Disclosure of Invention
The application aims to provide a manufacturing device and a manufacturing method of a solid-state battery micro-cell capable of improving the qualification rate of products.
In a first aspect, the present application provides a manufacturing apparatus for a solid-state battery micro-cell, which adopts the following technical scheme:
the manufacturing equipment of the solid-state battery micro-cell comprises an anode production line and a cathode production line, wherein the anode production line and the cathode production line both comprise carrier tape conveying mechanisms; the carrier tape conveying mechanism is sequentially provided with an extrusion feeding mechanism, a rolling mechanism, a coating slicing mechanism and a stripping and laminating mechanism along the conveying direction of the carrier tape conveying mechanism, wherein the stripping and laminating mechanism is used for transferring the coating on the traction film to the pole piece film with the aluminum/copper foil;
an isolating film covering mechanism is arranged on the positive electrode production line or the negative electrode production line; the isolating film covering mechanism is arranged behind the coating slicing mechanism along the conveying direction corresponding to the carrier tape conveying mechanism;
An anode-cathode composite production line is arranged between the anode production line and the cathode production line, and the conveying direction starting end of the anode-cathode composite production line is respectively connected with the conveying direction tail end of the anode production line and the conveying direction tail end of the cathode production line;
the positive and negative electrode laminating production line is sequentially provided with a positive and negative electrode laminating mechanism, a heat sealing mechanism and a cutting mechanism along the conveying direction of the positive and negative electrode laminating production line.
Through adopting the technical scheme, the positive electrode production line and the negative electrode production line are both provided with the carrier tape conveying mechanism, so that the belt type transportation of the coating is realized, the processes that the positive electrode material and the negative electrode material are sequentially fed, rolled, sliced and coated onto the pole piece film are realized by sequentially arranging the extrusion type feeding mechanism, the rolling mechanism, the coating slicing mechanism and the peeling and covering mechanism on the positive electrode production line and the negative electrode production line, and the setting of the isolation film composite mechanism in the positive electrode production line or the negative electrode production line can realize the setting of the isolation film in the micro-battery cell; and the positive electrode production line and the negative electrode production line are both communicated to the positive electrode and negative electrode covering production line, and the positive electrode and negative electrode covering production line sequentially sets the positive electrode and negative electrode pressing mechanism, the heat sealing mechanism and the cutting mechanism, so that the processes of pressing positive electrode materials and negative electrode materials, performing heat sealing after pressing and slicing the micro-battery cells after heat sealing are sequentially realized, and the full-automatic production process of the micro-battery cells is realized.
The traction film is arranged through the carrier belt conveying mechanism to realize the traction of the paint, and the coating, rolling, cutting and flaking of the paint and the continuous completion of the laminating isolating film on the traction film are realized; after the overturning, the pressing, hot cladding and cutting of the anode and cathode materials are realized, so that the finished product is produced at one time and the whole process of continuous production is carried out. In the process, repeated positioning is not needed in the production process of the product, so that the processing difficulty can be reduced, and the yield of the product is improved.
Optionally, the extrusion formula pan feeding mechanism includes a play feed cylinder, be provided with the piston board in the play feed cylinder, the piston board with play feed cylinder inner wall is followed play feed cylinder axial sliding connection, be provided with on the piston board can drive the piston board is followed play feed cylinder axial motion's coating drive assembly.
Through adopting above-mentioned technical scheme, extrusion formula pan feeding mechanism passes through the setting of ejection of compact section of thick bamboo, installs the coating in ejection of compact section of thick bamboo, then under the effect of coating driving piece, promotes the coating in the ejection of compact section of thick bamboo through the piston plate, can realize the automatic feeding of material.
Optionally, a pressure sensor is disposed between the paint driving assembly and the piston plate, and the pressure sensor is connected with the paint driving assembly and the piston plate along two axial sides of the discharging cylinder respectively.
Through adopting above-mentioned technical scheme, pressure sensor sets up between coating drive assembly and piston board, can carry out real-time detection to the pressure between coating drive assembly and the piston board to adjust the pressure of coating drive assembly to the piston board with this, make in the in-process of ejection of compact section of thick bamboo ejection of compact, the coating drive assembly can be even to the pressure of piston board, thereby make ejection of compact section of thick bamboo ejection of compact of ejection of compact.
Optionally, the rolling mechanism comprises a first roller and a second roller, the first roller and the second roller are axially arranged along the horizontal direction and are mutually parallel, and the outer side wall of the first roller and the outer side wall of the second roller are mutually spaced; one end of the discharging cylinder in the axial direction of the discharging cylinder is connected with the first roller and the second roller, and the discharging cylinder is communicated with a gap between the first roller and the second roller;
the carrier tape conveying mechanism comprises a traction film feeding assembly, wherein the traction film feeding assembly is arranged on one side of the first roller and can convey a traction film into a gap between the first roller and the second roller.
By adopting the technical scheme, the first roller and the second roller are arranged, so that the gap between the first roller and the second roller is communicated with the discharging cylinder, and when the discharging cylinder discharges, the paint can pass through the gap between the first roller and the second roller; the traction film is fed into a gap between the first roller and the second roller by matching with the traction film feeding component, so that the first roller and the second roller can press the paint into a sheet shape and attach the paint to the traction film, and the traction film becomes a conveying carrier of the paint, thereby being convenient for conveying the paint.
Optionally, the carrier tape conveying mechanism comprises a bracket, the bracket comprises a first long frame and a second long frame, the first long frame and the second long frame are mutually arranged at intervals along the length direction of the first long frame, and the extrusion feeding mechanism, the rolling mechanism and the coating slicing mechanism are all arranged on the upper side of the first long frame;
the stripping and laminating mechanism comprises a stripping and blanking assembly for winding the traction film and a laminating and charging assembly for unreeling the pole piece film, wherein the stripping and blanking assembly is arranged on the lower side of the first long frame, and the laminating and charging assembly is arranged on the lower side of the second long frame.
By adopting the technical scheme, the extrusion feeding mechanism, the rolling mechanism and the coating slicing mechanism are arranged on the first long frame, the traction film can pass through the first long frame along the length direction of the first long frame, and the stripping and blanking assembly is arranged below the first long frame, so that the rolling of the traction film is realized, and at the interval between the first long frame and the second long frame, the traction film can be separated from the sheet-shaped coating due to certain supporting hardness of the sheet-shaped coating when the traction film is rolled downwards;
the covering and feeding assembly is arranged below the second long frame, so that the pole piece film is conveyed to the second long frame from a gap between the second long frame and the first long frame, and when one side of the sheet-shaped coating moves between the gap between the first long frame and the second long frame, the sheet-shaped coating can be attached to the pole piece film;
Thereby realizing the transfer of the flaky paint from the traction film to the corresponding pole piece film.
Optionally, a blowing component is disposed between the first long frame and the second long frame, and the blowing component includes a jet head, where the jet head is disposed vertically downward and faces a gap between the first long frame and the second long frame.
Through adopting above-mentioned technical scheme, through the setting of air jet, when the waste material between two adjacent slice coating passes through the clearance between first long frame and the second long frame, the air jet is joined in marriage high-pressure air flow and is blown off the waste material, realizes the clearance of waste material.
Optionally, the air blowing assembly includes a waste collection box, the waste collection box opening is vertically upwards arranged, the waste collection box is arranged on the vertical lower side of the first long frame and the second long frame, and the air jet head and the waste collection box are directly opposite to each other along the vertical direction.
Through adopting above-mentioned technical scheme, the setting of garbage collection box is just to the jet head along vertical direction through the opening of garbage collection box for the jet head can spouts the waste material into the garbage collection box in, realizes the collection to the waste material.
Optionally, the positive and negative electrode covers and closes the production line still and is provided with traction mechanism, traction mechanism includes lower roller and two and goes up the pinch roller, two go up the coaxial setting of pinch roller and two go up the pinch roller and set up along self axial interval, go up the pinch roller axial with lower roller axial sets up along the horizontal direction and mutual parallel arrangement, it sets up along vertical direction to go up the pinch roller is in lower roller upside just go up the pinch roller with lower roller sets up along vertical direction interval each other, go up pinch roller coaxial coupling has can drive go up the rotatory driving piece that rectifies of pinch roller.
Through adopting above-mentioned technical scheme, traction mechanism's setting, through the cooperation of lower roller and last pinch roller, when the material area is through between lower roller and the last pinch roller, through the drive of rectifying the driving piece, can realize the transport function in material area.
Because the active material area of the packaged battery cell cannot be pressed, the upper pressing wheel is arranged at intervals along the axial direction of the upper pressing wheel, so that the upper pressing wheel only needs to press the packaging positions at two ends of the battery cell.
Meanwhile, when the material belt is deviated, the deviation correcting function of the material belt can be realized by adjusting the rotation speed difference of the two upper pressing wheels.
In a second aspect, the present application provides a method for manufacturing a solid-state battery micro-cell, which adopts the following technical scheme:
a manufacturing method of a solid-state battery micro-cell comprises the following steps:
s1: the positive electrode production line is used for producing the positive electrode of the solid-state battery:
firstly, positive electrode coating is loaded and pressed onto a traction film;
next, positive electrode slice: slicing the positive electrode coating on the traction film;
then, the positive electrode coating material was transferred: transferring the flaky anode paint on the traction film to a pole piece film provided with copper/aluminum foil;
finally, laminating a separation film: coating the sheet-shaped anode coating with a separation film;
S2: the production line of the negative electrode carries out the production of the negative electrode of the solid-state battery:
firstly, negative electrode feeding: the negative electrode coating is fed onto the traction film;
then, the negative electrode was sliced: slicing the negative electrode coating on the traction film;
finally, the negative electrode coating is transferred: transferring the flaky negative electrode coating on the traction film to a polar film provided with copper/aluminum foil;
s3: positive and negative electrode covering production line: coating and combining the anode coating and the cathode coating to prepare a final micro-cell:
first, the positive and negative electrodes are covered: performing counterpoint lamination on the positive electrode and the negative electrode of the solid-state battery;
then, the positive and negative electrodes are covered: performing heat sealing on the aligned positive electrode and negative electrode;
finally, cutting: slicing the covered solid-state battery.
By adopting the technical scheme, the traction film is used as a conveying carrier of the coating, so that continuous production of the positive electrode material and the negative electrode material and final covering and cutting of the positive electrode material and the negative electrode material are realized through conveying of the traction film. Through continuous production, repeated positioning is not needed in the production process, and the yield of the production of the product can be improved.
Optionally, step S1 is performed synchronously with step S2.
By adopting the technical scheme, the positive electrode and the negative electrode are synchronously produced, so that the production speed of the micro-battery cell can be improved.
In summary, the present application includes at least one of the following beneficial technical effects:
1. the application realizes the full-automatic production of the solid-state battery micro-cell by synchronously producing the positive electrode production line and the negative electrode production line and carrying out thermal lamination on the positive electrode material and the negative electrode material by matching with the positive electrode and negative electrode lamination production line.
2. According to the application, the coating is adhered on the traction film for conveying through the cooperation of the carrier belt conveying mechanism, the extrusion type feeding mechanism and the rolling mechanism, so that the production continuity can be realized, and the production efficiency can be improved.
3. According to the application, through the arrangement of the pressure sensor in the extrusion type feeding mechanism and the secondary thickness regulating component in the rolling mechanism, the thickness of the coating layer attached to the traction film can be uniform, so that the yield of the final product is improved.
4. The application uses the traction film as a transport carrier of the anode and cathode materials, realizes the process of coating and slicing the anode and cathode materials, reduces the repeated positioning difficulty between the anode and cathode materials, and improves the yield of products.
Detailed Description
The present application will be described in further detail with reference to fig. 1 to 7.
Referring to fig. 1, the manufacturing equipment of the solid-state battery micro-cell comprises an anode production line 1, a cathode production line 2 and a cathode covering production line 3, wherein the anode production line 1 is connected with the cathode covering production line 3 along the starting end of the conveying direction along the conveying direction at the tail end of the conveying direction and the tail end of the cathode production line 2, and the anode production and the cathode production of the solid-state battery micro-cell and the whole covering process of the anode and the cathode are realized through the arrangement of the anode production line 1, the cathode production line 2 and the cathode covering production line 3.
Referring to fig. 2 and 3, the positive electrode production line 1 and the negative electrode production line 2 each include a carrier tape conveying mechanism 100, and the carrier tape conveying mechanism 100 is provided with a squeeze-type feeding mechanism 200, a roll-in mechanism 300, a paint slicing mechanism 400, and a peeling and laminating mechanism 500 in this order along the conveying direction of itself.
Referring to fig. 1 and 2, the conveying directions of the positive electrode production line 1 and the negative electrode production line 2 are all set along the horizontal direction, the positive electrode production line 1 and the negative electrode production line 2 are set at intervals along the vertical direction, the positive electrode production line 1 is set on the negative electrode production line 2, the negative electrode production line 2 and the positive electrode coating production line 3 are set in line along the horizontal direction, and the separator coating mechanism 600 is further set on the carrier tape conveying mechanism 100 of the positive electrode production line 1 along the conveying direction thereof after the peeling coating mechanism 500. The positive electrode coating placed above the separator can be aligned with the negative electrode coating after 180 DEG steering, so that the separator is coated on the positive electrode so as not to cause the positive electrode coating to fall off during steering.
Referring to fig. 4, the extrusion type feeding mechanism 200 includes a discharging cylinder 201, the discharging cylinder 201 is axially disposed along a vertical direction, a piston plate 202 is disposed in the discharging cylinder 201, and the piston plate 202 is slidably connected with an inner wall of the discharging cylinder 201 along the vertical direction, so that after a corresponding positive electrode or negative electrode coating is filled in the discharging cylinder 201, the piston plate 202 can push out the coating from a lower end of the discharging cylinder 201, and a feeding function of the positive electrode coating and the negative electrode coating can be realized.
The upper side of the piston plate 202 is provided with a paint driving assembly 203, the paint driving assembly 203 comprises a feeding push rod 2031, the feeding push rod 2031 is arranged in the vertical direction, the lower end of the feeding push rod 2031 is connected with the piston plate 202, the upper end of the feeding push rod 2031 is provided with a paint driving piece 2032, and the paint driving piece 2032 adopts a ball screw pair driven by a servo motor as a power source, so that the feeding push rod 2031 can drive the piston plate 202 to push a material in a discharge cylinder 201 to extrude the material in the discharge cylinder 201, and the quantitative feeding function of the extrusion type feeding mechanism 200 is realized.
A pressure sensor 204 is arranged between the feeding push rod 2031 and the piston plate 202 along the vertical direction, the two sides of the pressure sensor 204 along the vertical direction are respectively connected with the feeding push rod 2031 and the piston plate 202, the pressure generated between the feeding push rod 2031 and the piston plate 202 is detected in real time through the pressure sensor 204, and the pressure of the feeding push rod 2031 to the piston plate 202 can be uniform through adjustment, so that the uniformity of coating feeding is improved.
Referring to fig. 4, the rolling mechanism 300 includes a first roller 301 and a second roller 302, the first roller 301 and the second roller 302 are axially disposed in parallel with each other and are disposed along a horizontal direction, an outer side wall of the first roller 301 and an outer side wall of the second roller 302 are disposed at intervals along the horizontal direction, and a lower end of the discharging cylinder 201 is respectively connected with the first roller 301 and the second roller 302; the gap between the first roller 301 and the second roller 302 communicates with the lower end of the discharge cylinder 201 in the vertical direction so that the paint in the discharge cylinder 201 is discharged from the gap between the first roller 301 and the second roller 302.
Referring to fig. 3 and 4, the carrier tape transport mechanism 100 includes a traction film feeding assembly 102, and the traction film feeding assembly 102 is disposed at one side of the first roller 301 in a horizontal direction, so that the traction film feeding assembly 102 can feed the traction film into a gap between the first roller 301 and the second roller 302. The paint in the discharging cylinder 201 enters the gap between the first roller 301 and the second roller 302, and the paint can be attached to the traction film by the extrusion of the first roller 301 and the second roller 302, so that the traction film becomes a transport carrier of the paint, and the paint can enter the subsequent process conveniently.
The carrier tape conveying mechanism 100 comprises a bracket 101, the bracket 101 comprises a first long frame 1011 and a second long frame 1012, the first long frame 1011 and the second long frame 1012 are arranged in a collinear manner and are arranged along the horizontal direction, the first long frame 1011 and the second long frame 1012 are arranged at intervals along the length direction of the first long frame 1011, one end of the first long frame 1011 is provided with a second-stage thickness regulating component 303, the second-stage thickness regulating component 303 comprises an upper press roll 3031 and a lower press roll 3032, the upper press roll 3031 and the lower press roll 3032 are axially arranged along the horizontal direction, the upper press roll 3031 and the lower press roll 3032 are arranged at intervals along the vertical direction, and a traction film passing through the first roll 301 and the second roll 302 passes through a gap between the upper press roll 3031 and the lower press roll 3032, so that the upper press roll 3031 and the lower press roll 3032 can carry out extrusion regulation on the thickness of a coating on the traction film; meanwhile, the traction film is conveyed to the first long frame 1011 through the arrangement of the secondary thickness adjusting component 303, so that the traction film is conveyed. The second-stage thickness adjusting component 303 can be arranged in a plurality along the length direction of the first long frame 1011, and is used for realizing multiple rolling of the paint on the traction film so as to improve the thickness uniformity of the paint on the traction film.
Referring to fig. 4, the secondary thickness adjusting assembly 303 further includes a thickness measuring sensor 3033, the thickness measuring sensor 3033 is disposed on the first long frame 1011, the thickness measuring sensor 3033 is disposed along a vertical direction, and a detecting portion of the thickness measuring sensor 3033 is vertically downward and is opposite to the first long frame 1011, so that the thickness measuring sensor 3033 can detect the thickness of the paint on the traction film, and thus, the gap between the upper press roll 3031 and the lower press roll 3032 is automatically adjusted through the thickness detection result, thus, the online closed-loop automatic control of the thickness of the paint is realized, and the multistage adjustment of the thickness of the paint on the traction film is realized, so as to improve the thickness precision of the paint.
Referring to fig. 4, anti-sticking components 304 are disposed on the second roller 302 and the upper press roller 3031, the anti-sticking components 304 include an oiling member 3041 and an oiling member 3042, the oiling member 3041 is in contact with the corresponding outer peripheral side of the second roller 302 and the upper press roller 3031, the oiling member 3042 is communicated with the oiling member 3041, so that anti-sticking oil is provided for the oiling member 3041 through the oiling member 3042, anti-sticking nano-coating is disposed on the surfaces of the second roller 302 and the upper press roller 3031, the release force of the treated roller surface is smaller than that of the traction film, and the possibility that the coating is stuck on the roller surface is reduced.
Referring to fig. 3, the paint slicing mechanism 400 includes a cutter die which is disposed on a first long frame 1011 in a vertical direction and is connected with a punching driving member, and cuts simultaneously along both sides of a length direction and both sides of a width direction of a paint layer when the cutter die is driven by the punching driving member to punch in the vertical direction, so that the paint layer on a traction film can be punched into a sheet shape, and the slice sizes of the paint layer are the same.
Referring to fig. 5, the peeling and laminating mechanism 500 is disposed between the first long frame 1011 and the second long frame 1012, and the peeling and laminating mechanism 500 includes a peeling and blanking assembly 501 and a laminating and blanking assembly 502, the peeling and blanking assembly 501 is disposed at a vertically lower side of the first long frame 1011, a side surface of the first long frame 1011 facing the second long frame 1012 is provided with a guide surface 1013, the guide surface 1013 extends obliquely upward from bottom to top in a vertical direction in a direction close to the second long frame 1012, the peeling and blanking assembly 501 adopts a roller, and a traction film on the first long frame 1011 is disposed and connected on the roller of the peeling and blanking assembly 501 and the traction film and the guide surface 1013 are in contact with each other, so that when the peeling and blanking assembly 501 drives the traction film to wind from the first long frame 1011, the sheet-like paint itself has a certain hardness, so that the sheet-like paint can be separated from the traction film.
The peel-off lamination mechanism 500 further includes a lamination assembly 502, where the lamination assembly 502 is disposed below the second long frame 1012, and the lamination assembly 502 uses a roller set to unwind the pole piece film from the lower side of the second long frame 1012 to the upper side of the second long frame 1012. Therefore, when the sheet coating is pushed to the gap between the first long frame 1011 and the second long frame 1012 by the traction film, the sheet coating can smoothly cross the gap between the first long frame 1011 and the second long frame 1012 due to certain self-supporting strength, and is mutually attached with the corresponding copper/aluminum foil on the sheet film, so that the transfer of the sheet coating is realized.
Referring to fig. 5, the peeling and laminating mechanism 500 further includes a first color mark sensor 504, where the first color mark sensor 504 is disposed below the second long frame 1012, the first color mark sensor 504 is disposed along a horizontal direction, and a detecting portion of the first color mark sensor 504 faces a side, where copper/aluminum foil is attached, of the pole piece film unreeled in the coating and material assembly 502 along the horizontal direction. The length of the copper/aluminum foil on the pole piece film and the gap between the adjacent copper/aluminum foils are determined through the detection of the first color mark sensor 504, so that the position of the cutting die and the conveying speed of the traction film are matched, and the positioning and attaching precision between the flaky paint and the corresponding copper/aluminum foil is improved.
Referring to fig. 5, the peeling and laminating mechanism 500 further includes an air blowing assembly 503, the air blowing assembly 503 includes a jet head 5031, the jet head 5031 is disposed on an upper side of a gap between the first long frame 1011 and the second long frame 1012 in a vertical direction, the jet head 5031 is disposed vertically downward and faces a gap between the first long frame 1011 and the second long frame 1012, so that when waste between two adjacent sheet-like coatings passes through the gap between the first long frame 1011 and the second long frame 1012, the jet head 5031 can jet high-pressure air flow to blow off the waste in the vertical direction.
The blowing assembly 503 further includes a waste collection box 5032, the waste collection box 5032 is vertically disposed below a gap between the first long frame 1011 and the second long frame 1012, an opening of the waste collection box 5032 is vertically upward disposed opposite to the gap between the first long frame 1011 and the second long frame 1012, and the waste collection box 5032 is vertically disposed opposite to the jet head 5031; so that the waste collection box 5032 can collect the waste when the jet head 5031 blows the waste off.
Referring to fig. 5, the peeling and laminating mechanism 500 further includes a second color patch sensor 505, the second color patch sensor 505 is disposed on the upper side of the second long frame 1012, the second color patch sensor 505 is disposed in the vertical direction, and the detecting portion is disposed vertically downward facing the upper side of the second long frame 1012. Thereby, the second color mark sensor 505 detects the blank area between the adjacent copper/aluminum foils on the pole piece film, and the position of the waste material between the adjacent sheet-shaped coating materials on the traction film can be calculated, so that the blowing time of the jet head 5031 can be controlled.
Referring to fig. 2, the separator laminating mechanism 600 is disposed on the upper side of the second long frame 1012, the separator laminating mechanism 600 includes a separator unreeling assembly 601 and a separator laminating assembly 602, the separator unreeling assembly 601 unreels the separator and stacks the separator onto the sheet-like coating, and the separator laminating assembly 602 laminates the separator with the positive coating through a heat release block compacting process.
Referring to fig. 1 and 6, the positive-negative electrode lamination line 3 is provided with a positive-negative pressure lamination mechanism 700, a heat seal mechanism 800, a traction mechanism 1000, and a cutting mechanism 900 in this order along the conveying direction thereof. A bracket 1014 is arranged below the positive and negative laminating production line, the bracket 1014 is arranged in line with a second long frame 1012 in the negative electrode production line 2, and the bracket 1014 is arranged at one side of the second long frame 1012 of the negative electrode production line 2 far away from the first long frame 1011. The positive and negative electrode pressing mechanism 700 and the heat sealing mechanism 800 are arranged on the second long frame 1012 of the negative electrode production line 2 far away from the upper side, the traction mechanism 1000 is arranged at the joint of the second long frame 1012 and the bracket 1014 of the negative electrode production line 2, and the cutting mechanism 900 is arranged on the bracket 1014.
Referring to fig. 1 and 6, the positive and negative pressure combining mechanism 700 includes a reversing roller 701, the reversing roller 701 is axially arranged along a horizontal direction, the upper side of the reversing roller 701 is tangentially arranged with the upper side of a second long frame 1012 of the positive electrode production line 1, the reversing roller 701 is arranged at one end of the second long frame 1012 of the positive electrode production line 1 far away from the first long frame 1011, the lower side of the reversing roller 701 is arranged with the upper side of the second long frame 1012 of the negative electrode production line 2 at intervals, a pole piece film covered with an isolating film on the positive electrode production line 1 is contacted with the outer side of the reversing roller 701, and the pole piece film on the positive electrode production line 1 is turned 180 degrees under the driving of the reversing roller 701, and the vertical direction of the sheet coating is changed into the vertical downward setting of the sheet coating. And when passing through the lower side of the reversing roller 701, the reversing roller 701 can press the pole piece film generated on the positive electrode production line 1 and the pole piece film on the negative electrode production line 2.
The two ends of the reversing roller 701 are provided with linear modules driven by a servo motor, and the driving direction of the linear modules is set along the length direction of the second long frame 1012, so that the reversing roller 701 can be driven to move along the length direction of the second long frame 1012, and after the alignment of the sheet-shaped coating of the positive electrode and the sheet-shaped coating of the negative electrode deviates, the deviation generated by the alignment is compensated by adjusting the reversing roller 701.
The positive and negative pressure combining mechanism 700 further comprises a third color code sensor 702, the third color code sensor 702 is arranged behind the isolating film covering mechanism 600 along the conveying direction of the positive electrode production line 1, the third color code sensor 702 is arranged on the upper side of a second long frame 1012 of the positive electrode production line 1, and the third color code sensor 702 is opposite to the upper side face of the second long frame 1012 of the positive electrode production line 1, so that the third color code sensor 702 can detect a pole piece film entering the positive electrode of the positive and negative pressure combining mechanism 700 in real time, and the second color code sensor 505 on the negative electrode production line 2 is matched to detect a pole piece film entering the negative electrode of the positive and negative pressure combining mechanism 700 in real time, so that the conveying speed of the positive electrode production line 1 and the negative electrode production line 2 can be controlled, and the positive electrode sheet paint and the negative electrode sheet paint can be aligned accurately.
Referring to fig. 1 and 6, the heat-sealing mechanism 800 includes a heat-sealing die disposed on the upper side of the second long frame 1012 of the negative electrode production line 2, and heat-sealing the positive electrode and the negative electrode is achieved by a process of compacting the heat blocks. The heat sealing die is provided with a linear die driven by a servo motor, and the driving direction of the linear die set is along the length direction of the second long frame 1012, so that when the moving speed of the linear die for driving the heat sealing die is the same as the material conveying speed after positive and negative pressure combination, the heat sealing can be realized without stopping the tape moving.
Referring to fig. 6 and 7, the traction mechanism 1000 includes a lower roller 1001 and two upper pinch rollers 1002, the lower roller 1001 is disposed in a gap between a second long frame 1012 and a bracket 1014 of the negative electrode production line 2, the two upper pinch rollers 1002 are coaxially disposed and the two upper pinch rollers 1002 are axially spaced along the self axis, the upper pinch rollers 1002 and the lower roller 1001 are axially disposed along the horizontal direction and are parallel to each other, the upper pinch rollers 1002 and the lower roller 1001 are vertically spaced from each other and the upper pinch rollers 1002 are disposed on the upper side of the lower roller 1001 along the vertical direction, the two upper pinch rollers 1002 are coaxially connected with a correction driving member 1003, the lower roller 1001 is coaxially disposed with an auxiliary driving member 1004, and the correction driving member 1003 and the auxiliary driving member 1004 are servo motors.
Since the heat-encapsulated web has no take-up mechanism, a traction mechanism 1000 is necessary to power the web transport prior to cutting. The lower roller 1001 and the upper pressing wheel 1002 are arranged along the vertical direction, so that the possibility of wrap angle of tape production is reduced. The two upper press rollers 3031 are arranged at intervals along the axial direction, and the upper press rollers 1002 are used for contacting the packaging positions at the two ends of the battery core, so that the packaged battery core can be conveyed, and meanwhile, the pressure can not be generated on the active material area of the battery core. When the fed material belt is deviated, the deviation correction can be realized by adjusting the driving speed of the deviation correction driving piece 1003 of the upper pressing wheels 1002 at the two ends and adjusting the speed difference of the two upper pressing wheels 1002.
Referring to fig. 6, the cutting mechanism 900 includes a cutting tool on which a linear module driven by a servo motor is provided, and a driving direction of the linear module is set along a length direction of the second long frame 1012, so that cutting with no stop of a tape can be achieved when a conveying speed of the cutting tool is consistent with that of the material tape.
The implementation principle of the embodiment of the application is as follows: the processing technology of the anode and the cathode is the same, the coating is arranged in the extrusion type feeding mechanism 200 and enters the rolling mechanism 300 after extrusion, in order to obtain uniform and high-consistency coating thickness, the coating needs to be rolled for a plurality of times, and in the process, the coating is adhered to a traction film with the thickness consistency less than or equal to 0.5 um; the rolled paint is attached to a traction film and then is conveyed to a paint slicing mechanism 400, the paint slicing mechanism 400 adopts a cutter die punching cutting mode to remove waste materials on two sides of the paint in the width direction, the paint is punched into sheet materials with corresponding sizes, the position of the punched block materials is kept unchanged, and the block materials are still attached to the traction film; after that, the traction film enters a stripping and laminating mechanism 500, the flaky paint and the traction film are stripped by a stripping and blanking assembly 501, and then the stripped flaky paint is transferred to a pole piece film provided with copper/aluminum foil through a laminating and loading assembly 502.
Then, the sheet film provided with the sheet-like paint on the positive electrode production line 1 is fed into the separator laminating mechanism 600, and a separator is laminated by thermal lamination.
Finally, products produced by the positive electrode production line 1 and the negative electrode production line 2 enter a positive and negative electrode pressure combining mechanism 700, and positive/negative electrode active materials are precisely attached face to face after reversing and pressing through a reversing roller 701; after being attached, the battery cell enters a heat sealing mechanism 800, and is packaged in a heat coating mode; and then the traction mechanism 1000 is used for accurately conveying the battery core to the cutting mechanism 900 for cutting, so that the single solid-state battery micro battery core is manufactured.
In practical application, the mechanism can realize continuous operation, and has the efficacy more than three times of that of the common existing technology. Second, because there is no transfer of positions, the yield is improved by more than 15% compared with the common existing technology (the highest yield of the common existing technology is 82%, and the main reason for waste products is damage to the dry roller coated sheet material in the transfer process, the yield of the application can reach 98%). Thirdly, there is no risk of contaminating the paint; in the common prior art, a magazine coating mechanism adopts a direct compression method tabletting process, so that in order to prevent paint from sticking to a pressing plate, each pressing plate is coated with anti-sticking silicone oil or a release agent, and thus the coated plate is possibly polluted. Fourth, the mechanism of continuous operation is fit for adopting online detection mechanism to realize that the counterpoint is inaccurate, lacks the material, heat cover close defect such as put in place, encapsulation insecure carries out multiple detection, has avoided the risk that the potential waste product that causes because the omission detects mixes the qualification product.
A manufacturing method of a solid-state battery micro-cell comprises the following steps:
s1: the positive electrode production line 1 is used for producing the positive electrode of the solid-state battery;
s11: positive electrode feeding: and (3) attaching the positive electrode coating on the traction film to realize the feeding and conveying of the positive electrode coating.
S111: extrusion feeding: paint is loaded into the discharge cylinder 201, the piston plate 202 is driven, and paint is pressed by the piston plate 202 to be metered into the space between the first roller 301 and the second roller 302 of the rolling mechanism 300.
S112: and (3) feeding a traction film: the traction film is fed between the first roller 301 and the second roller 302 by the traction film feeding assembly 102, and the paint is pressed on the traction film by the pressing of the first roller 301 and the second roller 302.
S113: and (3) regulating the thickness of the coating layer: the paint traction film is sent between the upper press roll 3031 and the lower press roll 3032 of the secondary thickness adjusting assembly 303, and the thickness of the paint layer on the traction film is adjusted so as to make the thickness of the paint uniform.
S114: closed loop control adjustment: the thickness of the paint on the traction film is detected through the thickness measuring sensor 3033, closed-loop control is realized, and the second-level thickness regulating component 303 is regulated to control the thickness of the paint, so that the highest precision of the thickness of the paint can be controlled to +/-0.5 um.
S115: anti-sticking adjustment: during the rotation of the first roller 301 and the upper press roller 3031, the anti-adhesion component 304 is used for carrying out anti-adhesion nano coating treatment on the upper surfaces of the first roller 301 and the second roller 302, so that the possibility of adhesion of the coating on the first roller 301 and the upper press roller 3031 is reduced.
S12: positive electrode slice: slicing the positive electrode coating on the traction film;
s121: length direction slice: the traction film passing through the rolling mechanism 300 is sent into a coating slicing mechanism 400, and a knife die stamping forming process is adopted to stamp and slice the positive coating layer on the traction film into blocks; meanwhile, a section of waste is punched between two adjacent flaky coatings along the length direction of the strong traction film and is used for corresponding to a blank area between two copper/aluminum foils of the bell on the flaky film, so that the transfer speed of the flaky coating on the traction film can be matched with the feeding speed of the flaky film.
S122: waste removal in the width direction: cutting off the coating layer scraps on the traction film along the width direction of the traction film by a coating slicing mechanism 400; since the edges of the sheet-like paint in the width direction are irregular curves after rolling, the scraps at the edges in the width direction are cleaned before the sheet-like paint (the width of the paint at the beginning of rolling is increased by about 15mm from the required width on one side), and the sheets with the same width size are left, so that the shapes of the sheet-like paint are the same.
S13: and (3) transferring a positive electrode coating: transferring the flaky anode paint on the traction film to a pole piece film provided with copper/aluminum foil;
s131: stripping: the sliced coating and the traction film are sent into the stripping and laminating mechanism 500, and the traction film is stripped from the sheet material in a mode of realizing large-angle foldback stripping through the cooperation of the stripping and blanking assembly 501 and the first long frame 1011.
S132: waste material blowing: after the traction film and the flaky paint are stripped, waste materials between two adjacent flaky paint can be sent into a gap between a first long frame 1011 and a second long frame 1012, and the detection of a blank area between two adjacent copper/aluminum foils on the polar film by a second color mark sensor 505 controls the blowing component 503 to jet high-pressure air flow so as to flow down the waste materials.
S133: and (3) covering: the stripped sheet paint has certain self-supporting strength, so that one side of the sheet paint enters a gap between the first long frame 1011 and the second long frame 1012 to be in contact with the sheet film unreeled by the coating and feeding assembly 502, and the sheet paint is transferred from the traction film to the sheet film provided with copper/aluminum foil.
S134: speed adjustment: the gap between two adjacent copper/aluminum foils on the pole piece film is detected by the first color mark sensor 504, and the conveying speed of the traction film is adjusted in cooperation with the punching position of the cutting die, so that the positioning precision of the flaky paint and the copper/aluminum foils is improved.
S2: the negative electrode production line 2 performs the negative electrode production of the solid-state battery, and the negative electrode production line 2 and the positive electrode production line 1 are produced synchronously.
S21: and (3) negative electrode feeding: and (3) attaching the negative electrode coating on the traction film to realize the feeding and conveying of the negative electrode coating.
S211: extrusion feeding: paint is loaded into the discharge cylinder 201, the piston plate 202 is driven, and paint is pressed by the piston plate 202 to be metered into the space between the first roller 301 and the second roller 302 of the rolling mechanism 300.
S212: and (3) feeding a traction film: the traction film is fed between the first roller 301 and the second roller 302 by the traction film feeding assembly 102, and the paint is pressed on the traction film by the pressing of the first roller 301 and the second roller 302.
S213: and (3) regulating the thickness of the coating layer: the paint traction film is sent between the upper press roll 3031 and the lower press roll 3032 of the secondary thickness adjusting assembly 303, and the thickness of the paint layer on the traction film is adjusted so as to make the thickness of the paint uniform.
S214: closed loop control adjustment: the thickness of the paint on the traction film is detected through the thickness measuring sensor 3033, closed-loop control is realized, and the second-level thickness regulating component 303 is regulated to control the thickness of the paint, so that the highest precision of the thickness of the paint can be controlled to +/-0.5 um.
S215: anti-sticking adjustment: during the rotation of the first roller 301 and the upper press roller 3031, the anti-adhesion assembly 304 is used for carrying out anti-adhesion nano coating treatment on the upper surfaces of the first roller 301 and the second roller 302, so that the possibility of adhesion between the first roller 301 and the upper press roller 3031 and the paint is reduced.
S22: negative electrode slice: slicing the negative electrode coating on the traction film;
s221: length direction slice: the traction film passing through the rolling mechanism 300 is sent into a coating slicing mechanism 400, and a knife die stamping forming process is adopted to stamp and slice the negative coating layer on the traction film into blocks; meanwhile, a section of waste is punched between two adjacent flaky coatings along the length direction of the strong traction film and is used for corresponding to a blank area between two copper/aluminum foils of the bell on the flaky film, so that the transfer speed of the flaky coating on the traction film can be matched with the feeding speed of the flaky film.
S222: waste removal in the width direction: cutting off the coating layer scraps on the traction film along the width direction of the traction film by a coating slicing mechanism 400; since the edges of the sheet-like paint in the width direction are irregular curves after rolling, the scraps at the edges in the width direction are cleaned before the sheet-like paint (the width of the paint at the beginning of rolling is increased by about 15mm from the required width on one side), and the sheets with the same width size are left, so that the shapes of the sheet-like paint are the same.
S23: and (3) transferring a negative electrode coating: transferring the flaky negative electrode coating on the traction film to a polar film provided with copper/aluminum foil;
s231: stripping: the sliced coating and the traction film are sent into the stripping and laminating mechanism 500, and the traction film is stripped from the sheet material in a mode of realizing large-angle foldback stripping through the cooperation of the stripping and blanking assembly 501 and the first long frame 1011.
S232: waste material blowing: after the traction film and the flaky paint are stripped, waste materials between two adjacent flaky paint can be sent into a gap between a first long frame 1011 and a second long frame 1012, and the detection of a blank area between two adjacent copper/aluminum foils on the polar film by a second color mark sensor 505 controls the blowing component 503 to jet high-pressure air flow so as to flow down the waste materials.
S233: and (3) covering: the stripped sheet paint has certain self-supporting strength, so that one side of the sheet paint enters a gap between the first long frame 1011 and the second long frame 1012 to be in contact with the sheet film unreeled by the coating and feeding assembly 502, and the sheet paint is transferred from the traction film to the sheet film provided with copper/aluminum foil.
S234: speed adjustment: the gap between two adjacent copper/aluminum foils on the pole piece film is detected by the first color mark sensor 504, and the conveying speed of the traction film is adjusted in cooperation with the punching position of the cutting die, so that the positioning precision of the flaky paint and the copper/aluminum foils is improved.
S3: positive and negative electrode lamination production line 3: and (3) coating and combining the anode coating and the cathode coating to prepare the final micro-battery cell.
S31: and (3) laminating the anode and the cathode: the positive electrode coating and the negative electrode coating are sent into the positive and negative electrode pressure combining mechanism 700, and the positive electrode coating and the negative electrode coating are pressed together.
S311: positive electrode overturning: the sheet-shaped coating of the positive electrode is turned 180 degrees through the reversing roller, so that the sheet-shaped coating of the positive electrode can be arranged opposite to the sheet-shaped coating of the negative electrode along the vertical direction, and the lamination is convenient.
S312: pressing: the turned positive plate-like paint and negative plate-like paint are sent into a gap between the reversing roller and the second long frame 1012 of the negative production line 2, so that the positive plate-like paint and the negative plate-like paint are pressed together.
S313: positioning and adjusting: the flaky paint on the electrode sheet film of the negative electrode is monitored in real time through a second color code sensor 505 on the negative electrode production line 2; the third color code sensor 702 on the positive electrode production line 1 monitors the flaky paint on the pole piece film of the positive electrode in real time; when the lamination of the sheet-shaped coating of the positive electrode and the sheet-shaped coating of the negative electrode deviates, the reversing roller can be controlled to move according to the monitoring result of the second color code sensor 505 on the negative electrode production line 2 and the third color code sensor 702 on the positive electrode production line 1, so that fine adjustment is realized, and the deviation of the alignment generated by the sheet-shaped coating of the positive electrode and the sheet-shaped coating of the negative electrode is compensated.
S32: and (3) laminating the anode and the cathode: the pressed material strips enter a heat sealing mechanism 800, and the positive electrode and the negative electrode are subjected to heat lamination through a heating and fast compacting process; and, the heat sealing die for realizing heat sealing of the heat sealing mechanism 800 synchronously moves along the conveying direction of the material belt and the material belt, so that the material belt can be heat sealed on the premise of not stopping the material belt.
S33: traction and deviation correction: the material belt after thermal lamination is sent into a traction mechanism 1000, and the traction mechanism 1000 realizes the conveying of the material belt through the cooperation of a lower roller 1001 and an upper press roller 3031; and when the material belt is deviated, the deviation correction of the material belt can be realized by controlling the rotation speed difference of the two upper press rollers 3031.
S34: cutting: the material strip after heat sealing is sent into a cutting mechanism 900 under the action of a traction mechanism 1000, and is cut into single micro-cells by a cutting tool. And the cutting tool synchronously moves with the material belt along the conveying direction of the material belt, so that the material belt can be cut on the premise of not stopping the material belt.
The implementation principle of the embodiment of the application is as follows: through the process, the continuous production process of the micro-battery cell is realized, repeated positioning is not needed in the whole process, and therefore the yield of products can be improved.
The embodiments of the present application are all preferred embodiments of the present application, and are not intended to limit the scope of the present application, wherein like reference numerals are used to refer to like elements throughout. Therefore: all equivalent changes in structure, shape and principle of the application should be covered in the scope of protection of the application.