CN113278471A - 用于果蔬清洗杀菌的贝壳粉微胶囊及其制备方法 - Google Patents
用于果蔬清洗杀菌的贝壳粉微胶囊及其制备方法 Download PDFInfo
- Publication number
- CN113278471A CN113278471A CN202110610109.7A CN202110610109A CN113278471A CN 113278471 A CN113278471 A CN 113278471A CN 202110610109 A CN202110610109 A CN 202110610109A CN 113278471 A CN113278471 A CN 113278471A
- Authority
- CN
- China
- Prior art keywords
- shell powder
- microcapsule
- vegetables
- cleaning
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000843 powder Substances 0.000 title claims abstract description 65
- 239000003094 microcapsule Substances 0.000 title claims abstract description 27
- 235000012055 fruits and vegetables Nutrition 0.000 title claims abstract description 13
- 238000004140 cleaning Methods 0.000 title claims abstract description 10
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title abstract description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 13
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 11
- 239000001116 FEMA 4028 Substances 0.000 claims abstract description 11
- 229920002774 Maltodextrin Polymers 0.000 claims abstract description 11
- 239000005913 Maltodextrin Substances 0.000 claims abstract description 11
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims abstract description 11
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims abstract description 11
- 229960004853 betadex Drugs 0.000 claims abstract description 11
- 238000001354 calcination Methods 0.000 claims abstract description 11
- 239000011162 core material Substances 0.000 claims abstract description 11
- 229940035034 maltodextrin Drugs 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 238000002791 soaking Methods 0.000 claims abstract description 6
- 238000001694 spray drying Methods 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 17
- 229930006000 Sucrose Natural products 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 239000005720 sucrose Substances 0.000 claims description 9
- -1 sucrose fatty acid ester Chemical class 0.000 claims description 9
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 230000004580 weight loss Effects 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 238000004945 emulsification Methods 0.000 claims description 3
- 235000013305 food Nutrition 0.000 abstract description 5
- 239000000447 pesticide residue Substances 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 230000003044 adaptive effect Effects 0.000 abstract description 2
- 238000004332 deodorization Methods 0.000 abstract description 2
- 238000009776 industrial production Methods 0.000 abstract description 2
- 230000001804 emulsifying effect Effects 0.000 abstract 1
- 238000005303 weighing Methods 0.000 description 6
- 239000012535 impurity Substances 0.000 description 4
- 238000004380 ashing Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000643 oven drying Methods 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
- A23L5/27—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
- A23L5/273—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption using adsorption or absorption agents, resins, synthetic polymers, or ion exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/20—After-treatment of capsule walls, e.g. hardening
- B01J13/206—Hardening; drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1233—Carbonates, e.g. calcite or dolomite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Nutrition Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Emergency Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Abstract
用于果蔬清洗杀菌的贝壳粉微胶囊及其制备方法，该方法包括：清洗贝壳后于氢氧化钠溶液中浸泡处理，之后干燥并粉碎形成贝壳粉；煅烧贝壳粉后烘干处理；以贝壳粉为芯材，麦芽糊精和β‑环状糊精为壁材，进行均质乳化制成乳化液；最后对乳化液采用喷雾干燥法进行微胶囊化。本发明通过将煅烧的贝壳粉用适配的壁材包埋而制成贝壳粉微胶囊，从而可以稳定地缓慢释放，用于果蔬的清洗杀菌时可以去除水果蔬菜表面农药残留，具有较强的杀菌、抑菌和脱臭能力，并且贝壳粉本身对环境无污染，对人体无毒无害，可以作为一种绿色环保的食品级洗涤用品，提高人们的饮食质量，保障食品安全。本发明简单易，尤其适合大规模工业化生产。
Description
技术领域
本发明涉及一种绿色清洗杀菌剂。
背景技术
水果蔬菜中含有多种维持机体生命活动的营养物质，是消费者每日饮食摄入的大部分营养来源，但由于微生物污染、农药残留、重金属、各种可见杂质的影响，果蔬的食品安全问题已经成为了人们日益关注的焦点。
发明内容
本发明的目的是提供一种绿色安全的果蔬清洗杀菌产品。
根据本发明的第一方面，提供了一种用于果蔬清洗杀菌的贝壳粉微胶囊的制备方法，包括：
提供贝壳，用去离子水洗净后置于0.15～0.20mol·L-1氢氧化钠溶液中浸泡1～2h，干燥并粉碎后过80～100目筛；
取粉碎好的贝壳粉进行煅烧，温度为400～600℃，时间为1～2h，然后将贝壳粉于170～190℃烘干20～30min；
以煅烧并烘干好的贝壳粉为芯材，麦芽糊精和β-环状糊精为壁材，芯材与壁材的质量比例为1：6～1：4，壁材麦芽糊精：β-环状糊精的质量比例为3:1～2:1，制成微胶囊液，微胶囊液总固形物(质量)含量为18～22％(W/W)，用蔗糖脂肪酸酯作为乳化剂进行乳化，用量为微胶囊液的0.3％～0.5％(质量比)，在1.5×104～1.6×104r/min条件下均质15～20min，制成乳化液；
对乳化液采用喷雾干燥法进行微胶囊化：进风温度110～130℃、出风温度70～90℃，进料量为3.0～5.0ml/min、进风压力为0.15～0.20MPa。
根据本发明的制备方法，可以通过计算贝壳粉失重率，确认贝壳粉煅烧或粉灰化完全。
根据本发明的第二方面，提供了一种贝壳粉微胶囊，根据上述方法制成。
本发明通过将煅烧的贝壳粉用适配的壁材包埋而制成贝壳粉微胶囊，从而可以稳定地缓慢释放，用于果蔬的清洗杀菌时可以去除水果蔬菜表面农药残留，具有较强的杀菌、抑菌和脱臭能力，并且贝壳粉本身对环境无污染，对人体无毒无害，可以作为一种绿色环保的食品级洗涤用品，提高人们的饮食质量，保障食品安全。本发明简单易，尤其适合大规模工业化生产。
具体实施方式
下面结合具体实施例对本发明作进一步的说明。
实施例1
(1)贝壳的预处理：以废弃贝壳为原料，将贝壳用去离子水洗净后置于0.15mol·L-1氢氧化钠溶液中浸泡1h，以除去附着在贝壳表面的杂物，放入干燥箱中烘干24h，将洗净干燥的贝壳粉碎后过80目筛。
(2)贝壳粉的制备：称取适量粉碎好的贝壳粉于坩埚中，放置于煅烧炉中煅烧，温度为400℃，煅烧时间为1h，然后将贝壳粉置于烘箱中，以170℃烘干20min，于干燥器内冷却后备用。通过称量贝壳粉灰化前后质量，计算贝壳粉失重率，确认贝壳粉灰化完全。
(3)贝壳粉的微胶囊化：以上述步骤(2)制备好的贝壳粉为芯材，麦芽糊精和β-环状糊精为壁材，芯材与壁材的质量比例为1：6，壁材麦芽糊精：β-环状糊精的质量比例为3:1，制成微胶囊液，微胶囊液总固形物质量含量为18％(W/W)，用蔗糖脂肪酸酯作为乳化剂进行乳化，用量为微胶囊液总量的0.3％(质量比)，在1.5×104r/min条件下均质15min,制成乳化液。微胶囊化采用喷雾干燥法：进风温度110℃、出风温度70℃，进料量为3.00ml/min、进风压力为0.15MPa。
实施例2
(1)贝壳的预处理：以废弃贝壳为原料，将贝壳用去离子水洗净后置于0.18mol·L-1氢氧化钠溶液中浸泡1.5h，以除去附着在贝壳表面的杂物，放入干燥箱中烘干30h，将洗净干燥的贝壳粉碎后过90目筛。
(2)贝壳粉的制备：称取适量粉碎好的贝壳粉于坩埚中，放置于煅烧炉中煅烧，温度为500℃，煅烧时间为1.5h，然后将贝壳粉置于烘箱中，以180℃烘干25min，于干燥器内冷却后备用。通过称量贝壳粉灰化前后质量，计算贝壳粉失重率，确认贝壳粉灰化完全。
(3)贝壳粉的微胶囊化：以上述步骤(2)制备好的贝壳粉为芯材，麦芽糊精和β-环状糊精为壁材，芯材与壁材的比例为1：5，壁材麦芽糊精：β-环状糊精的比例为2:1，制成微胶囊液，微胶囊液总固形物含量为20％(W/W)，用蔗糖脂肪酸酯作为乳化剂进行乳化，用量为微胶囊液总量的0.4％，在1.5×104r/min条件下均质18min,制成乳化液。微胶囊化采用喷雾干燥法：进风温度120℃、出风温度80℃，进料量为4.0ml/min、进风压力为0.18MPa。
实施例3
(1)贝壳的预处理：以废弃贝壳为原料，将贝壳用去离子水洗净后置于0.20mol·L-1氢氧化钠溶液中浸泡2h，以除去附着在贝壳表面的杂物，放入干燥箱中烘干36h，将洗净干燥的贝壳粉碎后过100目筛。
(2)贝壳粉的制备：称取适量粉碎好的贝壳粉于坩埚中，放置于煅烧炉中煅烧，温度为600℃，煅烧时间为2h，然后将贝壳粉置于烘箱中，以190℃烘干30min，于干燥器内冷却后备用。通过称量贝壳粉灰化前后质量，计算贝壳粉失重率，确认贝壳粉灰化完全。
(3)贝壳粉的微胶囊化：以上述步骤(2)制备好的贝壳粉为芯材，麦芽糊精和β-环状糊精为壁材，芯材与壁材的比例为1：4，壁材麦芽糊精：β-环状糊精的比例为2:1，制成微胶囊液，微胶囊液总固形物含量为22％(W/W)，用蔗糖脂肪酸酯作为乳化剂进行乳化，用量为微胶囊液总量的0.5％，在1.6×104r/min条件下均质20min。微胶囊化采用喷雾干燥法，最佳工艺为：进风温度130℃、出风温度90℃，进料量为5.0ml/min、进风压力为0.20MPa。
通过选择上述合适温度锻烧后，贝壳粉的分子结构发生了特殊的变化，加强了其自身的稳定性，从而对细菌起到了更好的抑菌作用；其自身孔隙和直径更小，从而单位体积内贝壳粉的数量增加，使其更容易接触到样品表面，从而对产品的保鲜效果更为显著。另外，贝壳粉煅烧后呈现多孔状结构，比表面积显著增大，吸附性能增强，对Pb2+、Cd2+、Zn2+、Cu2+等重金属离子具有显著增强的吸附作用。此外，贝壳粉天然的结构属性以及煅烧后pH大于12的碱性，对果蔬表面农药残留进行脱附与降解，不添加任何其他化学成分，对人体无毒无害、对环境友好。
Claims (3)
1.一种用于果蔬清洗杀菌的贝壳粉微胶囊的制备方法，包括：
提供贝壳，用去离子水洗净后置于0.15～0.20mol·L-1氢氧化钠溶液中浸泡1～2h，干燥并粉碎后过80～100目筛；
取粉碎好的贝壳粉进行煅烧，温度为400～600℃，时间为1～2h，然后将贝壳粉于170～190℃烘干20～30min；
以煅烧并烘干好的贝壳粉为芯材，麦芽糊精和β-环状糊精为壁材，芯材与壁材的质量比例为1：6～1：4，壁材麦芽糊精：β-环状糊精的质量比例为3:1～2:1，制成微胶囊液，微胶囊液总固形物含量为18～22％(W/W)，用蔗糖脂肪酸酯作为乳化剂进行乳化，用量为微胶囊液的0.3％～0.5％，在1.5×104～1.6×104r/min条件下均质15～20min，制成乳化液；
对乳化液采用喷雾干燥法进行微胶囊化：进风温度110～130℃、出风温度70～90℃，进料量为3.0～5.0ml/min、进风压力为0.15～0.20MPa。
2.根据权利要求1所述的制备方法，其中通过计算贝壳粉失重率，确认贝壳粉煅烧完全。
3.一种贝壳粉微胶囊，根据权利要求1或2所述的方法制成。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110610109.7A CN113278471A (zh) | 2021-06-01 | 2021-06-01 | 用于果蔬清洗杀菌的贝壳粉微胶囊及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110610109.7A CN113278471A (zh) | 2021-06-01 | 2021-06-01 | 用于果蔬清洗杀菌的贝壳粉微胶囊及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113278471A true CN113278471A (zh) | 2021-08-20 |
Family
ID=77282939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110610109.7A Pending CN113278471A (zh) | 2021-06-01 | 2021-06-01 | 用于果蔬清洗杀菌的贝壳粉微胶囊及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113278471A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116998689A (zh) * | 2023-08-14 | 2023-11-07 | 衡水志豪畜牧科技有限公司 | 定量卤制羊杂汤预制菜肴的工业化加工方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104388208A (zh) * | 2014-11-07 | 2015-03-04 | 舟山赛莱特海洋科技有限公司 | 一种基于贝壳粉末的脱农药果蔬清洗剂的制备方法 |
| CN104877808A (zh) * | 2015-06-26 | 2015-09-02 | 浙江海洋学院 | 基于贝壳粉的水产品清洗剂的制备方法 |
| CN106000249A (zh) * | 2016-05-19 | 2016-10-12 | 成都迈瑞斯特装饰材料有限公司 | 一种具有香味缓释功能的微胶囊的制备方法 |
| CN108432868A (zh) * | 2018-03-08 | 2018-08-24 | 天津农学院 | 一种木纳格葡萄的综合气调保鲜方法 |
| CN111434239A (zh) * | 2019-01-14 | 2020-07-21 | 爱利奇生物科技(深圳)有限公司 | 含有活氧贝壳粉组合物的微胶囊构造 |
-
2021
- 2021-06-01 CN CN202110610109.7A patent/CN113278471A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104388208A (zh) * | 2014-11-07 | 2015-03-04 | 舟山赛莱特海洋科技有限公司 | 一种基于贝壳粉末的脱农药果蔬清洗剂的制备方法 |
| CN104877808A (zh) * | 2015-06-26 | 2015-09-02 | 浙江海洋学院 | 基于贝壳粉的水产品清洗剂的制备方法 |
| CN106000249A (zh) * | 2016-05-19 | 2016-10-12 | 成都迈瑞斯特装饰材料有限公司 | 一种具有香味缓释功能的微胶囊的制备方法 |
| CN108432868A (zh) * | 2018-03-08 | 2018-08-24 | 天津农学院 | 一种木纳格葡萄的综合气调保鲜方法 |
| CN111434239A (zh) * | 2019-01-14 | 2020-07-21 | 爱利奇生物科技(深圳)有限公司 | 含有活氧贝壳粉组合物的微胶囊构造 |
Non-Patent Citations (1)
| Title |
|---|
| 江尧森: "《海洋贝类加工技术》", 31 July 1996, 中国农业出版社, pages: 83 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116998689A (zh) * | 2023-08-14 | 2023-11-07 | 衡水志豪畜牧科技有限公司 | 定量卤制羊杂汤预制菜肴的工业化加工方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20220039453A1 (en) | Dehydrated thc candy foodstuff compositions | |
| Jawad et al. | Adsorption of methylene blue onto acid-treated mango peels: kinetic, equilibrium and thermodynamic study | |
| CN102816022B (zh) | 一种利用沼液制备农药的方法 | |
| US20180103679A1 (en) | Insect production systems and methods | |
| CN109911995A (zh) | 一种兼具藻毒素脱除与藻液高效脱水的蓝藻资源化方法 | |
| CN113278471A (zh) | 用于果蔬清洗杀菌的贝壳粉微胶囊及其制备方法 | |
| CN100534573C (zh) | 一种过滤介质及制备方法、使用该过滤介质的滤芯、净水装置和饮水机 | |
| CN2895396Y (zh) | 纳米二氧化钛杀菌及水处理装置 | |
| CN105104920B (zh) | 一种中性条件下双氧水与乙醇脱除大米蛋白中稻瘟灵的方法 | |
| Gavali et al. | A comprehensive review of the development of nano-bio adsorbents for the separation of heavy metals from wastewater | |
| CN102093092A (zh) | 近临界水技术将城乡垃圾制备为有机肥的方法 | |
| CN103723852A (zh) | 一种基于无机和有机重金属吸附剂的污水处理方法 | |
| JP6569994B2 (ja) | 蜂産物エキスの製造方法及び蜂産物エキス | |
| CN101618307B (zh) | 环保保温建筑涂料用微胶囊的制备方法 | |
| KR20030071612A (ko) | 버섯소금 제조방법 | |
| CN101352207B (zh) | 凹凸棒海带清洗剂 | |
| CN110205207B (zh) | 一种基于贝壳的果蔬清洗剂及其制备方法和应用方法 | |
| CN112387092A (zh) | 一种以纯天然植物提取物组成的甲醛清除剂及制备方法 | |
| CN107854994B (zh) | 可吞噬有机污染物的绿色环保自降解生物活性酶，其制备方法及应用 | |
| CN116173954B (zh) | 一种金属铁改性污泥炭及其制备方法和应用 | |
| CN108835612A (zh) | 一种高温低浓度碱制制取琼脂的方法 | |
| CN113088412B (zh) | 一种用于清洗菜蔬的煅烧珍珠钙粉组合物的制备方法 | |
| CN104055196A (zh) | 一种净化装置 | |
| CN114180667A (zh) | 一种高效除磷剂的制备方法 | |
| CN1188679A (zh) | 发酵工业废水生产灭火剂的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210820 |