CN105463828B - A kind of method of the carried titanium dioxide nano wire on dacron - Google Patents
A kind of method of the carried titanium dioxide nano wire on dacron Download PDFInfo
- Publication number
- CN105463828B CN105463828B CN201511024971.0A CN201511024971A CN105463828B CN 105463828 B CN105463828 B CN 105463828B CN 201511024971 A CN201511024971 A CN 201511024971A CN 105463828 B CN105463828 B CN 105463828B
- Authority
- CN
- China
- Prior art keywords
- dacron
- titanium
- titanium dioxide
- immersed
- tio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Abstract
The invention discloses a kind of method of carried titanium dioxide nano wire on dacron, comprise the following steps：1) dacron is immersed in progress surface roughening processing in alkali amine aqueous solution；2) titanium colloidal sol is prepared, dacron is immersed, inculating crystal layer deposition is carried out on dacron surface；3) HCl treatment；4) preparing titanium dioxide nanowire growth liquid, and excessive titanium source is added, in dacron superficial growth hydrogen metatitanic acid nano wire；5) sulfuric acid treatment, obtains being loaded with the dacron of titanium dioxide nano thread.The inventive method achieves TiO2One-dimensional nano line and polymer-based end dacron it is compound, the more preferable self-cleaning performance of dacron and anti-microbial property are imparted, while its superior photocatalysis performance causes prepared terylene/TiO2Compound fabric has great application prospect in the filtering and degraded of sewage, air contaminant treatment field.
Description
Technical field
The present invention relates to a kind of method of the carried titanium dioxide nano wire on dacron, available for preparation antibacterial and certainly
Clean textile, products therefrom also can be used for the filtering and degraded of sewage, belong to medical environment-friendly materials technical field.
Background technology
Titanium dioxide, chemical formula TiO2, it is a kind of polymorphous semiconductor material with wide forbidden band, in photocatalytic water, photocatalytic-oxidation
Change, photo catalytic reduction, photocatalysis synthesis of organic substance, photocatalytic degradation organic matter, sterilizing, solar cell, automatically cleaning, gas are passed
The performance shown in terms of sensor and humidity sensor is noticeable, with important application prospect.Current TiO2Powder is given birth to
Production industrialization, but TiO2Powder haves the shortcomings that application aspect, for example：Due to nano-TiO2Particle is trickleer, in water
It is easy to cohesion, not free settling in solution and is difficult to reclaim, regeneration and recycling not only bad for product also results in water body
Secondary pollution.Therefore, people are increasingly prone to prepare the nano-TiO with high catalytic activity in recent years2Film.At present,
Realize and prepare nano-TiO in the inorganic substrates such as copper mesh, glass, sheet metal2Film.TiO in the flexible substrates such as polymer2It is thin
The growth of film, can further expand its application field.TiO is grown by substrate deposition of polymer2Polymer can also be improved
Some performances, for example, hydrophily, antibiotic property and UV resistance etc..
By TiO2It is combined with textile material, it is possible to produce with UV resistance, anti-microbial property and self-cleaning performance
Multi-functional textile.Further, since the hole of yarn fabric is adjustable, it may also be used for sewage water filtration and degraded.At present, utilize
TiO2Mainly there are two kinds to the method that staple fibre carries out functional modification：One is by TiO2Nano-particle is dispersed in spinning solution,
Direct fabrics are molded；Two be by TiO by coupling agent or other electric charge finishing agents, auxiliary agent2Nano-particle slurry is coated in fiber
Surface filming prepares TiO2Nanoparticle dispersion liquid is by the method padded in fiber surface film forming.For example, patent
CN101718035A is disclosed using PAA and ethanol as solvent and is prepared TiO2Nanoparticle dispersion liquid, then it is non-woven in terylene
The dacron with self-cleaning function is obtained after being padded on cloth.The shortcoming of first method is TiO2Nano-particle is nearly all wrapped
Bury in the fibre, the TiO of fiber surface exposure2Nano-particle is few, so that the functional modification effect to fiber in itself is little.The
The shortcoming of two kinds of methods is the TiO of the fiber surface after processing2The binding strength of film and fiber is not good, and the film on surface is
TiO2Film of nanoparticles, granularity is uneven, skewness, and photocatalytic activity is not so good as the TiO with one-dimensional nano structure2Film, it is such as uniform
TiO2Nano-wire array film and TiO2Nano flower array film etc..
Compared to load TiO2TiO is loaded on nano-particle, fabric2Nano-wire array is capable of the automatically cleaning of significant increase fabric
Function and anti-microbial property.At present, one-dimensional TiO is loaded on dacron2Nano-wire array there is no literature reported on.
The content of the invention
The purpose of the present invention is that TiO is loaded on dacron there is provided one kind in view of the shortcomings of the prior art2Nano wire
Method.Compared to existing terylene and TiO2The compound technology for preparing functional fabric, the technology of the present invention can be lifted significantly
The self-cleaning performance (photocatalysis performance) and anti-microbial property of fabric.
The concrete technical scheme of the present invention is as follows：
One kind loads TiO on dacron2The method of nano wire, comprises the following steps：
(1) dacron surface roughening is handled：Dacron is first cleaned and dried using acetone, second alcohol and water successively
It is dry, ethylenediamine, sodium hydroxide, accelerator 1631 are added in deionized water and are configured to alkali amine aqueous solution, by above-mentioned dacron
By 1:30~1:50 bath raio is immersed in alkali amine aqueous solution, and 20min is reacted at 55~75 DEG C, is cleaned and is dried after taking-up；
(2) titanium colloidal sol is configured：At 0~10 DEG C, by butyl titanate, deionized water, nitric acid, ethanol mix 10~
30min, is configured to titanium colloidal sol；The dacron handled through (1) is immersed in 6~36h in titanium colloidal sol, afterwards with 10~360mm/
The min rate of pulling takes out dacron, in 60~80 DEG C of dry 12~36h；
(3) dacron handled through (2) is immersed in 0.1~0.2M hydrochloric acid solution, reacted at 60~80 DEG C
24~36h, is dried after taking-up；
(4) titanium dioxide nano thread growth-promoting media is configured：Nitre is added in mass concentration is 20~30% hydrogen peroxide solution
Acid and melamine obtain growth-promoting media, and the concentration of nitric acid is 0.31M in growth-promoting media, the mass fraction of melamine for 0.06~
0.1%；Excessive titanium source is added, dacron is then immersed in wherein 24~72h of reaction, cleans, dries after taking-up；It is described
Titanium source be usually titanium sponge or titanium valve or titanium sheet；Described excess refers to the consumption of titanium source for hydrogen peroxide in solution
It is excessive；
(5) sulfuric acid treatment：The dacron handled through (4) is immersed in the sulfuric acid solution that pH value is 1.5~3.5,
48~144h is reacted at 60~80 DEG C, is cleaned and dried after taking-up, load completes titanium dioxide nano thread on dacron, obtains
Terylene/TiO2Compound fabric.
In above-mentioned technical proposal, ethylenediamine, sodium hydroxide, accelerator 1631 in the alkali amine aqueous solution described in step (1)
Mass fraction ratio preferably 2:28:0.08.
Butyl titanate, deionized water described in step (2), nitric acid, the mol ratio of ethanol are preferably 1:1:0.1:
9.25。
The beneficial effects of the invention are as follows：
The inventive method achieves TiO2One-dimensional nano structure (nano wire) and polymer-based end dacron it is compound,
The more preferable self-cleaning performance of dacron and anti-microbial property are imparted, while its superior photocatalysis performance causes prepared wash
Synthetic fibre/TiO2Compound fabric has great application prospect in the filtering and degraded of sewage, air contaminant treatment field.
Brief description of the drawings
Fig. 1 is the Flied emission scanning electron on the dacron surface for being loaded with titanium dioxide nano thread prepared by embodiment 1
Microphotograph.
Fig. 2 is the Flied emission scanning electron on the dacron surface for being loaded with titanium dioxide nano thread prepared by embodiment 2
Microphotograph.
Fig. 3 is the XRD spectrum on the dacron surface for being loaded with titanium dioxide nano thread prepared by embodiment 3.
Fig. 4 is the Flied emission scanning electron on the dacron surface for being loaded with titanium dioxide nano thread prepared by embodiment 4
Microphotograph.
Embodiment
The present invention is expanded on further with reference to embodiments, but the present invention is not limited solely to following embodiments.
Embodiment 1
(1) it is sample to choose the dacron that specification is the D of 75D × 120, takes 5 × 5cm of size2Sample respectively through acetone
Wash 1 time, ethanol is washed 3 times and deionization is washed 3 times, is dried.
(2) by ethylenediamine：Sodium hydroxide：Accelerator 1631 compares 2 according to mass fraction:28:0.08 adds in deionized water
Alkali amine aqueous solution is configured, 1 will be pressed by the dacron being cleaned and dried:30 bath raioes are immersed in alkali amine aqueous solution at 65 DEG C instead
20min is answered, is washed, is dried.
(3) at 4 DEG C, by butyl titanate：Deionized water：Nitric acid：Ethanol in molar ratio 1:1:0.1:9.25 stirring
10min, configures titanium colloidal sol, the sample after above-mentioned processing is submerged into the 24h in this titanium colloidal sol, then with 50mm/min speed
Lifting is taken out, and 24h is dried at 80 DEG C.
(4) sample after above-mentioned processing is immersed in 0.15M hydrochloric acid solutions and reacts 24h at 70 DEG C, it is rear to dry.
(5) growth-promoting media of titanium dioxide nano thread is configured：Nitric acid is added in mass concentration is 30% hydrogen peroxide solution
And melamine, the concentration of nitric acid is 0.31M in growth-promoting media, and the mass fraction of melamine is 0.06%；And add excess
Titanium sponge the sample after above-mentioned processing be immersed in this reaction solution as titanium source, then reacted after 72h, use deionization
Water is cleaned, and is dried.
(6) sample is immersed in the sulfuric acid solution that pH value is 2.5,72h is reacted at 80 DEG C, washed, dried, you can
To terylene/titanium dioxide compound fabric finished product, its SEM photograph is as shown in Figure 1.
Embodiment 2
(1) it is sample to choose the dacron that specification is the D of 30D × 30, takes 5 × 5cm of size2Sample respectively through acetone
Wash 1 time, ethanol is washed 3 times and deionization is washed 3 times, is dried.
(2) step of be the same as Example 1 (2).
(3) at 0 DEG C, by butyl titanate：Deionized water：Nitric acid：Ethanol in molar ratio 1:1:0.1:9.25 stirring
10min configures titanium colloidal sol.Sample after above-mentioned processing is submerged into the 24h in this titanium colloidal sol, then with 100mm/min speed
Lifting is taken out, and drying time is 24h at 80 DEG C.
(4) step of be the same as Example 1 (4).
(5) growth-promoting media of titanium dioxide nano thread is configured：Nitric acid is added in mass concentration is 30% hydrogen peroxide solution
And melamine, the concentration of nitric acid is 0.31M in growth-promoting media, and the mass fraction of melamine is 0.06%.And add excess
Titanium valve the sample after above-mentioned processing be immersed in this reaction solution as titanium source, then reacted after 48h, use deionized water
Cleaning, is dried.
(6) step of be the same as Example 1 (6), the SEM photograph of products therefrom is as shown in Figure 2.
Embodiment 3
(1) step of be the same as Example 1 (1).
(2) by ethylenediamine：Sodium hydroxide：Accelerator 1631 is according to mass ratio 2:28:0.08 adds configuration in deionized water
Alkali amine aqueous solution, will press 1 by the dacron being cleaned and dried:30 bath raioes are immersed in alkali amine aqueous solution reacts at 75 DEG C
20min, is washed, and is dried.
(3) at 8 DEG C, by butyl titanate：Deionized water：Nitric acid：Ethanol in molar ratio 1:1:0.1:9.25 configure titanium
Colloidal sol, stirs 10min.Sample after above-mentioned processing is submerged into the 24h in this titanium colloidal sol, then with 150mm/min speed
Lifting, drying time is 24h at 80 DEG C.
(4) step of be the same as Example 1 (4)
(5) growth-promoting media of titanium dioxide nano thread is configured：Nitric acid is added in mass concentration is 30% hydrogen peroxide solution
And melamine, the concentration of nitric acid is 0.31M in growth-promoting media, and the mass fraction of melamine is 0.1%.And add titanium sheet work
For titanium source, then the sample after above-mentioned processing is immersed in this reaction solution and reacted after 72h, is cleaned with deionized water, is done
It is dry.
(6) sample is immersed in the sulfuric acid solution that pH value is 3,120h is reacted at 80 DEG C, washed, dried, you can
To terylene/titanium dioxide compound fabric finished product, its XRD result is as shown in Figure 3.
Embodiment 4
(1) step of be the same as Example 2 (1)
(2) step of be the same as Example 3 (2)
(3) at 4 DEG C, by butyl titanate：Deionized water：Nitric acid：Ethanol in molar ratio 1:1:0.1:9.25 configure titanium
Colloidal sol, stirs 10min.Sample after above-mentioned processing is submerged into the 24h in this titanium colloidal sol, then with 200mm/min speed
Lifting, drying time is 24h at 80 DEG C.
(4) sample after above-mentioned processing to be immersed in 0.15M hydrochloric acid solutions and reacts 24h at 60 DEG C, it is rear dry
It is dry.
(5) growth-promoting media of titanium dioxide nano thread is configured：Nitric acid is added in mass concentration is 30% hydrogen peroxide solution
And melamine, the concentration of nitric acid is 0.31M in growth-promoting media, and the mass fraction of melamine is 0.1%.And add excessive
Then sample after above-mentioned processing is immersed in this reaction solution and reacts after 24h, use deionized water as titanium source by titanium sponge
Cleaning, is dried.
(6) sample is immersed in the sulfuric acid solution that pH value is 2,72h is reacted at 80 DEG C, washed, dried, you can obtain
Terylene/titanium dioxide compound fabric finished product, its SEM photograph is as shown in Figure 4.
Claims (3)
1. one kind loads TiO on dacron2The method of nano wire, it is characterised in that comprise the following steps：
（1）Dacron surface roughening is handled：Dacron is first cleaned and dried using acetone, second alcohol and water successively, will
Ethylenediamine, sodium hydroxide, accelerator 1631, which are added in deionized water, is configured to alkali amine aqueous solution, and above-mentioned dacron is pressed into 1:30
~1:50 bath raio is immersed in alkali amine aqueous solution, and 20 min are reacted at 55 ~ 75 DEG C, is cleaned and is dried after taking-up；
（2）Configure titanium colloidal sol：At 0 ~ 10 DEG C, butyl titanate, deionized water, nitric acid, ethanol are mixed 10 ~ 30
Min, is configured to titanium colloidal sol；Will be through（1）The dacron of processing is immersed in 6 ~ 36 h in titanium colloidal sol, afterwards with 10 ~ 360 mm/
The min rate of pulling takes out dacron, in 60 ~ 80 DEG C of dry 12 ~ 36 h；Described butyl titanate, deionized water,
Nitric acid, the mol ratio of ethanol are 1:1:0.1:9.25；
（3）Will be through（2）The dacron of processing is immersed in 0.1 ~ 0.2 M hydrochloric acid solution, and 24 ~ 36 are reacted at 60 ~ 80 DEG C
H, is dried after taking-up；
（4）Configure titanium dioxide nano thread growth-promoting media：Nitric acid and three is added in mass concentration is 20 ~ 30 % hydrogen peroxide solution
The concentration that poly cyanamid obtains nitric acid in growth-promoting media, growth-promoting media is 0.31 M, and the mass fraction of melamine is 0.06 ~ 0.1%,
Excessive titanium source is added, dacron is then immersed in wherein 24 ~ 72 h of reaction, cleans, dries after taking-up；
（5）Sulfuric acid treatment：Will be through（4）The dacron of processing is immersed in the sulfuric acid solution that pH value is 1.5 ~ 3.5,60 ~ 80
At DEG C react 48 ~ 144 h, after taking-up be cleaned and dried, complete on dacron carried titanium dioxide nano wire, obtain terylene/
TiO2Compound fabric.
2. the method for the carried titanium dioxide nano wire according to claim 1 on dacron, it is characterised in that step
（1）Described in alkali amine aqueous solution in ethylenediamine, sodium hydroxide, accelerator 1631 mass fraction ratio be 2:28:0.08.
3. the method for the carried titanium dioxide nano wire according to claim 1 on dacron, it is characterised in that step
（4）Described in titanium source be titanium sponge or titanium valve or titanium sheet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511024971.0A CN105463828B (en) | 2015-12-30 | 2015-12-30 | A kind of method of the carried titanium dioxide nano wire on dacron |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511024971.0A CN105463828B (en) | 2015-12-30 | 2015-12-30 | A kind of method of the carried titanium dioxide nano wire on dacron |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105463828A CN105463828A (en) | 2016-04-06 |
| CN105463828B true CN105463828B (en) | 2017-09-01 |
Family
ID=55601953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511024971.0A Active CN105463828B (en) | 2015-12-30 | 2015-12-30 | A kind of method of the carried titanium dioxide nano wire on dacron |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105463828B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105970601B (en) * | 2016-06-07 | 2018-06-26 | 浙江大学 | A kind of preparation method of titanium dioxide nano-rod/polypyrrole/terylene compound fabric |
| CN108442127B (en) * | 2018-03-28 | 2019-11-01 | 南通大学 | A kind of preparation method of low-surface-energy foaming dacron |
| CN109281155B (en) * | 2018-09-27 | 2021-12-10 | 和也健康科技有限公司 | Modified antibacterial functional fiber and preparation method thereof |
| CN110554022B (en) * | 2019-09-17 | 2021-11-09 | 山东师范大学 | Double-heterostructure surface-enhanced Raman substrate for in-situ detection and preparation method and application thereof |
| CN111155086B (en) * | 2020-01-19 | 2021-08-06 | 浙江大学 | Method for growing titanium dioxide nanowire film on surface of stainless steel |
| CN112458790B (en) * | 2020-12-08 | 2022-05-31 | 马鞍山市康辉纸箱纸品有限公司 | Processing technology for improving antibacterial property of antibacterial packaging carton of vegetable essential oils |
| CN113578384B (en) * | 2021-08-19 | 2023-07-18 | 江苏大学 | Ectopic reaction Cr 6+ Preparation method and application of ion imprinting photocatalytic film |
| CN115584061B (en) * | 2022-10-24 | 2023-10-27 | 温州中农汉普鞋材科技有限公司 | Modified hemp stalk core powder, composite cat litter and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001131862A (en) * | 1999-10-29 | 2001-05-15 | Toyota Central Res & Dev Lab Inc | Sheet material carrying functional particle crystal and its manufacture |
| CN1614133A (en) * | 2004-09-01 | 2005-05-11 | 东华大学 | Collosol-gel ultraviolet-proof finishing liquid and its use for preparing ultraviolet-proof textile |
| TW200810197A (en) * | 2006-08-15 | 2008-02-16 | Univ Chang Gung | Method for producing composite solid polymer electrolyte (SPE) |
| CN1920162B (en) * | 2006-09-15 | 2010-04-07 | 浙江大学 | Method of coating polyester piece goods by silk fibroin combination liquid |
| CN102557130B (en) * | 2012-02-22 | 2013-12-25 | 浙江大学 | Method for preparing titanium dioxide nanoflower array film |
| CN103566915B (en) * | 2013-11-06 | 2015-05-20 | 浙江大学 | Method for growing TiO2 nanowire thin film on surface of stainless steel wire screen |
-
2015
- 2015-12-30 CN CN201511024971.0A patent/CN105463828B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105463828A (en) | 2016-04-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105463828B (en) | A kind of method of the carried titanium dioxide nano wire on dacron | |
| Liu et al. | Synthesizing BaTiO3 nanostructures to explore morphological influence, kinetics, and mechanism of piezocatalytic dye degradation | |
| Cai et al. | Soft BiOBr@ TiO 2 nanofibrous membranes with hierarchical heterostructures as efficient and recyclable visible-light photocatalysts | |
| Kim et al. | Polydopamine-assisted immobilization of hierarchical zinc oxide nanostructures on electrospun nanofibrous membrane for photocatalysis and antimicrobial activity | |
| Zhou et al. | Heterojunction of g-C3N4/BiOI immobilized on flexible electrospun polyacrylonitrile nanofibers: facile preparation and enhanced visible photocatalytic activity for floating photocatalysis | |
| Tang et al. | One-step electrospinning synthesis of TiO2/g-C3N4 nanofibers with enhanced photocatalytic properties | |
| Karimi et al. | Using graphene/TiO 2 nanocomposite as a new route for preparation of electroconductive, self-cleaning, antibacterial and antifungal cotton fabric without toxicity | |
| CN110540430B (en) | Preparation method of piezoelectric photocatalytic composite fiber with multi-stage structure | |
| CN105970601B (en) | A kind of preparation method of titanium dioxide nano-rod/polypyrrole/terylene compound fabric | |
| CN109759114B (en) | g-C3N4/TiO2RGO three-dimensional Z-shaped photocatalyst and in-situ electrospinning preparation method thereof | |
| Ran et al. | Polydopamine-induced in-situ growth of zeolitic imidazolate framework-8/TiO2 nanoparticles on cotton fabrics for photocatalytic performance | |
| Wang et al. | In-situ mineralized robust polysiloxane–Ag@ ZnO on cotton for enhanced photocatalytic and antibacterial activities | |
| CN100455508C (en) | Method for producing Nano carbon tube clad by metallic sulfide | |
| CN109248711B (en) | Loaded TiO (titanium dioxide)2Preparation method of PPS photocatalytic film | |
| Chang | “Firecracker-shaped” ZnO/polyimide hybrid nanofibers via electrospinning and hydrothermal process | |
| Du et al. | Bismuth tungstate coating on polyester fabric modified with dopamine for photocatalytic property under visible light irradiation | |
| Ran et al. | Core–shell BiVO 4@ PDA composite photocatalysts on cotton fabrics for highly efficient photodegradation under visible light | |
| Tian et al. | Cellulose nanofibrils anchored Ag on graphitic carbon nitride for efficient photocatalysis under visible light | |
| Wang et al. | Enhancement in the photocatalytic activity of TiO2 nanofibers hybridized with g-C3N4 via electrospinning | |
| Dong et al. | Plasma enhanced decoration of nc-TiO2 on electrospun PVDF fibers for photocatalytic application | |
| US20230349095A1 (en) | Method for sonochemical deposition of metals on textile substrates and products thereof | |
| Li et al. | Preparation and photocatalytic performance of dumbbell Ag2CO3–ZnO heterojunctions | |
| CN100575245C (en) | A kind of method for preparing CNT/CdS nano flower composite material | |
| Wang et al. | Construction of tubular g-C3N4/TiO2 S-scheme photocatalyst for high-efficiency degradation of organic pollutants under visible light | |
| Yu et al. | Large-scale synthesis of flexible TiO2/N-doped carbon nanofibres: A highly efficient all-day-active photocatalyst with electron storage capacity |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |