CN113121213A - Ceramic material and processing method thereof - Google Patents

Ceramic material and processing method thereof Download PDF

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Publication number
CN113121213A
CN113121213A CN202110206786.2A CN202110206786A CN113121213A CN 113121213 A CN113121213 A CN 113121213A CN 202110206786 A CN202110206786 A CN 202110206786A CN 113121213 A CN113121213 A CN 113121213A
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ceramic
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张春生
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Ningbo Hesheng Health Technology Co ltd
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
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  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses a ceramic material, which comprises a ceramic processing basic raw material, a PAC (active element) material and water; the ceramic processing base raw material comprises 18 parts of kaolin, 20 parts of feldspar, 18 parts of quartz, 25 parts of agate crystal and 3 parts of rare earth in parts by mass. The one-time firing ceramic material process provided by the invention is suitable for manufacturing processes of various ceramic materials, especially for porcelain materials, and is particularly suitable for manufacturing and processing of thin-body ceramics, the raw material component parameters of the traditional thin-body ceramics are improved, the toughness and the adhesion of the clay are increased through the original improvement, the forming is facilitated, the finished product has good shaping, the ductility, the plasticity and the stability are improved, the production yield of the thin-body ceramics is improved, and in addition, the light transmission effect of the thin-body ceramics is good; the preparation process of the thin-body porcelain provides a brand-new thin-body porcelain and a manufacturing process thereof, has positive significance for promoting the development of thin-body porcelain products, and has positive economic benefits.

Description

Ceramic material and processing method thereof
Technical Field
The invention relates to the technical field of ceramic material processing, in particular to a ceramic material and a processing method thereof.
Background
Ceramics are a generic term for ceramics and porcelain. The ceramic material is a molded sintered body obtained by molding and high-temperature sintering, and the conventional ceramic material is mainly aluminosilicate.
Ceramic materials are now widely used in the market on drinking ware products.
The ceramic product is used in drinking vessels, and comprises teapots, tea cups and other tea sets made of purple sand, teapots, tea sets and other tea sets made of porcelain, and compared with stainless steel materials, the ceramic product has the advantages of being good in high temperature resistance and stability, and more beneficial to health after being used for a long time, and the ceramic product also obtains more enthusiasm of consumer groups.
In the aspect of using a drinking cup and a vacuum cup, the prior purple sand pottery product and porcelain product coexist, the pottery product has primitive and unsophisticated color and luster, and has long aftertaste when used as a drinking vessel, but the disadvantage is also that after the cup body made of purple sand material is used, aftertaste is easily left, for example, after the purple sand cup which has drunk tea is used, water, milk or other beverages such as coffee are removed, and the beverage can be doped with the aftertaste of the tea; the purple sand cup appliance which has drunk coffee has the same aftertaste of a large amount of coffee left when drinking milk, so that poor use experience is caused.
The pottery porcelain material in the household utensils is also extensively existed to current drink, but structural function is too single, and the in-service use experience is felt comparatively ordinary, lacks the popularization and propaganda bright spot, and the ceramic structure material of a novel structure and material constitution effectively promotes the technical scheme who uses experience and functional structure innovation, demand at present rather.
A ceramic structure product with beautiful appearance, portability, easy cleaning of an inner container and good material stability is suitable for novel product manufacturing processes of various types of pottery and porcelain products, and is required by the current market.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a ceramic material and a processing method thereof, which can effectively improve the integral structure of a drinking vessel, and have more beautiful appearance, light hand feeling, good structural stability and long service life; the defect factors of drinking water and unhealthy tea drinking of stainless steel products are reduced.
In order to solve the technical problems, the invention adopts the technical scheme that: a ceramic material comprises a ceramic processing base raw material, a PAC (active element) material and water.
As an improvement, the ceramic processing base raw material comprises 18 parts of kaolin, 20 parts of feldspar, 18 parts of quartz, 25 parts of agate crystal and 3 parts of rare earth by mass.
As an improvement, the PAC (active element) material comprises a seaweed extract capable of dispersing large-cluster molecules, and the PAC material comprises seaweed stock solution, trace elements such as sodium, potassium, calcium, magnesium, phosphorus and iron, and a composite solution of vitamin A, vitamin D, vitamin B1, vitamin B2, folic acid, nicotinic acid and pantothenic acid, which are prepared by fermenting flora, wherein the fermenting flora is flora consisting of at least two of lactobacillus plantarum, aspergillus niger, rhizopus, plant yeast and selenium-enriched yeast.
As an improvement, the processing technology of the ceramic material comprises the following steps:
step 1): processing and pulping, wherein the raw material components of the ceramic material comprise 18 parts by mass of kaolin, 20 parts by mass of feldspar, 18 parts by mass of quartz, 25 parts by mass of agate crystal, 3 parts by mass of rare earth and 2 parts by mass of PAC (active element) material, screening, removing impurities, cleaning and air-drying, then crushing, ball-milling and adding water to prepare slurry, wet ball-milling is carried out for 48 hours, and in the ball-milling procedure, the mass parts of the material, the ball and the water are 1: 3: 1.2;
step 2): processing and making a blank, namely preparing a product blank by using the slurry prepared in the step 1 and adopting a grouting processing technology, coating a layer of talcum powder in a cavity of a grouting mould before grouting, wherein the thickness of the blank is 2mm, and after grouting, rapidly cooling the blank by adopting a blowing cooling process until the blank is molded and forms a gap of 0.2mm with an inner cavity of the mould, wherein the air flow rate of blowing is 4m/S, and an air injection port is aligned with the position where the blank is attached to the inner wall of the mould;
step 3): processing and trimming, namely placing a ceramic material blank on a trimming machine for trimming, and spraying a water mixed solution of a PAC (active element) material on the inner surface of the trimmed ceramic material blank until the mixed solution is effectively adsorbed on the inner surface of the blank and does not have a sagging state;
step 4): and (3) firing, namely placing the trimmed ceramic material blank into a kiln to fire and form, wherein the firing temperature is 1350 ℃, and the firing time is 36 hours, so as to obtain a ceramic material finished product.
The process is especially suitable for firing the thin-wall ceramic, and the thin-wall ceramic with a blank of 1.5mm is obtained after one-time firing. And 3) secondarily spraying and supplementing a water-soluble mixed solution of the PAC (active element) material on the inner surface of the blank, so that the content of the whole active element material, especially the content of the inner surface, is improved, the actual use and experience effects are improved, and the supplement can be carried out under the condition that the forming strength of the blank can be ensured after the blank is formed.
The thin-core porcelain is also called 'tyre-removed porcelain' and 'eggshell porcelain', and is one of the long-standing special craft products in famous traditional porcelain varieties. The thin-body porcelain is characterized by that its porcelain body is thin, like egg shell, and its light-transmitting body is made up by using pure glaze. The green body of the thin-body porcelain is thin and low in strength, and is very easy to break and deform in the manufacturing process, and the manufacturing process comprises the steps of batching, blank drawing, blank trimming (fettling), glazing, drawing and firing, and is finished by four or more processes, and all the processes are manually fired for three times.
As a modification, in step 3, the blank is trimmed to a surface thickness of 1.8 mm.
PAC (active element) technical and technological materials are additionally arranged on the inner surface of the thin-blank ceramic liner, the materials contain a large amount of active element substances, the materials are sprayed on the thin-blank ceramic liner and then processed into finished products, so that the function of releasing negative oxygen ions by the liner is increased, the effect of grouping macromolecules in drinks is promoted, and the bitter and astringent feelings in tea soup and other drinks can be effectively removed; the design is simple and elegant, the structure of thin-tube ceramic is adopted, the high-temperature firing is exquisite in shape, and the work is delicate; the inner container adopts a vacuum structure, and in addition, the function of continuously releasing negative oxygen ions effectively realizes the antibacterial and purifying effect, is suitable for infusing various beverages such as tea soup, milk, coffee and the like, and effectively improves the taste.
The technical scheme adopted by the invention has the beneficial effects that: the one-time firing ceramic material process provided by the invention is suitable for manufacturing processes of various ceramic materials, especially for porcelain materials, and is particularly suitable for manufacturing and processing of thin-body ceramics, the raw material component parameters of the traditional thin-body ceramics are improved, the toughness and the adhesion of the clay are increased through the original improvement, the forming is facilitated, the finished product has good shaping, the ductility, the plasticity and the stability are improved, the production yield of the thin-body ceramics is improved, and in addition, the light transmission effect of the thin-body ceramics is good; the invention solves the process problems of manual blank drawing, glazing and multiple firing in the prior art, and has good molding state and quality and effectively improved yield through the grouting process. The preparation process of the thin-body porcelain provides a brand-new thin-body porcelain and a manufacturing process thereof, has positive significance for promoting the development of thin-body porcelain products, and has positive economic benefits.
Detailed Description
A ceramic material processing technology comprises the following steps:
step 1): processing and pulping, wherein the raw material components of the ceramic material comprise 18 parts by mass of kaolin, 20 parts by mass of feldspar, 18 parts by mass of quartz, 25 parts by mass of agate crystal, 3 parts by mass of rare earth and 2 parts by mass of PAC (active element) material, screening, removing impurities, cleaning and air-drying, then crushing, ball-milling and adding water to prepare slurry, wet ball-milling is carried out for 48 hours, and in the ball-milling procedure, the mass parts of the material, the ball and the water are 1: 3: 1.2;
step 2): processing and making a blank, namely preparing a product blank by using the slurry prepared in the step 1 and adopting a grouting processing technology, coating a layer of talcum powder in a cavity of a grouting mould before grouting, wherein the thickness of the blank is 1mm, and after grouting, rapidly cooling the blank by adopting a blowing cooling process until the blank is molded and forms a gap of 0.2mm with an inner cavity of the mould, wherein the air flow rate of blowing is 4m/S, and an air injection port is aligned with the position where the blank is attached to the inner wall of the mould;
step 3): processing and trimming, namely placing a ceramic material blank on a trimming machine for trimming, and spraying a PAC (active element) active material water mixed solution on the inner surface of the trimmed ceramic material blank until the mixed solution is effectively adsorbed on the inner surface of the blank and does not have a sagging state;
step 4): and (3) firing, namely placing the trimmed ceramic material blank into a kiln to fire and form, wherein the firing temperature is 1350 ℃, and the firing time is 36 hours, so as to obtain a ceramic material finished product.
The product which is preferentially adapted to the operation flow of the process, namely the thin-tube ceramic finished product, is selected, and the performance of the finished product is tested as follows.
Through experimental tests, the thickness of the blank is 2mm, the thickness of the blank is 1.8mm after trimming, and the thickness of the blank is 1.5mm after sintering, and the process forms a sintered product, and in practical tests, the process comprises the following groups:
reference group: the thickness of the blank is 2mm, the blank is 1.8mm after finishing and 1.5mm after sintering;
one group, 2.2mm of blank, 2.0 mm after finishing and 1.8mm after firing;
two groups, the blank is 1.8mm, the blank is 1.5mm after finishing and 1.3mm after sintering;
three groups, the blank is 1.6mm, 1.2 mm after finishing and 1mm after sintering;
hardness of Smoothness fluctuation Degree of gloss
A group of Mohs hardness 3.1 0.2% 95 degree
Two groups are Mohs hardness 3.3 0.21% 98 degree
Three groups Mohs hardness 3.2 0.22% 92 degree
Reference group Mohs hardness 3.6 0.16% 104 degree
The reference group of the present example process had the best hardness, the best surface smoothness, the lowest firing deformation amplitude and the best gloss. The technological parameters, flow and material composition are matched to the optimal sintering effect.
Taking the prepared thin-tube ceramic inner container for experimental test:
1) and detecting the release amount of negative ions: the opening of the thin-tire ceramic inner container is placed upwards stably, cold air of a blower blows the inner container for 10 seconds, original gas in the inner container is discharged, the inner container is kept stand for 5 minutes, the ambient temperature is 22.4 ℃, the ambient relative humidity is 36%, then a detector of the solid negative ion detector is tightly attached to the opening of the inner container to be tested by using the solid negative ion detector, and the real-time release density of negative ions is measured: 2479 pieces/s.cm2
2) And anti-mildew property
The detection method HG/T3950-2007 has the following detection results:
detecting items Grade of mold growth
Anti-mould performance 0
Description of the drawings: rating standard: grade 0-no-length, i.e., no growth observed under microscope (50 x magnification); level 1-trace growth, i.e. growth visible to the naked eye, but growth coverage area is less than 10%; level 2-growth coverage is greater than 10%.
3) And antibacterial property
The detection method JC/T897-2014 has the following detection results:
Figure BDA0002951167780000061
4) superconducting nuclear magnetic resonance (small molecule detection)
The main instruments used Superconducting nuclear magnetic resonance spectrometer Bruker400MHZ
Instrument numbering 1002875
Detecting items Oxygen spectrum
Basis of detection Nuclear magnetic resonance spectroscopy (NMR) of the fourth part 0441 of the "Chinese pharmacopoeia" 2015 edition
The sample detection information and results are as follows:
Figure BDA0002951167780000062
Figure BDA0002951167780000071
the finished product prepared by the process is obviously improved in both health use function and product stability.
Other embodiments of the present invention than the preferred embodiments described above will be apparent to those skilled in the art from the present invention, and various changes and modifications can be made therein without departing from the spirit of the present invention as defined in the appended claims.

Claims (5)

1. A ceramic material characterized by: comprises ceramic processing basic raw material, PAC (active element) material and water.
2. A ceramic material according to claim 1, characterized in that: the ceramic processing base raw material comprises 18 parts of kaolin, 20 parts of feldspar, 18 parts of quartz, 25 parts of agate crystal and 3 parts of rare earth in parts by mass.
3. A ceramic material according to claim 1, characterized in that: the PAC (active element) material comprises a seaweed extract capable of dispersing large-cluster molecules, and is prepared by fermenting a seaweed stock solution, trace elements such as sodium, potassium, calcium, magnesium, phosphorus and iron, and a composite solution of vitamin A, vitamin D, vitamin B1, vitamin B2, folic acid, nicotinic acid and pantothenic acid by a flora, wherein the fermentation flora is a flora consisting of at least two of lactobacillus plantarum, aspergillus niger, rhizopus, plant yeast and selenium-enriched yeast.
4. The process according to claim 1, wherein: the method comprises the following steps: step 1): processing and pulping, wherein the raw material components of the ceramic material comprise 18 parts by mass of kaolin, 20 parts by mass of feldspar, 18 parts by mass of quartz, 25 parts by mass of agate crystal, 3 parts by mass of rare earth and 2 parts by mass of PAC (active element) material, screening, removing impurities, cleaning and air-drying, then crushing, ball-milling and adding water to prepare slurry, wet ball-milling is carried out for 48 hours, and in the ball-milling procedure, the mass parts of the material, the ball and the water are 1: 3: 1.2; step 2): processing and making a blank, namely preparing a product blank by using the slurry prepared in the step 1 and adopting a grouting processing technology, coating a layer of talcum powder in a cavity of a grouting mould before grouting, wherein the thickness of the blank is 2mm, and after grouting, rapidly cooling the blank by adopting a blowing cooling process until the blank is molded and forms a gap of 0.2mm with an inner cavity of the mould, wherein the air flow rate of blowing is 4m/S, and an air injection port is aligned with the position where the blank is attached to the inner wall of the mould; step 3): processing and trimming, namely placing a ceramic material blank on a trimming machine for trimming, and spraying a water mixed solution of a PAC (active element) material on the inner surface of the trimmed ceramic material blank until the mixed solution is effectively adsorbed on the inner surface of the blank and does not have a sagging state; step 4): and (3) firing, namely placing the trimmed ceramic material blank into a kiln to fire and form, wherein the firing temperature is 1350 ℃, and the firing time is 36 hours, so as to obtain a ceramic material finished product.
5. The process according to claim 4, wherein: and in the step 3, trimming the blank to the surface thickness of 1.8 mm.
CN202110206786.2A 2021-02-24 2021-02-24 Ceramic material and processing method thereof Pending CN113121213A (en)

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