CN113338074B

CN113338074B - Novel painting transparent oil rice paper and manufacturing method thereof

Info

Publication number: CN113338074B
Application number: CN202110036002.6A
Authority: CN
Inventors: 刘秀娟
Original assignee: Individual
Current assignee: Individual
Priority date: 2021-01-12
Filing date: 2021-01-12
Publication date: 2022-11-15
Anticipated expiration: 2041-01-12
Also published as: CN113338074A

Abstract

The invention provides a new painting transparent oil rice paper and a manufacturing method thereof, belonging to the technical field of rice paper, and the rice paper is prepared from the following raw materials in parts by weight: 100-200 parts of pteroceltis tatarinowii bark fiber, 50-80 parts of wormwood, 150-300 parts of plant fiber, 20-40 parts of mixed oil, 2-5 parts of plant essential oil, 3-7 parts of graphene oxide and 1-2 parts of surfactant. The novel painting transparent oil rice paper prepared by the invention is transparent and hard in paper quality; the novel painting transparent rice paper prepared by the invention has affinity absorption effect on various pigments, including ink, mineral pigments, acrylic pigments, traditional Chinese painting pigments, watercolor pigments and oil painting pigments, can be used for painting, the painting effect is transparent and vivid, and the rice paper has a feeling of being close to the Song dynasty and has very artistic appreciation. Therefore, the novel transparent Xuan paper has wide application prospect.

Description

Novel painting transparent oil rice paper and manufacturing method thereof

Technical Field

The invention relates to the technical field of rice paper, in particular to novel painting transparent oil rice paper and a manufacturing method thereof.

Background

The rice paper has the characteristics of toughness, smoothness, whiteness, density, pure texture, no damage by twisting and folding, strong ink-moistening property and the like, and has unique penetrating and lubricating properties. The writing and painting paper has both the bone spirit and the spirit of painting, and becomes the painting and painting paper which can reflect the Chinese artistic style most.

The making process of the rice paper is mainly divided into eighteen steps, and the traditional method comprises the steps of steaming branches of the pteroceltis tatarinowii tree, soaking, peeling, drying in the sun, adding lime and soda (or sodium bicarbonate), steaming again, removing impurities, washing, tearing into thin strips, airing in the places facing the sun, and whitening after sun and rain. Then pulping the slivers into glue: pulping the processed bark and forage respectively, adding vegetable gum (such as succus Averrhoae Carambolae), stirring, making into paper with bamboo curtain, brushing on kang, oven drying, cutting, and finishing into sheet.

CN108411703A discloses a moisture-proof rice paper material, which comprises the following components in parts by weight: 9-14 parts of pteroceltis tatarinowii bark fiber, 18-32 parts of corna straw fiber, 6-11 parts of antioxidant, 2-7 parts of compatilizer, 0.8-3.4 parts of flame retardant, 26-43 parts of alfalfa fiber, 22-35 parts of reed stem fiber, 14-29 parts of basalt fiber, 23-37 parts of soybean meal and 32-46 parts of glutinous rice pulp; the soluble solid content of the glutinous rice pulp is 42% -52%; the monofilament diameter of the basalt fiber is 0.35-0.65um, and the monofilament length of the basalt fiber is 3-9mm.

CN109112870A discloses a rice paper raw stock, which comprises the following components in percentage by mass: 70-75 parts of cornfield straw, 28-35 parts of pteroceltis tatarinowii bark, 1-1.5 parts of plant photo-oxidant, 1-1.5 parts of auxiliary agent and 8-10 parts of calcium active powder, wherein the auxiliary agent is a mixture of a paper flame retardant and carambola juice agilawood powder.

CN106958164A discloses a method for preparing collosol water by using plant glue instead of animal glue, so as to prepare rice paper processing paper, which comprises the following steps: the materials are mixed according to the following weight portions: rice paper straw pulp 180-190, sisal hemp 2-4, straw 3-5, viscose fiber 1-3, alkylphenol polyoxyethylene 0.3-0.5, copper sulfate 0.1-0.2, polymalic acid 0.01-0.02, coconut oil acid 0.1-0.3, betaine 0.1-0.2, polyvinyl alcohol 0.1-0.2 and oxidized starch 0.1-0.3; soaking sisal hemp and straw in deionized water for 10-12 hours, grinding, placing in a closed cylinder, introducing water vapor with the temperature of 110-300 ℃ and the pressure of 1.0-5.0 MPa, hydrolyzing, drying, and grinding to obtain modified fiber for later use; adding appropriate amount of water into polymalic acid, coconut oleic acid and betaine, stirring at 40-60 deg.C for 0.5-1h, adding modified fiber, oxidized starch and copper sulfate, stirring, filtering, washing the filter residue with distilled water until the filtrate is neutral, and drying at 50-70 deg.C to obtain fiber antibacterial powder; uniformly mixing the fiber antibacterial powder with the rest raw materials prepared in the step (1), and preparing the mixture into rice paper by a conventional process; spraying collodion alum solution on the rice paper, and then ironing to obtain the rice paper; the collosol alum solution is prepared from the following raw materials in parts by weight: 8-15 parts of vegetable gum, 3-5 parts of sodium alginate, 2-8 parts of alum and a proper amount of water.

At present, after the rice paper on the market is drawn, only one side can be seen, and the other side does not have ornamental property.

Disclosure of Invention

The invention aims to provide the new painting transparent oil rice paper and the manufacturing method thereof, the prepared new painting transparent oil rice paper is transparent and hard, ink, acrylic paint and watercolor can be colored and painted, and the painted picture has the age feeling close to the Song Dynasty, has artistic appreciation and has wide application prospect.

The technical scheme of the invention is realized as follows:

the invention provides a new painting transparent oil rice paper which is prepared from the following raw materials in parts by weight: 100-200 parts of pteroceltis tatarinowii bark fiber, 50-80 parts of wormwood, 150-300 parts of plant fiber, 20-40 parts of mixed oil, 3-7 parts of graphene oxide and 1-2 parts of surfactant.

As a further improvement of the invention, the health-care food is prepared from the following raw materials in parts by weight: 120-180 parts of pteroceltis tatarinowii bark fiber, 60-70 parts of wormwood, 170-220 parts of plant fiber, 25-35 parts of mixed oil, 4-6 parts of graphene oxide and 1.2-1.8 parts of surfactant.

As a further improvement of the invention, the health-care food is prepared from the following raw materials in parts by weight: 150 parts of pteroceltis tatarinowii bark fiber, 65 parts of wormwood, 200 parts of plant fiber, 30 parts of mixed oil, 5 parts of graphene oxide and 1.6 parts of surfactant.

As a further improvement of the invention, the plant fiber is selected from one or a combination of several of straw fiber, cotton fiber, kapok fiber, bamboo fiber, sisal fiber, abaca fiber, coconut fiber, flax fiber, jute fiber and castor fiber, and the surfactant is selected from one or a combination of several of calcium stearate, sodium stearate, potassium stearate, sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, potassium dodecyl benzene sulfonate, potassium dodecyl sulfonate and potassium dodecyl sulfate.

As a further improvement of the invention, the mixed oil is selected from one or a combination of more of castor oil, peanut oil, olive oil and aromatic plant essential oil.

As a further improvement of the invention, the mixed oil is castor oil and aromatic plant essential oil.

The invention further provides a preparation method of the new painting transparent oil rice paper, which comprises the following steps: preparing wingceltis bark fiber, wormwood, plant fiber and graphene oxide into raw rice paper pulp, and preparing the new painting transparent oil rice paper after sequentially carrying out paper fishing, plate squeezing, drying and pasting, oil coating and paper drying.

As a further improvement of the invention, before the oil coating step, the surfactant is prepared into a 5-10wt% aqueous solution, the aqueous solution is uniformly coated on the rice paper, and the rice paper is dried.

As a further improvement of the invention, the step of brushing glue and brushing alum is also included after the step of coating oil.

The invention has the following beneficial effects: at present, when the common rice paper is in contact with limbs for a long time, bacteria and sweat stains on hands can be brought to the rice paper, bacteria such as escherichia coli, staphylococcus aureus, mould and the like are easy to breed, and the service life of the rice paper is influenced; meanwhile, the Xuan paper is greatly influenced by the environmental humidity, and is easy to damp and mildew particularly in the rainy weather; the invention provides the novel painting transparent oil rice paper, which is characterized in that the rice paper is easy to be bitten by insects and is influenced by the propagation of ova of the insects in the storage process, so that the damage of paper and painting and calligraphy is caused, and the ornamental value and the economic value of the paper and painting and calligraphy are greatly influenced.

According to the novel transparent painting oil rice paper, graphene oxide is added into the raw stock to be uniformly distributed on the surface of the prepared rice paper, a surfactant solution is further coated before oil coating, a hydrophilic end of the surfactant is bonded with the graphene oxide on the rice paper, a lipophilic end of the other end of the surfactant is exposed, then mixed oil is coated, and the mixed oil can be well fixed on the rice paper under the adsorption of the lipophilic end of the surfactant, so that the transparent rice paper is obtained.

The novel painting transparent oil rice paper prepared by the invention is transparent and hard in paper quality; the novel transparent rice paper for painting has affinity absorption effect on various pigments, including ink, mineral pigments, acrylic pigments, traditional Chinese painting pigments, watercolor pigments and oil painting pigments, can be used for painting, and the painting effect is transparent and flexible, and has the age feeling close to the Song Dynasty and very artistic ornamental value. Therefore, the novel transparent Xuan paper has wide application prospect.

The invention can respectively prepare raw rice paper, cooked rice paper and semi-rice paper, respectively prepare the raw rice paper or the cooked rice paper by the steps of gluing and vitriol brushing or not, and control the amount of gluing and vitriol brushing to prepare the semi-rice paper, thereby preparing various optional rice papers with different performances to meet market demands.

Drawings

In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.

FIG. 1 is a positive effect of a plot made by the method of example 1 of the present invention;

FIG. 2 is a graph showing the reverse effect of the drawing obtained by the method of example 1 of the present invention.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.

Example 1

The raw materials comprise the following components in parts by weight: 100 parts of pteroceltis tatarinowii bark fiber, 50 parts of wormwood, 150 parts of bamboo fiber, 18 parts of olive oil, 2 parts of lemon essential oil, 3 parts of graphene oxide and 1 part of potassium dodecyl benzene sulfonate serving as a surfactant.

The preparation method comprises the following steps:

the method comprises the following steps: preparing wingceltis bark fiber, wormwood, bamboo fiber and graphene oxide into raw rice paper stock, fishing paper, squeezing, drying, pasting, oiling, drying the paper in the sun in sequence to obtain the new painting transparent rice paper, preparing a 5wt% aqueous solution of a surfactant, namely potassium dodecylbenzene sulfonate, before the oiling step, uniformly coating the aqueous solution on the rice paper, drying, wherein the oiling step is to uniformly mix lemon essential oil and olive oil, uniformly coat the mixture on the rice paper, and then drying the rice paper to obtain the transparent oily raw rice paper. After the rice paper prepared in this example is painted, referring to fig. 1 and 2, fig. 1 shows the positive effect of the drawing prepared by the method in example 1 of the present invention, and fig. 2 shows the negative effect of the drawing prepared by the method in example 1 of the present invention, and it can be seen that both sides of the paper have good ornamental value.

Example 2

The raw materials comprise the following components in parts by weight: 200 parts of pteroceltis tatarinowii bark fiber, 80 parts of wormwood, 300 parts of castor fiber, 35 parts of rapeseed oil, 5 parts of lavender essential oil, 7 parts of graphene oxide and 2 parts of potassium dodecyl benzene sulfonate serving as a surfactant.

The preparation method comprises the following steps:

the method comprises the following steps: preparing wingceltis skin fiber, wormwood, castor fiber and graphene oxide into raw rice paper stock, fishing paper, squeezing, baking, coating oil, brushing glue, brushing alum and drying the paper in the sun in sequence to obtain the new painting transparent rice paper, preparing a 10wt% aqueous solution of a surfactant, namely potassium dodecyl benzene sulfonate, before the oil coating step, uniformly coating the aqueous solution on the rice paper, and drying, wherein the oil coating step is to uniformly mix lavender essential oil and rapeseed oil, uniformly coat the mixture on the rice paper, and then drying the paper in the sun to obtain the transparent boiled oil rice paper.

Wherein the steps of brushing glue and brushing alum are as follows: dissolving gelatin in water, heating and decocting to obtain gelatin material with relative density of 3.5; dissolving alum in water, controlling the mass concentration to be 12% to obtain alum water; and respectively brushing glue stock and the alum solution on the prepared rice paper, brushing the glue stock for 1 time, brushing the alum solution for 1 time, and brushing for 12 times in total to finish the step.

Example 3

The raw materials comprise the following components in parts by weight: 120 parts of pteroceltis tatarinowii bark fiber, 60 parts of wormwood, 170 parts of jute fiber, 22 parts of peanut oil, 3 parts of lemon essential oil, 4 parts of graphene oxide and 1.2 parts of surfactant potassium stearate.

The preparation method comprises the following steps:

the method comprises the following steps: preparing wingceltis bark fiber, wormwood, jute fiber and graphene oxide into raw rice paper stock, fishing paper, squeezing, baking, pasting, oiling, drying the paper in the sun in sequence to obtain the new painting transparent oil rice paper, preparing a 6wt% aqueous solution of a surfactant, namely potassium stearate before the oiling step, uniformly coating the aqueous solution on the rice paper, and drying, wherein the oiling step is to uniformly mix lemon essential oil and peanut oil, uniformly coat the mixture on the rice paper, and then drying the rice paper to obtain the transparent oil semi-rice paper.

Wherein the steps of brushing glue and brushing alum are as follows: dissolving gelatin in water, heating and decocting to obtain gelatin material with relative density of 3.5; dissolving alum in water, controlling the mass concentration to be 12% to obtain alum water; and respectively brushing glue stock and the alum solution on the prepared rice paper, brushing the glue stock for 3 times, brushing the alum solution for 1 time, and brushing for 12 times in total to finish the step.

Example 4

The raw materials comprise the following components in parts by weight: 180 parts of pteroceltis tatarinowii bark fiber, 70 parts of wormwood, 220 parts of coconut fiber, 31 parts of linseed oil, 4 parts of lavender essential oil, 6 parts of graphene oxide and 1.8 parts of potassium dodecyl sulfate serving as a surfactant.

The preparation method comprises the following steps:

the method comprises the following steps: preparing wingceltis skin fiber, wormwood, coconut fiber and graphene oxide into raw rice paper pulp, sequentially fishing paper, squeezing, baking, coating oil, drying the paper in the sun to obtain the new painting transparent rice paper, preparing a surfactant lauryl potassium sulfate into an 8wt% aqueous solution before the oil coating step, uniformly coating the aqueous solution on the rice paper, and drying.

Example 5

The raw materials comprise the following components in parts by weight: 150 parts of pteroceltis tatarinowii bark fiber, 65 parts of wormwood, 200 parts of jute fiber, 26.5 parts of linseed oil, 3.5 parts of lavender essential oil, 5 parts of graphene oxide and 1.6 parts of surfactant potassium stearate.

The preparation method comprises the following steps:

the method comprises the following steps: preparing wingceltis bark fiber, wormwood, jute fiber and graphene oxide into raw rice paper pulp, fishing paper, squeezing, drying, pasting, oiling, drying the paper in the sun to obtain the new painting transparent rice paper, preparing a 7wt% aqueous solution of a surfactant, namely potassium stearate before the oiling step, uniformly coating the aqueous solution on the rice paper, drying, uniformly coating lavender essential oil and linseed oil on the rice paper after the oiling step is uniformly mixed, and drying the rice paper to obtain the transparent oil raw rice paper.

Example 6

Compared with example 5, linseed oil was replaced by castor oil, and other conditions were not changed.

Test example 1

Taking the embodiment 1-6 prepared by the invention as a detection material, and carrying out a high-temperature aging test and a damp-heat aging test, the specific operations are as follows:

1. setting the temperature of a constant-temperature constant-humidity aging box to be 105 ℃, accelerating aging for 12 hours by using the natural humidity in the box, and taking out the aging box every 3 hours to test the change of chromaticity and mechanical property;

2. setting the temperature of a constant-temperature constant-humidity aging box at 80 ℃ and the relative humidity of 65 percent, accelerating aging for 28 days, and taking out every 7 days to test the tensile strength and the folding endurance change.

The indexes are shown in table 1:

table 1: performance test comparison table

Performance characterization	Example 1	Example 2	Example 3	Example 4	Example 5	Example 6
							Mechanical strength/N after 12h aging	24.5	20.7	21.1	25.4	25.9	27.5
Humid heat aging for 7 days pH value	8.2	7.5	7.9	8.3	8.7	9.2
							Damp-heat aging for 7 days and folding endurance per time	55	48	50	60	62	67

As can be seen from the above table, the new drawing transparent oil rice paper prepared by the embodiment of the invention has good mechanical properties and resistance to damp-heat aging.

Test example 2 detection of mechanical Properties

Subject: the new painting transparent oil rice paper and the commercial rice paper prepared in the examples 1 to 5 are prepared.

The experimental method comprises the following steps: the water vapor permeability is measured by adopting a static moisture-permeable dish method, the tensile strength is measured according to QB/T1670-92, the elongation at break is measured according to FZ/T60005-1991, and the tear strength is measured according to GB/T12829-2006. The results are shown in Table 2.

TABLE 2

As can be seen from the table above, the new painting transparent oil rice paper prepared by the embodiment of the invention has better mechanical property, and is obviously superior to similar products sold in the market.

Test example 3 antibacterial Property test

The antibacterial property of the sample was measured by the agar plate diffusion method in CB/T20944.1-2007 evaluation of antibacterial properties of textiles, and the antibacterial effects in examples 1-5 were measured by using Staphylococcus aureus ATCC25923 and Escherichia coli ATCC25922 as test strains, and the results are shown in Table 3.

TABLE 3 test results

As can be seen from the table, the ultra-soft non-woven fabric prepared by the embodiment of the invention also has excellent antibacterial performance, and is obviously superior to similar products sold in the market.

Example 6 compared with example 5, the linseed oil of mixed oil is replaced by castor oil, the castor oil has antioxidation, make the bacteriostatic zone expand apparently, bacteriostatic the very good effect, and have better resistance to wet heat aging, the transparent oil rice paper made is difficult to turn yellow and brittle, easy to store for a long time of the painting and calligraphy.

Compared with the prior art, at present, when the common rice paper is in contact with limbs for a long time, bacteria and sweat stains on hands can be brought to the rice paper, so that bacteria such as escherichia coli, staphylococcus aureus, mould and the like are easily bred, and the service life of the rice paper is influenced; meanwhile, the Xuan paper is greatly influenced by the environmental humidity, and is easy to damp and mildew particularly in the rainy weather; the invention provides a new painting transparent oil rice paper, which is characterized in that the rice paper is easy to be bitten by insects and is influenced by the propagation of ova of the insects in the storage process, so that the damage of the paper and the painting and calligraphy is caused, and the ornamental value and the economic value of the paper and the painting and calligraphy are greatly influenced;

according to the novel transparent painting oil rice paper prepared by the invention, graphene oxide is added into the raw stock, so that the graphene oxide is uniformly distributed on the surface of the prepared rice paper, a surfactant solution is further coated before oil coating, the hydrophilic end of the surfactant is bonded with the graphene oxide on the rice paper, the lipophilic end of the other end of the surfactant is exposed, then mixed oil is coated, and the mixed oil can be well fixed on the rice paper under the adsorption of the lipophilic end of the surfactant, so that the transparent rice paper is obtained, after painting on the rice paper, the painting presents two sides, and exquisite patterns can be seen on the front side and the back side;

The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims

1. The new painting transparent oil rice paper is characterized by being prepared from the following raw materials in parts by weight: 100-200 parts of pteroceltis tatarinowii bark fiber, 50-80 parts of wormwood, 150-300 parts of plant fiber, 20-40 parts of mixed oil, 3-7 parts of graphene oxide and 1-2 parts of surfactant;

the plant fiber is selected from one or a combination of more of straw fiber, cotton fiber, kapok fiber, bamboo fiber, sisal fiber, abaca fiber, coconut fiber, flax fiber, jute fiber and castor fiber;

the mixed oil is edible oil and aromatic plant essential oil; the edible oil is selected from one of castor oil, peanut oil and olive oil.

2. The new drawing transparent oil rice paper according to claim 1, which is prepared from the following raw materials in parts by weight: 120-180 parts of pteroceltis tatarinowii bark fiber, 60-70 parts of wormwood, 170-220 parts of plant fiber, 25-35 parts of mixed oil, 4-6 parts of graphene oxide and 1.2-1.8 parts of surfactant.

3. The new drawing transparent oil rice paper according to claim 2, which is prepared from the following raw materials in parts by weight: 150 parts of pteroceltis tatarinowii bark fiber, 65 parts of wormwood, 200 parts of plant fiber, 30 parts of mixed oil, 5 parts of graphene oxide and 1.6 parts of surfactant.

4. The new drawing transparent oil rice paper as claimed in claim 1, wherein the surfactant is selected from one or more of calcium stearate, sodium stearate, potassium stearate, sodium dodecylbenzene sulfonate, sodium dodecylsulfate, potassium dodecylbenzene sulfonate, and potassium dodecylsulfate.

5. The preparation method of the new drawing transparent oil rice paper as claimed in any one of claims 1 to 4, which comprises the following steps: preparing wingceltis bark fiber, wormwood, plant fiber and graphene oxide into raw rice paper pulp, and preparing the new painting transparent oil rice paper after sequentially carrying out paper fishing, plate squeezing, drying and pasting, oil coating and paper drying.

6. The preparation method of claim 5, wherein before the oiling step, the surfactant is prepared into a 5-10wt% aqueous solution, uniformly coated on the rice paper, and dried; and the oil coating step is to uniformly mix the mixed oil, uniformly coat the mixed oil on the rice paper, and then dry the rice paper.

7. The method of claim 6, further comprising the step of brushing the gum and brushing the alum after the step of oiling.