CN113278325A - Flocking ink for printing cigarette tipping paper and preparation method thereof - Google Patents
Flocking ink for printing cigarette tipping paper and preparation method thereof Download PDFInfo
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- CN113278325A CN113278325A CN202110563609.XA CN202110563609A CN113278325A CN 113278325 A CN113278325 A CN 113278325A CN 202110563609 A CN202110563609 A CN 202110563609A CN 113278325 A CN113278325 A CN 113278325A
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- acrylic resin
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- cyclodextrin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to the technical field of ink, in particular to flocking ink for printing cigarette tipping paper and a preparation method thereof. The flocking ink is composed of acrylic resin, modified cyclodextrin, a surfactant, ethanol, water and a water-soluble spice, and by adding the modified cyclodextrin and the alcohol-soluble acrylic resin, the temperature resistance of the ink can be further improved, so that tipping paper cannot be discolored due to high temperature of cigarette combustion; meanwhile, the overall wear resistance of the tipping paper can be improved, and the physical life is prolonged; in addition, can effectively prevent the adhesion of gloss oil layer, guarantee the quality of whole cigarette product.
Description
Technical Field
The invention relates to the technical field of ink, in particular to flocking ink for printing cigarette tipping paper and a preparation method thereof.
Background
The tipping paper is special paper for lapping the cigarette and the filter tip, is printed and processed into the tipping paper for the cigarette by adopting transfer paper, and is more and more accepted by the market and has higher and higher occupation ratio due to exquisite printing and bright color. Because the transfer paper is formed by processing a transfer resin layer, a meson layer or an aluminum layer on the base paper of the common tipping paper, the printing ink adhesion of the transfer paper is different from the adhesion of the original base paper through penetration, the resin adhesion is mainly depended on, the resin accumulation and softening lead to the temperature resistance reduction of the tipping paper, the cigarette wrapping and heat sealing process of the product is easy to cause cigarette adhesion due to the softening of the resin with overhigh temperature. The gloss oil in the current market mainly focuses on environmental protection, brightness, wear resistance and the like, the gloss oil basically has no requirement on temperature resistance, and the gloss oil with poor temperature resistance is used on tipping paper, so that the problem of high-temperature adhesion of the transferring tipping paper is difficult to avoid.
Disclosure of Invention
The invention aims to provide flocking ink for printing cigarette tipping paper and a preparation method thereof.
In order to achieve the purpose, the invention provides flocking ink for printing cigarette tipping paper, which consists of acrylic resin, modified cyclodextrin, a surfactant, ethanol, water and a water-soluble spice, and specifically consists of the following raw materials in parts by weight: 20-30 parts of water-soluble acrylic resin, 2-6 parts of alcohol-soluble acrylic resin, 10-20 parts of 2-hydroxypropyl-beta-cyclodextrin, 0.5-1.5 parts of tween 20, 1-2 parts of tween 80, 80-120 parts of ethanol, 100-160 parts of water and 20-40 parts of water-soluble perfume.
Preferably, the acrylic resin is one or a combination of two or more of water-soluble acrylic resin and alcohol-soluble acrylic resin.
Preferably, the alcohol-soluble acrylic resin is formed by polymerizing methacrylic resin and butyl acrylate.
Preferably, the modified cyclodextrin is formed by reacting cyclodextrin with one or more of alkyl, hydroxyalkyl and sulfoalkyl, and the cyclodextrin is one or more of alpha-cyclodextrin, beta-cyclodextrin and gamma-cyclodextrin.
Preferably, the modified cyclodextrin is 2-hydroxypropyl-beta-cyclodextrin.
Preferably, the surfactant is a tween series surfactant
The flocking ink is prepared from the following raw materials in parts by weight: 20 parts of water-soluble acrylic resin, 2 parts of alcohol-soluble acrylic resin, 10 parts of 2-hydroxypropyl-beta-cyclodextrin, 0.5 part of tween 20, 1 part of tween 80, 80 parts of ethanol, 100 parts of water and 20 parts of water-soluble perfume.
The flocking ink is prepared from the following raw materials in parts by weight: 30 parts of water-soluble acrylic resin, 6 parts of alcohol-soluble acrylic resin, 20 parts of 2-hydroxypropyl-beta-cyclodextrin, 1.5 parts of tween 20, 2 parts of tween 80, 120 parts of ethanol, 160 parts of water and 40 parts of water-soluble perfume.
The invention also provides a preparation method of the flocking ink for printing the cigarette tipping paper, which comprises the following steps:
(1) adding distilled water into the modified cyclodextrin, and stirring at 1000-1500 rpm for 10-15 min to obtain a modified cyclodextrin solution;
(2) adding ethanol into alcohol-soluble acrylic resin, stirring at 1000-1500 rpm for 10-15 min, then adding Tween 20 and Tween 80, and stirring for 5-10 min to obtain an alcohol-soluble acrylic resin solution;
(3) mixing and stirring the modified cyclodextrin solution obtained in the steps (1) and (2) and the alcohol-soluble acrylic resin solution at 2000-2500 rpm for 10-15 min, then adding a water-soluble perfume, and stirring for 5-10 min to obtain a mixed perfume solution;
(4) adding distilled water into the water-soluble acrylic resin, stirring for 10-15 min at 1000-1500 rpm, then adding ethanol, stirring for 5-10 min, then adding the mixed spice solution obtained in the step (3), mixing and stirring for 10-15 min at 2000-2500 rpm, and finally adding the residual amount of distilled water and mixing to obtain the finished product.
Compared with the prior art, the invention has the following beneficial effects:
1. according to the invention, the modified cyclodextrin and the alcohol-soluble acrylic resin are added, so that the temperature resistance of the ink can be further improved, and the tipping paper can not change color due to high temperature of cigarette combustion; meanwhile, the overall wear resistance of the tipping paper can be improved, and the physical life is prolonged; in addition, can effectively prevent the adhesion of gloss oil layer, guarantee the quality of whole cigarette product.
2. The raw materials of the invention are sufficient in China and proper in price, so that the large-scale production of the invention is not limited by too high cost; meanwhile, the preparation method is simple, the total production cost is low, and the industrial large-scale production is facilitated.
Detailed Description
Example 1
The specific raw materials were weighed as in table 1, and the preparation steps were as follows:
(1) adding 1/3 distilled water into 2-hydroxypropyl-beta-cyclodextrin, and stirring at 1000rpm for 15min to obtain modified cyclodextrin solution;
(2) adding 1/2% ethanol into alcohol soluble acrylic resin, stirring at 1000rpm for 15min, adding Tween 20 and Tween 80, and stirring for 5min to obtain alcohol soluble acrylic resin solution;
(3) mixing and stirring the modified cyclodextrin solution obtained in the steps (1) and (2) and the alcohol-soluble acrylic resin solution at 2000rpm for 15min, then adding a water-soluble perfume, and stirring for 5min to obtain a mixed perfume solution;
(4) adding 1/3 distilled water into water-soluble acrylic resin, stirring for 15min at 1000pm, adding 1/2 75% ethanol, stirring for 5min, adding the mixed perfume solution obtained in step (3), mixing and stirring at 2000rpm for 15min, and adding the rest amount of distilled water.
Example 2
(1) Adding 1/3 distilled water into 2-hydroxypropyl-beta-cyclodextrin, and stirring at 1500rpm for 10min to obtain modified cyclodextrin solution;
(2) adding 1/2% ethanol into alcohol soluble acrylic resin, stirring at 1500rpm for 10min, adding Tween 20 and Tween 80, and stirring for 10min to obtain alcohol soluble acrylic resin solution;
(3) mixing the modified cyclodextrin solution obtained in the steps (1) and (2) with the alcohol-soluble acrylic resin solution at 2500rpm, stirring for 10min, adding water-soluble perfume, and stirring for 10min to obtain a mixed perfume solution;
(4) adding 1/3 distilled water into water-soluble acrylic resin, stirring at 1500rpm for 10min, adding 1/2 75% ethanol, stirring for 10min, adding the mixed perfume solution obtained in step (3), mixing and stirring at 2500rpm for 10min, and adding the rest amount of distilled water.
Example 3
(1) Adding 1/3 distilled water into 2-hydroxypropyl-beta-cyclodextrin, and stirring at 1500rpm for 15min to obtain modified cyclodextrin solution;
(2) adding 1/2% ethanol into alcohol soluble acrylic resin, stirring at 1500rpm for 10min, adding Tween 20 and Tween 80, and stirring for 10min to obtain alcohol soluble acrylic resin solution;
(3) mixing and stirring the modified cyclodextrin solution obtained in the steps (1) and (2) and the alcohol-soluble acrylic resin solution at 2500rpm for 15min, then adding a water-soluble perfume, and stirring for 10min to obtain a mixed perfume solution;
(4) adding 1/3 distilled water into water-soluble acrylic resin, stirring at 1500rpm for 10min, adding 1/2 75% ethanol, stirring for 10min, adding the mixed perfume solution obtained in step (3), mixing and stirring at 2500rpm for 10min, and adding the rest amount of distilled water.
Comparative example 1
(1) Adding 1/3 distilled water into 2-hydroxypropyl-beta-cyclodextrin, and stirring at 1500rpm for 15min to obtain modified cyclodextrin solution;
(2) adding Tween 20 and Tween 80 into the modified cyclodextrin solution obtained in the step (1), stirring for 10min, adding water-soluble perfume at 2500rpm, and stirring for 10min to obtain mixed perfume solution;
(3) adding 1/3 distilled water into water-soluble acrylic resin, stirring at 1500rpm for 10min, adding 75% ethanol, stirring for 10min, adding the mixed perfume solution obtained in step (2), mixing and stirring at 2500rpm for 10min, and adding the rest amount of distilled water.
Comparative example 2
(1) Adding 1/2% ethanol into alcohol soluble acrylic resin, stirring at 1500rpm for 10min, adding Tween 20 and Tween 80, and stirring for 10min to obtain alcohol soluble acrylic resin solution;
(2) adding water-soluble perfume into the alcohol-soluble acrylic resin solution obtained in the step (1) at 2500rpm, and stirring for 10min to obtain a mixed perfume solution;
(3) adding 1/2 distilled water into water-soluble acrylic resin, stirring at 1500rpm for 10min, adding 1/2 75% ethanol, stirring for 10min, adding the mixed perfume solution obtained in step (2), mixing and stirring at 2500rpm for 10min, and adding the rest amount of distilled water.
TABLE 1
| Kind of material | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 |
| Water-soluble acrylic resin | 20 | 25 | 30 | 30 | 40 |
| Alcohol soluble acrylic resin | 2 | 4 | 6 | / | 6 |
| 2-hydroxypropyl-beta-cyclodextrin | 10 | 15 | 20 | 26 | / |
| Tween 20 | 0.5 | 1 | 1.5 | 1.5 | 1.5 |
| Tween 80 | 1 | 1.2 | 2 | 2 | 2 |
| 75% ethanol | 80 | 100 | 120 | 60 | 120 |
| Water (W) | 100 | 130 | 160 | 160 | 120 |
| Water-soluble perfume | 20 | 30 | 40 | 40 | 40 |
Example 4 ink Performance testing
Printing a layer of examples 1-3 and comparative examples 1 and 2 again on the graphic printing layer of the tipping paper by a gravure printing mode to obtain the tipping paper for the cigarette,
and (3) temperature resistance detection: a heat seal tester with the model number of HSR-01 is adopted. And opening the heat sealing tester to set the upper end temperature to be 130 ℃, the lower end temperature to be 30 ℃, the heat sealing time to be 0.5S, adjusting the heat sealing pressure to be 100 +/-5 KPa, keeping the temperature for 5 minutes after the temperature reaches a set value to prepare for testing, and immediately taking out the hot-pressed sample to observe the surface change of the detected sample. The same test sample paper was subjected to 3 sets of tests.
And (3) detecting the tack-back: and (3) placing the tipping paper bobbin paper sample in an oven at 80 ℃, pressing a weight (10KG), keeping for 30min, taking out, naturally cooling the tipping paper to room temperature, then manually peeling, and observing the adhesion state of the tipping paper sample paper. The same test sample paper was subjected to 3 sets of tests.
And (3) detecting the wear resistance: and (3) balancing the test sample for 30min, cutting the test sample into 60mm multiplied by 200mm, placing the test sample on an ink printing and decoloring tester, testing according to a method specified in GB10006-88, and observing the powder falling condition of each group of samples after the test is finished, wherein each group of samples are tested for at least 3 times. And (3) testing conditions are as follows: 50 times/min, 200 times.
Detecting the transparency and the fragrance amount: the cigarette tipping paper (after 3 months of preparation) of 50 testers and the prepared cigarette are randomly extracted for sensory evaluation.
The test results are shown in Table 2.
TABLE 2 ink Performance test results
The foregoing descriptions of specific exemplary embodiments of the present invention have been presented for purposes of illustration and description. It is not intended to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the above teaching. The exemplary embodiments were chosen and described in order to explain certain principles of the invention and its practical application to enable one skilled in the art to make and use various exemplary embodiments of the invention and various alternatives and modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the claims and their equivalents.
Claims (9)
1. The flocking ink for printing the cigarette tipping paper is characterized by comprising the following raw materials in parts by weight: 20-30 parts of water-soluble acrylic resin, 2-6 parts of alcohol-soluble acrylic resin, 10-20 parts of 2-hydroxypropyl-beta-cyclodextrin, 0.5-1.5 parts of tween 20, 1-2 parts of tween 80, 80-120 parts of ethanol, 100-160 parts of water and 20-40 parts of water-soluble perfume.
2. The flocking ink according to claim 1, wherein the acrylic resin is one or a combination comprising two or more of water-soluble acrylic resin, alcohol-soluble acrylic resin.
3. The flocking ink according to claim 2 wherein the alcohol soluble acrylic resin is polymerized from methacrylic resin and butyl acrylate.
4. The flocking ink according to claim 1, wherein the modified cyclodextrin is cyclodextrin reacted with one or more of alkyl, hydroxyalkyl, and sulfoalkyl, and the cyclodextrin is one or more of alpha-cyclodextrin, beta-cyclodextrin, and gamma-cyclodextrin.
5. The flocking ink of claim 4 wherein the modified cyclodextrin is 2-hydroxypropyl- β -cyclodextrin.
6. The flocking ink as claimed in claim 1, wherein said surfactant is a tween series surfactant.
7. The flocking ink according to claim 1, wherein the flocking ink is composed of the following raw materials in parts by weight: 20 parts of water-soluble acrylic resin, 2 parts of alcohol-soluble acrylic resin, 10 parts of 2-hydroxypropyl-beta-cyclodextrin, 0.5 part of tween 20, 1 part of tween 80, 80 parts of ethanol, 100 parts of water and 20 parts of water-soluble perfume.
8. The flocking ink according to claim 1, wherein the flocking ink is composed of the following raw materials in parts by weight: 30 parts of water-soluble acrylic resin, 6 parts of alcohol-soluble acrylic resin, 20 parts of 2-hydroxypropyl-beta-cyclodextrin, 1.5 parts of tween 20, 2 parts of tween 80, 120 parts of ethanol, 160 parts of water and 40 parts of water-soluble perfume.
9. A method for preparing a flocking ink as claimed in any one of claims 1 to 8, wherein the method comprises the steps of:
(1) adding distilled water into the modified cyclodextrin, and stirring at 1000-1500 rpm for 10-15 min to obtain a modified cyclodextrin solution.
(2) Adding ethanol into alcohol-soluble acrylic resin, stirring at 1000-1500 rpm for 10-15 min, then adding Tween 20 and Tween 80, and stirring for 5-10 min to obtain an alcohol-soluble acrylic resin solution;
(3) and (3) mixing and stirring the modified cyclodextrin solution obtained in the steps (1) and (2) and the alcohol-soluble acrylic resin solution at 2000-2500 rpm for 10-15 min, then adding a water-soluble perfume, and stirring for 5-10 min to obtain a mixed perfume solution.
(4) Adding distilled water into the water-soluble acrylic resin, stirring for 10-15 min at 1000-1500 rpm, then adding ethanol, stirring for 5-10 min, then adding the mixed spice solution obtained in the step (3), mixing and stirring for 10-15 min at 2000-2500 rpm, and finally adding the residual amount of distilled water and mixing to obtain the finished product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110563609.XA CN113278325A (en) | 2021-05-24 | 2021-05-24 | Flocking ink for printing cigarette tipping paper and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202110563609.XA CN113278325A (en) | 2021-05-24 | 2021-05-24 | Flocking ink for printing cigarette tipping paper and preparation method thereof |
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| CN113278325A true CN113278325A (en) | 2021-08-20 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113068395A (en) * | 2019-10-30 | 2021-07-02 | 韩国烟草人参公社 | Tipping paper suitable for finger smoke smell reducing technology, smoking article comprising tipping paper and preparation method of tipping paper |
| CN114318940A (en) * | 2021-12-31 | 2022-04-12 | 增和包装股份有限公司 | Production process of novel flocking tipping paper |
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| CN105385235A (en) * | 2015-12-08 | 2016-03-09 | 上海杰易森股份有限公司 | Aqueous touch gloss oil for gravure printing and preparation method thereof |
| CN110003868A (en) * | 2019-04-28 | 2019-07-12 | 北京大德广源石油技术服务有限公司 | 260 celsius temperature drilling fluid of superhigh temperature and preparation method thereof |
| CN111484766A (en) * | 2020-04-28 | 2020-08-04 | 安徽集友纸业包装有限公司 | Gloss oil with slow-release fragrance, cigarette tipping paper, filter element and smoking product |
| CN111827003A (en) * | 2020-07-31 | 2020-10-27 | 增和包装股份有限公司 | High-temperature-resistant gloss oil for tipping paper and preparation method thereof |
-
2021
- 2021-05-24 CN CN202110563609.XA patent/CN113278325A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105385235A (en) * | 2015-12-08 | 2016-03-09 | 上海杰易森股份有限公司 | Aqueous touch gloss oil for gravure printing and preparation method thereof |
| CN110003868A (en) * | 2019-04-28 | 2019-07-12 | 北京大德广源石油技术服务有限公司 | 260 celsius temperature drilling fluid of superhigh temperature and preparation method thereof |
| CN111484766A (en) * | 2020-04-28 | 2020-08-04 | 安徽集友纸业包装有限公司 | Gloss oil with slow-release fragrance, cigarette tipping paper, filter element and smoking product |
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| 柴春平等: "《高分子合成材料学》", vol. 1, 北京理工大学出版社, pages: 281 - 124 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113068395A (en) * | 2019-10-30 | 2021-07-02 | 韩国烟草人参公社 | Tipping paper suitable for finger smoke smell reducing technology, smoking article comprising tipping paper and preparation method of tipping paper |
| CN114318940A (en) * | 2021-12-31 | 2022-04-12 | 增和包装股份有限公司 | Production process of novel flocking tipping paper |
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