CN106243786B - A kind of preparation method of the fabric ultraviolet resistant of simple and efficient - Google Patents
A kind of preparation method of the fabric ultraviolet resistant of simple and efficient Download PDFInfo
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- CN106243786B CN106243786B CN201610613827.9A CN201610613827A CN106243786B CN 106243786 B CN106243786 B CN 106243786B CN 201610613827 A CN201610613827 A CN 201610613827A CN 106243786 B CN106243786 B CN 106243786B
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- fabric
- zinc
- preparation
- ultraviolet resistant
- drying
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Abstract
The invention discloses a kind of preparation method of the fabric ultraviolet resistant of simple and efficient, include the following steps：(1) fabric is immersed into zinc chloride ethanol solution, is ultrasonically treated, then takes out fabric, washed with water to remaining zinc chloride is removed, then dry；(2) zinc salt and sodium hydroxide are configured into mixed solution, then the fabric of drying is put into mixed liquor, is kept the temperature in a kettle；(3) fabric in reaction kettle is taken out, washes with water clean, then drying.The present invention, which has, to be prepared simply, and time-consuming short, fiber surface zinc oxide keeps nano-scale, it is evenly distributed, nano zine oxide is tightly combined with fiber, not easily to fall off, with solution system in fiber surface in-situ preparation zinc oxide crystal seed, the characteristics of the recyclable recycling of solution after reaction.
Description
Technical field
The present invention relates to a kind of preparation method of fabric ultraviolet resistant, particularly a kind of anti-purple of the fabric of simple and efficient
The preparation method of outside line coating.
Background technology
Recently as the improvement of people's living standards, requirement of the people to clothes is also higher and higher.High-grade, comfortable, tool
There is the textile of the functions such as uvioresistant, antibacterial, automatically cleaning more and more favored by consumers.
ZnO is a kind of multi-functional semi-conducting material, and ultraviolet is acted on excellent shielding protection.When these materials
Particle size is suitable with light wave or during smaller, due to small-size effect, causes light absorbs to significantly increase, the small Particle Scattering of particle diameter
Ability is strong, and shield effectiveness is good.Therefore zinc oxide nano-powder can decay ultraviolet, especially wavelength as 280nm-320nm's
Ultraviolet；Nano granular of zinc oxide has preferable visible light-transmissive effect at the same time, compared with traditional organic uv absorbers,
Nano zine oxide is inorganic constituents, and effective acting time length, grows the wave band of light radiation shielding, have very high chemical stability and
Thermostabilization structure, it is nontoxic, nonirritant, it is safe and reliable.Therefore tool can be developed by these characteristics of nano zine oxide
There are antibacterial, deodorization, the textile product of radiation proof function, formed industrialization product has antibacterial underwear, operation dress, nurse
Clothes, smelly eliminating dressing, deodorization bandage, lavatory textile and Summer care dress, summer cap, daylight umbrella, gym suit etc..
At present, the method for improving aramid fiber anti-ultraviolet ageing performance mainly utilizes sol-gel process, such as CN103898767A
Disclosed titania modified methyl silicon resin aramid fiber coating, first must activate 1~2h to aramid fiber, prepare titania gel
Reaction also needs 4~6h, and modified organic silicone resin and curing also need to 5~10h, and the process is complicated, takes longer.Second, mixing is spun
Silk method, i.e., add ultraviolet absorber in fiber spinning solution, but the ultraviolet absorber added often influences whether fibre crystallinity,
So that the bulk strength reduction of prepared fiber is larger.Zinc oxide colloidal sol is prepared in CN101012621A, by impregnating, drying,
Baking and banking up with earth the nano level zinc oxide in fiber surface depositing zinc oxide nanosized seeds, this deposition process can reunite so that
Final particle no longer keeps nanoscale, and zinc oxide crystal seed is also uneven in fiber surface distribution, and this method deposition
Zinc oxide fine particles easily come off.Third, use magnetron sputtering coater in fiber surface ion sputtering film coating, such as CN1970882A
Metal coating is plated in fiber surface, the fabric that this method processing makes loses insulating properties, and is needed during processing higher
Vacuum condition, be unfavorable for industrialization large-scale production.
The content of the invention
It is an object of the present invention to provide a kind of preparation method of the fabric ultraviolet resistant of simple and efficient, to make up
The deficiencies in the prior art or defect, meet the demands of production and living.The present invention, which has, prepares simple, time-consuming short, fiber surface
Zinc oxide keeps nano-scale, is evenly distributed, nano zine oxide is tightly combined with fiber, not easily to fall off, with solution system in fibre
The characteristics of dimension table face in-situ preparation zinc oxide crystal seed, solution after reaction recyclable recycling.
Technical scheme：A kind of preparation method of the fabric ultraviolet resistant of simple and efficient, including following step
Suddenly：
(1) fabric is immersed into zinc chloride ethanol solution, is ultrasonically treated, then takes out fabric, washed with water remaining to removing
Zinc chloride, then dry；
(2) zinc solution will be contained to mix with sodium hydroxide solution, then the fabric of drying will be put into mixed liquor, reacted
Kept the temperature in kettle；
(3) fabric in reaction kettle is taken out, washes with water clean, then drying.
The preparation method of the fabric ultraviolet resistant of foregoing simple and efficient, includes the following steps：
(1) fabric is immersed into the zinc chloride ethanol solution that mass fraction is 5%~50%, is ultrasonically treated at least 3 minutes, takes
Go out fabric, wash with water to remaining zinc chloride is removed, then dried at 40-60 DEG C；
(2) by zinc salt and sodium hydroxide in molar ratio 1:0.5~1.5 is made into mixed solution, then puts the fabric of drying
Enter in mixed liquor, keep the temperature in a kettle at least 1 it is small when, 70-90 DEG C of temperature；
(3) fabric in reaction kettle is taken out, washes with water clean, then drying.
The preparation method of the fabric ultraviolet resistant of foregoing simple and efficient, the molar ratio of the zinc salt and sodium hydroxide
For 1:1.
The preparation method of the fabric ultraviolet resistant of foregoing simple and efficient, the fabric are aramid fiber or polyamide fibre.
The preparation method of the fabric ultraviolet resistant of foregoing simple and efficient, the zinc salt is zinc gluconate, nitric acid
Zinc, zinc chloride or zinc acetate.
The preparation method of the fabric ultraviolet resistant of foregoing simple and efficient, in the step (1), sonication treatment time
For 3 minutes, ultrasonic power 600W, 50 DEG C of drying temperature.
The preparation method of the fabric ultraviolet resistant of foregoing simple and efficient, in the step (2), soaking time 1
Hour, 80 DEG C of holding temperature.
Beneficial effects of the present invention：
1st, it is solution system during present invention reaction, compared to existing sol system, prepares configuration simply, recyclable repetition
Utilize, save raw material, reduce production cost.
2nd, the present invention had an effect using carbonyl, amino of the zinc ion only with fiber surface, under ultrasonic heat effect
Fiber surface in-situ preparation nano zine oxide crystal seed, it is short the time required to ultrasonication, due to the directionality of zinc ion, generation
Crystal seed is evenly distributed in fiber surface.Nano zine oxide crystal seed generates in ultrasonic wave high vibration environment, with fiber knot
Close closely, it is difficult to come off.
3rd, the present invention expands seeded growth using low-temperature hydrothermal deposition, and nano zine oxide is in fiber surface oriented growth, knot
Brilliant degree is good, and ultraviolet-resistent property is good.
Experimental example：
The fibers for taking 20 groups of pristine fibres and 20 groups to be prepared through the present invention respectively, will wherein 5 groups of pristine fibres and 5 groups
First carry out green strength test through the fiber that is prepared of the present invention, by other 5 groups of carry out ultraviolet irradiation 6 it is small when after to test its strong
Degree, by other 5 groups of carry out ultraviolet irradiation 12 it is small when after test its intensity, by other 5 groups of carry out ultraviolet irradiation 24 it is small when after test
Its intensity, and results are averaged by test, the results are shown in Table 1, as can be seen from Table 1：Compared with pristine fibre, this hair
The intensity of the bright fiber being prepared at the beginning is not much different, and after ultraviolet irradiation is subject to, pristine fibre and through this hair
The intensity of bright obtained fiber decreases, and still, the intensity of pristine fibre is with the increase of ultraviolet irradiation time, under intensity
Range of decrease degree is larger, and the decline of the intensity through fiber produced by the present invention is more slow, illustrates the fiber that the present invention is prepared
Uvioresistant ability is significantly improved.
The intensity contrast of 1 pristine fibre of table and the fiber being prepared through the present invention
Brief description of the drawings
Attached drawing 1 is the atomic force microscopy diagram on the aramid fiber surface being prepared through the present invention.
It can be seen that from attached drawing 1：Nano zine oxide is evenly distributed in the surface of aramid fiber, and the size of nano zine oxide
Less than 100nm.
Embodiment
The present invention is further illustrated with reference to the accompanying drawings and examples, but be not intended as to the present invention limit according to
According to.
The embodiment of the present invention：
Embodiment 1：A kind of preparation method of the fabric ultraviolet resistant of simple and efficient, includes the following steps：
(1) aramid fiber or polyamide fibre are immersed into mass fraction for 30% zinc chloride ethanol solution, ultrasound under ultrasonic power 600W
Processing 3 minutes, takes out aramid fiber, washes with water to remaining zinc chloride is removed, is then dried at 50 DEG C；
(2) by zinc nitrate and sodium hydroxide in molar ratio 1:1 is made into mixed solution, and the aramid fiber of drying then is put into mixing
In liquid, when insulation 1 is small in a kettle, 80 DEG C of temperature；
(3) aramid fiber in reaction kettle is taken out, washes with water clean, then drying.
Embodiment 2：A kind of preparation method of the fabric ultraviolet resistant of simple and efficient, includes the following steps：
(1) polyamide fibre is immersed into the zinc chloride ethanol solution that mass fraction is 5%, 10 points is ultrasonically treated under ultrasonic power 600W
Clock, takes out polyamide fibre, washes with water to remaining zinc chloride is removed, is then dried at 40 DEG C；
(2) by zinc gluconate and sodium hydroxide in molar ratio 1:0.5 is made into mixed solution, then puts the polyamide fibre of drying
Enter in mixed liquor, when insulation 2 is small in a kettle, temperature 70 C；
(3) polyamide fibre in reaction kettle is taken out, washes with water clean, then drying.
Embodiment 3：A kind of preparation method of the fabric ultraviolet resistant of simple and efficient, includes the following steps：
(1) aramid fiber is immersed into the zinc chloride ethanol solution that mass fraction is 50%, 30 is ultrasonically treated under ultrasonic power 600W
Minute, aramid fiber is taken out, washes with water to remaining zinc chloride is removed, is then dried at 60 DEG C；
(2) by zinc acetate and sodium hydroxide in molar ratio 1:1.5 are made into mixed solution, are then put into the aramid fiber of drying mixed
Close in liquid, when insulation 5 is small in a kettle, 90 DEG C of temperature；
(3) aramid fiber in reaction kettle is taken out, washes with water clean, then drying.
Claims (7)
1. the preparation method of the fabric ultraviolet resistant of a kind of simple and efficient, it is characterised in that include the following steps：
(1) fabric is immersed into zinc chloride ethanol solution, is ultrasonically treated, then takes out fabric, washed with water to the chlorine for removing remnants
Change zinc, then dry；
(2) zinc solution will be contained to mix with sodium hydroxide solution, then the fabric of drying will be put into mixed liquor, in a kettle
Insulation；
(3) fabric in reaction kettle is taken out, washes with water clean, then drying.
2. the preparation method of the fabric ultraviolet resistant of simple and efficient according to claim 1, it is characterised in that including
Following steps：
(1) fabric is immersed into the zinc chloride ethanol solution that mass fraction is 5%~50%, be ultrasonically treated at least 3 minutes, taking-up is knitted
Thing, washes with water to remaining zinc chloride is removed, is then dried at 40-60 DEG C；
(2) by zinc salt and sodium hydroxide in molar ratio 1:0.5~1.5 is made into mixed solution, is then put into the fabric of drying mixed
Close liquid in, keep the temperature in a kettle at least 1 it is small when, 70-90 DEG C of temperature；
(3) fabric in reaction kettle is taken out, washes with water clean, then drying.
3. the preparation method of the fabric ultraviolet resistant of simple and efficient according to claim 2, it is characterised in that：It is described
The molar ratio of zinc salt and sodium hydroxide is 1:1.
4. the preparation method of the fabric ultraviolet resistant of simple and efficient according to claim 1 or 2, it is characterised in that：
The fabric is aramid fiber or polyamide fibre.
5. the preparation method of the fabric ultraviolet resistant of the simple and efficient according to claim 1,2 or 3, its feature exist
In：The zinc salt is zinc gluconate, zinc nitrate, zinc chloride or zinc acetate.
6. the preparation method of the fabric ultraviolet resistant of simple and efficient according to claim 2, it is characterised in that：It is described
In step (1), sonication treatment time is 3 minutes, ultrasonic power 600W, 50 DEG C of drying temperature.
7. the preparation method of the fabric ultraviolet resistant of simple and efficient according to claim 2, it is characterised in that：It is described
In step (2), when soaking time is 1 small, 80 DEG C of holding temperature.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610613827.9A CN106243786B (en) | 2016-07-29 | 2016-07-29 | A kind of preparation method of the fabric ultraviolet resistant of simple and efficient |
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| CN201610613827.9A CN106243786B (en) | 2016-07-29 | 2016-07-29 | A kind of preparation method of the fabric ultraviolet resistant of simple and efficient |
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| CN106243786A CN106243786A (en) | 2016-12-21 |
| CN106243786B true CN106243786B (en) | 2018-05-11 |
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| CN107385878B (en) * | 2017-07-28 | 2020-08-28 | 上海工程技术大学 | By using supercritical CO2Method for performing inorganic modification on aramid fiber by using fluid technology |
| CN107740273A (en) * | 2017-09-30 | 2018-02-27 | 江苏新瑞贝科技股份有限公司 | A kind of anti-ultraviolet finishing agent and preparation method thereof |
| CN108425244A (en) * | 2018-04-24 | 2018-08-21 | 吴刚 | A kind of preparation method of chitin modified silk fiber product |
| CN109098040B (en) * | 2018-08-22 | 2021-06-08 | 广西大学 | Preparation method of functional filter paper loaded with nano zinc oxide |
| CN109162086B (en) * | 2018-08-22 | 2020-09-04 | 广西大学 | Preparation method of nano-zinc oxide in-situ modified antibacterial fiber |
| CN109537264A (en) * | 2018-11-20 | 2019-03-29 | 合肥巧织纺织科技有限公司 | A method of in aramid fiber surface systematic function nano zine oxide-graphene |
| CN112391738B (en) * | 2020-10-16 | 2021-08-20 | 吉祥三宝高科纺织有限公司 | Warm-keeping flocculus with air lock function and preparation method thereof |
| CN114645454A (en) * | 2022-03-23 | 2022-06-21 | 闽江学院 | Ultraviolet-proof textile fabric and preparation process thereof |
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| CN101012621A (en) * | 2007-01-30 | 2007-08-08 | 东华大学 | Preparation method of zinc oxide nano-rod film on fibre product |
| CN102691204A (en) * | 2012-05-30 | 2012-09-26 | 南通大学 | Preparation method of nano-zinc-oxide-loaded antibacterial ultraviolet-resistant fibers or textiles |
| CN102936031A (en) * | 2012-11-16 | 2013-02-20 | 江苏大学 | Room temperature quick preparation method of nano-zinc oxide mesocrystal |
| CN102943379A (en) * | 2012-11-30 | 2013-02-27 | 苏州大学 | Preparation method of anti-bacterial ultraviolet-resistant textile |
| CN104118901A (en) * | 2014-07-23 | 2014-10-29 | 西安工程大学 | Preparation method of flower-like nano zinc oxide |
| CN105274828A (en) * | 2015-10-26 | 2016-01-27 | 贵州大学 | Method for quickly and efficiently improving anti-mildew and antibacterial properties of aramid fibers |
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2016
- 2016-07-29 CN CN201610613827.9A patent/CN106243786B/en active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101012621A (en) * | 2007-01-30 | 2007-08-08 | 东华大学 | Preparation method of zinc oxide nano-rod film on fibre product |
| CN102691204A (en) * | 2012-05-30 | 2012-09-26 | 南通大学 | Preparation method of nano-zinc-oxide-loaded antibacterial ultraviolet-resistant fibers or textiles |
| CN102936031A (en) * | 2012-11-16 | 2013-02-20 | 江苏大学 | Room temperature quick preparation method of nano-zinc oxide mesocrystal |
| CN102943379A (en) * | 2012-11-30 | 2013-02-27 | 苏州大学 | Preparation method of anti-bacterial ultraviolet-resistant textile |
| CN104118901A (en) * | 2014-07-23 | 2014-10-29 | 西安工程大学 | Preparation method of flower-like nano zinc oxide |
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| CN106243786A (en) | 2016-12-21 |
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