CN113481739A - Adjuvant formula for tablecloth dyeing and manufacturing method of carmine dye - Google Patents
Adjuvant formula for tablecloth dyeing and manufacturing method of carmine dye Download PDFInfo
- Publication number
- CN113481739A CN113481739A CN202110696184.XA CN202110696184A CN113481739A CN 113481739 A CN113481739 A CN 113481739A CN 202110696184 A CN202110696184 A CN 202110696184A CN 113481739 A CN113481739 A CN 113481739A
- Authority
- CN
- China
- Prior art keywords
- carmine
- dyeing
- dye
- tablecloth
- auxiliary agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 235000012730 carminic acid Nutrition 0.000 title claims abstract description 54
- 238000004043 dyeing Methods 0.000 title claims abstract description 40
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000002671 adjuvant Substances 0.000 title description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 21
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 13
- 230000000996 additive effect Effects 0.000 claims abstract description 13
- 229960001631 carbomer Drugs 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 238000000605 extraction Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229960000583 acetic acid Drugs 0.000 claims description 4
- 239000012362 glacial acetic acid Substances 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 229940037003 alum Drugs 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000243 solution Substances 0.000 description 18
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000003929 acidic solution Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000004106 carminic acid Substances 0.000 description 1
- 210000003855 cell nucleus Anatomy 0.000 description 1
- 229940080423 cochineal Drugs 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67316—Acids
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The invention discloses an auxiliary formula for tablecloth dyeing and a manufacturing method of carmine dye, wherein the auxiliary formula comprises the following components in parts by weight: 22-28% of hypochlorous acid solution, 42-48% of glycerol solution, 0.2-0.3% of carbomer additive and the balance of water, wherein the concentration of the hypochlorous acid solution is 8-10mol/L, and the concentration of the glycerol solution is 5-6 mol/L. According to the auxiliary agent formula for tablecloth dyeing and the manufacturing method of the carmine dye, the auxiliary agent is added, and glycerin is used as a medium to avoid the carmine from caking, so that the stability of the pH value of the carmine dye is well ensured, the stability of the color of the carmine is ensured, the viscosity of a system of the auxiliary agent is ensured on the premise of not influencing the dyeing effect of the carmine by using the carbomer additive, the carmine and the auxiliary agent can be better combined, and high-concentration carmine is not required and multiple dyeing operations are not required.
Description
Technical Field
The invention relates to the technical field of tablecloth dyeing, in particular to an auxiliary formula for tablecloth dyeing and a manufacturing method of carmine dye.
Background
Carmine is called carmine or carmine, which is prepared by drying tropical female cochineal, grinding into powder, extracting carmine, treating with Alumen, and removing impurities. Pure carmine cannot be dyed and can be dyed after being dissolved in acidic or alkaline solution, wherein the commonly used acidic solution comprises glacial acetic acid or picric acid, and the alkaline solution comprises ammonia water, borax and the like. The carmine makes excellent dye for cell nucleus and dyed specimen not easy to fade, and is suitable for dyeing section or tissue block, especially for dyeing small material integrally.
In the prior art, the magenta is directly used as a magenta dye for dyeing after being mixed with an acidic liquid, and the magenta dye has poor color stability and is easy to fade, so that the magenta with higher concentration is needed for ensuring the dyeing concentration, and the dyeing operation needs to be carried out for multiple times, so that the cost is increased, and meanwhile, the waste of the magenta is easily caused.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides an auxiliary formula for dyeing tablecloths and a manufacturing method of a carmine dye, and solves the problems that in the prior art, carmine is mixed with an acidic liquid and then directly used as the carmine dye for dyeing operation, the carmine dye has poor color stability and is easy to fade, so that carmine with higher concentration is needed for ensuring the dyeing concentration, and meanwhile, the dyeing operation needs to be carried out for multiple times, so that the cost is increased and the waste of the carmine is easily caused.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: an adjuvant formulation for tablecloth dyeing, the adjuvant formulation comprising: 22-28% of hypochlorous acid solution, 42-48% of glycerol solution, 0.2-0.3% of carbomer additive and the balance of water, wherein the concentration of the hypochlorous acid solution is 8-10mol/L, and the concentration of the glycerol solution is 5-6 mol/L.
The manufacturing method of the carmine dye for dyeing the tablecloth comprises the following specific operations:
s1, calculating and preparing a hypochlorous acid solution, a glycerol solution, a carbomer additive and water according to the formula of the assistant for dyeing the tablecloth and the production requirement;
s2, mixing the hypochlorous acid solution obtained in the step S1, water and a glycerol solution at normal temperature, and stirring for 30-40min to obtain a primary auxiliary agent;
s3, adding the carbomer additive obtained in the step S1 into the primary auxiliary obtained in the step S2, and then mixing and stirring for 30-40min at normal temperature to obtain an auxiliary;
s4, treating carmine with alum, removing impurities, and making carmine;
s5, selecting the carmine with specific mass obtained in the step S4, and mixing the carmine and the glycerol for 1-1.5h at normal temperature according to the mass ratio of 3:2 to prepare a dye base solution;
s6, adding the auxiliary agent obtained in the step S3 into the dye base liquid for mixing, wherein the mass ratio of the auxiliary agent to the dye base liquid is determined according to the dyeing concentration required by the product, and standing for more than 1 day to prepare the magenta dye;
s7, when the magenta dye is used, the magenta dye is mixed for 30min at normal temperature before extraction, and after extraction, the magenta dye and glacial acetic acid are mixed for 30min at normal temperature according to production requirements, and then dyeing operation can be carried out.
(III) advantageous effects
The invention provides an auxiliary formula for tablecloth dyeing and a manufacturing method of carmine dye. The method has the following beneficial effects:
according to the auxiliary agent formula for tablecloth dyeing and the manufacturing method of the carmine dye, the auxiliary agent is added, and glycerin is used as a medium to avoid the carmine from caking, so that the stability of the pH value of the carmine dye is well ensured, the stability of the color of the carmine is ensured, the viscosity of a system of the auxiliary agent is ensured on the premise of not influencing the dyeing effect of the carmine by using the carbomer additive, the carmine and the auxiliary agent can be better combined, and high-concentration carmine is not required and multiple dyeing operations are not required.
Detailed Description
The described embodiments are only some embodiments of the invention, not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
An auxiliary formula for tablecloth dyeing, which comprises the following components: 22-28% of hypochlorous acid solution, 42-48% of glycerol solution, 0.2-0.3% of carbomer additive and the balance of water, wherein the concentration of the hypochlorous acid solution is 8-10mol/L, and the concentration of the glycerol solution is 5-6 mol/L.
A manufacturing method of carmine dye for dyeing tablecloth comprises the following specific operations:
s1, calculating and preparing a hypochlorous acid solution, a glycerol solution, a carbomer additive and water according to the formula of the assistant for dyeing the tablecloth and the production requirement;
s2, mixing the hypochlorous acid solution obtained in the step S1, water and a glycerol solution at normal temperature, and stirring for 30-40min to obtain a primary auxiliary agent;
s3, adding the carbomer additive obtained in the step S1 into the primary auxiliary obtained in the step S2, and then mixing and stirring for 30-40min at normal temperature to obtain an auxiliary;
s4, treating carmine with alum, removing impurities, and making carmine;
s5, selecting the carmine with specific mass obtained in the step S4, and mixing the carmine and the glycerol for 1-1.5h at normal temperature according to the mass ratio of 3:2 to prepare a dye base solution;
s6, adding the auxiliary agent obtained in the step S3 into the dye base liquid for mixing, wherein the mass ratio of the auxiliary agent to the dye base liquid is determined according to the dyeing concentration required by the product, and standing for more than 1 day to prepare the magenta dye;
s7, when the magenta dye is used, the magenta dye is mixed for 30min at normal temperature before extraction, and after extraction, the magenta dye and glacial acetic acid are mixed for 30min at normal temperature according to production requirements, and then dyeing operation can be carried out.
In conclusion, the auxiliary agent formula for dyeing the tablecloth and the manufacturing method of the carmine dye have the advantages that the auxiliary agent is added, the glycerin is used as a medium to avoid the caking of the carmine, the stability of the pH value of the carmine dye is well guaranteed, the stability of the color of the carmine is guaranteed, the viscosity of the auxiliary agent is guaranteed on the premise of not influencing the dyeing effect of the carmine by using the carbomer additive, the carmine and the auxiliary agent can be better combined, and high-concentration carmine is not needed and multiple dyeing operations are not needed.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (2)
1. An auxiliary formula for tablecloth dyeing is characterized by comprising the following components in parts by weight: 22-28% of hypochlorous acid solution, 42-48% of glycerol solution, 0.2-0.3% of carbomer additive and the balance of water, wherein the concentration of the hypochlorous acid solution is 8-10mol/L, and the concentration of the glycerol solution is 5-6 mol/L.
2. A manufacturing method of carmine dye for dyeing tablecloth is characterized by comprising the following steps: the assistant for tablecloth dyeing according to claim 1, comprising the following steps:
s1, calculating and preparing a hypochlorous acid solution, a glycerol solution, a carbomer additive and water according to the formula of the assistant for dyeing the tablecloth and the production requirement;
s2, mixing the hypochlorous acid solution obtained in the step S1, water and a glycerol solution at normal temperature, and stirring for 30-40min to obtain a primary auxiliary agent;
s3, adding the carbomer additive obtained in the step S1 into the primary auxiliary obtained in the step S2, and then mixing and stirring for 30-40min at normal temperature to obtain an auxiliary;
s4, treating carmine with alum, removing impurities, and making carmine;
s5, selecting the carmine with specific mass obtained in the step S4, and mixing the carmine and the glycerol for 1-1.5h at normal temperature according to the mass ratio of 3:2 to prepare a dye base solution;
s6, adding the auxiliary agent obtained in the step S3 into the dye base liquid for mixing, wherein the mass ratio of the auxiliary agent to the dye base liquid is determined according to the dyeing concentration required by the product, and standing for more than 1 day to prepare the magenta dye;
s7, when the magenta dye is used, the magenta dye is mixed for 30min at normal temperature before extraction, and after extraction, the magenta dye and glacial acetic acid are mixed for 30min at normal temperature according to production requirements, and then dyeing operation can be carried out.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110696184.XA CN113481739A (en) | 2021-06-23 | 2021-06-23 | Adjuvant formula for tablecloth dyeing and manufacturing method of carmine dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110696184.XA CN113481739A (en) | 2021-06-23 | 2021-06-23 | Adjuvant formula for tablecloth dyeing and manufacturing method of carmine dye |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113481739A true CN113481739A (en) | 2021-10-08 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110696184.XA Pending CN113481739A (en) | 2021-06-23 | 2021-06-23 | Adjuvant formula for tablecloth dyeing and manufacturing method of carmine dye |
Country Status (1)
| Country | Link |
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| CN (1) | CN113481739A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR574819A (en) * | 1922-12-26 | 1924-07-19 | Du Pont | Basic dye enhancements |
| CN102256627A (en) * | 2008-12-19 | 2011-11-23 | 弗路荣有限公司 | Dye solution |
| CN105441065A (en) * | 2015-11-18 | 2016-03-30 | 浙江理工大学 | Fluorescent probe for detecting hypochlorite ions as well as preparation method and using method thereof |
| CN108147590A (en) * | 2018-02-24 | 2018-06-12 | 沈阳富创精密设备有限公司 | The processing method of dyeing waste-water |
| CN109846742A (en) * | 2019-02-12 | 2019-06-07 | 西南医科大学 | A kind of polychrome hair dyed agent and preparation method thereof and hair colouring methods |
| CN112336877A (en) * | 2020-11-09 | 2021-02-09 | 天津晶明新技术开发有限公司 | Staining solution for eye surface staining and preparation method thereof |
-
2021
- 2021-06-23 CN CN202110696184.XA patent/CN113481739A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR574819A (en) * | 1922-12-26 | 1924-07-19 | Du Pont | Basic dye enhancements |
| CN102256627A (en) * | 2008-12-19 | 2011-11-23 | 弗路荣有限公司 | Dye solution |
| CN105441065A (en) * | 2015-11-18 | 2016-03-30 | 浙江理工大学 | Fluorescent probe for detecting hypochlorite ions as well as preparation method and using method thereof |
| CN108147590A (en) * | 2018-02-24 | 2018-06-12 | 沈阳富创精密设备有限公司 | The processing method of dyeing waste-water |
| CN109846742A (en) * | 2019-02-12 | 2019-06-07 | 西南医科大学 | A kind of polychrome hair dyed agent and preparation method thereof and hair colouring methods |
| CN112336877A (en) * | 2020-11-09 | 2021-02-09 | 天津晶明新技术开发有限公司 | Staining solution for eye surface staining and preparation method thereof |
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| Title |
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| E.MENEZES等: "染整废水处理的新进展", 《国外纺织技术》 * |
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Application publication date: 20211008 |