CN107986747B - Natural crack ceramic product decorated by unglazed glaze and manufacturing process thereof - Google Patents

Natural crack ceramic product decorated by unglazed glaze and manufacturing process thereof Download PDF

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CN107986747B
CN107986747B CN201711029685.2A CN201711029685A CN107986747B CN 107986747 B CN107986747 B CN 107986747B CN 201711029685 A CN201711029685 A CN 201711029685A CN 107986747 B CN107986747 B CN 107986747B
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ceramic
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unglazed
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CN107986747A (en
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颜松疆
颜晓杰
陈乙坤
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Fujian Dehua Hengsheng Ceramics Co ltd
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Fujian Dehua Hengsheng Ceramics Co ltd
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5037Clay, Kaolin
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    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
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    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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Abstract

The invention relates to the technical field of ceramic manufacturing, in particular to a natural crack ceramic product decorated by unglazed glaze and a manufacturing process thereof. The blank raw materials of the natural crack ceramic product decorated by the unglazed glaze comprise: laterite, feldspar, black clay, quartz, spodumene, kaolin and ferric oxide. The glaze-free decorated natural crack ceramic product provided by the invention has the advantages that the surface is not decorated by glaze water, a rough green body is exposed, natural cracks are formed on the surface of the ceramic green body, the cracked lines are deeply inserted into the ceramic green body, the effect similar to corrosion is realized, and the texture effect is attractive; when the natural crack ceramic product decorated by the unglazed glaze is manufactured, the natural crack of the surface of the blank is caused by different internal and external contraction, but the crack does not penetrate through the ceramic blank and does not influence the normal use of the ceramic product.

Description

Natural crack ceramic product decorated by unglazed glaze and manufacturing process thereof
Technical Field
The invention relates to the technical field of ceramic manufacturing, in particular to a natural crack ceramic product decorated by unglazed glaze and a manufacturing process thereof.
Background
Along with the continuous improvement of the living standard of people, the aesthetic requirements are also continuously changed, the traditional method for improving the shape or pattern of the ceramic product in a small way cannot break through the existing design level, lacks innovation, and is difficult to adapt to the requirements of consumers for new and changed.
In order to solve the problems, ceramic decorations with various crack effects appear on the market, such as a manufacturing method of a ceramic product with a crack glaze surface disclosed by application publication No. CN102503565A, a preparation method of a color crack ceramic disclosed by application publication No. CN 105906211A, a low-temperature crack glaze disclosed by application publication No. CN105294173A, a low-temperature crack glaze ceramic product prepared by the low-temperature crack glaze ceramic product, a preparation method and the like; the ceramic surface is decorated by the glaze effect of the cracks.
The ceramic surface decorated by the existing cracks is decorated by cracking the glaze surface, fine cracks are formed on the glaze layer, the ceramic product has a specific artistic effect and is favored by people, the forming mechanism is that the expansion coefficient of the glaze is larger than that of the blank, when the ceramic is cooled, the shrinkage of the glaze is larger than that of the blank, so that the cracking of the glaze layer is caused, the difference value of the shrinkage is larger, and the cracking degree is larger; the less elastic the glaze, the greater the cracking. The surface cracking provides a brand-new ceramic decoration method, but the effect of cracking only the glaze surface lacks the stereoscopic impression, so the effect of cracking only the glaze surface at present needs to be further improved.
Disclosure of Invention
In order to solve the defects of the prior art, the invention provides a natural crack ceramic product decorated by unglazed glaze and a manufacturing process thereof.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows: the glaze-free decorated natural crack ceramic product is characterized in that the blank raw material components of the glaze-free decorated natural crack ceramic product are as follows: 35-45 parts of laterite, 15-20 parts of feldspar, 10-15 parts of black clay, 10-15 parts of quartz, 5-10 parts of spodumene, 5-10 parts of kaolin and 1-5 parts of ferric oxide.
Preferably, the blank raw material components of the natural crack ceramic product decorated by the unglazed glaze are as follows: 37 parts of laterite, 20 parts of feldspar, 15 parts of black clay, 13 parts of quartz, 6 parts of spodumene, 7 parts of kaolin and 2 parts of ferric oxide.
Preferably, the blank raw material components of the natural crack ceramic product decorated by the unglazed glaze are as follows: 41 parts of laterite, 18 parts of feldspar, 13 parts of black clay, 12 parts of quartz, 7 parts of spodumene, 6 parts of kaolin and 3 parts of ferric oxide.
Preferably, the blank raw material components of the natural crack ceramic product decorated by the unglazed glaze are as follows: 42 parts of laterite, 16 parts of feldspar, 12 parts of black clay, 11 parts of quartz, 8 parts of spodumene, 7 parts of kaolin and 4 parts of ferric oxide.
A manufacturing process of a natural crack ceramic product decorated by unglazed glaze comprises the following specific steps:
step 1, preparing biscuit powder, wherein the grain size of the biscuit powder is 0.3-0.5 mm;
step 2, preparing blank slurry according to the raw material components of the natural crack ceramic product decorated by the unglazed glaze;
step 3, preparing the blank slurry prepared in the step 2 into a ceramic blank;
step 4, when the water content of the ceramic blank body is 30-45%, scattering the biscuit powder prepared in the step 1 on the ceramic blank body;
and 5, after the water content of the ceramic blank is 3-5%, putting the ceramic blank into a kiln for sintering and forming, wherein the sintering temperature is 1150 +/-50 ℃.
Further, the raw material components of the biscuit powder in the step 1 are as follows: 45-50 parts of kaolin, 20-30 parts of quartz, 15-20 parts of dolomite, 5-10 parts of feldspar and 1-5 parts of zirconia.
Further, the raw material components of the biscuit powder are as follows: 48 parts of kaolin, 22 parts of quartz, 17 parts of dolomite, 9 parts of feldspar and 4 parts of zirconia.
Further, in step 1, the specific steps of preparing the biscuit powder are as follows:
s1, weighing and mixing the raw material components according to the biscuit powder, adding water and performing ball milling to obtain slurry;
s2, uniformly stirring the slurry, transferring the slurry into a granulator, starting the granulator to granulate, and preparing biscuit particles through the granulator;
s3, after drying the biscuit particles, putting the biscuit particles into a kiln to be fired and molded to obtain ceramic particles;
and S4, crushing and sieving the formed ceramic particles to obtain the biscuit powder.
Furthermore, the firing temperature of the ceramic particles is 1200-1250 ℃.
The glaze-free decorated natural crack ceramic product provided by the invention has the advantages that the surface is not decorated by glaze water, a rough green body is exposed, natural cracks are formed on the surface of the ceramic green body, the cracked lines are deeply inserted into the ceramic green body, the effect similar to corrosion is realized, and the texture effect is attractive; when the natural crack ceramic product decorated by the unglazed glaze is manufactured, specific blank raw materials and biscuit powder are selected, so that the ceramic blank has stronger plasticity, the contraction ratio of the ceramic blank to the biscuit powder is within a critical range, when the ceramic blank with high water content is sprinkled with the dried biscuit powder, the ceramic blank is dried and then is fired, the natural cracking of the surface of the blank is caused by the difference of the internal contraction and the external contraction, but the cracks do not penetrate through the ceramic blank and do not influence the normal use of the ceramic product.
Detailed Description
The invention is further described below by means of specific embodiments.
The glaze-free decorated natural crack ceramic product is characterized in that the blank raw material components of the glaze-free decorated natural crack ceramic product are as follows: 35-45 parts of laterite, 15-20 parts of feldspar, 10-15 parts of black clay, 10-15 parts of quartz, 5-10 parts of spodumene, 5-10 parts of kaolin and 1-5 parts of ferric oxide.
The first embodiment is as follows:
the glaze-free decorated natural crack ceramic product comprises the following raw material components: 37 parts of laterite, 20 parts of feldspar, 15 parts of black clay, 13 parts of quartz, 6 parts of spodumene, 7 parts of kaolin and 2 parts of ferric oxide.
The second embodiment is as follows:
the glaze-free decorated natural crack ceramic product comprises the following raw material components: 41 parts of laterite, 18 parts of feldspar, 13 parts of black clay, 12 parts of quartz, 7 parts of spodumene, 6 parts of kaolin and 3 parts of ferric oxide.
The third concrete embodiment:
the glaze-free decorated natural crack ceramic product comprises the following raw material components: 42 parts of laterite, 16 parts of feldspar, 12 parts of black clay, 11 parts of quartz, 8 parts of spodumene, 7 parts of kaolin and 4 parts of ferric oxide.
The manufacturing process of the natural crack ceramic product decorated by the unglazed glaze comprises the following specific steps:
step 1, preparing biscuit powder, wherein the biscuit powder comprises the following raw material components: 45-50 parts of kaolin, 20-30 parts of quartz, 15-20 parts of dolomite, 5-10 parts of feldspar and 1-5 parts of zirconia, preferably 48 parts of kaolin, 22 parts of quartz, 17 parts of dolomite, 9 parts of feldspar and 4 parts of zirconia,
s1, weighing and mixing the raw material components according to the biscuit powder, adding water and ball milling to prepare slurry,
s2, uniformly stirring the slurry, transferring the slurry into a granulator, starting the granulator to granulate, preparing biscuit particles through the granulator,
s3, after drying the biscuit particles, putting the biscuit particles into a kiln to be fired and molded at 1200-1250 ℃ to obtain ceramic particles,
s4, crushing and sieving the formed ceramic particles to obtain biscuit powder with the particle size of 0.3-0.5 mm;
step 2, preparing blank slurry according to the raw material components of the natural crack ceramic product decorated by the unglazed glaze;
step 3, preparing the blank slurry prepared in the step 2 into a ceramic blank;
step 4, when the water content of the ceramic blank body is 30-45%, scattering the biscuit powder prepared in the step 1 on the ceramic blank body;
and 5, after the water content of the ceramic blank is 3-5%, putting the ceramic blank into a kiln for sintering and forming, wherein the sintering temperature is 1150 +/-50 ℃.
The natural crack ceramic product decorated by the unglazed glaze prepared by the method has the advantages that the surface is not decorated by glaze water, a rough green body is exposed, natural cracks are formed on the surface of the ceramic green body, the cracked lines are deeply inserted into the ceramic green body, the effect similar to corrosion is achieved, and the texture effect is attractive; when the natural crack ceramic product decorated by the unglazed glaze is manufactured, specific blank raw materials and biscuit powder are selected, so that the ceramic blank has stronger plasticity, the contraction ratio of the ceramic blank to the biscuit powder is within a critical range, when the ceramic blank with high water content is sprinkled with the dried biscuit powder, the ceramic blank is dried and then is fired, the natural cracking of the surface of the blank is caused by the difference of the internal contraction and the external contraction, but the cracks do not penetrate through the ceramic blank and do not influence the normal use of the ceramic product.
The above description is only an embodiment of the present invention, but the design concept of the present invention is not limited thereto, and any insubstantial modifications made by using the design concept should fall within the scope of infringing the present invention.

Claims (6)

1. The glaze-free decorated natural crack ceramic product is characterized in that the blank raw material components of the glaze-free decorated natural crack ceramic product are as follows: 35-45 parts of laterite, 15-20 parts of feldspar, 10-15 parts of black clay, 10-15 parts of quartz, 5-10 parts of spodumene, 5-10 parts of kaolin and 1-5 parts of ferric oxide;
the manufacturing process of the natural crack ceramic product decorated by the unglazed glaze comprises the following specific steps:
step 1, preparing biscuit powder, wherein the grain diameter of the biscuit powder is 0.3-0.5mm, and the specific steps of the biscuit powder preparation are as follows:
s1, weighing and mixing the raw material components according to the biscuit powder, adding water and ball milling to prepare slurry,
the raw material components of the biscuit powder are as follows: 45-50 parts of kaolin, 20-30 parts of quartz, 15-20 parts of dolomite, 5-10 parts of feldspar and 1-5 parts of zirconia;
s2, uniformly stirring the slurry, transferring the slurry into a granulator, starting the granulator to granulate, and preparing biscuit particles through the granulator;
s3, after drying the biscuit particles, putting the biscuit particles into a kiln to be fired and molded to obtain ceramic particles;
s4, crushing and sieving the formed ceramic particles to obtain biscuit powder;
step 2, preparing blank slurry according to the raw material components of the natural crack ceramic product decorated by the unglazed glaze;
step 3, preparing the blank slurry prepared in the step 2 into a ceramic blank;
step 4, when the water content of the ceramic blank body is 30-45%, scattering the biscuit powder prepared in the step 1 on the ceramic blank body;
and 5, after the water content of the ceramic blank is 3-5%, putting the ceramic blank into a kiln for sintering and forming, wherein the sintering temperature is 1150 +/-50 ℃.
2. The unglazed decorated natural crack ceramic article according to claim 1, wherein the blank raw material composition of the unglazed decorated natural crack ceramic article is as follows: 37 parts of laterite, 20 parts of feldspar, 15 parts of black clay, 13 parts of quartz, 6 parts of spodumene, 7 parts of kaolin and 2 parts of ferric oxide.
3. The unglazed decorated natural crack ceramic article according to claim 1, wherein the blank raw material composition of the unglazed decorated natural crack ceramic article is as follows: 41 parts of laterite, 18 parts of feldspar, 13 parts of black clay, 12 parts of quartz, 7 parts of spodumene, 6 parts of kaolin and 3 parts of ferric oxide.
4. The unglazed decorated natural crack ceramic article according to claim 1, wherein the blank raw material composition of the unglazed decorated natural crack ceramic article is as follows: 42 parts of laterite, 16 parts of feldspar, 12 parts of black clay, 11 parts of quartz, 8 parts of spodumene, 7 parts of kaolin and 4 parts of ferric oxide.
5. The unglazed decorated natural crack ceramic article according to claim 1, wherein the raw material composition of the green body powder is as follows: 48 parts of kaolin, 22 parts of quartz, 17 parts of dolomite, 9 parts of feldspar and 4 parts of zirconia.
6. The unglazed decorated natural crack ceramic article according to claim 1, wherein the firing temperature of the ceramic particles is 1200-1250 ℃.
CN201711029685.2A 2017-10-30 2017-10-30 Natural crack ceramic product decorated by unglazed glaze and manufacturing process thereof Active CN107986747B (en)

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CN113045289B (en) * 2018-10-27 2022-08-05 福建省德化县冠鸿陶瓷有限公司 High-permeability colored permeable layer for ceramic products and method for making same
CN111978068A (en) * 2020-08-31 2020-11-24 福建省德化中发陶瓷有限公司 Open crack thick glaze white porcelain and manufacturing process thereof
CN113292311B (en) * 2021-05-20 2023-01-24 福建省德化十斗金工艺有限公司 Manual blank white porcelain crack-blasting thick-glaze porcelain and preparation method thereof
CN113480175B (en) * 2021-08-20 2022-10-14 德化县顺尔美工艺品有限公司 Lichen mottled glaze ceramic and preparation method thereof

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Publication number Priority date Publication date Assignee Title
JP2000128668A (en) * 1998-10-20 2000-05-09 Hagumu Fukami Manifestation of crackle pattern on ceramic ware
CN101269947A (en) * 2008-04-28 2008-09-24 丁绍杰 Celadon cracked-ice pattern tire bone and glaze material, production method for products produced thereof
CN104150873A (en) * 2014-08-25 2014-11-19 龙泉市尚唐瓷艺发展有限公司 Longquan celadon crackle glaze wine bottle and preparation method thereof
CN105906211A (en) * 2016-03-26 2016-08-31 景德镇陶瓷学院 Preparation method for colored crackle ceramic
CN106007663A (en) * 2016-05-24 2016-10-12 福建冠福实业有限公司 Unglazed high-density bright crystal ceramic and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000128668A (en) * 1998-10-20 2000-05-09 Hagumu Fukami Manifestation of crackle pattern on ceramic ware
CN101269947A (en) * 2008-04-28 2008-09-24 丁绍杰 Celadon cracked-ice pattern tire bone and glaze material, production method for products produced thereof
CN104150873A (en) * 2014-08-25 2014-11-19 龙泉市尚唐瓷艺发展有限公司 Longquan celadon crackle glaze wine bottle and preparation method thereof
CN105906211A (en) * 2016-03-26 2016-08-31 景德镇陶瓷学院 Preparation method for colored crackle ceramic
CN106007663A (en) * 2016-05-24 2016-10-12 福建冠福实业有限公司 Unglazed high-density bright crystal ceramic and preparation method thereof

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