CN106498766A - Antibacterial type cotton fabric special bio dyestuff - Google Patents

Antibacterial type cotton fabric special bio dyestuff Download PDF

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Publication number
CN106498766A
CN106498766A CN201610874433.9A CN201610874433A CN106498766A CN 106498766 A CN106498766 A CN 106498766A CN 201610874433 A CN201610874433 A CN 201610874433A CN 106498766 A CN106498766 A CN 106498766A
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Prior art keywords
earthworm
dyestuff
hours
cotton fabric
special bio
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CN201610874433.9A
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徐飞艳
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B61/00Dyes of natural origin prepared from natural sources, e.g. vegetable sources
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A kind of antibacterial type cotton fabric special bio dyestuff, it is characterised in that be made up of the composition of following percentage by weight:Earthworm extract 0.5 3%, Honegsukle flower P.E 0.2 1%, Tea Polyphenols 0.1 1%, sodium isoascorbate 0.5 2%, salt 0.2 0.5%, PAMA 0.1 1%, vitamin C 0.1 0.5%, balance of solvent.The present invention is applied to the dyeing of cotton fiber, it is also possible to for other plant fiber, and dyed fabric has good washing fastness and fastness to rubbing, and bright in colour, and there is good antibiotic property also, and bacteriostasis rate is more than 90%.The dyestuff extraction process is simple, ecological, environmental protective, and it is convenient to prepare, and is a kind of biological dye of function admirable, has a good application prospect.

Description

Antibacterial type cotton fabric special bio dyestuff
Technical field
The present invention relates to printing technology field, and in particular to a kind of antibacterial type cotton fabric special bio dyestuff.
Background technology
Under the influence of global environmental protection tide, natural plants dyeing returns to the visual field of people again.Natural dye There is ecological balance feature:Natural in color bright-coloured, safe, nontoxic and have certain nutritive value and medicine healthy sofa effect, Used as bio-renewables, production process is environmentally friendly, three wastes process problem, so causing again dyestuff circle to pay close attention to.
At present India, some dyestuff companies of the country such as Italian and German are all in Development and Production natural plant dye, but There is outstanding problem in the acquisition of vegetable colour, as in dye yielding herb, pigment content is less, it is desirable to obtain enough dyestuffs, just must Must pluck in large quantities and cut down plant, cause the destruction to ecological environment, run counter to using vegetable colour so as to reaching environmental protection Original intention.In addition, some subject matters that natural plant dyestuff is there is also in textile dyeing:1. poor repeatability is dyeed.Conventional The natural dye overwhelming majority be vegetable colour, even same plant, as the place of production is different, weather conditions are different and collection Time difference can all affect the composition and color and luster of pigment, cause production to be difficult to standardize a large amount of productions, and this inevitably results in dye The dyeing poor repeatability of material.Although the tone of contaminated fiber can be regulated and controled by using different mordants, the weight of dyeing Existing property is still very poor.2. the stability of natural dye is poor.Natural dye is affected greatly, easily by environmental condition (pH value, illumination, temperature) Decompose or oxidation decoloration, cause coloured light unstable.3. poor color fastness.Lack corresponding high color fastness ecological dyeing technology.Due to Natural dye chromophoric group inherent instability, causes natural dye washable and fastness to light is poor, although contaminating in natural dye In color, dyefastness can be improved using mordant dyeing and some post processings, traditional mordant contains mostly heavy metal ion, wherein permitted It is put into the list disabled by ecological textile more.
Content of the invention
The technical problem to be solved is to provide that a kind of Color is good, the stable antibacterial type cotton of end product quality Fabric special bio dyestuff.
The technical problem to be solved employs the following technical solutions to realize:
A kind of antibacterial type cotton fabric special bio dyestuff, is made up of the composition of following percentage by weight:Earthworm is extracted Liquid 0.5-3%, Honegsukle flower P.E 0.2-1%, Tea Polyphenols 0.1-1%, sodium isoascorbate 0.5-2%, salt 0.2- 0.5%th, PAMA 0.1-1%, vitamin C 0.1-0.5%, balance of solvent;
The solvent is ethanol, deionized water, methyl alcohol, one or more the mixture in acetone.
The preparation method of the earthworm extract is as follows:
(1) freezing earthworm is put into temperature for 6-8 DEG C, humidity is preservation in the fresh-keeping warehouse of 78-82% 4 hours, Ran Houqu Go out, be placed in vacuum and low temperature cold wind drier, dry to earthworm moisture in 48-54% under 40-45 DEG C of environment, taking-up is treated With;
Using cold wind low temperature drying, earthworm epidermis will not be made to produce oxidation, reduced the volatilization of active ingredient, protected to greatest extent Stay the active material in earthworm body;
(2) by cold air drying after earthworm crushed, cross 60~80 mesh medicines sieve, obtain moisten earthworm powder, by earthworm powder Sending in microwave processing equipment, microwave treatment being spaced under microwave frequency 2450MHz, power 500W, interval time is 5 minutes, Microwave treatment 10 minutes, is carried out continuously 3-4 time every time;Active ingredient in earthworm body is activated by microwave treatment, using composition Rapid extraction;
(3) earthworm powder is added in pure water after the microwave treatment, and is heated to 45 DEG C, continuously stirs 50-80 minutes, and Maintain the temperature at 45~60 DEG C to extract 2~4 hours, obtain extract;
The addition of wherein pure water is 1.5-5 times of earthworm slurry weight, earthworm slurry is diluted, by steam Bactericidal action is played in heating;
(4) it is 5.5 extract to be adjusted pH value, sends into grinder, and continuously grinding 2 hours takes out the earthworm after grinding and starches Material, sends into and boils material pot, is heated to 80 DEG C and turns off steam, adds, and is boiling boiling 2-5 in material pot After minute, recirculated cooling water is opened, cooled down to boiling material pot;
(5) when boiling the feed temperature in material pot and being cooled to 60 DEG C~65 DEG C, material is taken out, multiplex true using circulating water type Empty pump carries out vacuum filtration, obtains the feed liquid after suction filtration, feed liquid is bottled, using steam high-voltage sterilizing, then by sterilizing after bottle Cooling workshop is pushed, 2-4 hours drop to 20 DEG C in aseptic interior;
(6) metering packing warehouse-in.
The preparation method of above-mentioned biological dye is:Ball mill grinding is put into after said components are mixed, and about 4 hours, is tested Filter whether residual grains or caking, qualified after.
Contain lumbricin, vitamin and trace element in earthworm extract of the present invention, with obvious antioxidation activity, with Tea Polyphenols, Honegsukle flower P.E are used cooperatively, and with having, antibacterium, anti-malarial, antimycotic, disease-resistant former animal etc. are biological to live Property;The Multifunction ecofriendly dyes of antibacterial with health role, expelling parasite are developed, this ecofriendly dyes are successfully applied to Natural fiber or the dyeing of synthetic fibers, effect is significant.
Biological dye of the present invention is applied to the dyeing of the strings such as cotton fiber, and it is as follows which dyes citing technique:
Cotton fiber:Dye dosage be 3% (o.w.f), bath raio 1:30, dyeing temperature is 95 DEG C, and pH value is 4.0~5.0, dye Color 20min, then plus acetic acid continuation dye 20min.
Bamboo fibre:Dye dosage be 1% (o.w.f), bath raio 1:30, dyeing temperature is 85 DEG C, and pH value is 4.0~6.0, dye The color time is 45min.
The invention has the beneficial effects as follows:The present invention is applied to the dyeing of cotton fiber, it is also possible to for other plant fiber, dye Yarn dyed fabric has good washing fastness and fastness to rubbing, and bright in colour, and also there is good antibiotic property, bacteriostasis rate to exist More than 90%.The dyestuff extraction process is simple, ecological, environmental protective, and it is convenient to prepare, and is a kind of biological dye of function admirable, with good Good application prospect.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of antibacterial type cotton fabric special bio dyestuff, is made up of the composition of following percentage by weight:Earthworm is extracted Liquid 0.5%, Honegsukle flower P.E 0.2%, Tea Polyphenols 0.1%, sodium isoascorbate 0.5%, salt 0.2%, anion poly- third Acrylamide 0.1%, vitamin C 0.1%, balance of ethanol.
The preparation method of the earthworm extract is as follows:
(1) freezing earthworm is put into temperature for 6-8 DEG C, humidity is preservation in the fresh-keeping warehouse of 78-82% 4 hours, Ran Houqu Go out, be placed in vacuum and low temperature cold wind drier, dry to earthworm moisture in 48-54% under 40-45 DEG C of environment, taking-up is treated With;
Using cold wind low temperature drying, earthworm epidermis will not be made to produce oxidation, reduced the volatilization of active ingredient, protected to greatest extent Stay the active material in earthworm body;
(2) by cold air drying after earthworm crushed, cross 60~80 mesh medicines sieve, obtain moisten earthworm powder, by earthworm powder Sending in microwave processing equipment, microwave treatment being spaced under microwave frequency 2450MHz, power 500W, interval time is 5 minutes, Microwave treatment 10 minutes, is carried out continuously 3-4 time every time;Active ingredient in earthworm body is activated by microwave treatment, using composition Rapid extraction;
(3) earthworm powder is added in pure water after the microwave treatment, and is heated to 45 DEG C, continuously stirs 50-80 minutes, and Maintain the temperature at 45~60 DEG C to extract 2~4 hours, obtain extract;
The addition of wherein pure water is 1.5-5 times of earthworm slurry weight, earthworm slurry is diluted, by steam Bactericidal action is played in heating;
(4) it is 5.5 extract to be adjusted pH value, sends into grinder, and continuously grinding 2 hours takes out the earthworm after grinding and starches Material, sends into and boils material pot, is heated to 80 DEG C and turns off steam, adds, and is boiling boiling 2-5 in material pot After minute, recirculated cooling water is opened, cooled down to boiling material pot;
(5) when boiling the feed temperature in material pot and being cooled to 60 DEG C~65 DEG C, material is taken out, multiplex true using circulating water type Empty pump carries out vacuum filtration, obtains the feed liquid after suction filtration, feed liquid is bottled, using steam high-voltage sterilizing, then by sterilizing after bottle Cooling workshop is pushed, 2-4 hours drop to 20 DEG C in aseptic interior;
(6) metering packing warehouse-in.
The preparation method of above-mentioned biological dye is:Ball mill grinding is put into after said components are mixed, and about 4 hours, is tested Filter whether residual grains or caking, qualified after.
Embodiment 2
A kind of antibacterial type cotton fabric special bio dyestuff, is made up of the composition of following percentage by weight:Earthworm is extracted Liquid 3%, Honegsukle flower P.E 1%, Tea Polyphenols 1%, sodium isoascorbate 2%, salt 0.5%, PAMA 1%th, vitamin C 0.5%, balance of deionized water.
The preparation method of the earthworm extract is as follows:
(1) freezing earthworm is put into temperature for 6-8 DEG C, humidity is preservation in the fresh-keeping warehouse of 78-82% 4 hours, Ran Houqu Go out, be placed in vacuum and low temperature cold wind drier, dry to earthworm moisture in 48-54% under 40-45 DEG C of environment, taking-up is treated With;
Using cold wind low temperature drying, earthworm epidermis will not be made to produce oxidation, reduced the volatilization of active ingredient, protected to greatest extent Stay the active material in earthworm body;
(2) by cold air drying after earthworm crushed, cross 60~80 mesh medicines sieve, obtain moisten earthworm powder, by earthworm powder Sending in microwave processing equipment, microwave treatment being spaced under microwave frequency 2450MHz, power 500W, interval time is 5 minutes, Microwave treatment 10 minutes, is carried out continuously 3-4 time every time;Active ingredient in earthworm body is activated by microwave treatment, using composition Rapid extraction;
(3) earthworm powder is added in pure water after the microwave treatment, and is heated to 45 DEG C, continuously stirs 50-80 minutes, and Maintain the temperature at 45~60 DEG C to extract 2~4 hours, obtain extract;
The addition of wherein pure water is 1.5-5 times of earthworm slurry weight, earthworm slurry is diluted, by steam Bactericidal action is played in heating;
(4) it is 5.5 extract to be adjusted pH value, sends into grinder, and continuously grinding 2 hours takes out the earthworm after grinding and starches Material, sends into and boils material pot, is heated to 80 DEG C and turns off steam, adds, and is boiling boiling 2-5 in material pot After minute, recirculated cooling water is opened, cooled down to boiling material pot;
(5) when boiling the feed temperature in material pot and being cooled to 60 DEG C~65 DEG C, material is taken out, multiplex true using circulating water type Empty pump carries out vacuum filtration, obtains the feed liquid after suction filtration, feed liquid is bottled, using steam high-voltage sterilizing, then by sterilizing after bottle Cooling workshop is pushed, 2-4 hours drop to 20 DEG C in aseptic interior;
(6) metering packing warehouse-in.
The preparation method of above-mentioned biological dye is:Ball mill grinding is put into after said components are mixed, and about 4 hours, is tested Filter whether residual grains or caking, qualified after.
Embodiment 3
A kind of antibacterial type cotton fabric special bio dyestuff, is made up of the composition of following percentage by weight:Earthworm is extracted Liquid 1.5%, Honegsukle flower P.E 0.6%, Tea Polyphenols 0.6%, sodium isoascorbate 1%, salt 0.3%, anion pp In acid amides 0.6%, vitamin C 0.35%, balance of acetone.
The preparation method of the earthworm extract is as follows:
(1) freezing earthworm is put into temperature for 6-8 DEG C, humidity is preservation in the fresh-keeping warehouse of 78-82% 4 hours, Ran Houqu Go out, be placed in vacuum and low temperature cold wind drier, dry to earthworm moisture in 48-54% under 40-45 DEG C of environment, taking-up is treated With;
Using cold wind low temperature drying, earthworm epidermis will not be made to produce oxidation, reduced the volatilization of active ingredient, protected to greatest extent Stay the active material in earthworm body;
(2) by cold air drying after earthworm crushed, cross 60~80 mesh medicines sieve, obtain moisten earthworm powder, by earthworm powder Sending in microwave processing equipment, microwave treatment being spaced under microwave frequency 2450MHz, power 500W, interval time is 5 minutes, Microwave treatment 10 minutes, is carried out continuously 3-4 time every time;Active ingredient in earthworm body is activated by microwave treatment, using composition Rapid extraction;
(3) earthworm powder is added in pure water after the microwave treatment, and is heated to 45 DEG C, continuously stirs 50-80 minutes, and Maintain the temperature at 45~60 DEG C to extract 2~4 hours, obtain extract;
The addition of wherein pure water is 1.5-5 times of earthworm slurry weight, earthworm slurry is diluted, by steam Bactericidal action is played in heating;
(4) it is 5.5 extract to be adjusted pH value, sends into grinder, and continuously grinding 2 hours takes out the earthworm after grinding and starches Material, sends into and boils material pot, is heated to 80 DEG C and turns off steam, adds, and is boiling boiling 2-5 in material pot After minute, recirculated cooling water is opened, cooled down to boiling material pot;
(5) when boiling the feed temperature in material pot and being cooled to 60 DEG C~65 DEG C, material is taken out, multiplex true using circulating water type Empty pump carries out vacuum filtration, obtains the feed liquid after suction filtration, feed liquid is bottled, using steam high-voltage sterilizing, then by sterilizing after bottle Cooling workshop is pushed, 2-4 hours drop to 20 DEG C in aseptic interior;
(6) metering packing warehouse-in.
The preparation method of above-mentioned biological dye is:Ball mill grinding is put into after said components are mixed, and about 4 hours, is tested Filter whether residual grains or caking, qualified after.
Contain lumbricin, vitamin and trace element in earthworm extract of the present invention, with obvious antioxidation activity, with Tea Polyphenols, Honegsukle flower P.E are used cooperatively, and with having, antibacterium, anti-malarial, antimycotic, disease-resistant former animal etc. are biological to live Property;The Multifunction ecofriendly dyes of antibacterial with health role, expelling parasite are developed, this ecofriendly dyes are successfully applied to Natural fiber or the dyeing of synthetic fibers, effect is significant.
Biological dye of the present invention is applied to the dyeing of the strings such as cotton fiber, and it is as follows which dyes citing technique:
Cotton fiber:Dye dosage be 3% (o.w.f), bath raio 1:30, dyeing temperature is 95 DEG C, and pH value is 4.0~5.0, dye Color 20min, then plus acetic acid continuation dye 20min.
Bamboo fibre:Dye dosage be 1% (o.w.f), bath raio 1:30, dyeing temperature is 85 DEG C, and pH value is 4.0~6.0, dye The color time is 45min.
1 two kinds of strings of table dye color fastness
Table 1
Bacteriostasis rate of the 2 embodiment 1-3 dyestuff of table for string
Table 2
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel it should be appreciated that the present invention is not restricted to the described embodiments, simply explanation described in above-described embodiment and specification this The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes Change and improvement is both fallen within scope of the claimed invention.The claimed scope of the invention by appending claims and its Equivalent thereof.

Claims (5)

1. a kind of antibacterial type cotton fabric special bio dyestuff, it is characterised in that be made up of the composition of following percentage by weight: Earthworm extract 0.5-3%, Honegsukle flower P.E 0.2-1%, Tea Polyphenols 0.1-1%, sodium isoascorbate 0.5-2%, salt 0.2-0.5%, PAMA 0.1-1%, vitamin C 0.1-0.5%, balance of solvent.
2. antibacterial type cotton fabric special bio dyestuff according to claim 1, it is characterised in that the solvent is second One or more mixture in alcohol, deionized water, methyl alcohol, acetone.
3. antibacterial type cotton fabric special bio dyestuff according to claim 1, it is characterised in that the earthworm is extracted The preparation method of liquid is as follows:
(1) freezing earthworm is put into temperature for 6-8 DEG C, humidity is then taken out, put for preserving 4 hours in the fresh-keeping warehouse of 78-82% In vacuum and low temperature cold wind drier, dry under 40-45 DEG C of environment to earthworm moisture in 48-54%, take out stand-by;
(2) by cold air drying after earthworm crushed, cross 60~80 mesh medicines sieve, obtain moisten earthworm powder, earthworm powder is sent into In microwave processing equipment, microwave treatment is spaced under microwave frequency 2450MHz, power 500W, interval time is 5 minutes, every time Microwave treatment 10 minutes, is carried out continuously 3-4 time;
(3) earthworm powder is added in pure water after the microwave treatment, and is heated to 45 DEG C, is continuously stirred 50-80 minutes, and is kept Temperature is extracted 2~4 hours at 45~60 DEG C, obtains extract;
(4) it is 5.5 extract to be adjusted pH value, sends into grinder, and continuously grinding 2 hours takes out the earthworm slurry after grinding, send Enter to boil material pot, be heated to 80 DEG C and turn off steam, add, boil boiling 2-5 minutes in material pot Afterwards, recirculated cooling water is opened, is cooled down to boiling material pot;
(5) wait boil material pot in feed temperature be cooled to 60 DEG C~65 DEG C when, take out material, using multiplex vavuum pump of circulating water type Carry out vacuum filtration, obtain the feed liquid after suction filtration, feed liquid is bottled, using steam high-voltage sterilizing, then by sterilizing after bottle push Cooling workshop, 2-4 hours drop to 20 DEG C in aseptic interior;
(6) metering packing warehouse-in.
4. antibacterial type cotton fabric special bio dyestuff according to claim 2, it is characterised in that above-mentioned steps (3) 1.5-5 times for earthworm slurry weight of the addition of middle pure water.
5. a kind of method for preparing biological dye described in any one of claim 1-4, it is characterised in that after said components are mixed Input ball mill grinding, about 4 hours, whether residual grains or caking were filtered in test, qualified after.
CN201610874433.9A 2016-09-30 2016-09-30 Antibacterial type cotton fabric special bio dyestuff Pending CN106498766A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108570255A (en) * 2018-05-10 2018-09-25 河南科技学院 A kind of biological environmental production pigment and preparation method thereof for artistic design
CN111621994A (en) * 2019-02-28 2020-09-04 杭州唯铂莱生物科技有限公司 Low-temperature energy-saving printing and dyeing process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102733202A (en) * 2011-04-15 2012-10-17 李凤子 Anti-atopic dermatitis textiles
CN103451963A (en) * 2013-08-09 2013-12-18 常州纺织服装职业技术学院 Method for dyeing cotton fabric with tea dye and finishing liquor used by method
CN104845406A (en) * 2014-02-17 2015-08-19 山东禾本堂生物科技有限公司 Plant dye with functions of health care and color fixation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102733202A (en) * 2011-04-15 2012-10-17 李凤子 Anti-atopic dermatitis textiles
CN103451963A (en) * 2013-08-09 2013-12-18 常州纺织服装职业技术学院 Method for dyeing cotton fabric with tea dye and finishing liquor used by method
CN104845406A (en) * 2014-02-17 2015-08-19 山东禾本堂生物科技有限公司 Plant dye with functions of health care and color fixation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108570255A (en) * 2018-05-10 2018-09-25 河南科技学院 A kind of biological environmental production pigment and preparation method thereof for artistic design
CN111621994A (en) * 2019-02-28 2020-09-04 杭州唯铂莱生物科技有限公司 Low-temperature energy-saving printing and dyeing process

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