CN113120891A - Two-dimensional material transfer equipment - Google Patents

Two-dimensional material transfer equipment Download PDF

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Publication number
CN113120891A
CN113120891A CN202110387097.6A CN202110387097A CN113120891A CN 113120891 A CN113120891 A CN 113120891A CN 202110387097 A CN202110387097 A CN 202110387097A CN 113120891 A CN113120891 A CN 113120891A
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film
hot
dimensional material
target
melt adhesive
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钟国仿
杨方
陈炳安
肖蕴章
李小天
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Shenzhen Nashi Intelligent Equipment Co ltd
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Shenzhen Nashi Intelligent Equipment Co ltd
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • C01B32/194After-treatment

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  • Organic Chemistry (AREA)
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  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The invention provides two-dimensional material transfer equipment, relates to the technical field of two-dimensional materials, and comprises the following components: blowing device, hot press unit, separator, cleaning device, drying device and material collecting device, can be with the characteristic of two-dimensional material separation from the metal film through separator, make originally grow on the two-dimensional material on the metal film shifts to the target film on, clean and dry the target film that is attached with two-dimensional material respectively, make it satisfy the requirement of collecting, through the blowing, hot pressing, separation, it is clean, the operation of dry and receipts material can form the automation line that two-dimensional material shifted, and then realize the promotion of efficiency and productivity, and simultaneously, also can reduction in production cost, save equipment area occupied.

Description

Two-dimensional material transfer equipment
Technical Field
The invention relates to the technical field of two-dimensional materials, in particular to two-dimensional material transfer equipment.
Background
With the hot trends in research brought about by the discovery of graphene, a large group of novel two-dimensional materials, including but not limited to graphene, hexagonal boron nitride (h-BN), transition metal chalcogenides (TMDs), can be currently prepared by Chemical Vapor Deposition (CVD) techniques. Since the prerequisite for the application of two-dimensional materials is to transfer the two-dimensional materials first and then to use the two-dimensional materials, how to transfer the two-dimensional materials on a large scale is a focus of attention in the industry.
The existing two-dimensional material transfer method can only realize single-side manual transfer of two-dimensional materials, and the transfer efficiency is low.
Disclosure of Invention
The invention aims to provide two-dimensional material transfer equipment aiming at the defects in the prior art, so as to solve the problems of low efficiency and low capacity when the conventional two-dimensional material is transferred on one side manually.
In order to achieve the above purpose, the embodiment of the present invention adopts the following technical solutions:
in one aspect of the embodiments of the present invention, there is provided a two-dimensional material transfer apparatus, including: the device comprises a feeding device, a hot-pressing device, a separating device, a cleaning device, a drying device and a receiving device; the feeding device respectively conveys a metal film with two-dimensional materials growing on at least one surface and a target film to the hot pressing device, and the target film corresponds to the surface of the metal film with the two-dimensional materials growing on the target film; the hot-pressing device is used for hot-pressing the target thin film and one surface of the metal thin film on which the two-dimensional material grows to form a composite thin film and conveying the composite thin film to the separation device; the separating device is used for separating the composite film so as to transfer the two-dimensional material on the metal film to the target film and conveying the target film attached with the two-dimensional material to the cleaning device; the cleaning device is used for cleaning the target film attached with the two-dimensional material and conveying the target film attached with the two-dimensional material to the drying device; the drying device is used for drying the target film attached with the two-dimensional material and conveying the dried target film attached with the two-dimensional material to the material receiving device; the material receiving device is used for collecting the target film attached with the two-dimensional material.
Optionally, the discharging device comprises a raw material discharging mechanism and a first discharging mechanism; the raw materials drop feed mechanism conveys to hot-pressing device at least one side and grows the metal film that has the two-dimensional material, and first drop feed mechanism conveys to hot-pressing device and has coated the first target film of hot melt adhesive, and the one side that first target film coated with hot melt adhesive corresponds with the one side that metal film grows to have the two-dimensional material.
Optionally, the material discharging device comprises a raw material discharging mechanism, a first hot melt adhesive discharging mechanism and a first discharging mechanism; the raw materials drop feed mechanism conveys the metal film that at least one side grows to the hot-pressing device and has the two-dimensional material, and first drop feed mechanism conveys first target film to the hot-pressing device, and first hot melt adhesive drop feed mechanism conveys first hot melt adhesive film to the hot-pressing device, and the one side that the metal film grows to have the two-dimensional material corresponds the one side of first target film and first hot melt adhesive film is located between first target film and the metal film.
Optionally, the discharging device comprises a raw material discharging mechanism, a first discharging mechanism and a second discharging mechanism; the raw material feeding mechanism conveys metal films with two-dimensional materials growing on two sides to the hot pressing device, and the first feeding mechanism and the second feeding mechanism convey a first target film coated with hot melt adhesive and a second target film coated with hot melt adhesive to the hot pressing device respectively; one side of the first target film coated with the hot melt adhesive corresponds to one side of the metal film, and one side of the second target film coated with the hot melt adhesive corresponds to the other side of the metal film.
Optionally, the material discharging device comprises a raw material discharging mechanism, a first hot melt adhesive discharging mechanism, a second hot melt adhesive discharging mechanism, a first discharging mechanism and a second discharging mechanism; the raw material feeding mechanism conveys metal films with two-dimensional materials growing on two sides to the hot pressing device, and the first feeding mechanism and the second feeding mechanism convey a first target film and a second target film to the hot pressing device respectively; the first target film and the second target film are respectively positioned at two sides of the metal film, and the first hot melt adhesive discharging mechanism and the second hot melt adhesive discharging mechanism respectively convey the first hot melt adhesive film and the second hot melt adhesive film to the hot pressing device and are respectively bounded between the first target film and the metal film and between the second target film and the metal film.
Optionally, the discharging device comprises a raw material discharging mechanism, a first hot melt adhesive discharging mechanism, a first discharging mechanism and a second discharging mechanism; the two sides of a raw material feeding mechanism are provided with metal films with two-dimensional materials, the two sides of the metal films are provided with the two-dimensional materials, a first feeding mechanism feeds a first target film to the hot-pressing device, a second feeding mechanism feeds a second target film coated with hot melt adhesive to the hot-pressing device, the first target film and the second target film are respectively positioned on two sides of the metal films, the first hot melt adhesive feeding mechanism feeds the first hot melt adhesive film to the hot-pressing device and is between the first target film and the metal films, and one side of the second target film coated with the hot melt adhesive corresponds to the metal films.
Optionally, the raw material discharging mechanism comprises a raw material roller provided with a metal film coiled material, and the first discharging mechanism comprises a first roller provided with a first target film coiled material.
Optionally, the hot pressing device includes a hot pressing driver, a heating mechanism, and a first hot pressing roller and a second hot pressing roller which are arranged oppositely, and the heating mechanism is connected to at least one of the first hot pressing roller and the second hot pressing roller; the hot pressing driver is in driving connection with at least one of the first hot pressing roller wheel and the second hot pressing roller wheel and is used for driving the first hot pressing roller wheel and the second hot pressing roller wheel to be close to or far away from each other.
Optionally, the hot-pressing device further comprises a controller and a temperature sensor electrically connected with the controller, and the heating mechanism is electrically connected with the controller; the temperature sensor is used for collecting the temperature information of at least one of the first hot-pressing roller and the second hot-pressing roller and controlling the heating mechanism according to the temperature information, so that the control of the hot-pressing temperature is realized.
Optionally, the hot-pressing device further comprises a controller and a pressure sensor electrically connected with the controller; the pressure sensor is used for collecting pressure information between the first hot-pressing roller and the second hot-pressing roller and controlling the action of the hot-pressing driver according to the pressure information, so that the control of hot-pressing pressure is realized.
Optionally, the hot pressing device further includes a rotational speed driver, the rotational speed driver is in driving connection with at least one of the first hot pressing roller and the second hot pressing roller, and the rotational speed driver is used for adjusting the rotational speed of at least one of the first hot pressing roller and the second hot pressing roller.
Optionally, a rubber layer is disposed on a surface of at least one of the first hot press roller and the second hot press roller.
Optionally, the separation device comprises an electrolytic cell containing electrolyte, and a first separation roller, a second separation roller and an anode piece which are positioned in the electrolyte; the first separating roller and the second separating roller are respectively positioned at two opposite sides of the composite film to extrude the composite film, the anode piece is used as an anode, the metal film in the composite film is used as a cathode, the metal film in the composite film is separated from the two-dimensional material in an electrochemical bubbling mode, namely, a mode of bubbling hydrogen bubbles between the metal film and the two-dimensional material through electrolyzed water, and the first target film attached with the two-dimensional material is conveyed to a cleaning device through the first separating roller.
Optionally, the separating device further comprises a separating driver, and the separating driver is in driving connection with at least one of the first separating roller and the second separating roller and is used for driving the first separating roller and the second separating roller to approach or move away from each other.
Optionally, the receiving device includes a receiving roller for receiving the target film with the two-dimensional material attached thereto into a roll.
Optionally, the raw material discharging mechanism is a chemical vapor deposition device, and the chemical vapor deposition device is used for depositing a two-dimensional material on the surface of the metal film and conveying the metal film with the two-dimensional material grown on the surface to the hot pressing device.
Optionally, the receiving device is a two-dimensional material processing device, and the two-dimensional material processing device is used for processing the target film which is attached with the two-dimensional material after drying.
Optionally, the three devices, i.e., the open chemical vapor deposition device, the two-dimensional material transfer device and the two-dimensional material processing device, may form a production line in the above manner, so as to realize one-line automated production of growth, transfer and processing of the two-dimensional material.
Optionally, the discharging device, the hot pressing device, the separating device, the cleaning device, the drying device and the receiving device are arranged inside and between the discharging device, the hot pressing device, the separating device, the cleaning device, the drying device and the receiving device, the discharging device further comprises a guide roller and a tensioning roller, the guide roller is used for guiding the metal film, the target film and the composite film, and the tensioning roller is used for tensioning the metal film, the target film and the composite film.
Optionally, the two-dimensional material transfer apparatus further includes a deviation correcting device, and the deviation correcting device is used for correcting transmission of the metal film, the target film and the target film with the surface to which the two-dimensional material is attached.
Optionally, the separation device is further configured to convey the transferred metal thin film to the cleaning device; the cleaning device is also used for cleaning the metal film and conveying the cleaned metal film to the drying device; the drying device is also used for drying the metal film and conveying the dried metal film to the material receiving device.
The beneficial effects of the invention include:
the present invention provides a two-dimensional material transfer apparatus comprising: the feeding device, the hot pressing device, the separating device, the cleaning device, the drying device and the receiving device, wherein the feeding device can provide a target film and a metal film with at least one surface growing with a two-dimensional material, the metal film and the target film are conveyed to the hot pressing device, the hot pressing device presses the metal film and the target film to form a composite film, the composite film is conveyed to the separating device, the characteristic that the two-dimensional material can be separated from the metal film through the separating device is realized, the two-dimensional material originally attached to at least one surface of the metal film is transferred to the target film, the transfer of the two-dimensional material is realized, the target film attached with the two-dimensional material can be respectively cleaned, dried and received through the subsequent cleaning device and the subsequent drying device, the collection requirement is met, and an automatic production line for transferring the two-dimensional material can be formed through the operations of feeding, hot pressing, separation, cleaning, and then realize the promotion of efficiency and productivity, simultaneously, also can reduce manufacturing cost, save equipment area occupied. In addition, the single-side or double-side transfer process of the two-dimensional material can be correspondingly realized through different situations of the two-dimensional material with the single-side or double-side growing metal film, and the flexible adjustment of productivity of enterprises according to production requirements of different stages is realized. Furthermore, by integrating the two-dimensional material transfer equipment with the chemical vapor deposition equipment and/or the two-dimensional material processing device, a production line integrating growth, transfer, processing or growth, transfer and processing of the two-dimensional material can be formed; the damage and damage to the two-dimensional material caused by the intermediate link under the condition that the two-dimensional material grows, transfers and is processed disjointed are reduced, so that the quality of the transferred two-dimensional material or a two-dimensional material processing product is greatly improved. In addition, the metal film with the two-dimensional material removed from the surface and cleaned and dried can be used as a raw material for growing the two-dimensional material again. The method not only can realize the recycling of the metal film and further reduce the comprehensive cost, but also has better quality by using the two-dimensional material of the recycled metal film chemical vapor deposition according to the report of scientific research documents.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the embodiments will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present invention and therefore should not be considered as limiting the scope, and for those skilled in the art, other related drawings can be obtained according to the drawings without inventive efforts.
Fig. 1 is a schematic diagram of an overall structure of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
fig. 2 is a schematic structural diagram of a spraying device of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
fig. 3 is a schematic structural diagram of an immersion cleaning apparatus of a two-dimensional material transfer device according to an embodiment of the present invention;
fig. 4 is a schematic structural diagram of a drying blower of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
FIG. 5 is a schematic structural diagram of an electrically heated drying bellows of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
FIG. 6 is a schematic structural diagram of an infrared drying bellows of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
FIG. 7 is a schematic structural diagram of a chemical vapor deposition apparatus of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
fig. 8 is a schematic structural diagram of a two-dimensional material processing device of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
fig. 9 is a first schematic view of a single-sided two-dimensional material transfer of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
fig. 10 is a second schematic diagram of a single-sided two-dimensional material transfer of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
fig. 11 is a first schematic diagram of double-sided two-dimensional material transfer of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
fig. 12 is a schematic diagram of a two-sided two-dimensional material transfer of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
fig. 13 is a schematic diagram three of a double-sided two-dimensional material transfer of a two-dimensional material transfer apparatus according to an embodiment of the present invention;
fig. 14 is a schematic diagram of double-sided two-dimensional material transfer of a two-dimensional material transfer apparatus according to an embodiment of the present invention.
Icon: a-a material discharging device; a01-raw material discharging mechanism; a011-metal thin film; a012, namely chemical vapor deposition equipment; a02-a first discharging mechanism; a021-first target film; a03-a first hot melt adhesive discharge mechanism; a031-a first hot melt adhesive film; a04-a second discharging mechanism; a041-second target film; a05-a second hot melt adhesive discharge mechanism; a051-a second hot melt adhesive film; b-a hot-pressing device; b01 — first hot-press roller; b02 — a second hot-press roller; a C-separation device; c01-a first separating roller; c02-second separation roller; c03-anode member; c04-third separation roller; d-a cleaning device; d01-raffinate purge unit; d02-spraying device; d03-immersion type cleaning device; e-a drying device; e01-drying blower; e02-electric heating drying air box; E03-Infrared drying bellows; f-a material receiving device; f01-a first material receiving mechanism; f02-a second material receiving mechanism; f03-a third material receiving mechanism; f04-a release film receiving mechanism; f05-two-dimensional material processing device; g-a guide roller; h-a tension roller; i-deviation correcting device.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. The components of embodiments of the present invention generally described and illustrated in the figures herein may be arranged and designed in a wide variety of different configurations.
Thus, the following detailed description of the embodiments of the present invention, presented in the figures, is not intended to limit the scope of the invention, as claimed, but is merely representative of selected embodiments of the invention. It should be noted that, in the case of no conflict, various features in the embodiments of the present invention may be combined with each other, and the combined embodiments are still within the scope of the present invention.
In the description of the present invention, it should be noted that the terms "first", "second", "third", and the like are used only for distinguishing the description, and are not intended to indicate or imply relative importance.
In the description of the present invention, it should also be noted that, unless otherwise explicitly specified or limited, the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly and may, for example, be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
In one aspect of the embodiments of the present invention, there is provided a two-dimensional material transfer apparatus, as shown in fig. 1, including: the device comprises a feeding device A, a hot pressing device B, a separating device C, a cleaning device D, a drying device E and a receiving device F, wherein the feeding device A can provide a target film (the quantity of the target film can be flexibly set according to the single-sided or double-sided growth of two-dimensional materials of the metal film A011), a metal film A011 with two-dimensional materials grows on at least one side, the metal film A011 and the target film are conveyed to the hot pressing device B, the hot pressing device B presses the target film and the metal film to form a composite film with the metal film A011/the target film, the composite film is conveyed to the separating device C, the characteristic that the two-dimensional materials can be separated from the metal film A011 through the separating device C is realized, the two-dimensional materials originally attached to at least one side of the metal film A011 are transferred to the target film, the transfer of the two-dimensional materials is realized, and the target film attached with the two-dimensional materials can be cleaned and dried through the, the collecting device F collects the target film attached with the two-dimensional material, the target film is convenient to serve as a raw material of a follow-up two-dimensional material processing device F05 (a two-dimensional material element production line), an automatic production line for transferring the two-dimensional material can be formed through operations of discharging, hot pressing, separating, cleaning, drying and collecting, and therefore efficiency and productivity are improved, meanwhile, production cost can be reduced, and occupied area of equipment is saved.
In addition, the single-side or double-side transfer process of the two-dimensional material can be correspondingly realized through different situations of the two-dimensional material grown on the single side and the double side of the metal thin film A011, for example, when the two-dimensional material is grown on the single side of the metal thin film A011, one target thin film can be set as one, and one target thin film corresponds to the side, on which the two-dimensional material is grown, of the metal thin film A011; when two-dimensional materials grow on the two sides of the metal thin film A011, the two target thin films can be set to be two, and the two target thin films can respectively correspond to the two sides of the metal thin film A011, which are grown with the two-dimensional materials, so that enterprises can flexibly adjust productivity according to production requirements of different stages. In the case of single-sided transfer, the level of the composite film may be a target film/two-dimensional material/metal film, and in the case of double-sided transfer, the level of the composite film may be a target film/two-dimensional material/metal film/two-dimensional material/target film.
As shown in fig. 1, the discharging device a can be correspondingly provided with two or more discharging mechanisms according to single-sided transfer or double-sided transfer, that is, discharging of different films is realized through different discharging mechanisms, so that each discharging mechanism can discharge independently, and mutual interference is avoided. Meanwhile, in order to improve convenience of layout, the first discharging mechanism a02 may be disposed at one side of the raw material discharging mechanism a01 during single-side transfer, so that the target thin film and the metal thin film a011 can be made to correspond to each other on the side where the two-dimensional material is grown. In the case of double-sided transfer, the first discharge mechanism a02 and the second discharge mechanism a04 may be located on opposite sides of the raw material discharge mechanism a01, that is, the raw material discharge mechanism a01 may be located between the first discharge mechanism a02 and the second discharge mechanism, so that when the raw material discharge mechanism a01, the first discharge mechanism a02, and the second discharge mechanism a04 respectively convey their respective films to the hot press apparatus B, the first target film a021 may be made to face one side of the metal film a011, and the second target film a041 may be made to face the other side of the metal film a 011.
When the hot-pressing device B receives the target film and the metal film A011, the target film is hot-pressed and attached to the front surface of the metal film A011 through a hot-pressing process, and different composite film forms of the target film/two-dimensional material/metal film or the target film/two-dimensional material/metal film/two-dimensional material/target film can be respectively and correspondingly formed according to the difference of single-side transfer and double-side transfer. The temperature of each film can be improved through the effect of heat conduction through the hot pressing device B, so that the pressing tightness of each film is improved, and the stability of subsequent two-dimensional material transfer is ensured.
After receiving the composite thin film, the separation device C separates the two-dimensional material from the metal thin film a011 by its own separation characteristic, that is, the two-dimensional material grown on the surface of the metal thin film a011 can be separated from the surface of the metal thin film a011 and transferred to the surface of the target thin film.
After the separating device C separates the composite film, the target film with the two-dimensional material attached to the surface thereof is conveyed to the receiving device F, and the receiving device F correspondingly receives and collects the target film with the two-dimensional material attached thereto. The material receiving device F can collect a target film attached with two-dimensional materials by the second material receiving mechanism F02 when the single-side transfer is performed, and can correspondingly collect two target films attached with two-dimensional materials by the second material receiving mechanism F02 and the third material receiving mechanism F03 when the double-side transfer is performed. The receiving device F may further include a first receiving mechanism F01, and the first receiving mechanism F01 collects the metal thin film a011, which is conveyed out of the separating device C and has the surface from which the two-dimensional material is removed, so that the metal thin film is recycled or recovered while the two-dimensional material primary product is output.
The cleaning device is used for cleaning various films generated by the separation device, and comprises a spraying device as shown in FIG. 2 and an immersion cleaning device as shown in FIG. 3; the drying device is used for drying various films cleaned by the cleaning device, and includes, but is not limited to, a drying blower, an electrically heated drying air box, and an infrared drying air box.
Optionally, cleaning device D and drying device E can make the film coiled material after the transfer finally reach the clean, clean and tidy, dry surface, are suitable for long-term storage, satisfy customer's user demand.
As shown in fig. 9 to 14, the cleaning device D may include a residual liquid purging device D01, that is, a plurality of air nozzles are disposed on the front and back sides of the target thin film and the metal thin film a011, and air is blown through the air nozzles to each thin film to blow off the electrolyte remaining on each thin film in the electrolytic cell. As shown in fig. 2, the cleaning device D may include a spray device D02, that is, a plurality of spray nozzles are provided on both sides of the target thin film and the metal thin film a011, and the cleaning liquid is sprayed to each thin film through the spray nozzles to clean the electrolyte remaining on each thin film in the electrolytic cell. As shown in fig. 3, the cleaning device D may also include an immersion cleaning device D03, i.e., a cleaning tank is separately provided, and the cleaning liquid in the cleaning tank is used to clean the electrolyte remaining on each film by allowing each film to pass through the cleaning tank under the driving of the guide roller. In order to improve the cleaning effect, the conveying path of each film in the cleaning pool can be arc-shaped, such as circular arc, S-shaped and the like, and the cleaning liquid in the cleaning pool can be further made to be flowing water. The cleaning solution may be distilled water or deionized water.
As shown in fig. 4, the drying device E may include a drying blower E01, i.e., a plurality of air nozzles disposed on both sides of the target thin film and the metal thin film a011, and the air nozzles blow air to the respective thin films to accelerate the flow rate of air in the vicinity of the respective thin films, thereby increasing the drying rate. As shown in fig. 5, the drying device E may include an electrically heated drying air box E02, i.e., each film is passed through an electrically heated drying air box E02, and the drying speed of each film is accelerated by the heating. As shown in fig. 6, the drying device E may include an infrared drying wind box E03, i.e., each film is made to pass through an infrared drying wind box E03, and the drying speed of each film is accelerated by blowing air and infrared heating.
As shown in fig. 7, any one of the raw material discharge mechanisms a01 in fig. 9 to 14 can be replaced by an open type chemical vapor deposition apparatus a012 according to requirements; the two-dimensional material can be grown on the surface of the metal thin film a011 by the open chemical vapor deposition apparatus a012, and then the metal thin film a011 with the two-dimensional material grown on the surface is conveyed to the thermal compression apparatus B. Therefore, the two-dimensional material transfer equipment and the open type chemical vapor deposition equipment A012 can be integrated to form a production line for two-dimensional material growth and transfer, so that intermediate links of winding, transportation, unfolding and the like of the metal film A011 of the two-dimensional material to be transferred on the surface are reduced, and damage or quality reduction to graphene caused by the intermediate links is avoided. The transport speed of the open chemical vapor deposition apparatus should match the linear speed at which the two-dimensional material is transferred.
As shown in fig. 8, the material receiving device F of the target film having the two-dimensional material attached to the surface thereof shown in fig. 9 to 14 may be replaced with a two-dimensional material processing device F05, for example, a production line for producing two-dimensional material components, as required. The drying device E is used for directly conveying the target film with the two-dimensional material attached to the surface to the two-dimensional material processing device F05, so that the two-dimensional material transfer equipment and a production line for producing two-dimensional material components can be integrated, the integration from the growth and transfer of the two-dimensional material to a full production line for processing is realized, intermediate links of collecting, coiling, transporting, unfolding and the like of the target film with the two-dimensional material are reduced, and the damage or quality reduction of the two-dimensional material caused by the intermediate links is avoided. The conveying speed of the two-dimensional material processing apparatus F05 matches the linear speed at which the two-dimensional material is transferred.
Two-dimensional materials in the present application include, but are not limited to, graphene, hexagonal boron nitride (h-BN), transition metal chalcogenides (TMDs); the target film may be a non-conductive film such as a polyethylene terephthalate (PET) film, a Polyethylene (PE) film, or the like, and the target film may be a multi-layer film (hot melt adhesive/target film) or a single-layer film.
The following description will be made by taking the transfer of graphene grown on the surface of a copper foil to a PET film as an example, and respectively performing single-sided transfer and double-sided transfer in accordance with various cases of whether or not a target film is coated with a hot melt adhesive ethylene-vinyl acetate copolymer (EVA) (the PET film coated with EVA on the surface is expressed as EVA/PET or PET/EVA film):
the first embodiment is as follows: as shown in fig. 9, the metal film a011 is a copper foil with graphene grown on at least one side, and the first target film a021 is an EVA/PET film; the discharging device A comprises a raw material discharging mechanism A01 and a first discharging mechanism A02; raw materials drop feed mechanism A01 carries the copper foil that at least one side grows to hot pressing device B, first drop feed mechanism A02 carries EVA/PET film to hot pressing device B, the EVA face of EVA/PET film corresponds with the one side that the copper foil grows to have the graphite alkene, thus, the copper foil that has graphite alkene and EVA/PET film to at least one side growth carry out the hot pressing under hot pressing device B's effect, thereby form copper foil/graphite alkene/EVA/PET composite film, separator C can make graphite alkene and copper foil separation through the electrochemistry bubbling method, thereby the formation has graphite alkene/EVA/PET's film and the copper foil of graphite alkene has been got rid of on the surface. The graphene/EVA/PET film (or the copper foil with the graphene removed on the surface can be subjected to the same process as required) is cleaned and dried by the cleaning device D and the drying device E respectively, and is collected by the material collecting device F.
Example two: as shown in fig. 10, the metal film a011 is a copper foil with graphene grown on at least one surface thereof, the first target film a021 is a PET film, and the first hot melt adhesive film a031 is an EVA film; the emptying device A comprises a raw material emptying mechanism A01, a first hot melt adhesive emptying mechanism A03 and a first emptying mechanism A02; raw materials drop feed mechanism A01 carries the copper foil that at least one side grows to hot pressing device B has graphite alkene, first drop feed mechanism A02 carries the PET film to hot pressing device B, first hot melt adhesive drop feed mechanism A03 carries the EVA film to hot pressing device B, the one side of PET film and the one side correspondence that the copper foil grows to have graphite alkene and the EVA film is located between PET film and the copper foil, so, carry out the hot pressing with the three under hot pressing device B's effect, thereby form copper foil/graphite alkene/EVA/PET composite film, separator C can make graphite alkene and copper foil separation through the electrochemistry tympanic bulla method, thereby form the film that has graphite alkene/EVA/PET and the copper foil that graphite alkene has been got rid of on the surface. The graphene/EVA/PET film (the copper foil with the surface from which the graphene is removed can be subjected to the same process as required) is cleaned and dried by the cleaning device D and the drying device E respectively, and is collected by the material collecting device F.
Example three: as shown in fig. 11, the metal film a011 is a copper foil with graphene grown on both sides, the first target film a021 is a first EVA/PET film, and the second target film a041 is a second EVA/PET film; the emptying device A comprises a raw material emptying mechanism A01, a first emptying mechanism A02 and a second emptying mechanism A04; the raw material discharging mechanism A01 conveys copper foil with graphene growing on both sides to the hot pressing device B, the first discharging mechanism A02 and the second discharging mechanism A04 convey a first EVA/PET film and a second EVA/PET film to the hot pressing device B from both sides of the copper foil with graphene growing on both sides respectively, when in transportation, attention should be paid so that the EVA surface of the first EVA/PET film corresponds to one surface of the copper foil with graphene grown on both surfaces, the EVA surface of the second EVA/PET film corresponds to the other surface of the copper foil with graphene grown on both surfaces, and thus, the three are hot-pressed under the action of a hot-pressing device B, so that a PET/EVA/graphene/copper foil/graphene/EVA/PET composite film is formed, a separation device C can separate the graphene from the copper foil through an electrochemical bubbling method, thereby forming a copper foil with graphene removed on the surface and two graphene/EVA/PET films. The graphene/EVA/PET film (the copper foil with the surface from which the graphene is removed can be subjected to the same process as required) is cleaned and dried by the cleaning device D and the drying device E respectively, and is collected by the material collecting device F.
Example four: as shown in fig. 12, the metal film a011 is a copper foil with graphene grown on both sides, the first target film a021 is a first PET film, the second target film a041 is a second PET film, the first hot melt adhesive film a031 is a first EVA film, and the second hot melt adhesive film a051 is a second EVA film; the emptying device A comprises a raw material emptying mechanism A01, a first hot melt adhesive emptying mechanism A03, a second hot melt adhesive emptying mechanism A05, a first emptying mechanism A02 and a second emptying mechanism A04; the raw material discharging mechanism A01 conveys copper foil with graphene growing on both sides to the hot pressing device B, the first discharging mechanism A02 and the second discharging mechanism A04 convey a first PET film and a second PET film to the hot pressing device B from both sides of the copper foil with graphene growing on both sides, and the first hot melt adhesive discharging mechanism A03 and the second hot melt adhesive discharging mechanism A05 convey a first EVA film and a second EVA film to the hot pressing device B respectively; wherein, first EVA film is located between first PET film and the two-sided copper foil that has all grown graphene, and the second EVA film is located between second PET film and the two-sided copper foil that has all grown graphene, so, carry out the hot pressing with five films under hot press unit B's effect, thereby form PET/EVA/graphite alkene/copper foil/graphite alkene/EVA/PET composite film, separator C can make graphite alkene and copper foil separation through the electrochemistry bubbling method, thereby form the surface and remove the copper foil and two graphite alkene/EVA/PET films of graphite alkene. The graphene/EVA/PET film (the copper foil with the surface from which the graphene is removed can be subjected to the same process as required) is cleaned and dried by the cleaning device D and the drying device E respectively, and is collected by the material collecting device F.
Example five: as shown in fig. 13, the first hot melt adhesive film a031 is a first EVA film, and the second hot melt adhesive film a051 is a second EVA film; this embodiment is substantially the same as the fourth embodiment, except that: material collecting device F still includes from type membrane receiving agencies F04, and first hot melt adhesive drop feed mechanism A03 carries first EVA film and leaves the type membrane to hot-pressing device B respectively and from type membrane receiving agencies F04, and second hot melt adhesive drop feed mechanism A05 carries second EVA film and leaves the type membrane to hot-pressing device B respectively and from type membrane receiving agencies F04.
Example six: as shown in fig. 14, the metal film a011 is a copper foil with graphene grown on both sides, the first target film a021 is a PET film, the second target film a041 is an EVA/PET film, and the first hot melt adhesive film a031 is an EVA film; the emptying device A comprises a raw material emptying mechanism A01, a first hot melt adhesive emptying mechanism A03, a first emptying mechanism A02 and a second emptying mechanism A04; the raw material discharging mechanism A01 conveys copper foil with graphene growing on both sides to the hot pressing device B, the first discharging mechanism A02 and the second discharging mechanism A04 convey a PET film and an EVA/PET film to the hot pressing device B from both sides of the copper foil with graphene growing on both sides respectively, the first hot melt adhesive discharging mechanism A03 conveys the EVA film to the hot pressing device B and is positioned between the PET film and the copper foil with graphene growing on both sides, the EVA surface of the EVA/PET film corresponds to the other surface of the copper foil with graphene growing on both sides, and thus, the four films are hot-pressed under the action of a hot-pressing device B, so that a PET/EVA/graphene/copper foil/graphene/EVA/PET composite film is formed, a separation device C can separate the graphene from the copper foil through an electrochemical bubbling method, thereby forming a copper foil with graphene removed on the surface and two graphene/EVA/PET films. The graphene/EVA/PET film (the copper foil with the surface from which the graphene is removed can be subjected to the same process as required) is cleaned and dried by the cleaning device D and the drying device E respectively, and is collected by the material collecting device F.
In the above embodiments, fig. 9 to 14 also show a deviation correcting device I, a tension roller H and a residual liquid blowing device D01; the deviation correcting device is used for correcting and aligning various films conveyed to the hot pressing device B and various films conveyed to the material receiving device F.
As shown in fig. 9 to 14, in different embodiments of the present application, the raw material discharging mechanism a01 includes a raw material roller that can be provided with a copper foil coil, and the first discharging mechanism a02 includes a first roller that can be provided with a first EVA film coil, as required; as shown in fig. 11 to 14, the second discharging mechanism a04 includes a second roller on which a second EVA film roll may be disposed; as shown in fig. 10, and 12-14, the first hot melt adhesive dispensing mechanism a03 comprises a first hot melt adhesive roll upon which a first hot melt adhesive film a031 web can be disposed; as shown in fig. 12 and 13, the second hot melt adhesive dispensing mechanism a05 comprises a second hot melt adhesive roller upon which a second hot melt adhesive film a051 web can be disposed.
As shown in fig. 9 to 14, the receiving device F may include a receiving roller for collecting and winding the target film to which the two-dimensional material is attached into a roll. In addition, depending on the single-sided or double-sided two-dimensional material transfer, the material receiving device F may also be respectively composed of a first material receiving mechanism F01 and a second material receiving mechanism F02, or a first material receiving mechanism F01, a second material receiving mechanism F02 and a third material receiving mechanism F03, each of which includes a material receiving roller; the first, second and third material receiving mechanisms F are respectively used for collecting and winding the metal thin film a011 with the two-dimensional material removed from the surface and the first and second target thin films a041 with the two-dimensional material attached to the surface, which are dried by the drying device E, on the material receiving roller into a roll. The speed of all the discharging and receiving rollers should be matched with the linear speed of transferring the two-dimensional material.
Alternatively, as shown in fig. 9 to 14, the hot press apparatus B includes a hot press driver, a heating mechanism, and a first hot press roller B01 and a second hot press roller B02 which are oppositely disposed; the hot pressing driver is in driving connection with at least one of the first hot pressing roller B01 and the second hot pressing roller B02 (namely, the hot pressing driver is connected with the first hot pressing roller B01; the hot pressing driver is connected with the second hot pressing roller B02; and the hot pressing driver is connected with the first hot pressing roller B01 and the second hot pressing roller B02); the heating mechanism is integrated with at least one of the first hot-pressing roller B01 and the second hot-pressing roller B02 (i.e., including a heating mechanism integrated with the first hot-pressing roller B01, a heating mechanism integrated with the second hot-pressing roller B02, a heating mechanism integrated with the first hot-pressing roller B01 and the second hot-pressing roller B02), and the temperature of the first hot-pressing roller B01 and/or the second hot-pressing roller B02 is adjusted by the heating mechanism, so that the hot melt adhesive can better bond the first target film and the metal thin film A011 and the second target film and the metal thin film A011. The distance between the first hot-pressing roller B01 and the second hot-pressing roller B02 can be driven by a hot-pressing driver, such as an air cylinder, a motor and the like, when various film raw materials are installed, the two rollers are in a separated state, and all the film raw materials pass through the middle. When the hot-pressing device works normally, the two rollers are tightly extruded together by utilizing the hot-pressing driver, all film raw materials are tightly adhered together through the hot melt adhesive by heating and pressurizing to form a composite film, and the composite film is conveyed to the separating device C.
For further improvement of automation, a controller can be further arranged, the controller controls the operation of the whole two-dimensional material equipment, and the controller can also be connected with an air cylinder, a motor and the like so as to adjust the distance between the first hot-pressing roller B01 and the second hot-pressing roller B02 according to production needs.
Optionally, temperature sensors can be further arranged on the first hot-pressing roller B01 and the second hot-pressing roller B02, the controller is electrically connected with the temperature sensors and the heating mechanism respectively, the temperature sensors collect the temperature of the first hot-pressing roller B01 and the temperature of the second hot-pressing roller B02, when the temperature reaches a preset temperature, the controller can control the heating mechanism to stop heating, when the temperature is lower than the preset temperature, the controller can control the heating mechanism to start heating, and when the temperature is higher than a safety temperature, the controller can control the whole two-dimensional material transfer device to stop working, so that the safety of the whole process is ensured.
Optionally, a pressure sensor is disposed between the first hot pressing roller B01 and the second hot pressing roller B02 (which may be the first hot pressing roller B01, the second hot pressing roller B02, or both), the controller is electrically connected to the pressure sensor and the hot pressing driver, the pressure information of the pressing of the first hot pressing roller B01 and the second hot pressing roller B02 is collected by the pressure sensor, when the pressure reaches a preset pressure, the controller may control the hot pressing driver to stop, when the pressure is lower than the preset pressure, the controller may control the hot pressing driver to operate to drive the first hot pressing roller B01 and the second hot pressing roller B02 to continuously approach each other, so as to improve the pressing effect.
Alternatively, a rubber layer may be provided on the surface of at least one of the first hot nip roller B01 and the second hot nip roller B02. In this way, it is possible to allow the first hot-pressing roller B01 and the second hot-pressing roller B02 to reliably press each portion of the film. Avoid two running rollers to lead to the partial position pressfitting of film not in place because of the axis is incomplete parallel.
Optionally, the hot-pressing device B further includes a rotational speed driver, the rotational speed driver is in driving connection with at least one of the first hot-pressing roller B01 and the second hot-pressing roller B02, and the rotational speed driver is used for adjusting the rotational speed of at least one of the first hot-pressing roller B01 and the second hot-pressing roller B02. The rotating speed of the roller driven by the rotating speed driver can be set randomly within a certain range, so that the linear speed of the equipment for transferring the two-dimensional material is set.
Alternatively, as shown in fig. 9 to 14, the separating device C includes an electrolytic cell, a first separating roller C01, a second separating roller C02 and an anode member C03, and when two-dimensional material is transferred on both sides, a third separating roller C04 is further added. Electrolyte is added into the electrolytic cell, the electrolyte includes but is not limited to strong alkali NaOH or KOH aqueous solution, dilute sulphuric acid aqueous solution, and the water for preparing the electrolyte can be distilled water or deionized water. The first separating roller C01, the second separating roller C02 and the anode element C03 are all located in the electrolyte. The first separation roller C01 and the second separation roller C02 are respectively positioned at two opposite sides of the composite film, namely the composite film passes through between the first separation roller C01 and the second separation roller C02, the first separation roller C01 and the second separation roller C02 extrude the composite film, the anode piece C03 is connected with a power supply anode, the metal film A011 in the composite film is connected with a power supply cathode, namely the anode piece C03 is used as an anode, the metal film A011 in the composite film is used as a cathode, and the metal film A011 is separated from the two-dimensional material in a water electrolysis mode, wherein the working principle is as follows: the metal film A011 is used as a cathode (the metal guide roller G in the first material receiving mechanism F01 can be connected with the negative electrode of an electrolysis power supply), the anode piece C03 can be an inert electrode (including but not limited to platinum, gold or other metals or alloys coated with dense platinum or gold) used as an anode, and the composite film is separated into the metal film A011 with the surface removed with the two-dimensional material and a target film with the surface attached with the two-dimensional material layer by electrolyzing water in a mode of generating a large amount of hydrogen bubbles between the metal film A011 and the two-dimensional material. When the transfer is single-sided transfer, the first target film a021 to which the two-dimensional material is attached is conveyed to the cleaning device D by the first separation roller C01, and the metal film a011 is conveyed to the cleaning device D by the second separation roller C02; when the two-sided transfer is performed, the first target film A021 attached with the two-dimensional material is conveyed to the cleaning device D by the first separating roller C01, the second target film A041 attached with the two-dimensional material is conveyed to the cleaning device D by the second roller C02, and the separated films are guided to different material receiving devices F through different separating rollers, so that the purpose of transferring the two-dimensional material from the metal substrate to the non-conductive film is achieved. Further, the third separation roller C04 may be provided in the separation device C, and the metal thin film a011 may be guided to the first receiving mechanism F01 by the third separation roller C04.
In order to improve the electrolysis effect, as shown in fig. 9 to 14, the anode member C03 may be disposed corresponding to the first separation roller C01 and the second separation roller C02, that is, the anode member C03 may be disposed adjacent to the first separation roller C01 and the second separation roller C02. For the transfer of two-sided two-dimensional material, there may also be two anode pieces C03. The anode member C03 is a rod-like or tube-like inert electrode having a uniform cross-sectional area or an electrode whose surface is coated with an inert metal, parallel to and close to the first separating roller C01 and the second separating roller C02, but is not in contact with the metal thin film a011 whose surface is removed with a two-dimensional material. Alternatively, the surface of the third separating roller C04 may be tangent to the perpendicular to the plane passing through the line of contact of the first separating roller C01 and the second separating roller C02 and consisting of the axes of the first separating roller C01 and the second separating roller C02.
The separating apparatus C further includes a separating driver drivingly connected to at least one of the first separating roller C01 and the second separating roller C02 for driving the first separating roller C01 and the second separating roller C02 toward or away from each other. The size of the gap between the first separating roller C01 and the second separating roller C02 may be achieved by a separating driver, such as an air cylinder, a motor, etc., being driven. For further improvement of automation, a controller can be further arranged, the controller can control the operation of the whole two-dimensional material equipment, the controller can also be connected with a cylinder, a motor and the like so as to adjust the distance between the first separating roller C01 and the second separating roller C02 according to production requirements, and the automatic adjustment of the extrusion pressure between the first separating roller C01 and the second separating roller C02 can also be realized by referring to a hot-pressing driver.
Optionally, as shown in fig. 9 to 14, the two-dimensional material transfer apparatus further includes a guide roller G and a tension roller H, the guide roller G is configured to guide the metal thin film a011, the target thin film and the composite thin film, that is, there may be a plurality of guide rollers G, the plurality of guide rollers G are distributed in or between the discharging device a, the hot pressing device B, the separating device C, the cleaning device D, the drying device E and the receiving device F, the tension roller H is configured to tension the metal thin film a011, the target thin film and the composite thin film, that is, there may be a plurality of tension rollers H, the plurality of tension rollers H are distributed in or between the discharging device a, the hot pressing device B, the separating device C, the cleaning device D, the drying device E and the receiving device F, and the tension rollers H may prevent the films from wrinkling and the like.
Optionally, a plurality of drivers electrically connected with the controller may be further provided, each driver may correspondingly drive one roller, and the two-dimensional material transfer apparatus further includes a deviation correcting device I for correcting the transmission of the metal thin film a011, the target thin film, and the composite thin film. As shown in fig. 5, a deviation-correcting sensor (e.g., a deviation-correcting electric eye) electrically connected to the controller is disposed on the conveying path of each film, and the controller obtains information of the deviation-correcting sensor to adjust each roller in time, so as to achieve the function of deviation correction. Meanwhile, the rotation speed of each roller can be controlled through a controller, for example, the rotation speed of the first hot-pressing roller B01 and the rotation speed of the first separation roller C01 are controlled, and the control of the process time of each stage is realized. Each roller arranged in the separating device C can be made of corrosion-resistant non-metallic materials.
Optionally, an electrical control device may be further provided, which includes a computer software control system, and the two-dimensional material transfer device may be operated manually by a computer, or may be operated automatically according to a preset flow, and may automatically record each operation parameter, and automatically alarm and/or shut down safely when an abnormality occurs.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (18)

1. A two-dimensional material transfer apparatus, comprising: the device comprises a feeding device, a hot-pressing device, a separating device, a cleaning device, a drying device and a receiving device;
the discharging device respectively conveys a metal film with at least one surface growing with two-dimensional materials and a target film to the hot-pressing device, and the target film corresponds to the surface of the metal film growing with the two-dimensional materials;
the hot-pressing device is used for hot-pressing the target thin film and one surface of the metal thin film on which the two-dimensional material grows to form a composite thin film and conveying the composite thin film to the separation device;
the separating device is used for separating the composite film to transfer the two-dimensional material on the metal film to the target film and conveying the target film attached with the two-dimensional material to the cleaning device;
the cleaning device is used for cleaning the target film attached with the two-dimensional material and conveying the cleaned target film attached with the two-dimensional material to the drying device;
the drying device is used for drying the target film attached with the two-dimensional material and conveying the dried target film attached with the two-dimensional material to the material receiving device;
the material receiving device is used for collecting the target film attached with the two-dimensional material.
2. The two-dimensional material transfer apparatus of claim 1, wherein the discharge device comprises a raw material discharge mechanism and a first discharge mechanism; the hot-pressing device is characterized in that the raw material feeding mechanism conveys a metal film with at least one surface growing with two-dimensional materials to the hot-pressing device, the first feeding mechanism conveys a first target film coated with hot melt adhesive to the hot-pressing device, and the surface coated with the hot melt adhesive of the first target film corresponds to the surface growing with the two-dimensional materials of the metal film.
3. The two-dimensional material transfer apparatus of claim 1, wherein said dispensing device comprises a raw material dispensing mechanism, a first hot melt adhesive dispensing mechanism, and a first dispensing mechanism; raw materials drop feed mechanism to hot press unit carries the metal film that at least one side grows to have two-dimensional material, first drop feed mechanism to hot press unit carries first target film, first hot melt adhesive drop feed mechanism to hot press unit carries first hot melt adhesive film, the one side that metal film grows to have two-dimensional material corresponds the one side of first target film just first hot melt adhesive film is located first target film with between the metal film.
4. The two-dimensional material transfer apparatus according to claim 1, wherein the discharging device includes a raw material discharging mechanism, a first discharging mechanism, and a second discharging mechanism, the raw material discharging mechanism conveys a metal film on both sides of which the two-dimensional material is grown to the hot press device, the first discharging mechanism and the second discharging mechanism respectively convey a first target film coated with a hot melt adhesive and a second target film coated with a hot melt adhesive to the hot press device, the first target film coated with the hot melt adhesive corresponds to one side of the metal film, and the second target film coated with the hot melt adhesive corresponds to the other side of the metal film.
5. The two-dimensional material transfer apparatus of claim 1, wherein said dispensing device comprises a raw material dispensing mechanism, a first hot melt adhesive dispensing mechanism, a second hot melt adhesive dispensing mechanism, a first dispensing mechanism, and a second dispensing mechanism; the hot-pressing device is characterized in that the raw material feeding mechanism conveys a metal film with two-dimensional materials growing on two sides, the hot-pressing device conveys a metal film with two-dimensional materials growing on two sides, the first feeding mechanism and the second feeding mechanism respectively convey a first target film and a second target film to the hot-pressing device, the first target film and the second target film are respectively located on two sides of the metal film, and the first hot-melt adhesive feeding mechanism and the second hot-melt adhesive feeding mechanism respectively convey the first hot-melt adhesive film and the second hot-melt adhesive film to the hot-pressing device and respectively interface the first target film with the metal film and the second target film with the metal film.
6. The two-dimensional material transfer apparatus of claim 1, wherein said dispensing device comprises a raw material dispensing mechanism, a first hot melt adhesive dispensing mechanism, a first dispensing mechanism, and a second dispensing mechanism; the raw material discharging mechanism conveys a metal film with two-dimensional materials growing on two sides to the hot pressing device, the first discharging mechanism conveys a first target film to the hot pressing device, and the second discharging mechanism conveys a second target film coated with hot melt adhesive to the hot pressing device; the first target film and the second target film are respectively positioned on two sides of the metal film, the first hot melt adhesive discharging mechanism conveys the first hot melt adhesive film to the hot pressing device, the first hot melt adhesive discharging mechanism is arranged between the first target film and the metal film, and one surface of the second target film, which is coated with the hot melt adhesive, corresponds to the metal film.
7. A two-dimensional material transfer apparatus as claimed in any of claims 2 to 6, wherein said source material discharge mechanism comprises a source roll provided with a metallic film web and said first discharge mechanism comprises a first roll provided with a first target film web.
8. The two-dimensional material transfer apparatus according to any one of claims 1 to 6, wherein the hot press device includes a hot press driver, a heating mechanism, and a first hot press roller and a second hot press roller which are disposed opposite to each other, the heating mechanism being connected to at least one of the first hot press roller and the second hot press roller; the hot pressing driver is in driving connection with at least one of the first hot pressing roller wheel and the second hot pressing roller wheel and is used for driving the first hot pressing roller wheel and the second hot pressing roller wheel to be close to or far away from each other.
9. The two-dimensional material transfer apparatus of claim 8, wherein the thermal press apparatus further comprises a controller and a temperature sensor electrically connected to the controller; the heating mechanism is electrically connected with the controller, the temperature sensor is used for collecting temperature information of at least one of the first hot-pressing roller and the second hot-pressing roller, and the controller is used for controlling the heating mechanism to act according to the temperature information.
10. The two-dimensional material transfer apparatus of claim 8, wherein the thermal press further comprises a rotational speed drive drivingly coupled to at least one of the first thermal press roll and the second thermal press roll, the rotational speed drive for adjusting a rotational speed of at least one of the first thermal press roll and the second thermal press roll.
11. The two-dimensional material transfer apparatus of any one of claims 1 to 6, wherein the separation device comprises an electrolytic cell containing an electrolyte and a first separation roller, a second separation roller, and an anode member positioned in the electrolyte; the first separating roller and the second separating roller are respectively positioned at two opposite sides of the composite film to extrude the composite film, the anode piece is used as an anode, the metal film in the composite film is used as a cathode to electrolyze the composite film to separate the metal film from the two-dimensional material, and the target film with the two-dimensional material attached to the surface is conveyed to the cleaning device by the first separating roller.
12. The two-dimensional material transfer apparatus of claim 11, wherein the separating device further comprises a separation drive drivingly connected to at least one of the first and second separating rollers for driving the first and second separating rollers toward or away from each other.
13. The two-dimensional material transfer apparatus according to claim 1, wherein said material receiving device includes a material receiving roller for receiving said target film having the two-dimensional material attached thereto as a roll.
14. The two-dimensional material transfer apparatus according to any one of claims 2 to 6, wherein the raw material discharge mechanism is a chemical vapor deposition apparatus for depositing a two-dimensional material on the surface of the metal thin film and conveying the metal thin film on which the two-dimensional material is grown toward the hot pressing device.
15. The two-dimensional material transfer apparatus according to any one of claims 1 to 6, wherein the material receiving device is a two-dimensional material processing device for processing the target film to which the two-dimensional material is attached after drying.
16. The two-dimensional material transfer apparatus according to any one of claims 1 to 6, further comprising a guide roller for guiding the metal thin film, the target thin film and the composite thin film, and a tension roller for tensioning the metal thin film, the target thin film and the composite thin film.
17. The two-dimensional material transfer apparatus according to any one of claims 1 to 6, further comprising a correction device for correcting conveyance of the metal film, the target film, and the target film having the two-dimensional material attached to the surface thereof.
18. The two-dimensional material transfer apparatus of any one of claims 1 to 6, wherein the separating device is further configured to convey the transferred metal film to the cleaning device; the cleaning device is also used for cleaning the metal film and conveying the cleaned metal film to the drying device; the drying device is also used for drying the metal film and conveying the dried metal film to the material receiving device.
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