CN106243786A - A kind of preparation method of the fabric ultraviolet resistant of simple and efficient - Google Patents
A kind of preparation method of the fabric ultraviolet resistant of simple and efficient Download PDFInfo
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- CN106243786A CN106243786A CN201610613827.9A CN201610613827A CN106243786A CN 106243786 A CN106243786 A CN 106243786A CN 201610613827 A CN201610613827 A CN 201610613827A CN 106243786 A CN106243786 A CN 106243786A
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- Prior art keywords
- fabric
- preparation
- zinc
- efficient
- ultraviolet resistant
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- Granted
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- 239000004744 fabric Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 30
- 239000000243 solution Substances 0.000 claims abstract description 18
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000011592 zinc chloride Substances 0.000 claims abstract description 9
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 9
- RROAJOQUFRGVRG-UHFFFAOYSA-L dichlorozinc;ethanol Chemical compound [Cl-].[Cl-].[Zn+2].CCO RROAJOQUFRGVRG-UHFFFAOYSA-L 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 8
- 150000003751 zinc Chemical class 0.000 claims abstract description 7
- 239000011259 mixed solution Substances 0.000 claims abstract description 6
- 229920006231 aramid fiber Polymers 0.000 claims description 15
- 229920006052 Chinlon® Polymers 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 4
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical group [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 claims description 3
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 239000004246 zinc acetate Substances 0.000 claims description 3
- 239000011670 zinc gluconate Substances 0.000 claims description 3
- 235000011478 zinc gluconate Nutrition 0.000 claims description 3
- 229960000306 zinc gluconate Drugs 0.000 claims description 3
- 230000014759 maintenance of location Effects 0.000 claims description 2
- 238000000527 sonication Methods 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 28
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 23
- 239000011787 zinc oxide Substances 0.000 abstract description 11
- 239000013078 crystal Substances 0.000 abstract description 6
- 238000011065 in-situ storage Methods 0.000 abstract description 3
- 238000004064 recycling Methods 0.000 abstract description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940085805 fiberall Drugs 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- IJRVLVIFMRWJRQ-UHFFFAOYSA-N nitric acid zinc Chemical compound [Zn].O[N+]([O-])=O IJRVLVIFMRWJRQ-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- -1 titania modified methyl silicon Chemical class 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses the preparation method of the fabric ultraviolet resistant of a kind of simple and efficient, comprise the steps: that fabric is immersed zinc chloride ethanol solution, supersound process by (1), then take out fabric, clean to removing remaining zinc chloride with water, then dry；(2) zinc salt is configured mixed solution with sodium hydroxide, then the fabric of drying is put in mixed liquor, be incubated in a kettle.；(3) fabric in reactor is taken out, clean up with water, then dry.It is simple that the present invention has preparation, the shortest, and fiber surface zinc oxide keeps nano-scale, being evenly distributed, nano zine oxide is tightly combined with fiber, difficult drop-off, with solution system in fiber surface in-situ preparation zinc oxide crystal seed, the feature of the recyclable recycling of reacted solution.
Description
Technical field
The present invention relates to the preparation method of a kind of fabric ultraviolet resistant, the anti-purple of fabric of a kind of simple and efficient
The preparation method of outside line coating.
Background technology
Recently as the raising of people's living standard, people are more and more higher to the requirement of clothing.High-grade, comfortable, tool
The textile having the function such as uvioresistant, antibacterial, automatically cleaning is increasingly favored by consumer.
ZnO is a kind of multi-functional semi-conducting material, has excellent shielding protection effect to ultraviolet.When these materials
Particle size and light wave quite or less time, due to small-size effect, cause light to absorb and be obviously enhanced, the Particle Scattering that particle diameter is little
Ability is strong, and shield effectiveness is good.Therefore can decay ultraviolet, especially wavelength of zinc oxide nano-powder is 280nm-320nm's
Ultraviolet；Nano granular of zinc oxide has preferable visible light-transmissive effect simultaneously, compared with tradition organic uv absorbers,
Nano zine oxide is inorganic constituents, and effective acting time is long, to light radiation shielding wave band long, have the highest chemical stability and
Thermally-stabilised structure, nontoxic, nonirritant, safe and reliable.Therefore these characteristics by nano zine oxide can develop tool
Having antibacterial, deodorization, the textile product of radiation proof function, formed industrialization product has antibacterial underwear, operation dress, nurse
Clothes, smelly eliminating dressing, deodorization binder, lavatory textile and Summer care dress, cap in summer, daylight umbrella, gym suit etc..
At present, the method for raising aramid fiber anti-ultraviolet ageing performance is mainly by sol-gel process, such as CN103898767A
Disclosed titania modified methyl silicon resin aramid fiber coating, first must activate 1～2h to aramid fiber, prepare titania gel
Reaction also needs 4～6h, and modified organic silicone resin and solidification also need to 5～10h, and this process is complicated, the longest.Two is that mixing is spun
Silk method, i.e. adds ultraviolet absorber in fiber spinning solution, but the ultraviolet absorber added often has influence on fibre crystallinity,
The bulk strength making prepared fiber reduces bigger.CN101012621A is prepared zinc oxide colloidal sol, by impregnating, being dried,
Baking and banking up with earth at fiber surface depositing zinc oxide nanosized seeds, in this deposition process, nano level zinc oxide can be reunited so that
Final granule no longer keeps nanoscale, and zinc oxide crystal seed is the most uneven in fiber surface distribution, and this method deposition
Zinc oxide fine particles easily comes off.Three is at fiber surface ion sputtering film coating, as CN1970882A uses magnetron sputtering coater
Plating metal coating at fiber surface, the method processes the fabric made and loses insulating properties, and needs higher when processing
Vacuum condition, and be unfavorable for industrialization large-scale production.
Summary of the invention
It is an object of the invention to, it is provided that the preparation method of the fabric ultraviolet resistant of a kind of simple and efficient, to make up
The deficiencies in the prior art or defect, meet the demands of production and living.It is simple that the present invention has preparation, the shortest, fiber surface
Zinc oxide keeps nano-scale, is evenly distributed, and nano zine oxide is tightly combined with fiber, difficult drop-off, with solution system at fibre
Dimension table face in-situ preparation zinc oxide crystal seed, the feature of the recyclable recycling of reacted solution.
Technical scheme: the preparation method of the fabric ultraviolet resistant of a kind of simple and efficient, including walking as follows
Rapid:
(1) fabric is immersed zinc chloride ethanol solution, supersound process, then take out fabric, clean to removing remnants with water
Zinc chloride, then dry；
(2) zinc solution will be contained to mix with sodium hydroxide solution, then the fabric of drying be put in mixed liquor, in reaction
Still is incubated；
(3) fabric in reactor is taken out, clean up with water, then dry.
The preparation method of the fabric ultraviolet resistant of aforesaid simple and efficient, comprises the steps:
(1) fabric is immersed the zinc chloride ethanol solution that mass fraction is 5%～50%, supersound process at least 3 minutes, take
Go out fabric, clean to removing remaining zinc chloride with water, then dry at 40-60 DEG C；
(2) zinc salt is made into mixed solution with sodium hydroxide 1:0.5 in molar ratio～1.5, then the fabric of drying is put
Enter in mixed liquor, be incubated at least 1 hour in a kettle., temperature 70-90 DEG C；
(3) fabric in reactor is taken out, clean up with water, then dry.
The mol ratio of the preparation method of the fabric ultraviolet resistant of aforesaid simple and efficient, described zinc salt and sodium hydroxide
For 1:1.
The preparation method of the fabric ultraviolet resistant of aforesaid simple and efficient, described fabric is aramid fiber or chinlon.
The preparation method of the fabric ultraviolet resistant of aforesaid simple and efficient, described zinc salt is zinc gluconate, nitric acid
Zinc, zinc chloride or zinc acetate.
The preparation method of the fabric ultraviolet resistant of aforesaid simple and efficient, in described step (1), sonication treatment time
It is 3 minutes, ultrasonic power 600W, dry temperature 50 C.
The preparation method of the fabric ultraviolet resistant of aforesaid simple and efficient, in described step (2), temperature retention time is 1
Hour, holding temperature 80 DEG C.
Beneficial effects of the present invention:
1, the present invention is solution system when reacting, and compared to existing sol system, preparation configuration is simple, recyclable repetition
Utilize, economize in raw materials, reduce production cost.
2, the present invention utilizes zinc ion carbonyl, amino only with fiber surface to have an effect, under ultrasonic heat effect
Fiber surface in-situ preparation nano zine oxide crystal seed, ultrasonic Treatment required time is short, due to the directionality of zinc ion, generation
Crystal seed is evenly distributed at fiber surface.Nano zine oxide crystal seed generates in ultrasound wave high vibration environment, ties with fiber
Close closely, it is difficult to come off.
3, the present invention utilizes low-temperature hydrothermal deposition to expand seeded growth, and nano zine oxide is at fiber surface oriented growth, knot
Crystalline substance degree is good, and ultraviolet-resistent property is good.
Experimental example:
Take 20 groups of pristine fibres and 20 groups of fibers prepared through the present invention, general's wherein 5 groups of pristine fibres and 5 groups respectively
The fiber prepared through the present invention first carries out green strength test, tests it strong after carrying out ultraviolet irradiation 6 hours by other 5 groups
Degree, tests its intensity after carrying out ultraviolet irradiation 12 hours by other 5 groups, carries out ultraviolet irradiation by other 5 groups and test after 24 hours
Its intensity, and by the results averaged of test, result is as shown in table 1, as can be seen from Table 1: compared with pristine fibre, this
The bright fiber prepared intensity when initial is more or less the same, and after by ultraviolet irradiation, pristine fibre and through this
The intensity of bright prepared fiber all decreases, but, the intensity of pristine fibre is along with the increase of ultraviolet irradiation time, under intensity
Range of decrease degree is relatively big, and the intensity of the fiber prepared through the present invention declines more slow, and the fiber that the present invention prepares is described
Uvioresistant ability is significantly improved.
Table 1 pristine fibre and the intensity contrast of fiber prepared through the present invention
Accompanying drawing explanation
Accompanying drawing 1 is the atomic force microscope figure on the aramid fiber surface prepared through the present invention.
Can be seen that nano zine oxide is evenly distributed in the surface of aramid fiber, and the size of nano zine oxide from accompanying drawing 1
Less than 100nm.
Detailed description of the invention
The present invention is further illustrated with embodiment below in conjunction with the accompanying drawings, but is not intended as depending on restriction of the present invention
According to.
Embodiments of the invention:
Embodiment 1: the preparation method of the fabric ultraviolet resistant of a kind of simple and efficient, comprises the steps:
(1) aramid fiber or chinlon are immersed the zinc chloride ethanol solution that mass fraction is 30%, ultrasonic under ultrasonic power 600W
Process 3 minutes, take out aramid fiber, clean to removing remaining zinc chloride with water, then dry at 50 DEG C；
(2) zinc nitrate is made into mixed solution with sodium hydroxide 1:1 in molar ratio, then the aramid fiber of drying is put into mixing
In liquid, insulation 1 hour, temperature 80 DEG C in a kettle.；
(3) aramid fiber in reactor is taken out, clean up with water, then dry.
Embodiment 2: the preparation method of the fabric ultraviolet resistant of a kind of simple and efficient, comprises the steps:
(1) chinlon is immersed the zinc chloride ethanol solution that mass fraction is 5%, supersound process 10 points under ultrasonic power 600W
Clock, takes out chinlon, cleans to removing remaining zinc chloride with water, then dries at 40 DEG C；
(2) zinc gluconate is made into mixed solution with sodium hydroxide 1:0.5 in molar ratio, then the chinlon of drying is put
Enter in mixed liquor, in a kettle. insulation 2 hours, temperature 70 C；
(3) chinlon in reactor is taken out, clean up with water, then dry.
Embodiment 3: the preparation method of the fabric ultraviolet resistant of a kind of simple and efficient, comprises the steps:
(1) aramid fiber is immersed the zinc chloride ethanol solution that mass fraction is 50%, supersound process 30 under ultrasonic power 600W
Minute, take out aramid fiber, clean to removing remaining zinc chloride with water, then dry at 60 DEG C；
(2) zinc acetate is made into mixed solution with sodium hydroxide 1:1.5 in molar ratio, then the aramid fiber of drying is put into mixed
Close in liquid, in a kettle. insulation 5 hours, temperature 90 DEG C；
(3) aramid fiber in reactor is taken out, clean up with water, then dry.
Claims (7)
1. the preparation method of the fabric ultraviolet resistant of a simple and efficient, it is characterised in that comprise the steps:
(1) fabric is immersed zinc chloride ethanol solution, supersound process, then take out fabric, clean to removing remaining chlorine with water
Change zinc, then dry；
(2) zinc solution will be contained to mix with sodium hydroxide solution, then the fabric of drying be put in mixed liquor, in a kettle.
Insulation；
(3) fabric in reactor is taken out, clean up with water, then dry.
The preparation method of the fabric ultraviolet resistant of simple and efficient the most according to claim 1, it is characterised in that include
Following steps:
(1) fabric immersing the zinc chloride ethanol solution that mass fraction is 5%～50%, supersound process at least 3 minutes, taking-up is knitted
Thing, cleans to removing remaining zinc chloride with water, then dries at 40-60 DEG C；
(2) zinc salt is made into mixed solution with sodium hydroxide 1:0.5 in molar ratio～1.5, then the fabric of drying is put into mixed
Close in liquid, be incubated at least 1 hour in a kettle., temperature 70-90 DEG C；
(3) fabric in reactor is taken out, clean up with water, then dry.
The preparation method of the fabric ultraviolet resistant of simple and efficient the most according to claim 2, it is characterised in that: described
Zinc salt is 1:1 with the mol ratio of sodium hydroxide.
The preparation method of the fabric ultraviolet resistant of simple and efficient the most according to claim 1 and 2, it is characterised in that:
Described fabric is aramid fiber or chinlon.
5., according to the preparation method of the fabric ultraviolet resistant of the simple and efficient described in claim 1,2 or 3, its feature exists
In: described zinc salt is zinc gluconate, zinc nitrate, zinc chloride or zinc acetate.
The preparation method of the fabric ultraviolet resistant of simple and efficient the most according to claim 2, it is characterised in that: described
In step (1), sonication treatment time is 3 minutes, ultrasonic power 600W, dries temperature 50 C.
The preparation method of the fabric ultraviolet resistant of simple and efficient the most according to claim 2, it is characterised in that: described
In step (2), temperature retention time is 1 hour, holding temperature 80 DEG C.
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| CN201610613827.9A CN106243786B (en) | 2016-07-29 | 2016-07-29 | A kind of preparation method of the fabric ultraviolet resistant of simple and efficient |
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| CN201610613827.9A CN106243786B (en) | 2016-07-29 | 2016-07-29 | A kind of preparation method of the fabric ultraviolet resistant of simple and efficient |
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| CN106243786A true CN106243786A (en) | 2016-12-21 |
| CN106243786B CN106243786B (en) | 2018-05-11 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107385878A (en) * | 2017-07-28 | 2017-11-24 | 上海工程技术大学 | Utilize supercritical CO2The method that fluid technique carries out the inorganization modification of aramid fiber |
| CN107740273A (en) * | 2017-09-30 | 2018-02-27 | 江苏新瑞贝科技股份有限公司 | A kind of anti-ultraviolet finishing agent and preparation method thereof |
| CN108425244A (en) * | 2018-04-24 | 2018-08-21 | 吴刚 | A kind of preparation method of chitin modified silk fiber product |
| CN109098040A (en) * | 2018-08-22 | 2018-12-28 | 广西大学 | A kind of preparation method of supported nano zinc oxide function filter paper |
| CN109162086A (en) * | 2018-08-22 | 2019-01-08 | 广西大学 | A kind of preparation method of nano zine oxide in-situ modification anti-bacterial fibre |
| CN109537264A (en) * | 2018-11-20 | 2019-03-29 | 合肥巧织纺织科技有限公司 | A method of in aramid fiber surface systematic function nano zine oxide-graphene |
| CN112391738A (en) * | 2020-10-16 | 2021-02-23 | 吉祥三宝高科纺织有限公司 | Warm-keeping flocculus with air lock function and preparation method thereof |
| CN114645454A (en) * | 2022-03-23 | 2022-06-21 | 闽江学院 | Ultraviolet-proof textile fabric and preparation process thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101012621A (en) * | 2007-01-30 | 2007-08-08 | 东华大学 | Preparation method of zinc oxide nano-rod film on fibre product |
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| CN107385878B (en) * | 2017-07-28 | 2020-08-28 | 上海工程技术大学 | By using supercritical CO2Method for performing inorganic modification on aramid fiber by using fluid technology |
| CN107740273A (en) * | 2017-09-30 | 2018-02-27 | 江苏新瑞贝科技股份有限公司 | A kind of anti-ultraviolet finishing agent and preparation method thereof |
| CN108425244A (en) * | 2018-04-24 | 2018-08-21 | 吴刚 | A kind of preparation method of chitin modified silk fiber product |
| CN109098040A (en) * | 2018-08-22 | 2018-12-28 | 广西大学 | A kind of preparation method of supported nano zinc oxide function filter paper |
| CN109162086A (en) * | 2018-08-22 | 2019-01-08 | 广西大学 | A kind of preparation method of nano zine oxide in-situ modification anti-bacterial fibre |
| CN109098040B (en) * | 2018-08-22 | 2021-06-08 | 广西大学 | Preparation method of functional filter paper loaded with nano zinc oxide |
| CN109537264A (en) * | 2018-11-20 | 2019-03-29 | 合肥巧织纺织科技有限公司 | A method of in aramid fiber surface systematic function nano zine oxide-graphene |
| CN112391738A (en) * | 2020-10-16 | 2021-02-23 | 吉祥三宝高科纺织有限公司 | Warm-keeping flocculus with air lock function and preparation method thereof |
| CN112391738B (en) * | 2020-10-16 | 2021-08-20 | 吉祥三宝高科纺织有限公司 | Warm-keeping flocculus with air lock function and preparation method thereof |
| CN114645454A (en) * | 2022-03-23 | 2022-06-21 | 闽江学院 | Ultraviolet-proof textile fabric and preparation process thereof |
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