CN113233450A - Lithium battery negative electrode material inside-string graphitization furnace - Google Patents
Lithium battery negative electrode material inside-string graphitization furnace Download PDFInfo
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- CN113233450A CN113233450A CN202110566554.8A CN202110566554A CN113233450A CN 113233450 A CN113233450 A CN 113233450A CN 202110566554 A CN202110566554 A CN 202110566554A CN 113233450 A CN113233450 A CN 113233450A
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/20—Graphite
- C01B32/205—Preparation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The invention discloses a lithium battery cathode material inner string graphitization furnace, which comprises an inner string graphitization furnace body, wherein the inner string graphitization furnace body consists of side edge refractory concrete walls on two sides and end part refractory concrete walls on two ends, the two side edge refractory concrete walls and the two end part refractory concrete walls enclose a rectangular shape, electrodes are embedded and installed on the back surfaces of the two end part refractory concrete walls, two graphite block walls which are the same as and opposite to the end part refractory concrete walls in size are arranged in the inner string graphitization furnace body, a graphite powder layer is filled between the graphite block walls and the end part refractory concrete walls on the same side, and a lower carbon laminate and an upper carbon laminate which are distributed from bottom to top and are connected and abutted with the graphite block walls are arranged between the two graphite block walls.
Description
Technical Field
The invention relates to the technical field of graphitization furnaces, in particular to a lithium battery negative electrode material inner-string graphitization furnace.
Background
The graphite has the excellent characteristics of good conductivity, high crystallinity, two-dimensional layered structure and the like, is very suitable for embedding and separating Li ions, has small expansion coefficient and high safety in the charging and discharging processes of the battery, so that the graphite lithium battery cathode material is widely researched, popularized and applied, mainly comprises natural graphite, artificial graphite and composite graphite at present, and three types of graphite lithium battery cathode materials, and has the excellent performances of high specific discharge capacity, excellent cycle performance, excellent first-time charging and discharging performance, outstanding safety performance, stable and controllable quality and the like, and the usage ratio of the lithium battery cathode material is up to more than 90%. After the graphite negative electrode material is subjected to preliminary treatment such as jet milling, spheroidization, surface coating treatment, carbonization and the like to obtain a semi-finished product with a standard body and particle size distribution, the semi-finished product is subjected to high-temperature heat treatment at a temperature of more than 2800 ℃ in a special graphitizing furnace, so that the electrochemical properties such as capacity, multiplying power, cycle performance and the like of the graphite negative electrode material are in an ideal state. In the graphitization process, the container is made of graphite material, the temperature rises sharply with the zero short time rise of current to hundreds of thousands of amperes, and the requirement on the mechanical strength of the material is extremely high.
At present, most of graphitizing furnaces in inner strings adopt crucibles, the loss of cylindrical crucibles is high, the crucibles are cracked and damaged and are difficult to recycle, the resistance is large, the power transmission time is long, the heat diffusion is serious, and the heat utilization efficiency is low.
Therefore, a graphitizing furnace connected in series in the lithium battery negative electrode material is designed.
Disclosure of Invention
The invention aims to solve the defects in the prior art, and provides the interior-series graphitization furnace for the lithium battery cathode material, which can form a crucible between the adjustable second reinforcing partition plate and the first reinforcing partition plate, can adjust the size of the formed crucible, can disassemble the first reinforcing partition plate and the second reinforcing partition plate, is convenient to replace the first reinforcing partition plate and the second reinforcing partition plate with cracks, is simple and convenient to operate, and improves the utilization efficiency.
In order to achieve the purpose, the invention adopts the following technical scheme:
a lithium battery cathode material inner string graphitization furnace comprises an inner string graphitization furnace body, wherein the inner string graphitization furnace body is composed of side edge refractory concrete walls on two sides and end part refractory concrete walls on two ends, the two side edge refractory concrete walls and the two end part refractory concrete walls are enclosed into a rectangular shape, electrodes are embedded and installed on the back surfaces of the two end part refractory concrete walls, two graphite block walls which are the same as and opposite to the end part refractory concrete walls in size are arranged in the inner string graphitization furnace body, a graphite powder layer is filled between the graphite block walls and the end part refractory concrete walls on the same side, a lower carbon laminate and an upper carbon laminate which are distributed from bottom to top and are connected and butted with the graphite block walls are arranged between the two graphite block walls, the bottom of the lower carbon laminate is higher than the bottom of the graphite powder layer, and two first carbon wallboards which are butted with the graphite block walls are connected on the opposite surfaces of the two graphite block walls, the two first carbon wallboards are propped against the upper end of the lower carbon laminate, the opposite surfaces of the two first carbon wallboards are connected with supporting carbon wallboards which are propped against the first carbon wallboards, the two supporting carbon wallboards are propped against the upper end of the lower carbon laminate, a cavity is formed among the lower carbon laminate, the two second carbon wallboards and the side refractory concrete wall body, a carbon felt heat-insulating board is arranged in the cavity and is in a rectangular frame shape with an open edge, just be equipped with coupling mechanism between the carbon felt heated board, the both sides of carbon plywood are equipped with two second carbon wallboards rather than being connected down, two the second carbon wallboard offsets and is connected with the both ends of first carbon wallboard two be equipped with between the second carbon wallboard can dismantle and rather than a plurality of first enhancement baffles of vertically, adjacent two all be equipped with the detachable second between the first enhancement baffle, between first enhancement baffle and the first carbon wallboard and strengthen the baffle.
Preferably, coupling mechanism includes first chimb and the second chimb integrative with the carbon felt heated board, first chimb is located the top and the counterbalance of second chimb, just first chimb and second chimb breach phase-match, first chimb runs through from top to bottom and is equipped with a plurality of first through-holes, the second chimb runs through from top to bottom and is equipped with a plurality of second through-holes, just relative with the second through-hole first through-hole, and the upper end of first chimb is equipped with the recess, the recess is linked together with first through-hole, and is relative install the carbon rod jointly in first through-hole and the second through-hole, the upper end fixedly connected with lug of carbon rod, the lug is located the recess.
Preferably, two opposite surfaces of the second carbon wallboards are provided with guide grooves, two sides of the lower carbon layer board are fixedly connected with first carbon blocks, and the first carbon blocks are positioned in the guide grooves and abut against the bottom in the guide grooves.
Preferably, both sides of the first carbon wallboard are fixedly connected with second carbon blocks, and the second carbon blocks are positioned in the guide grooves and are abutted against the guide grooves.
Preferably, both sides of the upper carbon laminate are fixedly connected with third carbon blocks, a supporting groove is formed in the upper end of the inner wall of the guide groove, and the third carbon blocks are abutted to the inner wall of the supporting groove.
Preferably, the support groove has a width greater than that of the guide groove.
Preferably, two the opposite one side of second carbon wallboard all is equipped with the cell body, the both ends of first enhancement baffle are located the cell body.
Preferably, the both ends of second enhancement baffle are run through respectively and are equipped with first draw-in groove and second draw-in groove, the thickness of first draw-in groove and second draw-in groove is the same with the thickness of first enhancement baffle, first draw-in groove and second draw-in groove card are on first enhancement baffle, be equipped with mutually back on the second enhancement baffle and mutually matched card post and post groove, card post and post groove set up mutually away from.
Compared with the prior art, the invention has the beneficial effects that:
1. when the carbon felt insulation board needs to be replaced, a worker pulls the convex block to drive the carbon rod to move upwards until the carbon rod is separated from the first through hole and the second through hole, and at the moment, the first convex edge and the second convex edge are not limited any more, so that the soft carbon felt insulation board can be pulled out and replaced; through using the carbon felt heated board as insulation material, compare with prior art's carbon black, change convenient and fast more, and clean health.
2. The adjustable crucible can be formed by the first reinforcing partition plate, the second reinforcing partition plate and the second carbon wall plates, and the distance between the second reinforcing partition plate and the second carbon wall plates on two sides can be adjusted by moving the second reinforcing partition plate, so that different cavities, namely different crucibles, are formed, the first reinforcing partition plate and the second reinforcing partition plate can be conveniently detached and replaced, the operation is simple and convenient, and the utilization efficiency is improved; and adjacent second is strengthened the baffle and is passed through card post and post groove and connect, and whole more stable.
In conclusion, the crucible is formed between the adjustable second reinforcing partition plate and the adjustable first reinforcing partition plate, the size of the formed crucible can be adjusted, the first reinforcing partition plate and the second reinforcing partition plate can be disassembled, the first reinforcing partition plate and the second reinforcing partition plate with cracks can be conveniently replaced, the operation is simple and convenient, and the utilization efficiency is improved.
Drawings
Fig. 1 is a schematic top view of a graphitizing furnace in series in the negative electrode material of a lithium battery according to the present invention;
FIG. 2 is a side view of a part of the structure of an internal series graphitization furnace for the negative electrode material of the lithium battery provided by the present invention;
FIG. 3 is a perspective view of a second reinforcing separator in a series graphitization furnace for negative electrode material of lithium battery according to the present invention;
FIG. 4 is a side view of a carbon felt insulation board in a series graphitization furnace in a lithium battery cathode material according to the present invention;
FIG. 5 is an enlarged view of the structure at A in FIG. 4;
fig. 6 is a top view of the first convex edge in the graphitizing furnace arranged in the negative electrode material of the lithium battery according to the present invention.
In the figure: 1 side fire-resistant concrete wall body, 2 tip fire-resistant concrete wall bodies, 3 interior strings of graphitization furnace body, 4 graphite powder layer, 5 graphite block wall, 6 first carbon wallboard, 7 support carbon wallboard, 8 second carbon wallboard, 9 electrode, 10 carbon felt heated board, 11 first enhancement baffle, 12 second enhancement baffle, 13 cell body, 14 first draw-in groove, 15 second draw-in groove, 16 calorie of post, 17 post groove, 18 lower carbon plywood, 19 upper carbon plywood, 20 guide way, 21 second carbon block, 22 first carbon block, 23 support groove, 24 third carbon block, 25 first chimb, 26 second chimb, 27 first through-hole, 28 second through-hole, 29 recess, 30 carbon stick, 31 lug.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
Referring to fig. 1-6, an inner string graphitization furnace for lithium battery cathode materials comprises an inner string graphitization furnace body 3, wherein the inner string graphitization furnace body 3 is composed of side edge refractory concrete walls 1 on two sides and end part refractory concrete walls 2 on two ends, the two side edge refractory concrete walls 1 and the two end part refractory concrete walls 2 are enclosed into a rectangular shape, and electrodes 9 are embedded and installed on the back surfaces of the two end part refractory concrete walls 2.
Two graphite block walls 5 which are the same as and opposite to the end refractory concrete wall body 2 in size are arranged in the inner series graphitization furnace body 3, a graphite powder layer 4 is filled between the graphite block wall 5 and the end refractory concrete wall body 2 on the same side, a lower carbon laminate 18 and an upper carbon laminate 19 which are distributed from bottom to top and are connected and abutted with the two graphite block walls 5 are arranged between the two graphite block walls 5, guide grooves 20 are arranged on the opposite surfaces of the two second carbon laminates 8, first carbon blocks 22 are fixedly connected to the two sides of the lower carbon laminate 18, and the first carbon blocks 22 are positioned in the guide grooves 20 and abutted with the inner bottom parts of the guide grooves; both sides of the upper carbon floor 19 are fixedly connected with third carbon blocks 24, the upper end of the inner wall of the guide groove 20 is provided with a support groove 23, and the third carbon blocks 24 are abutted against the inner wall of the support groove 23; wherein, the width of the supporting groove 23 is larger than that of the guiding groove 20, so that the third carbon block 24 can be supported.
The bottom of carbon plywood 18 is higher than the bottom of graphite powder layer 4 down, and the one side that two graphite block walls 5 are relative all is connected with two first carbon wallboard 6 rather than counterbalance, and two first carbon wallboard 6 counterbalance rather than the upper end of carbon plywood 18 down, and the one side that two first carbon wallboard 6 are relative all is connected with rather than the support carbon wallboard 7 that offsets, and two support carbon wallboard 7 counterbalance with the upper end of carbon plywood 18 down.
A cavity is formed among the lower carbon layer plate 18, the two second carbon wall plates 8 and the side refractory concrete wall body 1, a carbon felt insulation board 10 is installed in the cavity, the carbon felt insulation board 10 is in a rectangular frame shape with an open edge, a connecting mechanism is arranged between the carbon felt insulation boards 10 and comprises a first convex edge 25 and a second convex edge 26 which are integrated with the carbon felt insulation board 10, the first convex edge 25 is positioned above and abutted against the second convex edge 26, gaps of the first convex edge 25 and the second convex edge 26 are matched, a plurality of first through holes 27 are arranged in the first convex edge 25 in an up-and-down penetrating manner, a plurality of second through holes 28 are arranged in the second convex edge 26 in an up-and-down penetrating manner, the first through holes 27 are opposite to the second through holes 28, a groove 29 is arranged at the upper end of the first convex edge 25, the groove 29 is communicated with the first through holes 27, a carbon rod 30 is installed in the first through hole 27 and the second through hole 28, and a bump 31 is fixedly connected at the upper end of the carbon rod 30, the projection 31 is located within the recess 29.
Two second carbon wallboards 8 connected with the lower carbon wallboard 18 are arranged on two sides of the lower carbon wallboard, the two second carbon wallboards 8 are propped against and connected with two ends of the first carbon wallboard 6, second carbon blocks 21 are fixedly connected with two sides of the first carbon wallboard 6, and the second carbon blocks 21 are positioned in the guide grooves 20 and are propped against the guide grooves.
Be equipped with between two second carbon wallboards 8 and dismantle and rather than a plurality of first enhancement baffles 11 of vertically, two second carbon wallboards 8 one side relative all are equipped with cell body 13, and first both ends of strengthening baffle 11 are located cell body 13.
Detachable second reinforcing partition plates 12 are arranged between every two adjacent first reinforcing partition plates 11 and between the first reinforcing partition plates 11 and the first carbon wall plates 6, two ends of each second reinforcing partition plate 12 are respectively provided with a first clamping groove 14 and a second clamping groove 15 in a penetrating mode, the thicknesses of the first clamping grooves 14 and the second clamping grooves 15 are the same as those of the first reinforcing partition plates 11, the first clamping grooves 14 and the second clamping grooves 15 are clamped on the first reinforcing partition plates 11, the second reinforcing partition plates 12 are provided with clamping columns 16 and column grooves 17 which are opposite and matched, and the clamping columns 16 and the column grooves 17 are opposite; wherein the first reinforcing separator 11 and the second reinforcing separator 12 are made of graphite.
The method comprises the following operation steps:
s1, first, the first reinforcing partition plate 11 is installed in the groove 13 of the second carbon wall plate 8, and then the second reinforcing partition plate 12 is installed on the first reinforcing partition plate 11;
s2, adjusting the position of the second reinforcing partition plate 12 according to actual conditions, so as to form different chambers with the second carbon wall plates 8 on two sides;
s3, inserting and connecting the carbon felt heat-insulation board 10 through the cavity and then the carbon rod 30;
s4, when the carbon felt heat-insulation board 10 needs to be replaced, the carbon rod 30 is pulled out, the carbon felt heat-insulation board 10 can be taken out, the new carbon felt heat-insulation board 10 can be replaced, and the replacement is convenient and more clean and sanitary.
Specifically, when the carbon felt insulation board 10 needs to be replaced, a worker pulls the bump 31 to drive the carbon rod 30 to move upwards until the carbon rod 30 is separated from the first through hole 27 and the second through hole 28, and at the moment, the first convex edge 25 and the second convex edge 26 are not limited any more, so that the soft carbon felt insulation board 10 can be pulled out and replaced; by using the carbon felt heat-insulation plate 10 as a heat-insulation material, compared with the carbon black in the prior art, the replacement is more convenient and quicker, and the carbon felt heat-insulation plate is clean and sanitary;
meanwhile, an adjustable crucible can be formed by the first reinforcing partition plate 11, the second reinforcing partition plate 12 and the second carbon wall plates 8, and the distance between the second reinforcing partition plate 12 and the second carbon wall plates 8 on two sides can be adjusted by moving the second reinforcing partition plate 12, so that different cavities, namely different crucibles, are formed, the first reinforcing partition plate 11 and the second reinforcing partition plate 12 can be conveniently detached and replaced, the operation is simple and convenient, and the utilization efficiency is improved; and the adjacent second reinforcing partition plates 12 are connected through the clamping columns 16 and the column grooves 17, so that the whole body is more stable.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (8)
1. A lithium battery cathode material inner string graphitization furnace comprises an inner string graphitization furnace body (3), wherein the inner string graphitization furnace body (3) is composed of side edge refractory concrete walls (1) at two sides and end refractory concrete walls (2) at two ends, the two side edge refractory concrete walls (1) and the two end refractory concrete walls (2) are enclosed into a rectangular shape, the two end refractory concrete walls (2) are embedded with electrodes (9) at the opposite sides, the inner string graphitization furnace body (3) is characterized in that two graphite block walls (5) which are the same as and opposite to the end refractory concrete walls (2) in size are arranged in the inner string graphitization furnace body, a graphite powder layer (4) is filled between the graphite block walls (5) and the end refractory concrete walls (2) at the same side, a lower carbon laminate (18) and an upper carbon laminate (19) which are distributed from bottom to top and are connected and abutted against with the graphite block walls (5) are arranged between the two graphite block walls (5), the bottom of the lower carbon laminate (18) is higher than the bottom of the graphite powder layer (4), one side of each of the two graphite block walls (5) opposite to each other is connected with two first carbon wallboards (6) which are abutted against the graphite block walls, the upper ends of the two first carbon wallboards (6) and the lower carbon laminate (18) are abutted against each other, one side of each of the two first carbon wallboards (6) opposite to each other is connected with a supporting carbon wallboard (7) which is abutted against each other, the two supporting carbon wallboards (7) are abutted against the upper ends of the lower carbon laminate (18), a cavity is formed between the lower carbon laminate (18), the two second carbon wallboards (8) and the side fireproof concrete wall body (1), a carbon felt insulation board (10) is installed in the cavity, the carbon felt insulation board (10) is in a rectangular frame shape with an open edge, a connecting mechanism is arranged between the carbon felt insulation boards (10), two second carbon wallboards (8) connected with the lower carbon laminate (18) are arranged on two sides, two the both ends of second carbon wallboard (8) and first carbon wallboard (6) offset and are connected, two be equipped with between second carbon wallboard (8) can dismantle and rather than a plurality of first enhancement baffles (11) of vertically, adjacent two all be equipped with detachable second between first enhancement baffle (11), between first enhancement baffle (11) and first carbon wallboard (6) and strengthen baffle (12).
2. The lithium battery cathode material inside-string graphitization furnace as claimed in claim 1, wherein the connecting mechanism comprises a first convex edge (25) and a second convex edge (26) which are integrated with the carbon felt heat insulation board (10), the first convex edge (25) is located above and abutted against the second convex edge (26), gaps of the first convex edge (25) and the second convex edge (26) are matched, a plurality of first through holes (27) are arranged on the first convex edge (25) in a vertically penetrating manner, a plurality of second through holes (28) are arranged on the second convex edge (26) in a vertically penetrating manner, the first through holes (27) are opposite to the second through holes (28), a groove (29) is arranged at the upper end of the first convex edge (25), the groove (29) is communicated with the first through holes (27), and carbon rods (30) are installed in the first through holes (27) and the second through holes (28) which are opposite to each other, the upper end of the carbon rod (30) is fixedly connected with a lug (31), and the lug (31) is located in the groove (29).
3. The lithium battery cathode material in-line graphitization furnace as claimed in claim 1, wherein one side of the second carbon wall plate (8) opposite to the first carbon wall plate is provided with a guide groove (20), two sides of the lower carbon wall plate (18) are fixedly connected with first carbon blocks (22), and the first carbon blocks (22) are located in the guide groove (20) and abut against the inner bottom of the guide groove (20).
4. The lithium battery cathode material in-line graphitization furnace as claimed in claim 3, wherein both sides of the first carbon wall plate (6) are fixedly connected with second carbon blocks (21), and the second carbon blocks (21) are located in the guide grooves (20) and are abutted against the guide grooves.
5. The lithium battery cathode material in-line graphitization furnace as claimed in claim 4, wherein both sides of the upper carbon laminate (19) are fixedly connected with third carbon blocks (24), the upper end of the inner wall of the guide groove (20) is provided with a support groove (23), and the third carbon blocks (24) are abutted against the inner wall of the support groove (23).
6. The in-line graphitization furnace for lithium battery negative electrode material according to claim 5, wherein the width of the support groove (23) is greater than the width of the guide groove (20).
7. The graphitizing furnace in series for lithium battery negative electrode material as claimed in claim 1, wherein the two opposite sides of the second carbon wall plates (8) are provided with grooves (13), and two ends of the first reinforcing partition plate (11) are located in the grooves (13).
8. The graphitizing furnace in series for lithium battery negative electrode material as claimed in claim 1, wherein a first clamping groove (14) and a second clamping groove (15) are respectively formed at two ends of the second reinforcing partition plate (12) in a penetrating manner, the thicknesses of the first clamping groove (14) and the second clamping groove (15) are the same as the thickness of the first reinforcing partition plate (11), the first clamping groove (14) and the second clamping groove (15) are clamped on the first reinforcing partition plate (11), a clamping column (16) and a column groove (17) which are opposite and matched with each other are formed on the second reinforcing partition plate (12), and the clamping column (16) and the column groove (17) are opposite.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115159518A (en) * | 2022-07-29 | 2022-10-11 | 开封平煤新型炭材料科技有限公司 | U-shaped inner-string graphitization furnace and manufacturing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115159518A (en) * | 2022-07-29 | 2022-10-11 | 开封平煤新型炭材料科技有限公司 | U-shaped inner-string graphitization furnace and manufacturing method thereof |
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| CN113233450B (en) | 2022-12-09 |
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