is significantly improved.
Disclosure of Invention
The invention aims to provide AG anti-glare glass and a production method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
a production method of AG anti-glare glass comprises the following steps:
(1) preparing a silk screen, wherein the silk screen is an oblique weaving net, and the mesh number is 60-300 meshes;
(2) preparing glass, and separating air surface and tin surface of the glass;
(3) preparing glass pretreatment liquid, pretreating glass, and cleaning the surface of the glass;
(4) preparing etching ink;
(5) printing ink on the clean glass surface by using a full-automatic printing machine, wherein the retention time of the ink on the glass surface is 1-5 minutes, and the ink is printed twice on the air surface of the glass;
(6) and cleaning and drying the glass by a cleaning machine to obtain the AG anti-glare glass.
In a further technical scheme, in the step (3), the glass is pretreated by immersing the glass into the pretreatment liquid for 1-2 minutes, or spraying the pretreatment liquid onto the surface of the glass and standing for 1-2 minutes;
the pretreatment liquid is prepared by mixing 15 wt.% of sulfuric acid, 5 wt.% of hydrochloric acid and 80 wt.% of water.
In a further technical scheme, in the step (4), the etching ink is prepared from a component A and a component B according to a mass ratio of 2: 1, mixing;
wherein the component A comprises the following raw material components: 150 g of ammonium fluoride, 450 g of ammonium bifluoride, 179910 g of polyvinyl alcohol, 100 g of starch, 100 g of citric acid, 200 g of barium sulfate, 450 g of water, 50 g of sucrose and 5 g of perfluorosilane;
the preparation method of the component A comprises the following steps: firstly, putting water into a batching tank with a stirrer, heating to 80 ℃, then adding polyvinyl alcohol 1799, stirring and mixing for 30 minutes at the rotating speed of 3000-plus 5000rpm, then adding citric acid, ammonium fluoride, ammonium bifluoride, perfluorosilane and sucrose, continuously stirring for 30 minutes, then adding starch and barium sulfate, continuously stirring for 60 minutes, and grinding by a three-roll machine to ensure that the fineness of the mixture reaches 280-plus 320 meshes;
the component B is prepared by mixing the following raw material components: 800 g of water, 300 g of potassium fluoride, 100 g of potassium nitrate and 200 g of glycerol;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding potassium fluoride and potassium nitrate, quickly stirring and mixing for 30 minutes, then adding glycerol, and continuously stirring for 30 minutes to obtain the component B.
The invention also provides the AG anti-glare glass produced by the method, and the surface roughness Ra of the AG anti-glare glass is 0.05-0.1 mu m.
In a further technical scheme, in the step (4), the etching ink is prepared from a component A and a component B according to a mass ratio of 3: 1, mixing;
wherein the component A comprises the following raw material components: 450 g of water, 100 g of xanthan gum, 150 g of ammonium fluoride, 500 g of ammonium bifluoride, 250 g of hydrochloric acid, 150 g of barium sulfate and 50 g of starch;
the preparation method of the component A comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding xanthan gum, stirring at the rotating speed of 3000rpm for 30 minutes, then sequentially adding ammonium fluoride, ammonium bifluoride, hydrochloric acid, barium sulfate and starch, stirring for 30 minutes, and grinding to the fineness of 280-320 meshes by using a three-roll mill;
the component B is prepared by mixing the following raw material components: 800 g of water, 200 g of potassium chloride, 100 g of potassium bifluoride, 50 g of white carbon black and 200 g of glycerol;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, sequentially adding potassium chloride and potassium bifluoride, adding white carbon black and glycerol after crystals are completely dissolved, and quickly stirring for 30 minutes to obtain the component B.
The invention also provides the AG anti-glare glass produced by the method, and the surface roughness Ra of the AG anti-glare glass is 0.1-0.2 mu m.
In a further technical scheme, in the step (4), the etching ink is prepared from a component A and a component B according to a mass ratio of 3: 1, mixing;
wherein the component A comprises the following raw material components: 1000 g of water, 200 g of ammonium fluoride, 400 g of ammonium bifluoride, 50 g of xanthan gum, 50 g of starch, 50 g of oxalic acid, 50 g of sulfuric acid, 50 g of sucrose, 5 g of perfluorosilane and 200 g of barium sulfate;
the preparation method of the component A comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, sequentially adding ammonium fluoride, ammonium bifluoride and xanthan gum, stirring at the rotating speed of 3000rpm for 30 minutes, then adding starch, oxalic acid, sulfuric acid, sucrose, perfluorosilane and barium sulfate, continuously stirring for 2 hours, and grinding by a three-roll machine to ensure that the fineness reaches 280-320 meshes;
the component B is prepared by mixing the following raw material components: 800 g of water, 200 g of potassium chloride, 40 g of ferric chloride, 50 g of 40% hydrofluoric acid, 50 g of calcium fluoride, 200 g of ethylene glycol and 100 g of white carbon black;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding potassium chloride, ferric chloride, 40% hydrofluoric acid, calcium fluoride and ethylene glycol, quickly stirring for 30 minutes, then adding white carbon black, continuously stirring for 30 minutes, and grinding by a three-roll machine to ensure that the fineness of the white carbon black reaches 200-300 meshes to obtain the component B.
The invention also provides the AG anti-glare glass produced by the method, and the surface roughness Ra of the AG anti-glare glass is 0.2-0.4 mu m.
In a further technical scheme, in the step (4), the etching ink is prepared from a component A and a component B according to a mass ratio of 1: 1, mixing;
wherein the component A comprises the following raw material components: 1000 g of water, 500 g of ammonium bifluoride, 50 g of sulfamic acid, 50 g of xanthan gum, 50 g of starch, 100 g of hydrochloric acid, 50 g of sucrose, 5 g of perfluorosilane and 200 g of barium sulfate;
the preparation method of the component A comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, sequentially adding ammonium bifluoride, sulfamic acid and xanthan gum, stirring at the rotating speed of 3000rpm for 30 minutes, then adding starch, hydrochloric acid, sucrose, perfluorosilane and barium sulfate, continuously stirring for 2 hours, and grinding by a three-roll machine to ensure that the fineness reaches 280-320 meshes;
the component B is prepared by mixing the following raw material components: 800 g of water, 50 g of potassium chloride, 100 g of magnesium chloride, 30 g of sodium fluosilicate, 20 g of calcium chloride, 100 g of 40% hydrofluoric acid, 50 g of calcium fluoride, 100 g of white carbon black and 100 g of glycerol;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding potassium chloride, magnesium chloride, sodium fluosilicate, calcium chloride, 40% hydrofluoric acid and calcium fluoride, quickly stirring for 30 minutes, then adding white carbon black and glycerol, continuously stirring for 30 minutes, and grinding by a three-roller machine to ensure that the fineness of the mixture reaches 200-300 meshes, thus obtaining the component B.
The invention also provides the AG anti-glare glass produced by the method, and the surface roughness Ra of the AG anti-glare glass is 0.8-1.2 mu m.
Compared with the prior art, the invention has the following technical effects:
the AG anti-glare glass provided by the invention realizes the adjustment of the surface roughness of the AG anti-glare glass by adjusting the components of the printing ink, and can meet the requirements of different application scenes.
Additional features and advantages of the invention will be set forth in the detailed description which follows.
Detailed Description
In order to make the technical means, the creation features, the achievement purposes and the effects of the invention easy to understand, the invention is further clarified with the specific embodiments.
All the starting materials in the present invention, the sources of which are not particularly limited, may be either commercially available or prepared according to conventional methods well known to those skilled in the art. All the raw materials used in the present invention are not particularly limited in purity, and the present invention preferably employs a purity which is conventional in the field of analytical purification or composite materials.
The invention provides a production method of AG anti-glare glass, which comprises the following steps:
(1) preparing a silk screen, wherein the silk screen is an oblique weaving net, and the mesh number is 60-300 meshes; the size of the mesh number of the screen directly determines the size of the surface roughness and the glossiness of the produced AG anti-glare glass;
(2) preparing glass, and separating air surface and tin surface of the glass;
(3) preparing glass pretreatment liquid, pretreating glass, and cleaning the surface of the glass;
(4) preparing etching ink;
(5) printing ink on the clean glass surface by using a full-automatic printing machine, wherein the retention time of the ink on the glass surface is 1-5 minutes, and the ink is printed twice on the air surface of the glass;
in the invention, in order to ensure that the surface roughness of the AG anti-glare glass meets the specified requirement, the humidity is kept between 70 and 80 percent in the printing environment of the printing ink;
(6) and cleaning and drying the glass by a cleaning machine to obtain the AG anti-glare glass.
According to the method provided by the invention, in the step (3), the glass is pretreated by immersing the glass into the pretreatment liquid for 1-2 minutes or spraying the pretreatment liquid on the surface of the glass and standing for 1-2 minutes;
the pretreatment liquid is prepared by mixing 15 wt.% of sulfuric acid, 5 wt.% of hydrochloric acid and 80 wt.% of water.
According to the method provided by the invention, an important process condition for determining the surface roughness of the AG anti-glare glass is used as the ink, and in the invention, the ink is prepared by mixing an A component and a B component, wherein the A component is mainly used for adjusting the haze of the glass, and the B component is mainly used for adjusting the surface roughness of the glass.
The AG anti-glare glass and the production method thereof provided by the present invention are further illustrated by the following specific examples.
A production method of AG anti-glare glass comprises the following steps:
(1) preparing a silk screen, wherein the silk screen is an oblique weaving screen, and the mesh number is 200 meshes;
(2) preparing glass, and separating air surface and tin surface of the glass;
(3) preparing glass pretreatment liquid, wherein the glass pretreatment liquid is prepared by mixing 15 wt.% of sulfuric acid, 5 wt.% of hydrochloric acid and 80 wt.% of water, and the glass is pretreated, specifically, the glass is immersed in the pretreatment liquid for 2 minutes, and then the surface of the glass is cleaned;
(4) preparing etching ink, wherein the ink is prepared by mixing a component A and a component B;
(5) printing ink on the clean glass surface by using a full-automatic printing machine, wherein the retention time of the ink on the glass surface is 4 minutes, the ink is printed twice on the air surface of the glass, and the humidity of the ink in the printing environment is kept at 75%;
(6) and cleaning and drying the glass by a cleaning machine to obtain the AG anti-glare glass.
Example 1
Based on the production of the AG anti-glare glass, in the step (4), the etching ink is prepared from a component A and a component B in a mass ratio of 2: 1, mixing;
wherein the component A comprises the following raw material components: 150 g of ammonium fluoride, 450 g of ammonium bifluoride, 179910 g of polyvinyl alcohol, 100 g of starch, 100 g of citric acid, 200 g of barium sulfate, 450 g of water, 50 g of sucrose and 5 g of perfluorosilane;
the preparation method of the component A comprises the following steps: firstly, putting water into a batching tank with a stirrer, heating to 80 ℃, then adding polyvinyl alcohol 1799, stirring and mixing for 30 minutes at the rotating speed of 3000rpm, then adding citric acid, ammonium fluoride, ammonium bifluoride, perfluorosilane and sucrose, continuing to stir for 30 minutes, then adding starch and barium sulfate, continuing to stir for 60 minutes, and then grinding by a three-roll machine to enable the fineness of the mixture to reach 300 meshes;
the component B is prepared by mixing the following raw material components: 800 g of water, 300 g of potassium fluoride, 100 g of potassium nitrate and 200 g of glycerol;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding potassium fluoride and potassium nitrate, quickly stirring and mixing for 30 minutes, then adding glycerol, and continuously stirring for 30 minutes to obtain the component B.
The AG anti-glare glass produced based on this example 1 had a surface roughness Ra of 0.08 μm.
Example 2
Based on the production of the AG anti-glare glass, in the step (4), the etching ink is prepared from a component A and a component B in a mass ratio of 3: 1, mixing;
wherein the component A comprises the following raw material components: 450 g of water, 100 g of xanthan gum, 150 g of ammonium fluoride, 500 g of ammonium bifluoride, 250 g of hydrochloric acid, 150 g of barium sulfate and 50 g of starch;
the preparation method of the component A comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding xanthan gum, stirring at the rotating speed of 3000rpm for 30 minutes, then sequentially adding ammonium fluoride, ammonium bifluoride, hydrochloric acid, barium sulfate and starch, stirring for 30 minutes, and grinding to the fineness of 300 meshes by using a three-roll machine;
the component B is prepared by mixing the following raw material components: 800 g of water, 200 g of potassium chloride, 100 g of potassium bifluoride, 50 g of white carbon black and 200 g of glycerol;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, sequentially adding potassium chloride and potassium bifluoride, adding white carbon black and glycerol after crystals are completely dissolved, and quickly stirring for 30 minutes to obtain the component B.
The AG anti-glare glass produced based on this example 2 had a surface roughness Ra of 0.15 μm, and the AG anti-glare glass was suitably used for industrial control panel glass.
Example 3
Based on the production of the AG anti-glare glass, in the step (4), the etching ink is prepared from a component A and a component B in a mass ratio of 3: 1, mixing;
wherein the component A comprises the following raw material components: 1000 g of water, 200 g of ammonium fluoride, 400 g of ammonium bifluoride, 50 g of xanthan gum, 50 g of starch, 50 g of oxalic acid, 50 g of sulfuric acid, 50 g of sucrose, 5 g of perfluorosilane and 200 g of barium sulfate;
the preparation method of the component A comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, sequentially adding ammonium fluoride, ammonium bifluoride and xanthan gum, stirring at the rotating speed of 3000rpm for 30 minutes, then adding starch, oxalic acid, sulfuric acid, sucrose, perfluorosilane and barium sulfate, continuously stirring for 2 hours, and grinding by a three-roll machine to enable the fineness to reach 300 meshes;
the component B is prepared by mixing the following raw material components: 800 g of water, 200 g of potassium chloride, 40 g of ferric chloride, 50 g of 40% hydrofluoric acid, 50 g of calcium fluoride, 200 g of ethylene glycol and 100 g of white carbon black;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding potassium chloride, ferric chloride, 40% hydrofluoric acid, calcium fluoride and ethylene glycol, quickly stirring for 30 minutes, then adding white carbon black, continuously stirring for 30 minutes, and grinding by a three-roll machine to enable the fineness of the white carbon black to reach 300 meshes to obtain the component B.
The AG anti-glare glass produced based on this example 3 had a surface roughness Ra of 0.3 μm, and the AG anti-glare glass was suitably used for refrigerator panels.
Example 4
Based on the production of the AG anti-glare glass, in the step (4), the etching ink is prepared from a component A and a component B in a mass ratio of 1: 1, mixing;
wherein the component A comprises the following raw material components: 1000 g of water, 500 g of ammonium bifluoride, 50 g of sulfamic acid, 50 g of xanthan gum, 50 g of starch, 100 g of hydrochloric acid, 50 g of sucrose, 5 g of perfluorosilane and 200 g of barium sulfate;
the preparation method of the component A comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, sequentially adding ammonium bifluoride, sulfamic acid and xanthan gum, stirring at the rotating speed of 3000rpm for 30 minutes, then adding starch, hydrochloric acid, sucrose, perfluorosilane and barium sulfate, continuously stirring for 2 hours, and grinding by a three-roll machine to enable the fineness to reach 300 meshes;
the component B is prepared by mixing the following raw material components: 800 g of water, 50 g of potassium chloride, 100 g of magnesium chloride, 30 g of sodium fluosilicate, 20 g of calcium chloride, 100 g of 40% hydrofluoric acid, 50 g of calcium fluoride, 100 g of white carbon black and 100 g of glycerol;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding potassium chloride, magnesium chloride, sodium fluosilicate, calcium chloride, 40% hydrofluoric acid and calcium fluoride, quickly stirring for 30 minutes, then adding white carbon black and glycerol, continuously stirring for 30 minutes, and grinding by a three-roller machine until the fineness of the mixture reaches 300 meshes to obtain the component B.
The AG anti-glare glass produced based on this example 4 had a surface roughness Ra of 1.0 μm, and the AG anti-glare glass was suitable for use in a panel of an education integrator.
The foregoing shows and describes the general principles, essential features, and inventive features of this invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (10)
1. The production method of the AG anti-glare glass is characterized by comprising the following steps of:
(1) preparing a silk screen, wherein the silk screen is an oblique weaving net, and the mesh number is 60-300 meshes;
(2) preparing glass, and separating air surface and tin surface of the glass;
(3) preparing glass pretreatment liquid, pretreating glass, and cleaning the surface of the glass;
(4) preparing etching ink;
(5) printing ink on the clean glass surface by using a full-automatic printing machine, wherein the retention time of the ink on the glass surface is 1-5 minutes, and the ink is printed twice on the air surface of the glass;
(6) and cleaning and drying the glass by a cleaning machine to obtain the AG anti-glare glass.
2. The method according to claim 1, wherein in the step (3), the glass is pretreated by immersing the glass in the pretreatment liquid for 1 to 2 minutes, or spraying the pretreatment liquid onto the surface of the glass and leaving it for 1 to 2 minutes;
the pretreatment liquid is prepared by mixing 15 wt.% of sulfuric acid, 5 wt.% of hydrochloric acid and 80 wt.% of water.
3. The method according to claim 1, wherein in the step (4), the etching ink is prepared from a component A and a component B according to a mass ratio of 2: 1, mixing;
wherein the component A comprises the following raw material components: 150 g of ammonium fluoride, 450 g of ammonium bifluoride, 179910 g of polyvinyl alcohol, 100 g of starch, 100 g of citric acid, 200 g of barium sulfate, 450 g of water, 50 g of sucrose and 5 g of perfluorosilane;
the preparation method of the component A comprises the following steps: firstly, putting water into a batching tank with a stirrer, heating to 80 ℃, then adding polyvinyl alcohol 1799, stirring and mixing for 30 minutes at the rotating speed of 3000-plus 5000rpm, then adding citric acid, ammonium fluoride, ammonium bifluoride, perfluorosilane and sucrose, continuously stirring for 30 minutes, then adding starch and barium sulfate, continuously stirring for 60 minutes, and grinding by a three-roll machine to ensure that the fineness of the mixture reaches 280-plus 320 meshes;
the component B is prepared by mixing the following raw material components: 800 g of water, 300 g of potassium fluoride, 100 g of potassium nitrate and 200 g of glycerol;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding potassium fluoride and potassium nitrate, quickly stirring and mixing for 30 minutes, then adding glycerol, and continuously stirring for 30 minutes to obtain the component B.
4. The method according to claim 1, wherein in the step (4), the etching ink is prepared from a component A and a component B in a mass ratio of 3: 1, mixing;
wherein the component A comprises the following raw material components: 450 g of water, 100 g of xanthan gum, 150 g of ammonium fluoride, 500 g of ammonium bifluoride, 250 g of hydrochloric acid, 150 g of barium sulfate and 50 g of starch;
the preparation method of the component A comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding xanthan gum, stirring at the rotating speed of 3000rpm for 30 minutes, then sequentially adding ammonium fluoride, ammonium bifluoride, hydrochloric acid, barium sulfate and starch, stirring for 30 minutes, and grinding to the fineness of 280-320 meshes by using a three-roll mill;
the component B is prepared by mixing the following raw material components: 800 g of water, 200 g of potassium chloride, 100 g of potassium bifluoride, 50 g of white carbon black and 200 g of glycerol;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, sequentially adding potassium chloride and potassium bifluoride, adding white carbon black and glycerol after crystals are completely dissolved, and quickly stirring for 30 minutes to obtain the component B.
5. The method according to claim 1, wherein in the step (4), the etching ink is prepared from a component A and a component B in a mass ratio of 3: 1, mixing;
wherein the component A comprises the following raw material components: 1000 g of water, 200 g of ammonium fluoride, 400 g of ammonium bifluoride, 50 g of xanthan gum, 50 g of starch, 50 g of oxalic acid, 50 g of sulfuric acid, 50 g of sucrose, 5 g of perfluorosilane and 200 g of barium sulfate;
the preparation method of the component A comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, sequentially adding ammonium fluoride, ammonium bifluoride and xanthan gum, stirring at the rotating speed of 3000rpm for 30 minutes, then adding starch, oxalic acid, sulfuric acid, sucrose, perfluorosilane and barium sulfate, continuously stirring for 2 hours, and grinding by a three-roll machine to ensure that the fineness reaches 280-320 meshes;
the component B is prepared by mixing the following raw material components: 800 g of water, 200 g of potassium chloride, 40 g of ferric chloride, 50 g of 40% hydrofluoric acid, 50 g of calcium fluoride, 200 g of ethylene glycol and 100 g of white carbon black;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding potassium chloride, ferric chloride, 40% hydrofluoric acid, calcium fluoride and ethylene glycol, quickly stirring for 30 minutes, then adding white carbon black, continuously stirring for 30 minutes, and grinding by a three-roll machine to ensure that the fineness of the white carbon black reaches 200-300 meshes to obtain the component B.
6. The method according to claim 1, wherein in the step (4), the etching ink is prepared from a component A and a component B in a mass ratio of 1: 1, mixing;
wherein the component A comprises the following raw material components: 1000 g of water, 500 g of ammonium bifluoride, 50 g of sulfamic acid, 50 g of xanthan gum, 50 g of starch, 100 g of hydrochloric acid, 50 g of sucrose, 5 g of perfluorosilane and 200 g of barium sulfate;
the preparation method of the component A comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, sequentially adding ammonium bifluoride, sulfamic acid and xanthan gum, stirring at the rotating speed of 3000rpm for 30 minutes, then adding starch, hydrochloric acid, sucrose, perfluorosilane and barium sulfate, continuously stirring for 2 hours, and grinding by a three-roll machine to ensure that the fineness reaches 280-320 meshes;
the component B is prepared by mixing the following raw material components: 800 g of water, 50 g of potassium chloride, 100 g of magnesium chloride, 30 g of sodium fluosilicate, 20 g of calcium chloride, 100 g of 40% hydrofluoric acid, 50 g of calcium fluoride, 100 g of white carbon black and 100 g of glycerol;
the preparation method of the component B comprises the following steps: adding water into a beaker with a stirrer, starting the stirrer, adding potassium chloride, magnesium chloride, sodium fluosilicate, calcium chloride, 40% hydrofluoric acid and calcium fluoride, quickly stirring for 30 minutes, then adding white carbon black and glycerol, continuously stirring for 30 minutes, and grinding by a three-roller machine to ensure that the fineness of the mixture reaches 200-300 meshes, thus obtaining the component B.
7. The AG anti-glare glass produced according to the method of claim 3, wherein the AG anti-glare glass has a surface roughness Ra of 0.05 to 0.1 μm.
8. The AG anti-glare glass produced according to the method of claim 4, wherein the AG anti-glare glass has a surface roughness Ra of 0.1 to 0.2 μm.
9. The AG anti-glare glass produced according to the method of claim 5, wherein the AG anti-glare glass has a surface roughness Ra of 0.2 to 0.4 μm.
10. The AG anti-glare glass produced according to the method of claim 6, wherein the AG anti-glare glass has a surface roughness Ra of 0.8 to 1.2 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110702448.8A CN113493310A (en) | 2021-06-22 | 2021-06-22 | AG anti-glare glass and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110702448.8A CN113493310A (en) | 2021-06-22 | 2021-06-22 | AG anti-glare glass and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113493310A true CN113493310A (en) | 2021-10-12 |
Family
ID=77997700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110702448.8A Pending CN113493310A (en) | 2021-06-22 | 2021-06-22 | AG anti-glare glass and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113493310A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115557707A (en) * | 2022-10-21 | 2023-01-03 | 江西沃格光电股份有限公司 | Frosting powder composition, frosting liquid, preparation method, frosting method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110753736A (en) * | 2016-12-29 | 2020-02-04 | 康宁公司 | Glass etching composition and method for producing antiglare glass |
| US20200361812A1 (en) * | 2019-05-17 | 2020-11-19 | Corning Incorporated | Method of modifying a textured glass substrate with a region under compressive stress to increase strength of the glass substrate |
-
2021
- 2021-06-22 CN CN202110702448.8A patent/CN113493310A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110753736A (en) * | 2016-12-29 | 2020-02-04 | 康宁公司 | Glass etching composition and method for producing antiglare glass |
| US20200361812A1 (en) * | 2019-05-17 | 2020-11-19 | Corning Incorporated | Method of modifying a textured glass substrate with a region under compressive stress to increase strength of the glass substrate |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115557707A (en) * | 2022-10-21 | 2023-01-03 | 江西沃格光电股份有限公司 | Frosting powder composition, frosting liquid, preparation method, frosting method and application |
| CN115557707B (en) * | 2022-10-21 | 2024-02-23 | 江西沃格光电股份有限公司 | Frosting powder composition, frosting liquid, preparation method, frosting method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108191253B (en) | Frosting liquid, preparation method and application thereof, and method for preparing anti-dazzle glass | |
| CN105884202B (en) | A kind of high anti-dazzle glas and its preparation process | |
| CN101215097B (en) | Formulation of anti-dazzle glass product etching liquid and etching technique | |
| CN102432185B (en) | Etching liquid and etching process for anti-dazzle glass product | |
| CN107739159B (en) | High-haze low-glossiness anti-glare film and preparation method thereof | |
| CN101314522B (en) | Method for preparing anti-dazzle glass | |
| CN102887647A (en) | Process for producing anti-glare glass by using high-boron silicon and high-aluminium silicon glasses | |
| CN113493310A (en) | AG anti-glare glass and production method thereof | |
| CN111233339A (en) | Glass etching solution, high-alumina-silica glass etching method and high-alumina-silica glass with texture on surface | |
| CN109604630B (en) | High-length-diameter-ratio silver nanowire and preparation method thereof | |
| US11560330B2 (en) | Patterned glass articles and methods of making the same | |
| CN106186713A (en) | A kind of anti-dazzle glas etching solution and the method utilizing this anti-dazzle liquid processing anti-dazzle glas | |
| CN110903035A (en) | Anti-glare glass and preparation method thereof | |
| CN113213770A (en) | Local AG glass processing method | |
| CN103934756B (en) | The processing technology of glare proof glass | |
| TW201938505A (en) | Anti-glare glass sheet | |
| US20190062202A1 (en) | Low sparkle glass sheet and process of making it | |
| CN114195400A (en) | Production method of low-cost anti-dazzle 3D curved glass | |
| CN114426401A (en) | Local AG anti-glare glass and preparation method thereof | |
| US20220153633A1 (en) | Production Method for Sheets of Glass with a Diffuse Finish, and Resulting Sheet of Glass | |
| CN205787185U (en) | A kind of LCDs two-in-one plated film of anti-dazzle antireflective | |
| CN106630667A (en) | An anti-glare (AG) glass processing process adopting silicon oxide sedimentation | |
| CN112062475B (en) | Manufacturing process for square flash point effect of high-alumina-silica glass | |
| CN116675438A (en) | Frosting powder for non-flash point anti-dazzle glass and preparation method and application thereof | |
| CN114873925B (en) | Multi-texture frosted glass and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211012 |