CN113388295A - High-wear-resistance self-cleaning wood floor and production process thereof - Google Patents
High-wear-resistance self-cleaning wood floor and production process thereof Download PDFInfo
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- CN113388295A CN113388295A CN202110683280.0A CN202110683280A CN113388295A CN 113388295 A CN113388295 A CN 113388295A CN 202110683280 A CN202110683280 A CN 202110683280A CN 113388295 A CN113388295 A CN 113388295A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Floor Finish (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to the technical field of wood floors, and particularly relates to a high-wear-resistance self-cleaning wood floor and a production process thereof. According to the invention, the effects of large hardness, good elastic tensile property, low surface energy and relatively large roughness of the floor surface coating are achieved by adding the graphene, the boron carbide, the modified polytetrafluoroethylene particles, the fluorine-containing resin and the curing accelerator into the floor surface coating, and the purposes of high wear resistance, hydrophobicity, oleophobicity and self-cleaning of the floor surface are finally realized. The invention has the following advantages: firstly, the floor surface coating has the advantages of high hardness, outstanding tensile resistance, low surface energy and relatively large roughness, so the floor surface has the double advantages of high wear resistance and self-cleaning of hydrophobic and oleophobic properties; secondly, the coating operation of the floor surface coating is simple and efficient; thirdly, the coating does not select the material of the wood veneer on the floor surface, and the application range is wide.
Description
Technical Field
The invention belongs to the technical field of wood floors, and particularly relates to a high-wear-resistance self-cleaning wood floor and a production process thereof.
Background
The existing functional improved wood floor can be endowed with various new functions of wear resistance, moisture resistance, silence, flame retardance, self-cleaning and heat preservation generally, and the realization mode mainly depends on the painting of the surface of the wood floor, so the formula composition and the coating process of the coating are particularly important.
The existing high-wear-resistance self-cleaning wood floor is realized by adding wear-resistant powder and an antibacterial agent into a floor surface coating, wherein the wear-resistant powder can be calcium carbonate powder or alumina powder, and the wear-resistant powder and the antibacterial agent are silver ion antibacterial agents or zinc oxide whiskers, but the high-wear-resistance self-cleaning wood floor still has at least the following two problems: firstly, the wear resistance is not enough, the surface wear resistance value is generally only about 0.08-0.09g/100r, and when the paint is used in public places, the paint is ground in less than half a year; secondly, the self-cleaning effect is limited to sterilization, and when oily pollutants or water-based pollutants are treated, the problems of residual pollutants and difficulty in cleaning are easily caused.
Therefore, in view of the above, a novel super-hydrophobic and super-oleophobic wood floor with outstanding wear resistance is urgently needed in the market.
The patent publication No. CN111360965A, Chinese patent application publication No. 2020.07.03 discloses a floor containing graphene paint, which comprises a wear-resistant decorative layer, a base material layer and a protective layer, wherein the wear-resistant decorative layer, the base material layer and the protective layer are sequentially arranged from top to bottom, and the base material layer is made of a wood substrate and graphene paint coated on the surface of the wood substrate; the invention also discloses a preparation method of the floor, which comprises the following steps: firstly, sanding and polishing a wood substrate; secondly, carrying out vacuum impregnation treatment by adopting an impregnation modifier; and thirdly, coating the graphene coating.
However, in the graphene coated floor in the patent, the graphene is used alone, so that the wear resistance of the floor is improved only from the aspect of increasing elastic stretching, and the hardness of the coating layer is not significantly improved, so that the overall wear resistance is not outstanding enough.
On the other hand, the graphene component in the patent of the invention has the secondary function of improving the tensile strength of the wood floor and also mainly ensures the heat conduction effect, so that the functions of hydrophobic and oleophobic property and self-cleaning of the floor are avoided.
Disclosure of Invention
The invention provides a high-wear-resistance self-cleaning wood floor and a production process thereof, which can achieve the effects of large hardness, good elastic tensile property, low surface energy and relatively large roughness of a floor surface coating by adding graphene, boron carbide, modified polytetrafluoroethylene particles, fluorine-containing resin and a curing accelerator into the floor surface coating, and finally achieve the purposes of high wear resistance, hydrophobic and oleophobic property and self cleaning of the floor surface.
The technical scheme adopted by the invention for solving the problems is as follows: a high wear-resistant self-cleaning wooden floor comprises the following components: graphene, boron carbide, modified polytetrafluoroethylene particles, fluorine-containing resin, a curing accelerator and water.
The further preferred technical scheme is as follows: the weight ratio of the graphene to the boron carbide is 1: (0.15-0.30).
In the invention, the Young modulus of the graphene is about 1000 GPa, the elastic stretching is about 20%, and the graphene serving as a toughening agent in the coating can well improve the elastic stretching performance of a floor surface coating and finally shows that the wear resistance of the floor is outstanding. In addition, the boron carbide has a diamond structure, high hardness (Mohs hardness of 9.36), and light weight (density of 2.52 g/cm)3) Abrasion resistance and impact resistance, and can improve the abrasion resistance of the floor surface coating to the maximum extent.
Secondly, the graphene is a two-dimensional plane structure, the boron carbide is a diamond structure, so when the content of the graphene is relatively excessive, the tensile strength of the floor surface coating is sufficient but the compressive strength is insufficient, so that the coating is easy to be flattened and fall off after 2-3 years of use, and conversely, when the content of the boron carbide is relatively excessive, the transverse tensile strength of the floor surface coating is insufficient, and the coating is easy to crack after 2-3 years of use, so the relative proportion of the graphene and the boron carbide is determined, and the wood floor coated with the coating of the invention can be effectively used in public places for 3-5 years, and the common floor can be used for only 1-2 years.
The further preferred technical scheme is as follows: the modified polytetrafluoroethylene particles are filled and modified polytetrafluoroethylene particles, the filling material is any one of lead powder, nickel powder or tin powder, and the density of the modified polytetrafluoroethylene particles is 2.50-2.65g/cm3The particle size is 225-275 μm.
The existing hydrophobic and oleophobic principle tells us that: the smaller surface energy and the relatively larger roughness are the key to ensuring and improving the hydrophobic and oleophobic performance, which is also the key to designing the coating formula of the invention.
In the invention, the polytetrafluoroethylene particles modified by lead powder, nickel powder or tin powder have the following functions: firstly, the surface energy of the polytetrafluoroethylene is small, so that the hydrophobic and oleophobic effects of a basic coating can be ensured, which is also the reason for selecting the polytetrafluoroethylene particles from a plurality of particles for structure reinforcement; second, lead powder, nickel powder or tin powder are modified, the density of the modified polytetrafluoroethylene particles is greatly improved, so that the modified polytetrafluoroethylene particles can sink as soon as possible in a coating system, occupy relatively more lower-layer spaces, and distribute graphene and boron carbide on the surface of the coating as much as possible, so that the roughness of the surface of the coating is increased, and the hydrophobic, oleophobic and self-cleaning effects of the coating can be further improved.
The further preferred technical scheme is as follows: the fluorine-containing resin is polytetrafluoroethylene resin, and the relative molecular weight of the polytetrafluoroethylene resin is 1150-1180 ten thousand.
In the present invention, the polytetrafluoroethylene resin having a relatively large molecular weight has the following advantages: firstly, the surface energy is small, which is the key; secondly, the components of the modified polytetrafluoroethylene particles are the same, so that the uniformity of the whole coating system can be better ensured; thirdly, the density is relatively high, so that the sinking speed of graphene and boron carbide can be properly reduced, the graphene and the boron carbide are distributed on the surface of the coating as much as possible, and the roughness of the surface of the coating needs to be increased.
The further preferred technical scheme is as follows: the curing accelerator is a polyamide curing agent.
In the invention, the polyamide curing agent has a general curing acceleration effect, but compared with other amine curing agents, the polyamide curing agent has the advantage of low surface energy, which is also the main reason for selecting the polyamide curing agent, and in the whole coating system, only faster curing can the graphene and the boron carbide be subjected to relatively less sedimentation action so as to ensure the roughness of the coating surface, which is also the reason for using the curing accelerator.
The further preferred technical scheme is as follows: 20 parts of graphene, 3-6 parts of boron carbide, 11-16 parts of modified polytetrafluoroethylene particles, 60-75 parts of fluorine-containing resin, 2-4 parts of a curing accelerator and 25-35 parts of water.
The further preferred technical scheme is as follows: the surface wear resistance of the floor surface coating is less than or equal to 0.04g/100r, and the water contact angle is 161-168 degrees.
In relevant standards and laws and regulations of Q/TBB 0040 plus 2019 commercial solid wood composite floor, GB/T18103 plus 2013 solid wood composite floor and GB/T31815 plus 2015 self-cleaning coating for outer surface of building, the required standard surface abrasion resistance is 0.08g/100r, and the waterproof performance of the waterproof wood floor requires that the water contact angle is less than or equal to 150 degrees, so the wood floor has the double advantages of high abrasion resistance and good self-cleaning performance.
The further preferred technical scheme is as follows: the roughness Ra of the floor surface coating is 3.8-4.2 mu m.
In the invention, the roughness Ra of 3.8-4.2 μm can ensure that the hydrophobic and oleophobic effect of the coating surface is further improved, and of course, the small surface energy is also ensured.
The production process of high wear resistance and self-cleaning wooden floor board includes coating the surface of the wooden floor board at 60-65 deg.c and 10-25cm/s in speed, coating 3 layers of the coating with the thickness of the lower two layers of 0.05-0.11mm and the thickness of the upper layer of 0.12-0.13mm in the interval of 2-3 min.
In the invention, a heating and layering coating mode is adopted, so that the curing can be ensured as soon as possible. And the surface of the coating obtained by curing has relatively more graphene and boron carbide so as to ensure the surface roughness of the coating, and the thickness of the last layer is the maximum so as to leave more graphene and boron carbide on the surface of the coating.
The further preferred technical scheme is as follows: the coating mode is that the floor surface is sprayed after being inverted and faced downwards.
In the invention, the existing paint spray gun is adopted to spray the surface of the inverted wood floor, so that graphene and boron carbide can be further left on the surface of the coating, the modified polytetrafluoroethylene particles are also adopted to ensure the sufficient roughness of the surface of the coating, the inverted wood floor is straightened after 5-15min after the spraying to complete the final coating curing effect, and the harmful problem that the solid material distribution is extremely uneven in the whole coating can be avoided.
The invention has the following advantages: firstly, the floor surface coating has the advantages of high hardness, outstanding tensile resistance, low surface energy and relatively large roughness, so the floor surface has the double advantages of high wear resistance and self-cleaning of hydrophobic and oleophobic properties; secondly, the coating operation of the floor surface coating is simple and efficient; thirdly, the coating does not select the material of the wood veneer on the floor surface, and the application range is wide.
Detailed Description
The following description is only a preferred embodiment of the present invention and is not intended to limit the scope of the present invention.
Example 1
The utility model provides a high wear-resisting, automatically cleaning wooden floor, from the top down includes coating, wooden cortex, substrate layer and dampproof course in proper order, and wooden cortex material wherein is the oak, and the substrate layer is concatenation pine stick, and the dampproof course is the kraft paper, and the used coating of top coating constitutes and includes: 20 parts of graphene, 3 parts of boron carbide, 12 parts of lead powder modified polytetrafluoroethylene particles, 60 parts of polytetrafluoroethylene resin, 2 parts of polyamide curing agent and 25 parts of water.
Wherein the density of the lead powder modified polytetrafluoroethylene particles is 2.50g/cm3Particle diameter ofThe relative molecular weight of the polytetrafluoroethylene resin was 1150 ten thousand at 228 μm.
Then, the coating itself had a surface abrasion resistance of 0.036g/100r, a water contact angle of 162 degrees, and a roughness Ra of 3.8 μm.
In the coating process of the coating, the control parameters are as follows: the coating temperature is 60 ℃, the coating speed is 10cm/s, 3 layers are coated, the thickness of the lower two layers is 0.05mm, the thickness of the uppermost layer is 0.12mm, the coating interval of each layer is 2min, the coating mode is that the floor surface is inverted and sprayed downwards, namely the layer with the thickness of 0.12mm is sprayed finally, the adopted spraying equipment is a paint spraying gun, and the manufacturer is Taiwan Baoli and the model is RL-103P.
Example 2
The utility model provides a high wear-resisting, automatically cleaning wooden floor, from the top down includes coating, wooden cortex, substrate layer and dampproof course in proper order, and wooden cortex material wherein is pine, and the substrate layer is PVC wood-plastic board, and the dampproof course is the kraft paper, and the used coating of top coat layer constitutes and includes: 20 parts of graphene, 4 parts of boron carbide, 13 parts of lead powder modified polytetrafluoroethylene particles, 63 parts of polytetrafluoroethylene resin, 3 parts of polyamide curing agent and 28 parts of water.
Wherein the density of the lead powder modified polytetrafluoroethylene particles is 2.56g/cm3The particle size was 231. mu.m, and the relative molecular weight of the polytetrafluoroethylene resin was 1160 ten thousand.
Then, the surface abrasion resistance of the coating itself was 0.032g/100r, the water contact angle was 163 °, and the roughness Ra was 3.9. mu.m.
In the coating process of the coating, the control parameters are as follows: the coating temperature is 62 ℃, the coating speed is 12cm/s, 3 layers are coated, the thickness of the lower two layers is 0.06mm, the thickness of the uppermost layer is 0.13mm, the coating interval of each layer is 2min, the coating mode is that the floor surface is inverted and sprayed downwards, namely the layer with the thickness of 0.13mm is sprayed finally, the adopted spraying equipment is a paint spraying gun, and the manufacturer is Taiwan Baoli and the model is RL-103P.
Example 3
The utility model provides a high wear-resisting, automatically cleaning wooden floor, from the top down includes coating, wooden cortex, substrate layer and dampproof course in proper order, and wooden cortex material wherein is fir, and the substrate layer is for extruding wood and moulds the board, and the dampproof course is the kraft paper, and the used coating of top coating constitutes and includes: 20 parts of graphene, 6 parts of boron carbide, 16 parts of lead powder modified polytetrafluoroethylene particles, 72 parts of polytetrafluoroethylene resin, 4 parts of polyamide curing agent and 32 parts of water.
Wherein the density of the lead powder modified polytetrafluoroethylene particles is 2.61g/cm3The particle size is 245 mu m, and the relative molecular weight of the polytetrafluoroethylene resin is 1180 ten thousand.
Then, the coating itself had a surface abrasion resistance of 0.037g/100r, a water contact angle of 165 ℃ and a roughness Ra of 4.2. mu.m.
In the coating process of the coating, the control parameters are as follows: the coating temperature is 63 ℃, the coating speed is 12cm/s, 3 layers are coated, the thickness of the lower two layers is 0.07mm, the thickness of the uppermost layer is 0.13mm, the coating interval of each layer is 2min, the coating mode is that the floor surface is inverted and sprayed downwards, namely the layer with the thickness of 0.13mm is sprayed finally, the adopted spraying equipment is a paint spraying gun, and the manufacturer is Taiwan Baoli and the model is RL-103P.
Example 4
The utility model provides a high wear-resisting, automatically cleaning wooden floor, from the top down includes coating, wooden cortex, substrate layer and dampproof course in proper order, and wooden cortex material wherein is poplar, and the substrate layer is wood-plastic plate, and the dampproof course is the kraft paper, and the used coating of top coat layer constitutes and includes: 20 parts of graphene, 6 parts of boron carbide, 16 parts of lead powder modified polytetrafluoroethylene particles, 75 parts of polytetrafluoroethylene resin, 2 parts of polyamide curing agent and 35 parts of water.
Wherein the density of the lead powder modified polytetrafluoroethylene particles is 2.53g/cm3The particle size is 261 mu m, and the relative molecular weight of the polytetrafluoroethylene resin is 1150 ten thousand.
Then, the surface abrasion resistance of the coating itself was 0.032g/100r, the water contact angle was 168 °, and the roughness Ra was 4.2. mu.m.
In the coating process of the coating, the control parameters are as follows: the coating temperature is 65 ℃, the coating speed is 12cm/s, 3 layers are coated, the thickness of the lower two layers is 0.07mm, the thickness of the uppermost layer is 0.13mm, the coating interval of each layer is 3min, the coating mode is that the floor surface is inverted and sprayed downwards, namely the layer with the thickness of 0.13mm is sprayed finally, the adopted spraying equipment is a paint spray gun, the manufacturer is a rockfield, and the model is a W-71WB water-based paint spray gun.
While the embodiments of the present invention have been described in detail, the present invention is not limited to the above embodiments, and various modifications can be made within the knowledge of those skilled in the art without departing from the spirit of the present invention. These are non-inventive modifications, which are intended to be protected by patent laws within the scope of the claims appended hereto.
Claims (10)
1. A high wear-resistant self-cleaning wooden floor is characterized in that the surface coating of the floor comprises the following components: graphene, boron carbide, modified polytetrafluoroethylene particles, fluorine-containing resin, a curing accelerator and water.
2. A highly wear resistant, self cleaning wood floor as claimed in claim 1, wherein: the weight ratio of the graphene to the boron carbide is 1: (0.15-0.30).
3. A highly wear resistant, self cleaning wood floor as claimed in claim 1, wherein: the modified polytetrafluoroethylene particles are filled and modified polytetrafluoroethylene particles, the filling material is any one of lead powder, nickel powder or tin powder, and the density of the modified polytetrafluoroethylene particles is 2.50-2.65g/cm3The particle size is 225-275 μm.
4. A highly wear resistant, self cleaning wood floor as claimed in claim 1, wherein: the fluorine-containing resin is polytetrafluoroethylene resin, and the relative molecular weight of the polytetrafluoroethylene resin is 1150-1180 ten thousand.
5. A highly wear resistant, self cleaning wood floor as claimed in claim 1, wherein: the curing accelerator is a polyamide curing agent.
6. A highly wear resistant, self-cleaning wood floor as claimed in claim 2, characterized in that said floor surface coating comprises the following components by weight: 20 parts of graphene, 3-6 parts of boron carbide, 11-16 parts of modified polytetrafluoroethylene particles, 60-75 parts of fluorine-containing resin, 2-4 parts of a curing accelerator and 25-35 parts of water.
7. A highly wear resistant, self cleaning wood floor as claimed in claim 1, wherein: the surface wear resistance of the floor surface coating is less than or equal to 0.04g/100r, and the water contact angle is 161-168 degrees.
8. A highly wear resistant, self cleaning wood floor as claimed in claim 1, wherein: the roughness Ra of the floor surface coating is 3.8-4.2 mu m.
9. The method for manufacturing a highly abrasion-resistant, self-cleaning wooden floor as claimed in claim 1, wherein the coating temperature of the surface coating of the floor is 60-65 ℃, the coating speed is 10-25cm/s, 3 layers are coated, the thickness of the lower two layers is 0.05-0.11mm, the thickness of the upper layer is 0.12-0.13mm, and the coating interval of each layer is 2-3 min.
10. The method for producing a highly wear-resistant, self-cleaning wooden floor as claimed in claim 9, wherein: the coating mode is that the floor surface is sprayed after being inverted and faced downwards.
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086665A (en) * | 2015-09-29 | 2015-11-25 | 北京志盛威华化工有限公司 | Self-cleaning nano coating |
| CN106634269A (en) * | 2016-12-06 | 2017-05-10 | 江苏纳纤新材料科技有限公司 | Hydrophobic-oleophobic antifouling paint and preparation method and application thereof |
| CN106634264A (en) * | 2016-12-04 | 2017-05-10 | 亚士漆(上海)有限公司 | Graphene-reinforced superhydrophobic finish-coat paint and preparation method thereof |
| CN108912867A (en) * | 2018-06-25 | 2018-11-30 | 东南大学 | A kind of environmental protection high transparency super hydrophobic coating and its preparation method and application |
| CN110343430A (en) * | 2012-09-28 | 2019-10-18 | 卡尔博迪昂有限公司 | Fluoropolymer coating |
| CN112294092A (en) * | 2020-10-23 | 2021-02-02 | 上海承一化学科技有限公司 | Pan with non-stick coating |
| CN112457701A (en) * | 2019-09-28 | 2021-03-09 | 汪百战 | Formula and preparation process of graphene-containing fluoropolymer coating |
| CN112745723A (en) * | 2019-10-30 | 2021-05-04 | 中国石油化工股份有限公司 | Water-based fluorocarbon resin heavy-duty anticorrosive paint and preparation method thereof |
-
2021
- 2021-06-21 CN CN202110683280.0A patent/CN113388295A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343430A (en) * | 2012-09-28 | 2019-10-18 | 卡尔博迪昂有限公司 | Fluoropolymer coating |
| CN105086665A (en) * | 2015-09-29 | 2015-11-25 | 北京志盛威华化工有限公司 | Self-cleaning nano coating |
| CN106634264A (en) * | 2016-12-04 | 2017-05-10 | 亚士漆(上海)有限公司 | Graphene-reinforced superhydrophobic finish-coat paint and preparation method thereof |
| CN106634269A (en) * | 2016-12-06 | 2017-05-10 | 江苏纳纤新材料科技有限公司 | Hydrophobic-oleophobic antifouling paint and preparation method and application thereof |
| CN108912867A (en) * | 2018-06-25 | 2018-11-30 | 东南大学 | A kind of environmental protection high transparency super hydrophobic coating and its preparation method and application |
| CN112457701A (en) * | 2019-09-28 | 2021-03-09 | 汪百战 | Formula and preparation process of graphene-containing fluoropolymer coating |
| CN112745723A (en) * | 2019-10-30 | 2021-05-04 | 中国石油化工股份有限公司 | Water-based fluorocarbon resin heavy-duty anticorrosive paint and preparation method thereof |
| CN112294092A (en) * | 2020-10-23 | 2021-02-02 | 上海承一化学科技有限公司 | Pan with non-stick coating |
Non-Patent Citations (2)
| Title |
|---|
| 《化工百科全书》编辑委员会编: "《化工百科全书 第9卷 聚合机理和方法-空间化学 ju-kong》", 30 June 1995, 化学工业出版社 * |
| 蒋宫澄: "《多孔介质油气藏岩石表面气体润湿性理论基础与应用》", 31 December 2015, 中国石油大学出版社 * |
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Application publication date: 20210914 |