CN113455872A - Nano silver wire stone needle fiber magnetic therapy pillow - Google Patents

Nano silver wire stone needle fiber magnetic therapy pillow Download PDF

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Publication number
CN113455872A
CN113455872A CN202110917659.3A CN202110917659A CN113455872A CN 113455872 A CN113455872 A CN 113455872A CN 202110917659 A CN202110917659 A CN 202110917659A CN 113455872 A CN113455872 A CN 113455872A
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stone needle
solution
nano silver
pillow
silver wire
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CN113455872B (en
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方彦雯
方志财
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Heye Health Technology Co Ltd
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Heye Health Technology Co Ltd
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    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/10—Pillows
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/007—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows comprising deodorising, fragrance releasing, therapeutic or disinfecting substances
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/02—Bed linen; Blankets; Counterpanes
    • A47G9/0238—Bed linen
    • A47G9/0253—Pillow slips
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N2/00—Magnetotherapy
    • A61N2/002—Magnetotherapy in combination with another treatment
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N2/00—Magnetotherapy
    • A61N2/06—Magnetotherapy using magnetic fields produced by permanent magnets
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N5/00—Radiation therapy
    • A61N5/06—Radiation therapy using light
    • A61N5/0613—Apparatus adapted for a specific treatment
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N5/00—Radiation therapy
    • A61N5/06—Radiation therapy using light
    • A61N2005/0658—Radiation therapy using light characterised by the wavelength of light used
    • A61N2005/0659—Radiation therapy using light characterised by the wavelength of light used infrared

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  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Public Health (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Animal Behavior & Ethology (AREA)
  • Radiology & Medical Imaging (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Otolaryngology (AREA)
  • Pulmonology (AREA)
  • Pathology (AREA)
  • Magnetic Treatment Devices (AREA)

Abstract

The invention relates to the technical field of massage articles, in particular to a nano silver wire stone needle fiber magnetic therapy pillow which can carry out magnetic therapy on the head of a person and can be used for normal rest of the person by arranging the equipment, so that the practicability is improved, and the functions are increased; including the pillow, the fixed plate, the slider, the annular ring, the gear, pivot and pillowcase, the fixed plate is installed respectively on pillow top and bottom, the slider is installed respectively in the fixed plate outside, the inside spout that all is provided with of annular ring, slider on the fixed plate slides respectively in the spout of annular ring, the inside annular of annular ring is provided with the tooth, the fixed plate right part all is provided with the gear groove, the gear is located the gear inslot respectively, the gear meshes with the tooth mutually, the pillowcase is installed on the annular ring, the pillowcase one side is thicker the one side and is thinner.

Description

Nano silver wire stone needle fiber magnetic therapy pillow
Technical Field
The invention relates to the technical field of massage articles, in particular to a nano silver wire stone needle fiber magnetic therapy pillow.
Background
The stone needle is named as magical stone and also named as stone capable of treating diseases, is a precious rock variety, has little reserve, is microcrystalline limestone and has the main chemical component ofCalcium carbonate. The microcrystalline limestone is mostly used as a traditional Chinese medicine physical therapy appliance, a health care product and the like, has no radioactivity and is harmless to a human body; the stone needle contains more than forty trace elements and mineral substances beneficial to human bodies and more than twenty anti-aging elements, has a singular energy field, can generate infrared rays and ultrasonic waves when acting on the human bodies, can move along the channels, and has the effect of health preservation.
However, the existing magnetic therapy pillow can only be used when people need to perform magnetic therapy, cannot be used for people to have a rest normally, and has single function and poor practicability.
Disclosure of Invention
In order to solve the technical problems, the invention provides the nano silver wire stone needle fiber magnetic therapy pillow which can carry out magnetic therapy on the head of a person, can be used for normal rest of the person, improves the practicability and increases the functions.
The invention relates to a nano silver wire stone needle fiber magnetic therapy pillow which comprises a pillow inner, two groups of fixing plates, four groups of sliding blocks, two groups of annular rings, two groups of gears, a rotating shaft and a pillow case, wherein the two groups of fixing plates are respectively arranged at the top end and the bottom end of the pillow inner, the four groups of sliding blocks are respectively arranged at the outer sides of the two groups of fixing plates, the two groups of sliding blocks on the two groups of fixing plates respectively slide in the four groups of sliding grooves of the two groups of annular rings, the two groups of annular rings are internally and annularly provided with teeth, the right parts of the two groups of fixing plates are respectively provided with gear grooves, the bottom end of the rotating shaft penetrates through an upper side gear groove in the upper side fixing plate, the pillow inner and a lower side fixing plate to be rotatably arranged in the lower side gear grooves, the rotating shaft is rotatably connected with the two groups of fixing plates and the pillow inner, the two groups of gears are respectively arranged in the two groups of gear grooves, and are meshed with the two groups of teeth, the pillowcase is arranged on the two groups of annular rings, and one side of the pillowcase is thicker and the other side is thinner.
According to the nano silver wire stone needle fiber magnetic therapy pillow, zippers are arranged on the pillowcase and the two groups of annular rings, and the pillowcase and the two groups of annular rings are detachably connected through the zippers.
The invention relates to a nano silver wire stone needle fiber magnetic therapy pillow which further comprises a bent pipe, wherein the bent pipe is installed at the top end of a rotating shaft.
The invention relates to a nano silver wire stone needle fiber magnetic therapy pillow which further comprises a telescopic rod, wherein the telescopic rod is slidably arranged in a bent pipe.
The invention relates to a nano silver wire stone needle fiber magnetic therapy pillow which further comprises a handle, wherein the handle is rotatably arranged on the right side of the top end of a telescopic rod.
The invention relates to a nano silver wire stone needle fiber magnetic therapy pillow which further comprises a support frame, wherein the support frame is installed on a lower side fixing plate.
According to the nano silver wire stone needle fiber magnetic therapy pillow, the handle is provided with the handle sleeve.
According to the nano silver wire stone needle fiber magnetic therapy pillow, the bent pipe is detachably connected with the rotating shaft.
Preferably, the pillow inner and/or the pillowcase are/is woven by nano silver thread stone needle fibers.
More preferably, the preparation method of the nano silver wire stone needle fiber material comprises the following steps:
1) dissolving polyvinylpyrrolidone, iodide and stone needle powder in ethylene glycol, wherein the mass ratio of polyvinylpyrrolidone to iodide to stone needle powder is 160-260: 1: 30-50, fully stirring and dissolving to obtain a solution A;
2) dissolving silver nitrate in an ethylene glycol solution, stirring until the silver nitrate is dissolved, wherein the mass ratio of the silver nitrate to the stone needle powder is 1: 1-3, obtaining a solution B;
3) stirring and heating the solution A to 140-180 ℃, turning off the heating, and uniformly adding the solution B into the solution A;
4) after full reaction, quickly cooling to room temperature, stopping the reaction, and washing the reaction by using an organic solvent to obtain superfine nano silver wires/stone needles;
5) dissolving 30-35 parts by weight of superfine nano silver wire/stone needle in 40-60 parts by weight of polar solvent, adding 25-30 parts by weight of chitosan, magnetically stirring at room temperature for 30-60 min, and fully mixing to prepare a uniform spinning solution; the concentration of the spinning solution is 1-65 wt%;
6) and spinning the spinning solution by using an electrostatic spinning device to obtain the superfine nano silver wire/stone needle fiber material.
According to the invention, the stone needle in the traditional Chinese medical therapy is used as a material to be added into the processing process of the antibacterial material, silver is a metal simple substance with a very good antibacterial and disinfection effect, and is widely applied to the antibacterial field, and the nano silver wire has better stability than nano silver particles and can be applied to the textile field; the superfine nano silver wire/stone needle fiber capable of releasing infrared rays and resisting bacteria is prepared by adding silver nitrate, so that the conductivity of the fiber is further improved, and the prepared superfine nano silver wire/stone needle fiber has the function of releasing infrared rays.
The invention provides a preparation method of a nano silver wire stone needle fiber material, wherein the nano silver wire has a larger specific surface area, so that more sites of the nano silver wire are in contact with bacterial colonies, and the antibacterial and bacteriostatic effects can be better achieved; according to the traditional Chinese medicine, the stone needle has the effects of soothing the nerves, regulating qi and blood and dredging channels and collaterals, certain treatment and health care functions are achieved through microcrystalline infrared rays and pulses, the stone needle fiber can promote blood circulation and help sleep, and the nano silver wire/stone needle fiber antibacterial material has the double functions of antibiosis and health care by combining the microcrystalline infrared rays and the microcrystalline infrared rays; the preparation process is relatively simple and easy to operate.
Although the pillowcase and pillow core in the current market have antibacterial function, the effect is general, and the pillow can not play a good role in protecting skin. The stone needle is less applied to the textile pillow, and the nano silver wire has larger specific surface area, so that more sites are in contact with bacterial colonies, and the antibacterial and bacteriostatic effects can be better achieved; the pillow can resist bacteria, promote the blood circulation of the head in the process of wiping the pillow with the skin and is helpful for sleeping through the double modification of the stone needle fiber and the nano silver; the combination of the two can make the pillow have the functions of antibiosis and health care.
Preferably, the preparation method of the nano silver wire stone needle fiber material comprises the following specific steps:
1) dissolving polyvinylpyrrolidone, iodide and stone needle powder in ethylene glycol, wherein the mass ratio of polyvinylpyrrolidone to iodide to stone needle powder is 200: 1: 40, fully stirring and dissolving to obtain a solution A;
2) dissolving silver nitrate in an ethylene glycol solution, and stirring until the silver nitrate is dissolved, so that the mass ratio of the stone needle powder to the silver nitrate is 2: 1, obtaining a solution B;
3) stirring and heating the solution A to 140-180 ℃, turning off the heating, and uniformly adding the solution B into the solution A;
4) after full reaction, quickly cooling to room temperature, stopping the reaction, and washing the reaction with an organic solvent for 3-5 times to obtain the superfine nano silver wire stone needle;
5) dissolving 30-35 parts by weight of superfine nano silver wire stone needle into 40-60 parts by weight of polar solvent, adding 25-30 parts by weight of chitosan, magnetically stirring at room temperature for 30-60 min, and fully mixing to prepare uniform spinning solution; the concentration of the spinning solution is 1-65%;
6) and spinning the spinning solution by using an electrostatic spinning device to obtain the superfine nano silver wire/stone needle fiber material.
Preferably, an antistatic composite system is added into the solution A, and the antistatic composite system comprises the following components in a mass ratio of 1: 2-5 of a mixture of mixed graphene powder and an antistatic fluid;
the preparation method of the antistatic fluid comprises the following steps:
(1) mixing the components in a mass ratio of 1: 1-3, grinding the mixed polytetrafluoroethylene and polyaniline to 30-150nm of particle size to obtain primary antistatic micro powder;
(2) mixing the primary antistatic micro powder and a modifier according to a mass ratio of 1: 2-3, carrying out modification treatment to obtain modified antistatic micro powder;
(3) adding the modified antistatic micro powder into butanol at the temperature of 40-60 ℃, and performing ultrasonic treatment and stirring for 60-120s to obtain the antistatic fluid.
Preferably, the modifier comprises: expanded graphite, glycerol, sulfuric acid and a dimethyl pyrrolidone solution.
Preferably, the modification treatment comprises: adding the primary antistatic micro powder into 0.2-0.4mol/L hydrochloric acid solution, stirring at constant temperature of 25-35 deg.C for 5-10min, adding glycerol and dimethyl pyrrolidone solution, stirring for 15-20min, and adding expanded graphite.
According to the invention, the glycerol, the dimethyl pyrrolidone and the expanded graphite are added to modify the primary antistatic micro powder, so that the obtained material has good electric conductivity and heat conductivity and better antistatic property.
More preferably, the method for preparing the expanded graphite comprises: will be provided withPotassium permanganateAndflake graphiteAdding into the mixture, stirring for 1-1.5h at constant temperature of 30-40 ℃ in water bath, filtering, washing with deionized water for multiple times, drying, and performing microwave action of 500-700W for 30-40s to obtain the expansionGraphite。
The fabric made of the nano silver wire stone needle fiber material prepared by the invention has the far infrared emissivity as high as 93 percent. The crystallinity of the superfine nano silver wires/stone needle fibers is improved by adopting a combined process, and the breaking strength of the superfine nano silver wires/stone needle fibers prepared by the method is 6.6-7.3 cN/dtex; the boiling water shrinkage is 1.8-2.5%.
Preferably, in the step 1), the iodide is one or a combination of sodium iodide, potassium iodide and lithium iodide.
Preferably, in the step 4), the organic solvent is one or a combination of acetone or ethanol.
Preferably, in the step 5), the polar solvent is one or a combination of formic acid, glacial acetic acid or trifluoroacetic acid; the deacetylation degree of the chitosan is 80-100%. The value of the deacetylation degree of the chitosan has an influence on the antibacterial effect of the finally obtained superfine silver nanowire/stone needle fiber, and if the deacetylation degree of the chitosan is too small or too large, the antibacterial rate of the superfine silver nanowire/stone needle fiber can be reduced.
Preferably, in the step 6), the electrostatic spinning process parameters are as follows: 1-50 kV, the receiving distance is 1-50 cm, and the solution flow is 0.01-20 mL/h.
Compared with the prior art, the invention has the beneficial effects that:
1. under normal conditions, the thicker side of the pillowcase is upward for people to have a normal rest, when people need to carry out magnetic therapy on the head, the rotating shaft is rotated to drive the two groups of gears to rotate, the two groups of gears are meshed with the two groups of teeth, the two groups of teeth drive the two groups of annular rings to rotate, the four groups of sliding blocks slide in the four groups of sliding grooves, the two groups of annular rings drive the pillowcase to rotate, when the thinner side of the pillowcase rotates to the upper side, the people place the head on the pillowcase, then the pillow core carries out magnetic therapy on the head of the people through the pillowcase, and by arranging the device, the magnetic therapy can be carried out on the head of the people, and the pillow can also be used for people to have a normal rest, so that the practicability and the functions of the pillow are improved;
2. although the pillowcase and pillow core in the current market have antibacterial function, the effect is general, and the pillow can not play a good role in protecting skin. The application of the stone needle in the textile pillow is less, and the superfine nano silver wire has larger specific surface area, so that more sites are in contact with bacterial colonies, and the antibacterial and bacteriostatic effects can be better achieved; the double modification of the stone needle fiber and the superfine nano silver can make the pillow antibacterial, promote the blood circulation of the head in the wiping process with the skin and be helpful for sleeping; the combination of the two can make the pillow have the functions of antibiosis and health care.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 is a schematic cross-sectional view of FIG. 1;
FIG. 3 is a schematic top cross-sectional view of FIG. 1;
FIG. 4 is an enlarged schematic view of A in FIG. 2;
in the drawings, the reference numbers: 1. a pillow core; 2. a fixing plate; 3. a slider; 4. an annular ring; 5. a chute; 6. teeth; 7. a gear groove; 8. a gear; 9. a rotating shaft; 10. a pillowcase; 11. a zipper; 12. bending the pipe; 13. a telescopic rod; 14. a handle; 15. a support frame.
Detailed Description
The following detailed description of embodiments of the present invention is provided in connection with the accompanying drawings and examples. The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
As shown in figures 1 to 4, the nano silver wire stone needle fiber magnetic therapy pillow comprises a pillow core 1, two groups of fixing plates 2, four groups of sliding blocks 3, two groups of annular rings 4, two groups of gears 8, a rotating shaft 9 and a pillow case 10, wherein the two groups of fixing plates 2 are respectively arranged at the top end and the bottom end of the pillow core 1, the four groups of sliding blocks 3 are respectively arranged at the outer sides of the two groups of fixing plates 2, two groups of sliding grooves 5 are respectively arranged inside the two groups of annular rings 4, the four groups of sliding blocks 3 on the two groups of fixing plates 2 respectively slide in the four groups of sliding grooves 5 of the two groups of annular rings 4, teeth 6 are annularly arranged inside the two groups of annular rings 4, gear grooves 7 are respectively arranged at the right parts of the two groups of fixing plates 2, the bottom end of the rotating shaft 9 penetrates through an upper side gear groove 7 in the upper side fixing plate 2, the pillow core 1 and the lower side fixing plate 2 and is rotatably arranged inside the lower side gear grooves 7, the rotating shaft 9 is rotatably connected with the two groups of fixing plates 2 and the pillow core 1, the two groups of gears 8 are respectively arranged at the upper part and the lower part of the rotating shaft 9, two groups of gears 8 are respectively positioned in two groups of gear grooves 7, the two groups of gears 8 are meshed with the two groups of teeth 6, a pillowcase 10 is arranged on the two groups of annular rings 4, and one surface of the pillowcase 10 is thicker and the other surface is thinner; under the normal condition, pillowcase 10's thick one side supplies people to carry out normal rest up, when the people need carry out the magnetotherapy to the head, through rotating pivot 9, pivot 9 then drives two sets of gear 8 rotations, two sets of gear 8 then with two sets of tooth 6 meshing, two sets of tooth 6 then drive two sets of rings 4 and rotate, four group's sliders 3 are then slided in four group's spouts 5, two sets of rings 4 then drive pillowcase 10 and rotate, when the thinner one side of pillowcase 10 rotates to the upside, the people places the head on pillowcase 10, then pillow 1 sees through pillowcase 10 and carries out the magnetotherapy to the head of people, through setting up this equipment, not only can carry out the magnetotherapy to the head of people, and also can supply people to normally have a rest and use, improve its practicality, increase its function.
According to the nano silver wire stone needle fiber magnetic therapy pillow, zippers 11 are arranged on a pillowcase 10 and two groups of annular rings 4, and the pillowcase 10 and the two groups of annular rings 4 are detachably connected through the zippers 11; through setting up zip fastener 11, be convenient for dismantle pillowcase 10 to be convenient for wash pillowcase 10.
The nano silver wire stone needle fiber magnetic therapy pillow further comprises a bent pipe 12, wherein the bent pipe 12 is installed at the top end of the rotating shaft 9; the elbow 12 is arranged to facilitate rotation of the rotating shaft 9.
The nano silver wire stone needle fiber magnetic therapy pillow further comprises a telescopic rod 13, wherein the telescopic rod 13 is slidably arranged in the bent pipe 12; by providing the telescopic rod 13, the length of the elbow 12 can be conveniently adjusted, thereby facilitating the operation thereof.
The nano silver wire stone needle fiber magnetic therapy pillow further comprises a handle 14, wherein the handle 14 is rotatably arranged on the right side of the top end of the telescopic rod 13; by arranging the handle 14, the telescopic rod 13 is convenient to operate.
The nano silver wire stone needle fiber magnetic therapy pillow further comprises a support frame 15, wherein the support frame 15 is installed on the lower side fixing plate 2; through setting up support frame 15, rotate pillowcase 10 when needs and make, make support frame 15 and plane contact, can reduce pillowcase 10 and planar friction, improve the practicality.
According to the nano silver wire stone needle fiber magnetic therapy pillow, a handle sleeve is arranged on the handle 14; the friction force can be increased, and the anti-skid function is realized.
According to the nano silver wire stone needle fiber magnetic therapy pillow, the bent pipe 12 is detachably connected with the rotating shaft 9; when the pillow case 10 needs to be rotated, the bent tube 12 is arranged on the rotating shaft 9, so that the bent tube 12 can be prevented from affecting the use of the pillow core 1 integrally.
The first embodiment is as follows:
1000g of polyvinylpyrrolidone, 5g of sodium iodide and 200g of stone needle powder are dissolved in ethylene glycol, wherein the mass ratio of the polyvinylpyrrolidone to the stone needle powder is 200: 1: 40, fully stirring and dissolving to obtain a solution A; dissolving 100g of silver nitrate in an ethylene glycol solution, and stirring until the silver nitrate is dissolved, wherein the mass ratio of the stone needle powder to the silver nitrate is 2: 1, obtaining a solution B; stirring and heating the solution A to 140 ℃, turning off the heating, and uniformly adding the solution B into the solution A; and after full reaction, quickly cooling to room temperature, stopping the reaction, and washing the reaction with an organic solvent acetone for 3 times to obtain the superfine nano silver wire/stone needle. Dissolving 30 parts by weight of superfine nano silver wires/stone needles in 40 parts by weight of polar solvent formic acid, adding 30 parts by weight of chitosan into the solution, wherein the deacetylation degree of the chitosan is 80%, magnetically stirring the mixture at room temperature for 60min, and fully mixing the mixture to prepare a uniform spinning solution; the concentration of the spinning solution is 1%; spinning the spinning solution by using an electrostatic spinning device, wherein the process parameters of electrostatic spinning are as follows: 10 kilovolt, the receiving distance is 10 cm, the solution flow is 5mL/h, and the superfine nano silver wire/stone needle fiber material is obtained.
The antibacterial result is as follows: the antibacterial rate of the escherichia coli is as follows: 99.2 percent; the antibacterial rate of staphylococcus aureus is as follows: 99.4 percent; the candida albicans is: 98.9 percent.
The fiber specific conductivity of the pillowcase prepared from nano silver line stone needle fiber material is 0.75 x 103Omega cm, specific conductance after hundred washes 1.12 x 103Ω*cm。
Example two:
1000g of polyvinylpyrrolidone, 5g of potassium iodide and 200g of stone needle powder are dissolved in ethylene glycol, wherein the mass ratio of the polyvinylpyrrolidone to the stone needle powder is 200: 1: 40, fully stirring and dissolving to obtain a solution A; dissolving 100g of silver nitrate in an ethylene glycol solution, and stirring until the silver nitrate is dissolved, wherein the mass ratio of the stone needle powder to the silver nitrate is 2: 1, obtaining a solution B; stirring and heating the solution A to 160 ℃, turning off the heating, and uniformly adding the solution B into the solution A; after full reaction, the temperature is quickly reduced to room temperature, the reaction is stopped, and the reaction is washed for 3 times by using organic solvent ethanol, so that the superfine nano silver wire/stone needle is obtained. Dissolving 30 parts by weight of superfine nano silver wires/stone needles in 50 parts by weight of polar solvent glacial acetic acid, adding 35 parts by weight of chitosan into the solution, wherein the deacetylation degree of the chitosan is 90%, magnetically stirring the solution at room temperature for 60min, and fully mixing the solution to prepare a uniform spinning solution; the concentration of the spinning solution is 5%; spinning the spinning solution by using an electrostatic spinning device, wherein the process parameters of electrostatic spinning are as follows: 20 kilovolt, the receiving distance is 20 cm, the solution flow is 2mL/h, and the superfine nano silver wire/stone needle fiber material is obtained.
The antibacterial result is as follows: the antibacterial rate of the escherichia coli is as follows: 98.3 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.1 percent; the candida albicans is: 98.6 percent.
The fiber specific conductivity of the pillowcase prepared from nano silver line stone needle fiber material is 0.75 x 103Omega cm, specific conductance after hundred washes 1.12 x 103Ω*cm。
Example three:
600g of polyvinylpyrrolidone, 3g of lithium iodide and 120g of stone needle powder are dissolved in ethylene glycol, wherein the mass ratio of the polyvinylpyrrolidone to the stone needle powder is 200: 1: 40, fully stirring and dissolving to obtain a solution A; dissolving 60g of silver nitrate in an ethylene glycol solution, and stirring until the silver nitrate is dissolved, so that the mass ratio of the stone needle powder to the silver nitrate is 2: 1, obtaining a solution B; stirring and heating the solution A to 180 ℃, turning off the heating, and uniformly adding the solution B into the solution A; after full reaction, the temperature is quickly reduced to room temperature, the reaction is stopped, and the reaction is washed for 3 times by using organic solvent ethanol, so that the superfine nano silver wire/stone needle is obtained. Dissolving 30 parts by weight of superfine nano silver wires/stone needles in 50 parts by weight of polar solvent trifluoroacetic acid, adding 35 parts by weight of chitosan into the solution, wherein the deacetylation degree of the chitosan is 90%, magnetically stirring the solution at room temperature for 60min, and fully mixing the solution to prepare a uniform spinning solution; the concentration of the spinning solution is 10%; spinning the spinning solution by using an electrostatic spinning device, wherein the process parameters of electrostatic spinning are as follows: 50 kilovolt, the receiving distance is 50 cm, the solution flow is 10mL/h, and the superfine nano silver wire/stone needle fiber material is obtained.
The antibacterial result is as follows: the antibacterial rate of the escherichia coli is as follows: 99.5 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.9 percent; the candida albicans is: 99.1 percent.
The fiber specific conductivity of the pillowcase prepared from nano silver line stone needle fiber material is 0.75 x 103Omega cm, specific conductance after hundred washes 1.12 x 103Ω*cm。
Example four
1) Dissolving polyvinylpyrrolidone, iodide and stone needle powder in ethylene glycol, wherein the mass ratio of polyvinylpyrrolidone to iodide to stone needle powder is 180: 1: 35, fully stirring and dissolving to obtain a solution A;
2) dissolving silver nitrate in an ethylene glycol solution, stirring until the silver nitrate is dissolved, wherein the mass ratio of the silver nitrate to the stone needle powder is 1: 2, obtaining a solution B;
3) stirring and heating the solution A to 160 ℃, turning off the heating, and uniformly adding the solution B into the solution A;
4) after full reaction, quickly cooling to room temperature, stopping the reaction, and washing the reaction by using an organic solvent to obtain superfine nano silver wires/stone needles;
5) dissolving 32 parts by weight of superfine nano silver wire/stone needle in 50 parts by weight of polar solvent, adding 28 parts by weight of chitosan, magnetically stirring for 40min at room temperature, and fully mixing to prepare a uniform spinning solution; the concentration of the spinning solution was 35 wt%;
6) and spinning the spinning solution by using an electrostatic spinning device to obtain the superfine nano silver wire/stone needle fiber material.
In step 1), the iodide is one or a combination of sodium iodide, potassium iodide and lithium iodide.
In the step 4), the organic solvent is one or a combination of acetone or ethanol.
In the step 5), the polar solvent is one or the combination of formic acid, glacial acetic acid or trifluoroacetic acid; the degree of deacetylation of chitosan was 90%.
In the step 6), the technological parameters of electrostatic spinning are as follows: 30 kV, receiving distance 20 cm, solution flow rate 80 mL/h.
The solution A is added with an anti-static composite system, wherein the anti-static composite system comprises the following components in a mass ratio of 1: 3 a mixture of the mixed graphene powder and an antistatic fluid;
the preparation method of the antistatic fluid comprises the following steps:
(1) mixing the components in a mass ratio of 1: 2 grinding and crushing the mixed polytetrafluoroethylene and polyaniline to the particle size of 90nm to obtain primary antistatic micro powder;
(2) mixing the primary antistatic micro powder and a modifier according to a mass ratio of 1: 2, carrying out modification treatment to obtain modified antistatic micro powder; the modifier comprises: expanded graphite, glycerol, sulfuric acid and a dimethyl pyrrolidone solution; the modification treatment comprises the following steps: adding the primary antistatic micro powder into a 0.3mol/L hydrochloric acid solution, stirring for 7min at a constant temperature of 28 ℃, adding a glycerol and dimethyl pyrrolidone solution, continuously stirring for 18min, and adding expanded graphite;
the preparation method of the expanded graphite comprises the following steps: will be provided withPotassium permanganateAndflake graphiteAdding into the mixture, stirring for 1.2h at constant temperature of 36 deg.C in water bath, filtering, washing with deionized water for several times, oven drying, and microwave treating at 600W for 30-40s to obtain the final productGraphite；
(3) Adding the modified antistatic micro powder into butanol at 50 ℃, and performing ultrasonic treatment and stirring for 80s to obtain the antistatic fluid.
The superfine nano silver wire/stone needle fiber finally prepared by the invention has the antibacterial result that: the antibacterial rate of the escherichia coli is as follows: 99.4 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.7 percent; the candida albicans is: 99.1 percent;
the far infrared emissivity of the material is as high as 93%. The breaking strength is 7.3 cN/dtex; the boiling water shrinkage was 2.5%. Antistatic performance parameters: the pillowcase prepared from nano silver line stone needle fiber material has the fiber specific conductance of 0.68 x 103Omega cm, specific conductance after hundred washes 1.05 x 103Ω*cm。
EXAMPLE five
1) Dissolving polyvinylpyrrolidone, iodide and stone needle powder in ethylene glycol, wherein the mass ratio of polyvinylpyrrolidone to iodide to stone needle powder is 260: 1: 50, fully stirring and dissolving to obtain a solution A;
2) dissolving silver nitrate in an ethylene glycol solution, stirring until the silver nitrate is dissolved, wherein the mass ratio of the silver nitrate to the stone needle powder is 1: 3, obtaining a solution B;
3) stirring and heating the solution A to 180 ℃, turning off the heating, and uniformly adding the solution B into the solution A;
4) after full reaction, quickly cooling to room temperature, stopping the reaction, and washing the reaction by using an organic solvent to obtain superfine nano silver wires/stone needles;
5) dissolving 35 parts by weight of superfine nano silver wire/stone needle in 60 parts by weight of polar solvent, adding 30 parts by weight of chitosan into the polar solvent, magnetically stirring the mixture at room temperature for 60min, and fully mixing the mixture to prepare uniform spinning solution;
the concentration of the spinning solution was 65 wt%;
6) and spinning the spinning solution by using an electrostatic spinning device to obtain the superfine nano silver wire/stone needle fiber material.
In step 1), the iodide is one or a combination of sodium iodide, potassium iodide and lithium iodide.
In the step 4), the organic solvent is one or a combination of acetone or ethanol.
In the step 5), the polar solvent is one or the combination of formic acid, glacial acetic acid or trifluoroacetic acid; the degree of deacetylation of chitosan was 100%.
In the step 6), the technological parameters of electrostatic spinning are as follows: 50 kV, receiving distance 50 cm, solution flow rate 20 mL/h.
The solution A is added with an anti-static composite system, wherein the anti-static composite system comprises the following components in a mass ratio of 1: 5, mixing the graphene powder and the antistatic fluid;
the preparation method of the antistatic fluid comprises the following steps:
(1) mixing the components in a mass ratio of 1: 3 grinding and crushing the mixed polytetrafluoroethylene and polyaniline to the particle size of 150nm to obtain primary antistatic micro powder;
(2) mixing the primary antistatic micro powder and a modifier according to a mass ratio of 1: 3, carrying out modification treatment to obtain modified antistatic micro powder; the modifier comprises: expanded graphite, glycerol, sulfuric acid and a dimethyl pyrrolidone solution; the modification treatment comprises the following steps: adding the primary antistatic micro powder into a 0.4mol/L hydrochloric acid solution, stirring for 10min at a constant temperature of 35 ℃, adding a glycerol and dimethyl pyrrolidone solution, continuously stirring for 20min, and adding expanded graphite;
the preparation method of the expanded graphite comprises the following steps: will be provided withPotassium permanganateAndflake graphiteAdding into the mixture, stirring for 1.5h at constant temperature of 40 deg.C in water bath, filtering, washing with deionized water for several times, oven drying, and microwave treating at 700W for 40s to obtain the final productGraphite；
(3) Adding the modified antistatic micro powder into butanol at 60 ℃, and performing ultrasonic treatment and stirring for 120s to obtain the antistatic fluid.
The superfine nano silver wire/stone needle fiber finally prepared by the invention has the antibacterial result that: the antibacterial rate of the escherichia coli is as follows: 99.2 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.5 percent; the candida albicans is: 99.0 percent;
the far infrared emissivity is as high as 93%; the breaking strength is 6.6 cN/dtex; the boiling water shrinkage was 1.8%.
Antistatic performance parameters: the fiber specific conductance of the pillowcase prepared from the nano silver line stone needle fiber material is 0.69 x 103Omega cm, specific conductance after hundred washes 1.08X 103Ω*cm。
EXAMPLE six
1) Dissolving polyvinylpyrrolidone, iodide and stone needle powder in ethylene glycol, wherein the mass ratio of polyvinylpyrrolidone to iodide to stone needle powder is 160: 1: 30, fully stirring and dissolving to obtain a solution A;
2) dissolving silver nitrate in an ethylene glycol solution, stirring until the silver nitrate is dissolved, wherein the mass ratio of the silver nitrate to the stone needle powder is 1: 2, obtaining a solution B;
3) stirring and heating the solution A to 140 ℃, turning off the heating, and uniformly adding the solution B into the solution A;
4) after full reaction, quickly cooling to room temperature, stopping the reaction, and washing the reaction by using an organic solvent to obtain superfine nano silver wires/stone needles;
5) dissolving 30 parts by weight of superfine nano silver wire/stone needle in 40 parts by weight of polar solvent, adding 25 parts by weight of chitosan into the polar solvent, magnetically stirring the mixture at room temperature for 30min, and fully mixing the mixture to prepare uniform spinning solution;
the concentration of the spinning solution is 1-65 wt%;
6) and spinning the spinning solution by using an electrostatic spinning device to obtain the superfine nano silver wire/stone needle fiber material.
In step 1), the iodide is one or a combination of sodium iodide, potassium iodide and lithium iodide.
In the step 4), the organic solvent is one or a combination of acetone or ethanol.
In the step 5), the polar solvent is one or the combination of formic acid, glacial acetic acid or trifluoroacetic acid; the degree of deacetylation of chitosan was 80%.
In the step 6), the technological parameters of electrostatic spinning are as follows: 1 kV, receiving distance 1 cm, solution flow rate 0.01 mL/h.
The solution A is added with an anti-static composite system, wherein the anti-static composite system comprises the following components in a mass ratio of 1: 2-5 of a mixture of mixed graphene powder and an antistatic fluid;
the preparation method of the antistatic fluid comprises the following steps:
(1) mixing the components in a mass ratio of 1: 1-3, grinding the mixed polytetrafluoroethylene and polyaniline to 30-150nm of particle size to obtain primary antistatic micro powder;
(2) mixing the primary antistatic micro powder and a modifier according to a mass ratio of 1: 2, carrying out modification treatment to obtain modified antistatic micro powder; the modifier comprises: expanded graphite, glycerol, sulfuric acid and a dimethyl pyrrolidone solution; the modification treatment comprises the following steps: adding the primary antistatic micro powder into a 0.2mol/L hydrochloric acid solution, stirring for 5min at a constant temperature of 25 ℃, adding a glycerol and dimethyl pyrrolidone solution, continuously stirring for 15-20min, and adding expanded graphite;
the preparation method of the expanded graphite comprises the following steps: will be provided withPotassium permanganateAndflake graphiteAdding into the mixture, stirring for 1h at constant temperature of 30 deg.C in water bath, filtering, washing with deionized water for several times, oven drying, and subjecting to 500W microwave for 30-40s to obtain the final productGraphite；
(3) Adding the modified antistatic micro powder into butanol at 40 ℃, and performing ultrasonic treatment and stirring for 60s to obtain the antistatic fluid.
The superfine nano silver wire/stone needle fiber finally prepared by the invention has the antibacterial result that: the antibacterial rate of the escherichia coli is as follows: 99.1 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.3 percent; the candida albicans is: 98.6 percent;
the far infrared emissivity is as high as 93%; the breaking strength is 6.8 cN/dtex; the boiling water shrinkage was 1.9%.
Antistatic performance parameters: the pillowcase prepared from nano silver line stone needle fiber material has the fiber specific conductance of 0.68 x 103Omega cm, specific conductance after hundred washes 1.07 x 103Ω*cm。
EXAMPLE seven
The method is similar to the first embodiment, except that an antistatic composite system is added into the solution A, and the antistatic composite system comprises the following components in a mass ratio of 1: 5, mixing the graphene powder and the antistatic fluid;
the preparation method of the antistatic fluid is the same as that of the fourth embodiment.
The superfine nano silver wire/stone needle fiber finally prepared by the invention has the antibacterial result that: the antibacterial rate of the escherichia coli is as follows: 99.5 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.9 percent; the candida albicans is: 99.1 percent;
the far infrared emissivity is as high as 93%; the breaking strength is 6.6 cN/dtex; the boiling water shrinkage was 1.8%.
Antistatic performance parameters: the pillowcase prepared from nano silver line stone needle fiber material has the fiber specific conductance of 0.65 x 103Omega cm, specific conductance after hundred washes 1.02 x 103Ω*cm。
Example eight
The method is similar to the second embodiment, except that an antistatic composite system is added into the solution A, and the antistatic composite system comprises the following components in a mass ratio of 1: 2, a mixture of the mixed graphene powder and an antistatic fluid;
the preparation method of the antistatic fluid is the same as that of the fifth embodiment.
The superfine nano silver wire/stone needle fiber finally prepared by the invention has the antibacterial result that: the antibacterial rate of the escherichia coli is as follows: 99.5 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.9 percent; the candida albicans is: 99.1 percent;
the far infrared emissivity of the material is as high as 93%. The breaking strength is 6.7 cN/dtex; the boiling water shrinkage was 1.9%.
Antistatic performance parameters: pillowcase prepared from nano silver line stone needle fiber material with fiber specific conductance of 0.64 x 103Omega cm, specific conductance after hundred washes 1.04 x 103Ω*cm。
Example nine
The method is similar to the third embodiment, except that an antistatic composite system is added into the solution A, and the antistatic composite system comprises the following components in a mass ratio of 1: 3 a mixture of the mixed graphene powder and an antistatic fluid;
the preparation method of the antistatic fluid is the same as that of the sixth embodiment.
The superfine nano silver wire/stone needle fiber finally prepared by the invention has the antibacterial result that: the antibacterial rate of the escherichia coli is as follows: 99.5 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.9 percent; the candida albicans is: 99.1 percent;
the far infrared emissivity of the material is as high as 93%. The breaking strength is 6.8 cN/dtex; the boiling water shrinkage was 1.8.
Antistatic performance parameters: the fiber specific conductance of the pillowcase prepared from the nano silver line stone needle fiber material is 0.63 x 103Omega cm, specific conductance after hundred washes 1.01 x 103Ω*cm。
Comparative example 1
1) Dissolving polyvinylpyrrolidone, iodide and stone needle powder in ethylene glycol, wherein the mass ratio of polyvinylpyrrolidone to iodide to stone needle powder is 150: 1: 60, fully stirring and dissolving to obtain a solution A;
2) dissolving silver nitrate in an ethylene glycol solution, stirring until the silver nitrate is dissolved, wherein the mass ratio of the silver nitrate to the stone needle powder is 1: 1, obtaining a solution B;
3) stirring and heating the solution A to 130 ℃, turning off the heating, and uniformly adding the solution B into the solution A;
4) after full reaction, quickly cooling to room temperature, stopping the reaction, and washing the reaction by using an organic solvent to obtain superfine nano silver wires/stone needles;
5) dissolving 40 parts by weight of superfine nano silver wire/stone needle in 35 parts by weight of polar solvent, adding 20 parts by weight of chitosan into the polar solvent, magnetically stirring the mixture at room temperature for 30min, and fully mixing the mixture to prepare uniform spinning solution;
the concentration of the spinning solution is 1-65 wt%;
6) and spinning the spinning solution by using an electrostatic spinning device to obtain the superfine nano silver wire/stone needle fiber material.
The antibacterial result is as follows: the antibacterial rate of the escherichia coli is as follows: 92.5 percent; the antibacterial rate of staphylococcus aureus is as follows: 93.9 percent; the candida albicans is: 99.1 percent; the far infrared emissivity is 85%; the breaking strength is 4.7 cN/dtex; the boiling water shrinkage was 1.7%. Antistatic performance parameters: the fiber specific conductivity of the pillowcase prepared from nano silver line stone needle fiber material is 0.61 x 103Omega cm, specific conductance after hundred washes is 0.93 x 103Ω*cm。
Comparative example No. two
1) Dissolving polyvinylpyrrolidone, iodide and stone needle powder in ethylene glycol, wherein the mass ratio of polyvinylpyrrolidone to iodide to stone needle powder is 260: 1: 20, fully stirring and dissolving to obtain a solution A;
2) dissolving silver nitrate in an ethylene glycol solution, stirring until the silver nitrate is dissolved, wherein the mass ratio of the silver nitrate to the stone needle powder is 1: 3, obtaining a solution B;
3) stirring and heating the solution A to 200 ℃, turning off the heating, and uniformly adding the solution B into the solution A;
4) after full reaction, quickly cooling to room temperature, stopping the reaction, and washing the reaction by using an organic solvent to obtain superfine nano silver wires/stone needles;
5) dissolving 30 parts by weight of superfine nano silver wire/stone needle in 70 parts by weight of polar solvent, adding 35 parts by weight of chitosan into the polar solvent, magnetically stirring the mixture at room temperature for 30-60 min, and fully mixing the mixture to prepare a uniform spinning solution; the concentration of the spinning solution is 1-65 wt%;
6) and spinning the spinning solution by using a conventional spinning device to obtain the superfine nano silver wire/stone needle fiber material.
The antibacterial result is as follows: the antibacterial rate of the escherichia coli is as follows: 92.6 percent; the antibacterial rate of staphylococcus aureus is as follows: 91.7 percent; the candida albicans is: 99.1 percent. The far infrared emissivity is 87%; the breaking strength is 4.6 cN/dtex; the boiling water shrinkage was 1.6%. Antistatic performance parameters: the pillowcase prepared from nano silver line stone needle fiber material has the fiber specific conductance of 0.62 x 103Omega cm, specific conductance after hundred washes 0.94 x 103Ω*cm。
From the experimental data of examples one to nine and comparative examples one to two, it can be seen that:
1. the proportion of the solution A and the stirring temperature of the solution A influence the antibacterial rate of the superfine nano silver wire/stone needle fiber material, wherein the mass ratio of polyvinylpyrrolidone, iodide and stone needle powder is 200: 1: the mixture ratio is optimal at 40;
2. when other conditions are the same, the solution A is added with an antistatic composite system, so that the superfine nano silver wire/stone needle fiber with better far infrared emissivity and antistatic performance parameters can be obtained.
When the nano silver wire stone needle fiber magnetic therapy pillow works, firstly, under normal conditions, the thicker side of a pillow case 10 faces upwards for people to have a normal rest, when people need to carry out magnetic therapy on the head, a rotating shaft 9 is rotated, the rotating shaft 9 drives two groups of gears 8 to rotate, the two groups of gears 8 are meshed with two groups of teeth 6, the two groups of teeth 6 drive two groups of annular rings 4 to rotate, four groups of sliding blocks 3 slide in four groups of sliding grooves 5, two groups of annular rings 4 drive the pillow case 10 to rotate, when the thinner side of the pillow case 10 rotates to the upper side, the people place the head on the pillow case 10, and then a pillow core 1 carries out magnetic therapy on the head of the people through the pillow case 10.
The nano silver wire stone needle fiber magnetic therapy pillow has the advantages that the installation mode, the connection mode or the arrangement mode are common mechanical modes, and the installation mode, the connection mode or the arrangement mode can be implemented as long as the beneficial effects are achieved.
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.

Claims (10)

1. A magnetic therapy pillow with nano silver wire and stone needle fibers is characterized by comprising a pillow inner (1), a fixing plate (2), a sliding block (3), an annular ring (4), gears (8), a rotating shaft (9) and a pillow case (10), wherein the fixing plate (2) is respectively installed at the top end and the bottom end of the pillow inner (1), the sliding block (3) is respectively installed at the outer side of the fixing plate (2), sliding grooves (5) are respectively formed in the annular ring (4), the sliding block (3) on the fixing plate (2) slides in the sliding grooves (5) of the annular ring (4), teeth (6) are annularly arranged in the annular ring (4), gear grooves (7) are respectively formed in the right part of the fixing plate (2), the bottom end of the rotating shaft (9) penetrates through an upper side gear groove (7) in the upper side fixing plate (2), the pillow inner (1) and a lower side fixing plate (2) and can be rotatably installed in the lower side gear groove (7), the rotating shaft (9) is rotatably connected with the fixing plate (2) and the pillow inner (1), gears (8) are respectively arranged on the upper portion and the lower portion of the rotating shaft (9), the gears (8) are respectively located in gear grooves (7), the gears (8) are meshed with teeth (6), a pillow case (10) is arranged on the annular ring (4), and one side of the pillow case (10) is thick and the other side of the pillow case is thin.
2. The nano-silver wire stone needle fiber magnetic therapy pillow according to claim 1, wherein zippers (11) are arranged on the pillowcase (10) and the two groups of annular rings (4), and the pillowcase (10) and the two groups of annular rings (4) are detachably connected through the zippers (11).
3. The nano silver wire stone needle fiber magnetic therapy pillow according to claim 2, characterized by further comprising an elbow (12), wherein the elbow (12) is installed at the top end of the rotating shaft (9).
4. The nano silver wire stone needle fiber magnetic therapy pillow according to claim 3, characterized by further comprising a telescopic rod (13), wherein the telescopic rod (13) is slidably installed in the elbow (12).
5. The magnetic therapy pillow of the nano silver wire stone needle fibers as claimed in claim 4, characterized by further comprising a handle (14), wherein the handle (14) is rotatably installed at the right side of the top end of the telescopic rod (13).
6. The magnetic therapy pillow with nano silver thread stone needle fibers as claimed in any one of claims 1 to 5, characterized in that the pillow inner (1) and/or the pillow case (10) are woven by nano silver thread stone needle fibers.
7. The nano-silver wire stone needle fiber magnetic therapy pillow according to claim 6, wherein the preparation method of the nano-silver wire stone needle fiber material comprises the following steps:
1) dissolving polyvinylpyrrolidone, iodide and stone needle powder in ethylene glycol, wherein the mass ratio of polyvinylpyrrolidone to iodide to stone needle powder is 160-260: 1: 30-50, fully stirring and dissolving to obtain a solution A;
2) dissolving silver nitrate in an ethylene glycol solution, stirring until the silver nitrate is dissolved, wherein the mass ratio of the silver nitrate to the stone needle powder is 1: 1-3, obtaining a solution B;
3) stirring and heating the solution A to 140-180 ℃, turning off the heating, and uniformly adding the solution B into the solution A;
4) after full reaction, quickly cooling to room temperature, stopping the reaction, and washing the reaction by using an organic solvent to obtain superfine nano silver wires/stone needles;
5) dissolving 30-35 parts by weight of superfine nano silver wire/stone needle in 40-60 parts by weight of polar solvent, adding 25-30 parts by weight of chitosan, magnetically stirring at room temperature for 30-60 min, and fully mixing to prepare a uniform spinning solution; the concentration of the spinning solution is 1-65 wt%;
6) and spinning the spinning solution by using an electrostatic spinning device to obtain the superfine nano silver wire/stone needle fiber material.
8. The nano silver wire stone needle fiber magnetic therapy pillow according to claim 7, wherein an antistatic composite system is added into the solution A, and the antistatic composite system comprises the following components in a mass ratio of 1: 2-5 of a mixture of mixed graphene powder and an antistatic fluid;
the preparation method of the antistatic fluid comprises the following steps:
(1) mixing the components in a mass ratio of 1: 1-3, grinding the mixed polytetrafluoroethylene and polyaniline to 30-150nm of particle size to obtain primary antistatic micro powder;
(2) mixing the primary antistatic micro powder and a modifier according to a mass ratio of 1: 2-3, carrying out modification treatment to obtain modified antistatic micro powder;
(3) adding the modified antistatic micro powder into butanol at the temperature of 40-60 ℃, and performing ultrasonic treatment and stirring for 60-120s to obtain the antistatic fluid.
9. The nano-silver wire stone needle fiber magnetic therapy pillow according to claim 8, wherein the modifier comprises: expanded graphite, glycerol, sulfuric acid and a dimethyl pyrrolidone solution; the modification treatment comprises the following steps: adding the primary antistatic micro powder into 0.2-0.4mol/L hydrochloric acid solution, stirring at constant temperature of 25-35 deg.C for 5-10min, adding glycerol and dimethyl pyrrolidone solution, stirring for 15-20min, and adding expanded graphite.
10. The preparation method of the nano silver wire/stone needle fiber antibacterial material according to claim 9, characterized by comprising the following steps: the preparation method of the expanded graphite comprises the following steps: will be provided withPotassium permanganateAndflake graphiteAdding into the mixture, stirring for 1-1.5h at constant temperature of 30-40 ℃ in water bath, filtering, washing with deionized water for multiple times, drying, and performing microwave action of 500-700W for 30-40s to obtain the expansionGraphite。
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Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000037274A (en) * 1998-05-21 2000-02-08 Mym Corp Sound sleep pillow
CN2526029Y (en) * 2002-02-08 2002-12-18 刘振兴 Comfortable health pillow
CN2882664Y (en) * 2005-12-15 2007-03-28 天津工业大学 Human shaped pillow
CN101396584A (en) * 2007-09-24 2009-04-01 北京玛格涅磁应用技术有限责任公司 Magnetotherapy pillow
CN201727222U (en) * 2010-04-21 2011-02-02 程合梅 Stone needle health-caring pillow
CN102586923A (en) * 2011-12-30 2012-07-18 天津市赛远保健品有限公司 Stone needle functional fibers and processing technology thereof
CN202665000U (en) * 2012-06-29 2013-01-16 惠州会德宝实业有限公司 Magnet therapy pillow
CN203987261U (en) * 2014-08-08 2014-12-10 山东富帅无辐射技术股份有限公司 A kind of far-infrared health-care pillow with gold magnet
US20150040322A1 (en) * 2013-08-09 2015-02-12 Tech Cheng Pillow
JP3202891U (en) * 2015-12-16 2016-02-25 信行 降魔 Rotating sofa cover
CN105970327A (en) * 2016-07-19 2016-09-28 青岛百草纤维科技股份有限公司 Stone needle-containing healthcare regenerated cellulose fiber and preparation method thereof
US20160333499A1 (en) * 2015-05-11 2016-11-17 Acelon Chemicals and Fiber Corporation Fabricating method for meltblown nonwoven from natural cellulose fiber blended with nano silver
CN108149338A (en) * 2017-12-22 2018-06-12 平原恒丰纺织科技有限公司 A kind of stone needle modified polyester fiber and preparation method thereof and fabric
CN108330555A (en) * 2018-02-10 2018-07-27 中科纺织研究院（青岛）有限公司 A kind of stone needle polyester fiber and preparation method thereof
CN109222542A (en) * 2018-10-29 2019-01-18 浙江和也健康科技有限公司 Support adjustable magnetic health-care pillow
CN109431188A (en) * 2018-12-12 2019-03-08 浙江和也健康科技有限公司 A kind of Magnetotherapeutic pillow with rotary massaging device
CN109431189A (en) * 2018-12-12 2019-03-08 浙江和也健康科技有限公司 A kind of height-adjustable Magnetotherapeutic pillow
CN208676871U (en) * 2018-02-10 2019-04-02 湖南工艺美术职业学院 A kind of magnetic therapy tea perfume function tea culture pillow
CN209235586U (en) * 2017-09-08 2019-08-13 天津市琦沅工贸有限责任公司 A kind of Novel medical health pillow
CN209391579U (en) * 2018-11-23 2019-09-17 荆门千年健医疗保健科技有限公司 A kind of novel pillow

Patent Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000037274A (en) * 1998-05-21 2000-02-08 Mym Corp Sound sleep pillow
CN2526029Y (en) * 2002-02-08 2002-12-18 刘振兴 Comfortable health pillow
CN2882664Y (en) * 2005-12-15 2007-03-28 天津工业大学 Human shaped pillow
CN101396584A (en) * 2007-09-24 2009-04-01 北京玛格涅磁应用技术有限责任公司 Magnetotherapy pillow
CN201727222U (en) * 2010-04-21 2011-02-02 程合梅 Stone needle health-caring pillow
CN102586923A (en) * 2011-12-30 2012-07-18 天津市赛远保健品有限公司 Stone needle functional fibers and processing technology thereof
CN202665000U (en) * 2012-06-29 2013-01-16 惠州会德宝实业有限公司 Magnet therapy pillow
US20150040322A1 (en) * 2013-08-09 2015-02-12 Tech Cheng Pillow
CN203987261U (en) * 2014-08-08 2014-12-10 山东富帅无辐射技术股份有限公司 A kind of far-infrared health-care pillow with gold magnet
US20160333499A1 (en) * 2015-05-11 2016-11-17 Acelon Chemicals and Fiber Corporation Fabricating method for meltblown nonwoven from natural cellulose fiber blended with nano silver
JP3202891U (en) * 2015-12-16 2016-02-25 信行 降魔 Rotating sofa cover
CN105970327A (en) * 2016-07-19 2016-09-28 青岛百草纤维科技股份有限公司 Stone needle-containing healthcare regenerated cellulose fiber and preparation method thereof
CN209235586U (en) * 2017-09-08 2019-08-13 天津市琦沅工贸有限责任公司 A kind of Novel medical health pillow
CN108149338A (en) * 2017-12-22 2018-06-12 平原恒丰纺织科技有限公司 A kind of stone needle modified polyester fiber and preparation method thereof and fabric
CN108330555A (en) * 2018-02-10 2018-07-27 中科纺织研究院（青岛）有限公司 A kind of stone needle polyester fiber and preparation method thereof
CN208676871U (en) * 2018-02-10 2019-04-02 湖南工艺美术职业学院 A kind of magnetic therapy tea perfume function tea culture pillow
CN109222542A (en) * 2018-10-29 2019-01-18 浙江和也健康科技有限公司 Support adjustable magnetic health-care pillow
CN209391579U (en) * 2018-11-23 2019-09-17 荆门千年健医疗保健科技有限公司 A kind of novel pillow
CN109431188A (en) * 2018-12-12 2019-03-08 浙江和也健康科技有限公司 A kind of Magnetotherapeutic pillow with rotary massaging device
CN109431189A (en) * 2018-12-12 2019-03-08 浙江和也健康科技有限公司 A kind of height-adjustable Magnetotherapeutic pillow

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