CN113277736A - UV colored glass glaze capable of being sintered and tempered at high temperature - Google Patents

UV colored glass glaze capable of being sintered and tempered at high temperature Download PDF

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Publication number
CN113277736A
CN113277736A CN202010104346.1A CN202010104346A CN113277736A CN 113277736 A CN113277736 A CN 113277736A CN 202010104346 A CN202010104346 A CN 202010104346A CN 113277736 A CN113277736 A CN 113277736A
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China
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oxide
high temperature
glass
temperature
organic
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CN202010104346.1A
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Chinese (zh)
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吴帝权
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Guangdong Octopus Enterprise Co ltd
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Guangdong Octopus Enterprise Co ltd
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Priority to CN202010104346.1A priority Critical patent/CN113277736A/en
Publication of CN113277736A publication Critical patent/CN113277736A/en
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
    • C03C17/04—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass by fritting glass powder
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/11—Deposition methods from solutions or suspensions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/30—Aspects of methods for coating glass not covered above
    • C03C2218/32—After-treatment

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The UV colored glass glaze capable of being sintered and toughened at high temperature is characterized by comprising three components of glass phase powder, high-temperature pigment and organic UV ink-regulating oil adhesive, wherein the ratio and the preparation process comprise 50-85% of the glass phase powder, 10-40% of the high-temperature pigment and 15-50% of the organic UV ink-regulating oil adhesive, and the components are mixed according to the ratio and are processed and ground by grinding equipment to prepare the UV colored glass glaze.

Description

UV colored glass glaze capable of being sintered and tempered at high temperature
The technical field is as follows:
the invention belongs to the field of glass color ink, and particularly relates to a UV color glaze capable of being sintered and toughened at high temperature and applied to glass.
Background art:
the glass product is a common article in life of people, almost relates to the square aspect of life, and along with the continuous pursuit of people for quality of life, the basic requirement of printing various colored patterns on the glass product is also provided, and the modern people have increasingly improved awareness of environmental protection and energy conservation, so that the requirement on the glass colored glaze is higher and higher. Most of glass in the current market is oily-based solvent type colored glaze, and the colored glaze is easy to fall off and fade after being drawn on the glass and dried and cured and is easy to be washed away by water; in recent years, a part of oil colored glaze products are replaced by hydrophilic glaze materials, but the VOC (volatile organic compound) of the hydrophilic glaze materials is also high in emission, (the VOC is an English abbreviation of volatile organic compounds (volatile organic compounds) and refers to an active volatile organic compound, namely a volatile organic compound which can generate harm.) the environment and the health are damaged to a certain extent in the using process.
At present, UV low-temperature color ink (UV refers to ultraviolet (Ultra-Violet Ray) curing) appears on the market, the low-temperature UV ink can not be sintered or toughened at high temperature (550-730 ℃), and can be burnt or can not be effectively combined with glass at high temperature of 500 ℃, and the defects of peeling, roughness and the like are shown, and the defects of poor adhesive force, poor weather resistance and the like are caused because the ink is not toughened glass colored glaze.
The invention provides a colored glaze which can be sintered and toughened with glass at high temperature, aiming at solving the defects of the existing glass glaze and meeting the actual requirements of people on the glass glaze.
The invention content is as follows:
the UV colored glass glaze capable of being sintered and toughened at high temperature is characterized by comprising three components of glass phase powder, high-temperature pigment and organic UV ink-regulating oil adhesive, wherein the ratio and the preparation process comprise 50-85% of the glass phase powder, 10-40% of the high-temperature pigment and 15-50% of the organic UV ink-regulating oil adhesive, and the components are mixed according to the ratio and are processed and ground by grinding equipment to prepare the UV colored glass glaze.
The UV colored glass glaze capable of being sintered and tempered at high temperature is characterized in that the glass phase powder comprises the following components: silicon dioxide SiO2(20% -30%) bismuth oxide Bi2O3(10% -65%), boron oxide B2O3(5% -70%), sodium carbonate NaCO3(10% -15%), TiO titanium oxide2(1% -10%), zirconium oxide ZrO2(1% -20%), alumina Al2O3(5% -20%), KCO3(3% -20%), lithium oxide Li2O (1-10%), CaO (1-10%); the preparation process comprises the steps of mixing the materials according to the proportion, melting the materials uniformly at the high temperature of 1000-1300 ℃, pouring the melted materials into water to be quenched to form glass beads, and performing ball milling to obtain powder, thus preparing the glass phase powder.
The UV colored glass glaze capable of being sintered and tempered at high temperature is characterized in that the components of high-temperature pigment are as follows: chromium oxide Cr2O3(30-50 percent), copper oxide CuO (30-50 percent), iron oxide FeO (10-30 percent) and manganese oxide MnO2(10% -30%) cobalt oxide Co2O3(10-20%), nickel oxide NiO (10-20%); the preparation process comprises mixing the above materials at the above ratio, and reacting at high temperature of 900-1000 deg.C to obtain copper-chromium black (CuCr)2O4) Chrome-nickel-iron black (Ni, Fe) (Cr, Fe)2O4Chrome-cobalt-iron black (Co, Fe) (Fe, Cr)2O4Titanium white, titanium yellow, cobalt blue, cobalt green and iron red; and then the raw materials formed by the reaction are ball-milled into powder to prepare the high-temperature pigment.
A UV colored glass glaze capable of being sintered and tempered at high temperature is characterized in that the organic UV varnish adhesive comprises the following components: hexanediol acrylate, functional acrylate polymer (10-90%), photoinitiator, coupling agent and other resin (1-10%); the preparation process comprises the step of mixing the organic materials for reaction to prepare the organic UV varnish adhesive.
The action principle of the novel function of the UV colored glass glaze capable of being sintered and tempered at high temperature is as follows: the glaze material comprises glass phase powder as main component and Bi as main chemical component2O3-B2O3-SiO2Bi is formed at high temperature of about 1200 DEG C2Si2O2Glass body containing metal oxide TiO2，ZrO2，Al2O3，Na2O，K2O，Li2O, CaO and glass phase can form a connector to connect the glass and the color glaze together and play a role in controlling the melting performance and durability of the glaze.
The utility model provides a but UV colored glass glaze of high temperature sintering tempering, there is the high temperature pigment of different colors, thereby play the various color effects that the user required, through technologies such as silk screen printing, spraying, digital printing with UV colored glass glaze evenly attached to on glass, through the UV solidification of 6000W's UV lamp 15-20 seconds kind, then put into high temperature furnace with glass and carry out sintering or tempering treatment, UV colored glaze and glass surface firmly sinter together, produce the required color effect promptly after the processing finishes, the glaze reaches antiseized, high adhesive force, the purpose of fish tail effect resistance.
Description of the drawings:
FIG. 1 is a flow chart of a glass phase powder production process of a high-temperature sintering toughened UV colored glass glaze;
FIG. 2 is a flow chart of a high-temperature pigment production process of a high-temperature sintering toughened UV colored glass glaze;
FIG. 3 is a flow chart of the production process of organic adhesive for high-temperature sintering toughened UV colored glass glaze;
FIG. 4 is a flow chart of a production process of a high-temperature sintering toughened UV colored glass glaze.
The specific implementation mode is as follows:
as shown in figure 1, the glass phase powder of the UV colored glass glaze capable of being sintered and tempered at high temperature is prepared by taking silicon dioxide SiO according to a certain proportion2(20% -30%) bismuth oxide Bi2O3(10% -65%), boron oxide B2O3(5% -70%), sodium carbonate NaCO3(10% -15%), TiO titanium oxide2(1% -10%), zirconium oxide ZrO2(1% -20%), alumina Al2O3(5% -20%), KCO3(3% -20%), lithium oxide Li2O (1-10 percent) and CaO (1-10 percent), uniformly mixing the raw materials, uniformly melting the mixture at the high temperature of 1000-1300 ℃, pouring the uniformly melted substance into water to quench into glass beads, and finally ball-milling the glass beads into powder to prepare the glass phase powder.
As shown in figure 2, the high-temperature pigment of the high-temperature sintering toughened UV colored glass glaze is prepared by taking chromium oxide Cr according to a certain proportion2O3(30-50 percent), copper oxide CuO (30-50 percent), iron oxide FeO (10-30 percent) and manganese oxide MnO2(10% -30%) cobalt oxide Co2O3(10-20%) and nickel oxide NiO (10-20%), uniformly mixing the above-mentioned raw materials, making the mixture undergo the process of high-temp. 900-1000 deg.C reaction to obtain the copper-chromium black (CuCr)2O4) Chrome-nickel-iron black (Ni, Fe) (Cr, Fe)2O4Chrome-cobalt-iron black (Co, Fe) (Fe, Cr)2O4The high-temperature melanin is prepared by grinding the formed substance into powder by grinding equipment, and other color pigments can be prepared or added in the same way.
As shown in figure 3, the organic adhesive of the UV colored glass glaze capable of being sintered and tempered at high temperature is prepared by mixing and reacting hexanediol acrylate, functional acrylate polymer (10-90%), photoinitiator, coupling agent and other resin (1-10%) according to a certain proportion to prepare the organic UV varnish adhesive.
As shown in figure 4, the UV colored glass glaze capable of being sintered and tempered at high temperature is prepared by uniformly mixing 50-85% of glass phase powder, 10-40% of high-temperature pigment and 15-50% of organic UV ink-adjusting oil adhesive according to a certain proportion, and then processing and grinding the mixture by using grinding equipment to prepare the final finished product UV colored glass glaze.
The utility model provides a but UV colored glass glaze of high temperature sintering tempering, when using through technologies such as silk screen printing, spraying, digital printing with UV glass colored glaze evenly adhere to on glass, UV solidification through 6000W's UV lamp 15-20 seconds, then put into high temperature furnace with glass and sinter or tempering treatment, UV colored glaze and glass surface firmly sinter together, produce the required color effect promptly after the processing finishes, the glaze reaches antiseized, high adhesive force, the purpose of anti fish tail effect.
Has the advantages that: a high-temperature sintering toughened UV colored glass glaze is a high-temperature sintering glass glaze which takes inorganic materials as main raw materials, the inorganic materials are used as an intermediate combined with glass, the high-temperature sintering glass glaze has the properties of high anti-sticking property, high acid resistance, high adhesive force and the like, inorganic pigments are added to play the effects of shading, coloring and the like, and meanwhile, the organic UV varnish adhesive is matched to have better printing performance and environmental protection. The invention has the following effects: 1. environmental protection-no heavy metals; 2. environmental protection, namely reduction of VOC emission, is superior to oily and aqueous glaze materials; 3. energy conservation, namely short UV curing time, short furnace length, space saving and the like; 4. the high acid resistance is more than 48 hours (0.1N sulfuric acid is soaked at 80 ℃), so that the glass glaze material is ensured to have weather resistance and safety after being attached and does not fall off, and the high acid resistance is superior to UV low-temperature printing ink; 5. high scratch resistance, namely the hardness (0.7mm hardness pen) of more than 15N after high-temperature sintering at 550-730 ℃ is superior to UV low-temperature printing ink; 6. the UV curing adhesive force is strong, the oil-based glaze and the water-based glaze can be pretreated by water washing and the like before sintering, and the advantages can be achieved without any way, so that the UV curing glaze has great benefits in practical application, such as: the glaze cannot be affected in the processes of carrying, cleaning, edging and the like of the glass. The invention has the common properties of the colored glaze material, such as light-shielding property, durability, color and the like, simultaneously has the advantages of UV ink, and is the combination of the two advantages.
The above description specifically describes the UV color glass glaze medium raw material capable of high-temperature sintering tempering, the UV varnish binder and the manufacturing method thereof, and the description is made with reference to specific examples, but the above description is only the best example of the present invention, and the scope of the present invention should not be limited thereby.

Claims (4)

1. The UV colored glass glaze capable of being sintered and toughened at high temperature is characterized by comprising three components of glass phase powder, high-temperature pigment and organic UV ink-regulating oil adhesive, wherein the ratio and the preparation process comprise 50-85% of the glass phase powder, 10-40% of the high-temperature pigment and 15-50% of the organic UV ink-regulating oil adhesive, and the components are mixed according to the ratio and are processed and ground by grinding equipment to prepare the UV colored glass glaze.
2. The UV colored glass glaze capable of high-temperature sintering tempering according to claim 1, wherein the glass phase powder comprises the following components: silicon dioxide SiO2(20% -30%) bismuth oxide Bi2O3(10% -65%), boron oxide B2O3(5% -70%), sodium carbonate NaCO3(10% -15%), TiO titanium oxide2(1% -10%), zirconium oxide ZrO2(1% -20%), alumina Al2O3(5% -20%), KCO3(3% -20%), lithium oxide Li2O (1-10%), CaO (1-10%); the preparation process comprises the steps of mixing the materials according to the proportion, melting the materials uniformly at the high temperature of 1000-1300 ℃, pouring the melted materials into water to be quenched to form glass beads, and performing ball milling to obtain powder, thus preparing the glass phase powder.
3. The UV colored glass glaze capable of being sintered and tempered at high temperature according to claim 1, wherein the high temperature pigment comprises the following components: chromium oxide Cr2O3(30-50 percent), copper oxide CuO (30-50 percent), iron oxide FeO (10-30 percent) and manganese oxide MnO2(10% -30%) cobalt oxide Co2O3(10-20%), nickel oxide NiO (10-20%); the preparation process comprises mixing the above materials at the above ratio, and reacting at high temperature of 900-1000 deg.C to obtain copper-chromium black (CuCr)2O4) Chrome-nickel-iron black (Ni, Fe) (Cr, Fe)2O4Chrome-cobalt-iron black (Co, Fe) (Fe, Cr)2O4Titanium white, titanium yellow, cobalt blue, cobalt green and iron red; and then the raw materials formed by the reaction are ball-milled into powder to prepare the high-temperature pigment.
4. The UV colored glass glaze capable of being sintered and tempered at high temperature according to claim 1, wherein the organic UV varnish binder comprises the following components: hexanediol acrylate, functional acrylate polymer (10-90%), photoinitiator, coupling agent and other resin (1-10%); the preparation process comprises the step of mixing the organic materials for reaction to prepare the organic UV varnish adhesive.
CN202010104346.1A 2020-02-19 2020-02-19 UV colored glass glaze capable of being sintered and tempered at high temperature Pending CN113277736A (en)

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CN202010104346.1A CN113277736A (en) 2020-02-19 2020-02-19 UV colored glass glaze capable of being sintered and tempered at high temperature

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117805948A (en) * 2024-03-01 2024-04-02 河南百合特种光学研究院有限公司 High-temperature sintering method of quartz fly-eye lens

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105368140A (en) * 2015-12-07 2016-03-02 佛山市高明绿色德化工有限公司 Photo-cured high-temperature colored glass printing ink and preparation method therefor and painting method thereof
CN109775986A (en) * 2017-11-10 2019-05-21 广东奥迪博士实业有限公司 A kind of anti-sticking masking silver wire glaze of vehicle glass

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105368140A (en) * 2015-12-07 2016-03-02 佛山市高明绿色德化工有限公司 Photo-cured high-temperature colored glass printing ink and preparation method therefor and painting method thereof
CN109775986A (en) * 2017-11-10 2019-05-21 广东奥迪博士实业有限公司 A kind of anti-sticking masking silver wire glaze of vehicle glass

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117805948A (en) * 2024-03-01 2024-04-02 河南百合特种光学研究院有限公司 High-temperature sintering method of quartz fly-eye lens
CN117805948B (en) * 2024-03-01 2024-05-17 河南百合特种光学研究院有限公司 High-temperature sintering method of quartz fly-eye lens

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Application publication date: 20210820