CN109775986A - A kind of anti-sticking masking silver wire glaze of vehicle glass - Google Patents
A kind of anti-sticking masking silver wire glaze of vehicle glass Download PDFInfo
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- CN109775986A CN109775986A CN201711103009.5A CN201711103009A CN109775986A CN 109775986 A CN109775986 A CN 109775986A CN 201711103009 A CN201711103009 A CN 201711103009A CN 109775986 A CN109775986 A CN 109775986A
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- oxide
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- high temperature
- glaze
- silver wire
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Abstract
The present invention provides a kind of anti-sticking vehicle glass, masking silver wire and acid resistance glaze, it is characterised in that by glass phase powder 50%-85%；High temperature pigment 10%-40%；Organic bond 10%-30%；It is uniformly mixed and is ground using milling apparatus processing.Glass phase powder is by silica SiO2(20%-30%)；Bismuth oxide Bi2O3(10%-65%)；Boron oxide B2O3(5%-70%)；Sodium carbonate NaCO3(10%-15%)；Titanium oxide TiO2(1%--10%)；Zirconium oxide ZrO2(1%--20%)；Aluminium oxide Al2O3(5%--20%)；Potassium carbonate KCO3(3%-20%)；Lithia Li2O (1%-10%)；Calcium oxide CaO (1-10%) composition.High temperature pigment is by chromium oxide Cr2O3(30%-50%)；Copper oxide CuO (30%-50%)；Iron oxide FeO (10%-30%)；Manganese oxide MnO2(10%-30%)；Cobalt oxide Co2O3(10-20%)；Nickel oxide NiO (10-20%) composition.Organic bond is made of terpinol, ethers (10%-90%) and resin and auxiliary agent (1%-10%).
Description
Technical field:
The present invention relates to a kind of vehicle glass glaze, refer in particular to a kind of front heat applied in vehicle glass compression moulding technique
Curved and tempered glass is anti-sticking, covers silver wire and acid resistance glaze.
Background technique:
Status of the glass moulding processes in modern auto industry becomes more and more important.Since Automobile Design is to meeting
Aerodynamics, the beautiful glass for using surface with complex shape with visual demand, more and more manufacturer's selections.
In addition, the lightweight of Automobile Design also makes the increase in demand of thin glass.Applying glaze in the periphery of vehicle glass can protect
The injury that the binder of shield below is irradiated far from ultraviolet light.Meanwhile painting glaze can also cover the uneven part of cementing layer, play
The effect of decoration improves the aesthetics of glass.
Glass glaze is overlying on the vehicle glass cut by silk-screen printing, after dry, by glass substrate sinter molding.
And for the front hot bending of vehicle glass and rear gear tempered glass, before sintering, it is also necessary to on the glaze after drying
Add print silver paste bus and heater wire, plays the role of glass demisting, defrosting.
The durability of glass glaze and its can these performances in glass forming process in conjunction with glass surface, make its at
For a kind of special functional material.
In traditional mode of production vehicle glass technique, the gravity method of forming is in glass manufacturing industry using very extensive.It uses iron
The mould support plate glass edge of matter moves glass in average 500 DEG C or so of continuous tunnel furnace with mold, then passes through
Local heating makes glass temperature rise to 600 DEG C or more, keeps glass sagging by self weight melting, until completely attached to mold,
Reach curved effect.But the technical process still has a little shortcoming: production efficiency is low, is unable to depth bending, different moulds
Cannot be completely the same between tool etc..In addition, the vehicle glass glaze of cooperation the method does not usually have shielding to silver wire, it is leaded,
The chemical properties such as acidproof are poor.
New vehicle glass production technology passes through vacuum suction pressure mold auxiliary glass hot bending shape.This pressure molding technique goes out
Now greatly change the status of automotive glass industries.I.e. on the basis of traditional vehicle glass production technology, according to glass
The specific requirements of shape vacuumize negative pressure to the glass after heating using mold and attach to mold forming.This method
Advantage is that the shape and size of glass can be made more accurate, can make the glass of complicated shape, tool changing speed it is fast and
High production efficiency.But in glass forming process, to prevent mold temperature is excessively high from melt glass, the covering of the surface of mold by
Woven cloth made of stainless steel or glass fibre.During compacting, glass glaze is directly contacted with pressing mold cloth, therefore is just needed
Want a kind of glaze to have antistick characteristic, to avoid in Improving Glass Manufacturing Processes with mold adhesion it is not easily to fall off, generate bubble or breakage etc.
Defect, special depth bending process require the anti-adhesion performance of glaze higher.
In order to make up deficiency of traditional glaze on masking silver paste bus, heater wire and acid resistance and antistick characteristic, specially send out
Anti-sticking, masking silver wire and acid resistance glaze is illustrated.
Summary of the invention:
The invention aims to make up the deficiency of existing glass glaze effect and providing a kind of has effects that anti-sticking and screening
Cover the glass glaze of silver wire performance.In order to achieve the above objectives, the technical solution adopted by the present invention is that:
Vehicle glass is anti-sticking, covers the ingredient of silver wire and acid resistance glaze:
Glass phase powder 50%-85%.
The preparation of glass phase powder: silica SiO2(20%-30%)；Bismuth oxide Bi2O3(10%-65%)；Oxidation
Boron2O3(5%-70%)；Sodium carbonate NaCO3(10%-15%)；Titanium oxide TiO2(1%--10%)；Zirconium oxide ZrO2(1%--
20%)；Aluminium oxide Al2O3(5%--20%)；Potassium carbonate KCO3(3%-20%)；Lithia Li2O (1%-10%)；Calcium oxide
CaO (1-10%).These materials mix according to the above ratio, by 1000 DEG C of high temperature -- after 1300 DEG C of meltings uniformly, it is poured into water
Quenching forms bead, using ball milling powdering, prepares glass phase powder.
High temperature pigment 10%-40%.
The preparation of high temperature pigment: chromium oxide Cr2O3(30%-50%)；Copper oxide CuO (30%-50%)；Iron oxide FeO
(10%-30%)；Manganese oxide MnO2(10%-30%)；Cobalt oxide Co2O3(10-20%), nickel oxide NiO (10-20%).These
Material is mixed according to above-mentioned ratio, by 900 DEG C of -1000 DEG C of reactions of high temperature, forms copper-chrome black (CuCr2O4), chromium ferronickel is black
(Ni, Fe) (Cr, Fe)2O4, chromium ferro-cobalt black (Co, Fe) (Fe, Cr)2O4, then ball milling powdering, prepare high temperature pigment.
Organic bond 10%-30%
The preparation of organic bond: terpinol, ethers (10%-90%)；Resin and auxiliary agent (1%-10%).Have above
Machine material hybrid reaction prepares organic bond.
Vehicle glass is anti-sticking, covers silver wire and acid resistance glaze for glass phase powder, high temperature pigment, organic bond by upper
Ratio mixing is stated, processes and grinds using milling apparatus, prepare final finished glaze.
Vehicle glass is anti-sticking, cover silver wire and the action principle of new function is presented in acid resistance glaze: glaze is by low melting point glass
Glass phase powder is main component, and chemical component is mainly Bi2O3-B2O3-SiO2, in 1200 DEG C of high temperature or so formation Bi2Si2O2It is anti-
Viscous crystal is simultaneously TiO containing metal oxide2, ZrO2, Al2O3, Na2O, K2O, Li2O, CaO.Glass phase can form connection
Body links together glass and black enamel, and plays the role of controlling glaze melting behaviour and durability.Glass phase is also right
The anti-adhesion performance of glaze plays conclusive influence, and anti-sticking glaze surface crystallization occurs in 580 DEG C -730 DEG C of tempering temperature
Phenomenon is easy demoulding so that glaze and the metal mold cloth of compacting will not be sticky.And effectively barrier heater wire silver ion penetrates into
The tin ion of glass surface and glass surface restores, and avoids frit surface from color difference occur, influences appearance.
High temperature pigment is mainly by copper-chrome black (CuCr2O4), chromium ferronickel black (Ni, Fe) (Cr, Fe)2O4, chromium ferro-cobalt it is black (Co,
Fe) (Fe, Cr)2O4Composition.These substances can effectively prevent silver ion and enter surface layer of glass through glaze at 700 DEG C of high temperature or so
Reduction reaction occurs with the Sn ion of surface layer of glass and shows rufous, the glass surface of black does not have apparent color difference, to play
It covers silver wire and improves the effect of antistick characteristic.
The anti-sticking glaze of vehicle glass is equably printed on vehicle glass by silk screen printing process, passes through temperature 150-200
It DEG C about 3-5 minutes dries, then puts glass into high temperature furnace and be sintered, compression process mistake is carried out after then glass is come out of the stove
Journey, glaze are securely sintered together with glass surface, and satisfactory vehicle glass is produced after being disposed, and glaze reaches
Anti-sticking and masking silver wire and acid-resistance effect purpose.
Detailed description of the invention:
Fig. 1 is glass phase powder production process flow chart
Fig. 2 is high temperature pigment production technological process
Fig. 3 is organic bond production technological process
Fig. 4 is the anti-sticking masking silver wire of automobile and acid-resistant glaze material manufacturing technique flow chart
Specific embodiment:
As shown in Figure 1, taking silica SiO according to a certain percentage2(20%-30%)；Bismuth oxide Bi2O3(10%-
65%)；Boron oxide B2O3(5%-70%)；Sodium carbonate NaCO3(10%-15%)；Titanium oxide TiO2(1%--10%)；Zirconium oxide
ZrO2(1%--20%)；Aluminium oxide Al2O3(5%--20%)；Potassium carbonate KCO3(3%-20%)；Lithia Li2O (1%-
10%)；Calcium oxide CaO (1-10%)；Above-mentioned raw materials are uniformly mixed；It is equal that mixture carries out 1000 DEG C of -1300 DEG C of meltings of high temperature
It is even；It is melted middle quenching of uniformly falling back and forms bead；Bead is subjected to ball milling powdering again, prepares glass phase powder
End.
As shown in Fig. 2, taking chromium oxide Cr according to a certain percentage2O3(30%-50%)；Copper oxide CuO (30%-50%)；
Iron oxide FeO (10%-30%)；Manganese oxide MnO2(10%-30%)；Cobalt oxide Co2O3(10-20%)；Nickel oxide NiO (10-
20%)；Above-mentioned raw materials are uniformly mixed；By mixture by 900 DEG C of -1000 DEG C of reactions of high temperature；Copper-chrome black is formed after reaction
(CuCr2O4), chromium ferronickel black (Ni, Fe) (Cr, Fe)2O4, chromium ferro-cobalt black (Co, Fe) (Fe, Cr)2O4；It is worn by milling apparatus
Powdery prepares high temperature pigment.
As shown in figure 3, taking terpinol, ethers (10%-90%) and resin and auxiliary agent (1%-10%) according to a certain percentage；
The above organic material hybrid reaction is prepared into organic bond.
As shown in figure 4, taking glass phase powder 50%-85% according to a certain percentage；High temperature pigment 10%-40%；It is organic viscous
Mixture 10%-30%；It is uniformly mixed；It processes and grinds using milling apparatus；Prepare final finished glaze.
Anti-sticking to vehicle glass provided by the invention above, masking silver wire and acid resistance glaze media stock and its manufacturer
Method is specifically described, and is explained in conjunction with specific embodiments, but best implementation only of the invention described above
Example cannot be limited the scope of implementation of the present invention with this.Those skilled in the art in the art are made according to the present invention
Subtle variation or improvement all should belong to the range that the invention patent covers.
Claims (4)
1. a kind of vehicle glass is anti-sticking, covers silver wire and acid resistance glaze, it is characterised in that by glass phase powder 50%-85%；
High temperature pigment 10%-40%；Organic bond 10%-30%；It is uniformly mixed and is ground using milling apparatus processing.
2. glass phase powder according to claim 1 is by silica SiO2(20%-30%)；Bismuth oxide Bi2O3(10%-
65%)；Boron oxide B2O3(5%-70%)；Sodium carbonate NaCO3(10%-15%)；Titanium oxide TiO2(1%--10%)；Zirconium oxide
ZrO2(1%--20%)；Aluminium oxide Al2O3(5%--20%)；Potassium carbonate KCO3(3%-20%)；Lithia Li2O (1%-
10%)；Calcium oxide CaO (1-10%)；1000 DEG C of -1300 DEG C of meltings of high temperature are carried out after mixing by above-mentioned raw materials uniformly to fall again
Enter quenching-in water and forms bead；Bead progress ball milling powdering is made again.
3. high temperature pigment according to claim 1 is by chromium oxide Cr2O3(30%-50%)；Copper oxide CuO (30%-
50%)；Iron oxide FeO (10%-30%)；Manganese oxide MnO2(10%-30%)；Cobalt oxide Co2O3(10-20%)；Nickel oxide
NiO (10-20%) is passed through 900 DEG C of -1000 DEG C of reactions of high temperature after mixing by above-mentioned raw materials and forms copper-chrome black (CuCr2O4), chromium
Ferronickel black (Ni, Fe) (Cr, Fe)2O4, chromium ferro-cobalt black (Co, Fe) (Fe, Cr)2O4；Powdery is worn by milling apparatus again and prepares institute
?.
4. organic bond according to claim 1 is by terpinol, ethers (10%-90%) and resin and auxiliary agent (1%-
10%) by above organic material hybrid reaction preparation gained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711103009.5A CN109775986A (en) | 2017-11-10 | 2017-11-10 | A kind of anti-sticking masking silver wire glaze of vehicle glass |
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|---|---|---|---|
| CN201711103009.5A CN109775986A (en) | 2017-11-10 | 2017-11-10 | A kind of anti-sticking masking silver wire glaze of vehicle glass |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110342821A (en) * | 2018-04-08 | 2019-10-18 | 广东奥迪博士实业有限公司 | A kind of anti-sticking glaze of 3D touch-control glass hot bending compression moulding |
| CN112125517A (en) * | 2019-06-24 | 2020-12-25 | 湖南衡义材料科技有限公司 | Anti-sticking shielding silver paste ink for high-acid-resistance automobile rear windshield and preparation method thereof |
| CN113277736A (en) * | 2020-02-19 | 2021-08-20 | 广东奥迪博士实业有限公司 | UV colored glass glaze capable of being sintered and tempered at high temperature |
| CN113493308A (en) * | 2020-03-20 | 2021-10-12 | 广东奥迪博士实业有限公司 | High-reflection glass glaze capable of improving conversion rate of solar cell |
| CN115159851A (en) * | 2022-08-12 | 2022-10-11 | 江苏拜富科技股份有限公司 | Anti-sticking glass glaze for automobiles and preparation method thereof |
| CN116102262A (en) * | 2022-12-27 | 2023-05-12 | 日鸿半导体材料（南通）有限公司 | Glass powder and preparation method thereof |
| CN116217246A (en) * | 2023-02-27 | 2023-06-06 | 合肥水泥研究设计院有限公司 | Inorganic binder and preparation method of inorganic binder/TiC composite material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643023A (en) * | 2012-05-04 | 2012-08-22 | 台州市定向反光材料有限公司 | Environmental-friendly black glaze for automotive glass and preparation method of black glaze |
| CN104529172A (en) * | 2014-12-17 | 2015-04-22 | 中国科学院上海硅酸盐研究所 | Lead-free and cadmium-free glass powder for automobile toughened glass ink and preparation method thereof |
-
2017
- 2017-11-10 CN CN201711103009.5A patent/CN109775986A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643023A (en) * | 2012-05-04 | 2012-08-22 | 台州市定向反光材料有限公司 | Environmental-friendly black glaze for automotive glass and preparation method of black glaze |
| CN104529172A (en) * | 2014-12-17 | 2015-04-22 | 中国科学院上海硅酸盐研究所 | Lead-free and cadmium-free glass powder for automobile toughened glass ink and preparation method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 化学工业出版社组织编写: "《中国化工产品大全.中卷》", 31 January 2005, 化学工业出版社 * |
| 孙德彬等主编: "《家具表面装饰工艺技术》", 30 April 2009, 中国轻工业出版社 * |
| 池至铣编著: "《陶瓷釉色料及装饰》", 30 November 2015, 中国建材工业出版社 * |
| 汪建编著: "《陶瓷颜料应用及配制技术》", 28 February 2017, 江西高校出版社 * |
| 王承遇等: "《玻璃表面装饰》", 31 August 1998, 新时代出版社 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110342821A (en) * | 2018-04-08 | 2019-10-18 | 广东奥迪博士实业有限公司 | A kind of anti-sticking glaze of 3D touch-control glass hot bending compression moulding |
| CN112125517A (en) * | 2019-06-24 | 2020-12-25 | 湖南衡义材料科技有限公司 | Anti-sticking shielding silver paste ink for high-acid-resistance automobile rear windshield and preparation method thereof |
| CN113277736A (en) * | 2020-02-19 | 2021-08-20 | 广东奥迪博士实业有限公司 | UV colored glass glaze capable of being sintered and tempered at high temperature |
| CN113493308A (en) * | 2020-03-20 | 2021-10-12 | 广东奥迪博士实业有限公司 | High-reflection glass glaze capable of improving conversion rate of solar cell |
| CN115159851A (en) * | 2022-08-12 | 2022-10-11 | 江苏拜富科技股份有限公司 | Anti-sticking glass glaze for automobiles and preparation method thereof |
| CN116102262A (en) * | 2022-12-27 | 2023-05-12 | 日鸿半导体材料（南通）有限公司 | Glass powder and preparation method thereof |
| CN116217246A (en) * | 2023-02-27 | 2023-06-06 | 合肥水泥研究设计院有限公司 | Inorganic binder and preparation method of inorganic binder/TiC composite material |
| CN116217246B (en) * | 2023-02-27 | 2023-12-19 | 合肥水泥研究设计院有限公司 | Inorganic binder and preparation method of inorganic binder/TiC composite material |
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Addressee: GUANGDONG OCTOPUS ENTERPRISE Co.,Ltd. Document name: Notification of Passing Examination on Formalities |
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| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20190521 |