CN113576738A

CN113576738A - Stone needle physiotherapy waistband

Info

Publication number: CN113576738A
Application number: CN202110850806.XA
Authority: CN
Inventors: 方彦雯; 方志财
Original assignee: Heye Health Technology Co Ltd
Current assignee: Heye Health Technology Co Ltd
Priority date: 2021-07-27
Filing date: 2021-07-27
Publication date: 2021-11-02

Abstract

The invention relates to the technical field of stone needle waistbands, in particular to a stone needle physiotherapy waistband which comprises a waistband body and a moxibustion box, wherein the moxibustion box is fixedly sleeved in the waistband body, folding corrugated pipes which are uniformly distributed are fixedly sleeved between the waistband body and the moxibustion box, a box cover is movably plugged in a square hole formed in one side of the waistband body and one side of the moxibustion box, a medicine placing frame is welded on one side of the box cover, and two rotary grooves are formed in the other side of the waistband body and the other side of the moxibustion box. The multifunctional waist belt overcomes the defects of the prior art, the waist belt can perform stone needle thermal therapy on people and perform moxibustion on the people through the arrangement of the moxibustion box, the medicine placing frame, the folding bellows and the moxibustion threaded pipe, physical therapy is facilitated, heat generated by burning of the medicines in the medicine placing frame can be transferred into the conductive liquid groove through the heat conducting block to heat the conductive liquid, the use of the electric heating pipe is reduced, electric power resources are saved, the position of the moxibustion threaded pipe can be adjusted through rotating the rotating frame, and the practicability of the waist belt is improved.

Description

Stone needle physiotherapy waistband

Technical Field

The invention relates to the technical field of stone needle waistbands, in particular to a stone needle physiotherapy waistband.

Background

A stone needle belt, also called a stone belt, a stone needle waist support and a stone needle physiotherapy belt, belongs to the field of health care products, and is the stone needle belt with health care and physiotherapy effects. Comprises a bridle and stone needles, wherein the front belt and/or the rear belt of the bridle are/is provided with at least one stone needle which is a natural stone block which is detected to be free of radioactivity and is harmless to a human body. The stone needle waistband can be used for carrying out stone needle thermal therapy, and the stone needle thermal therapy is to heat a stone needle product and then act on a body or a focus point to achieve the purposes of accelerating blood circulation, warming and dredging channels and collaterals and quickly relieving fatigue or pain. The stone needle has a special energy field, and can realize the purposes of health preservation and health care and disease conditioning after long-term use. The heated stone needle can fully exert the infrared and ultrasonic effects of the stone needle, thereby achieving better physical therapy effect.

The stone needle waistband heats the heat conduction material through electric heating pipe or electric heating wire greatly, gives the stone needle heat with heat transfer by the heat conduction material again, comes to heat the stone needle, but the heat conduction material in the present stone needle waistband keeps warm the effect relatively poor, needs electric heating pipe or heating wire to open always and heats the stone needle, and electric heating pipe or heating wire are probably overheated after long-time operation to shorten electric heating pipe or heating wire's life, so can't satisfy required.

Disclosure of Invention

Aiming at the defects of the prior art, the invention provides a stone needle physiotherapy waistband, which overcomes the defects of the prior art and aims to solve the problem that the heat insulation effect of a heat conduction material in the stone needle waistband cannot be improved.

In order to achieve the purpose, the invention provides the following technical scheme: a stone needle physiotherapy waistband comprises a waistband body and a moxibustion box, wherein the moxibustion box is fixedly sleeved in the waistband body, uniformly distributed folding corrugated pipes are fixedly sleeved between the waistband body and the moxibustion box, a box cover is movably plugged in a square hole formed in one side of the waistband body and one side of the moxibustion box, a medicine placing frame is welded on one side of the box cover, two rotary grooves are formed in the other side of the waistband body and the moxibustion box, rotary frames are rotatably sleeved in the rotary grooves, the medicine placing frame and the rotary frames are both positioned in the moxibustion box, a heat conducting block is embedded in one side of each rotary frame, which is close to the medicine placing frame, a conductive liquid groove is formed between the heat conducting block and the rotary frame, conductive liquid is filled in the conductive liquid groove, an electric heating pipe is fixedly installed on the inner wall of the conductive liquid groove through bolts, uniformly distributed second stone needles are embedded in one side of the rotary frame, which is far away from the box cover, one end of each second stone needle is fixedly sleeved in the conductive liquid groove, two round holes symmetrically formed in the rotating frame are sleeved with moxibustion threaded pipes in a threaded manner.

As a preferred technical scheme of the invention, a silica gel sleeve is fixedly sleeved on the outer wall of one end of the moxibustion threaded pipe, which is far away from the box cover, the silica gel sleeve is positioned outside the belt body, and the two rotating frames are symmetrically distributed by taking the medicine placing frame as a center.

As a preferred technical scheme of the invention, two symmetrically distributed bandages are sewn on the outer wall of the waistband body, and the two bandages are matched and adhered through magic tapes.

As a preferable technical scheme of the invention, the folding corrugated pipe is communicated with the interior of the moxibustion box, and the moxibustion threaded pipe is communicated with the interior of the moxibustion box.

As a preferable technical scheme of the invention, the medicine placing frame is positioned between the box cover and the rotating frame, and the heat conducting block is positioned between the medicine placing frame and the electric heating pipe.

As a preferable technical scheme of the invention, the electric heating tube is positioned between the heat conducting block and the second stone needles, and the first stone needles are uniformly distributed and embedded between the waistband body and the moxibustion box.

As a preferred technical scheme, the waistband body is formed by weaving nano cuprous oxide @ copper oxide/stone needle fibers, and the preparation method of the nano cuprous oxide @ copper oxide/stone needle fibers comprises the following steps:

1) stone needle powder and soluble copper salt are mixed according to the mass ratio of 3-5: 1, dissolving in deionized water, and ultrasonically dispersing for 30-60 min, wherein the solution is marked as suspension A;

2) adding 4-6 mol/L of strong base into the solution A, and magnetically stirring until the solution is uniform for 10-30 min, wherein the solution is marked as suspension B;

3) adding a weak reducing agent into the suspension, wherein the molar ratio of the weak reducing agent to the soluble copper salt is 1: 1.5-2.5, performing magnetic stirring for 30-60 min, centrifuging, and washing with deionized water and ethanol for several times to obtain a product C;

4) dispersing the product C in hydrogen peroxide with the mass fraction of 10-20%, magnetically stirring for 6-10 h, centrifuging, and drying at 60-80 ℃ for 0.5-2 h to obtain nano cuprous oxide @ copper oxide/stone needle;

5) dissolving 30-35 parts by weight of nano cuprous oxide @ copper oxide/stone needle and 25-35 parts by weight of chitosan into 45-55 parts by weight of polar solution, magnetically stirring at room temperature for 30-60 min, and fully mixing to prepare uniform spinning solution; the mass concentration of the spinning solution is 2-60%;

6) and spinning the spinning solution by using an electrostatic spinning device to obtain the nano antibacterial cuprous oxide @ copper oxide/stone needle material.

Stone needle generally refers to microcrystalline limestone; the microcrystalline limestone is a compact massive microcrystalline aggregate of limestone, and the main chemical component of the microcrystalline limestone is calcium carbonate, which is a sedimentary rock. The microcrystalline limestone is mainly used as a traditional Chinese medicine physical therapy apparatus, a health care product and the like, and comprises more than forty trace elements and mineral substances beneficial to a human body and more than twenty anti-aging elements, and the stone needle has a singular energy field, can generate infrared rays and ultrasonic waves when acting on the human body, and can run along the channels. Has effects in balancing body pH, promoting blood circulation, improving sub-health, caring skin, and promoting health.

The stone needle in the traditional Chinese medical therapy is used as a material to be added into the processing process of the antibacterial material, so that the antibacterial stone needle is widely applied to the antibacterial field and can be applied to the textile field; the nano antibacterial cuprous oxide @ cupric oxide/stone needle fiber capable of releasing infrared rays and resisting bacteria is prepared by adding cupric salt.

The invention relates to a nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material, which is a nano antibacterial material consisting of cuprous oxide composite copper oxide and stone needle fibers. The invention provides a preparation method of a nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material, wherein the nano cuprous oxide @ copper oxide has a larger specific surface area, so that more sites of the nano cuprous oxide @ copper oxide are in contact with bacterial colonies, and the antibacterial and bacteriostatic effects can be better achieved; according to the traditional Chinese medicine, the stone needle has the effects of soothing the nerves, regulating qi and blood and dredging channels and collaterals, certain treatment and health care functions are achieved through microcrystalline infrared rays and pulses, the stone needle fiber can promote blood circulation and help sleep, and the nano silver wire/stone needle fiber antibacterial material has the double functions of antibiosis and health care by combining the microcrystalline infrared rays and the microcrystalline infrared rays; the preparation process is relatively simple and easy to operate.

Preferably, an antistatic composite system is added into the suspension A, and the antistatic composite system comprises the following components in a mass ratio of 1: 2-5 of a mixture of mixed graphene powder and an antistatic fluid;

the preparation method of the antistatic fluid comprises the following steps:

(1) mixing the components in a mass ratio of 1: grinding and crushing 1-3 mixed polytetrafluoroethylene and polyaniline to the particle size of 30-150nm to obtain primary antistatic micro powder;

(2) mixing the primary antistatic micro powder and a modifier according to a mass ratio of 1: 2-3, carrying out modification treatment to obtain modified antistatic micro powder;

(3) adding the modified antistatic micro powder into butanol at the temperature of 40-60 ℃, and performing ultrasonic treatment and stirring for 60-120s to obtain the antistatic fluid.

Preferably, the modifier comprises: expanded graphite, glycerol, sulfuric acid and a dimethyl pyrrolidone solution.

Preferably, the modification treatment comprises: adding the primary antistatic micro powder into 0.2-0.4mol/L hydrochloric acid solution, stirring at constant temperature of 25-35 deg.C for 5-10min, adding glycerol and dimethyl pyrrolidone solution, stirring for 15-20min, and adding expanded graphite.

According to the invention, the glycerol, the dimethyl pyrrolidone and the expanded graphite are added to modify the primary antistatic micro powder, so that the obtained material has good electric conductivity and heat conductivity and better antistatic property.

More preferably, the method for preparing the expanded graphite comprises: adding potassium permanganate and crystalline flake graphite into the mixture, stirring the mixture for 1 to 1.5 hours at constant temperature in a water bath of between 30 and 40 ℃, filtering the mixture, washing the mixture for multiple times by using deionized water, drying the washed mixture, and performing microwave action of 500-700W for 30 to 40 seconds to obtain the expanded graphite.

The fabric made of the cuprous oxide @ copper oxide/stone needle fiber antibacterial material prepared by the method has the far infrared emissivity of up to 93 percent and the fiber breaking strength of 6.6-7.3 cN/dtex; the boiling water shrinkage is 1.8-2.5%.

Preferably, in the step 1), the copper salt is one or a combination of copper acetate, copper citrate or copper lactate; the strong base is one or the combination of sodium hydroxide or potassium hydroxide.

Preferably, in the step 3), the weak reducing agent is one or a combination of glucose and ascorbic acid.

Preferably, in the step 5), the polar solvent is one or a combination of formic acid, glacial acetic acid or trifluoroacetic acid; the deacetylation degree of the chitosan is 80-100%.

Preferably, in the step 6), the electrostatic spinning process parameters are as follows: 1-50 kV, the receiving distance is 1-50 cm, and the solution flow is 0.01-20 mL/h.

Compared with the prior art, the invention has the beneficial effects that:

(1) according to the invention, the electric heating pipe is used for heating the conductive liquid, and then the conductive liquid transfers heat to the second stone needle to heat the second stone needle, so that the heated second stone needle can be used for carrying out thermal therapy on people.

(2) According to the invention, through the arrangement of the moxibustion box, the medicine placing rack, the folding bellows and the moxibustion threaded pipe, the belt can perform stone needle thermal therapy on people and perform moxibustion on people, physical therapy on people is facilitated, heat generated by combustion of medicines in the medicine placing rack can be transferred into the conductive liquid groove through the heat conducting block to heat the conductive liquid, so that the use of electric heating pipes is reduced, electric power resources are saved, the position of the moxibustion threaded pipe can be adjusted by rotating the rotary rack, and the practicability of the belt is improved.

(3) According to the invention, the moxibustion threaded pipe can be attached to a human body through the silica gel sleeve, and people can drive the moxibustion threaded pipe to move after rotating the moxibustion threaded pipe, so that when the second stone needle and the waistband are overheated, the distance between the waistband body and the human body is controlled by controlling the exposed length of the moxibustion threaded pipe, the human body is prevented from being scalded due to overheating of the second stone needle and the waistband, and the applicability of the waistband is improved;

(4) the waistband body material is a nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material, and the nano cuprous oxide @ copper oxide has a large specific surface area, so that more sites of the nano cuprous oxide @ copper oxide are in contact with bacterial colonies, and the antibacterial and bacteriostatic effects can be better achieved; the stone needle fiber can promote blood circulation and is beneficial to sleep, and the combination of the two can ensure that the waistband body has the double functions of antibiosis and health care; the preparation process is relatively simple and easy to operate.

Drawings

FIG. 1 is an elevational view of the overall construction of the present invention;

FIG. 2 is a top sectional view of the overall structure of the present invention;

FIG. 3 is an enlarged view of the structure A of FIG. 2 according to the present invention;

FIG. 4 is an SEM image of nano-sized antibacterial cuprous oxide @ cupric oxide/stone needle of example 1.

FIG. 5 is an SEM image of the nano-sized antibacterial cuprous oxide @ cupric oxide/stone needle of example 2.

FIG. 6 is an SEM image of nano-sized antibacterial cuprous oxide @ cupric oxide/stone needle of example 3.

In the figure: 1. a belt body; 11. binding bands; 12. magic tape; 13. a first stone needle; 2. a moxibustion box; 21. folding the corrugated pipe; 22. a box cover; 23. placing a medicine rack; 24. rotating the groove; 3. rotating the frame; 31. a conductive liquid tank; 32. an electric heating tube; 33. a heat conducting block; 34. a second stone needle; 35. moxibustion threaded pipes; 36. and (4) a silica gel sleeve.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Referring to fig. 1-6, a stone needle physiotherapy waistband comprises a waistband body 1 and a moxibustion box 2, wherein the moxibustion box 2 is fixedly sleeved in the waistband body 1, the moxibustion box 2 can be softly protected by the waistband body 1, uniformly distributed folding corrugated pipes 21 are fixedly sleeved between the waistband body 1 and the moxibustion box 2, the folding corrugated pipes 21 can discharge waste smoke in the moxibustion box 2 and ventilate the moxibustion box 2, and the folding corrugated pipes 21 can be stretched and folded, so that the waste smoke can be conveniently discharged to an area far away from a human body through the folding corrugated pipes 21;

a box cover 22 is movably plugged in a square hole formed in one side of the waistband body 1 and one side of the moxibustion box 2, the box cover 22 can cover the waistband body 1 and the moxibustion box 2, a medicine placing frame 23 is welded on one side of the box cover 22, the box cover 22 can support the medicine placing frame 23, moxa and some medicines can be placed in the medicine placing frame 23, two rotating grooves 24 are formed in the other side of the waistband body 1 and the moxibustion box 2, a rotating frame 3 is sleeved in the rotating grooves 24 in a rotating manner, the rotating grooves 24 can support and limit the frame 3, the medicine placing frame 23 and the rotating frame 3 are both positioned in the moxibustion box 2, so that the moxibustion box 2 can shield and protect the medicine placing frame 23 and the rotating frame 3, a heat conducting block 33 is embedded in one side of the rotating frame 3 close to the medicine placing frame 23, the heat conducting block 33 can be made of materials with good heat conducting effect such as metal or ceramics, a conductive liquid groove 31 is formed between the heat conducting block 33 and the rotating frame 3, the heat conducting block 33 can transfer heat on the medicine placing frame 23 to the conductive liquid groove 31, conductive liquid is filled in the conductive liquid groove 31, conductive liquid is the liquid in the current electric hot water bag, can heat repeatedly and use, there is electric heating pipe 32 at the inner wall of conductive liquid groove 31 through bolt fixed mounting, electric heating pipe 32 can heat conductive liquid, one side that lid 22 was kept away from to revolving rack 3 is inlayed and is had evenly distributed's second stone needle 34, be convenient for fix second stone needle 34, the fixed cover of 34 one end of second stone needle is in conductive liquid groove 31, make conductive liquid can heat second stone needle 34, two downthehole equal thread cover that the internal symmetry of revolving rack 3 was seted up has moxa-moxibustion screwed pipe 35, it supports and is spacing to moxa-moxibustion screwed pipe 35 to be convenient for revolving rack 3.

Specifically, referring to fig. 1-3, a silica gel sleeve 36 is fixedly sleeved on the outer wall of one end of the moxibustion threaded pipe 35 away from the box cover 22, the silica gel sleeve 36 does not irritate the human body, the silica gel sleeve 36 is positioned outside the waistband body 1, so that the silica gel sleeve 36 can be conveniently attached to the human body to moxibustion the human body, and the two rotating frames 3 are symmetrically distributed by taking the medicine placing frame 23 as the center, so that the two rotating frames 3 can uniformly receive the heat of medicine combustion on the medicine placing frame 23.

Specifically, referring to fig. 1-2, two symmetrically distributed straps 11 are sewn on the outer wall of the belt body 1, and the two straps 11 are matched and bonded through a magic tape 12, so that the belt body 1 can be conveniently tied on the waist of a human body through the straps 11 and the magic tape 12.

Specifically, referring to fig. 2-3, the folding corrugated tube 21 is communicated with the inside of the moxibustion box 2, so that the moxibustion box 2 can discharge smoke and ventilate through the folding corrugated tube 21, the moxibustion threaded tube 35 is communicated with the inside of the moxibustion box 2, so that the moxibustion box 2 can perform moxibustion on the human body through the moxibustion threaded tube 35.

Specifically, referring to fig. 2-3, the medicine placing frame 23 is located between the box cover 22 and the rotating frame 3, so that the box cover 22 can shield the medicine placing frame 23, the medicine placing frame 23 can transfer heat to the rotating frame 3, and the heat conducting block 33 is located between the medicine placing frame 23 and the electric heating tube 32, so that the heat conducting block 33 can transfer heat on the medicine placing frame 23 to the conductive liquid.

Specifically, referring to fig. 1-3, the electric heating tube 32 is located between the heat conducting block 33 and the second stone needle 34, the first stone needles 13 are uniformly distributed and embedded between the waistband body 1 and the moxibustion box 2, the first stone needles 13 can increase the number of the whole stone needles on the waistband, increase the contact area between people and the stone needles, and can perform physical therapy on human body better.

Preparing a waistband body material:

example one

Stone needle powder and soluble copper acetate are mixed according to a mass ratio of 4: 1, dissolving in deionized water, and ultrasonically dispersing for 60min, wherein the solution is marked as suspension A; adding 4M sodium hydroxide into the solution A, magnetically stirring the solution A until the solution A is uniform for 30min, and marking the solution A as suspension B; adding glucose as a weak reducing agent into the suspension, wherein the molar ratio of the glucose to the soluble copper acetate is 1: 2, magnetically stirring for 60min, centrifuging, and washing with deionized water and ethanol for several times to obtain a product C; and dispersing the product C in 100mL of hydrogen peroxide with the mass fraction of 15%, magnetically stirring for 6h, centrifuging, and drying at 60 ℃ for 1h to obtain the nano cuprous oxide @ copper oxide/stone needle. Dissolving 30 parts by weight of nano cuprous oxide @ copper oxide/stone needle and 25 parts by weight of chitosan in 55 parts by weight of polar solution acetic acid, wherein the deacetylation degree of the chitosan is 80%, magnetically stirring at room temperature for 60min, and fully mixing to prepare a uniform spinning solution; the concentration of the spinning solution is 2%; spinning the spinning solution by using an electrostatic spinning device, wherein the process parameters of electrostatic spinning are as follows: and (3) 20 kilovolts, the receiving distance is 25 centimeters, and the solution flow is 5mL/h, so that the nano antibacterial cuprous oxide @ cupric oxide/stone needle material is obtained.

Wherein, FIG. 5 is an SEM image of the nano-antibacterial cuprous oxide @ cupric oxide/stone needle material, and the fiber diameter is 150-; the antibacterial properties are shown in the following table 1; the bactericidal properties are given in table 2.

The far infrared emissivity is up to 93 percent through detection; the breaking strength is 6.6 cN/dtex; the boiling water shrinkage was 1.8%.

Antistatic performance parameters: the specific conductance of the fiber of the waistband body prepared from the nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material is 0.61 x 10³Omega cm, specific conductance after hundred washes 1.01 x 10³Ω*cm。

Example two

Stone needle powder and soluble copper citrate are mixed according to a mass ratio of 4: 1, dissolving in deionized water, and ultrasonically dispersing for 30min, wherein the solution is marked as suspension A; adding 6M potassium hydroxide into the solution A, magnetically stirring the solution A until the solution A is uniform for 30min, and marking the solution A as suspension B; adding a weak reducing agent sodium borohydride into the suspension, wherein the molar ratio of the sodium borohydride to the soluble copper citrate is 1: 2, magnetically stirring for 60min, centrifuging, and washing with deionized water and ethanol for several times to obtain a product C; and dispersing the product C in 100mL of hydrogen peroxide with the mass fraction of 15%, magnetically stirring for 6h, centrifuging, and drying at 60 ℃ for 1h to obtain the nano cuprous oxide @ copper oxide/stone needle. Dissolving 35 parts by weight of nano cuprous oxide @ copper oxide/stone needle and 35 parts by weight of chitosan in 45 parts by weight of polar solution acetic acid, wherein the deacetylation degree of the chitosan is 90%, magnetically stirring at room temperature for 60min, and fully mixing to prepare a uniform spinning solution; the concentration of the spinning solution is 2%; spinning the spinning solution by using an electrostatic spinning device, wherein the process parameters of electrostatic spinning are as follows: and (3) 30 kilovolts, the receiving distance is 30 centimeters, the solution flow is 10mL/h, and the nano antibacterial cuprous oxide @ cupric oxide/stone needle material is obtained.

Wherein, FIG. 6 is an SEM image of the nano-antibacterial cuprous oxide @ cupric oxide/stone needle material, and the fiber diameter is 200-400 nm; the antibacterial properties are shown in the following table 1; the bactericidal properties are given in table 2.

The far infrared emissivity is up to 93 percent through detection. The breaking strength is 6.7 cN/dtex; the boiling water shrinkage was 1.9%;

antistatic performance parameters: the specific conductance of the fiber of the waistband body prepared from the nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material is 0.64 x 10³Omega cm, specific conductance after hundred washes 1.04 x 10³Ω*cm。

EXAMPLE III

Stone needle powder and soluble copper lactate are mixed according to a mass ratio of 4: 1, dissolving in deionized water, and ultrasonically dispersing for 30min, wherein the solution is marked as suspension A; adding 6M potassium hydroxide into the solution A, magnetically stirring the solution A until the solution A is uniform for 30min, and marking the solution A as suspension B; adding glucose as a weak reducing agent into the suspension, wherein the molar ratio of the glucose to the soluble copper citrate is 1: 2, magnetically stirring for 60min, centrifuging, and washing with deionized water and ethanol for several times to obtain a product C; and dispersing the product C in 100mL of hydrogen peroxide with the mass fraction of 15%, magnetically stirring for 6h, centrifuging, and drying at 80 ℃ for 1h to obtain a final product of nano cuprous oxide @ copper oxide/stone needle. Dissolving 35 parts by weight of nano cuprous oxide @ copper oxide/stone needle and 25 parts by weight of chitosan in 55 parts by weight of polar solution acetic acid, wherein the deacetylation degree of the chitosan is 100%, magnetically stirring at room temperature for 60min, and fully mixing to prepare a uniform spinning solution; the concentration of the spinning solution is 20%; spinning the spinning solution by using an electrostatic spinning device, wherein the process parameters of electrostatic spinning are as follows: 50 kilovolts, the receiving distance is 50 centimeters, the solution flow is 20mL/h, and the nano antibacterial cuprous oxide @ cupric oxide/stone needle material is obtained.

The fiber diameter is 200-380 nm; the antibacterial property is shown in the following table 1, and the bactericidal property is shown in the following table 2.

The far infrared emissivity of the material is up to 93 percent through detection. The breaking strength is 6.8 cN/dtex; the boiling water shrinkage was 1.8; antistatic performance parameters: nano cuprous oxide @ copper oxide/stone needleThe specific fiber conductivity of the waistband body made of the fiber antibacterial material is 0.63 x 10³Omega cm, specific conductance after hundred washes 1.01 x 10³Ω*cm。

TABLE 1 antibacterial Properties of Nano antibacterial cuprous oxide @ cupric oxide/Stone needle Material

Sample (I)	Escherichia coli	Staphylococcus aureus
			Example 1 antimicrobial cuprous oxide @ cupric oxide/Bian Stone needle	99.1％	98.7％
Example 2 antimicrobial cuprous oxide @ cupric oxide/Bian Stone needle	99.3％	99.2％
			Example 3 antibacterial cuprous oxide @ cupric oxide/Bian Stone needle	99.5％	99.1％

TABLE 2 Bactericidal Properties of Nano antibacterial cuprous oxide @ cupric oxide/Stone needle Material

Example four

A preparation method of nano cuprous oxide @ copper oxide/stone needle fiber comprises the following specific steps:

1) stone needle powder and soluble copper salt are mixed according to the mass ratio of 3: 1, dissolving in deionized water, and ultrasonically dispersing for 30min, wherein the solution is marked as suspension A;

2) adding 4mol/L strong base into the solution A, magnetically stirring the solution A until the solution A is uniform for 10min, and marking the solution A as suspension B;

3) adding a weak reducing agent into the suspension, wherein the molar ratio of the weak reducing agent to the soluble copper salt is 1: 1.5, performing magnetic stirring for 30min, centrifuging, and washing with deionized water and ethanol for several times to obtain a product C;

4) dispersing the product C in 100mL of hydrogen peroxide with the mass fraction of 10-20%, magnetically stirring for 6h, centrifuging and drying at 60 ℃ for 0.5h to obtain nano cuprous oxide @ copper oxide/stone needle;

5) dissolving 30 parts by weight of nano cuprous oxide @ copper oxide/stone needle and 25 parts by weight of chitosan into 45 parts by weight of polar solution, magnetically stirring for 30min at room temperature, and fully mixing to prepare uniform spinning solution; the mass concentration of the spinning solution is 30 percent;

EXAMPLE five

1) stone needle powder and soluble copper salt are mixed according to the mass ratio of 5: 1, dissolving in deionized water, and ultrasonically dispersing for 30-60 min, wherein the solution is marked as suspension A;

2) adding 6mol/L strong base into the solution A, and magnetically stirring the solution A until the solution A is uniform for 30min, wherein the solution is marked as suspension B;

3) adding a weak reducing agent into the suspension, wherein the molar ratio of the weak reducing agent to the soluble copper salt is 1: 2.5, magnetically stirring for 60min, centrifuging, and washing with deionized water and ethanol for several times to obtain a product C;

4) dispersing the product C in 100mL of hydrogen peroxide with the mass fraction of 20%, magnetically stirring for 10h, centrifuging, and drying at 80 ℃ for 2h to obtain nano cuprous oxide @ copper oxide/stone needle;

5) dissolving 35 parts by weight of nano cuprous oxide @ copper oxide/stone needle and 35 parts by weight of chitosan into 55 parts by weight of polar solution, magnetically stirring at room temperature for 60min, and fully mixing to prepare uniform spinning solution; the mass concentration of the spinning solution is 60 percent;

EXAMPLE six

The same as the first embodiment, except that an antistatic composite system is added into the suspension A, and the antistatic composite system comprises the following components in a mass ratio of 1: 3 a mixture of the mixed graphene powder and an antistatic fluid;

the preparation method of the antistatic fluid comprises the following steps:

(1) mixing the components in a mass ratio of 1: 2 grinding and crushing the mixed polytetrafluoroethylene and polyaniline to the particle size of 90nm to obtain primary antistatic micro powder;

(2) mixing the primary antistatic micro powder and a modifier according to a mass ratio of 1: 2, carrying out modification treatment to obtain modified antistatic micro powder; the modifier comprises: expanded graphite, glycerol, sulfuric acid and a dimethyl pyrrolidone solution; the modification treatment comprises the following steps: adding the primary antistatic micro powder into a 0.3mol/L hydrochloric acid solution, stirring for 7min at a constant temperature of 28 ℃, adding a glycerol and dimethyl pyrrolidone solution, continuously stirring for 18min, and adding expanded graphite;

the preparation method of the expanded graphite comprises the following steps: adding potassium permanganate and crystalline flake graphite into the mixture, stirring the mixture for 1.2 hours in a water bath at a constant temperature of 36 ℃, filtering the mixture, washing the mixture for multiple times by using deionized water, drying the washed mixture, and performing microwave action at 600W for 30 to 40 seconds to obtain expanded graphite;

(3) adding the modified antistatic micro powder into butanol at 50 ℃, and performing ultrasonic treatment and stirring for 80s to obtain the antistatic fluid.

The nano cuprous oxide @ copper oxide/stone needle fiber finally prepared by the invention has the antibacterial result that: the antibacterial rate of the escherichia coli is as follows: 99.4 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.7 percent; the candida albicans is: 99.1 percent;

the far infrared emissivity of the material is as high as 93%. The breaking strength is 7.3 cN/dtex; the boiling water shrinkage was 2.5%.

Antistatic performance parameters: the specific conductance of the fiber of the waistband body prepared from the nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material is 0.68 x 10³Omega cm, specific conductance after hundred washes 1.05 x 10³Ω*cm。

EXAMPLE seven

The same as the second embodiment, except that an antistatic composite system is added into the suspension A, and the antistatic composite system comprises the following components in a mass ratio of 1: 5, mixing the graphene powder and the antistatic fluid;

the preparation method of the antistatic fluid comprises the following steps:

(1) mixing the components in a mass ratio of 1: 3 grinding and crushing the mixed polytetrafluoroethylene and polyaniline to the particle size of 150nm to obtain primary antistatic micro powder;

(2) mixing the primary antistatic micro powder and a modifier according to a mass ratio of 1: 3, carrying out modification treatment to obtain modified antistatic micro powder; the modifier comprises: expanded graphite, glycerol, sulfuric acid and a dimethyl pyrrolidone solution; the modification treatment comprises the following steps: adding the primary antistatic micro powder into a 0.4mol/L hydrochloric acid solution, stirring for 10min at a constant temperature of 35 ℃, adding a glycerol and dimethyl pyrrolidone solution, continuously stirring for 20min, and adding expanded graphite;

the preparation method of the expanded graphite comprises the following steps: adding potassium permanganate and crystalline flake graphite into the mixture, stirring the mixture for 1.5 hours at a constant temperature of 40 ℃ in a water bath, filtering the mixture, washing the mixture for multiple times by using deionized water, drying the washed mixture, and performing microwave action of 700W for 40 seconds to obtain expanded graphite;

(3) adding the modified antistatic micro powder into butanol at 60 ℃, and performing ultrasonic treatment and stirring for 120s to obtain the antistatic fluid.

The nano cuprous oxide @ copper oxide/stone needle fiber finally prepared by the invention has the antibacterial result that: the antibacterial rate of the escherichia coli is as follows: 99.2 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.5 percent; the candida albicans is: 99.0 percent;

the far infrared emissivity is as high as 93%; the breaking strength is 6.6 cN/dtex; the boiling water shrinkage was 1.8%.

Antistatic performance parameters: the specific conductance of the fiber of the waistband body prepared from the nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material is 0.69 x 10³Omega cm, specific conductance after hundred washes 1.08X 10³Ω*cm。

Example eight

The method is similar to the third embodiment, except that an antistatic composite system is added into the suspension A, and the antistatic composite system comprises the following components in a mass ratio of 1: 2-5 of a mixture of mixed graphene powder and an antistatic fluid;

the preparation method of the antistatic fluid comprises the following steps:

(1) mixing the components in a mass ratio of 1: 1-3, grinding the mixed polytetrafluoroethylene and polyaniline to 30-150nm of particle size to obtain primary antistatic micro powder;

(2) mixing the primary antistatic micro powder and a modifier according to a mass ratio of 1: 2, carrying out modification treatment to obtain modified antistatic micro powder; the modifier comprises: expanded graphite, glycerol, sulfuric acid and a dimethyl pyrrolidone solution; the modification treatment comprises the following steps: adding the primary antistatic micro powder into a 0.2mol/L hydrochloric acid solution, stirring for 5min at a constant temperature of 25 ℃, adding a glycerol and dimethyl pyrrolidone solution, continuously stirring for 15-20min, and adding expanded graphite;

the preparation method of the expanded graphite comprises the following steps: adding potassium permanganate and crystalline flake graphite into the mixture, stirring the mixture for 1h at a constant temperature of 30 ℃ in a water bath, filtering the mixture, washing the mixture for multiple times by using deionized water, and then drying the washed mixture, wherein the expanded graphite is prepared under the action of 500W of microwave for 30-40 s;

(3) adding the modified antistatic micro powder into butanol at 40 ℃, and performing ultrasonic treatment and stirring for 60s to obtain the antistatic fluid.

The nano cuprous oxide @ copper oxide/stone needle fiber finally prepared by the invention has the antibacterial result that: the antibacterial rate of the escherichia coli is as follows: 99.1 percent; the antibacterial rate of staphylococcus aureus is as follows: 98.3 percent; the candida albicans is: 98.6 percent;

the far infrared emissivity is as high as 93%; the breaking strength is 6.8 cN/dtex; the boiling water shrinkage was 1.9%. Antistatic performance parameters: the specific conductance of the waistband body prepared from the nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material is 0.68 x 103 omega cm, and the specific conductance after hundreds of washing is 1.07 x 103 omega cm.

Comparative example 1

1) stone needle powder and soluble copper salt are mixed according to the mass ratio of 6: 1, dissolving in deionized water, and ultrasonically dispersing for 15min, wherein the solution is marked as suspension A;

2) adding 3mol/L strong base into the solution A, and magnetically stirring the solution A until the solution A is uniform for 8min, wherein the solution is marked as suspension B;

3) adding a weak reducing agent into the suspension, wherein the molar ratio of the weak reducing agent to the soluble copper salt is 1: 1, magnetically stirring for 30min, centrifuging, and washing with deionized water and ethanol for several times to obtain a product C;

4) dispersing the product C in 100mL of hydrogen peroxide with the mass fraction of 10-20%, magnetically stirring for 6-10 h, centrifuging, and drying at 60-80 ℃ for 0.5-2 h to obtain nano cuprous oxide @ copper oxide/stone needle;

5) dissolving 25 parts by weight of nano cuprous oxide @ copper oxide/stone needle and 40 parts by weight of chitosan into 55 parts by weight of polar solution, magnetically stirring for 30min at room temperature, and fully mixing to prepare uniform spinning solution;

6) and spinning the spinning solution by using a conventional electrostatic spinning device to obtain the nano antibacterial cuprous oxide @ copper oxide/stone needle material.

The antibacterial result is as follows: the antibacterial rate of the escherichia coli is as follows: 95.1 percent; the antibacterial rate of staphylococcus aureus is as follows: 94.3 percent. The far infrared emissivity is 83%; the breaking strength is 4.7 cN/dtex; the boiling water shrinkage was 1.5%. Antistatic performance parameters: the specific conductance of the fiber of the waistband body prepared from the nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material is 0.58 x 10³Omega cm, specific conductance after hundred washes 0.92 x 10³Ω*cm。

Comparative example No. two

1) stone needle powder and soluble copper salt are mixed according to a mass ratio of 2: 1, dissolving in deionized water, and ultrasonically dispersing for 20min, wherein the mark is suspension A;

2) adding 8mol/L strong base into the solution A, and magnetically stirring the solution A until the solution A is uniform for 30min, wherein the solution is marked as suspension B;

3) adding a weak reducing agent into the suspension, wherein the molar ratio of the weak reducing agent to the soluble copper salt is 1: 3, magnetically stirring for 30min, centrifuging, and washing with deionized water and ethanol for several times to obtain a product C;

4) dispersing the product C in 100mL of hydrogen peroxide with the mass fraction of 8%, magnetically stirring for 10h, centrifuging, and drying at 60 ℃ for 0.4h to obtain nano cuprous oxide @ copper oxide/stone needle;

5) dissolving 40 parts by weight of nano cuprous oxide @ copper oxide/stone needle and 20 parts by weight of chitosan into 45 parts by weight of polar solution, and magnetically stirring at room temperature for 60 min;

The antibacterial result is as follows: the antibacterial rate of the escherichia coli is as follows: 93.5 percent; the antibacterial rate of staphylococcus aureus is as follows: 92.9 percent. The far infrared emissivity is 85%; the breaking strength is 4.5 cN/dtex; the boiling water shrinkage was 1.7%. Antistatic performance parameters: the specific conductance of the fiber of the waistband body prepared from the nano cuprous oxide @ copper oxide/stone needle fiber antibacterial material is 0.59 x 10³Omega cm, specific conductance after hundred washes is 0.93 x 10³Ω*cm。

From the experimental data of examples one to eight and comparative examples one to two, it can be seen that:

1. the proportion of the suspension A and the stirring temperature of the suspension A influence the antibacterial rate of the nano cuprous oxide @ copper oxide/stone needle fiber material, wherein the stone needle powder and the soluble copper salt are mixed according to the mass ratio of 4: 1, the mixture ratio is optimal;

2. when other conditions are the same, the anti-static composite system is added into the suspension A, and the nano cuprous oxide @ copper oxide/stone needle fiber with better far infrared emissivity and antistatic performance parameters can be obtained.

The working principle of the stone needle physiotherapy waistband of the invention is as follows: when the waist band body 1 is used, the waist band body 1 can be bound on the waist of a human body by utilizing the binding band 11 and the magic tape 12, the electric heating pipe 32 is opened, the electric heating pipe 32 can heat the conductive liquid in the conductive liquid groove 31, then the conductive liquid transfers heat to the second stone needle 34 to heat the second stone needle 34, the heated second stone needle 34 can carry out thermotherapy on people, when people need moxibustion, the medicine can be placed in the medicine placing frame 23 and ignited, then the box cover 22 is plugged into the waist band, the medicine can be discharged smoke and ventilated through the folding corrugated pipe 21 after being ignited, the moxibustion is carried out on the human body through the moxibustion threaded pipe 35, the heat of medicine combustion in the medicine placing frame 23 can be transferred into the conductive liquid groove 31 through the heat conducting block 33 to heat the conductive liquid, the use of the electric heating pipe 32 is reduced, the rotating frame 3 can also drive the moxibustion threaded pipe 35 to rotate, adjust the position of moxa-moxibustion screwed pipe 35 and human contact, moxa-moxibustion screwed pipe 35 can be laminated on the human body through silica gel cover 36, people rotate the moxa-moxibustion screwed pipe 35 after, can drive moxa-moxibustion screwed pipe 35 and remove under the spacing of revolving rack 3, be convenient for when second stone needle 34 and waistband are overheated, through the length that exposes of control moxa-moxibustion screwed pipe 35, adjust the interval between the waistband body 1 and the human body, prevent to scald the human body because second stone needle 34 and waistband are overheated.

Finally, it should be noted that: in the description of the present invention, it should be noted that the terms "vertical", "upper", "lower", "horizontal", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of describing the present invention and simplifying the description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention.

In the description of the present invention, it should also be noted that, unless otherwise explicitly specified or limited, the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly and may, for example, be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.

Although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that changes may be made in the embodiments and/or equivalents thereof without departing from the spirit and scope of the invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims

1. The utility model provides a stone needle physiotherapy waistband, includes the waistband body (1) and moxa-moxibustion box (2), its characterized in that: the moxibustion box (2) is fixedly sleeved in the waistband body (1), the folding corrugated pipes (21) which are uniformly distributed are fixedly sleeved between the waistband body (1) and the moxibustion box (2), a box cover (22) is movably plugged in a square hole formed in one side of the waistband body (1) and the moxibustion box (2), a medicine placing frame (23) is welded on one side of the box cover (22), two rotating grooves (24) are formed in the other side of the waistband body (1) and the moxibustion box (2), a rotating frame (3) is sleeved in the rotating grooves (24) in a rotating manner, the medicine placing frame (23) and the rotating frame (3) are both positioned in the moxibustion box (2), a heat conducting block (33) is embedded in one side of the rotating frame (3) close to the medicine placing frame (23), a conductive liquid groove (31) is formed between the heat conducting block (33) and the rotating frame (3), and conductive liquid is filled in the conductive liquid groove (31), conductive liquid groove (31) inner wall has electric heating pipe (32) through bolt fixed mounting, one side that lid (22) were kept away from in revolving rack (3) is inlayed and is had evenly distributed's second stone needle (34), the fixed cover of second stone needle (34) one end is in conductive liquid groove (31), two downthehole equal screw thread covers that the symmetry was seted up in revolving rack (3) have moxa-moxibustion screwed pipe (35).

2. The stone needle physiotherapy waistband of claim 1, which is characterized in that: moxa-moxibustion screwed pipe (35) keep away from the fixed cover of one end outer wall of lid (22) has silica gel cover (36), silica gel cover (36) are located the waistband body (1) outside, two revolving rack (3) use medicine rack (23) as central symmetry distribution.

3. The stone needle physiotherapy waistband of claim 1, which is characterized in that: two bandages (11) which are symmetrically distributed are sewn on the outer wall of the waistband body (1), and the two bandages (11) are matched and bonded through magic tapes (12).

4. The stone needle physiotherapy waistband of claim 1, which is characterized in that: folding bellows (21) and moxa-moxibustion box (2) are inside to communicate with each other, moxa-moxibustion screwed pipe (35) and inside communicating with each other of moxa-moxibustion box (2).

5. The stone needle physiotherapy waistband of claim 1, which is characterized in that: the medicine placing frame (23) is positioned between the box cover (22) and the rotating frame (3), and the heat conducting block (33) is positioned between the medicine placing frame (23) and the electric heating pipe (32).

6. The stone needle physiotherapy waistband of claim 1, which is characterized in that: electric heating pipe (32) are located between heat conduction piece (33) and second stone needle (34), inlay between the waistband body (1) and moxa-moxibustion box (2) and have evenly distributed's first stone needle (13).

7. The stone needle physiotherapy waistband according to any one of claims 1 to 6, which is characterized in that: the waistband body (1) is formed by weaving nano cuprous oxide @ copper oxide/stone needle fibers, and the preparation method of the nano cuprous oxide @ copper oxide/stone needle fibers comprises the following steps:

4) and dispersing the product C in 100mL of hydrogen peroxide with the mass fraction of 10-20%, magnetically stirring for 6-10 h, centrifuging, and drying at 60-80 ℃ for 0.5-2 h to obtain the nano cuprous oxide @ copper oxide/stone needle.

8. The stone needle physiotherapy waistband of claim 7, which is characterized in that: in the step 1), the copper salt is one or a combination of copper acetate, copper citrate or copper lactate; the strong base is one or the combination of sodium hydroxide or potassium hydroxide.

9. The stone needle physiotherapy waistband of claim 8, which is characterized in that: the weak reducing agent in the step 3) is one or the combination of glucose or ascorbic acid.

10. The stone needle physiotherapy waistband of claim 9, which is characterized in that: an anti-static composite system is added into the suspension A, and the anti-static composite system comprises the following components in a mass ratio of 1: 2-5 of a mixture of mixed graphene powder and an antistatic fluid;

the preparation method of the antistatic fluid comprises the following steps: