CN113388263A - Green harmless plant dye for thermosensitive clothing material and dyeing method thereof - Google Patents
Green harmless plant dye for thermosensitive clothing material and dyeing method thereof Download PDFInfo
- Publication number
- CN113388263A CN113388263A CN202110691439.3A CN202110691439A CN113388263A CN 113388263 A CN113388263 A CN 113388263A CN 202110691439 A CN202110691439 A CN 202110691439A CN 113388263 A CN113388263 A CN 113388263A
- Authority
- CN
- China
- Prior art keywords
- extract
- thermosensitive
- plant dye
- dye
- green
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 53
- 238000004043 dyeing Methods 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims description 14
- 239000000284 extract Substances 0.000 claims abstract description 101
- 241000196324 Embryophyta Species 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 241000512259 Ascophyllum nodosum Species 0.000 claims abstract description 23
- COHYTHOBJLSHDF-UHFFFAOYSA-N Indigo Chemical compound N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 9
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 9
- 241001330002 Bambuseae Species 0.000 claims abstract description 9
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 9
- 239000011425 bamboo Substances 0.000 claims abstract description 9
- 239000006229 carbon black Substances 0.000 claims abstract description 9
- 229930002875 chlorophyll Natural products 0.000 claims abstract description 9
- 235000019804 chlorophyll Nutrition 0.000 claims abstract description 9
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 claims abstract description 9
- KBPHJBAIARWVSC-RGZFRNHPSA-N lutein Chemical compound C([C@H](O)CC=1C)C(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\[C@H]1C(C)=C[C@H](O)CC1(C)C KBPHJBAIARWVSC-RGZFRNHPSA-N 0.000 claims abstract description 9
- 229960005375 lutein Drugs 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- KBPHJBAIARWVSC-XQIHNALSSA-N trans-lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C KBPHJBAIARWVSC-XQIHNALSSA-N 0.000 claims abstract description 9
- FJHBOVDFOQMZRV-XQIHNALSSA-N xanthophyll Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C=C(C)C(O)CC2(C)C FJHBOVDFOQMZRV-XQIHNALSSA-N 0.000 claims abstract description 9
- 239000004229 Alkannin Substances 0.000 claims abstract description 8
- NEZONWMXZKDMKF-JTQLQIEISA-N Alkannin Chemical compound C1=CC(O)=C2C(=O)C([C@@H](O)CC=C(C)C)=CC(=O)C2=C1O NEZONWMXZKDMKF-JTQLQIEISA-N 0.000 claims abstract description 8
- 235000019232 alkannin Nutrition 0.000 claims abstract description 8
- UNNKKUDWEASWDN-UHFFFAOYSA-N alkannin Natural products CC(=CCC(O)c1cc(O)c2C(=O)C=CC(=O)c2c1O)C UNNKKUDWEASWDN-UHFFFAOYSA-N 0.000 claims abstract description 8
- YBHILYKTIRIUTE-UHFFFAOYSA-N berberine Chemical compound C1=C2CC[N+]3=CC4=C(OC)C(OC)=CC=C4C=C3C2=CC2=C1OCO2 YBHILYKTIRIUTE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229940093265 berberine Drugs 0.000 claims abstract description 8
- QISXPYZVZJBNDM-UHFFFAOYSA-N berberine Natural products COc1ccc2C=C3N(Cc2c1OC)C=Cc4cc5OCOc5cc34 QISXPYZVZJBNDM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000012680 lutein Nutrition 0.000 claims abstract description 8
- 239000001656 lutein Substances 0.000 claims abstract description 8
- ORAKUVXRZWMARG-WZLJTJAWSA-N lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C ORAKUVXRZWMARG-WZLJTJAWSA-N 0.000 claims abstract description 8
- 229920005610 lignin Polymers 0.000 claims abstract description 7
- 229940106705 chlorophyll Drugs 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 88
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 38
- 239000002994 raw material Substances 0.000 claims description 33
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- 239000003208 petroleum Substances 0.000 claims description 19
- 238000000605 extraction Methods 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 14
- 238000005303 weighing Methods 0.000 claims description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Substances OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000000706 filtrate Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000003153 chemical reaction reagent Substances 0.000 claims description 7
- PSLIMVZEAPALCD-UHFFFAOYSA-N ethanol;ethoxyethane Chemical compound CCO.CCOCC PSLIMVZEAPALCD-UHFFFAOYSA-N 0.000 claims description 7
- 239000012153 distilled water Substances 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229940097275 indigo Drugs 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000009967 direct dyeing Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- 238000003860 storage Methods 0.000 claims description 2
- 241000123069 Ocyurus chrysurus Species 0.000 claims 1
- 235000013311 vegetables Nutrition 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 230000003115 biocidal effect Effects 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 18
- 230000000844 anti-bacterial effect Effects 0.000 description 8
- 241000015177 Saccharina japonica Species 0.000 description 7
- 238000013329 compounding Methods 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241001149655 Rubia tinctorum Species 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 240000009235 Rubia cordifolia Species 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- -1 rare earth ions Chemical class 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241001071917 Lithospermum Species 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- IINNWAYUJNWZRM-UHFFFAOYSA-L erythrosin B Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 IINNWAYUJNWZRM-UHFFFAOYSA-L 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 235000008210 xanthophylls Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B65/00—Compositions containing mordants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Textile Engineering (AREA)
- Pest Control & Pesticides (AREA)
- Insects & Arthropods (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Coloring (AREA)
Abstract
The invention provides a green harmless plant dye for a thermosensitive clothing material and a preparation method thereof, wherein the green harmless plant dye is prepared from the following components in percentage by weight: 10-20% of plant dye, 0.1-2% of mordant, 20-40% of organic solvent and the balance of water. Specifically, the vegetable dye comprises 5% of coffee residue extract, 5% of orange extract and 5% of kelp extract, and the balance is one or more of lignin, lutein, berberine, chlorophyll, indigo blue, alkannin, bamboo carbon black powder and radix Rubiae extract. The green harmless plant dye for the thermosensitive garment material has the advantages of harmlessness, environmental protection, antibiosis, high dye uptake, strong color fastness and the like, and is beneficial to improving the dyeing effect of the thermosensitive garment material.
Description
Technical Field
The invention relates to the technical field of dyes, in particular to a green harmless plant dye for a thermosensitive garment material and a dyeing method thereof.
Background
The plant dye is obtained by extracting pigment from natural flowers, grasses, trees, stems, leaves, fruits, seeds, barks and roots. The plant dye has the advantages of small side effect, small toxicity, high safety coefficient, biodegradability, environmental protection, reproducibility, no harm to human health and the like, which are not possessed by chemical dyes.
The natural plant dye has wide sources, is closer to nature, has rich colors, and mostly has the problems of low dye uptake, poor color fastness, poor dyeing effect and the like.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a green harmless plant dye for a thermosensitive garment material and a dyeing method thereof.
In order to achieve the purpose, the invention is realized by the following technical scheme:
a green harmless plant dye for thermosensitive clothing materials is prepared from the following components in percentage by weight: 10-20% of plant dye, 0.1-2% of mordant, 20-40% of organic solvent and the balance of water.
Preferably, the plant dye is one or more of red lignin, lutein, berberine, chlorophyll, indigo blue, alkannin, bamboo carbon black powder, coffee grounds extract, orange extract, madder extract and kelp extract.
By the technical scheme, the erythrosin has the advantages of strong bleaching-resistant capability and good dyeing effect, the lutein has good antibacterial and antioxidant effects, the berberine has the characteristic of high dye-uptake rate, the chlorophyll, the indigo, the alkannin, the bamboo carbon black powder and the madder extract belong to green environment-friendly raw materials, the coffee residue extract contains more antibacterial and antioxidant substances, the orange extract has the advantages of high dye-uptake rate, high color fastness and the like, the kelp extract has the advantages of good water solubility, high dye-uptake rate and the like, and the plant dye has the advantages of environmental friendliness, bacteria resistance, high dye-uptake rate, high color fastness and the like by adopting the raw materials as the plant dye.
Preferably, the vegetable dye comprises 5% of coffee extract, 5% of orange extract and 5% of kelp extract, and the balance is one or more of lignin, lutein, berberine, chlorophyll, indigo, alkannin, bamboo carbon black powder and radix rubiae extract.
By adopting the technical scheme, the plant dye comprises the coffee grounds extract, the orange extract and the kelp extract, so that the plant dye has the advantages of good antibacterial property, good oxidation resistance, high dye-uptake rate, high color fastness and the like, and the comprehensive performance of the thermosensitive garment material dyed by the plant dye is favorably improved.
Preferably, the extraction method of the coffee grounds extract comprises the following steps: weighing 100g of coffee grounds, soaking in distilled water for 1-2h to make the coffee grounds fully expand, then putting into 1000ml of 1.2g/L NaOH solution, heating to 75-80 ℃, preserving heat for 60-80min to make the coffee extract fully dissolve out, standing, cooling, filtering to obtain filtrate, namely the coffee extract, and storing for later use.
By adopting the technical scheme, the coffee grounds are soaked by the NaOH solution, so that the coffee extracts in the coffee grounds can be fully dissolved out.
Preferably, the extraction method of the orange extract comprises the following steps: weighing 100g of dried orange peel, crushing, sieving by a 40-50 mesh sieve, adding 1000ml of petroleum ether-ethanol mixed reagent, carrying out microwave treatment for 15-20min under the microwave condition that the power is 350W and the stirring speed is 350-400r/min, standing for 1-1.5h under the temperature condition of 55-60 ℃, and finally carrying out suction filtration by a vacuum pump to obtain the orange extract for storage and standby.
Preferably, in the petroleum ether-ethanol mixed reagent, the mass ratio of the petroleum ether to the ethanol is 1.5:1.
By adopting the technical scheme, the orange extract in the dried orange peel can be fully dissolved out by adopting the petroleum ether-ethanol mixed reagent with the mass ratio of 1.5:1 under the condition of microwave treatment.
Preferably, the extraction method of the kelp extract comprises the following steps: weighing 100g of kelp cleaned by cold water, soaking in 45 ℃ warm water for 30-40min, taking out, cutting into small pieces of 1cm multiplied by 1cm, drying until the weight is reduced to 1/10-1/9 of the original weight, crushing, sieving with a 40-50 mesh sieve, adding into 900ml of distilled water, rapidly heating to boil, keeping for 45-50min, extracting the filtrate, extracting the filter residue again, repeating for 3 times, and combining the three filtrates to obtain the kelp extract, and storing for later use.
By adopting the technical scheme, the kelp extract in the kelp can be conveniently and fully dissolved out.
A method for dyeing a green harmless plant dye for thermosensitive clothing materials comprises the following steps:
(1) weighing the raw materials of the components according to the proportion, adding the raw materials into a cylinder, adding 3000ml of 60 ℃ warm water of 2000-;
(2) heating the solution obtained in the step (1) to 75 ℃ at the temperature of 1 ℃/min, preserving heat for 20-30min, adjusting the pH to 4-5, adding 10-15g/l of a softening and solidifying agent, uniformly stirring, preserving heat for 20-30min, and then dyeing the thermosensitive clothing material by adopting a direct dyeing method, wherein the bath water ratio is controlled to be 1: and 40, dyeing for 100min to finish the dyeing work of the thermosensitive clothing material.
Preferably, the stirring speed of the three salt adding solutions in the step (1) is 350-400 r/min.
Through setting up above-mentioned technical scheme, after weighing each component raw materials, divide the cubic to add the salt solution to the jar to this each component vegetable dye of being convenient for dissolves each other, adds gentle solidification agent after, is favorable to vegetable dye to heat-sensitive clothing material and dyes.
Preferably, the mordant is a rare earth-citric acid complex.
By adopting the technical scheme, the rare earth ions can be used as central ions to be complexed with the plant dye ions of the ligand, in addition, the complex also has the effect similar to that of an electrolyte and has certain dyeing promotion property, and the rare earth-citric acid complex is selected as a mordant, so that the dye uptake of the plant dye is favorably improved.
The invention has the beneficial effects that:
the red lignin has the advantages of strong bleaching agent resistance and good dyeing effect, the lutein has good antibacterial and antioxidant effects, the berberine has the characteristic of high dye uptake, the chlorophyll, the indigo, the alkannin, the bamboo carbon black powder and the madder extract belong to green and environment-friendly raw materials, the coffee residue extract contains more antibacterial and antioxidant substances, the orange extract has the advantages of high dye uptake, high color fastness and the like, the kelp extract has the advantages of good water solubility, high dye uptake and the like, and the plant dye has the advantages of environmental friendliness, antibiosis, high dye uptake, high color fastness and the like by adopting the raw materials as the plant dye.
After weighing the raw materials of each component, adding the salt solution into the cylinder for three times, so that the vegetable dyes of each component are dissolved mutually, and after adding the soft curing agent, the vegetable dyes are favorable for dyeing the thermosensitive garment material.
The rare earth ions can be used as central ions to be complexed with the plant dye ions of the ligand, in addition, the complex also has the function similar to an electrolyte and has certain dyeing promotion property, and the rare earth-citric acid complex is selected as a mordant to be beneficial to improving the dye uptake of the plant dye.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are some embodiments of the present invention, but not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
A green harmless plant dye for thermosensitive clothing materials is prepared from the following components in percentage by weight: 10-20% of plant dye, 0.1-2% of rare earth-citric acid complex, 20-40% of organic solvent and the balance of water.
Wherein the vegetable dye comprises 5% of coffee extract, 5% of orange extract and 5% of kelp extract, and the balance is one or more of lignin, lutein, berberine, chlorophyll, indigo blue, alkannin, bamboo carbon black powder, and radix Rubiae extract.
The extraction method of the coffee residue extract comprises the following steps: weighing 100g of coffee grounds, soaking in distilled water for 1-2h to make the coffee grounds fully expand, then putting into 1000ml of 1.2g/L NaOH solution, heating to 75-80 ℃, preserving heat for 60-80min to make the coffee extract fully dissolve out, standing, cooling, filtering to obtain filtrate, namely the coffee extract, and storing for later use.
The extraction method of the orange extract comprises the following steps: weighing 100g of dried orange peel, crushing and sieving by a 40-50 mesh sieve, adding 1000ml of petroleum ether-ethanol mixed reagent with the mass ratio of 1.5:1, carrying out microwave treatment for 15-20min under the microwave condition that the power is 350W and the stirring speed is 350-400r/min, then standing for 1-1.5h under the temperature condition of 55-60 ℃, and finally carrying out suction filtration by a vacuum pump to obtain the orange extract, and storing for later use.
The extraction method of the kelp extract comprises the following steps: weighing 100g of kelp cleaned by cold water, soaking in 45 ℃ warm water for 30-40min, taking out, cutting into small pieces of 1cm multiplied by 1cm, drying until the weight is reduced to 1/10-1/9 of the original weight, crushing, sieving with a 40-50 mesh sieve, adding into 900ml of distilled water, rapidly heating to boil, keeping for 45-50min, extracting the filtrate, extracting the filter residue again, repeating for 3 times, and combining the three filtrates to obtain the kelp extract, and storing for later use.
A method for dyeing a green harmless plant dye for a thermosensitive garment material comprises the following steps:
(1) weighing the raw materials of the components according to the proportion, adding the raw materials into a cylinder, adding 3000ml of 60 ℃ warm water of 2000-;
wherein the stirring speed of the three-time salt adding solution is 350-400 r/min;
(2) heating the solution obtained in the step (1) to 75 ℃ at the temperature of 1 ℃/min, preserving heat for 20-30min, adjusting the pH to 4-5, adding 10-15g/l of a softening and solidifying agent, uniformly stirring, preserving heat for 20-30min, and then dyeing the thermosensitive clothing material by adopting a direct dyeing method, wherein the bath water ratio is controlled to be 1: and 40, dyeing for 100min to finish the dyeing work of the thermosensitive clothing material.
Example 1:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
table 1 proportioning of raw material components in example 1
Example 2:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
table 2 proportioning of each raw material components in example 2
| Components | Weight/% of |
| Coffee grounds extract | 2.5 |
| Orange extract | 2.5 |
| Laminaria japonica extract | 2.5 |
| Xanthophyll | 2.5 |
| Rare earth-citric acid complex | 0.1 |
| 95% ethanol | 20 |
| Water (W) | 69.9 |
Example 3:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
table 3 proportioning of raw material components in example 3
Example 4:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
table 4 proportioning of raw material components in example 4
| Components | Weight/% of |
| Coffee grounds extract | 2.5 |
| Orange extract | 2.5 |
| Laminaria japonica extract | 2.5 |
| Chlorophyll | 2.5 |
| Rare earth-citric acid complex | 0.1 |
| 95% ethanol | 20 |
| Water (W) | 69.9 |
Example 5:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
TABLE 5 compounding ratio of raw material components in example 5
| Components | Weight/% of |
| Coffee grounds extract | 2.5 |
| Orange extract | 2.5 |
| Laminaria japonica extract | 2.5 |
| Indigo blue | 2.5 |
| Rare earth-citric acid complex | 0.1 |
| 95% ethanol | 20 |
| Water (W) | 69.9 |
Example 6:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
table 6 compounding ratio of each raw material component in example 6
| Components | Weight/% of |
| Coffee grounds extract | 2.5 |
| Orange extract | 2.5 |
| Laminaria japonica extract | 2.5 |
| Lithospermum pigment | 2.5 |
| Rare earth-citric acid complex | 0.1 |
| 95% ethanol | 20 |
| Water (W) | 69.9 |
Example 7:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
table 7 compounding ratio of each raw material component in example 7
| Components | Weight/% of |
| Coffee grounds extract | 2.5 |
| Orange extract | 2.5 |
| Laminaria japonica extract | 2.5 |
| Bamboo carbon black powder | 2.5 |
| Rare earth-citric acid complex | 0.1 |
| 95% ethanol | 20 |
| Water (W) | 69.9 |
Example 8:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
table 8 compounding ratio of each raw material component in example 8
| Components | Weight/% of |
| Coffee grounds extract | 2.5 |
| Orange extract | 2.5 |
| Laminaria japonica extract | 2.5 |
| Rubia cordifolia extract | 2.5 |
| Rare earth-citric acid complex | 0.1 |
| 95% ethanol | 20 |
| Water (W) | 69.9 |
Example 9:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
TABLE 9 compounding ratio of raw material components in example 9
| Components | Weight/% of |
| Coffee grounds extract | 5 |
| Orange extract | 5 |
| Laminaria japonica extract | 5 |
| Rubia cordifolia extract | 5 |
| Rare earth-citric acid complex | 2 |
| 95% ethanol | 40 |
| Water (W) | 38 |
Example 10:
a green harmless plant dye for thermosensitive clothing materials comprises the following raw material components in percentage by weight:
TABLE 10 compounding ratio of each raw material component in example 10
Comparative example 1:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: no coffee grounds extract was added.
Comparative example 2:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: orange extract was not added.
Comparative example 3:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: no kelp extract was added.
Comparative example 4:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: other kinds of mordants are used instead of rare earth-citric acid complexes, such as alum.
Comparative example 5:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: in the extraction method of the orange extract, the mass ratio of the petroleum ether to the ethanol is 0.5: 1.
Comparative example 6:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: in the extraction method of the orange extract, the mass ratio of the petroleum ether to the ethanol is 1: 1.
Comparative example 7:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: in the extraction method of the orange extract, the mass ratio of the petroleum ether to the ethanol is 2: 1.
Comparative example 8:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: in the extraction method of the orange extract, the mass ratio of the petroleum ether to the ethanol is 2.5: 1.
Comparative example 9:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: in the extraction method of the orange extract, the mass ratio of the petroleum ether to the ethanol is 1.5: 1.5.
Comparative example 10:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: in the extraction method of the orange extract, the mass ratio of the petroleum ether to the ethanol is 1.5:2.
Comparative example 11:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: in the extraction method of the orange extract, the mass ratio of the petroleum ether to the ethanol is 1.5: 2.5.
Comparative example 12:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: in the extraction method of the orange extract, the mass ratio of the petroleum ether to the ethanol is 1:2.
Comparative example 13:
a green harmless plant dye for a thermosensitive garment material, which is different from that of example 10 only in that: in the extraction method of the orange extract, the mass ratio of the petroleum ether to the ethanol is 1: 2.5.
The vegetable dyes obtained in the above examples 1 to 10 and comparative examples 1 to 13 were subjected to a performance test to determine the overall performance of the vegetable dyes, and the results are shown in Table 11.
TABLE 11 Performance parameters of the vegetable dyes obtained in examples 1 to 10 and comparative examples 1 to 13
As can be seen from Table 11:
the comparative examples 1, 2 and 3, in which no coffee grounds extract, orange extract or kelp extract is added, all reduce the color fastness to washing, the color fastness to dry rubbing and the staphylococcus aureus bacteriostasis rate of the vegetable dye, so that both the color fastness and the antibacterial performance of the vegetable dye are reduced.
The replacement of rare earth-citric acid complex with other mordant types, such as alum, in comparative example 4, resulted in a decrease in the color fastness to washing, dry crocking and Staphylococcus aureus inhibition of the vegetable dye.
Compared with the example 10, the comparative examples 5 to 13 show that the orange peel is extracted by the petroleum ether-ethanol mixed reagent with the mass ratio of the petroleum ether to the ethanol of 1.5:1, so that the orange extract is fully dissolved, and the antibacterial performance of the vegetable dye is obviously improved.
In conclusion, the coffee grounds extract contains more antibacterial and antioxidant substances, the orange extract has the advantages of high dye uptake, high color fastness and the like, the kelp extract has the advantages of good water solubility, high dye uptake and the like, and the plant dye has the advantages of environmental friendliness, antibiosis, high dye uptake, high color fastness and the like by adopting the raw materials as the plant dye.
The above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (10)
1. A green harmless plant dye for thermosensitive clothing materials is characterized by being prepared from the following components in percentage by weight: 10-20% of plant dye, 0.1-2% of mordant, 20-40% of organic solvent and the balance of water.
2. The green harmless plant dye for heat-sensitive clothing material according to claim 1, wherein the plant dye is one or more of red lignin, lutein, berberine, chlorophyll, indigo, alkannin, bamboo carbon black powder, coffee grounds extract, orange extract, madder extract and kelp extract.
3. The green harmless plant dye for heat-sensitive clothing material as claimed in claim 2, wherein said plant dye comprises 5% coffee grounds extract, 5% orange extract and 5% kelp extract, and the balance is one or more of lignin, lutein, berberine, chlorophyll, indigo, alkannin, bamboo carbon black powder, and radix rubiae extract.
4. The green harmless plant dye for the thermosensitive clothing material according to claim 3, characterized in that the extraction method of the coffee grounds extract is: weighing 100g of coffee grounds, soaking in distilled water for 1-2h to make the coffee grounds fully expand, then putting into 1000ml of 1.2g/L NaOH solution, heating to 75-80 ℃, preserving heat for 60-80min to make the coffee extract fully dissolve out, standing, cooling, filtering to obtain filtrate, namely the coffee extract, and storing for later use.
5. The green harmless plant dye for thermosensitive garment materials according to claim 3, wherein the orange extract is extracted by a method comprising: weighing 100g of dried orange peel, crushing, sieving by a 40-50 mesh sieve, adding 1000ml of petroleum ether-ethanol mixed reagent, carrying out microwave treatment for 15-20min under the microwave condition that the power is 350W and the stirring speed is 350-400r/min, standing for 1-1.5h under the temperature condition of 55-60 ℃, and finally carrying out suction filtration by a vacuum pump to obtain the orange extract for storage and standby.
6. The green harmless plant dye for the thermosensitive clothing material according to claim 5, wherein the mass ratio of the petroleum ether to the ethanol in the petroleum ether-ethanol mixed reagent is 1.5:1.
7. The green harmless plant dye for thermosensitive clothing materials according to claim 3, characterized in that the extraction method of the kelp extract is: weighing 100g of kelp cleaned by cold water, soaking in 45 ℃ warm water for 30-40min, taking out, cutting into small pieces of 1cm multiplied by 1cm, drying until the weight is reduced to 1/10-1/9 of the original weight, crushing, sieving with a 40-50 mesh sieve, adding into 900ml of distilled water, rapidly heating to boil, keeping for 45-50min, extracting the filtrate, extracting the filter residue again, repeating for 3 times, and combining the three filtrates to obtain the kelp extract, and storing for later use.
8. A dyeing method of green harmless plant dye for heat-sensitive clothing material according to any one of claims 1 to 7, characterized in that the dyeing method comprises the following steps:
(1) weighing the raw materials of the components according to the proportion, adding the raw materials into a cylinder, adding 3000ml of 60 ℃ warm water of 2000-;
(2) heating the solution obtained in the step (1) to 75 ℃ at the temperature of 1 ℃/min, preserving heat for 20-30min, adjusting the pH to 4-5, adding 10-15g/l of a softening and solidifying agent, uniformly stirring, preserving heat for 20-30min, and then dyeing the thermosensitive clothing material by adopting a direct dyeing method, wherein the bath water ratio is controlled to be 1: and 40, dyeing for 100min to finish the dyeing work of the thermosensitive clothing material.
9. The method for dyeing temperature-sensitive clothing materials with green and harmless plant dyes as claimed in claim 8, wherein the stirring speed of the three salt solutions in the step (1) is 350-400 r/min.
10. The dyeing method of green harmless plant dye for thermosensitive clothing material according to claim 8, characterized in that the mordant is rare earth-citric acid complex.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110691439.3A CN113388263A (en) | 2021-06-22 | 2021-06-22 | Green harmless plant dye for thermosensitive clothing material and dyeing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110691439.3A CN113388263A (en) | 2021-06-22 | 2021-06-22 | Green harmless plant dye for thermosensitive clothing material and dyeing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113388263A true CN113388263A (en) | 2021-09-14 |
Family
ID=77623374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110691439.3A Pending CN113388263A (en) | 2021-06-22 | 2021-06-22 | Green harmless plant dye for thermosensitive clothing material and dyeing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113388263A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102321983A (en) * | 2011-08-10 | 2012-01-18 | 无锡市联盛印染有限公司 | Silk dyeing and finishing method using shikonin derivatives |
| CN103741505A (en) * | 2013-12-20 | 2014-04-23 | 大连创达技术交易市场有限公司 | Silk dyeing process adopting gardenia yellow vegetable dye |
| CN106634027A (en) * | 2016-11-15 | 2017-05-10 | 姚佑灿 | Dye for embroidery threads |
| CN108912729A (en) * | 2018-07-04 | 2018-11-30 | 武汉纺织大学 | The natural dye and colouring method for extracting the method for natural dye from madder and being prepared by this method |
| CN108978264A (en) * | 2018-08-10 | 2018-12-11 | 三亚新动力文化传播有限公司 | A kind of vegetation dye formula and its colouring method |
| KR102245292B1 (en) * | 2019-11-06 | 2021-04-26 | 재단법인경북테크노파크 | Method of producing a natural dye ink for digital textile priting using the coffee sludge |
-
2021
- 2021-06-22 CN CN202110691439.3A patent/CN113388263A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102321983A (en) * | 2011-08-10 | 2012-01-18 | 无锡市联盛印染有限公司 | Silk dyeing and finishing method using shikonin derivatives |
| CN103741505A (en) * | 2013-12-20 | 2014-04-23 | 大连创达技术交易市场有限公司 | Silk dyeing process adopting gardenia yellow vegetable dye |
| CN106634027A (en) * | 2016-11-15 | 2017-05-10 | 姚佑灿 | Dye for embroidery threads |
| CN108912729A (en) * | 2018-07-04 | 2018-11-30 | 武汉纺织大学 | The natural dye and colouring method for extracting the method for natural dye from madder and being prepared by this method |
| CN108978264A (en) * | 2018-08-10 | 2018-12-11 | 三亚新动力文化传播有限公司 | A kind of vegetation dye formula and its colouring method |
| KR102245292B1 (en) * | 2019-11-06 | 2021-04-26 | 재단법인경북테크노파크 | Method of producing a natural dye ink for digital textile priting using the coffee sludge |
Non-Patent Citations (3)
| Title |
|---|
| 万骏等: ""天然染料的应用现状及研究进展"", 《纺织导报》 * |
| 吴赞敏主编: "《纺织品清洁染整加工技术》", 31 December 2007, 中国纺织出版社 * |
| 胡树凯主编: "《食品微生物学第2版》", 31 December 2016, 北京交通大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106087475B (en) | A kind of technique for using some vegetable colours contaminate on colorant match | |
| CN103554974A (en) | Formula for preparing coffee-colored wheat straw dye and production method of coffee-colored wheat straw dye | |
| Hamdy et al. | Various natural dyes from different sources | |
| CN105348851A (en) | Preparation of anthocyanin dye and application of anthocyanin dye in cellulosic fiber fabric dyeing | |
| CN104059382A (en) | Natural textile dye and preparation method thereof | |
| WO2022105916A1 (en) | Use of neem bark pigment in preparation for multifunctional wool fabric | |
| CN110393686A (en) | A kind of preparation method and application of bush tealeaves compound botanical hair dye | |
| CN113388263A (en) | Green harmless plant dye for thermosensitive clothing material and dyeing method thereof | |
| CN110669353B (en) | Extraction method of dark red dye in coconut shell | |
| US6749647B2 (en) | Fiber dyeing method and dyed fiber products | |
| CN111647284A (en) | Grass dye and dyeing process thereof | |
| CN111155337A (en) | Green dyeing-assisted buddleja officinalis cloth dyeing method | |
| CN105713418A (en) | Natural mango dye based on mango yellow pigment and preparation method of natural mango dye | |
| CN102604422A (en) | Preparation method of purslane natural dye and application of the purslane natural dye | |
| CN105200814A (en) | Preparation method of lonicera edulis dyeing cloth with high color fastness | |
| CN102535189B (en) | Method for dyeing metachrome silk fabric by using parslane herb dye liquor | |
| KR100918726B1 (en) | Manufacturing method of natural dye using canphor tree and dyeing method | |
| CN108086017B (en) | Method for dyeing acrylic fabric by barberry plant dye | |
| CN112962330A (en) | Plant coloring agent and preparation method thereof | |
| CN106498766A (en) | Antibacterial type cotton fabric special bio dyestuff | |
| CN113355927A (en) | Environment-friendly plant dye for blended material and dyeing process thereof | |
| CN108589277A (en) | A kind of production technology of twill | |
| JP2003129389A (en) | Method for dyeing textile fiber and the resultant dyed textile fiber | |
| CN105332292B (en) | Cotton fabric dyeing process method with aromatic health function | |
| JPH0413611A (en) | Natural hair dyeing agent and production thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210914 |