CN113208951B - Butter modified attapulgite and application thereof in preparation of lipstick - Google Patents

Abstract

The invention discloses a butter modified attapulgite. The shortening modified attapulgite is attapulgite of which the surface is subjected to shortening modification treatment. Compared with the prior art, the shortening modified attapulgite can meet the requirement of pursuing beautiful and fashionable lipstick, can reduce the using amount of the colorant in the lipstick, and has higher safety, thereby solving the defect that the existing shortening modified attapulgite has monotonous color and luster patterns.

Description

Butter modified attapulgite and application thereof in preparation of lipstick

Technical Field

The invention belongs to the field of cosmetics, and particularly relates to a ghee modified attapulgite and an application thereof in preparation of lipstick.

Background

The butter is a special yak milk product, is extracted from yak milk, is similar to a yellow oily substance, and is one of favorite foods of Tibetan people. As early as one thousand years ago, Tibetan medicine Yutuo, Yundan tribute cloth in the four medical classics discusses the nutritional effect of ghee on human body, and the fresh ghee is cool and capable of strengthening tendons, generating luster and removing red and bara heat, namely the fresh ghee is capable of moistening qi and blood and is full of energy, so that the skin is not chapped, and mucus and febrile diseases can be treated. Tibetan medicine believes that long-term consumption or use of ghee in high-cold and anoxic environments can build up body, moisten intestines and stomach, warm spleen, moisten qi and invigorate human energy.

Lipstick is one of the common cosmetics at present. Lipstick includes lip glaze, lip gloss, lipstick, lip gloss, etc. and may be solid, gel, liquid, emulsion, oily, paste, etc. in different forms, and may be matte, water glossy, velvet, etc. in different forms. The most popular classification of lipsticks is mainly classified into liquid lipsticks, stick-shaped lipsticks and disc-shaped lipsticks according to the difference of texture and shape. With the pursuit of beauty and fashion, lipstick has become a necessity for more and more women. According to investigation of a plurality of consumers, the safety is highest in all selection indexes except the beautiful color, so that the research and development of the lipstick which not only has the beautiful color, but also is safe is a product which is urgently needed by the consumers at present.

The application of ghee in lipstick is reported in documents, for example, Chinese patent CN 110025561A, CN 104352396A emphasizes on general moistening and moisturizing effects, has the defect of monotonous color, and cannot meet the requirements of consumers on safety, beauty and fashion.

Disclosure of Invention

Based on the defects of the prior art, the invention aims to provide the shortening modified attapulgite, which can obtain a better color development effect under the same colorant dosage, thereby providing a rich and colorful color selection for shortening base lipstick.

In order to achieve the purpose, the technical scheme adopted by the invention is as follows:

a ghee modified attapulgite is characterized in that: the shortening modified attapulgite is attapulgite of which the surface is subjected to shortening modification treatment.

The preparation method of the ghee modified attapulgite comprises the following steps: mixing and grinding attapulgite and ghee to obtain the ghee modified attapulgite.

After milling, the excess ghee is washed away with an organic solvent.

The organic solvent can be diethyl ether and n-hexane.

The shortening modified attapulgite is applied to the preparation of lipstick.

A lipstick is characterized in that: the lipstick comprises the butter modified attapulgite.

Preferably, the lipstick consists essentially of oil, fat, wax, colorant and shortening modified attapulgite.

Preferably, the weight parts of the components are as follows:

20-25 parts of wax, namely,

1-4 parts of grease,

50-70 parts of oil, namely,

0.1 to 8 parts of butter modified attapulgite,

0.1-3 parts of a coloring agent.

More preferably still, the first and second liquid crystal compositions are,

the oil is a shortening oil which is prepared by mixing the raw materials,

the fat is vaseline which is obtained by mixing fat with fat,

the wax is beeswax.

Preferably, the using amount of the ghee modified attapulgite in the lipstick is 0.5-3 parts.

Preferably, the lipstick contains 1-10 parts of a smoothing agent. More preferably, the slip agent is octyldodecanol.

The preparation method of the lipstick comprises the following steps:

uniformly mixing the butter modified attapulgite with a colorant to obtain a pigment;

and then mixing the pigment and the other components uniformly to obtain the lipstick.

The shortening modified attapulgite can overcome the defects of the existing shortening base lipstick, can obtain better color development effect under the same colorant dosage, can meet the requirement of pursuing beautiful and fashionable lipstick, and can reduce the colorant dosage in the lipstick.

Drawings

Fig. 1 is a contact angle test of attapulgite before and after ghee modification.

Detailed Description

The present invention will be described in further detail with reference to the following examples and the accompanying drawings.

The purification of attapulgite clay is carried out according to the method disclosed in the invention patent 201911416417.5 of the subject group, which comprises the following steps:

(1) crushing attapulgite raw ore into small particles of 2-5 cm, and naturally airing or artificially heating to dehydrate to constant weight;

(2) preparing the dried particles obtained in the step (1) into slurry with the mass fraction of 5-20%, stirring, performing ultrasonic dispersion, sieving with a 1200-mesh sieve for separation, and concentrating the filtrate to obtain slurry with the water content of 50-75%. Wherein the stirring time is 20-60 min; the ultrasonic dispersion time is 15-45 min;

(3) adding egg white into the slurry obtained in the step (2), stirring for 15-40 min at 2-10 ℃, and introducing ammonia gas to enable foams containing attapulgite to float upwards; the adding amount of egg white is 5-20% of the mass of the slurry;

(4) collecting the floating foam obtained in the step (3), adding citric acid for defoaming, centrifuging and washing to obtain purified attapulgite for later use; the addition amount of the citric acid is 1-10% of the mass of the slurry.

The attapulgite of the present invention is not limited to the purification by the above-mentioned method, and the attapulgite purified by other methods is also applicable to the present invention.

The colorant used in the present invention is not particularly limited, and may be used alone or in combination according to the requirements of different colors, and meets the requirements of "hygienic standards for cosmetics".

Example 1

Mixing attapulgite and butter according to the mass of 1-5% of the attapulgite, grinding for 3-10 minutes in a high-speed ball mill, and after the grinding is finished, washing the butter/attapulgite mixture for 1-2 times by using diethyl ether and 3-4 times by using normal hexane in sequence to obtain butter modified attapulgite for later use. The contact angle is used for testing the modification effect, and the result is shown in fig. 1, the modified attapulgite clay is changed from hydrophilicity to hydrophobicity, the contact angle is 54 degrees, and the fact that the ghee is grafted to the surface of the attapulgite clay is proved.

Example 2

A shortening-based edible lipstick is prepared by the following steps:

1. blending the ghee modified attapulgite and the colorant according to the mass ratio of about 1:1, and performing high-speed ball milling for a certain time to obtain a pigment, wherein the pigment is marked as SF-ATP.

2. Mixing 20 parts by weight of beeswax, 1 part by weight of vaseline, 60 parts by weight of butter, 1 part by weight of octyl dodecanol and 1 part by weight of SF-ATP, stirring uniformly at 60-80 ℃, and filling into a mold to obtain the butter-based edible lipstick.

	Example 2	Control sample 1	Control sample 2
				Beeswax (Cera flava)	20	20	20
Vaseline	1	1	1
				Butter	60	60	60
Octyl dodecanol	1	1	1
				Butter modified attapulgite	0.5	--	--
Unmodified attapulgite	--	0.5	--
				Coloring agent	0.5	0.5	0.5
Color development effect	Dark and bright in color	Light and dull color	---

Control sample 1 and control sample 2 were prepared as in example 2. The color development effect of the control sample 1 and the example 2 in the above table is significantly different from the color and the brightness of the control sample 2.

Example 3

A shortening-based edible lipstick is prepared by the following steps:

1. blending the ghee modified attapulgite and the colorant according to the mass ratio of about 1:1, and performing high-speed ball milling for a certain time to obtain a pigment, wherein the pigment is marked as SF-ATP.

2. Mixing 24 parts by weight of beeswax, 2 parts by weight of vaseline, 70 parts by weight of butter, 2 parts by weight of octyl dodecanol and 2 parts by weight of SF-ATP, stirring uniformly at 60-80 ℃, and filling into a mold to obtain the butter-based edible lipstick.

Example 4

A shortening-based edible lipstick is prepared by the following steps:

1. blending the ghee modified attapulgite and the colorant according to the mass ratio of about 1:1, and performing high-speed ball milling for a certain time to obtain a pigment, wherein the pigment is marked as SF-ATP.

2. Mixing 25 parts by weight of beeswax, 4 parts by weight of vaseline, 80 parts by weight of butter, 3 parts by weight of octyl dodecanol and 3 parts by weight of SF-ATP, stirring uniformly at 60-80 ℃, and filling into a mold to obtain the butter-based edible lipstick.

Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments described above, or equivalents may be substituted for elements thereof. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (9)

1. The application of the ghee modified attapulgite in preparing cosmetics;

the surface of the butter modified attapulgite is modified by butter; mixing attapulgite with butter and grinding in a high-speed ball mill to obtain the butter modified attapulgite.

2. Use according to claim 1, characterized in that the cosmetic product is a lipstick.

3. A lipstick, characterized in that: the lipstick comprises the shortening modified attapulgite as claimed in claim 1.

4. A lipstick according to claim 3, wherein: the lipstick mainly comprises oil, grease, wax, colorant and butter modified attapulgite.

5. A lipstick according to claim 4 wherein: the weight parts of the components are as follows:

20-25 parts of wax,

1-4 parts of grease,

50-70 parts of oil, namely,

0.1 to 8 parts of butter modified attapulgite,

0.1-3 parts of a coloring agent.

6. A lipstick according to claim 4 or 5 wherein:

the oil is a shortening oil which is prepared by mixing the raw materials,

the fat is vaseline which is obtained by mixing fat with fat,

the wax is beeswax.

7. A lipstick according to claim 4 or 5 wherein: the lipstick further comprises 1-10 parts of a smoothing agent.

8. A lipstick according to claim 7 wherein: the smoothing agent is octyl dodecanol.

9. A process for preparing a lipstick as claimed in any one of claims 5 to 8 comprising:

uniformly mixing the butter modified attapulgite with a colorant to obtain a pigment;

and then mixing the pigment and the rest components uniformly to obtain the lipstick.

Images